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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
511

Parallelized QC-LDPC Decoder ona GPU : An evaluation targeting LDPC codes adhering to the 5G standard / Paralleliserad QC-LDPC-avkodare på en GPU : En utvärdering av LDPC-koder som följer 5G-standarden

Hedlund, Olivia January 2024 (has links)
Over the last ten years, there has been an incremental growth of mobile network data traffic. The evolution leading to the development of 5G stands as a testament to the increased demands for high speed networks. Channel coding plays a pivotal role in 5G networks, making it possible to recover messages from errors introduced when sent through the network. Channel decoding is however a time consuming task for a receiver, and making optimization to this process could therefore have a significant impact on receiver processing time. Low-Density Parity-Check (LDPC) codes are one of the channel coding schemes used in the 5G standard. These codes could benefit from parallel processing, making Graphics Processing Units (GPUs) with their parallel computation abilities a possible platform for effective LDPC decoding. In this thesis, our goal is to evaluate a GPU as a platform for 5G LDPC decoding. The LDPC codes adhering to the 5G standard belong to the Quasi-Cyclic LDPC (QC-LDPC) subclass. Optimizations targeting this subclass, as well as other optimization techniques, are implemented in our thesis project to promote fast execution times. A GPU-based decoder is evaluated against a Central Processing Unit (CPU)-based decoder, written with Compute Unified Device Architecture (CUDA) and C++ respectively. The functionally equivalent decoders implement the layered offset Min-Sum Algorithm (MSA) with early termination to decode messages. Execution time for the decoders were measured while varying message size, Signal-to-Noise Ratio (SNR) and maximum iterations. Additionaly, we evaluated the decoders with and without including early termination, and also evaluated the GPU-decoder when it was integrated into a MATLAB 5G channel simulator used by Tietoevry. The results from the experiments showed that the GPU-based decoder experienced up to 4.3 times faster execution than the CPU-based decoder for message sizes ranging from 3000-12000 bits. The GPU-based decoder however experienced a higher baseline execution time, making the CPU-based decoder faster for smaller message sizes. It was also concluded that the benefit of including early termination in the decoder generally outweighs the cost of additional processing time. / Under de senaste tio åren har det skett en gradvis ökning av datatrafik i mobilnät. Utvecklingen som lett till framtagandet av 5G står som ett bevis på de ökade kraven på höghastighetsnätverk. Kanalkodning spelar en avgörande roll i 5G- nätverk, vilket gör det möjligt att återställa meddelanden från fel som uppstår när de skickas genom nätverket. Kanalavkodning är dock en tidskrävande uppgift för en mottagare, och optimering av denna process kan därför ha en betydande inverkan på mottagarens exekveringstider. LDPC-koder är en av de kanalkoder som används i 5G-standarden. Dessa koder kan dra nytta av parallell bearbetning, vilket gör GPUs med deras parallella beräkningsförmåga till en möjlig plattform för effektiv LDPC- avkodning. I denna masteruppsats är vårt mål att utvärdera en GPU som en plattform för 5G LDPC- avkodning. LDPC-koder som följer 5G-standarden tillhör underklassen QC-LDPC. Optimeringar som riktar sig mot denna underklass, samt andra optimeringstekniker, implementeras i vårt avhandlingsprojekt för att främja snabba exekveringstider. En GPU-baserad avkodare utvärderas mot en CPU-baserad avkodare, skrivna med programspråken CUDA respektive C++. De funktionellt likvärdiga avkodarna implementerar den lagrade offset MSA med tidig terminering för att avkoda meddelanden. Exekveringstiden för avkodarna mättes medan meddelandestorlek, SNR och maximalt antal iterationer varierades. Vi utvärderade också avkodarna med och utan att inkludera tidig terminering, samt utvärderade GPU-avkodaren när den integrerats i en MATLAB 5G-kanalsimulator som används av Tietoevry. Resultaten från experimenten visade att den GPU-baserade avkodaren hade upp till 4.3 gånger snabbare exekvering än den CPU-baserade avkodaren för meddelandestorlekar mellan 3000 och 12000 bitar. Den GPU-baserade avkodaren hade dock en högre baslinje för exekveringstiden, vilket gjorde den CPU-baserade avkodaren snabbare för mindre meddelandestorlekar. Det konstaterades också att fördelen med att inkludera tidig terminering i avkodaren i allmänhet överväger kostnaden för ytterligare bearbetningstid.
512

The engineering and optimization of expression of rotavirus-like particles in insect cells using a South African G9P[6] rotavirus strain / by Maria J. van der Westhuizen.

