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No description available.

京都大学 / 新制・課程博士 / 博士(工学) / 甲第24903号 / 工博第5183号 / 新制||工||1989(附属図書館) / 京都大学大学院工学研究科分子工学専攻 / (主査)教授 梶 弘典, 教授 関 修平, 教授 寺村 謙太郎 / 学位規則第4条第1項該当 / Doctor of Philosophy (Engineering) / Kyoto University / DFAM

Recently, as a promising lighting source, light-emitting diodes (LEDs) have become more and more attractive and have great opportunity to replace traditional lighting sources - incandescent, fluorescent and HID because of the advantages such as high luminous efficacy, long lifetime, quick on/off time, wide color gamut, eco-friendly etc. Based on the research from U.S. Department of Energy, over 30% of total electric consumption in U.S. each year is for lighting, 75% of which are for indoor lighting (including both residential and commercial buildings). In the indoor LED lighting application, to provide multiple current source outputs for multiple LED strings, traditional solutions usually adopt a two-stage structure, which is complicated and cost-ineffective. How to design a simple, low-cost and efficient LED driver with multiple current source outputs is in great demand and really challenging. In this thesis, a single-stage multi-channel constant current (MC3) LED driver structure has been proposed. Multiple transformer structure is utilized to provide multiple current source outputs. The current control scheme is also simple - only one LED string current is sensed and controlled; other strings' currents are cross regulated. Firstly, a PWM half bridge topology is chosen to implement the proposed single-stage MC3 LED driver concept. In order to analyze the current cross regulation, a general model is derived. The circuit has been simulated under various LED load conditions to verify its good current sharing capability. In order to further improve efficiency, simplify the driver's complexity and reduce cost, a LLC resonant topology is also investigated. LLC current gain characteristic has been derived by considering LED's i-v character and a design procedure is developed. A 100 kHz, 200 W, 4-string MC3 LLC LED driver is designed and tested. The experimental results show that the driver can maintain constant current output within the whole input and output variations, achieve good efficiency and realize current sharing under both balanced and unbalanced LED conditions. The dimming function can also be realized through frequency modulation method and burst mode control method. As a conclusion, a single-stage MC3 LED driver concept is proposed and implemented with two topologies. The proposed idea provides a simple, low-cost and efficient solution for indoor LED lighting application with multiple LED string configuration. It also has good current sharing capability and robustness to LED forward voltage variations or short failures. / Master of Science

Organic semiconducting materials have received a lot of attention in recent years and can now be found in many applications. One of the applications, the light emitting electrochemical cell (LEC) has emerged due to its flat and lightweight device structure, low operating voltage, and possibility to be fully solution processed. Today LECs can emit light of various colors, but to be applicable in the lighting industry, white light need to be produced in an efficient way. White light on the other hand, is one of the toughest "colors" to achieve in an efficient way, and is of particular interest in general lighting applications, where high color-rendering index devices are necessary. In this thesis I show that blue light can be partially converted, into white light, by utilizing the photoluminescence of color conversion layers (CCLs). Furthermore, I show that a high color-quality white light can be attained by adopting a blue-emitting LEC with a CCL. Particularly, three different color-conversion materials were embedded onto a blue bottom-emitting LEC, to study the resulting spectrum. One of the materials, MEH-PPV, have good absorption compatibility with the electroluminescence of the blue emitters, but the materials photoluminescence do not cover the red to deep-red range of the spectrum. These parts of the spectrum are necessary to obtain high color rendering indices (≥80). A single layer of MEH-PPV adapted onto a blue-emitting LEC, led to a cold white LEC with CIE-coordinates x = 0.29, and y = 0.36, color-rendering index = 71, and correlated color temperature = 7200 K. These properties makes it potentially useful in outdoor-lighting applications. The photoluminescence of another studied color-converting material, polymer red, covers the red to deep-red range of the spectrum but the material lacks absorption in the green parts of the blue emitters electroluminescence spectrum. Thus it is necessary to combine it with MEH-PPV to be able to absorb all wavelengths from the blue-emitter and get a broad light-spectrum out of the device. In order to preserve a part of the blue light, a new device configuration was designed. It features a top-emitting blue LEC with a dual-layer CCL which reach an impressive color rendering index = 89 at a correlated color temperature = 6400 K (CIE-coordinates x = 0.31, y = 0.33). The color-rendering index is the highest reported for a white LEC. The absence of UV-, and IR-radiation, together with the high color rendering properties make the white LEC a possible candidate for even the most demanding lighting-applications, such as art galleries, and shop display windows, together with indoor lighting. In this thesis, I show that the CCLs function well. However, for the LECs to be worthy competitors, the efficiency and lifetime of the blue emitter need improvements.

