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Electrochemical characterization of nanostructured SnO2 and TiO2 forpotential application as dielectric materials in sulfonated-polyaniline based supercapacitorsNgqongwa, Lundi Vincent January 2010 (has links)
<p>In this research project, nanostructured composites based on Tin dioxide (SnO2) and Titanium dioxide (TiO2) with poly-4-styrene sulfonic acid (PSSA) doped polyaniline (PANI) conducting polymer has been investigated based on their structural, electrical and electrochemical properties. The synthesis of conducting polymers and their metal oxide or composites have been carried out chemically or electrochemically according to methods modified from the literature. Layer-by-layer construction of nano-Metal Oxide/PSSA doped polyaniline composites were successfully constructed by electroanalytical methods on the surface of a glassy carbon working electrode (GCE).</p>
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Electrochemical ochratoxin a immunosensors based on polyaniline nanocomposites templated with amine- and sulphate-functionalised polystyrene latex beadsMuchindu, Munkombwe January 2010 (has links)
<p>Polyaniline nanocomposites doped with poly(vinylsulphonate) (PV-SO3 &minus / ) and nanostructured polystyrene (PSNP) latex beads functionalized with amine (PSNP-NH2) and sulphate (PSNP-OSO3 &minus / ) were prepared and characterised for use as nitrite electro-catalytic chemosensors and ochratoxin A immunosensors. The resultant polyaniline electrocatalytic chemosensors (PANI, PANI|PSNP-NH2 or PANI|PSNP-OSO3 &minus / ) were characterized by cyclic voltammetry (CV), ultraviolet-visible (UV-Vis) spectroscopy and scanning electron microscopy (SEM). Brown-Anson analysis of the multi-scan rate CV responses of the various PANI films gave surface concentrations in the order of 10&minus / 8 mol/cm. UV-vis spectra of the PANI films dissolved in dimethyl sulphoxide showed typical strong absorbance maxima at 480 and 740 nm associated with benzenoid p-p* transition and quinoid excitons of polyaniline, respectively. The SEM images of the PANI nanocomposite films showed cauliflower-like structures that were < / 100 nm in diameter. When applied as electrochemical nitrite sensors, sensitivity values of 60, 40 and 30 &mu / A/mM with corresponding limits of detection of 7.4, 9.2 and 38.2 &mu / M NO2 &minus / , were obtained for electrodes, PANI|PSNP-NH2, PANI and PANI|PSNP-SO3 &minus / , respectively. Immobilisation of ochratoxin A antibody onto PANI|PSNP-NH2, PANI and PANI|PSNPSO3 - resulted in the fabrication of immunosensors.</p>
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Boron-doped Diamond Sensors for the Determination of Organic Compounds in Aqueous MediaHess, Euodia January 2010 (has links)
<p>In electrochemical oxidation treatment of wastewater, the electrode material is an important parameter in optimizing oxidative electrochemical processes, since the mechanism and products of several anodic reactions are known to depend on the anode material. The electrochemical oxidation of benzaldehyde, nitrobenzene and m-cresol on bare boron-doped diamond (BDD) electrode was investigated. Cytochrome c was then electrochemically immobilsed onto the functionalized BDD electrode by cyclic voltammetry. Oxidation and reduction reaction mechanism of each flavonoid was studied. There was one oxidation and reduction peaks for quercitin and catechin respectively, and two oxidation and two reduction peaks for rutin. The cytochrome c modified BDD electrode showed good sensitivity for all three flavonoids and low detection limits i.e. 0.42 to 11.24 M as evaluated at oxidation and reduction peaks, respectively.</p>
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Nanocomposite immunosensor for anti-transglutaminase antibodyNatasha West January 2009 (has links)
<p>Coeliac disease (CD) is a gluten intolerance condition that results in the flattening of the villi, which line the bowel. It is the most common cause of malabsorption of food nutrients. This inability to absorb sufficient levels of nutrients causes many of the common symptoms experienced by CD patients. Some of the symptoms, which lead to an increase in mortality rate, include chronic diarrhea, fatigue, iron-deficient anemia and osteoporosis. People with CD have higher than normal levels of certain antibodies in their blood. Thus, the concentration of anti-transglutaminase antibody (anti-tTG) in human sera is an important analytical marker for the diagnosis of CD. An immunosensor is a type of biosensor that has an antigen or antibody fragment as its biological recognition component. The specificity of the molecular recognition of antigens by antibodies to form a stable complex is the basis of immunosensor technology. In this work, overoxidized polypyrrole (OvoxPpy) was electrosynthesized as a noval sensor platform on a glassy carbon electrode (GCE). The OvoxPpy was then doped with gold-nanoparticles (GNP) by electrodeposition using cyclic voltammetry to form GNP|OvoxPpy||GCE electrode system. Morphology and size of the GNP|OvoxPpy||GCE nanocomposite were determined using scanning electron microscopy. The electrochemical immunosensor for anti-tTG antibodies was prepared by immobilizing transglutaminase antigen (tTG-antigen) onto the GNP|OvoxPpy||GCE by drop coating and allowed to incubate for 2 hrs. The electrochemical characterization of the nanocomposite platform and immunosensor were studied by voltammetry and electrochemical impedance spectroscopy (EIS)...</p>
