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Saltwater intrusion, which can be facilitated by natural conditions, human activities and climate change, is a big threat to mankind from social-economic, environmental and ecological perspective. Agriculture, the largest consumer of water, is identified as both contributor and most vulnerable sector to saltwater intrusion, especially in coastal low-lying areas, with the increasing demands and competition of water owing to economic bloom, population growth and climate fluctuations. Sustainable water resource management is urgently needed owing to its essential in solving this issue. Hence this study is to deliver the understanding of linkage between saltwater ingress and agriculture and seek appropriate water resource management strategies in coastal low-lying areas to address saltwater intrusion and reduce its impacts on agriculture.   This study conducts a comparative case study between Texel, the Netherlands and Shouguang, China to specify the linkages between saltwater intrusion and agriculture with local features. The reasons, impacts and associated mitigations and/or adaptations of the issue, together with the legislation of each region have been investigated and compared.   The results show that for combating the saltwater intrusion and reducing the losses from agriculture, both study areas have adapted specific approaches. Among them similar approaches, despite different legislations and policies, such as developing alternative water resource (treated wastewater and rainwater) and saline agriculture are implemented by both of the regions. Through the comparison, each can learn the lessons from the other. The integrated water legislation together with its effective implementation, the strong involvements of different stakeholders and ecological approach to post-treat effluent of Texel can no doubt inspire Shouguang. While the highlights of counteract measures taken by Shouguang such separating rainwater from wastewater during collection and treatment, water diversion and development of special market to achieve high profit for saline products can obviously inspire Texel as well.   The analysis and comparison between these two case studies can reflect the general problems regarding to water management on saltwater intrusion and agriculture in all the regions that suffer from this problem. Hence, it is concluded that 1) integrated water legislation and management (with climate change considered and integrated as well) are the foundations, while water conservation should be core idea that always kept in mind; 2) strong involvements of different stakeholders and necessary supervision systems can guarantee the effectiveness of implementation; 3) all actions should be based on both technical knowledge and local-cultural knowledge; 4) self-sufficient approaches should be promoted at micro level to reduce the dependency on external water intrusion; 5) economic means should be carefully combined with environmental and ecological ways as well to achieve the goal of development of sustainability; 6) monitoring systems are of great significance.

This dissertation, which is both exploratory and descriptive in nature, initially describes the development of the polygraph against a background of understanding society's rejection of the lying phenomenon. The theoretical foundations of polygraph thinking are then presented as forerunner to practical illustration of polygraph use in the private sector. The criminal justice system represents the sphere of polygraph ulitization central to the research. With strong American accent, polygraph use in all four components of the system is described in such a manner so as to provoke thought on the part of criminal justice functionaries as to polygraph possibilities in the execution of their functions. Research findings and recommendations aimed at stimulating thought and improvement in the field of polygraphy conclude the dissertation. / Criminology / M.A (Penology)

This is an examination of the predictive validity of two personality scales, the NEO PPI and the CRT-HR when administered to a sample of 595 Psychiatric Aide job applicants. The research design also tests the moderating advantages of two faking suppression techniques, the use of a lie scale and warning the test takers. The individual applicant profile provided by the screen was evaluated with criterion including turnover, performance, absenteeism and employee injury collected six months after employment began.

L'inondation est l'un des principaux risques d'origine naturelle dans le monde. Face à ce risque amplifié par le changement climatique, penser les stratégies de gestion est devenu fondamental, particulièrement sur les côtes basses. La perception du risque, notion complexe renvoyant à des aspects cognitifs, sociaux, économiques et environnementaux, constitue un réel apport pour révéler les points de vulnérabilité des populations. Cette thèse porte sur l'analyse de la perception du risque d'inondation de la population de la communauté urbaine de Dunkerque. Sur ce territoire, situé sur une côte basse densément peuplée, urbanisée et historiquement concernée par l'inondation, une large enquête de perception a été menée auprès des habitants et des acteurs de la gestion du risque. Le but étant de mesurer leur perception du risque d'inondation et de mettre en évidence les différents facteurs qui l'influencent. L'enquête a été menée selon une méthodologie se situant à la croisée de plusieurs disciplines (géographie, sociologie, psychosociologie et économie). Les résultats mettent en évidence, dans la population : (1) une perception dissonante du risque d'inondation et une faible préoccupation à son sujet ; (2) des représentations spatiales du risque très différentes des officielles ; (3) l'influence de la perception du risque sur le consentement à payer pour s'en prémunir. Cette thèse fournit un apport pour les sciences cindyniques et la géographie des risques. Elle propose des adaptations pour diminuer la vulnérabilité de ces habitants face aux inondations. / Flooding is one of the world's main natural hazards. In view of this risk, being amplified by climate change, management has become crucial, especially in low-lying coastal areas. Risk perception, as a complex notion referring to cognitive, social, economic and environmental aspects, is a real contribution to reveal the vulnerability points of populations. This PhD thesis adresses the analysis of the population's perception of the flood risk within the "Communauté Urbaine de Dunkerque". In this territory, located on a densely populated, urbanized and historically flood-affected low-lying coastal area, a large perception survey was carried out among inhabitants and risk management stakeholders. Its aim was to measure their flood risk perception and to bring to light various factors that influence it. The survey was conducted according to a methodology at the crossroads of several disciplines (geography, sociology, psychosociology and economics). The results highlight : (1) a discordant perception of this risk and a low concern ; (2) spatial risk representations very different from official ones ; (3) the influence of risk perception on willingness to pay to prevent themselves from risk. This thesis provides input to cindynics sciences and risk geography. It suggests adjustments to reduce these inhabitant's vulnerability to flood risk.

