Au cours de cette thèse, nous étudions la compétition entre les états onde de densité de charge (ODC) et supraconducteur dans le composé multi-bandes à deux chaines TTF[Ni(dmit)2]2. Nous avons réalisé des mesures de résistivité, de pouvoir thermoélectrique et de conductivité thermique sous pression hydrostatique jusqu'aux basses températures. A basse pression, deux ondes de densité de charge détectées par mesures de rayons X et observées par nos mesures de résistivité transverse sont associées aux bandes 1D LUMO et HOMOI de la chaine Ni(dmit)2. A 12kbar, la fusion de ces deux instabilités est associée à l'emboîtement des bandes LUMO avec les bandes HOMOI à travers le point Γ de la première zone de Brillouin. A 18kbar et sur un intervalle de 5-6kbar, on observe un pic de commensurabilité attribué au vecteur d'emboîtement commensurable 2kF = 1/3b*.La supraconductivité est observée à partir de 2kbar et jusqu'à 22kbar avec une température critique 0.6K qui augmente avec la pression et est corrélée à la variation des températures de transition ODC. La supraconductivité est associée à la bande 2D HOMOII du Ni(dmit)2. Les mesures de champ magnétique critique ont permis de donner des informations sur l'évolution de la texture de coexistence métal- ODC en fonction de la pression. Elles mettent aussi en évidence une supraconductivité non conventionnelle avec des nœuds dans le gap.Ces résultats nous ont permis de revisiter le diagramme de phase Température-Pression de ce composé qui s'est révélé beaucoup plus riche que ce qui avait été rapporté jusqu'à maintenant.

Approximation theory is a fundamental tool in order to study the representation theory of a ring R. Roughly speaking, it consists in determining suitable additive or abelian subcategories of the whole module category Mod-R with nice enough functorial properties. For example, torsion theory is a well suited incarnation of approximation theory. Of course, such an idea has been generalised to the additive setting itself, so that both Mod-R and other interesting categories related with R may be linked functorially. By the seminal work of Beilinson, Bernstein and Deligne (1982), the derived category of the ring turns out to admit useful torsion theories, called t-structures: they are pairs of full subcategories of D(R) whose intersection, called the heart, is always an abelian category. The so-called standard t-structure of D(R) has as its heart the module category Mod-R itself. Since then a lot of results devoted to the module theoretic characterisation of the hearts have been achieved, providing evidence of the usefulness of the t-structures in the representation theory of R. In 2020, following a research line promoted by many other authors, Saorin and Stovicek proved that the heart of any compactly generated t-structure is always a locally finitely presented Grothendieck categories (actually, this is true for any t-structure in a triangulated category with coproducts). Essentially, this means that the hearts of D(R) come equipped with a finiteness condition miming that one valid in Mod-R. In the present thesis we tackle the problem of characterising when the hearts of certain compactly generated t-structures of a commutative ring are even locally coherent. In this commutative context, after the works of Neeman and Alonso, Jeremias and Saorin, compactly generated t-structures turned out to be very interesting over a noetherian ring, for they are in bijection with the Thomason filtrations of the prime spectrum. In other words, they are classified by geometric objects, moreover their constituent subcategories have a precise cohomological description. However, if the ascending chain condition lacks, such classification is somehow partial, though provided by Hrbek. The crucial point is that the constituents of the t-structures have a different description w.r.t. that available in the noetherian setting, yet if one copies the latter for an arbitrary ring still obtains a t-structure, but it is not clear whether it must be compactly generated. Consequently, pursuing the study of the local coherence of the hearts given by a Thomason filtration, we ended by considering two t-structures. Our technique in order to face the lack of the ascending chain condition relies on a further approximation of the hearts by means of suitable torsion theories. The main results of the thesis are the following: we prove that for the so-called weakly bounded below Thomason filtrations the two t-structures have the same heart (therefore it is always locally finitely presented), and we show that they coincide if and only they are both compactly generated. Moreover, we achieve a complete characterisation of the local coherence for the hearts of the Thomason filtrations of finite length.

