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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
191

Analyse de la diversité et de la structuration spatio-temporelle des assemblages démersaux dans la zone économique exclusive mauritanienne / Analysis of the diversity and spatio-temporal structuring of demersal assemblages in Mauritania's exclusive economic zone

Kide, Saïkou Oumar 11 April 2018 (has links)
La zone économique exclusive Mauritanienne est le siège d’upwelling et constitue une zone de transition où cohabitent des espèces d’affinités tempérée et tropicale. Pour comprendre le comportement spatio-temporel des assemblages démersaux du point de vue de leur composition, structuration, distribution de probabilité et diversité face aux préoccupations écologiques. Les facteurs abiotiques contribuent à la structuration des assemblages démersaux persistants au cours du temps. Les effets de la pêche étaient relativement faibles. Les trajectoires temporelles entre les assemblages et les conditions environnementales ont été mises en évidence pour certaines années et des zones. Dans les types d’habitats, un groupe minoritaire d’espèces très agrégatives obéissant au modèle de distribution en log-séries de Fisher et un autre majoritaire peu ou pas du tout agrégatives obéissant au modèle de distribution binomiale négative tronquée ont été identifiés. La diversité spécifique peut être divisé en deux groupes distincts et complémentaires : la richesse spécifique et l'autre associé à l’équitabilité. Un seul composant de la diversité ne peut donc pas représenter la diversité des poissons démersaux de la zone étudiée. Les GLM des indices complémentaires ont montré essentiellement un effet temporel et l’interaction Année-Strates bathymétriques. Aucun effet de l’effort de pêche n’a été observé sur la richesse spécifique, ni de la concentration en chlorophylle sur l’équitabilité. Ce travail pourrait fournir aux gestionnaires et aux scientifiques des connaissances complémentaires sur la dynamique spatio-temporelle des assemblages démersaux exploités dans des écosystèmes d’upwelling. / The Mauritanian exclusive economic zone is the seat of an upwelling phenomenon and constitutes a transition zone where species of temperate and tropical affinities coexist. To understand the spatio-temporal behavior of demersal assemblages from the point of view of their composition, structure, distribution of probability and diversity faced to ecological concerns. Abiotic factors contribute in the structuring of persistent groundfish assemblages over time. The fishing effects were relatively low, although significant in some years and in some specific geographic areas. Temporal trajectories between groundfish assemblages and environmental conditions have been highlighted for some years and in some specific areas. In each type habitats, two species groups were identified: a minority group of species very aggregative well fitted by Fisher’s log-series distribution and another majority of species little or not aggregative well fitted by the truncated negative binomial distribution. Diversity indices analyzed reveal that this set can be split into two distinct and complementary groups: a group associated with the species richness and another group associated with evenness. One component of diversity may not represent the diversity of the groundfish in the study area. GLMs of complementary indices showed essentially a temporal effect and Bathymetric strata-Year interaction. No effect of fishing effort was observed on the species richness and neither was the concentration of chlorophyll a on the evenness. This work could provide managers and scientists to further knowledge on the spatio-temporal dynamics of groundfish species assemblages exploited in upwelling ecosystems.
192

Lietuvos Respublikos jūros erdvių delimitavimas / Maritime delimitation of the republic of lithuania

Keniausytė, Aušra 24 November 2010 (has links)
Darbe nagrinėjamas Lietuvos Respublikos jūros erdvių delimitavimas po nepriklausomybės atkūrimo. Pirmiausia pateikiamos jūros erdvių sąvokos, jų delimitavimo principai, nustatyti atitinkamose konvencijose ir Tarptautinio Teisingumo Teismo praktikoje. Po to yra analizuojamos Lietuvos derybos dėl jūros erdvių delimitavimo su kaimyninėmis valstybėmis – aptariama derybų eiga, pateikiamos pozicijos atitinkamais klausimais, jų pagrindimas, derybų rezultatai. Derybų pozicijos bei rezultatai yra vertinami pagal konvencijas, nustatančias jūros erdvių delimitavimą, ir pagal teismų praktiką. / The object of this work is the analysis of maritime delimitation of the Republic of Lithuania after the independence reestablishment. Firstly it is presented maritime definitions, principles of the maritime delimitation established in the conventions and in the case of law. Latter in the work it is analyzed Lithuanian negotiations with the neighbourhood states on the maritime delimitation. It is discussed the processes of the negotiations, presented the positions on the respective questions, the substantiation of the mentioned positions, the results of the negotiations. The positions and outcomes of the negotiations are estimated according to the conventions on the maritime delimitations and according to the case of law.
193

