Mesoporous alumina (Al2O3) in the gamma (γ) phase is widely used as a support in catalytic applications because of its high surface area, large pore volume, acid-base characteristics, and thermal stability. To improve the thermal stability of gamma alumina, dopants such as lanthanum, magnesium, zirconia, and silica are often introduced. Current laboratory-based methods for synthesizing gamma alumina generally involve 10-15 steps and/or use toxic, expensive surfactants and solvents. Industrial methods, while simpler, lack control of pore properties and surface chemistry. In contrast, we have developed an innovative solvent deficient, one-step method that is able to synthesize a wide range of pure and silica-doped aluminas with high surface areas, pore volumes from 0.3 to 1.8 cm3/g, and pore diameters from 5 to 40 nm. More significantly, our silica-doped aluminas are stable up to temperatures as high as 1300<°>C, which is 200<°>C higher than other pure and doped gamma alumina materials.The usefulness of gamma-alumina as a catalyst support is dependent on its favorable combination of textural, thermal, structural, and chemical properties, yet the relationship between structure and these other properties is still not clearly understood due to the poorly crystallized nature of the material. In particular, the mechanism by which the gamma structure is stabilized thermally by so many dopants is still not well understood. Based on our previous PDF experiments on pure and La-doped alumina, we have developed a hypothesis regarding the mechanism by which dopants increase thermal stability. To validate or refute this hypothesis, we collected PDF data on a wider range of laboratory and industrial alumina samples. Herein, we have utilized PDF analysis to study the local to intermediate-range structure of a series of our pure and silica-doped aluminas calcined at 50<°>C intervals between 50 and 1300<°>C as well as pure and silica-doped aluminas from commercial sources and other synthetic methods. This thorough study of alumina local structure will allow us to separate general trends in the local structure from idiosyncrasies based on synthetic method/conditions, and it will help us identify the structural features responsible for improved thermal stability. Having access to these PDF experiments, we have validated our current hypothesis on the nature of stabilization afforded by dopants and, more generally, developed a better understanding of the role structure plays in the properties of aluminas.

In the present study / ten autosomal human-specific Alu insertion polymorphisms / ACE, APO, A25, B65, D1, FXIIIB, HS4.32, HS4.69, PV92 and TPA25 were analyzed in approximately 100 unrelated individuals from Anatolia. Alu insertion polymorphisms offer several advantages over other nuclear DNA polymorphisms for human evolution studies. The frequencies of the ten biallelic Alu insertions in Anatolians were calculated and all systems were found to be in Hardy-Weinberg equilibrium (p&gt / 0.05). By combining the results of this study with results of previous studies done on worldwide populations, the genetic distance (Nei&rsquo / s DA) between each pair of populations was calculated and neighbor joining trees were constructed. In general, geographically closer populations were found to be also genetically similar. Principal component analysis (PCA) was performed and Anatolia was found to be in the European cluster. As a result of PCA / it was concluded that FXIIIB, PV92 and ACE were the variables contributing the most to the explanation of the variation between the populations. Additionally / canonical variates analysis (CVA) concluded that the most discriminative markers for the groups of populations were PV92, D1, ACE and HS4.32. Pair-wise Fst values were also calculated between Anatolians and some of the populations for which the data was available. It was concluded that, Anatolians have non-significant pair-wise Fst values with Swiss and French Acadian populations. Lastly, heterozygosity vs. distance from centroid graph was constructed and it was found that Anatolians and India-Hindu had exactly the expected heterozygosity value predicted by the model of Harpending and Ward (1982).

This paper deals with knives excavated in the Birka Garrison between 1997 and 2004, in a selection of 100 knives out of approximately 400. The aim is to measure and analyze the material to find out if certain elements in design points to a specific craft. Two groups of knifeblades can be seen, one with a convex bevel and one with a flat bevel of the blade. Considering osteological evidence, historical sources, and the main suitabillity of the knives, it is concluded that some of the flat beveled knives may have been used for crafting leather and fur, whereas the convex beveled knives are of an allround type.