Bakgrund: Den tekniska utvecklingen går snabbt framåt och kan innebära en utmaning för många grupper i samhället, framförallt äldre. Sverige har som mål att år 2025 vara bäst på eHälsa och som ett delmål har ett register i form av Nationella Läkemedelslistan tagits fram. Registret ska ge patienter, vård- och apotekspersonalen tillgång till samma information med målet att öka patientsäkerheten och patienters delaktighet i vården. För att komma åt den här information krävs inloggning till eHälsomyndighetens tjänst Läkemedelskollen. Äldre personer har ofta mindre datorvana och väljer i många fall papper framför digitala tjänster. Apotekslistan är den analoga tjänsten som just nu erbjuder receptinformation i pappersform till patienterna. Syfte: Studiens syfte var att beskriva äldre patienters upplevelser av att använda receptinformation i analog form och deras uppfattning om digitala alternativ. Material och metod: En kvalitativ semistrukturerad intervjustudie har genomförts och urval har skett strategiskt och målstyrt för att fånga respondenter med olika nivå av teknikvana och på olika demografiska platser i Sverige. Rekrytering skedde med snöbollsurval och resulterade i 9 respondenter. Resultatet tolkades sedan med hjälp av UTAUT och TTF. Resultat: Den fysiska Apotekslistan fyller en viktig funktion i patientens läkemedelsprocess och skapar trygghet för individen. Många respondenter har svårt att se fördelarna med en digital version och upplever att den fysiska listan är tillförlitlig och uppfyller alla krav och behov som finns. Slutsats: En del av den åldrande befolkningen vill ha tillgång till det fysiska pappret som ett alternativ till digitala tjänster och upplever att den skapar trygghet och förenklar vardagen. För att locka fler äldre att testa Läkemedelskollen kan utbildningar tas fram för att minska äldre personers teknostress. En utveckling av tjänsten skulle kunna öka intresset och tillföra ett mervärde som förenklar livet med läkemedel. / Background: Technical development is advancing rapidly and entails a need for skills development for many groups in society, especially the elderly. Sweden aims to be the best in eHealth by 2025, and as an intermediate goal, a register in the form of the “National Medication List” has been introduced. The register will give patients, care and pharmacy staff access to the same information with the aim of increasing patient safety and patients' participation in care. To access this information, login to the eHealth Authority's service Läkemedelskollen is required. Older people often have less computer skills and, in many cases, choose paper over digital services. Apotekslistan is the analogue service that currently offers prescription information on paper to patients. Purpose: The purpose of the study was to describe elderly patients' experiences of using prescription information in analog form and their attitude to digital alternatives. Material and method: A qualitative semi-structured interview study were conducted and selection has been made strategically and goal-oriented to capture participants with different levels of technical knowledge and in different demographic locations in Sweden. Recruitment took place with a snowball selection and resulted in 9 participants. The result was interpreted using UTAUT and TTF. Result: The physical list Apotekslistan fulfills an important function in the patient's drug process and gives the patient a feeling of security. Many people find it difficult to see the benefits of a digital version and feel that the physical list is reliable and meets all the requirements and needs that exist. Conclusion: Part of the aging population wants access to the physical paper as an alternative to digital services and feels that it creates security and simplifies everyday life. To attract more elderly people to try Läkemedelskollen, training can be developed to reduce older people's technology stress. A development of the service could increase interest and add value that simplifies living with chronic disease.

