O Teste da Simulação de Falar em Público (SFP) é um teste sensível a drogas que interferem com a neurotransmissão mediada por serotonina (5-HT), e algumas evidências sugerem que ele possa recrutar os mesmos sistemas neuronais envolvidos na fisiopatogenia do Transtorno do Pânico (TP). Diferentes fármacos que, direta ou indiretamente, modulam receptores serotoninérgicos, já foram testados em voluntários saudáveis submetidos ao SFP, mas nenhum estudo, até o momento, utilizou drogas que permitissem avaliar o papel de receptores do tipo 5-HT1D na ansiedade. O sumatriptano, um agonista específico de receptores 5-HT1D, parece ser um bom candidato como sonda farmacológica, tendo em vista sua ampla utilização na prática clínica para o tratamento de enxaqueca, com segurança e boa tolerabilidade. A hipótese testada neste estudo foi a de que, devido à ativação de receptores pré-sinápticos 5-HT1D e conseqüente redução na liberação de 5-HT, o sumatriptano aumentaria o medo provocado pelo SFP. Para tanto, foi conduzido um estudo duplo cego, randomizado, utilizando 36 voluntários saudáveis do sexo masculino, distribuídos em três grupos de tratamento: placebo (n = 12), 50mg (n = 12) ou 100mg (n = 12) de sumatriptano, administrado duas horas antes do SFP. Antes, durante, e após o SFP, medidas subjetivas de ansiedade foram registradas através da Escala Analógica Visual do Humor (VAMS) e da Escala dos Sintomas Somáticos (ESS). Também foram tomadas medidas fisiológicas de ansiedade (pressão arterial, freqüência cardíaca, dosagem hormonal e eletrocondutância da pele). Os resultados foram submetidos à análise multivariada de variância, sendo a medida basal utilizada como covariada (MANCOVA). O grupo tratado com 100mg de sumatriptano apresentou aumento mais pronunciado da ansiedade subjetiva do que os grupos tratados com 50mg de sumatriptano e com placebo durante as fases de preparação e de desempenho. O grupo tratado com 100 mg de sumatriptano também mostrou-se mais alerta na fase de preparação e desempenho do que o grupo placebo. Não foram observados efeitos significativos do tratamento sobre as medidas de pressão arterial, freqüência cardíaca e eletrocondutância da pele. O sumatriptano provocou redução dos níveis de prolactina, independentemente da fase da sessão experimental, mas não interferiu nos níveis de cortisol plasmático. Por outro lado, observou-se um amento dos níveis de cortisol plasmático imediatamente após o SPF, em comparação com os níveis pré-teste, independente do grupo de tratamento. A redução da disponibilidade de 5-HT levou a um aumento do medo provocado pelo SFP, o que está de acordo com a proposição de que a diminuição de 5-HT na matéria cinzenta periaquedutal dorsal (MCPD) aumenta o medo incondicionado. Devido a esse efeito ansiogênico do uso agudo do sumatriptano também poder ocorrer na prática clínica, em pacientes com migrânea, deve-se atentar para a possibilidade da manifestação de sintomas semelhantes aos de ataque de pânico em pacientes ansiosos. A diminuição da função 5-HT também provocou redução dos níveis plasmáticos de prolactina, provavelmente pela facilitação da transmissão dopaminérgica. Por sua vez, embora discreto, o aumento dos níveis plasmáticos do cortisol sugerem uma atuação do eixo hipotálamo-hipófise-adrenal (HHA) pelo SFP. A interpretação da resposta do cortisol ao estresse psicológico é complexa e depende de vários fatores, como tema do discurso, tipo de avaliação social, falta de controle da situação, tamanho amostral e estratégias de regulação emocional do voluntário. Mais estudos são necessários para elucidar o papel dos receptores 5-HT1D na ansiedade e para compreender a resposta do cortisol ao estresse psicológico. / The Simulated Public Speaking Test (SPS) is an experimental model sensitive to drugs that interfere with the neurotransmission mediated by serotonin (5-HT). It has been proposed that the SPS recruits the same neural systems involved in the pathophysiology of panic disorder (PD). Different drugs that directly or indirectly modulate serotonin receptors, have been tested in healthy volunteers submitted to the SFP, but no study have been carried out so far for assessing the role of 5-HT1D receptors in anxiety. Sumatriptan, a specific agonist of 5-HT1D receptors, seems to be a good candidate as a probe drug, given its wide use in clinical practice for the treatment of migraine, with good safety and tolerability. The hypothesis tested in this study was that, due to the activation of presynaptic 5-HT1D receptors and consequent reduction in the release of 5-HT, sumatriptan would increase the fear caused by the SPS. To that end, we conducted a double-blind, randomized study using 36 healthy male volunteers who were divided into three treatment groups: placebo (n = 12), 50mg (n = 12) or 100mg (n = 12) of sumatriptan, administered two hours before the SFP. Before, during, and after the SPS, subjective measures of anxiety were recorded by Visual Analogue Mood Scale (VAMS) and the Bodily Symptom Scale (BSS). Physiological measures were also taken for anxiety (blood pressure, heart rate, hormone dosage and skin conductance). The results were submitted to multivariate analysis of variance (MANCOVA) with the baseline measures as covariate. The