Urbanisation is an ever-growing global phenomenon which creates altered environments characterised by increased human habitation, exotic species, impermeable surfaces, artificial structures, landscape fragmentation, habitat loss, and modified energy– and resource pathways. The vulnerable Rand Highveld Grassland vegetation unit in the Tlokwe Municipal area, South Africa, has been extensively degraded and transformed by urbanisation and agriculture. Only 1% of this endangered ecosystem is currently being actively conserved. Grassland fragments in urban areas are considered to be less species rich and less functional than their more “natural” counterparts, and are therefore not a priority for conservation. In this study the effects of landscape matrix quality on intra patch variables, namely plant species diversity and functional diversity, and fine-scale biogeochemical landscape function (as determined by Landscape Function Analysis or LFA) of 30 fragments of the Rand Highveld Grassland vegetation unit were explored. Four urbanisation measures (percentage urban land cover, percentage grass land cover, edge density, and density of people), acting as indicators for patterns and processes associated with urban areas, were calculated for matrix areas with a 500m radius surrounding each selected grassland fragment to quantify the position of each grassland remnant along an urban-to-rural gradient. Using the specific urbanisation measures, the grassland fragments were objectively classified into two classes of urbanisation, namely “rural/peri-urban” and “urban”, to allow for statistical comparisons between intra-patch variables for grassland remnants exposed to similar urbanisation pressures. Plant species composition and diversity were determined in the selected grassland fragments and nine functional traits were described for each species. Plant functional diversity was determined by five functional diversity indices, namely functional richness, evenness, divergence, dispersion, and specialisation. Fine-scale biogeochemical landscape function was determined by executing the LFA method. LFA assesses fine-scale landscape patchiness and 11 soil surface indicators to produce three main LFA parameters (stability, infiltration, and nutrient cycling), which indicates how well a system is functioning in terms of resource conservation and soil processes. Possible relationships between fine-scale biogeochemical landscape function and plant species- and functional diversity were also investigated. NMDS ordinations and basic statistics were used to determine trends and effects within the data. The results indicated that urban grassland remnants had lower mean plant species richness, Shannon species diversity (significantly), and Pielou species evenness than rural/peri-urban grassland fragments. Urban grassland fragments also contained significantly higher percentage of exotic species. Correlations were found between the four urbanisation measures and percentage species of the total species richness possessing certain functional attributes. This indicated that increased urbanisation may influence the species composition and the occurrence of certain plant traits in the selected grassland fragments. Urbanisation seems to have no effect on fine-scale landscape heterogeneity of the selected grassland fragments. Rural/peri-urban grassland fragments had higher infiltration capacity, nutrient cycling potential, and total SSA functionality (although not significantly), which may be ascribed to differences in management practices, such as mowing in urban areas and grazing in rural areas. Rand Highveld Grassland fragments in the urban landscape matrix of Potchefstroom city are just as conservable in terms of plant species diversity and functional diversity, as well as on a biophysical function level involving soil processes than rural/peri-urban grassland fragments. High plant species diversity and the presence of certain plant traits did not contribute to high soil surface stability, infiltration capacity, nutrient cycling potential and total soil surface functioning. / MSc (Environmental Sciences), North-West University, Potchefstroom Campus, 2013