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Polymeric tyrosinase nanobiosensor system for the determination of endocrine disrupting bisphenol AMatyholo, Virginia Busiswa January 2011 (has links)
The main objective of this work was to develop simple and sensitive electrochemical sensors for the detection of bisphenol A. To investigate the electrochemical behavior of BPA on a bare glassy carbon electrode. To apply the developed biosensor for the determination BPA by differential pulse voltammetry, electrochemical impedance spectrometry, square wave voltammetry and steady-state amperometry. To characterize the synthesized PDMA-PSS by cyclic voltammetry (CV), UV-Vis spectroscopy, transmission electron microscopy (TEM), scanning electron microscopy (SEM).
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Synthesis and electrochemistry of novel conducting dendrimeric star copolymers on poly(propylene imine) dendrimerBaleg, Abd Almonam Abd Alsalam January 2011 (has links)
<p>One of the most powerful aspects of conducting polymers is their ability to be nanostructured through innovative, synthetically manipulated, transformations, such as to tailor-make the polymers for specialized applications. In the exponentially increasing wide field of nanotechnology, some special attention is being paid to innovative hybrid dendrimer-core based polymeric smart materials. Star copolymers are a class of branched macromolecules having a central core with multiple linear polymer chains extending from the core. This intrinsic structural feature yields a unique 3D structure with extended conjugated linear polymer chains, resulting in star copolymers, which have higher ionic conductivities than their corresponding non-star conducting polymer counterparts. In this study an in-depth investigation was carried out into the preparation and characterization of specialized electronic &lsquo / smart materials&rsquo / . In particular, the preparation and characterization of novel conducting dendrimeric star copolymers which have a central poly(propylene imine) (PPI) dendrimer core with conducting polypyrrole (PPy) chains extending from the core was carried out. This involved, first, the preparation of a series of dendrimeric polypyrrole poly(propylene imine) star copolymers (PPI-co-PPy), using generations 1 to 4 (G1 to G4) PPI dendrimer precursors. The experimental approach involved the use of both chemical and electrochemical synthesis methods. The basic procedure involved a condensation reaction between the primary amine of a diamino functional PPI dendrimer surface and 2-pyrrole aldehyde, to afford the pyrrole functionalized PPI dendrimer (PPI-2Py). Polymerization of the intrinsically contained monomeric Py units situated within the dendrimer backbone was achieved via two distinctly different routes: the first involved chemical polymerization and the second was based on potentiodynamic oxidative electrochemical polymerization. The star copolymers were then characterized using various sophisticated analytical techniques, in-situ and ex-situ. Proton nuclear magnetic resonance spectroscopy (1HNMR) and Fourier transform infrared spectroscopy (FTIR) were used to determine the structures. Scanning electron microscopy (SEM) was used to determine the morphology. Themogravimetric analysis (TGA) was used to study the thermal stability of the prepared materials. X-ray diffraction analysis (XRD) was used to study the structural make-up of phases, crystallinity and amorphous content. Hall effect measurements were carried out to determine the electrical conductivity of the chemically prepared star copolymers. The PPI-co-PPy exhibited improved thermal stability compared to PPI-2Py, as confirmed by TGA. SEM results showed that the surface morphology of the functionalized dendrimer and star copolymer differed. The surface morphology of the chemically prepared star copolymers resembled that of a flaky, waxy material, compared to the ordered morphology of the electrochemically grown star copolymers, which resembled that of whelk-like helixes. In the case the electrochemically grown star copolymers, SEM images recorded at higher magnifications showed that the whelk-like helixes of the star copolymers were hollow tubes with openings at their tapered ends, and had an average base diameter of 2.0 &mu / m. X-ray diffraction analysis of the first