group treated with 100 mg of sumatriptan was more anxious than, respectively, 50mg and placebo groups during the test, and also proved to be more alert in preparation and performance than the placebo group. There were no significant effects of treatment on measures of blood pressure, heart rate and skin eletrocondutance. Sumatriptan caused a reduction of prolactin levels, independently of the experimental phase of the session, but did not interfere with plasma cortisol levels. On the other hand, there was an increased of plasma cortisol levels immediately after the SPF, compared with the pre-test, independently of treatment group. The reduced availability of 5-HT led to an increase of fear caused by the SFP, which is consistent with the proposition that a reduction of 5-HT in the dorsal periaqueductal gray (MCPD) increases unconditioned fear. Because of this anxiogenic effect of acute use of sumatriptan also can occur in clinical practice in patients with migraine should be alert to the possibility of manifestation of symptoms similar to panic attacks in patients anxious. The decreased function of 5-HT also caused a reduction in plasma levels of prolactin, probably by facilitating dopamine transmission. In turn, although slight, the increase in plasma cortisol levels suggest a role of the hypothalamic-pituitary-adrenal (HPA) for the SFP.The interpretation of the cortisol response to psychological stress is complex and depends on several factors, such as theme of the discourse, type of social assessment, lack of control of the situation, sample size, emotional regulation strategies of the volunteer. Further studies are needed to elucidate the role of 5-HT1D receptors in anxiety and to understand the cortisol response to psychological stress.

Les nano-objets unidimensionnels alliés présentent des propriétés physiques spécifiques qui résultent à la fois de leur morphologie, de leur taille et de la répartition chimique des atomes. Nous exploitons un modèle d’Ising sur réseau qui rend compte en particulier des effets de ségrégation au sein de nanofils bimétalliques pour obtenir une compréhension fine des effets gouvernant cette répartition à l’équilibre.Dans une première section, nous détaillons l’équilibre d’un nanofil en fonction de sa taille et de sa composition, de manière à mettre en évidence le rôle des effets de taille finie sur la thermodynamique d’équilibre d’objets bimétalliques 1D. Contrairement aux systèmes infinis, l’équilibre dépend de l’ensemble statistique considéré. Ainsi la ségrégation est plus marquée dans l’ensemble canonique, où la concentration du nanofil est imposée, que dans l’ensemble pseudo-Grand Canonique (p-GC) où le nanofil est en équilibre avec un réservoir qui fixe la différence de potentiel chimique entre les espèces. De même, la contrainte de composition dans l’ensemble canonique induit des corrélations chimiques d’occupation des sites qui favorisent davantage les paires hétéroatomiques. Nous montrons que l’écart observé entre les isothermes des deux ensembles croît avec la courbure de l’isotherme canonique et avec l’amplitude des fluctuations de la concentration nominale dans l’ensemble p-GC. Ces fluctuations diminuant avec la taille du nanofil considéré, l’écart entre les ensembles s’annule à la limite thermodynamique. Les effets de taille finie se traduisent par ailleurs par l’apparition, à basse température et pour de petits nanofils, d’une coexistence d’un mode pur en l’espèce ségrégeante et d’un mode de faible concentration nominale constitué principalement de configurations de type cœur-coquille et Janus. Nous développons alors un formalisme permettant de caractériser cette bimodalité.Alors que les résultats évoqués précédemment concernent un nanofil considéré seul, nous étudions dans la deuxième section l’équilibre de l’ensemble des nanofils formant un co-dépôt unidimensionnel inférieur à la mono-couche. Nous montrons que la distribution en taille de ces nanofils varie globalement selon une loi de puissance, quelle que soit la composition du codépôt, de sorte que la ségrégation n’a que peu d’influence sur la microstructure observée. Par contre, en raison du rapport surface/volume et des corrélations chimiques dans ces objets, la composition des nanofils du co-dépôt varie très fortement selon leur taille, les petits nanofils étant plus riches en l’espèce ségrégeante que les plus grands. Enfin, nous étendons le diagramme de bimodalité d’un nanofil seul à l’ensemble des nanofils du co-dépôt et montrons que cette bimodalité est difficilement observable car elle ne concerne que des amas de petite taille qui sont très minoritaires du fait de la cohésion atomique. / The chemical configuration and the specific shape of 1D bimetallic nano-objects endow them with physical properties (such as magnetic ones) that strongly differ from their bulk counterparts. To get a deep insight of the parameters that govern the equilibrium configuration, we consider a rigid lattice-gas Ising model that accounts for segregation effects within bimetallic nanowires that decorate a step edge.In a first section, we detail the equilibrium of a nanowire as a function of both its size and composition in order to specify the role of finite-size effects onto