Global ETD Search

1	Towards new π-conjugated systems for photovoltaic applications / Vers de nouveaux systèmes π-conjugués pour des applications photovoltaïques Chevrier, Michèle 15 September 2016 (has links) Le développement des énergies renouvelables est aujourd’hui devenu un enjeu mondial majeur comme alternative aux énergies fossiles dans la production d'énergie. Parmi elles, l’énergie solaire est considérée comme la source la plus prometteuse, permettant de couvrir l’ensemble des besoins énergétiques liés à l’activité humaine. Les cellules photovoltaïques les plus performantes aujourd’hui, entre 16 et 18 % en modules, sont composées de silicium, un semi-conducteur inorganique. Cependant, leur coût de production élevé a nécessité le développement de matériaux alternatifs moins couteux. Parmi les voies explorées, les cellules solaires organiques ont émergé comme une alternative prometteuse pour produire l’électricité à faible coût. Le sujet de cette thèse s’intègre dans ce contexte de recherche. Deux types de cellules solaires ont été étudiés : les cellules à hétérojonction en volume (BHJ) et sensibilisées au colorant (DSSCs). Le courant photogénéré repose généralement (i) dans les cellules BHJ, sur le transfert entre de charge entre un polymère donneur et un accepteur d’électrons (fullerène), tels que le couple poly(3-hexyl)thiophène (P3HT) et [6,6]-phényl-C61-butanoate de méthyle (PCBM), et (ii) dans les DSSCs, la sensibilisation de la surface d’un semi-conducteur inorganique tel que l’oxyde de titane par un colorant et la présence d’un électrolyte, jouant le rôle de médiateur redox. Bien qu’ayant atteint des rendements de photoconversion respectifs de 5 et 13 %, ces cellules nécessitent des améliorations pour une commercialisation à grande échelle. Tout d’abord, les performances des cellules BHJ à base de P3HT sont considérablement limitées par sa faible absorption, ne couvrant pas la globalité du spectre solaire. Afin de palier ce problème, nous avons combiné le P3HT avec des chromophores, i.e. des porphyrines, ayant une absorption plus étendue. Ensuite, pour assurer une meilleure extraction des charges au sein du dispositif, une couche interfaciale cathodique à base de polyélectrolytes pi-conjugués a été ajoutée. Enfin, des colorants extraits de la biomasse ont été préparés afin de remplacer les colorants coûteux à base de ruthénium. En outre, les électrolytes liquides étant volatils et corrosifs, ce qui limite considérablement la stabilité des DSSCs, des électrolytes solides à base de polymères ont été étudiés comme alternative. / Among renewable energies, the sunlight has by far the highest theoretical potential to meet the worldwide need in energy. Photovoltaic devices are thus currently the subject of intense research for low-cost conversion of sunlight into electrical power. In particular, organic photovoltaics have emerged as an interesting alternative to produce electricity due to their low manufacturing cost compared to silicon solar cells, their mechanical flexibility and the versatility of the possible chemical structures. In this dissertation, we focused our research on the development of new organic pi-conjugated materials for organic solar cells applications. Two types of solar cells have been studied during this work: bulk heterojunction and dye-sensitized solar cells. The charge transfer leading to the photocurrent is usually based on (i) a polymer donor and a fullerene acceptor in BHJ solar cells, such as the widely studied poly(3-hexylthiophene) (P3HT) and [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) materials and (ii) a metal oxide (titanium oxide) sensitized with a dye and an electrolyte in DSSCs. Despite power conversion efficiencies have reached 5 and 13 % respectively for these two types of devices, they still display several drawbacks that limit their commercialization. P3HT displays a narrow absorption of the solar spectrum thus limiting the conversion efficiency. To overcome this limitation, we combined P3HT with chromophores, i.e. porphyrins, having an extending absorption. Then, to ensure better charge transfer and extraction within the device, a cathode interfacial layer based on cationic pi-conjugated polyelectrolytes was added. Finally, dyes extracted from the biomass (chlorophyll a derivatives) were synthesized to replace the expensive ruthenium dyes in DSSCs. Since liquid electrolytes are volatile and corrosive, which considerably limit the DSSCs stability, solid polymer electrolytes were also developed as an alternative. Cellule solaire à hétérojonction Cellule solaire à colorant Polymérisation KCTP Polyélectrolyte conjugué Colorant à base de chlorophylle A Bulk-Heterojunction solar cell Dye-Sensitized solar cell KCTP polymerization Conjugated polyelectrolyte Dye base on chlorophyll A
2	Individual Approaches in Rich Learning Situations Material-based Learning with Pinboards Katzenbach, Michael 02 May 2012 (has links) (PDF) Active Approaches provide chances for individual, comprehension-oriented learning and can facilitate the acquirement of general mathematical competencies. Using the example of pinboards, which were developed for different areas of the secondary level, workshop participants experience, discuss and further develop learning tasks, which can be used for free activities, for material based concept formation, for coping with heterogeneity, for intelligent exercises, as tool for the presentation of students’ work and as basis for games. The material also allows some continuous movements and can thus prepare an insightful usage of dynamic geometry programs. Central Part of the workshop is a work-sharing group work with learning tasks for grades 5 to 8. The workshop will close with a discussion of general aspects of material-based learning. Individuelle Zugänge Lernumgebung Individualisierung verständnisorientiert Steckbrett Heterogenität Intelligente Übung Dynamische Geometrie Kreativität Präsentation Freiarbeit Koordinatensystem Symmetrie Funktion Bruchrechnung materialgestützt individuell Kommunikation Entdecken Vermuten Operative Serie Horizontale Vernetzung Vertikale Vernetzung Selbstkontrolle Eigenverantwortung Grundvorstellung Transfer Mentale Operation Kompetenz Experimentell Fehlende Werte Reichhaltige Lernumgebung Individual Approach Learning environment Individualization Comprehension-oriented Pinboard Heterogeneity Intelligent exercise Dynamic geometry Creativity Presentation Coordinate system Symmetry Function Fraction Material-based Individual Communication Discover Presume Structured series horizontal integration Vertical integration Self-control Self-responsibility Basic concept Transfer Mental operation Competency experimental Missing data Richlearning situation ddc:510 rvk:SD 2009
3	Individual Approaches in Rich Learning Situations Material-based Learning with Pinboards Katzenbach, Michael 02 May 2012 (has links) Active Approaches provide chances for individual, comprehension-oriented learning and can facilitate the acquirement of general mathematical competencies. Using the example of pinboards, which were developed for different areas of the secondary level, workshop participants experience, discuss and further develop learning tasks, which can be used for free activities, for material based concept formation, for coping with heterogeneity, for intelligent exercises, as tool for the presentation of students’ work and as basis for games. The material also allows some continuous movements and can thus prepare an insightful usage of dynamic geometry programs. Central Part of the workshop is a work-sharing group work with learning tasks for grades 5 to 8. The workshop will close with a discussion of general aspects of material-based learning. info:eu-repo/classification/ddc/510 ddc:510

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