Over the last decades organic light-emitting diodes (OLEDs) and organic solar cells (OSCs) have gained considerable attention as efficient, flexible, lightweight, and potentially low-cost technology for lighting and display applications or as a renewable energy source, respectively. However, achieving long-term stability remains challenging. Revealing and understanding aging processes is therefore of great interest. This work presents fundamental investigations to understand and circumvent organic device degradation. In the first part, single materials used in organic devices were investigated. By tailoring an attenuated total reflection infrared (ATR-IR) spectrometer to the specific needs and subsequent measurements, it is shown that the tris(8-hydroxyquinoline)aluminum (Alq3) molecule, a well known fluorescent green emitter, degrades during air exposure by the formation of carbonyl groups. By using a laser desorption/ionization time of flight mass spectrometer (LDI-TOF-MS) it was shown that a,w-bis-(dicyanovinylen)-sexithiophen (DCV6T-Bu4), a well known small-molecule material which is used as part of the active layer, reacts with oxygen during ultraviolet (UV) irradiation. By using climate boxes and a sun simulator the impact of dry and humid air as well as sunlight on C60, a widely-used acceptor molecule in organic solar cells, was investigated. The breaking of the C60 cage to C58 and C56 and the further reaction of these components with oxygen as well as the dimerization of C58 and C56 molecules were found. The degradation products such as C58O increase with air exposure time but they are independent of the humidity level of the ambient air as well as sunlight irradiation. Subsequent annealing leads to a decrease of the C58O concentration. Many efficient n-dopants are prone to degradation in air, due to the low ionization potentials, thereby limiting the processing conditions. It was found that the air exposure of the highly efficient n-dopant tetrakis(1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidinato)ditungsten(II) (W2(hpp)4) leads to oxidation reactions of the molecule to [W(hpp)2 + O] and other degradation products. The decay constant of W2(hpp)4 and the matching mean growth time of the [W(hpp)2 + O] degradation as well as a second very quick degradation of the dopant could be determined. The two decay constants can be explained by the assumption that W2(hpp)4 molecules, which are involved in the charge transfer, do degrade slower due to the fact that the charge transfer leads to a downshift of the energy levels of the W2(hpp)4 molecule. Apart from the properties of the organic materials, other effects such as the impact of different purification systems on the material purity as well as the dependence of material purity on the OLED lifetime has been investigated. No correlations between the purification grade and the amount of impurities were found. OLEDs which contain N,N\'-di(naphthalen-1-yl)-N,N\'-diphenyl-benzidine (alpha-NPD) purified in a vertically interlaced stainless steel sublimation systems shows slightly higher external quantum efficiencies compared to tube-based vacuum sublimation systems. The devices which contain alpha-NPD purified by a sublimation system have an extended lifetime. Finally, the impact of residual gases during device fabrication on OLED lifetime and electrical characteristics was investigated. It was found that water vapor introduces an additional series resistance to the OLED, while the other gases do not influence the electric characteristics. The presence of nitrogen or oxygen impacts the lifetime of the OLEDs by the same amount. Nitrogen is non-reactive, this leads to the conclusion that the influence of nitrogen and oxygen on the OLED lifetime is of non-chemical nature, such as changes in the morphology of the organic layers. Water vapor introduces an additional, even faster degradation process within the first hours of OLED operation. As major sources of device degradation, the dimerization of 4,7-diphenyl-1,10-phenanthroline (BPhen) as well as the complexation reaction of alpha-NPD with a bis(1-phenylisoquinoline)iridium(III) (Ir(piq)2) fragment was identified.