Política internacional dos oceanos : caso brasileiro sobre o processo diplomático para a plataforma continental estendida / International ocean policy : Brazilian case of the diplomatic process for the extended continental shelf brazilian case of the diplomatic process for the extended continental shelf

Marroni, Etiene Villela January 2013 (has links)
A diversidade do uso do espaço oceânico e a antiga concepção da “doutrina da liberdade dos mares” forçou uma readequação do ordenamento político-econômico e espacial do ecossistema oceânico. Este redirecionamento, que envolveu o sistema internacional, originou uma nova geopolítica ou uma nova ordem global para o planejamento espacial oceânico, nos termos da Convenção das Nações Unidas sobre o Direito do Mar (CNUDM). Em razão de tais alterações, contextualizar-se-á a história do mar territorial brasileiro, em 1970, e suas implicações políticas nacionais e internacionais. Após, serão averiguadas as coalizões integradas pelo Brasil em uma aparente “batalha diplomática”, que se estendeu além de nove anos, envolveu mais de 130 países e originou um dos tratados mais bem sucedidos da história: a Convenção das Nações Unidas sobre o Direito do Mar. A partir de então, dentre outras conquistas, os Estados Partes garantiram o seu direito legal ao solo e subsolo marinho, mediante submissões para a plataforma continental além das 200 milhas náuticas, definidos no artigo 76 da Convenção. Tal conquista possibilitou aos países em desenvolvimento e a pequenas nações insulares acesso a valiosos recursos naturais, como o petróleo, gás e minerais. Os Estados costeiros, signatários da Convenção, passaram a ter assegurado o direito de reivindicar seu território submerso, ou a plataforma continental estendida, para até 350 milhas náuticas. Com a nova regulamentação, a análise das submissões passou a ser feita pela Comissão de Limites da Plataforma Continental (CLPC), organismo derivado da CNUDM, onde especialistas, selecionados segundo o critério de equidade geográfica, aceitam, modificam ou rejeitam as reivindicações. Demonstrar-se-á procedimentos adotados por Estados costeiros (insulares ou arquipelágicos) ao solicitar a ampliação de seus limites oceânicos, o modo dos especialistas brasileiros trabalharem a ampliação da plataforma continental estendida e de que forma foi feito o planejamento e o gerenciamento em termos políticos, através da Comissão Interministerial para os Recursos do Mar. Finalmente, averiguar-se-á se o Governo do Brasil terá condições de assumir tal responsabilidade, considerando o possível aumento de suas fronteiras e a capacidade do Estado, em termos científicos, tecnológicos e políticos, de internalizar e cumprir os preceitos da Convenção em sua política nacional para o mar. / The diversity of uses of the oceanic space and the old conception of “freedom of the seas doctrine” has compelled an adaptation of the political-economic and spatial legal framework for the oceanic ecosystem. This changing of direction encompassed the international system and has given rise to a new geopolitics for the legal framework of oceanic spaces around the globe, in terms of the United Nations Convention on the Law of the Sea (UNCLOS). Because of such modifications, this study contextualizes the history of Brazilian territorial sea in 1970 and its political implications, on the national as well as on the international level. After that, it examines the alliances Brazil has formed, engaging in a so called “diplomatic battle”. This process went on for over nine years, comprised more than 130 countries and originated one of the most successful treaties in history: the United Nations Convention on the Law of the Sea. Since then, the signatory states managed to secure their legal rights over the maritime soil and subsoil by means of submissions for the continental shelf beyond 200 nautical miles, as defined by the Convention in its article 76. This achievement was of utmost importance because it enabled developing countries and small island states to access valuable natural resources such as oil, gas and minerals. Every coastal state who has signed the Convention acquired the right to claim its underwater territory or extended continental shelf up to 350 nautical miles from its coast. Due to the new regulations, the Commission on the Limits of the Continental Shelf (CLCS) began to undertake the analysis of submissions. This Commission is a body set up by the UNCLOS, in which experts, selected according to the criterion of geographic equity will accept, modify or reject claims. Furthermore, this study aims to account for procedures taken by coastal, insular, and archipelagic states when claiming the extension of its oceanic limits, with the main focus on measures taken by Brazil. More specifically, it intends to explain how Brazilian experts have brought about the expansion of the extended continental shelf and in which way planning and management, in political terms, can be carried out through the Interministerial Commission for Maritime Resources. Ultimately, it will be examined if the Brazilian government is able to assume such responsibility in the face of the growth of its borders and the capability of the state, in scientific, technological and political terms, of incorporating and enforcing the precepts of the Convention in its national policy for the seas.
194

