Correntes de densidade são fluxos gravitacionais gerados pela diferença de densidade entre dois fluidos. Correntes de turbidez fazem parte de uma sub-classificação das correntes de densidade, na qual o fluido mais denso tem, na sua composição, partículas em suspensão. Muitos trabalhos numéricos já estudaram a dinâmica das correntes de turbidez, mas, nenhum dos encontrados aplicou mudanças de relevo concomitantes com a simulação, causadas pela sedimentação das próprias partículas da corrente e nem alterou o relevo após a passagem de cada evento em um domínio tridimensional. O presente trabalho pretende analisar a alteração no relevo de fundo causada por uma corrente de turbidez. No código Incompact3d, as equações de Navier-Stokes, Continuidade e Transporte e Difusão são resolvidas em uma malha cartesiana tridimensional. A condição inicial adotada é a de Lock-Exchange. As simulações realizadas utilizaram Simulação Numérica Direta (DNS). O código utiliza um esquema compacto centrado de sexta ordem, em diferenças finitas, para o esquema espacial, e Adams-Bashfort de terceira ordem para o esquema temporal. A validação do código foi realizada comparando-se com trabalhos experimental e numéricos. A análise das diferentes proporções granulométricas mostrou que quanto maior é a quantidade de material grosso na condição inicial, maior será seu depósito para um dado tempo. Em consequência, mais relevante se torna a consideração da alteração do relevo de fundo. Além disso, quanto maior o fator de compactação do sedimento, maior será o erro de não considerar a atualização de fundo. Os resultados também apontaram que os erros médios ao não considerar a atualização do fundo são da ordem de 4% da massa de depósito em 20 tempos adimensionais, para os parâmetros utilizados. Ao se propagar uma corrente de turbidez sobre o depósito de outra, os erros se mostram menores. / Gravity currents are gravitational fluxes triggered by density di erence between two fluids. A sub-classification of those are turbidity currents, in which the denser fluid is composed by the lighter fluid plus suspended particles. Many papers had shown turbidity currents dynamics, although none of the papers found had applied changes in the simulated topography due to deposit during the own simulation, neither they had altered a 3D domain topography after each flux, applying the changes caused by the previous current. The present dissertation aims to analyse the turbidity current dynamics alteration caused by the influence of its own deposit, altering the topography during the very simulation. The analysis is conducted in a polidispersed turbidity current. The Incompact3d code solves Navier-Stokes, continuity and transport-di usion equation, in a tridimensional cartesian mesh. Lock-exchange was chosen to be the initial condition. Direct Numerical Simulations (DNS) are performed. Sixth order compact finite-di erence schemes are used on the spatial domain, while third order Adams-Bashfort is applied for the temporal evaluation. Comparisons with numerical and experimental papers were performed for code verification. Results showed the coarser the particles on the starting lock-exchange, the higher its deposit is, and the more the terrain will be altered. Nevertheless, the bigger the compacting factor, the bigger the error of not considering bathymetry alteration. Results also point that the average errors of not considering the update are in order of 4% on the mass deposit, after 20 dimensionless times, for the used parameters. When a current propagates over the deposit of a previous one, these errors are smaller.

Cette HDR, présente les travaux de simulation et de modélisation de la combustion turbulente des écoulements diphasiques. la simulation numérique directe est la base de ces travaux. Un code de DNS a été couplé avec un solveur Lagrangien pour décrire une phase liquide dispersé s'évaporant dans le domaine. Tous les aspects présents dans les chambres de combustion sont abordés : dispersion, évaporation, mélange et combustion.

Worldwide demand for energy is increasing rapidly, partly driven by dramatic economic growth in developing countries. This growth has sparked concerns over the finite availability of fossil fuels and the impact of their combustion on climate change. Consequently, many recent research efforts have been devoted to the development of renewable fuels and sustainable energy systems. Interest in liquid biofuels, such as ethanol, has been particularly high because these fuels fit into the conventional infrastructure for the transportation sector. Ethanol is a renewable fuel produced through the anaerobic fermentation of sugars obtained from biomass. However, the relatively high energy demand of its production process is a major factor limiting the usefulness of ethanol as a fuel. Due to the dilute nature of the fermentation product stream and the presence of the ethanol-water azeotrope, the separation processes currently used to recover anhydrous ethanol are particularly inefficient. In fact, the ethanol separation processes account for a large fraction of the total process energy demand. In the conventional ethanol separation process, ethanol is recovered using several distillation steps combined with a dehydration process. In this dissertation, a new hybrid pervaporation-distillation system, named Membrane Dephlegmation, was proposed and investigated for use in ethanol recovery. In this process, countercurrent vapour-liquid contacting is carried out on the surface of a pervaporation membrane, leading to a combination of distillation and pervaporation effects. It was intended that this new process would lead to improved economics and energy efficiency for the entire ethanol production process. The Membrane Dephlegmation process was investigated using both numerical and experimental techniques. Multiphase Computational Fluid Dynamics (CFD) was used to study vapour-liquid contacting behaviour in narrow channels and to estimate heat and mass transfer rates. Results from the CFD studies were incorporated into a simplified design model and the Membrane Dephlegmation process was studied numerically. The results indicated that the Membrane Dephlegmation process was more efficient than simple distillation and that the ethanol-water azeotrope could be broken. Subsequently, a pilot-scale experimental system was constructed using commercially available, hydrophilic NaA zeolite membranes. Results obtained from the experimental system confirmed the accuracy of the simulations.

