Ce travail présente la formation et la caractérisation sous ultravide de monocouches moléculaires issu de l'auto-assemblage et de la polymérisation de molécules organiques (hexahydroxy triphenyléne-HHTP et acide diborique benzoique-BDBA) sur des surfaces monocristallines métalliques et isolantes. L'adsorption de molécules HHTP sur Ag(111) donne lieu à plusieurs réseaux moléculaires dépendants de la température. Cette étude, menée par microscopie à effet tunnel (STM), montre qu'un réseau robuste est obtenu suite à la déshydrogénation, activée thermiquement, des groupes alcool périphériques. Cela induit la formation de liaisons hydrogène entre les fonctions alcools et cétones ainsi obtenues. L'étude STM de molécules de BDBA vapo-déposées sur Ag(111) a démontrée la formation d'architectures bidimensionnelles étendues, liées de manière covalente, suite à la polymérisation des précurseurs en surface. Un résultat similaire a pu être obtenu par la copolymérisation des molécules de BDBA et d'HHTP. Ces polymères nanoporeux s'étendent en monocouche et présentent une stabilité en température exceptionnelle. Enfin, l'étude de BDBA sur le substrat isolant de KCl, menée par microscopie à force atomique en mode non contact (nc-AFM), montre un auto-assemblage étendu par des liaisons hydrogène, et met en évidence le rôle décisif de la nature chimique du substrat sur la faisabilité de la polymérisation de ces molécules en surface. L'approche développée dans ce travail, mettant en jeu des réactions chimiques en surface, constitue une voie nouvelle pour la conception de nano-architectures moléculaires originales et robustes sur surfaces.

Im Rahmen dieser Arbeit wurden erste Untersuchungen zur Herstellung dünner NiSi(2-x)Al(x)- bzw. NiSi(2-x)Ga(x)-Schichten auf Si(001) erbracht. Dazu wurden Ni-Si-Al-Schichten mittels DC-Magnetron-Sputtern sowie Ni-Si-Ga-Schichten mittels Molekular-Strahl-Epitaxie (MBE) abgeschieden und anschließend in Abhängigkeit von der Herstellungsprozedur in einer RTA-Anlage thermisch behandelt. Die so entstandenen Reaktionsschichten wurden anschließend mittels RBS charakterisiert, wobei zusätzlich REM-, TEM-, AES-Tiefenprofil- und XRD-Untersuchungen ergänzend genutzt wurden. Es zeigt sich, dass unabhängig von der Abscheideprozedur bei ausreichend hoher Temper- bzw. Substrattemperatur die thermodynamisch stabilen Endphasen NiSi(2-x)Al(x) bzw. NiSi(2-x)Ga(x) gebildet werden. Während die Bildungstemperatur bei Festphasenreaktionen ohne Al- bzw. Ga-Zugabe für NiSi2 etwa 700°C beträgt, reduziert sich diese unter Anwesenheit von Al- bzw. Ga-Atomen auf 500°C und darunter. Dabei scheinen bereits eine Al- bzw. Ga-Konzentration von unter einem Atomprozent als notwendiger Stoffmengenanteil auszureichen. Befindet sich der Ort der Keimbildung der NiSi(2-x)Al(x)- bzw. NiSi(2-x)Ga(x)-Kristallite an der Grenzfläche zum Si(001)-Substrat, so ist eine Änderung der bevorzugten Wachstumsorientierung von NiSi(2-x)Al(x)(001)[100] || Si(001)[100] bzw. NiSi(2-x)Ga(x)(001)[100] || Si(001)[100] (A-Typ) zu einer NiSi(2-x)Al(x)(220) || Si(001)- bzw. NiSi(2-x)Ga(x)(220) || Si(001)-Vorzugsorientierung festzustellen. Die dafür notwendige Konzentration von Al- bzw. Ga-Atomen scheint jedoch höher zu sein als die, die für die Erniedrigung der Bildungstemperatur notwendig ist.

