• Refine Query
  • Source
  • Publication year
  • to
  • Language
  • 88
  • 22
  • 21
  • 7
  • 2
  • 1
  • 1
  • 1
  • 1
  • 1
  • Tagged with
  • 167
  • 36
  • 34
  • 30
  • 28
  • 25
  • 24
  • 20
  • 20
  • 18
  • 18
  • 18
  • 17
  • 17
  • 16
  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
121

GeraÃÃo de Facetas para Politopos de Conjuntos Independentes / Facet-generating Procedures for Stable Set Polytopes

Alinson Santos Xavier 26 September 2011 (has links)
Conselho Nacional de Desenvolvimento CientÃfico e TecnolÃgico / Um conjunto independente de um grafo à um subconjunto de vÃrtices que nÃo contÃm nenhum par de vÃrtices vizinhos. O problema do maior conjunto independente consiste em encontrar um conjunto independente de cardinalidade mÃxima. O problema do maior subgrafo induzido k-partido consiste em encontrar k conjuntos independentes cuja uniÃo tenha cardinalidade mÃxima. AlÃm de possuÃrem aplicaÃÃo em diversas Ãreas, como visÃo computacional, biologia molecular e projeto de circuitos integrados, estes problemas tambÃm modelam outros problemas de otimizaÃÃo combinatÃria, como empacotamento de conjuntos e coloraÃÃo de vÃrtices. Neste trabalho, estudamos os politopos associados aos dois problemas. Primeiro, descrevemos um novo procedimento de geraÃÃo de facetas para o politopo de conjuntos independentes, que unifica e generaliza diversos procedimentos anteriores. AlÃm de gerar vÃrias classes de desigualdades indutoras de facetas jà conhecidas, este procedimento tambÃm gera novas desigualdades que ainda nÃo foram descritas na literatura. Em seguida, estudamos o politopo do subgrafo induzido k-partido associado à formulaÃÃo por representantes de cor. Identificamos suas facetas mais simples, mostramos que facetas podem ser geradas a partir de subgrafos induzidos, e descrevemos duas classes de subgrafos que geram facetas deste politopo. Para obter os principais resultados desta dissertaÃÃo, fazemos um estudo da relaÃÃo de afim-isomorfismo entre poliedros, e desenvolvemos um novo procedimento de conversÃo de faces em facetas que generaliza as diversas versÃes do procedimento de levantamento de variÃveis. / A stable set of a graph is a set of pairwise non-adjacent vertices. The maximum stable set problem is to find a stable set of maximum cardinality in a given graph. The maximum induced k-partite subgraph problem is to find k stable sets such that their union has maximum cardinality. Besides having applications in various fields, including computer vision, molecular biology and VLSI circuit design, these problems also model other important combinatorial problems, such as set packing and vertex coloring. In the present work, we study the facial structure of the polytopes associated with both problems. First, we describe a new facet generating procedure for the stable set polytope, which unifies and subsumes several previous procedures. Besides generating many well-known facet inducing inequalities, this procedure can also generate new facet-inducing inequalities which have not been previously described. Then, we study the maximum induced k-partite polytope formulated by asymmetric representatives. We describe its simplest facets, show that some of its facets arise from vertex induced subgraphs, and identify two classes of subgraphs which generate facets of the polytope. To reach these main results, we study the affine equivalence between polyhedra, and also develop a new facet generating procedure for general polyhedra which subsumes the many versions of the lifting of variables.
122

An integer programming approach to layer planning in communication networks / Une approche de programmation entière pour le problème de planification de couches dans les réseaux de communication