This dissertation has three parts which are distinctive from the perspective of their frequency regime of operation and from the nature of their contributions to the science and engineering communities. The first part describes work that was conducted on a vertical-external-cavity surface emitting-laser (VECSEL) in the optical frequency regime. We designed, fabricated, and tested a hybrid distributed Bragg reflector (DBR) mirror for a VECSEL sub-cavity operating at the laser emission wavelength of 1057 nm. The DBR mirror was terminated with a highly reflecting gold surface and integrated with an engineered pattern of titanium. This hybrid mirror achieved a reduction in half of the number of DBR layer pairs in comparison to a previously reported, successful VECSEL chip. Moreover, the output power of our VECSEL chip was measured to be beyond 4.0Wwith an optical-to-optical efficiency of 19.4%. Excellent power output stability was demonstrated; a steady 1.0 W output at 15.0 W pump power was measured for over an hour. The second part reports on an ultrafast in situ pump-probing of the nonequlibrium dynamics of the gain medium of a VECSEL under mode-locked conditions. We proposed and successfully tested a novel approach to measure the response of the inverted carriers in the active region of a VECSEL device while it was operating under passively mode-locked conditions. We employed the dual-frequency-comb spectroscopy (DFCS) technique using an asynchronous optical sampling (ASOPS) method based on modified time-domain spectroscopy (TDS) to measure the nonequilibrium dynamics of the gain medium of a phase-locked VECSEL that we designed and fabricated to operate at the1030 nm emission wavelength. Our spectroscopic studies used a probe pulse of 100 fs and an in situ pump pulse of 13 ps. We probed the gain medium of the VECSEL and recorded a depletion time of 13 ps, a fast recovery period of 17 ps, and 110 ps for the slow recovery time. Our scans thus demonstrated a 140 ps full depletion-recovery cycle in the nonequilibrium state. The third part discusses work in the microwave and millimeter wave frequency regimes. A new method to fabricate Luneburg lenses was proposed and demonstrated. This type of lens is well known; it is versatile and has been used for many applications, including high power radars, satellite communications, and remote sensing systems. Because the fabrication of such a lens requires intricate and time consuming processes, we demonstrated the design, fabrication and testing of a Luneburg lens prototype using a 3-D printing rapid prototyping technique both at the X and Ka-V frequency bands. The measured results were in very good agreement with their simulated values. The fabricated X-band lens had a 12 cm diameter and produced a beam having a maximum gain of 20 dB and a beam directivity (half-power beam width (HPBW)) ranging from 12° to 19°). The corresponding Ka-V band lens had a 7 cm diameter; it produced a beam with a HPBW about the same as the X-band lens, but with a maximum gain of more than 20 dB.

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近來LED在日常生活中的照明應用如火如荼，幾乎到處可見到它的蹤跡。由於不但輕薄短小，更具節能環保特性，因此發展潛力無限，已被視為取代傳統照明的明日之星。 從較小功率的訊號指示燈運用開始，隨著開發與製造技術的提升，逐漸擴展應用到液晶電視背光板，而後家用照明、商業照明，進而車用照明等更高發光效率、更大功率、更廣色域的運用領域，儼然已成照明主流。 然而，在車用領域，雖然照明的需求非常多，諸如方向燈、煞車燈、標示燈、儀表燈、閱讀燈、晝行燈、霧燈、頭燈等，都是LED潛在的應用市場，但各家車廠在追求時尚與科技感的同時，亦無法忽略安全與耐久性的考量。尤其是在同時具有高度車廠品牌識別功能的頭、尾燈及晝行燈照明方面。 因此，從LED照明供應商至車廠，無不花費巨資、卯足全力，競相研發、推廣，如何及時將LED新產品引進到車上，以能更快更多地擄獲潛在車主歡心，取得整體商品價值與銷售市占提升的相輔相成效果。 本研究之目的，正是針對引進新產品LED照明的國產小客車，以產業龍頭公司個案為例，探討如何結合產品、訂價、通路、促銷，以及人員、流程、有形展示等7Ps行銷組合(marketing mix)策略，達到促進LED新產品在國產小客車市場的擴大應用。 本研究除了將針對企業市場競爭策略，及行銷策略組合的理論基礎加以探討外，也將同時對LED小客車的產業環境，以及個案公司有關LED國產小客車市場競爭策略、行銷策略與業務規劃等一併進行了解與分析，冀望藉此進一步推移出未來國產小客車用照明市場中，LED新產品引進及銷售的提升與發展方向。

This study addresses quality control for Light Emitting Diodes (LED) according to fouraspects, the power factor of LED lamps, their harmonics and total harmonic distortion (THD), the luminosity for total power to radiated power ratio. It focuses on four brands and six different LED lamps, and concludes that IKEA's LED lamps pertain as the quality lamp, with a power factor over 0.9, THD less than 4% and a power to radiated light of over 4%.