the equilibrium thermodynamics of 1D bimetallic objects. Contrary to infinite systems, this equilibrium depends on the statistical ensemble to be considered. The segregation profile is indeed stiffer in the canonical ensemble where the nanowire concentration is imposed, than in the semi-grand-canonical ensemble (s-GC) where the nanowire is in equibrium with a reservoir that sets the difference of chemical potentials between the species. Moreover, the composition constraint in the canonical ensemble yields chemical correlations between occupation sites that favor heteroatomic pairs. We show that the deviation observed between the isotherms related to the two ensembles increases with the curvature of the canonical isotherm and with the amplitude of the fluctuations of the nominal concentration within the s-GC ensemble. As these fluctuations decrease with the nanowire size, the deviation between ensembles vanishes at the thermodynamical limit. The finite-size effects also imply at low temperature for small nanowires, that a pure mode of the segregating species coexists with a low-concentration mode that mainly corresponds to core-shell and Janus configurations. We develop a framework to characterize the resulting two-mode density of compositions.While the abovementioned results deal with a fixed-size nanowire, we study in the second section the equilibrium of the set of nanowires that forms a submonolayer 1D-codeposit. We show that the size distribution of these nanowires globally varies as a power law, whatever the codeposit composition, so that segregation has a slight influence onto the observed microstructure. However, due to the surface/volume ratio and chemical correlations within these objects, the composition of the nanowires of the codeposit varies strongly with their size, the smaller the richer in the segregating species. Finally we extend the two-mode diagram of the single nanowire to the set of nanowires forming the codeposit and show that this two-mode distribution is hardly visible as it concerns only short nanowires which are very rare, mainly due to atomic cohesion that is reinforced at low temperature.

No description available.

[pt] O atual esgotamento de campos de petróleo tradicionais tem aumentado a demanda pela produção e transporte óleos não convencionais, que podem possuir uma alta viscosidade dinâmica. Neste contexto, o estudo do escoamento simultâneo de gás e óleos viscosos em tubulações é de grande importância para a indústria de Óleo e Gás. Simulações numéricas uni-dimensionais desempenham um papel essencial nestes estudos, especialmente aquelas baseadas no Modelos de Dois-Fluidos 1D, cuja solução numérica em malhas refinadas consiste na Metodologia de Captura de Regimes. O propósito deste trabalho é utilizar esta abordagem para reproduzir dados experimentais de escoamentos óleo viscoso-gás em golfadas e estratificado ondulado em um duto horizontal em escala laboratorial. Para aprimorar os resultados desta metodologia, dados experimentais foram usados conjuntamente com um procedimento de otimização e uma versão simplificada do Modelos de Dois-Fluidos 1D para criar duas novas expressões para o fator de atrito interfacial, as quais mostraram maior eficiência que correlações padrão da literatura. O efeito da introdução da pressão dinâmica, difusão axial de quantidade de movimento e tensão interfacial dinâmica no Modelo de Dois-Fluidos 1D foi analisado. Resultados de gradiente de pressão e de fração volumétrica de líquido (histogramas, valores médios e perfis transientes) foram comparados com dados experimentais. Observou-se, com o auxílio de análises de boa-colocação, que a pressão dinâmica e as novas expressões para o fator de atrito interfacial fornecem resultados satisfatórios. / [en] The current depletion of traditional oil fields is increasing the demand for the production and transport of unconventional oils, which might possess a high dynamic viscosity. In this context, the study of the simultaneous flow of gas and viscous oils in pipelines is of paramount importance for the Oil and Gas industry. One-dimensional numerical simulations play a key role in such studies, especially the ones based on the 1D Two-Fluid Model, whose numerical solution in fine meshes consists in the Regime Capturing Methodology. The purpose of this work is to use this approach for reproducing the experimental data of isothermal slug and stratified wavy viscous oil-gas flows in a horizontal laboratory-scale pipe. For improving the results of the methodology, experimental data were used together with an optimization procedure and a simplified version of the 1D Two-Fluid Model for successfully creating two new expressions for the interfacial friction factor, which showed better efficiency than standard literature correlations. The effect of introducing a dynamic pressure, axial momentum diffusion and dynamic interfacial shear in the 1D Two-Fluid Model was examined. Results of pressure gradient and liquid holdup (histograms, mean values and transient profiles) were compared against experimental data. It was seen, with the aid of well-posedness analyses, that the dynamic pressure and the new expressions for the interfacial shear stress provided satisfactory results.