generation star copolymer G1PPI-co-PPy revealed a broadly amorphous structure associated with PPy, and crystalline peaks for PPI. Cyclic voltammetry (CV), square wave voltammetry (SWV) and electrochemical impedance spectroscopy (EIS) techniques were used to study and model the electrochemical reactivity of the star copolymer materials. Electrochemical impedance spectroscopy data showed that the G1PPI-co-PPy exhibited slightly higher ionic conductivity than pristine PPy in lithium perchlorate. The second generation star copolymer G2PPI-co-PPy electrochemically deposited on a platinum (Pt) electrode had a lower electrochemical charge transfer resistance compared to electrodeposited polypyrrole (PPy) on a Pt electrode, and bare Pt. The decrease in charge transfer resistance was attributed to an increase in the conjugation length of the polymer as a result of the linking of the highly conjugated PPy to the PPI dendrimer. Bode impedimetric analysis indicated that G2PPI-co-PPI was a semiconductor, with a maximum phase angle shift of 45.3° / at 100 MHz. The star copolymer exhibited a 2- electron electrochemistry and a surface coverage of 99%. Results of Hall effect measurements showed that the star copolymer is a semiconducting material, having a conductivity of 0.7 S cm-1, in comparison to the 1.5 S cm-1 of PPy. To the best of my knowledge, these new star copolymers have not been reported in the open literature. Their properties make them potentially applicable for use in biosensors.</p>
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Applications for Molten Carbonate Fuel CellsRexed, Ivan January 2014 (has links)
Molten Carbonate Fuel cells are high temperature fuel cells suitable for distributed generation and combined heat and power, and are today being installed on commercial basis in sizes from 100kW to several MW. Novel applications for MCFC which have attracted interest lately are MCFC used for CO2 separation from combustion flue gas, and high temperature electrolysis with reversible fuel cells. In the first application, the intrinsic capability of the MCFC to concentrate CO2 from the cathode to the anode side through the cell reaction is utilized. In the second application, the high operating temperature and relatively simple design of the MCFC is utilized in electrolysis, with the aim to produce a syngas mix which can be further processed into hydrogen of synthetic fuels. In this thesis, the effect on fuel cell performance of operating a small lab-scale molten carbonate fuel cell in conditions which simulate those that would apply if the fuel cell was used for CO2 separation in combustion flue gas was studied. Such operating conditions are characterized especially by a low CO2 concentration at the cathode compared to normal operating conditions. Sulfur contaminants in fuel gas, especially H2S, are known poisoning agents which cause premature degradation of the MCFC. Furthermore, combustion flue gas often contains sulfur dioxide which, if entering the cathode, causes performance degradation by corrosion and by poisoning of the fuel cell. This makes poisoning by sulfur contaminants of great concern for MCFC development. In this thesis, the effect of sulfur contaminants at both anode and cathode on fuel cell degradation was evaluated in both normal and in low CO2 simulated flue gas conditions. The results suggested that the poisoning effect of SO2 at the cathode is similar to that of H2S at the anode, and that it is possibly due to a transfer of sulfur from cathode to anode. Furthermore, in combination with low CO2 conditions at the cathode, SO2 contaminants cause fuel cell poisoning and electrolyte degradation, causing high internal resistance. By using a small lab-scale MCFC with commercial materials and standard fuel cell operating conditions, the reversible MCFC was demonstrated to be feasible. The electrochemical performance was investigated in both fuel cell (MCFC) and electrolysis cell (MCEC) modes. The separate electrodes were studied in fuel cell and electrolysis modes under different operating conditions. It was shown that the fuel cell exhibited lower polarization in MCEC mode than in MCFC mode, and a high CO2 concentration at the fuel cell anode reduced the polarization in electrolysis mode, which suggested that CO2 is reduced to produce CO or carbonate. / Smältkarbonatbränsleceller (MCFC) är en typ av högtemperaturbränsleceller som är anpassade för kombinerad el- och värmeproduktion i mellan-till stor skala. Idag installeras MCFC på kommersiell basis i storlekar mellan 100kW och flera MW. En ny typ av tillämpning för MCFC som har väckt intresse på senare tid är användandet av MCFC för CO2-avskiljning i kombination med konventionell elproduktion genom förbränning. En annan ny tillämpning är högtemperaturelektrolys genom användandet av reversibla bränsleceller. I det första fallet utnyttjas att CO2 kan koncentreras från katod- till anodsidan, vilket sker genom