Monitoramento ambiental da costa do Rio Grande do Norte com base em sensoriamento remoto e geod?sia de precis?o

Ferreira, Anderson Targino da Silva 16 September 2013 (has links)
Made available in DSpace on 2015-02-24T19:48:45Z (GMT). No. of bitstreams: 1 AndersonTSF_TESE_ Capa_ate_pag22.pdf: 11459625 bytes, checksum: fd30a979bc39cf6180f782c772106ee3 (MD5) Previous issue date: 2013-09-16 / Coordena??o de Aperfei?oamento de Pessoal de N?vel Superior / This paper presents models of parameters of Sea Surface Layer (SSL), such as chlorophyll-a, sea surface temperature (SST), Primary Productivity (PP) and Total Suspended Matter (TSM) for the region adjacent to the continental shelf of Rio Grande do Norte (RN), Brazil. Concentrations of these parameters measured in situ were compared in time quasi-synchronous with images AQUA-MODIS between the years 2003 to 2011. Determination coefficients between samples in situ and bands reflectance sensor AQUA-MODIS were representative. From that, concentrations of SSL parameters were acquired for the continental shelf of the RN (eastern and northern) analyzing the geographic distribution of variation of these parameters between the years 2009-2012. Geographical and seasonal variations mainly influenced by global climate phenomena such as El Ni?o and La Ni?a, were found through the analysis of AQUA-MODIS images by Principal Components Analysis (PCA). Images show qualitatively the variance and availability of TSM in the regions, as well as their relationship with coastal erosion hotspots, monitored along the coast of the RN. In one of the areas identified as being of limited availability of TSM, we developed a methodology for assessment and evaluation of Digital Elevation Models (DEM) of beach surfaces (emerged and submerged sections) from the integration of topographic and bathymetric data measured in situ and accurately georeferenced compatible to studies of geomorphology and coastal dynamics of short duration. The methodology consisted of surveys with GNSS positioning operated in cinematic relative mode involved in topographic and bathymetric executed in relation to the stations of the geodetic network of the study area, which provided geodetic link to the Brazilian Geodetic System (GBS), univocal , fixed, and relatively stable over time. In this study Ponta Negra Beach, Natal / RN, was identified as a region with low variance and availability of MPS in the region off, as characterized by intense human occupation and intense coastal erosion in recent decades, which presents potential of the proposed methodology for accuracy