La conception des filtres a réponse impulsionnelle finie (RIF) peut être formulée comme un problème d'optimisation non linéaire réputé pour être difficile sa résolution par les approches conventionnelles. Afin d'optimiser la conception des filtres RIF, nous explorons plusieurs méthodes stochastiques capables de traiter de grands espaces. Nous proposons un nouvel algorithme génétique dans lequel certains concepts innovants sont introduits pour améliorer la convergence et rendre son utilisation plus facile pour les praticiens. Le point clé de notre approche découle de la capacité de l'algorithme génétique (AG) pour adapter les opérateurs génétiques au cours de la vie génétique tout en restant simple et facile à mettre en oeuvre. Ensuite, l’optimisation par essaim de particules (PSO) est proposée pour la conception de filtres RIF. Finalement, un algorithme génétique hybride (HGA) est proposé pour la conception de filtres numériques. L'algorithme est composé d'un processus génétique pur et d’une approche locale dédiée. Notre contribution vise à relever le défi actuel de démocratisation de l'utilisation des AG’s pour les problèmes d’optimisation. Les expériences réalisées avec différents types de filtres mettent en évidence la contribution récurrente de l'hybridation dans l'amélioration des performances et montrent également les avantages de notre proposition par rapport à d'autres approches classiques de conception de filtres et d’autres AG’s de référence dans ce domaine d'application. / The design of finite impulse response (FIR) filters can be formulated as a non-linear optimization problem reputed to be difficult for conventional approaches. In order to optimize the design of FIR filters, we explore several stochastic methodologies capable of handling large spaces. We propose a new genetic algorithm in which some innovative concepts are introduced to improve the convergence and make its use easier for practitioners. The key point of our approach stems from the capacity of the genetic algorithm (GA) to adapt the genetic operators during the genetic life while remaining simple and easy to implement. Then, the Particle Swarm Optimization (PSO) is proposed for FIR filter design. Finally, a hybrid genetic algorithm (HGA) is proposed for the design of digital filters. The algorithm is composed of a pure genetic process and a dedicated local approach. Our contribution seeks to address the current challenge of democratizing the use of GAs for real optimization problems. Experiments performed with various types of filters highlight the recurrent contribution of hybridization in improving performance. The experiments also reveal the advantages of our proposal compared to more conventional filter design approaches and some reference GAs in this field of application.

Ce travail présente une étude théorique et expérimentale portant sur le concept de Moteur Hybride Pneumatique ( MHP). En première approche, un modèle 0D d’un MHP monocylindre, incluant un sous-modèle cinématique original pour l’actuateur entièrement variable muant la soupape de charge, est présenté puis exploité. La modélisation 1D de la dynamique des gaz dans chaque tubulure est traitée, incluant différents modèles de Condition Limite de Soupape (CLS), basées sur la méthode des caractéristiques et issues de la littérature. Il est montré que ces CLS ne sont pas adaptées à la modélisation d’un MHP : existence de chocs numériques, problème de non-convergence et mise en défaut face à des relevés expérimentaux. Un modèle original de CLS, évitant ces problèmes et demeurant basé sur la méthode des caractéristiques, est alors développé puis validé expérimentalement à la foi sur bancs d’essais moteurs et de dynamique des gaz à la soupape. Une étude expérimentale des échanges de chaleur convectifs, en mode pneumatique et sans combustion, est conduite et débouche alors sur une modification nécessaire de la corrélation standard de Woschni, afin de correctement décrire l’extinction du mouvement de tumble en fin de course de compression. Une exploitation de la plate-forme de simulation 1D de MHP monocylindre, incluant l’ensemble des éléments développés, est finalement conduite afin de déterminer les phasages optimums d’ouverture et de fermeture de la soupape de charge, pour différents mode et conditions opératoires. Cette étude, nécessaire à de futures simulations de cycles routier, confirme d’une part, la viabilité du concept et d’autre part, montre l’importance que revêt la prise en compte de la cinématique de l’actuateur soupape et de la dynamique des gaz dans la tubulure de charge. / This work presents an experimental and theoretical study on the concept of Pneumatic Hybrid Engine (PHE). In a first approach, a 0D model of a single cylinder PHE, including an original kinematic sub-model of the fully variable actuator that moves the charging valve, is presented and exploited. Then, the 1D modelling of the gaz dynamics inside each pipes is treated, including several valve boundary conditions (VBC), based on the method of characteristics and issued from literature. It is shown that these VBC are not suitable for a PHE modelling : numerical shocks, non-convergence and contraticted when compared to measurements. An original VBC, avoiding these problems and still based on the method of characteristics, is then developed and experimentally validated on both engine and valve gas dynamics tests benches. An experimental study on the convective heat transfer, in pneumatic mode without combustion, is conducted and leads to a necessary modification of the standard Woschni correlation in order to correctly describe the decay of the tumble motion near the end of the compression stroke. The 1D simulation platform, including all components developed, has finally been conducted in order to determine the optimum timings for the charging valve opening and closing, for different modes and operating conditions. This study, necessary for future driving cycle simulations, first confirms the viability of the PHE concept and second, shows the importance of taking into account the kinematic capability of the charing valve actuator and the gas dynamics inside the charging pipe.