Urbanisation is an ever-growing global phenomenon which creates altered environments characterised by increased human habitation, exotic species, impermeable surfaces, artificial structures, landscape fragmentation, habitat loss, and modified energy– and resource pathways. The vulnerable Rand Highveld Grassland vegetation unit in the Tlokwe Municipal area, South Africa, has been extensively degraded and transformed by urbanisation and agriculture. Only 1% of this endangered ecosystem is currently being actively conserved. Grassland fragments in urban areas are considered to be less species rich and less functional than their more “natural” counterparts, and are therefore not a priority for conservation. In this study the effects of landscape matrix quality on intra patch variables, namely plant species diversity and functional diversity, and fine-scale biogeochemical landscape function (as determined by Landscape Function Analysis or LFA) of 30 fragments of the Rand Highveld Grassland vegetation unit were explored. Four urbanisation measures (percentage urban land cover, percentage grass land cover, edge density, and density of people), acting as indicators for patterns and processes associated with urban areas, were calculated for matrix areas with a 500m radius surrounding each selected grassland fragment to quantify the position of each grassland remnant along an urban-to-rural gradient. Using the specific urbanisation measures, the grassland fragments were objectively classified into two classes of urbanisation, namely “rural/peri-urban” and “urban”, to allow for statistical comparisons between intra-patch variables for grassland remnants exposed to similar urbanisation pressures. Plant species composition and diversity were determined in the selected grassland fragments and nine functional traits were described for each species. Plant functional diversity was determined by five functional diversity indices, namely functional richness, evenness, divergence, dispersion, and specialisation. Fine-scale biogeochemical landscape function was determined by executing the LFA method. LFA assesses fine-scale landscape patchiness and 11 soil surface indicators to produce three main LFA parameters (stability, infiltration, and nutrient cycling), which indicates how well a system is functioning in terms of resource conservation and soil processes. Possible relationships between fine-scale biogeochemical landscape function and plant species- and functional diversity were also investigated. NMDS ordinations and basic statistics were used to determine trends and effects within the data. The results indicated that urban grassland remnants had lower mean plant species richness, Shannon species diversity (significantly), and Pielou species evenness than rural/peri-urban grassland fragments. Urban grassland fragments also contained significantly higher percentage of exotic species. Correlations were found between the four urbanisation measures and percentage species of the total species richness possessing certain functional attributes. This indicated that increased urbanisation may influence the species composition and the occurrence of certain plant traits in the selected grassland fragments. Urbanisation seems to have no effect on fine-scale landscape heterogeneity of the selected grassland fragments. Rural/peri-urban grassland fragments had higher infiltration capacity, nutrient cycling potential, and total SSA functionality (although not significantly), which may be ascribed to differences in management practices, such as mowing in urban areas and grazing in rural areas. Rand Highveld Grassland fragments in the urban landscape matrix of Potchefstroom city are just as conservable in terms of plant species diversity and functional diversity, as well as on a biophysical function level involving soil processes than rural/peri-urban grassland fragments. High plant species diversity and the presence of certain plant traits did not contribute to high soil surface stability, infiltration capacity, nutrient cycling potential and total soil surface functioning. / MSc (Environmental Sciences), North-West University, Potchefstroom Campus, 2013

The goal of this research was to improve ocean colour chlorophyll a (Chla) retrievals in the coastal Case 2 waters of the Salish Sea by characterizing the main drivers of optical variability and using this information to parameterize empirical algorithms based on an optical classification. This was addressed with three specific objectives: (1) build a comprehensive spatio-temporal data set of in situ optical and biogeochemical parameters, (2) apply a hierarchical clustering analysis to classify above-water remote sensing reflectance (Rrs) and associated bio-optical regimes, (3) optimize and validate class-specific empirical algorithms for improved Chla retrievals. Biogeochemical and optical measurements, acquired at 145 sites, showed considerable variation; Chla (mean=1.64, range: 0.10 – 7.20 µg l-1), total suspended matter (TSM) (3.09, 0.82 – 20.69 mg l-1), and absorption by chromophoric dissolved organic matter (a_cdom (443)) (0.525, 0.007 – 3.072 m-1), thus representing the spatial and temporal variability of the Salish Sea. A comparable range was found in the measured optical properties; particulate scattering (b_p (650)) (1.316, 0.250 – 7.450 m-1), particulate backscattering (b_bp (650)) (0.022, 0.005 – 0.097 m-1), total beam attenuation coefficient (c_t (650)) (1.675, 0.371 – 9.537 m-1), and particulate absorption coefficient (a_p (650)) (0.345, 