Neste trabalho estudamos dinâmica Hamiltoniana em $\\mathbb{R}^4$ restrita a níveis de energia próximos a níveis críticos. Mais precisamente, consideramos uma função Hamiltoniana $H: \\mathbb{R}^4 \\to \\mathbb{R}$ que possui um ponto de equilíbrio do tipo sela-centro $p_c \\in H^{-1}(0)$ e assumimos que $p_c$ pertence a um conjunto singular estritamente convexo $S_0 \\subset H^{-1}(0)$. Então, mostramos que os níveis de energia $H^{-1}(E)$, com $E>0$ suficientemente pequeno, contêm uma $3$-bola fechada $S_E$ próxima a $S_0$ que admite um sistema de seções transversais $F_E$, chamado folheação $2-3$. $F_E$ é uma folheação singular de $S_E$ com conjunto singular formado por duas órbitas periódicas $P_{2,E}\\subset \\partial S_E$ e $P_{3,E}\\subset S_E\\setminus \\partial S_E$. A órbita $P_{2,E}$ é hiperbólica dentro do nível de energia $H^{-1}(E)$, pertence à variedade central do sela-centro $p_c$, tem índice de Conley-Zehnder $2$ e é o limite assintótico de dois planos rígidos de $F_E$ que, unidos com $P_{2,E}$, constituem a $2$-esfera $\\partial S_E$. A órbita $P_{3,E}$ tem índice de Conley-Zehnder $3$ e é o limite assintótico de uma família a um parâmetro de planos de $F_E$ contida em $S_E\\setminus \\partial S_E$. Um cilindro rígido conectando as órbitas $P_{3,E}$ e $P_{2,E}$ completa a folheação $F_E$. Uma vez que $F_E$ é um sistema de seções transversais, todas as suas folhas regulares são transversais ao fluxo Hamiltoniano de $H$. Como consequência da existência de uma tal folheação em $S_E$, concluímos que a órbita hiperbólica $P_{2,E}$ admite pelo menos uma órbita homoclínica contida em $S_E \\setminus \\partial S_E$. / In this work we study Hamiltonian dynamics in $\\mathbb R ^4$ restricted to energy levels close to critical levels. More precisely, we consider a Hamiltonian function $H:\\mathbb R ^4 \\to \\mathbb R$ containing a saddle-center equilibrium point $p_c \\in H^ -1 (0)$ and we assume that $p_c$ lies on a strictly convex singular set $S_0 \\subset H^ -1 (0)$. Then we prove that the energy levels $H^ -1 (E)$, with $E>0$ sufficiently small, contain a closed $3$-ball $S_E$ near $S_0$ admitting a system of transverse sections $F_E$, called a $2-3$ foliation. $F_E$ is a singular foliation of $S_E$ and its singular set consists of two periodic orbits $P_{2,E}\\subset \\partial S_E$ and $P_{3,E}\\subset S_E\\setminus \\partial S_E$. The orbit $P_{2,E}$ is hyperbolic inside the energy level $H^ -1 (E)$, lies on the center manifold of the saddle-center $p_c$, has Conley-Zehnder index $2$ and is the asymptotic limit of two rigid planes of $F_E$, which compose the $2$-sphere $S_E$ together with $P_{2,E}$. The orbit $P_{3,E}$ has Conley-Zehnder index $3$ and is the asymptotic limit of a one parameter family of planes of $F_E$ contained in $S_E \\setminus \\partial S_E$. A rigid cylinder connecting the orbits $P_{3,E}$ and $P_{2,E}$ completes the foliation $F_E$. Since $F_E$ is a system of transverse sections, all its regular leaves are transverse to the Hamiltonian flow of $H$. As a consequence of the existence of such foliation in $S_E$, we conclude that the hyperbolic orbit $P_{2,E}$ admits at least one homoclinic orbit contained in $S_E\\setminus \\partial S_E$.