cellreaktionen för MCFC. I det andra fallet utnyttjas den höga arbetstemperaturen och den relativt enkla cell-designen för att använda reversibla MCFC till elektrolys, med syfte att producera en syngas-blandning som kan förädlas till vätgas eller till syntetiskt bränsle. I denna avhandling studeras effekten på bränslecellens prestanda genom att operera en MCFC i lab-skala med driftförhållanden som simulerar de som förväntas uppkomma om bränslecellen användes för CO2-avskiljning ur rökgaser från förbränning. Dessa driftförhållanden karaktäriseras av låg CO2-koncentration på katodsidan jämfört med normal drift. Svavelföroreningar i bränsle, speciellt H2S, är kända för att orsaka förgiftning av anoden, vilket i sin tur försämrar bränslecellens prestanda. Dessutom innehåller rökgaser ofta SO2, vilket antas orsaka korrosion och förgiftning av katoden. Detta gör effekten av svavelföroreningar till ett prioriterat ämne för utvecklingen av MCFC. I denna avhandling undersöks effekten av svavelföroreningar på både anod- och katodsidan, i normala driftförhållanden och i förhållanden med låg CO2 som simulerar användandet av rökgaser för CO2-avskiljning. Resultaten tyder på att effekten av förgiftning med SO2 på katoden liknar den med H2S på anoden, och att detta kan vara orsakat av en transport av svavel från katod till anod. Vidare, i kombination med låg CO2 koncentration på katoden så orsakar SO2-föroreningar elektrolytdegradering, vilket orsakar hög inre resistans. Genom att använda en liten MCFC i lab-skala med kommersiella material och standardförhållanden för MCFC påvisades att reversibla smältkarbonatbränsleceller kan vara ett lovande koncept. Den elektrokemiska prestandan av både cell och separata elektroder undersöktes både som bränslecell (MCFC)och vid elektrolys (MCEC). Resultaten visade att cellen uppvisade lägre polarisation vid elektrolys än som bränslecell, och att ten hög CO2-koncentration på det som är bränslecellens anodsida gav upphov till en minskad elektrodpolarisation, vilket indikerar att CO2 reduceras för att producera CO eller karbonat. / <p>QC 20141028</p>
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Etude de la durabilité de cellules d'électrolyse de la vapeur d'eau à haute température : influence des paramètres de fonctionnement / Durability study of a cathode supported cell for the High Temperature Steam Electrolysis (HTSE) : influence of operating parametersMansuy, Aurore 04 December 2012 (has links)
Ce travail porte sur l’analyse du comportement en durabilité d’une cellule à oxydes solides en fonctionnement en mode Electrolyse de la vapeur d’eau à Haute Température (EHT). Il s’agit plus particulièrement d’identifier les paramètres influant sur la durabilité de la cellule et de comprendre les mécanismes associés, de manière à établir le meilleur compromis durabilité-performance. Un premier axe de recherche correspond à la caractérisation électrochimique initiale de la mono-cellule choisie pour l’étude, à savoir une cellule à électrode support de type LSFC/YDC/8YSZ/Ni-YSZ dont le comportement électrochimique est étudié sous diverses températures, conditions de gaz et densités de courant. Ensuite, la dégradation des performances est étudiée in situ par spectroscopie d’impédance électrochimique et voltampérométrie lors de diverses études séquentielles par paliers de 200 heures. L’influence du taux de conversion et de la densité de courant sur la dégradation des performances est ainsi analysée. Pour compléter cette étude, des analyses physico-chimiques et microstructurales post tests ont été réalisées sur des échantillons ayant fonctionné 1000 heures afin de faire le lien entre les modifications électrochimiques observées et les changements de structure et de composition des matériaux de cellule. Des hypothèses de mécanismes de dégradation ont ainsi pu être formulées. / This work is dedicated to the study on the long term behavior of a solid oxide electrolysis cell (SOEC). More specifically, the target is to identify and understand the influence of main working parameters on the cell durability in order to find the best compromise between performances and durability. The initial part of this work is to characterize electrochemically the single cell selected for the study, that is to say a cathode supported cell of the type LSFC/YDC/8YSZ/Ni-YSZ at different gas conditions, temperature and current density. Then, the degradation of the cell performances has been studied by Electrochemical Impedance Spectroscopy (EIS) and voltamperometry (i-V) curves during sequential tests of 200h. The influence of the most important working parameters like the current density and the steam conversion has been analyzed. To complete this study, physico-chemical and microstructural analyses have been performed on cells that have been operated over 1000 hours, to make a link between electrochemical degradation observed on the cell and composition and structural changes of cell materials.