Intelligent conversational agents (ICAs) are artificial intelligence (AI)-enabled systems that can communicate with humans through text or voice using natural language. The first ICA, “Eliza,” appeared in 1966 to simulate human conversation using pattern matching. Commercial ICAs appeared on the AOL and MSN platforms in 2001 and aided in developing advanced AI and Human-Computer Interaction (HCI). Since then, ICAs have progressively appeared in consumer products and services. Their success depends on the user’s experience and attitude towards these services. This research examines customer attitudes towards ICAs through a theoretical framework of integrated Expectation Confirmation Theory (ECT) and Task Technology Fit Theory (TTF). By exploring user experience via an experiment that engages end-users with ICA’s different functions and tasks, this study examines user perception of ICA’s AI capabilities, such as Conversation Ability, Friendliness, Intelligence, Responsiveness, Task Performance, and Trust. This research investigates how customer satisfaction with ICA capabilities and perceived task technology fit influence their intention to use ICAs. A field survey of 380 Canadian end-users utilizing ICAs on the websites of five large Canadian telecom service providers enabled empirical testing of the model. / Thesis / Doctor of Philosophy (PhD)

We study unconventional superconductivity in two-dimensional systems. Unbiased numerical calculations within two-dimensional Hubbard models have found no evidence for long-range superconducting order. Most of the two-dimensional theories suggest that the superconducting state can be obtained by destabilizing an antiferromagnetic or spin-liquid insulating state. An antiferromagnet is a half-filled system because each site has one electron or hole. However, in anisotropic triangular lattices, numerical calculation finds pairing enhancement at quarter-filling but no long-range superconducting order. Many organic superconductors are dimerized in nature. Such a dimer lattice is effectively half-filled because each dimer has one electron or hole. Some theories suggest that magnetic fluctuation in such a system can give superconductivity. However, at zero temperature, we performed density matrix renormalization group (DMRG) calculations in such a system, and we find no superconducting long-range order. We also find that the antiferromagnetic order is not necessary to get a superconducting state. Failure in explaining superconductivity in two-dimensional systems suggests that only repulsive interactions between electrons are not sufficient, and other interactions are required. The most likely candidate is the electron-phonon interaction. However, existing theories of superconductivity emphasize either electron-electron or electron-phonon interactions, each of which tends to cancel the effect of the other. We present direct evidence from quantum Monte Carlo calculations of cooperative, as opposed to competing, effects of electron-electron and electron-phonon interactions within the frustrated Hubbard Hamiltonian, uniquely at the band-filling of one-quarter. Bond-coupled phonons and the onsite Hubbard U cooperatively reinforce d-wave superconducting pair-pair correlations at this filling while competing with one another at all other densities. Our work further gives new insight into how intertwined charge-order and superconductivity appear in real materials.

This thesis describes investigations into the properties of -phase BEDT-TTF charge transfer salts. Charge transfer salts are mainly studied as they are very useful test beds for fundamental physics due to the tuneability of their proper- ties and ground states. The effects of temperature and pressure on such systems have been studied, as these allow access to a wide range of different states and properties. Transport properties of these systems have been studied to obtain information about the Fermi surface and effective mass, and the effect of deuter- ation and also change of pressure media will be discussed. The interaction of infrared radiation with these systems has also been investigated and simultaneous pressure and temperature measurements will be presented, something not greatly studied due to the large technical challenges. The techniques and approaches for overcoming these are also discussed. Chapter 1 provides an introduction to the organic materials themselves with particular emphasis on the actual compounds studied. Chapter 2 provides the necessary theoretical background for studying organic charge transfer salts using magnetic quantum oscillations and their infrared re- ectivity. Chapter 3 covers the experimental techniques and also discusses some of the challenges encountered and their solutions to aid others working in this area. Chapter 4 describes an investigation into the transport properties of - (ET)2Cu(SCN)2 by studying Shubnikov-de Haas oscillations using both deuter- ated and normal samples and using two different pressure media, and comparing it to work done using a third. Chapter 5 presents an investigation into the pressure dependence of selected phonon modes in -(ET)2Cu(SCN)2 using infrared radiation on a deuterated sam- ple. Chapter 6 presents what is believed to be the first pressure and temperature dependent infrared study of an organic molecular material. In this case the or- ganic molecular material is d8--(ET)2Cu[N(CN)2]Br, but the techniques should be readily transferable to other materials.