Worldwide demand for energy is increasing rapidly, partly driven by dramatic economic growth in developing countries. This growth has sparked concerns over the finite availability of fossil fuels and the impact of their combustion on climate change. Consequently, many recent research efforts have been devoted to the development of renewable fuels and sustainable energy systems. Interest in liquid biofuels, such as ethanol, has been particularly high because these fuels fit into the conventional infrastructure for the transportation sector. Ethanol is a renewable fuel produced through the anaerobic fermentation of sugars obtained from biomass. However, the relatively high energy demand of its production process is a major factor limiting the usefulness of ethanol as a fuel. Due to the dilute nature of the fermentation product stream and the presence of the ethanol-water azeotrope, the separation processes currently used to recover anhydrous ethanol are particularly inefficient. In fact, the ethanol separation processes account for a large fraction of the total process energy demand. In the conventional ethanol separation process, ethanol is recovered using several distillation steps combined with a dehydration process. In this dissertation, a new hybrid pervaporation-distillation system, named Membrane Dephlegmation, was proposed and investigated for use in ethanol recovery. In this process, countercurrent vapour-liquid contacting is carried out on the surface of a pervaporation membrane, leading to a combination of distillation and pervaporation effects. It was intended that this new process would lead to improved economics and energy efficiency for the entire ethanol production process. The Membrane Dephlegmation process was investigated using both numerical and experimental techniques. Multiphase Computational Fluid Dynamics (CFD) was used to study vapour-liquid contacting behaviour in narrow channels and to estimate heat and mass transfer rates. Results from the CFD studies were incorporated into a simplified design model and the Membrane Dephlegmation process was studied numerically. The results indicated that the Membrane Dephlegmation process was more efficient than simple distillation and that the ethanol-water azeotrope could be broken. Subsequently, a pilot-scale experimental system was constructed using commercially available, hydrophilic NaA zeolite membranes. Results obtained from the experimental system confirmed the accuracy of the simulations.

In dieser Arbeit wird ein Modell zum Aufzählen von DNA-Codes entwickelt. Indem eine Ordnung auf der Menge aller DNA-Codewörter eingeführt und auf die Menge aller Codes erweitert wird, erlaubt das Modell das Auffinden von DNA-Codes mit bestimmten Eigenschaften, wie Überlappungsfreiheit, Konformität, Kommafreiheit, Stickyfreiheit, Überhangfreiheit, Teilwortkonformität und anderer bezüglich einer gegebenen Involution auf der Menge der Codewörter. Ein auf Grundlage des geschaffenen Modells entstandenes Werkzeug erlaubt das Suchen von Codes mit beliebigen Kombinationen von Codeeigenschaften. Ein weiterer wesentlicher Bestandteil dieser Arbeit ist die Untersuchung der Optimalität von DNA-Codes bezüglich ihrer Informationsrate sowie das Finden solider DNA-Codes. / In this work a model for enumerating DNA codes is developed. By applying an order on the set of DNA codewords and extending this order on the set of codes, this model assists in the discovery of DNA codes with properties like non-overlappingness, compliance, comma-freeness, sticky-freeness, overhang-freeness, subword-compliance, solidness and others with respect to a given involution on the set of codewords. This tool can be used to find codes with arbitrary combinations of code properties with respect to the standard Watson-Crick-DNA involution. The work also investigates DNA codes with respect to the optimizing of the information rate, as well as finding solid DNA codes.

The Domain Name System (DNS) is a critical component of the Internet. DNS provides the ability to map human-readable and memorable domain names to machine-level IP addresses and other records. These mappings lie at the heart of the Internet's success and are essential for the majority of core Internet applications and protocols. The critical nature of DNS means that it is often the target of abuse. Cyber-criminals rely heavily upon the reliability and scalability of the DNS protocol to serve as an agile platform for their illicit operations. For example, modern malware and Internet fraud techniques rely upon DNS to locate their remote command-and-control (C&C) servers through which new commands from the attacker are issued, serve as exfiltration points for information stolen from the victims' computers, and to manage subsequent updates to their malicious toolset. The research described in this thesis scientifically addresses problems in the area of DNS-based detection of illicit operations. In detail, this research studies new methods to quantify and track dynamically changing reputations for DNS based on passive network measurements. The research also investigates methods for the creation of early warning systems for DNS. These early warning systems enables the research community to identify emerging threats (e.g., new botnets and malware infections) across the DNS hierarchy in a timelier manner.