Ozsoy, Feyzullah Aykut 12 May 2011 (has links)
In this thesis, we introduce the Partitioning-Hub Location-Routing problem (PHLRP), which can be classified as a variant of the hub location problem.<p>PHLRP consists of partitioning a network into sub-networks, locating at least one hub in each subnetwork and routing the traffic within the network such that all inter-subnetwork traffic is routed through the hubs and all intra-subnetwork traffic stays within the sub-networks all the way from the source to the destination. Obviously, besides the hub location component, PHLRP also involves a graph partitioning component and a routing component. PHLRP finds applications in the strategic planning or deployment of the Intermediate System-Intermediate System (ISIS) Internet Protocol networks and the Less-than-truck load freight distribution systems.<p><p>First, we introduce three IP formulations for solving PHLRP. The hub location component and the graph partitioning components of PHLRP are<p>modeled in the same way in all three formulations. More precisely, the hub location component is represented by the p-median variables and constraints; and the graph partitioning component is represented by the size-constrained graph partitioning variables and constraints. The formulations differ from each other in the way the peculiar routing requirements of PHLRP are modeled.<p><p>We then carry out analytical and empirical comparisons of the three IP<p>formulations. Our thorough analysis reveals that one of the formulations is<p>provably the tightest of the three formulations. We also show analytically that the LP relaxations of the other two formulations do not dominate each other. On the other hand, our empirical comparison in a standard branch-and-cut framework that is provided by CPLEX shows that not the tightest but the most compact of the three formulations yield the best performance in terms of solution time. <p><p>From this point on, based on the insight gained from detailed analysis of the formulations, we focus our attention on a common sub-problem of the three formulations: the so-called size-constrained graph partitioning problem. We carry out a detailed polyhedral analysis of this problem. The main benefit from this polyhedral analysis is that the facets we identify for the size-constrained graph partitioning problem constitute strong valid inequalities for PHLRP.<p><p>And finally, we wrap up our efforts for solving PHLRP. Namely, we present<p>the results of our computational experiments, in which we employ some facets<p>of the size-constrained graph partitioning polytope in a branch-and-cut algorithm for solving PHLRP. Our experiments show that our approach brings<p>significant improvements to the solution time of PHLRP when compared with<p>the default branch-and-cut solver of XPress. <p><p>/<p><p>Dans cette thèse, nous introduisons le problème Partitionnement-Location des Hubs et Acheminement (PLHA), une variante du problème de location de hubs. Le problème PLHA partitionne un réseau afin d'obtenir des sous-réseaux, localise au moins un hub dans chaque sous-réseau et achemine le traffic dans le réseau de la maniére suivante :le traffic entre deux<p>sous-réseaux distincts doit être éxpedié au travers des hubs tandis que le traffic entre deux noeuds d'un même sous-réseau ne doit pas sortir de celui-ci. PLHA possède des applications dans le planning stratégique, ou déploiement, d'un certain protocole de communication utilisé<p>dans l'Internet, Intermediate System - Intermediate System, ainsi que dans la distribution des frets.<p><p>Premièrement, nous préesentons trois formulations linéaires en variables entières pour résoudre PLHA. Le partitionnement du graphe et la localisation des hubs sont modélisées de la même maniére dans les trois formulations. Ces formulations diffèrent les unes des autres dans la maniére dont l'acheminement du traffic est traité.<p><p>Deuxièmement, nous présentons des comparaisons analytiques et empiriques des trois formulations. Notre comparaison analytique démontre que l'une des formulations est plus forte que les autres. Néanmoins, la comparaison empirique des formulations, via le solveur CPLEX, montre que la formulation la plus compacte (mais pas la plus forte) obtient les meilleures performances en termes de temps de résolution du problème.<p><p>Ensuite, nous nous concentrons sur un sous-problème, à savoir, le partitionnement des graphes sous contrainte de taille. Nous étudions le polytope des solutions réalisables de ce sous-problème. Les facettes de ce polytope constituent des inégalités valides fortes pour<p>PLHA et peuvent être utilisées dans un algorithme de branch-and-cut pour résoudre PLHA.<p><p>Finalement, nous présentons les résultats d'un algorithme de branch-and-cut que nous avons développé pour résoudre PLHA. Les résultats démontrent que la performance de notre méthode est meilleure que celle de l'algorithme branch-and-cut d'Xpress.<p> / Doctorat en Sciences / info:eu-repo/semantics/nonPublished
123