Les tapis de nanotubes de carbone verticalement alignés sont des candidats potentiels pour des applications telles que les interconnexions ou les matériaux d'interface thermique. Ce travail de recherche porte sur la synthèse de tapis de nanotubes de carbone alignés selon le procédé de dépôt chimique en phase vapeur (CVD) d'aérosols liquides, sur l'élaboration de nanocomposites constitués de différentes nuances de matrices époxy infiltrées au sein de ces tapis, ainsi que sur l'étude des propriétés mécaniques et thermiques longitudinales et transverses des tapis secs eux-mêmes et des nanocomposites 1D formés. Les conditions de synthèse permettent notamment de faire varier les caractéristiques des tapis telles que leur épaisseur, leur masse volumique, le diamètre externe moyen des nanotubes de carbone (NTC), l'espace intertube et la teneur volumique en NTC, alors que leur structure cristalline peut être modifiée par le biais d'un traitement thermique à haute température. L'objectif principal de ce travail consiste à démontrer et quantifier l'effet de certaines caractéristiques des tapis de nanotubes de carbone sur les propriétés mécaniques et thermiques des différents types de tapis et matériaux composites obtenus. Les deux méthodes d'imprégnation mises en oeuvre, voie liquide et infusion, conduisent à des tapis de NTC alignés denses avec un alignement des NTC conservé et une répartition homogène des NTC au sein du système époxy. La fraction volumique en NTC s'avère être le paramètre-clé permettant d'exacerber, dans la direction longitudinale aux NTC, les propriétés mécaniques et thermiques des nanocomposites. Par ailleurs, les tapis de NTC et les nanocomposites voient leurs propriétés de conduction thermique longitudinale nettement exacerbées lorsque les NTC présentent une amélioration de leur structure cristalline. L'augmentation significative des performances apportées par les tapis de NTC verticalement alignés au sein de ces matériaux nanocomposites anisotropes par rapport aux matrices organiques non chargées est prometteuse et ouvre des pistes de réflexion visant à répondre aux nouvelles exigences de multifonctionnalité des secteurs de l'aéronautique et de l'aérospatial. / Vertically aligned carbon nanotube carpets are potential candidates for applications such as interconnections or thermal interface materials (TIMs). This research work deals with the synthesis of aligned carbon nanotube carpets from the aerosol assisted chemical vapour deposition (CVD) technique, with the elaboration of nanocomposites made of different grades of epoxy matrix infiltrated within these carpets, as well as the study of both longitudinal and transverse mechanical and thermal properties of dry carpets themselves and 1D-nanocomposites separately. The synthesis conditions notably enable to vary characteristics of the differents carpets such as their thickness, their density, the mean external diameter of the carbon nanotubes (CNT), the intertube space and the CNT volume fraction, whereas their crystalline structure can be modified with a high temperature thermal treatment. The main goal of this work is to prove and quantify the effect of some of the characteristics of the carbon nanotubes carpets on both mechanical and thermal properties of the different kinds of CNT carpets and resulting composite materials. The two impregnation methods used, liquid way and infusion, lead to dense CNT carpets with a preserved alignment of the CNT and an homogeneous distribution of these latest within the epoxy system. The CNT volume content is evidenced as the key-parameter exacerbating the mechanical and thermal properties mainly in the longitudinal direction compared with the alignment axis of the CNTs. Moreover the mechanical and thermal conduction properties of the CNT carpets and the 1D-nanocomposites are clearly increased when the crystalline structure of the CNT is improved. The significant increasing of the properties brought by the vertically aligned CNT within these anisotropic 1D-nanocomposites compared with the only organic matrixes is promising and opens new pathways aiming to meet the latest specifications related to multifunctionnality in fields such as aeronautics and aerospace.