The exceptional self-assembly properties of DNA as well as its ability to interact with different kinds of chemical compounds and biological structures make this biomolecule to an interesting object for the fabrication of artificial nanostructures. In this work several methods for a DNA-based self-assembly of electronic nanocircuitry are explored. For this, four basic steps, which turned out to be essential within a circuit assembly process, are addressed: (i) The formation of multi-branched DNA junctions by a simple building-block procedure. (ii) The site-specific attachment of nanoobjects (gold colloids) at the center of DNA junctions. (iii) The integration of DNA into microstructured gold electrode arrays, in particular the stretching of single DNA molecules between two electrodes. For this a simple, but reliable methods for the functionalization of gold electrodes by using aminoethanethiol was developed, which enables end-specific attachment of the DNA but does not require DNA modification. (iv) The metallization of DNA. A synthesis procedure was developed, which results in the formation of continuous chains of 5nm platinum clusters along the DNA. The metal deposition process turned out to take place exclusively at the DNA while background metallization is completely suppressed.

Le but de cette thèse est d'étudier numériquement les écoulements diphasiques liquide-gaz à l'aide d'une méthode de suivi d'interface précise. Tout d'abord, nous mettons en place une configuration turbulence homogène isotrope diphasique. Cette configuration est utilisée pour étudier la turbulence liquide-gaz ainsi que le modèle ELSA. A l'aide de la simulation présentée il a été possible de déterminer les constantes de modélisation et de valider les termes sources utilisés dans la zone dense du spray. Ensuite, le phénomène d'évaporation est étudié en utilisant dans un premier temps un scalaire passif puis en utilisant un formalisme DNS d'évaporation. Les équations d'énergie et des espèces ont été ajoutées dans le code ARCHER. La validation de la DNS d'évaporation a été réalisée en comparant nos résultats aux solutions théoriques, tel que la loi du D2. Les limitations et les apports de cette approche sont finalement discutés et des perspectives d'améliorations sont proposées.

IPv6, protocole succédant à IPv4, est en cours de déploiement dans l'Internet. Il repose fortement sur le mécanisme Neighbor Discovery Protocol (NDP). Celui-ci permet non seulement à deux nœuds IPv6 de pouvoir communiquer, à l'instar du mécanisme Address Resolution Protocol (ARP) en IPv4, mais il apporte aussi de nouvelles fonctionnalités, telles que l'autoconfiguration d'adresse IPv6. Aussi, sa sécurisation pour le bon fonctionnement de l'Internet en IPv6 est critique. Son mécanisme de sécurité standardisée à l'Internet Engineering Task Force (IETF) se nomme Secure Neighbor Discovery (SEND). Il s'appuie à la fois sur l'utilisation d'identifiants cryptographiques, adresses IPv6 appelées Cryptographically Generated Addresses (CGA) et qui sont générées à partir d'une paire de clés publique/privée, et de certificats électroniques X.509. L'objet de cette thèse est l'étude de ces identifiants cryptographiques, les adresses CGA, ainsi que le mécanisme SEND les employant, et leurs réutilisations potentielles pour la sécurisation IPv6. Dans une première partie de cette thèse, tout d'abord, nous posons l'état de l'art. Dans une deuxième partie de cette thèse, nous nous intéressons à la fiabilité du principal mécanisme connu employant les adresses CGA, le mécanisme SEND. Dans une troisième et dernière partie de cette thèse, nous présentons des utilisations des identifiants cryptographiques pour la sécurisation IPv6

La méso-combustion est le régime de combustion où la taille caractéristique du domaine est juste supérieure à la distance de coincement de la flamme , typiquement de l'ordre du centimètre. La difficile réalisation de systèmes de combustion fonctionnant en ce régime de flamme particulier suscite l'intérêt : il devient alors possible de tirer parti de la haute densité énergétique des hydrocarbures pour concevoir des systèmes de production d'énergie plus compacts. Nous nous intéressons à la réalisation de calculs DNS compressibles d'une chambre de combustion cubique de 8 x 10 x 8 mm3. Ce travail présente autant la mise en œuvre des calcules, en particulier la problématique de la condition frontière mur, que les résultats obtenus. Ces derniers nous permettent d'analyser la phénoménologie complexe de cet écoulement réactif confiné et serviront de base à des modélisations futures.