Cutter-workpiece engagement identification in multi-axis milling

Aras, Eyyup 11 1900 (has links)
This thesis presents cutter swept volume generation, in-process workpiece modeling and Cutter Workpiece Engagement (CWE) algorithms for finding the instantaneous intersections between cutter and workpiece in milling. One of the steps in simulating machining operations is the accurate extraction of the intersection geometry between cutter and workpiece. This geometry is a key input to force calculations and feed rate scheduling in milling. Given that industrial machined components can have highly complex geometries, extracting intersections accurately and efficiently is challenging. Three main steps are needed to obtain the intersection geometry between cutter and workpiece. These are the Swept volume generation, in-process workpiece modeling and CWE extraction respectively. In this thesis an analytical methodology for determining the shapes of the cutter swept envelopes is developed. In this methodology, cutter surfaces performing 5-axis tool motions are decomposed into a set of characteristic circles. For obtaining these circles a concept of two-parameter-family of spheres is introduced. Considering relationships among the circles the swept envelopes are defined analytically. The implementation of methodology is simple, especially when the cutter geometries are represented by pipe surfaces. During the machining simulation the workpiece update is required to keep track of the material removal process. Several choices for workpiece updates exist. These are the solid, facetted and vector model based methodologies. For updating the workpiece surfaces represented by the solid or faceted models third party software can be used. In this thesis multi-axis milling update methodologies are developed for workpieces defined by discrete vectors with different orientations. For simplifying the intersection calculations between discrete vectors and the tool envelope the properties of canal surfaces are utilized. A typical NC cutter has different surfaces with varying geometries and during the material removal process restricted regions of these surfaces are eligible to contact the in-process workpiece. In this thesis these regions are analyzed with respect to different tool motions. Later using the results from these analyses the solid, polyhedral and vector based CWE methodologies are developed for a range of different types of cutters and multi-axis tool motions. The workpiece surfaces cover a wide range of surface geometries including sculptured surfaces. / Applied Science, Faculty of / Mechanical Engineering, Department of / Graduate
124

Efficient search-based strategies for polyhedral compilation : algorithms and experience in a production compiler / Stratégies exploratoires efficaces pour la compilation polyédrique : algorithmes et expérience dans un compilateur de production

Trifunovic, Konrad 04 July 2011 (has links)
Une pression accrue s'exerce sur les compilateurs pour mettre en œuvre des transformations de programmes de plus en plus complexes délivrant le potentiel de performance des processeurs multicœurs et des accélérateurs hétérogènes. L'espace de recherche des optimisations de programmes possibles est gigantesque est manque de structure. La recherche de la meilleure transformation, qui inclut la prédiction des gains estimés de performance offerts par cette transformation, constitue le problème le plus difficiles pour les compilateurs optimisants modernes. Nous avons choisi de nous concentrer sur les transformations de boucles et sur leur automatisation, exprimées dans le modèle polyédrique. Les méthodes d'optimisation de programmes dans le modèle polyédrique se répartissent grossièrement en deux classes. La première repose sur l'optimisation linéaire d'une fonction de analytique de coût. La deuxième classe de méthodes met en œuvre une recherche itérative. La première approche est rapide, mais elle est facilement mise en défaut en ce qui concerne la découverte de la solution optimale. L'approche itérative est plus précise, mais le temps de compilation peut devenir prohibitif. Cette thèse contribue une approche nouvelle de la recherche itérative de transformations de programmes dans le modèle polyédrique. La nouvelle méthode proposée possède la précision et la capacité effective à extraire des transformations profitables des méthodes itératives, tout en en minimisant les faiblesses. Notre approche repose sur l'évaluation systématique d'une fonction de coût et de prédiction de performances non-linéaire. Par ailleurs, la parallélisation automatique dans le modèle polyédrique est actuellement dominée par des outils de compilation source-à-source. Nous avons choisi au contraire d'implémenter nos techniques dans la plateforme GCC, en opérant sur une représentation de code de bas niveau, à trois adresses. Nous montrons que le niveau d'abstraction de la représentation intermédiaire choisie engendre des difficultés de passage à l'échelle, et nous montrons comment les surmonter. À l'inverse, nous montrons qu'une représentation intermédiaire de bas niveau ouvre de nouveaux degrés de liberté, bénéficiant à notre stratégie itérative de recherche de transformations, et à la compilation polyédrique de manière générale. / In order to take the performance advantages of the current multicore and heterogeneous architectures the compilers are required to perform more and more complex program transformations. The search space of the possible program optimizations is huge and unstructured. Selecting the best transformation and predicting the potential performance benefits of that transformation is the major problem in today's optimizing compilers. The promising approach to handling the program optimizations is to focus on the automatic loop optimizations expressed in the polyhedral model. The current approaches for optimizing programs in the polyhedral model broadly fall into two classes. The first class of the methods is based on the linear optimization of the analytical cost function. The second class is based on the exhaustive iterative search. While the first approach is fast, it can easily miss the optimal solution. The iterative approach is more precise, but its running time might be prohibitively expensive. In this thesis we present a novel search-based approach to program transformations in the polyhedral model. The new method combines the benefits - effectiveness and precision - of the current approaches, while it tries to minimize their drawbacks. Our approach is based on enumerating the evaluations of the precise, nonlinear performance predicting cost-function. The current practice is to use the polyhedral model in the context of source-to-source compilers. We have implemented our techniques in a GCC framework that is based on the low level three address code representation. We show that the chosen level of abstraction for the intermediate representation poses scalability challenges, and we show the ways to overcome those problems. On the other hand, it is shown that the low level IR abstraction opens new degrees of freedom that are beneficial for the search-based transformation strategies and for the polyhedral compilation in general.
125