Ce travail de thèse a été réalisé dans le cadre d'un contrat avec l'ANR (ANR-09-VERS-013 « THID ») et porte sur le développement d'une nouvelle génération de tags Chipless à bas coûts fonctionnant dans le domaine THz, pour des applications d'identification et/ou authentification unitaire des articles commerciaux, des papiers d'identités, des personnes pour le contrôle d'accès... Les structures proposées, constituées d'un empilement périodique de couches diélectriques d'indices de réfraction différents, utilisent les propriétés particulières des cristaux photoniques 1D de présenter une réponse électromagnétique entrecoupée de bandes interdites photoniques (BIP). Toute perturbation de la périodicité de la structure engendre des pics dans les bandes interdites qui sont utilisés pour coder une information binaire. Cette structuration particulière des matériaux permet donc de manipuler précisément une signature électromagnétique. Pour des raisons liées à l'industrialisation (facilité de fabrication en masse) et aussi de coût, nous avons retenu des matériaux de base déjà couramment utilisés dans l'industrie papetière : le papier et le polyéthylène. Le choix de ces matériaux, qui doivent allier contraste d'indice élevé et faible absorption, représente une étape cruciale dans ce travail. Ainsi, à partir des résultats expérimentaux obtenus par spectroscopie THz dans le domaine temporel (THz-TDS) sur un grand nombre de matériaux, nous avons pu concevoir deux familles de tags sur la base de ces différents matériaux. Par ailleurs, nous avons développé deux méthodes de codage d'une information binaire, toutes deux basées sur l'absence ou la présence de pics dans une BIP, pics dont la position et le nombre dépendent bien évidemment des défauts de périodicité introduits. Pour des applications liées à l'identification, des capacités de codage de près de 20 bits ont été démontrées. Nous avons aussi montré que la richesse d'information contenue dans la réponse électromagnétique de ces Tags THz peut être utilisée pour les applications liées à l'authentification unitaire, en utilisant comme critère de discrimination le coefficient d'autocorrélation. Nous avons ainsi pu évaluer les performances d'un test d'authentification basé sur ce critère dans différents domaines d'analyse : temporel, fréquentiel et temps-fréquence. Nous avons montré qu'une étude du spectrogramme (combinant temps et fréquence) est ainsi bien plus pertinente qu'une étude dans les seuls domaines temporel ou fréquentiel. / This thesis work deals with the development of a new generation of low-cost Chipless tags operating in the THz frequency domain, it has been supported by the french national agency for research (ANR-09-VERS-013 « THID » ). It covers a wide area of applications such as the identification and/or unitary authentication of commercial items, identity papers, access control…To manufacture these tags, we proposed to use a periodic stack of dielectric material layers with different refractive index and whose thickness is of the order of the wavelength, commonly known as a one dimensional photonic crystal. The electromagnetic signature of such a structure exhibits photonic bandgaps (PBG), i.e. frequency windows in which light propagation is prohibited. We suggested modifying the periodicity of the crystal to create defect levels (peaks) for example in the 1st PBG to encode binary information. This particular structure allows to precisely tuned an electromagnetic signature. To ensure a mass and cost effective industrialization, we retained basic materials which are widely used in the pulp and paper industry: paper and polyethylene. The choice of these materials, which must combine high index contrast and low absorption, represents the first and a crucial step in this work. We characterize a wide range of materials using classical THz time domain spectroscopy (THz-TDS) and we propose two families of tags based on paper and polyethylene. Furthermore, we developed two methods to encode binary information, both based on the absence or presence of peaks in a PBG, peaks whose number and position depend on the introduced defects of periodicity. In a real identification test, a coding capacity of nearly 20-bit has been demonstrated. We also showed that the information contained in the electromagnetic response of these THz tags can be used for other applications related to the unitary authentication and by using the correlation coefficient as criterion for discrimination of the different signatures. Therefore, we evaluate the performance of an authentication test based on this criterion in various analysis domains: time, frequency and time-frequency. We showed that a study of the spectrogram (combining time and frequency representation) is much more relevant than a study in the only time or frequency domain.