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Etude numérique et expérimentale d’écoulements diphasiques : application aux écoulements à bulles générées par voie électrochimique / Numerical and experimental study of two-phase flows : application to bubbly flows in the vicinity of gas-evolving electrodesSchillings, Jonathan 18 July 2017 (has links)
La production pariétale de bulles de gaz et son impact sur la dynamique de la phase liquide en canal vertical est étudiée numériquement et expérimentalement. Dans un premier temps, un modèle de mélange 2D stationnaire est utilisé pour décrire l’évolution moyenne des panaches de gaz. Grâce à cette approche, un modèle de couche limite a pu être développé et a permis l’identification des nombres adimensionnels pertinents (analogues aux nombres de Rayleigh et de Prandtl pour la thermique) afin de caractériser les écoulements à bulles dispersées. Dans un second temps, un modèle Eulérien-Lagrangien 3D instationnaire, prenant en compte le couplage quadrilatéral (interactions bullesliquide et bullesbulles) est résolu par Simulation Numérique Directe (DNS) et permet ainsi une description plus fine de l’écoulement à l’échelle de la phase dispersée. Enfin, ces approches numériques sont complétées par des mesures de Spectroscopie d’Impédance Electrochimique (SIE) lors de la production de dihydrogène et de dioxygène par électrolyse alcaline. Les modèles d’écoulement proposés ici montrent globalement un très bon accord avec les résultats expérimentaux tirés de la littérature. Les approches homogènes et DNS présentent toutefois quelques disparités sur l’évaluation du taux de vide dans certaines conditions. Parallèlement, les mesures et simulations de SIE ont montré être clairement affectées par les évolutions du panache de bulles, les spectres d’impédance ont notamment mis en évidence une contribution basse fréquence fortement dépendante de la nature de la phase dispersée (taille de bulle et lois de dispersion). Les trois approches (modèle homogène, DNS et SIE) menées conjointement sont donc fortement complémentaires. Elles permettent non seulement une meilleure compréhension de la physique de l’écoulement diphasique, mais offrent aussi une capacité d’analyse de la pertinence des modèles existants tout en ouvrant la voie à leurs futures améliorations / The wall production of gas bubbles and its impact on the liquid dynamics in a vertical channel is studied by means of numerical simulations and experimentation. First, a 2D stationary mixture model is used to describe the averaged plumes evolutions. Through this approach, a boundary layer model has been developed and identified dimensionless numbers (Raleigh-like and Prandtl-like) characteristic of bubbly flows. Secondly, a 3D non-stationary four-way coupled (with bubblesliquid and bubblesbubbles interactions) Eulerian-Lagrangian model is solved by Direct Numerical Simulation (DNS) and allows a finer description of the two-phase flows at bubble-scale. Finally, the numerical methods are completed by Electrochemical Impedance Spectroscopy (EIS) measurements during hydrogen and oxygen production by alkaline electrolysis.The two-phase flow models are in good agreement with experimental results from literature. There are still some disparities between the homogeneous model and the DNS about the void fraction calculation under certain conditions, though. In the meantime, both EIS measurements and simulations were clearly affected by bubbles plume evolutions, the impedance spectra highlighted a low frequency contribution highly sensible to the nature of the dispersed phase (bubble size a dispersion laws). The 3 approaches (homogeneous model, DNS and EIS) used collectively are strongly complementary. They allow not only a better comprehension of the physics of the two-phase flow, but also serve the analysis of existing models while leading the way for further improvements
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Synthèse et caractérisations de nanotubes de TiO2 pour applications biomédicales : propriétés électrochimiques et bioactivité / Synthesis and characterizations of TiO2 nanotubes for biomedical applications : electrochemical properties and bioactivityHilario, Fanny 02 October 2017 (has links)