Recoloração convexa de grafos: algoritmos e poliedros / Convex recoloring of graphs: algorithms and polyhedra

Phablo Fernando Soares Moura 07 August 2013 (has links)
Neste trabalho, estudamos o problema a recoloração convexa de grafos, denotado por RC. Dizemos que uma coloração dos vértices de um grafo G é convexa se, para cada cor tribuída d, os vértices de G com a cor d induzem um subgrafo conexo. No problema RC, é dado um grafo G e uma coloração de seus vértices, e o objetivo é recolorir o menor número possível de vértices de G tal que a coloração resultante seja convexa. A motivação para o estudo deste problema surgiu em contexto de árvores filogenéticas. Sabe-se que este problema é NP-difícil mesmo quando G é um caminho. Mostramos que o problema RC parametrizado pelo número de mudanças de cor é W[2]-difícil mesmo se a coloração inicial usa apenas duas cores. Além disso, provamos alguns resultados sobre a inaproximabilidade deste problema. Apresentamos uma formulação inteira para a versão com pesos do problema RC em grafos arbitrários, e então a especializamos para o caso de árvores. Estudamos a estrutura facial do politopo definido como a envoltória convexa dos pontos inteiros que satisfazem as restrições da formulação proposta, apresentamos várias classes de desigualdades que definem facetas e descrevemos os correspondentes algoritmos de separação. Implementamos um algoritmo branch-and-cut para o problema RC em árvores e mostramos os resultados computacionais obtidos com uma grande quantidade de instâncias que representam árvores filogenéticas reais. Os experimentos mostram que essa abordagem pode ser usada para resolver instâncias da ordem de 1500 vértices em 40 minutos, um desempenho muito superior ao alcançado por outros algoritmos propostos na literatura. / In this work we study the convex recoloring problem of graphs, denoted by CR. We say that a vertex coloring of a graph G is convex if, for each assigned color d, the vertices of G with color d induce a connected subgraph. In the CR problem, given a graph G and a coloring of its vertices, we want to find a recoloring that is convex and minimizes the number of recolored vertices. The motivation for investigating this problem has its roots in the study of phylogenetic trees. It is known that this problem is NP-hard even when G is a path. We show that the problem CR parameterized by the number of color changes is W[2]-hard even if the initial coloring uses only two colors. Moreover, we prove some inapproximation results for this problem. We also show an integer programming formulation for the weighted version of this problem on arbitrary graphs, and then specialize it for trees. We study the facial structure of the polytope defined as the convex hull of the integer points satisfying the restrictions of the proposed ILP formulation, present several classes of facet-defining inequalities and the corresponding separation algorithms. We also present a branch-and-cut algorithm that we have implemented for the special case of trees, and show the computational results obtained with a large number of instances. We considered instances which are real phylogenetic trees. The experiments show that this approach can be used to solve instances up to 1500 vertices in 40 minutes, comparing favorably to other approaches that have been proposed in the literature.
126

Polyedrisierung dreidimensionaler digitaler Objekte mit Mitteln der konvexen Hülle