<p></p><p></p><p>The unprecedented properties of 2D materials such as graphene and MoS2 have been researched extensively [1,2] for a range of applications including nanoscale electronic and optoelectronic devices [3–6]. Their unique physical and electronic properties promise them as the next generation materials for electrodes and other functional units in nanostructured devices. However, successful incorporation of 2D materials into devices entails development of high resolution patterning techniques that are applicable to 2D materials. Patterning at the sub-10 nm scale is particularly of great interest as the next technology nodes require patterning of (semi)conductors and insulators at 7 nm and 5 nm scales for nanoelectronics. It will also benefit organic photovoltaic cells as phase segregation of p/n-type semiconducting polymers on 2D electrodes at length scales smaller than the typical exciton diffusion length (10 nm)</p> <p>is expected to improve the charge separation efficiency [7].</p><br><p></p><p></p><p>Characterizing locally modulated properties of non-ovalently functionalized 2D materials requires high-resolution imaging techniques capable of extracting measurements of various physical/chemical properties. One such method is scanning probe microscopy (SPM) [18–21]. In Chapter 1, we present a brief review of SPM modalities, some of which are used to characterize interfacial properties, such as conductivity and local contact potential differences that can be modulated by amphiphilic assemblies [17, 22]. Atomic force microscopy (AFM) is one of main techniques that we use to determine topography. All imaging in this work were performed in attractive AC mode [23,24] in order to minimize disruption to the self-assembly of the amphiphiles by the scanning tip.</p><br><p></p><p></p><p>One challenge of using SAMs for locally modulated functionalization is that the proximity to the nonpolar interface can modify the behavior of the functionalities present on the surface in conjunction with the steric hindrance of 2D molecular assemblies. For instance, ionizable functional groups, one of the strongest local modulators of surface chemistry, undergo substantial pKa shifts (in some cases, > 5 units) at nonpolar interfaces, limiting their ability to ionize. In order to apply molecular assembly to create 2D chemical patterns, we needed to design alternative structures that can avoid such penalties against the intrinsic properties of functionalities present in the assemblies. Among amphiphiles, we observed that the chiral centers of phospholipids have the potential of elevating the terminal functional group in the head from the surface for improved accessibility. We refer to this type of assembly as a ’sitting’ phase. Chapter 2 describes sitting phase assembly of phospholipids; the projection of the terminal functionality allows it to maintain solution phase-like behavior while the dual alkyl tails provide additional stabilizing interactions with the substrates. Given the diversity of phospholipid architecture [25], the sitting phase assembly suggests the possibility of greatly diversifying the orthogonality of the chemical patterns, allowing highly precise control over surface functionalities.</p><br><p></p><p></p><p>While a variety of methods including drop-casting [26–28] and microcontact printing [29] have been used previously by others for noncovalent assembly of materials on the surface, they mostly address patterning scale in the sub-μm range. Here, we utilize Langmuir-Schaefer(LS) transfer, which has been historically used to transfer standing phase multilayers [30], and lying-down domains of PCDA at < 100 nm scales in the interest of molecular electronics [14, 31–33], as our sample preparation technique. LS transfer is remarkable in that the transferred molecules relinquish their pre-existing interactions in the standing phase at air-water interface to undergo ∼ 90◦ rotation and assemble into the striped phase on a substrate. This introduces the possibility of modulating local transfer rate across the substrate by manipulating local environment of the molecules. Thus, LS transfer has the potential to offer spatial control over the noncovalent chemical functionalization of the 2D substrate, essential in device applications.</p><br><p></p><p></p><p>In Chapter 3 and 4, We make comparative studies of various experimental factors such as surface pressure, temperature and molecular interactions that affect the efficiency of LS conversion. Considering the energetics of the transfer process, we predicted that the rate of transfer from the air-water interface to the substrate should be the highest from the regions around defects, which would be the energetically</p> <p>least stable regions of the Langmuir film [34, 35]. In Langmuir films, two phases of lipid assemblies—liquid expanded (LE) and liquid condensed (LC)—often coexist at the low surface pressures (< 10 mN/m) used for sample preparation. Hence, we hypothesized that the microscale structural heterogeneity of Langmuir films could be translated into microscale patterns in the transferred film on HOPG. We compare the transfer rates between LE and LC phases and investigate the impacts of physical conditions during LS transfer such as temperature, packing density, dipping rate and contact time to conclude that local destabilization of Langmuir films leads to increased transfer efficiency. (Chapter 3)</p><p><br></p><p></p><p>As in the case of lipid membranes that reorganize routinely based on the structure of the constituent molecules [36–38], the structure of Langmuir films is strongly dependent on the molecular structures of the constituent molecules [39–43]. Accordingly, we expected the molecular structures/interactions to provide additional control over the LS transfer process. In Chapter 4, we compare domain morphologies and the average coverages between three single chain amphiphiles and two phospholipids, each</p><p></p><p> </p><p>of which contain hydrogen bonding motifs of varying strengths. We show that by influencing the adsorption and diffusion rates, molecular architecture indeed influences LS conversion efficiency and subsequent assembly on the substrate. The presence of strong lateral interactions limits transfer and diffusion, forming vacancies in the transferred films with smaller domain sizes while weaker intermolecular interactions enabled high transfer efficiencies.</p><p></p><p><br></p><p></p>

