This work addresses the growth of ultrathin magnetite (Fe3O4) and cobalt ferrite (CoFe2O4) films and their thorough structural, electronic, and magnetic characterization. In a first step, ultrathin Fe3O4 films are grown on SrTiO3(001) substrates by reactive molecular beam epitaxy (RMBE) and the substrate-induced anomalous strain behavior of the films is investigated by complementary high-resolution transmission electron microscopy (HRTEM) and (grazing incidence) X-ray diffraction [(GI)XRD] measurements. Next, an additional CoO film is deposited on similar Fe3O4/SrTiO3(001) heterostructures to demonstrate an alternative route for the synthesis of cobalt ferrite films through the thermally mediated interdiffusion of both oxide films. The evolution from the initial bilayer stacks to completely reacted cobalt ferrite films is extensively monitored by soft and hard X-ray photoelectron spectroscopy (soft XPS and HAXPES) and (GI)XRD. Complete intermixing and formation of single cobalt ferrite films is confirmed by angular-resolved HAXPES (AR-HAXPES) and X-ray reflectivity (XRR). The study of the cationic distribution resulting from this novel synthesis technique and its effects on the magnetic properties of the cobalt ferrite films is the subject of the subsequent part. Here, X-ray magnetic circular dichroism (XMCD) and superconducting quantum interference device (SQUID) magnetometry serve as key investigation techniques, which are further complemented by AR-HAXPES and atomic force microscopy (AFM) measurements. In a final step, highly crystalline cobalt ferrite films with different cationic stoichiometries are grown on MgO substrates using RMBE while their growth behavior is captured in real-time using operando XRD. Further structural characterization of the films is carried out by low-energy electron diffraction and XRR, whereas HAXPES and SQUID provide fundamental information on the electronic, chemical, and magnetic properties of the films.

Friction stir welding (FSW) of HSLA steel commonly produces a hard zone (HZ) on the advancing side (AS) of the weld. Despite its detrimental effects on weld toughness, the mechanisms of its formation have not been thoroughly investigated and are not well understood. This paper investigates the various mechanisms in FSW believed to affect the weld HZ, namely: strain, strain-rate, peak temperature and cooling rate. Gleeble tests indicate that strain and strain rate have negligible effects on weld HZ with cooling rate and peak temperature as dominant effects. Jominy tests resulted in cooling rate having 270% greater influence than peak temperature on the formation of lath ferrite microstructures similar to what is observed in the HZ of FSW X65. Comparing weld HZ microstructures to Jominy tests, it is estimated that cooling rates on the AS of the weld are at least 150°C/s higher than the retreating side. Reducing the cooling rate on the AS will likely lead to an improved microstructure at the weld HZ.

A linear, direct drive, scale model prototype generator has been designed at KTH Royal Institute of technology in Sweden. The prototype is based on a scaled down electromagnetic optimization made by researcher Anders Hagnestål. The aim of the project is to verify the calculations experimentally and by using ferrite magnets, there is an opportunity to develop a competitively priced and environmentally friendly generator for wave power plants. Based on the electromagnetic optimization a mechanical design has been developed using computer aided design (CAD). Structural calculations have been made to ensure that the design withstands the large magnetic forces involved. Furthermore, different techniques and challenges appearing in the build of the prototype have been evaluated and explained. A description of the advantages of the design and the basic electromagnetic design is also included. The build is underway and is expected to be finished during 2018. / En linjär direktdriven generatorprototyp har designats på KTH, Kungliga Tekniska högskolan i Sverige. Prototypen är baserad på en nerskalad elektromagnetisk optimering gjord av Anders Hagnestål. Målet med projektet är att verifiera beräkningar experimentellt och genom att använda ferritmagneter finns det en möjlighet att utveckla en konkurrenskraftig och miljövänligare generator för vågkraftverk. Baserat på den elektromagnetiska optimeringen har en mekanisk design tagits fram med hjälp av datorstödd design (CAD). Hållfasthetsberäkningar har gjorts för att säkerställa att designen klarar av de stora magnetiska krafter den utsätts för. Vidare har även olika tekniker och utmaningar som uppstått i byggnationen utvärderats och beskrivits. En beskrivning av designens fördelar och den grundläggande elektromagnetiska designen har även inkluderats. Byggnationen pågår och beräknas vara färdig under 2018.

No description available.

No description available.

No description available.

No description available.

An impedance-based core loss measurement technique for power ferrites, the modeling and analysis of mechanisms of high-frequency losses, and design methodology for optimization for high-frequency magnetics are presented. The high-frequency losses of ferrite materials are characterized employing a large-signal impedance measurement technique. The impedance analyzer controlled through an IEEE-488 interface, measures the impedance of the inductor under test under large signal excitation via a power amplifier. The core loss is a form of a parallel resistance is derived from measured impedance characteristics. A wideband impedance probe, enables core loss characterization up to 100 MHz. A comprehensive analysis of all major loss mechanisms in ferrites is presented. A new form of residual losses due to a magnetoelectric effect is postulated to account for losses at high frequencies. Two models of losses in ferrites are proposed, one with emphasis on analysis of loss mechanisms, and the other with an emphasis on the design of high-frequency magnetic components. Both models include the important effect of static bias field, which is the case in many power electronics applications. Magnetic losses due to magnetostriction are measured. Dependence of magnetoelastic resonances on the magnetic bias. core material, core shape and size is studied. The influence of diffusion after-effect on core loss under time-varying bias field is investigated. Thermal stability of high-frequency magnetics is studied. A verification of one- and two- dimensional models of winding losses for solid and litz wire is performed. The optimum design method for high-frequency power transformers and inductors is proposed. / PhD