Schulz, Henrik 21 July 2008 (has links)
Für die Visualisierung dreidimensionaler digitaler Objekte ist im Allgemeinen nur ihre Oberfläche von Interesse. Da von den bildgebenden Verfahren das gesamte räumliche Objekt in Form einer Volumenstruktur digitalisiert wird, muss aus den Daten die Oberfläche berechnet werden. In dieser Arbeit wird ein Algorithmus vorgestellt, der die Oberfläche dreidimensionaler digitaler Objekte, die als Menge von Voxeln gegeben sind, approximiert und dabei Polyeder erzeugt, die die Eigenschaft besitzen, die Voxel des Objektes von den Voxeln des Hintergrundes zu trennen. Weiterhin werden nicht-konvexe Objekte klassifiziert und es wird untersucht, für welche Klassen von Objekten die erzeugten Polyeder die minimale Flächenanzahl und den minimalen Oberflächeninhalt besitzen.
127

Automatic code generation and optimization of multi-dimensional stencil computations on distributed-memory architectures / Génération automatique de code et optimisation de calculs stencils sur des architectures à mémoire distribuée

Saied, Mariem 25 September 2018 (has links)
Nous proposons Dido, un langage dédié (DSL) implicitement parallèle qui capture les spécifications de haut niveau des stencils et génère automatiquement du code parallèle de haute performance pour les architectures à mémoire distribuée. Le code généré utilise ORWL en tant que interface de communication et runtime. Nous montrons que Dido réalise un grand progrès en termes de productivité sans sacrifier les performances. Dido prend en charge une large gamme de calculs stencils ainsi que des applications réelles à base de stencils. Nous montrons que le code généré par Dido est bien structuré et se prête à de différentes optimisations possibles. Nous combinons également la technique de génération de code de Dido avec Pluto l'optimiseur polyédrique de boucles pour améliorer la localité des données. Nous présentons des expériences qui prouvent l'efficacité et la scalabilité du code généré qui atteint de meilleures performances que les implémentations ORWL et MPI écrites à la main. / In this work, we present Dido, an implicitly parallel domain-specific language (DSL) that captures high-level stencil abstractions and automatically generates high-performance parallel stencil code for distributed-memory architectures. The generated code uses ORWL as a communication and synchronization backend. We show that Dido achieves a huge progress in terms of programmer productivity without sacrificing the performance. Dido supports a wide range of stencil computations and real-world stencil-based applications. We show that the well-structured code generated by Dido lends itself to different possible optimizations and study the performance of two of them. We also combine Dido's code generation technique with the polyhedral loop optimizer Pluto to increase data locality and improve intra-node data reuse. We present experiments that prove the efficiency and scalability of the generated code that outperforms both ORWL and MPI hand-crafted implementations.
128

K-Separator problem / Problème de k-Séparateur

Mohamed Sidi, Mohamed Ahmed 04 December 2014 (has links)
Considérons un graphe G = (V,E,w) non orienté dont les sommets sont pondérés et un entier k. Le problème à étudier consiste à la construction des algorithmes afin de déterminer le nombre minimum de nœuds qu’il faut enlever au graphe G pour que toutes les composantes connexes restantes contiennent chacune au plus k-sommets. Ce problème nous l’appelons problème de k-Séparateur et on désigne par k-séparateur le sous-ensemble recherché. Il est une généralisation du Vertex Cover qui correspond au cas k = 1 (nombre minimum de sommets intersectant toutes les arêtes du graphe) / Let G be a vertex-weighted undirected graph. We aim to compute a minimum weight subset of vertices whose removal leads to a graph where the size of each connected component is less than or equal to a given positive number k. If k = 1 we get the classical vertex cover problem. Many formulations are proposed for the problem. The linear relaxations of these formulations are theoretically compared. A polyhedral study is proposed (valid inequalities, facets, separation algorithms). It is shown that the problem can be solved in polynomial time for many special cases including the path, the cycle and the tree cases and also for graphs not containing some special induced sub-graphs. Some (k + 1)-approximation algorithms are also exhibited. Most of the algorithms are implemented and compared. The k-separator problem has many applications. If vertex weights are equal to 1, the size of a minimum k-separator can be used to evaluate the robustness of a graph or a network. Another application consists in partitioning a graph/network into different sub-graphs with respect to different criteria. For example, in the context of social networks, many approaches are proposed to detect communities. By solving a minimum k-separator problem, we get different connected components that may represent communities. The k-separator vertices represent persons making connections between communities. The k-separator problem can then be seen as a special partitioning/clustering graph problem
129