and productivity, and the progress achieved in relation to the classical methods of surveying beach profiles / Este trabalho apresenta modelos de par?metros da Camada Superficial do Mar (CSM), tais como: Clorofila-a, Temperatura da Superf?cie do Mar (TSM), Produtividade Prim?ria (PP) e Material Particulado em Suspen??o (MPS), para a regi?o adjacente a plataforma continental do Rio Grande do Norte (RN), Brasil. Concentra??es desses par?metros medidos in situ foram comparadas em tempo quase-s?ncronos com imagens AQUAMODIS entre os anos de 2003 at? 2011. Coeficientes de determina??o foram representativos entre as amostras in situ e as bandas de reflect?ncia do sensor AQUAMODIS. A partir disso, concentra??es de par?metros da CSM foram adquiridos para a plataforma continental do RN (Plataforma Oriental e Setentrional) analisando a distribui??o geogr?fica da varia??o desses par?metros entre os anos de 2009-2012. Varia??es geogr?ficas e sazonais influenciadas principalmente por fen?menos clim?ticos globais como o fen?meno El Ni?o e La Ni?a, foram constatadas atrav?s das an?lises das imagens AQUA-MODIS por an?lise de Principais Componentes (PC). As imagens apontam de maneira qualitativa a vari?ncia e disponibilidade do MPS nas regi?es, assim como sua rela??o com hotspots de eros?o costeira, monitorados ao longo do litoral do RN. Em uma das regi?es identificadas como sendo de pouca disponibilidade de MPS, foi desenvolvida uma metodologia para levantamento e avalia??o de Modelos Digitais de Eleva??o (MDE) de superf?cies praiais (setores emersos e submersos) a partir da integra??o de dados topogr?ficos e batim?tricos mensurados in situ e georreferenciados com precis?o compat?vel aos estudos de geomorfologia e din?mica costeira de curta dura??o. A metodologia desenvolvida consistiu de levantamentos com posicionamentos GNSS operados no modo relativo cinem?tico envolvidos nos levantamentos topogr?ficos e batim?tricos executados em rela??o ?s esta??es da rede geod?sica da ?rea de estudo, que forneceram referencial geod?sico vinculado ao Sistema Geod?sico Brasileiro (SGB), o qual ? un?voco, fixo e relativamente est?vel no tempo. No estudo foi apresentado a Praia de Ponta Negra, Natal/RN, identificada como uma regi?o com baixa vari?ncia e disponibilidade de MPS ao largo, assim como, caracterizada por intensa ocupa??o antr?pica e intensa eros?o costeira nas ?ltimas d?cadas, no qual s?o apresentadas as potencialidades da metodologia proposta, quanto ? acur?cia e produtividade, al?m dos avan?os alcan?ados em rela??o aos m?todos cl?ssicos de levantamento de perfis de praia
195