This thesis provides several nanomaterial systems that can be used as contrast agents in magnetic resonance imaging (MRI) and for optical fluorescence imaging. Nanoparticle systems described in this thesis fall under three categories: (a) graphene oxide-nanoparticle composites for MRI contrast agent application, (b) core-shell nanoparticles for MRI contrast agent application and (c) nanoparticle systems for both MRI and optical fluorescence imaging. In the case of graphene oxide based nano-composites, the following observations were made: (i) in the case of graphene oxide-Fe3O4 nanoparticle composite, it was observed that high extent of oxidation of the graphene oxide and large spacing between the graphene oxide sheets containing Fe3O4 nanoparticles provides the optimum structure for yielding a very high transverse proton relaxivity value, (ii) in the case of graphene oxide-Gd2O3 nanoparticle composite, it was observed that this composite exhibits high value for both longitudinal and transverse relaxivity values making it a potential materials for multi-contrast study of pathologies with a single agent, (iii) in the case of graphene oxide-CoFe2O4 nanoparticle composites, it was observed that an increase in the reflux time of the reaction mixture containing this composite led to appreciable variations in the proton relaxivity values. Transverse relaxivity value of the water protons increased monotonically with increase in the reflux time. Whereas, the longitudinal relaxivity value initially increased and then decreased with increase in the reflux time. In the case of coreshell nanoparticles for MRI contrast agent application two different core-shell systems were investigated. They are MnFe2O3-Fe3O4 core-shell nanoparticles and CoFe2O4-MnFe2O4 coreshell nanoparticles. Investigations of both the core-shell nanoparticle systems revealed that the proton relaxivity value obtained in the dispersion of the core-shell nanoparticles was considerably greater than the proton relaxivity value obtained in the presence of single phase nanoparticles of the core and shell phases. Very high value of transverse relaxivity in the case core-shell nanoparticles was due to the large magnetic inhomogeneity created by the core-shell nanoparticles in the water medium surrounding it. In the case of nanoparticle systems for both MRI and optical fluorescence imaging, two different systems were investigated. They were CoFe2O4-ZnO core-shell nanoparticles and Gd doped ZnS nanoparticles [Zn1-xGdxS, x= 0.1, 0.2 and 0.3] formed on graphene oxide sheets or coated with chitosan. In the case of CoFe2O4-ZnO core-shell nanoparticles it was observed that fluorescent CoFe2O4-ZnO core-shell nanoparticles with the unique geometry in which CoFe2O4 ferrite nanoparticles agglomerates were present within larger sized hollow ZnO capsules yields very high value of transverse proton relaxivity when compared to the proton relaxivity value exhibited by the individual CoFe2O4-ZnO coreshell nanoparticles. In the case of Gd doped ZnS nanoparticles, two different systems were synthesized and the values of the longitudinal and transverse proton relaxivity obtained were compared. These systems were (i) graphene oxide- Zn1-xGdxS (x= 0.1, 0.2 and 0.3) nanoparticle composites and (ii) chitosan coated Zn1-xGdxS (x= 0.1, 0.2 and 0.3) nanoparticles. It was observed that Gd doped ZnS nanoparticles in both cases exhibit both longitudinal and transverse relaxivity values. The relaxivity values showed a clear dependence on the composition of the nanoparticles and the nanoparticle environment (presence and absence of graphene oxide). It was also observed that Gd doped ZnS nanoparticle can be used for florescence imaging.

This thesis presents solutions and studies related to the design of wideband antennas for wireless handheld terminal applications. A method of electrically shortening the terminal chassis length to obtain resonance at high frequencies has been proposed and evaluated, thereby increasing the antennas impedance bandwidth. No significant effect on the lower frequency band in a dual-band antenna prototype has been observed, making the method suitable for multi-band applications. The chassis has further been utilized as a zero-thickness 0.9 - 2.7 GHz high efficiency antenna by inserting a notch in the chassis center, and a feasibility study for typical phones has been performed. Additionally, the effect of talk position on the chassis wave-mode has been investigated, where the standard equivalent circuit model for terminal antennas has been modified to include the presence of the users head. The model has been used to explain measured and simulated effects concerning frequency detuning, efficiency reduction and bandwidth enhancements when the terminal is placed in talk position. The use of a hands-free earpiece cord is currently mandatory for FM radio reception as the cord is utilized as antenna. However, there is currently a market driven demand for removing the cord requirement since many modern phones are equipped with speakers and Bluetooth headsets. In this thesis, an active ferrite loop antenna is proposed as an internal replacement/complement with a performance of -23 dB (G/T degradation) compared to a full-size lossless dipole in urban environments. Also, a modification to the cord is suggested for DVB H reception. Complex matching networks have been investigated to increase the bandwidth of dual band PIFA antennas, and a printed dual band dipole has been integrated with a modified Marchand balun for dual resonance at two separate frequency bands, thus covering the commercial cellular bands 824-960 and 1710-2170 MHz with a single antenna.