La simulation fine de systèmes d'OA a grand champ de type MOAO, MCAO ou LTAO pour l'ELT se heurte a deux problématiques: L'augmentation du nombre de degrés de liberté du système (au carre du diamètre du télescope). Cette augmentation rend les codes de simulation classiques peu (ou pas) utilisables, en particulier en ce qui concerne les processus d'inversion et de calcul matriciel. Il faut donc envisager des approches d'inversion itératives d'un modèle direct y = A * x en s'appuyant sur les théories d'optimisation a base de matrices creuses. La complexite des systèmes, combinant des étoiles naturelles et laser, de grands miroirs déformables couvrant tous le champs et des miroirs dédiés dans les instruments eux memes, des rotations différentielles de pupille et ou de champs. Cette complexité conduit aux développements de procédures nouvelles d'étalonnages, de filtrages et fusion de données, de commandes distribuée ou globale. Ces procédures doivent être simulées finement, comparées et quantifiées en termes de performances, avant d'être implantées dans de futurs systèmes. Pour répondre a ces deux besoins. J'ai développé en, collaboration avec l'ONERA, un code de simulation complet base sur une approche de résolution itérative de systèmes linéaires a grand nombre de paramètres (utilisation de matrices creuses). Sur cette base, j'ai introduit de nouveaux concepts de filtrage et de fusion de données (étoiles laser et étoiles naturelles) pour gérer efficacement les modes de tip/tilt/defoc dans le processus complet de reconstruction tomographique. Ce code permettra aussi, a terme, de développer et tester des lois de commandes complexes (multi-DM et multi-champs) ayant a gérer la combinaison du télescope adaptatif et d'instrument post-focaux comportant eux aussi des miroirs déformables dédiés. La première application de cet outil s'est faite naturellement dans le cadre du projet de spectrographe multi-objets EAGLE, un des instruments phares du futur E-ELT, qui, du point de vue de l'optique adaptative combinera l'ensemble de ces problématiques.

Dans cette thèse, la dynamique de photodissociation de l'azoture de chlore (ClN3) est étudiée dans le domaine temporel par imagerie de vecteur vitesse des photofragments, spécialement du chlore et de N3. Cette imagerie résolue à l'échelle femtoseconde permet d'extraire les temps de dissociation, l'établissement temporel de la balance d'énergie de la réaction ainsi que la conservation des moments. Cette étude a permis de différencier deux domaines d'énergie: l'un menant à la formation d'un fragment N3 linéaire (étude autour de 4.5 eV d'excitation électronique) et le plus intéressant aboutissant à la formation d'un fragment N3 cyclique (autour de 6 eV). Dans une seconde étude, la dynamique de relaxation électronique du tétrathiafulvalène (C6H4S4-TTF) est étudiée autour de 4 eV par spectroscopie de masse résolue en temps ainsi que par spectroscopie de photoélectron. Les seuils d'ionisation dissociative sont extraits d'une détection en coïncidence entre les photoélectrons de seuil et les fragments ionisés réalisée sur rayonnement synchrotron. Les deux dernières expériences sont basées sur la génération d'harmoniques d'ordre élevé dans l'XUV d'une impulsion femtoseconde à 800 nm ou à 400 nm. Dans la première expérience, les harmoniques sont couplées à un imageur de vecteur vitesse en tant que rayonnement secondaire VUV. Par imagerie de photoélectron résolue en temps, nous avons révélé ainsi les dynamiques de relaxation des états de Rydberg initiée par une impulsion femtoseconde XUV à 15.5 eV dans l'argon et à 9.3 eV dans l'acétylène. Dans la seconde expérience, couramment nommée spectroscopie attoseconde, les harmoniques constituent le signal pompe sonde. Deux types de spectroscopie attoseconde ont été réalisés pour étudier la dynamique vibrationnelle de SF6: une expérience en réseau transitoire créé par deux impulsions pompe Raman avec une impulsion sonde intense générant les harmoniques à partir du réseau d'excitation et une expérience d'interférence de deux rayonnement XUV en champ lointain créés par deux impulsions sonde intenses.