Política internacional dos oceanos : caso brasileiro sobre o processo diplomático para a plataforma continental estendida / International ocean policy : Brazilian case of the diplomatic process for the extended continental shelf brazilian case of the diplomatic process for the extended continental shelf

Marroni, Etiene Villela January 2013 (has links)
A diversidade do uso do espaço oceânico e a antiga concepção da “doutrina da liberdade dos mares” forçou uma readequação do ordenamento político-econômico e espacial do ecossistema oceânico. Este redirecionamento, que envolveu o sistema internacional, originou uma nova geopolítica ou uma nova ordem global para o planejamento espacial oceânico, nos termos da Convenção das Nações Unidas sobre o Direito do Mar (CNUDM). Em razão de tais alterações, contextualizar-se-á a história do mar territorial brasileiro, em 1970, e suas implicações políticas nacionais e internacionais. Após, serão averiguadas as coalizões integradas pelo Brasil em uma aparente “batalha diplomática”, que se estendeu além de nove anos, envolveu mais de 130 países e originou um dos tratados mais bem sucedidos da história: a Convenção das Nações Unidas sobre o Direito do Mar. A partir de então, dentre outras conquistas, os Estados Partes garantiram o seu direito legal ao solo e subsolo marinho, mediante submissões para a plataforma continental além das 200 milhas náuticas, definidos no artigo 76 da Convenção. Tal conquista possibilitou aos países em desenvolvimento e a pequenas nações insulares acesso a valiosos recursos naturais, como o petróleo, gás e minerais. Os Estados costeiros, signatários da Convenção, passaram a ter assegurado o direito de reivindicar seu território submerso, ou a plataforma continental estendida, para até 350 milhas náuticas. Com a nova regulamentação, a análise das submissões passou a ser feita pela Comissão de Limites da Plataforma Continental (CLPC), organismo derivado da CNUDM, onde especialistas, selecionados segundo o critério de equidade geográfica, aceitam, modificam ou rejeitam as reivindicações. Demonstrar-se-á procedimentos adotados por Estados costeiros (insulares ou arquipelágicos) ao solicitar a ampliação de seus limites oceânicos, o modo dos especialistas brasileiros trabalharem a ampliação da plataforma continental estendida e de que forma foi feito o planejamento e o gerenciamento em termos políticos, através da Comissão Interministerial para os Recursos do Mar. Finalmente, averiguar-se-á se o Governo do Brasil terá condições de assumir tal responsabilidade, considerando o possível aumento de suas fronteiras e a capacidade do Estado, em termos científicos, tecnológicos e políticos, de internalizar e cumprir os preceitos da Convenção em sua política nacional para o mar. / The diversity of uses of the oceanic space and the old conception of “freedom of the seas doctrine” has compelled an adaptation of the political-economic and spatial legal framework for the oceanic ecosystem. This changing of direction encompassed the international system and has given rise to a new geopolitics for the legal framework of oceanic spaces around the globe, in terms of the United Nations Convention on the Law of the Sea (UNCLOS). Because of such modifications, this study contextualizes the history of Brazilian territorial sea in 1970 and its political implications, on the national as well as on the international level. After that, it examines the alliances Brazil has formed, engaging in a so called “diplomatic battle”. This process went on for over nine years, comprised more than 130 countries and originated one of the most successful treaties in history: the United Nations Convention on the Law of the Sea. Since then, the signatory states managed to secure their legal rights over the maritime soil and subsoil by means of submissions for the continental shelf beyond 200 nautical miles, as defined by the Convention in its article 76. This achievement was of utmost importance because it enabled developing countries and small island states to access valuable natural resources such as oil, gas and minerals. Every coastal state who has signed the Convention acquired the right to claim its underwater territory or extended continental shelf up to 350 nautical miles from its coast. Due to the new regulations, the Commission on the Limits of the Continental Shelf (CLCS) began to undertake the analysis of submissions. This Commission is a body set up by the UNCLOS, in which experts, selected according to the criterion of geographic equity will accept, modify or reject claims. Furthermore, this study aims to account for procedures taken by coastal, insular, and archipelagic states when claiming the extension of its oceanic limits, with the main focus on measures taken by Brazil. More specifically, it intends to explain how Brazilian experts have brought about the expansion of the extended continental shelf and in which way planning and management, in political terms, can be carried out through the Interministerial Commission for Maritime Resources. Ultimately, it will be examined if the Brazilian government is able to assume such responsibility in the face of the growth of its borders and the capability of the state, in scientific, technological and political terms, of incorporating and enforcing the precepts of the Convention in its national policy for the seas.
196

Política internacional dos oceanos : caso brasileiro sobre o processo diplomático para a plataforma continental estendida / International ocean policy : Brazilian case of the diplomatic process for the extended continental shelf brazilian case of the diplomatic process for the extended continental shelf