0.048 – 2.020 m-1). Empirical orthogonal function (EOF) analysis revealed 95% of the Rrs variance was highly correlated to b_p (r = 0.90), b_bp (r = 0.82), and TSM concentration (r = 0.80), suggesting a strong influence from riverine systems in this region. Hierarchical clustering on the normalized Rrs revealed four spectral classes. Class 1 is defined by high overall Rrs magnitudes in the red, indicating more turbid waters, Class 2 showed high Rrs values in the red and well defined fluorescence and absorption features, indicated by a high Chla and TSM presence, Class 3 showed low TSM influence and more defined Chla signatures, and Class 4 is characterized by overall low Rrs values, suggesting more optically clear oceanic waters. Spectral similarities justified a simplification of this classification into two dominant water classes – (1) estuarine class (Classes 1 and 2) and (2) oceanic class (Classes 3 and 4) – representing the dominant influences seen here. In situ Chla and above-water remote sensing reflectance measurements, used to validate and parameterize the OC3M/OC3S3, two-band ratio, FLH and, modified FLH (ModFLH) empirical algorithms, showed a systematic overestimation of low Chla concentrations and underestimation of higher Chla values for all four algorithms when tuned to regional data. FLH and ModFLH algorithms performed best for these data (R2 ~ 0.40; RMSE ~ 0.32). Algorithm accuracy was significantly improved for the class-specific parametrizations with the two-band ratio showing a strong correlation to the Chla concentrations in the estuarine class (R2 ~ 0.71; RMSE ~ 0.33) and the ModFLH algorithm in the oceanic class (R2 ~ 0.70; RMSE ~ 0.26). These results demonstrated the benefit of applying an optical classification as a necessary first step into improving Chla retrievals from remotely sensed data in the contrasted coastal waters of the Salish Sea. With accurate Chla information, the health of the Salish Sea can be viably monitored at spatial and temporal scales suitable for ecosystem management. / Graduate / 0416 / stephen.uvic@gmail.com

We study the space-time characteristics of global tropical rainfall. The data used is from the Tropical Rainfall Measuring Mission (TRMM) and spans the years 2000-2009. Using anomaly fields constructed by removing a single mean and by subtracting the climatology of the ten year dataset, we extract the dominant modes of variability of tropical rainfall from an Empirical Orthogonal Function (EOF) analysis. To our knowledge, this is the first attempt at applying the EOF formal-ism to high spatio-temporal resolution global tropical rainfall. Spatial patterns and temporal indices obtained from the EOF analysis with single annual mean removed show large scale patterns associated with the seasonal cycle. Even though the seasonal cycle is dominant, the principal component (PC) time series show fluctuations at subseasonal scales. When the climatological mean is removed, spatial patterns of the dominant modes resemble features associated with tropical intraseasonal variability (ISV). Correspondingly, the signature of a seasonal cycle is relatively suppressed, and the PCs have prominent fluctuations at subseasonal scales. The significance of the leading EOFs is demonstrated by means of a novel ratio plot of the variance captured by the leading EOFs to the variance in the data. This shows that, in regions of high variability (which go hand in hand with high rainfall), the EOF/PC pairs capture a fair amount of the variance (up to 20% for the first EOF/PC pair) in the data. We then pursue an EOF analysis of the finest data resolution available. In particular, we per-form a regional analysis (a global analysis is beyond our present computational resources) of the tropics with 0.25◦×0.25◦, 3-hourly data. The regions we focus on are the Indian region, the Maritime Continent and South America. The spatial patterns obtained reveal a rich hierarchical structure to the leading modes of variability in these regions. Similarly, the PCs associated with these leading spatial modes show variability all the way from 90 days to the diurnal scale. With the results from EOF analysis in hand, we quantify the multiscale spatio-temporal structures encountered in our study. In particular, we examine the power spectra of the PCs and EOFs. A robust feature of the space and time spectra is the distribution of energy or variance across a range of scales. On the temporal front, aside from a seasonal and diurnal peaks, the variance scales as a power-law from a few days to the 90 day period. Similarly, below the planetary scale, from approximately 5000 km to 200 km the spatial spectrum also follows a power-law. Therefore, when trying to understand the variability of tropical rainfall, all scales are important, and it is difficult to justify a focus on isolated space and time scales.