Submitted by Franciele Moreira (francielemoreyra@gmail.com) on 2018-03-28T11:58:56Z No. of bitstreams: 2 Dissertação - Jeferson Arley Poveda Contreras - 2018.pdf: 763599 bytes, checksum: 6800571168e0aa9de85d151e4c912725 (MD5) license_rdf: 0 bytes, checksum: d41d8cd98f00b204e9800998ecf8427e (MD5) / Approved for entry into archive by Luciana Ferreira (lucgeral@gmail.com) on 2018-03-29T11:29:24Z (GMT) No. of bitstreams: 2 Dissertação - Jeferson Arley Poveda Contreras - 2018.pdf: 763599 bytes, checksum: 6800571168e0aa9de85d151e4c912725 (MD5) license_rdf: 0 bytes, checksum: d41d8cd98f00b204e9800998ecf8427e (MD5) / Made available in DSpace on 2018-03-29T11:29:24Z (GMT). No. of bitstreams: 2 Dissertação - Jeferson Arley Poveda Contreras - 2018.pdf: 763599 bytes, checksum: 6800571168e0aa9de85d151e4c912725 (MD5) license_rdf: 0 bytes, checksum: d41d8cd98f00b204e9800998ecf8427e (MD5) Previous issue date: 2018-03-07 / Conselho Nacional de Pesquisa e Desenvolvimento Científico e Tecnológico - CNPq / The goal of this work is study limit cycles of piecewise smooth vector fields. First, we present the basic theory, passing through the areas of analysis, qualitative theory of differential equations and algebra. We also present basic concepts of Filippov fields, which are indispensable for the study of piecewise smooth fields. In chapter one, was the main topic, a general method for finding limit cycles will be described; in the second chapter limit cycles are found in a piecewise smooth vector field with non-degenerate center being perturbed by a piecewise polynomial vector field. In the fourth chapter, we study limit cycles in piecewise smooth Hamiltonian fields. / O objetivo deste trabalho é estudar ciclos limite de campos de vetores suaves por parte. Primeiro apresentaremos a teoria básica, passando pelas áreas de análise, teoria qualitativa das equações diferenciais e álgebra. Apresentamos também conceitos básicos de campos de Filippov, os quais são imprescindíveis para o estudo dos campos suaves por partes. No capítulo dos, como tópico principal, será descrito um método geral para encontrar ciclos limite; no segundo três são encontrados ciclos limites em um campo de vetores suave por partes com um centro não degenerado sendo perturbado por um polinômio. No quarto capitulo estudaremos os ciclos limites de campos de vetores Hamiltonianos por parte.

<p>Theoretical investigations of spectroscopic and magnetic properties of metallic systems in the bulk, as well as in nanostructured materials, have been performed within the density functional theory. The major part of the present work studies the differences between binding energies of electrons tightly bound to the atoms, the so-called core electrons (in contrast with the valence electrons), that is, core-level binding energy shift (CLS). </p><p>By comparison between corresponding elemental core-levels for atoms situated in different chemical environments we obtain fundamental understanding of bonding properties of materials. The method of choice was the complete screening picture, which includes initial and final state effects on the same footing. The usefulness of CLS stems from that it is sensitive to differences in the chemical environment of an atom, which can be affected on one hand by the global composition of e.g. disordered materials, surfaces and interfaces, and on the other hand by the very local environment around an atom. Here CLSs have been obtained for both components in the fcc random alloys AgPd, CuPd, CuNi, CuPt, CuAu, PdAu, NiPd and NiPt. Moreover the model was extended to the Auger kinetic energy shift for the LMM Auger transition in AgPd alloys. Studies were also applied to the near surface and interface regions of PdMn nano structures on Pd(100), thin CuPd and AgPd films on inert Ru(0001), and at interfaces. The disorder broadening on CLS due to local environment effects was calculated in selected alloys.</p><p>A part of the thesis concern investigations related to the magnetic ordering in Invar alloys, including the influence of local environment effects. A study was made for the dependence of effective exchange parameter on the electron concentration, volume and local chemical composition.</p>