Marroni, Etiene Villela January 2013 (has links)
A diversidade do uso do espaço oceânico e a antiga concepção da “doutrina da liberdade dos mares” forçou uma readequação do ordenamento político-econômico e espacial do ecossistema oceânico. Este redirecionamento, que envolveu o sistema internacional, originou uma nova geopolítica ou uma nova ordem global para o planejamento espacial oceânico, nos termos da Convenção das Nações Unidas sobre o Direito do Mar (CNUDM). Em razão de tais alterações, contextualizar-se-á a história do mar territorial brasileiro, em 1970, e suas implicações políticas nacionais e internacionais. Após, serão averiguadas as coalizões integradas pelo Brasil em uma aparente “batalha diplomática”, que se estendeu além de nove anos, envolveu mais de 130 países e originou um dos tratados mais bem sucedidos da história: a Convenção das Nações Unidas sobre o Direito do Mar. A partir de então, dentre outras conquistas, os Estados Partes garantiram o seu direito legal ao solo e subsolo marinho, mediante submissões para a plataforma continental além das 200 milhas náuticas, definidos no artigo 76 da Convenção. Tal conquista possibilitou aos países em desenvolvimento e a pequenas nações insulares acesso a valiosos recursos naturais, como o petróleo, gás e minerais. Os Estados costeiros, signatários da Convenção, passaram a ter assegurado o direito de reivindicar seu território submerso, ou a plataforma continental estendida, para até 350 milhas náuticas. Com a nova regulamentação, a análise das submissões passou a ser feita pela Comissão de Limites da Plataforma Continental (CLPC), organismo derivado da CNUDM, onde especialistas, selecionados segundo o critério de equidade geográfica, aceitam, modificam ou rejeitam as reivindicações. Demonstrar-se-á procedimentos adotados por Estados costeiros (insulares ou arquipelágicos) ao solicitar a ampliação de seus limites oceânicos, o modo dos especialistas brasileiros trabalharem a ampliação da plataforma continental estendida e de que forma foi feito o planejamento e o gerenciamento em termos políticos, através da Comissão Interministerial para os Recursos do Mar. Finalmente, averiguar-se-á se o Governo do Brasil terá condições de assumir tal responsabilidade, considerando o possível aumento de suas fronteiras e a capacidade do Estado, em termos científicos, tecnológicos e políticos, de internalizar e cumprir os preceitos da Convenção em sua política nacional para o mar. / The diversity of uses of the oceanic space and the old conception of “freedom of the seas doctrine” has compelled an adaptation of the political-economic and spatial legal framework for the oceanic ecosystem. This changing of direction encompassed the international system and has given rise to a new geopolitics for the legal framework of oceanic spaces around the globe, in terms of the United Nations Convention on the Law of the Sea (UNCLOS). Because of such modifications, this study contextualizes the history of Brazilian territorial sea in 1970 and its political implications, on the national as well as on the international level. After that, it examines the alliances Brazil has formed, engaging in a so called “diplomatic battle”. This process went on for over nine years, comprised more than 130 countries and originated one of the most successful treaties in history: the United Nations Convention on the Law of the Sea. Since then, the signatory states managed to secure their legal rights over the maritime soil and subsoil by means of submissions for the continental shelf beyond 200 nautical miles, as defined by the Convention in its article 76. This achievement was of utmost importance because it enabled developing countries and small island states to access valuable natural resources such as oil, gas and minerals. Every coastal state who has signed the Convention acquired the right to claim its underwater territory or extended continental shelf up to 350 nautical miles from its coast. Due to the new regulations, the Commission on the Limits of the Continental Shelf (CLCS) began to undertake the analysis of submissions. This Commission is a body set up by the UNCLOS, in which experts, selected according to the criterion of geographic equity will accept, modify or reject claims. Furthermore, this study aims to account for procedures taken by coastal, insular, and archipelagic states when claiming the extension of its oceanic limits, with the main focus on measures taken by Brazil. More specifically, it intends to explain how Brazilian experts have brought about the expansion of the extended continental shelf and in which way planning and management, in political terms, can be carried out through the Interministerial Commission for Maritime Resources. Ultimately, it will be examined if the Brazilian government is able to assume such responsibility in the face of the growth of its borders and the capability of the state, in scientific, technological and political terms, of incorporating and enforcing the precepts of the Convention in its national policy for the seas.
197

Piritização de elementos-traço em sedimentos recentes do sistema de ressurgência de Cabo Frio (Rio de Janeiro)