Denmark has a long tradition of teaching aural skills i.e. ear training and to educate ear training teachers. Books from Danish authors are still extensively being used within the Nordic countries. The function analysis system was introduced the same year in Denmark and Sweden, but Denmark has developed more terminology than its Swedish counterpart. The purpose of this study was to research how music majors are expressing themselves about newly introduced function analysis terminology and how they experience the use for the terminology in their profession as musicians. The study was made through a survey and a semi structured interview with six participants and the data was analysed according to the social cultural theory. The participants expressed themselves mainly positive about the new terminology and said it gave them a more nuanced picture of the harmony. They also found the new terminology useful for their profession as musicians. The results suggest that music majors would be interested in having a more comprehensive system as they use in Denmark and that teachers in aural training should consider incorporating this new terminology in their teaching.

No description available.

Thesis (MSc)--Stellenbosch University, 2011. / ENGLISH ABSTRACT: The Exxaro Namakwa Sands heavy mineral sands mine at Brand-se-Baai, on the west coast of South Africa, is an important source of income, development and job-creation in the region. However, this comes at a great environmental cost, as strip mining causes large scale destruction of ecosystems through the complete removal of vegetation and topsoil. This is particularly problematic in an environment, such as Namaqualand, where the arid and windy climate, as well as saline and nutrient-poor soils, hamper rehabilitation. These environmental constraints create the need to develop a site-specific rehabilitation program. At Namakwa Sands the objective of rehabilitation is to “rehabilitate and re-vegetate disturbed areas and establish a self-sustaining Strandveld vegetation cover in order to control dust generation, control wind and water erosion, as well as restore land capability. In general, vegetation will be rehabilitated to a minimum grazing standard capable of supporting small stock (sheep) grazing.” In order to achieve this Namakwa Sands conducted rehabilitation experiments with topsoil replacement, seeding of indigenous species and translocation of mature plants. Monitoring is an important part of the rehabilitation process as it allows rehabilitation practitioners to evaluate success and to adapt their management strategies and rehabilitation methods, as well as to evaluate and, if necessary, change their rehabilitation objectives. This study forms part of the monitoring process at Namakwa Sands. It assesses the success of sites that were experimentally rehabilitated in 2001 and a site that was rehabilitated in 2008, using current practice, in order to identify possible management requirements on rehabilitated sites as well as improvements on rehabilitation objectives, methods and monitoring. This study also tests the Landscape Function Analysis (LFA) as rehabilitation monitoring tool by correlating LFA indices with traditional measurements of biophysical variables or their surrogates. Results showed that experimental sites were not successful in returning vegetation cover and plant species richness to the required levels, but did achieve the grazing capacity objective. These sites will need adaptive management to achieve the vegetation cover and plant species richness objectives. The recently rehabilitated site achieved the three-year vegetation cover and plant species richness objectives, as well as the grazing capacity objective, within two years after rehabilitation. Namakwa Sands should therefore continue using the current rehabilitation method. However, rehabilitation should be done in multiple stages in future to decrease the mortality of nursery cuttings and to facilitate the return of late successional species to rehabilitated sites. The sustainability of small stock farming