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior - CAPES / This research was conducted with the objective of studying the dynamics of soil temperature and water content as a function of the different amounts of black oat residue (Avena sativa Schreb.) in the soil cover, through existing relationships with meteorological variables, as well as the simulation of these dynamics using Hydrus-1D. The experiment was carried out in an Argissolo Vermelho Distrófico arênico (Rhodic Paleudalf) in Santa Maria - RS. The treatments consisted of the use of 3, 6 and 9 Mg ha-1 of oat straw in soil cover and an uncovered soil treatment (0 Mg ha-1). Soil temperature and water content at different depths, in addition to meteorological conditions, were measured during the period from December 1, 2014 to December 6, 2015. The effect of straw on soil temperature was analyzed at different depths, correlating covered soil temperature with uncovered soil temperature. The equations used for estimating soil surface temperature were adjusted by the least square method, where the surface temperature is estimated as a function of air temperature and incident solar radiation, and its performance compared to the sinusoidal equation. The hydraulic and thermal parameters required for the simulation of soil temperature and water content were optimized by the reverse solution and validated on uncovered soils. The optimized parameters were used to simulate the temperature and water content in soils with different amounts of straw with two contour conditions for the soil surface temperature, one measure and the other estimated. The straw affected the soil temperature down to 50 cm deep. The uncovered soil temperature at which inversion of the straw effect occurred was 19.6 ° C at the surface and 15.8 ° C at 50 cm depth. The presence of straw keeps the soil warmer than the soil without straw at the beginning of the day, but prevents it from warming similar to the ground without straw for the rest of the day, causing in turn that, bare soil gets warmer during the day and cools more at night compared to the covered soil. This temperature was similar in all amounts of straw, but decreased in depth. The temperature of the soil surface can be estimated as a function of air temperature and solar radiation. In uncovered soil the proposed equation presents better performance compared to the sinusoidal equation. In covered soils the sinusoidal equation had better performance. The optimal hydraulic and thermal parameters of the soil improved the simulations of temperature and soil water content. The soil temperature with different amounts of oat straw can be simulated using Hydrus-1D, and the use of the contour condition with the measured surface temperature performed better than the estimated surface temperature. / Esta pesquisa foi conduzida com o objetivo de estudar a dinâmica da temperatura e do conteúdo de água do solo em função de diferentes quantidades de resíduos de aveia preta disposta em cobertura por meio das relações existente com variáveis meteorológicas, bem como a representação destes comportamentos por meio de simulação utilizando o Hydrus-1D. O experimento foi conduzido em um Argissolo Vermelho Distrófico arênico em Santa Maria - RS. Os tratamentos consistiram da utilização de três diferentes níveis de cobertura do solo (3, 6 e 9 Mg ha-1) com palha de aveia (Avena sativa) e um tratamento com solo descoberto (0 Mg ha-1). A temperatura do solo e o conteúdo volumétrico de água, em diferentes profundidades, além das condições meteorológicas, foram mensurados durante o período de 01/12/2014 a 06/12/2015. O efeito da cobertura do solo com resíduos vegetais na temperatura do solo foi analisado nas diferentes profundidades correlacionando a temperatura do solo com palha e a temperatura do solo descoberto. O método dos mínimos quadrados foi usado para gerar equações de estimativa da temperatura da superfície do solo em função da temperatura do ar e da radiação solar e o seu desempenho foi comparado com a equação senoidal. Os parâmetros hidráulicos e térmicos, necessários para a simulação da temperatura e do conteúdo de água do solo, com o Hydrus-1D, foram otimizados por meio da solução inversa e validados em solos descobertos. Os parâmetros otimizados foram usados para a simulação da temperatura e do conteúdo de água em solos com diferentes quantidades de palha com duas condições de contorno para a temperatura da superfície do solo, uma medida e outra estimada. A palha exerce influência sobre a temperatura do solo até 50 cm de profundidade. A temperatura do solo descoberto em que ocorre a inversão do efeito da palha foi de 19,6 °C na superfície e 15,8 °C a 50 cm de profundidade. A presença de cobertura de palha mantém o solo mais aquecido que o solo sem palha no início do dia, mas impede que ele se aqueça igual ao solo sem palha no restante do dia. Assim resultando em uma percepção de que a palha aquece e resfria o solo em relação à temperatura do solo desnudo. Essa temperatura foi semelhante em todas as quantidades de palha, porém decresceu em profundidade. A estimativa da temperatura da superfície do solo pode ser estimada em função da temperatura do ar e da radiação solar. Em solo descoberto as equações propostas tem melhor desempenho que a equação senoidal. Em solos cobertos a equação senoidal teve melhor desempenho. Os parâmetros hidráulicos e térmicos do solo otimizados melhoraram as simulações da temperatura e conteúdo de água do solo. A simulação da temperatura do solo com diferentes quantidades de cobertura vegetal pode ser simulada usando o Hydrus-1D, sendo que o uso da condição de contorno com a temperatura da superfície medido teve melhor desempenho que o utilizando a temperatura da superfície estimada.