Theoretical investigations of spectroscopic and magnetic properties of metallic systems in the bulk, as well as in nanostructured materials, have been performed within the density functional theory. The major part of the present work studies the differences between binding energies of electrons tightly bound to the atoms, the so-called core electrons (in contrast with the valence electrons), that is, core-level binding energy shift (CLS). By comparison between corresponding elemental core-levels for atoms situated in different chemical environments we obtain fundamental understanding of bonding properties of materials. The method of choice was the complete screening picture, which includes initial and final state effects on the same footing. The usefulness of CLS stems from that it is sensitive to differences in the chemical environment of an atom, which can be affected on one hand by the global composition of e.g. disordered materials, surfaces and interfaces, and on the other hand by the very local environment around an atom. Here CLSs have been obtained for both components in the fcc random alloys AgPd, CuPd, CuNi, CuPt, CuAu, PdAu, NiPd and NiPt. Moreover the model was extended to the Auger kinetic energy shift for the LMM Auger transition in AgPd alloys. Studies were also applied to the near surface and interface regions of PdMn nano structures on Pd(100), thin CuPd and AgPd films on inert Ru(0001), and at interfaces. The disorder broadening on CLS due to local environment effects was calculated in selected alloys. A part of the thesis concern investigations related to the magnetic ordering in Invar alloys, including the influence of local environment effects. A study was made for the dependence of effective exchange parameter on the electron concentration, volume and local chemical composition.

Μελετάµε χωρικά εντοπισµένες και χρονικά περιοδικές λύσεις σε διακριτά συστήµατα που εκτείνονται σε µία χωρική διάσταση. Αυτού του είδους οι λύσεις είναι γνωστές µε τον όρο discrete breathers (DB) ή intrinsic localized modes (ILM). Στην ελληνική ϐιϐλιογραϕία, έχουν ονοµαστεί ∆ιακριτές Πνοές. Απαραίτητα χαρακτηριστικά για την εµϕάνιση τέτοιων λύσεων είναι η ύπαρξη ενός άνω φράγµατος του γραµµικού φάσµατος καθώς και η µη γραµµικότητα των εξισώσεων κίνησης, χαρακτηριστικά που συναντάµε σε πολλά φυσικά συστήµατα. Συγκεκριμένα, ασχολούµαστε µε πλέγµατα τύπου Klein Gordon και παρουσιάσουµε μια αποδείξη ύπαρξης τέτοιων λύσεων καθώς και αριθµητικά αποτελέσµατα µελετώντας παράλληλα την ευστάθεια των περιοδικών αυτών λύσεων µέσω της ϑεωρίας Floquet. Πέραν του κλασικού µοντέλου, όπου έχουµε αλληλεπιδράσεις πλησιέστερων γειτόνων, εισάγουµε επίσης ένα νέο µοντέλο µε αλληλεπιδράσεις µακράς εµβέλειας η οποία ελέγχεται µέσω µιας παράµετρου α και µελετάµε τις επιπτώσεις που έχει η μεταβολή του εύρους αλληλεπίδρασης στον χωρικό εντοπισµό και την ευστάθεια ενός DB. / We study time-periodic and spatially localized solutions in discrete dynamical systems describing Hamiltonian lattices in one spatial dimension. These solutions are called discrete breathers (DBs) or intrinsic localized modes (ILM). Necessary conditions for their occurrence are the boundedness of the spectrum of linear oscillations of the system as well as the nonlinearity of the equations of motion. More specifically, we focus on a Klein Gordon lattice and present an existence proof for such solutions, as well as numerical results revealing the stability (or instability) of DBs using Floquet theory. Besides reporting on the classical Klein Gordon model with nearest neighbor interactions, we also introduce long range interactions in our model, which are controlled by a parameter α and study the effect of varying the range of interactions on the spatial localization and the stability of a DB.

No description available.