Relaxations in mixed-integer quadratically constrained programming and robust programming / Relaxations en programmation mixte en nombres entiers avec contraintes quadratiques et en programmation robuste

Wang, Guanglei 28 November 2016 (has links)
De nombreux problèmes de la vie réelle sont exprimés sous la forme de décisions à prendre à l’aide de l’information accessible dans le but d’atteindre certains objectifs. La programmation numérique a prouvé être un outil efficace pour modéliser et résoudre une grande variété de problèmes de ce type. Cependant, de nombreux problèmes en apparence faciles sont encore durs à résoudre. Et même des problèmes faciles de programmation linéaire deviennent durs avec l’incertitude de l’information disponible. Motivés par un problème de télécommunication où l’on doit associer des machines virtuelles à des serveurs tout en minimisant les coûts, nous avons employé plusieurs outils de programmation mathématique dans le but de résoudre efficacement le problème, et développé de nouveaux outils pour des problèmes plus généraux. Dans l’ensemble, résumons les principaux résultats de cette thèse comme suit. Une formulation exacte et plusieurs reformulations pour le problème d’affectation de machines virtuelles dans le cloud sont données. Nous utilisons plusieurs inégalités valides pour renforcer la formulation exacte, accélérant ainsi l’algorithme de résolution de manière significative. Nous donnons en outre un résultat géométrique sur la qualité de la borne lagrangienne montrant qu’elle est généralement beaucoup plus forte que la borne de la relaxation continue. Une hiérarchie de relaxation est également proposée en considérant une séquence de couverture de l’ensemble de la demande. Ensuite, nous introduisons une nouvelle formulation induite par les symétries du problème. Cette formulation permet de réduire considérablement le nombre de termes bilinéaires dans le modèle, et comme prévu, semble plus efficace que les modèles précédents. Deux approches sont développées pour la construction d’enveloppes convexes et concaves pour l’optimisation bilinéaire sur un hypercube. Nous établissons plusieurs connexions théoriques entre différentes techniques et nous discutons d’autres extensions possibles. Nous montrons que deux variantes de formulations pour approcher l’enveloppe convexe des fonctions bilinéaires sont équivalentes. Nous introduisons un nouveau paradigme sur les problèmes linéaires généraux avec des paramètres incertains. Nous proposons une hiérarchie convergente de problèmes d’optimisation robuste – approche robuste multipolaire, qui généralise les notions de robustesse statique, de robustesse d’affinement ajustable, et de robustesse entièrement ajustable. En outre, nous montrons que l’approche multipolaire peut générer une séquence de bornes supérieures et une séquence de bornes inférieures en même temps et les deux séquences convergent vers la valeur robuste des FARC sous certaines hypothèses modérées / Many real life problems are characterized by making decisions with current information to achieve certain objectives. Mathematical programming has been developed as a successful tool to model and solve a wide range of such problems. However, many seemingly easy problems remain challenging. And some easy problems such as linear programs can be difficult in the face of uncertainty. Motivated by a telecommunication problem where assignment decisions have to be made such that the cloud virtual machines are assigned to servers in a minimum-cost way, we employ several mathematical programming tools to solve the problem efficiently and develop new tools for general theoretical problems. In brief, our work can be summarized as follows. We provide an exact formulation and several reformulations on the cloud virtual machine assignment problem. Then several valid inequalities are used to strengthen the exact formulation, thereby accelerating the solution procedure significantly. In addition, an effective Lagrangian decomposition is proposed. We show that, the bounds providedby the proposed Lagrangian decomposition is strong, both theoretically and numerically. Finally, a symmetry-induced model is proposed which may reduce a large number of bilinear terms in some special cases. Motivated by the virtual machine assignment problem, we also investigate a couple of general methods on the approximation of convex and concave envelopes for bilinear optimization over a hypercube. We establish several theoretical connections between different techniques and prove the equivalence of two seeming different relaxed formulations. An interesting research direction is also discussed. To address issues of uncertainty, a novel paradigm on general linear problems with uncertain parameters are proposed. This paradigm, termed as multipolar robust optimization, generalizes notions of static robustness, affinely adjustable robustness, fully adjustable robustness and fills the gaps in-between. As consequences of this new paradigms, several known results are implied. Further, we prove that the multipolar approach can generate a sequence of upper bounds and a sequence of lower bounds at the same time and both sequences converge to the robust value of fully adjustable robust counterpart under some mild assumptions
130