Lors d’une opération de forage, un certain nombre d’événements imprévus par rapport à l’écoulement du fluide de forage dans le puits, peuvent se produire assez rapidement. Des exemples de tels événements sont les afflux de pétrole ("kick") ainsi que les pertes de boue dans la formation. Un "kick" qui augmente en intensité peut entraîner, par ce que l’on nomme, un "blowout" (par exemple l’incident Deepwater Horizon en 2010). Les pertes et les gains sont habituellement détectés en contrôlant l’équilibre de la boue de forage dans le puits, en particulier en contrôlant le débit sortant du puits et en le comparant au débit entrant induit par les pompes. La plupart des méthodes de surveillance, de l’écoulement du puits en cours de forage, est d’utiliser un simple "paddle" (capteur qui mesure la hauteur du fluide de forage avec l’inclinaison d’une pagaie) dans la ligne d’écoulement de retour, ou d’utiliser un débitmètre de Coriolis (débitmètre connu pour sa précision, mais coûteux et nécessite une installation complexe en ajoutant un "by-pass"). Il y a un besoin évident d’un nouveau débitmètre précis, mais facile à installer et peu coûteux. Le canal Venturi a été utilisé comme débitmètre pendant des années dans l’industrie des eaux. Il apparaît comme une solution peu chère mais précise pour mesurer des débits importants. Beaucoup de personnes ont travaillé sur cette solution pour améliorer sa précision et élargir son champ d’application. Ils ont développé des modèles, sur la base d’un processus d’étalonnage, permettant de relier la hauteur en amont au débit. Cela signifie que les modèles actuels, comme ISO NORM 4359 [1], peuvent être uniquement utilisés pour l’écoulement d’eau et pour une géométrie bien spécifique. Comme nous le savons, les boues ont des comportement non- Newtonien, et donc ces modèles établis ne peuvent pas être utilisés avec ce type de fluides. Pour notre application, la forme trapézoïdale apparaît comme un bon compromis entre la précision et la portée des mesures de débit. Ainsi, nous avons développé un modèle capable de calculer le débit en prenant en compte les propriétés du fluide ainsi que les paramètres géométriques du canal. Ce modèle a été simplifié sous forme 1D en utilisant la théorie des eaux peux profondes, et a été complété par un modèle de friction tenant en compte de la variation des propriétés des fluides et de la géométrie du canal. Ce modèle a été validé par une série d’expériences avec les deux types de fluides: Newtonien et non-Newtonien, où nous avons mesuré le débit et la hauteur de l’écoulement à différents endroits le long du canal Venturi. Nous avons également réalisé des simulations 3D, en simulant des écoulements Newtoniens et non- Newtonien le long du canal. Pour généraliser cette étude, cette démarche a été étendue à une autre forme de Venturi plus adapté à un certain design de plate-forme pétrolière. Les corrélations et les modèles développés et validés expérimentalement au cours de cette étude peuvent être utilisés pour étendre l’utilisation des canaux Venturi à tous les fluides Newtonien mais aussi non-Newtonien. Il est maintenant l’occasion pour les industries de proposer une solution, peu chère mais précise pour mesurer les débits dans des canaux ouverts et pour tous types de fluides. / During a drilling operation, a certain number of unexpected events, related to the flow of drilling fluid in the well, may happen rather quickly. Examples of such events are formation fluid influx (kick) and mud loss to the formation. An uncontrolled kick that increases in intensity may result in what is known as a blowout (e.g. the Deepwater Horizon incident in 2010). Influxes and kicks are traditionally detected by monitoring the drilling mud balance in the well, in particular, by monitoring the flow out the well and comparing it to the incoming flow induced by the pumps. Most methods of monitoring the flow out of the well while drilling consists in using a simple paddle (sensor that measures the height of drilling fluid with the inclination of a paddle) in the return flow line, or in using a Coriolis flow meter (flow meter known for its accuracy but expensive and requires a complex installation by adding a bypass). There is a clear need of a new accurate flow meter, but easy to install and inexpensive. The Venturi flume has been used as flow meter for years in water industry. It appears as a cheap but accurate solution to measure large flow rates. Many people have worked on this solution to improve its accuracy and to expand its scope. They have developed models, based on a calibration process, to relate the upstream height to the flow rate. This means that current models, as ISO NORM 4359 [1], can be used only for water flow and specific geometry. As known, muds have non-Newtonian behavior and water models cannot be used with this kind of fluids. For our application, trapezoidal shape appears as a good compromise between accuracy and range of flow rate measurements. Thus, we built a model able to compute the flow rate with taking into account fluid properties and geometrical parameters. This model is simplified in 1D form by using the Shallow Water theory, and completed by a friction model taking into account the variation of fluid properties and geometry along the open channel. It have been validated by series of experiments with both Newtonian and non-Newtonian fluids, where we measured the flow rate and heights of the flow at different locations along the trapezoidal Venturi flume. It have been also completed by 3D CFD which has been simulated both Newtonian and non-Newtonian flows along the flume. To generalized this study, the work was extended to another shape of Venturi more suited to some rig design. The correlations and models developed and experimentally validated during this research can be used to extend the use of Venturi flume flow meters for any fluids : Newtonian and non- Newtonian. It is an opportunity for industries to propose a cheap but accurate solution to measure flow rates in open channels with any kind of fluids.