Cette thèse contient deux sujets différents la simulation d'événements rares et un transport d'homotopie pour l'estimation du modèle de volatilité stochastique, dont chacun est couvert dans une partie distincte de cette thèse. Les méthodes de particules, qui généralisent les modèles de Markov cachés, sont largement utilisées dans différents domaines tels que le traitement du signal, la biologie, l'estimation d'événements rares, la finance, etc. Il existe un certain nombre d'approches basées sur les méthodes de Monte Carlo, tels que Markov Chain Monte Carlo (MCMC), Monte Carlo séquentiel (SMC). Nous appliquons des algorithmes SMC pour estimer les probabilités de défaut dans un processus d'intensité basé sur un processus stable afin de calculer un ajustement de valeur de crédit (CV A) avec le wrong way risk (WWR). Nous proposons une nouvelle approche pour estimer les événements rares, basée sur la génération de chaînes de Markov en simulant le système hamiltonien. Nous démontrons les propriétés, ce qui nous permet d'avoir une chaîne de Markov ergodique et nous montrons la performance de notre approche sur l'exemple que nous rencontrons dans la valorisation des options. Dans la deuxième partie, nous visons à estimer numériquement un modèle de volatilité stochastique, et à le considérer dans le contexte d'un problème de transport, lorsque nous aimerions trouver «un plan de transport optimal» qui représente la mesure d'image. Dans un contexte de filtrage, nous le comprenons comme le transport de particules d'une distribution antérieure à une distribution postérieure dans le pseudo-temps. Nous avons également proposé de repondérer les particules transportées, de manière à ce que nous puissions nous diriger vers la zone où se concentrent les particules de poids élevé. Nous avons montré sur l'exemple du modèle de la volatilité stochastique de Stein-Stein l'application de notre méthode et illustré le biais et la variance. / The thesis introduces simulation techniques that are based on particle methods and it consists of two parts, namely rare event simulation and a homotopy transport for stochastic volatility model estimation. Particle methods, that generalize hidden Markov models, are widely used in different fields such as signal processing, biology, rare events estimation, finance, etc. There are a number of approaches that are based on Monte Carlo methods that allow to approximate a target density such as Markov Chain Monte Carlo (MCMC), sequential Monte Carlo (SMC). We apply SMC algorithms to estimate default probabilities in a stable process based intensity process to compute a credit value adjustment (CV A) with a wrong way risk (WWR). We propose a novel approach to estimate rare events, which is based on the generation of Markov Chains by simulating the Hamiltonian system. We demonstrate the properties, that allows us to have ergodic Markov Chain and show the performance of our approach on the example that we encounter in option pricing.In the second part, we aim at numerically estimating a stochastic volatility model, and consider it in the context of a transportation problem, when we would like to find "an optimal transport map" that pushes forward the measure. In a filtering context, we understand it as the transportation of particles from a prior to a posterior distribution in pseudotime. We also proposed to reweight transported particles, so as we can direct to the area, where particles with high weights are concentrated. We showed the application of our method on the example of option pricing with Stein­Stein stochastic volatility model and illustrated the bias and variance.