on rangeland with the grazing capacity that is identified as the minimum objective is questionable and this merits further investigation. LFA can be a useful tool to monitor nutrient cycling and soil stability at Namakwa Sands, provided that enough replicates are used. However, LFA cannot be used as is to assess water infiltration at Namakwa Sands, due to assumptions in the calculation of this index that do not hold for the Namaqualand environment. Landscape functioning should be monitored annually to complement vegetation surveys. / AFRIKAANSE OPSOMMING: Die Exxaro Namakwa Sands swaarminerale-sandmyn by Brand-se-Baai, aan die weskus van Suid-Afrika, is ‘n belangrike bron van inkomste, ontwikkeling en werkskepping in die streek. Daar is egter negatiewe omgewingsimpakte aan verbonde, aangesien die strookmyntegniek grootskaalse vernietiging van ekosisteme veroorsaak deur die algehele verwydering van die plantegroei en bogrond. Dit is veral problematies in ‘n omgewing, soos Namakwaland, waar die droë en winderige klimaat, asook die souterige en voedingstof-arme grond, rehabilitasie belemmer. Hierdie beperkings wat deur die omgewing veroorsaak word skep die behoefte om ‘n rehabilitasieprogram te ontwikkel wat spesifiek is tot die terrein. Die doel van rehabilitasie by Namakwa Sands is om te rehabiliteer en herplant op versteurde gebiede en om selfonderhoudende Strandveld plantbedekking te vestig om sodoende stofgenerering te beheer, om wind- en watererosie te beheer, en om grondgebruik-vermoë te herstel. In die algemeen sal plantbedekking gerehabiliteer word tot ‘n minimum weidingskapasiteit wat kleinveeweiding (skaapweiding) kan onderhou. Om dit te bereik het Namakwa Sands rehabilitasie-eksperimente uitgevoer met terugplasing van bogrond, saai van inheemse spesies en oorplanting van volwasse inheemse plante. Monitering is ‘n belangrike deel van die rehabilitasieproses, aangesien dit rehabilitasie-praktisyns in staat stel om sukses te evalueer en om bestuurstrategieë en rehabilitasiemetodes aan te pas, sowel as om rehabilitasiedoelwitte te evalueer en, indien nodig, aan te pas. Hierdie studie vorm deel van die moniteringsproses by Namakwa Sands. Dit assesseer die sukses op persele wat eksperimenteel gerehabiliteer is in 2001 en ‘n perseel wat in 2008 gerehabiliteer is, volgens die huidige praktyk, om moontlike bestuursbehoeftes op gerehabiliteerde persele en verbeteringe aan rehabilitasiedoelwitte, -metodes en –monitering te identifiseer. Hierdie studie toets ook die geskiktheid van die Landscape Function Analysis (LFA) as ‘n rehabilitasie-moniteringsinstrument deur LFA-indekse met tradisionele metings van biofisiese veranderlikes of hul surrogate te korreleer. Resultate dui daarop dat eksperimentele persele nie suksesvol was om plantbedekking en plantspesies-rykdom tot die vereiste vlakke te herstel nie, maar wel die weidingskapasiteit-doelwit bereik het. Hierdie persele benodig aanpassingsbestuur om plantbedekking- en plantspesiesrykdom-doelwitte te bereik. Die perseel wat onlangs gerehabiliteer is, het binne twee jaar na rehabilitasie die drie-jaar plantbedekking- en plantspesiesrykdom-doelwitte, sowel as die weidingskapasiteitdoelwit bereik. Daarom moet Namakwa Sands voortgaan om die huidige rehabilitasiemetode te gebruik. Rehabilitasie moet egter in die toekoms in veelvoudige stadiums gedoen word om die mortaliteit van kwekery-steggies te verminder en om die terugkeer van laatsuksessionele spesies na gerehabiliteerde persele te fasiliteer. Die volhoubaarheid van kleinveeboerdery op weiveld met die minimum vereiste weidingskapasiteit word betwyfel en vereis verdere ondersoek. LFA kan ‘n bruikbare instrument wees om siklering van voedingstowwe en grondstabiliteit te monitor by Namakwa Sands indien genoeg repliserings gebruik word. LFA kan egter nie in die huidige vorm gebruik word om waterinfiltrasie by Namakwa Sands te assesseer nie, aangesien daar aannames in die berekening van die indeks is wat nie juis is in die Namakwaland omgewing nie. Landskapfunksionering behoort jaarliks gemoniteer te word om plantopnames aan te vul.