Ramírez, Manuel Antonio Moreira 13 April 2016 (has links)
Submitted by Biblioteca de Pós-Graduação em Geoquímica BGQ (bgq@ndc.uff.br) on 2016-04-13T15:18:33Z No. of bitstreams: 1 Mestrado Manuel Moreira.pdf: 7413069 bytes, checksum: 0f15055b235c438ffd4fac6dde85f099 (MD5) / Made available in DSpace on 2016-04-13T15:18:33Z (GMT). No. of bitstreams: 1 Mestrado Manuel Moreira.pdf: 7413069 bytes, checksum: 0f15055b235c438ffd4fac6dde85f099 (MD5) / Coordenação de Aperfeiçoamento de Pessoal de Nível Superior / Fundação de Amparo à Pesquisa do Estado do Rio de Janeiro / Universidade Federal Fluminense. Instituto de Química. Programa de Pós-Graduação em Geociências-Geoquímica. Niterói, RJ / Elementos-tarços são freqüentemente utilizados como indicadores das condições redox e da paleoprodutividade marinha, que podem afetar a distribuição e o fracionamento geoquímico destes elementos. O potencial efeito do ciclo re-oxidativo da pirita sedimentar sobre o grau de piritização destes indicadores (degree of trace metal pyritization – DTMP) não tem sido anteriormente avaliado. Esta avaliação foi realizada em testemunhos sedimentares da plataforma continental sob influência do Sistema de Ressurgência de Cabo Frio (RJ). A relação do DTMP com a assinatura isotópica do S na pirita (δ34S), que se torna mais leve em resposta ao ciclo re-oxidativo da pirita na área de estudo, sugere que a influência pode ser alta (para Pb, As, Cd e Mn), baixa (para Zn e Cu) ou desprezível (para Cr e Ni), dependendo do elemento considerado. Sedimentos mais antigos e ricos em pirita possibilitaram a identificação de um aparente limiar para o efeito da re-oxidação, após o qual os elementos Pb, As, Cd, Mn e Zn apresentaram maior piritização. Um testemunho em posição intermediária na plataforma apresentou correlações negativas das concentrações reativas de Mn, Cu, Ni e Pb com as concentrações de Fe na pirita, assim como outros dois testemunhos apresentaram em relação a Mn e Pb. Isto sugere um consumo de óxidos de Mn (e metais associados) em reação com a pirita, contribuindo para explicar o alto DTMP apresentado pelo Pb, que discorda das predições termodinâmicas e de cinética de incorporação deste metal pela pirita. As assinaturas isotópicas da pirita na área de estudo (que apresenta condições óxicas), foram semelhantes às de ambientes sedimentares anóxicos e euxínicos reportadas na literatura, sugerindo que o ciclo re-oxidativo pode afetar a susceptibilidade de incorporação e a preservação dos elementos na pirita em uma ampla variedade de condições sedimentares. A abordagem metodológica proposta pode subsidiar a melhor interpretação do processo de piritização e suas aplicações para a indicação de condições paleo-redox e de paleo-produtividade / Potential effects of sedimentary pyrite re-oxidative cycling on the degree of trace metals pyritization (DTMP) were evaluated in four sediment cores from the continental shelf under the influence of a tropical upwelling system (Cabo Frio, Brazil). The DTMP relation with stable isotope signals (δ34S) of chromium reducible sulfur, which became lighter in response to intense pyrite re-oxidative cycling in the study area, suggests high (Pb, As, Cd and Mn), low (Zn and Cu) or negligible (Cr and Ni) re-oxidation influences. Oldest pyrite-richer sediments provide an apparent threshold for intense pyrite re-oxidation, after which most trace elements (Pb, As, Cd, Mn and Zn) presented more accentuated DTMP. A middle shelf core presented negative correlations of reactive Mn, Cu, Ni and Pb with pyrite iron, suggesting Mn oxide (and associated metals) depletion in reaction with pyrite. This contributes to explain the observed high degree of Pb pyritization in disagreement with predictions derived from both thermodynamics and water exchange reaction kinetics. Pyrite δ34S signatures under the oxic bottom water from the study area were similar to those from euxinic sedimentary environments, suggesting that pyrite re-oxidative cycling can affect trace element susceptibility to be incorporated and preserved into pyrite in a wide range of sedimentary conditions
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Variabilité spatio-temporelle des flux sédimentaires dans le Golfe de Gascogne : contributions relatives des forçages climatiques et des activités de chalutage / Spatio-temporal variability of sediment fluxes in the Bay of Biscay : relative contributions of climate forcings and trawling activities