No description available.

A discrete analogue of the Witten Laplacian on the n-dimensional integer lattice is considered. After rescaling of the operator and the lattice size we analyze the tunnel effect between different wells, providing sharp asymptotics of the low-lying spectrum. Our proof, inspired by work of B. Helffer, M. Klein and F. Nier in continuous setting, is based on the construction of a discrete Witten complex and a semiclassical analysis of the corresponding discrete Witten Laplacian on 1-forms. The result can be reformulated in terms of metastable Markov processes on the lattice. / In dieser Arbeit wird auf dem n-dimensionalen Gitter der ganzen Zahlen ein Analogon des Witten-Laplace-Operatoren eingeführt. Nach geeigneter Skalierung des Gitters und des Operatoren analysieren wir den Tunneleffekt zwischen verschiedenen Potentialtöpfen und erhalten vollständige Aymptotiken für das tiefliegende Spektrum. Der Beweis (nach Methoden, die von B. Helffer, M. Klein und F. Nier im Falle des kontinuierlichen Witten-Laplace-Operatoren entwickelt wurden) basiert auf der Konstruktion eines diskreten Witten-Komplexes und der Analyse des zugehörigen Witten-Laplace-Operatoren auf 1-Formen. Das Resultat kann im Kontext von metastabilen Markov Prozessen auf dem Gitter reformuliert werden und ermöglicht scharfe Aussagen über metastabile Austrittszeiten.

In recent decades historians have 'discovered' agency in a wide range of geographical and temporal contexts, amongst many different types of actor. This dissertation employs the concept of agency to dissect the dynamics of power in early nineteenth-century London charities. Concurrently, it uses charity to test the potential applications of agency as a historical concept and as a tool for historical analysis. Through case studies of five different types of charity in early nineteenth-century London, this dissertation explores the varied ways in which plebeians exercised their agency. The case studies engage with current definitions of agency 'intentional action, resistance, the defence of rights and customs, exerting control over one's own life, autonomy, strategy, choice, and voice' and test the boundaries of the concept, proposing different ways in which scholars might characterise agency. This dissertation not only examines how the poor exerted their agency, but also how philanthropists conceptualised the agency of the poor. Although agency had a different set of meanings in the early nineteenth century than it does today, Georgian commentators nevertheless discussed the same phenomena that historians today label as agency. This dissertation considers how philanthropists attempted to mould the agency of their beneficiaries and how the agency of the poor shaped charitable organisations. For all its prevalence, agency is an under-theorised and problematic concept. There is no consensus about what agency is or how to locate it. As a result, agency is a slippery concept that seems to elude meaning. Historians are often so personally invested in the project of recovering the agency of subalterns that they underestimate the structural constraints acting on agency or they project modern conceptions of agency on to the subjects of their study. This dissertation subjects agency to critical examination that is long overdue. It argues that agency, as an 'essentially contested' concept, is a powerful tool for dissecting subtle and diverse dynamics of power. This dissertation proposes and demonstrates ways in which scholars can employ the concept usefully, mitigating its problematic aspects.

This dissertation thesis called 'Lie Detection Through Verbal and Nonverbal Behavior' deals with lying and lies from the viewpoint of its types, functions and considering the development of an individual and it describes the role of lying in our lives. Lying itself is not considered as a negative term, but as a type of communication, a social phenomenon, which is a part of our everyday existence. Attention is aimed to verbal behaviour, but especially to nonverbal aspects of lying persons. Then it examines the use of information on lying and lies in the system of forensic psychology during the deception detection tests. It describes historical approaches to lie detection and its current appearance as well as some other aspects, that may be considered lying even if they are not lying at all - false memories or suggestions. The empirical part compares two research designs, one of them trying to find possible personal determinants of successful lie detectors on a group of psychology students and connecting lie detection ability with the concept of emotional inteligence. The second research analyzes the ability to detect deception among Czech police officers as a specific population group, that uses lie detection methods as a means of investigation. Keywords: lying, deception detection, nonverbal...