Nanostructuration of epoxy networks by using polyhedral oligomeric silsesquioxanes POSS and its copolymers / Nanostructuration de réseaux époxy des à l'aide de polyédriques oligomères POSS silsesquioxanes et ses copolymères

Chen, Jiangfeng 08 June 2012 (has links)
Une série de composant hybride basée sur réactives polyédriques oligomères silsesquioxane (POSS) precusors et ses copolymères réactifs de PGMA ont été synthétisés et utilisés pour nanobuild en époxy. POSS réactifs et de copolymères en dispersion dans la matrice homogène dans, au délà de POSS-POSS interaction, ce qui a entraîné la séparation de phase macroscopique. Les nanocomposites obtenus ont été analysés par microscopie électronique à balayage, microscopie électronique à transmission, diffusion des rayons X et l'analyse mécanique dynamique. Un analogue de POSS (notée POSSMOCA) a été synthétisé par réaction d'addition, qui a réactive liaison groupe amino dans le réseau époxy et d'améliorer la stabilité thermique, en raison du silicium, d'azote et un atome d'halogène structurel. Époxy / polyédriques silsesquioxanes oligomères (POSS) composites hybrides ont été préparés à partir de pré-réaction entre l'éther de silanol POSS-OH et diglycidylique trifonctionnel de bisphénol A (DGEBA) par l'intermédiaire du silanol et un groupe oxiranne. Réactif POSS-PGMA a été polymérisé par polymérisation par transfert de réversible par addition-fragmentation. Il est facile à queue de la compatibilité du copolymère séquencé époxyde avec une matrice de l'étape de croissance-polymérisé, pour former par réaction avec nanostructure segements PGMA. Dans le cas d'inertes POSS-PMMA copolymères modifiés époxy, topologie de copolymère défini la morphologie finale et l'interaction entre époxy et entre eux, en raison de la liaison hydrogène directionnelle à effet de dilution. Tg de conversion époxyde différente, obéi de Gordon-Taylor équation et l'équation Kwei, k qui reflète l'interaction de modificateur et les oligomères DGEBA / MEDA et époxy / amine, était cohérente de la rhéologie et les résultats dynamiques. / A series of hybrid component based on reactive polyhedral oligomeric silsesquioxane(POSS) precusors and its reactive copolymers of PGMA were synthesized and utilized to nanobuild in epoxy. Reactive POSS and copolymer dispersed in homogenous in matrix, overcomed POSS-POSS interaction, which resulted in macroscale phase separation. The nanocomposites obtained were analyzed by Scanning electron microscopy, Transmission electron microscopy, X-ray scattering and dynamic mechanical. An analogue of POSS (denoted as POSSMOCA) was synthesized via addition reaction, which had reactive amino group bonding into epoxy network and improved the thermostability, because of the structural silicon, nitrogen and halogen. Epoxy/polyhedral oligomeric silsesquioxanes (POSS) hybrid composites were prepared from prereaction between trifunctional silanol POSS-OH and diglycidyl ether of bisphenol A (DGEBA) via silanol and the oxirane group. Reactive POSS-PGMA was polymerized via Reversible addition-fragmentation transfer polymerization. It was easy to tail the compatibility of the epoxide block copolymer with a step-growth polymerized matrix, to form nanostructure via reaction with PGMA segements. In the case of inert POSS-PMMA copolymers modified epoxy, topology of copolymer defined the final morphology and interaction between epoxy and them, because of directional hydrogen bonding and dilution effect. Tg of different epoxide conversion, obeyed of Gordon-Taylor equation and Kwei equation, k which reflected the interaction of modifier and DGEBA/MEDA and epoxy/amine oligomers, was consistent of the rheology and dynamic results.

Page generated in 0.0538 seconds