[pt] Esta tese investiga as propriedades eletrônicas de sistemas nanoscópicos com interações de muitos corpos, dando origem ao efeito Kondo. Primeiramente estudamos a transição SU(4)-SU(2) devido a um campo magnético externo e as propriedades de filtro de spin de um nanossistema de dois pontos quânticos capacitivamente acoplados. A transição é caracterizada pela diferença entre as polarizações de spin da ocupação eletrônica nos dois pontos quânticos, como uma função do potencial de porta aplicado sobre os pontos quânticos. Apesar do fato de que o campo magnético externo quebra a simetria SU(4) do Hamiltoniano, o estado fundamental a preserva, como uma propriedade emergente, na região do espaço de parâmetros onde os elétrons não estão polarizados. As propriedades de filtro de spin devido à população eletrônica spin polarizada nos pontos quânticos também é discutida. Estas propriedades são estudadas usando o formalismo dos operadores de projeção, que descreve de forma muito acurada a física associada ao estado fundamental dos sistemas Kondo. No capítulo subsequente, analisamos os efeitos da interação spin-órbita num ponto quântico conectado a contatos, representados pelo modelo da impureza de Anderson no efeito Kondo. Contrariamente ao resultado prévio de vários outros autores, nós mostramos que a interação spin-órbita reduz exponencialmente a temperatura Kondo enquanto a ação da interação no próprio ponto quântico pode ser um mecanismo de destruição do regime Kondo, conforme quebra a simetria SU(2). Usando o modelo de Anderson com acoplamento spin-órbita nós propomos um transistor de spin feito de um ponto quântico conectado a uma nanofaixa submetida à interação spin-órbita Rashba, depositada sobre um substrato ferromagnético. O ponto quântico também é conectado a dois contatos metálicos laterais, através do qual a corrente flui ao longo do sistema. A interação spin-órbita Rashba cria um mecanismo de inversão do spin no ponto quântico. Nós mostramos que o sistema é capaz de operar como um transistor de spin. / [en] This thesis investigates the electronic properties of nanoscopic systems under the presence of many body interactions, given rise to the Kondo effect. Firstly we studied the SU(4)-SU(2) crossover driven by an external magnetic field and the spin-filter properties of a capacitively coupled double quantum dot nanosystem. The crossover is characterized by the difference between the spin polarization of the electronic occupation at the double quantum dot, as a function of the gate potential applied to the quantum dots. Despite the fact that the external magnetic field breaks the SU(4) symmetry of the Hamiltonian, the ground state preserves it, as an emergent property, in a region in the parameter space where the electron are not polarized. The spinfilter properties due the spin polarized electronic population at the dots is also discussed. These properties are studied using the projector projection operator approach, which describes very accurately the physics associated to the ground state of Kondo systems. In a subsequent chapter, we analyze the effect of the spin-orbit interaction in a quantum dot connected to leads, represented by the Anderson impurity model on the Kondo effect. Contrary to several other authors previous results, we show that the Rashba spin-orbit interaction exponentially reduces the Kondo temperature while the action of the interaction on the quantum dot itself could be a mechanism of destroying the Kondo regime, as it breaks SU(2) symmetry. Using the Anderson model with spin-orbit coupling we propose a spin transistor device made of a quantum dot connected to a Rashba spinorbit interacting nanoribbon, deposited on a ferromagnetic substrate. The quantum dot is also connected to two lateral metallic contacts, through which the current flows along the system. The Rashba spin-orbit interaction creates a spin-flip mechanism at the quantum dot. We show that the system is capable of operating as a spin-transistor.

GaugThe first half of the thesis concerns Abelian vortices and Yang-Mills theory. It is proved that the 5 types of vortices recently proposed by Manton are actually symmetry reductions of (anti-)self-dual Yang-Mills equations with suitable gauge groups and symmetry groups acting as isometries in a 4-manifold. As a consequence, the twistor integrability results of such vortices can be derived. It is presented a natural definition of their kinetic energy and thus the metric of the moduli space was calculated by the Samols' localisation method. Then, a modified version of the Abelian–Higgs model is proposed in such a way that spontaneous symmetry breaking and the Bogomolny argument still hold. The Painlevé test, when applied to its soliton equations, reveals a complete list of its integrable cases. The corresponding solutions are given in terms of third Painlevé transcendents and can be interpreted as original vortices on surfaces with conical singularity. The last two chapters present the following results in projective differential geometry and Hamiltonians of hydrodynamic-type systems. It is shown that the projective structures defined by the Painlevé equations are not metrisable unless either the corresponding equations admit first integrals quadratic in first derivatives or they define projectively flat structures. The corresponding first integrals can be derived from Killing vectors associated to the metrics that solve the metrisability problem. Secondly, it is given a complete set of necessary and sufficient conditions for an arbitrary affine connection in 2D to admit, locally, 0, 1, 2 or 3 Killing forms. These conditions are tensorial and simpler than the ones in previous literature. By defining suitable affine connections, it is shown that the problem of existence of Killing forms is equivalent to the conditions of the existence of Hamiltonian structures for hydrodynamic-type systems of two components.