Mengual, Baptiste 12 December 2016 (has links)
L'étude de la variabilité spatio-temporelle des flux sédimentaires sous l'influence des forçages naturels et des activités de chalutage a été entreprise à l'échelle du plateau continental du Golfe de Gascogne, en associant des données in situ et une modélisation numérique 3D déterministe. Deux campagnes en mer spécifiques ont été menées pour quantifier les impacts physiques induits par un chalut professionnel au niveau de la Grande-Vasière, en termes de remise en suspension (panache turbide), et de perturbation de la structure et de la nature du sédiment superficiel. Ces données ont permis d'estimer à 0.13 kg.m-2 le taux d'érosion moyen. Leur croisement avec des données d'effort de pêche a conduit à une cartographie mensuelle du flux d'érosion par chalutage. D'autre part, un modèle hydro-sédimentaire 3D réaliste a été mis en place et calibré à partir de mesures au point fixe. Une attention particulière a été accordée au paramétrage de l'érosion naturelle sous l'influence combinée des vagues et des courants. Une nouvelle formulation de la loi d'érosion adaptée aux mélanges de sable fin et de vase classiquement rencontrés sur les plateaux continentaux a été proposée et a permis d'optimiser significativement la réponse du modèle en termes de turbidité. Deux simulations de 5 ans ont été réalisées en incluant ou non l'influence du chalutage de fond, dans le but de quantifier et comparer les contributions relatives des forçages naturels et anthropique sur les flux verticaux (érosion) et horizontaux (transport solide) de sédiments. La variabilité temporelle des flux est décrite en une succession de régimes caractéristiques répondant à divers forçages (e.g. marée, vent, vagues, chalutage), et les flux résiduels saisonniers et annuels sont commentés : sans tenir compte des apports fluviaux, le flux de matériel vaseux a été estimé à 1.6 Mt/an sortant par le nord (au droit de La Pointe du Raz) et à 0.62 Mt/an vers le talus continental (au niveau de l'isobathe 180 m). / The spatio-temporal variability of sediment fluxes under the influence of natural forcings and trawling activities was assessed at the scale of the Bay of Biscay shelf, from in situ data and a 3D process-based numerical modelling. Two sea trials were carried out to quantify physical impacts induced by a professional trawling gear over an intensively trawled area of the shelf, the "Grande-Vasière", in terms of resuspension (turbid plume) and alteration of the surficial sediment nature and structure. These data enabled to estimate an average trawling-induced erosion rate of 0.13 kg.m-2. Their combination with fishing effort data led to monthly spatial distributions of trawling-induced erosion fluxes.Besides, a 3D realistic hydro-sedimentary model has been set up and calibrated from measurements acquired at a mooring station. The calibration task mainly consisted in assessing the natural erosion law setting under the influence of waves and currents. A new formulation of the erosion law has been proposed to describe the erosion of any mixture of mud and fine sand (sediment facies classically encountered on continental shelves) and led to a noteworthy improvement of the model response in terms of turbidity. Two 5-year simulations were performed accounting for natural forcings only or both natural and anthropogenic forcings in order to quantify and compare their respective contributions to sediment fluxes (vertical and horizontal sediment dynamics). The temporal variability of sediment fluxes is described in a succession of typical regimes occurring in response to various conditions of forcings (e.g. tide, wind, wave, trawling), and residual fluxes are assessed at seasonal and annual scales: without accounting for riverine sediment inputs, the mud flux is estimated to 1.6 Mt/yr outflowing northward (at the latitude of the Pointe du Raz) and to 0.62 Mt/yr toward the continental slope (through the 180 m isobath).
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The British North Sea: The Importance Of And Factors Affecting Tax Revenue From Oil Production

Hill, Mark 10 February 2004 (has links) (PDF)
The oil industry is the richest and most influential industry in the world. The industry has moved the fates of nations. Oil is required to fight wars and exert power, and the restriction of this energy source is paramount to the restriction of movement, control, and in the end, power. Management of this resource and the tax revenue it generates are of serious strategic importance, both domestically and internationally. Understanding the results of taxation for this important commodity is important to international relations as well. The tax system affects tax revenue, government actions, oil company actions, and the oil supply itself. Each of these is important to international relations.

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