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Although many terminologies, taxonomies and also first ontologies for visualization have been suggested, there is still no unified and formal knowledge representation including the various fields of this interdisciplinary domain. We moved a step towards such an ontology by systematically reviewing existing models and classifications, identifying important fields and discussing inconsistently used terms. Finally, we specified an initial visualization ontology which can be used for both classification and synthesis of graphical representations. Our ontology can also serve the visualization community as a foundation to further formalize, align and unify its existing and future knowledge.

Description Logics (DLs) are a class of knowledge representation formalisms that can represent terminological and assertional knowledge using a well-defined semantics. Often, knowledge engineers are experts in their own fields, but not in logics, and require assistance in the process of ontology design. This thesis presents three methods that can extract terminological knowledge from existing data and thereby assist in the design process. They are based on similar formalisms from Formal Concept Analysis (FCA), in particular the Next-Closure Algorithm and Attribute-Exploration. The first of the three methods computes terminological knowledge from the data, without any expert interaction. The two other methods use expert interaction where a human expert can confirm each terminological axiom or refute it by providing a counterexample. These two methods differ only in the way counterexamples are provided.

Domain feature models concisely express commonality and variability among variants of a software product line. For separation of concerns, e.g., due to legal restrictions, technical considerations, and business requirements, multi-view approaches restrict the configuration choices on feature models for different stakeholders. However, recent approaches lack a formalization for precise, yet flexible specifications of views that ensure every derivable configuration perspective to obey feature model semantics. Here, we introduce a novel approach for clustering feature models to create multi-perspectives. Such customized perspectives result from composition of multiple concern-relevant views. A structured view model is used to organize feature groups, whereat a feature can be contained in multiple views. We provide formalizations for view composition and guaranteed consistency of the resulting perspectives w.r.t. feature model semantics. Thereupon, an efficient algorithm to verify consistency for entire clusterings is provided. We present an implementation and evaluate our concepts on two case studies.

Work includes certification procedures for experimental aeroplanes. Producer must answer individual work for right procedure certification. Office UCL give works and control production procedure aeroplane. Stationery (applications, confirmation, tec.) are part of work and is need make and feed. Part of work is VUT 001 MARABU and technical characteristics aeroplane.

This diploma thesis deals with a stability and manoeuvrability of experimental aircraft VUT 001 MARABU. It contains calculation of aerodynamic stability derivations and other data necessary for evaluation of static and dynamic stability. Assessment of convenient autopilot.

In my master´s thesis I focus on the design of information security management system for the company INNC s.r.o., which specializes in the design and implementation of computer networks. The thesis is divided into two parts. The first part provides theoretical knowledge of the issue. Second part is the analysis and proposal of security measures.

Title Interaction of Organic Molecules with Metal Passivated Silicon Surfaces Studied via STM Author Petr Zimmermann Department Department of Plasma and Surface Science Supervisor Doc. RNDr. Pavel Sobotík, CSc. Department of Plasma and Surface Science Abstract Organic molecules offer a wide range of optical, electronic or chemical properties. Coupling them to silicon could pave way to novel applications and devices, however, a controlled molecular functionalization of silicon remains challenging due to the presence of highly reactive dangling bonds on its surfaces. We attempt to decrease the reactivity of low index silicon surfaces with an ultra-thin layer of a metal adsorbates and study their interaction with organic molecules via scanning tunnelling microscopy. In the first part we investigate the interaction of ethylene, a small unsaturated molecule, with tin and indium 1D chains grown on Si(001) - 2 × 1. The chains consist of dimers structurally analogous to the dimers of the underlying Si(001) - 2 × 1 surface. Aided by photoelectron spectroscopy we find that the Sn chains are less reactive than the Si(001) surface and that the absence of a π dimer bond renders indium chains inert. In the second part we study the interaction of copper phthalocyanine, a small macrocyclic heteroaromatic compound, with the...