Le travail présenté porte sur l'analyse et l'interprétation théorique du spectre d'absorption du dioxyde de carbone dans le proche infrarouge: spectroscopie d'absorption ultrasensible et modélisation théorique des positions et intensités des raies d'absorption. Ce travail vise à affiner et étendre l'ensemble des paramètres des opérateurs effectifs nécessaires à la génération des listes de raies pour les bases de données spectroscopiques. Les résultats obtenus peuvent être divisés en trois parties.Dans la première partie, nous avons établi les équations relatives aux paramètres q0 J, qJ, q2J and q3J-types des éléments de matrice de l'opérateur moment dipolaire effectif en fonction des dérivées du moment dipolaire et des constantes de force obtenues par transformation de contact pour les isotopologues: 16O12C18O, 16O12C17O, 16O13C18O, 16O13C17O, 17O12C18O. En utilisant ces équations et les relations isotopiques obtenues pour les constantes moléculaires, des calculs numériques nous ont permis de dériver les paramètres effectifs du moment dipolaire des séries de transitions ∆P= 0, 2, 4, 6 et 8, pour les six isotopologues asymétriques ci-dessus. La comparaison des paramètres rapportés dans la littérature et obtenus dans ce travail a été effectuée et discutée.La deuxième partie est consacrée à l'analyse du spectre d'absorption du dioxyde de carbone hautement enrichi en 18O, enregistré avec une très grande sensibilité par spectroscopie CW-Cavity Ring Down Spectroscopy entre 5851 et 6990 cm-1 (1.71-1.43 µm). Au total, 19526 transitions appartenant à onze isotopologues (12C16O2, 13C16O2, 16O12C18O, 16O12C17O, 16O13C18O, 16O13C17O, 12C18O2, 17O12C18O, 12C17O2, 13C18O2 et 17O13C18O) ont été attribuées sur la base des prévisions du modèle de l'Hamiltonien effectif. Toutes les bandes identifiées correspondent aux séries de transitions ∆P= 8, 9 et 10, où P=2V1+V2+3V3 est le nombre de polyade (V1,V2,V3 sont les nombres quantiques vibrationnels). Les intensités des transitions les plus faibles sont de l'ordre de 2×10-29 cm/molécule. Les paramètres spectroscopiques précis de 211 bandes appartenant à neuf isotopologues ont été calculés. Au total, neuf perturbations de résonance de la structure rotationnelle de l'état supérieur ont été observées et identifiées pour les isotopologues 16O12C18O, 12C18O2, 13C18O2, 16O13C18O, 16O12C17O et 17O12C18O. Un nouvel ensemble de paramètres du Hamiltonien effectif a été obtenu par un ajustement global de nos données et de l'ensemble des données de la littérature. En utilisant une approche similaire, les ajustements globaux des intensités obtenues pour les transitions des séries ∆P= 8, 9 and 10 ont permis d'obtenir l'ensemble de paramètres effectifs du moment dipolaire.Dans la troisième partie, nous présentons l'analyse du spectre CW-CRDS du dioxyde de carbone naturel entre 7909 et 8370 cm-1 (1.26-1.19 µm). Au total, 3425 transitions appartenant à 61 bandes de six isotopologues - 12C16O2, 13C16O2, 16O12C18O, 16O12C17O, 16O13C18O et 16O13C17O- ont été attribuées. Dans la région spectrale étudiée, toutes les bandes appartiennent à la série ∆P=11. Les paramètres spectroscopiques précis des états supérieurs de 57 bandes ont été obtenus à partir d'un ajustement des positions mesurées (rms typiques des écarts de l'ordre de 0.6×10-3 cm-1). Les ajustements globaux des intensités obtenues ont permis de déterminer les paramètres effectifs du moment dipolaire de la série ∆P=11 des six isotopologues étudiés.Les résultats obtenus ont eu un grand impact sur la modélisation globale des spectres de du dioxyde de carbone. Ils ont permis d'affiner et d'étendre les mesures existantes et d'améliorer considérablement les paramètres de l'Hamiltonien et moment dipolaire effectifs. Les résultats obtenus ont d'ores et déjà été intégrés dans les bases de données spectroscopiques de CO2 les plus couramment utilisées (HITRAN, GEISA, CDSD). / This thesis is devoted to the investigation of the high resolution near infrared spectra of carbon dioxide and includes experimental measurements and theoretical modeling of line positions and intensities and refinement and extension of the set of effective operator parameters. The obtained results can be divided by three parts:In the first part, we present the equations for the q0 J, qJ, q2J and q3J-types parameters of the matrix elements of the effective dipole-moment operator in terms of the dipole-moment derivatives and force field constants derived by means of contact transformation method for the following carbon dioxide isotopologues: 16O12C18O, 16O12C17O, 16O13C18O, 16O13C17O, 17O12C18O and 17O13C18O. Using these equations and the obtained isotopic relations for the molecular constants, we derived the effective dipole-moment parameters for the ∆P= 0, 2, 4, 6 and 8 series of transitions of the six above asymmetric carbon dioxide isotopologues (P=2V1+V2+3V3 is the polyad number where V1,V2 and V3 are the vibrational quantum numbers). The comparison of the parameters reported in the literature and obtained in this work is performed and discussed.The second part is devoted to the analysis of the room temperature absorption spectrum of highly 18O enriched carbon dioxide recorded by very high sensitivity CW-Cavity Ring Down Spectroscopy between 5851 and 6990 cm-1 (1.71-1.43 µm ). Overall, 19526 transitions belonging to eleven isotopologues (12C16O2, 13C16O2, 16O12C18O, 16O12C17O, 16O13C18O, 16O13C17O, 12C18O2, 17O12C18O, 12C17O2, 13C18O2 and 17O13C18O) were assigned on the basis of the predictions of the effective Hamiltonian model. Line intensities of the weakest transitions are on the order of 2×10-29 cm/molecule. The line positions were determined with accuracy better than 1×10-3 cm-1 while the absolute line intensities are reported with an uncertainty better than 10%. All the identified bands correspond to the ∆P= 8, 9 and 10 series of transitions. The accurate spectroscopic parameters for a total of 211 bands belonging to nine isotopologues were derived. Nine resonance perturbations of the upper state rotational structure were identified for 16O12C18O, 12C18O2, 13C18O2, 16O13C18O, 16O12C17O and 17O12C18O isotopologues. New sets of Hamiltonian parameters have been obtained by the global modeling of the line positions within the effective Hamiltonian approach. Using a similar approach, the global fits of the obtained intensity values of the ∆P= 8, 9 and 10 series of transitions were used to derive the corresponding set of effective dipole moment parameters.In the third part, we report the analysis of the absorption spectrum of natural carbon dioxide by high sensitivity CW-Cavity Ring Down spectroscopy between 7909 and 8370 cm-1 (1.26-1.19 µm). Overall, 3425 transitions belonging to 61 bands of 12C16O2, 13C16O2, 16O12C18O, 16O12C17O, 16O13C18O and 16O13C17O were assigned. In the studied spectral region, all bands correspond to ∆P= 11 series of transitions. The accurate spectroscopic parameters of the upper states of 57 bands were derived from a fit of the measured line positions (typical rms deviations of about 0.6×10-3 cm-1). The global fits of the obtained intensity values of the ∆P= 11 series of transitions were used to determine the corresponding set of effective dipole moment parameters of the six studied isotopologues.The large set of new observations obtained in this thesis has an important impact on the global modeling of high resolution spectra of carbon dioxide. It has allowed refining and extending the sets of effective dipole moment and effective Hamiltonian parameters. The obtained results have allowed improving importantly the quality of the line positions and intensities in the most currently used spectroscopic databases of carbon dioxide (HITRAN, GEISA, CDSD).