Le Titane (Ti) est un matériau biocompatible largement utilisé dans le domaine biomédical, notamment pour les implants orthopédiques (prothèse de hanche ou du genou par exemple). Il se distingue plus particulièrement par son excellente résistance à la corrosion et sa capacité d’ostéo-intégration. Cependant, une surface plane de Ti n’est pas assez bioactive pour être implantée ; il est nécessaire d’avoir recours à un traitement de surface pour améliorer ses propriétés. La modification de la surface du titane par anodisation permet la synthèse de nanotubes (NTs) de TiO2 ordonnés et verticalement alignés. Cette technique, peu couteuse, rapide et facile à mettre en œuvre permet également de contrôler finement la morphologie des NTs (diamètre, longueur, aspect des parois…). De plus, les NTs étant amorphes après anodisation, la structure cristalline peut être ajustée par un traitement thermique, conduisant à une structure anatase (450°C) ou à une structure mixte d’anatase et de rutile (550°C).Ainsi, des surfaces de différentes morphologies et différentes structures cristallines ont été synthétisées dans ce travail de thèse, afin d’évaluer l’influence des caractéristiques morpho-structurelles sur la résistance à la corrosion en milieu physiologique et sur la bioactivité (formation d’hydroxyapatite et réponse cellulaire).Nous avons démontré dans cette étude que les NTs cristallisés présentent une plus grande résistance à la corrosion et une meilleure bioactivité que les NTs amorphes (ou que les surfaces planes de Ti). Plus précisément, en tenant compte des aspects électrochimiques, thermiques, mécaniques, chimiques et de bioactivité, il semblerait que des NTs mixtes d’environ 720 nm de long et 90 nm de diamètre constituent une surface optimale pour les applications visées.D’autre part, dans le cadre de l’étude des propriétés électrochimiques de l’interface, une attention toute particulière a été accordée dans ce travail de thèse à la modélisation des résultats de mesures par Spectroscopie d’Impédance Electrochimique (SIE). Il s’avère que la réponse en impédance des NTs de TiO2 en milieu physiologique correspond au modèle d’électrode poreuse de De Levie. Toutefois, pour des électrodes poreuses non-idéales, cette théorie peut être généralisée et modélisée par des lignes de transmission. Ainsi, le modèle de ligne de transmission proposé dans cette étude s’ajuste de façon très satisfaisante aux mesures expérimentales. Il permet notamment de mettre en évidence la nature très peu réactive des NTs de TiO2, justifiant ainsi leurs applications dans le domaine biomédical. / Titanium (Ti) is a biocompatible material widely used in the biomedical field, especially for orthopedic implants (for instance hip or knee replacement). It is particularly corrosion resistant and shows remarkable osseointegration properties. However, plane Ti surfaces are not bioactive enough to be implanted; they need to be improved by surface treatments. Surface modification of Ti by anodization enables to synthesize self-organized and vertically aligned TiO2 nanotubes (NTs). This cheap, fast and easily implementable technique also permits a fine tuning of NTs morphology (diameter, length, wall look, etc.). Moreover, since as-anodized NTs are amorphous, crystalline structure may be adjusted by heat treatment, producing anatase structure (450°C) or a mixed structure of anatase and rutile (550°C).Therefore, surfaces of different morphologies and crystalline structures have been synthesized in order to evaluate the influence of these characteristics on corrosion resistance in physiological medium and on bioactivity (hydroxyapatite formation and cell response).We demonstrated that crystallized NTs are more corrosion resistant and more bioactive than amorphous ones or even than flat Ti surfaces. More precisely, considering electrochemical, thermal, mechanical, chemical and bioactive aspects, it seems that mixed NTs of about 720 nm in length and 90 nm in diameter constitute an optimal surface for the present applications.Additionally, in the frame of electrochemical investigations, we focused on modeling experimental results from Electrochemical Impedance Spectroscopy (EIS) measurements. The impedance response of TiO2 NTs in physiological conditions can correspond to porous electrode model as developed by De Levie. However, for non-ideal electrodes, this theory can be generalized and modeled by transmission lines. Thus, the transmission line model developed in this study fits very well with experimental measurements. It suggests that TiO2 NTs are almost non-reactive, justifying their applications in biomedical fields.
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