Van der Westhuizen, Maria Jacoba January 2012 (has links)
Rotavirus infection causes gastroenteritis, specifically severe gastroenteritis, affecting children younger than five globally, regardless of hygiene and water quality. Current licensed, live, attenuated vaccines do not contain the G9 genotype, which is a prevalent rotavirus strain circulating in sub-Saharan Africa, a region that carries a high rotavirus disease burden. Rotavirus-like particles (RV-VLPs) is an attractive non-live vaccine candidate, which has shown promising results in animal studies. Previously, dsRNA was extracted from a stool sample containing a South African human G9P[6] neonatal strain, and amplified cDNA using a sequence-independent procedure. The consensus sequence was obtained for the genome segments using 454® pyrosequencing. The insect-cell-codon-optimized genome segments 2 (VP2), 4 (VP4), 6 (VP6) and 9 (VP7) were cloned into a modified pFASTBACquad vector (pFBq). Several combinations of the genome segments were cloned to produce double-layered particles (DLP; pFBqVP2VP6) or triple-layered particles (TLP; pFBqVP2VP6VP7). In the current study, a ΔTLP (pFBqdVP2-VP8*VP6VP7) construct was generated. The first 92 amino acids of VP2 are not necessary for the conformation of recombinant RV-VLPs. The ORF of VP8*, which contains immune important epitopes, was fused to the 5’ end of the dVP2 coding region resulting in a dVP2-VP8* fused protein which was expressed in the presence of VP6 and VP7 to produce ΔTLPs. The Bac-to-Bac® Baculovirus Expression System and Spodoptera frugiperda (Sf) 9 insect cells were used for expression. All the proteins were successfully expressed. VP2, VP6, VP4 and the dVP2-VP8* fused protein were visible on Coomassie stained SDS-PAGE. Expression of VP7 could only be confirmed with western blot analysis. Particle formation, as assessed by transmission electron microscopy (TEM), was observed for DLPs. No TLPs of dVP2-8*/6/7 or VP2/6/7 were visualized due to the lower expression level of VP7 and the lack of calcium supplements during the assembly process. In conclusion, it was possible to produce RV-DLPs derived from the consensus sequence determined for a G9P[6] rotavirus directly from stool without prior propagation in cell culture or virus isolation. This strain contains both the G9 and P[6] genotypes that are currently prevalent in sub-Saharan Africa. / Thesis (MSc (Biochemistry))--North-West University, Potchefstroom Campus, 2013.
513

The engineering and optimization of expression of rotavirus-like particles in insect cells using a South African G9P[6] rotavirus strain / by Maria J. van der Westhuizen.

Van der Westhuizen, Maria Jacoba January 2012 (has links)
Rotavirus infection causes gastroenteritis, specifically severe gastroenteritis, affecting children younger than five globally, regardless of hygiene and water quality. Current licensed, live, attenuated vaccines do not contain the G9 genotype, which is a prevalent rotavirus strain circulating in sub-Saharan Africa, a region that carries a high rotavirus disease burden. Rotavirus-like particles (RV-VLPs) is an attractive non-live vaccine candidate, which has shown promising results in animal studies. Previously, dsRNA was extracted from a stool sample containing a South African human G9P[6] neonatal strain, and amplified cDNA using a sequence-independent procedure. The consensus sequence was obtained for the genome segments using 454® pyrosequencing. The insect-cell-codon-optimized genome segments 2 (VP2), 4 (VP4), 6 (VP6) and 9 (VP7) were cloned into a modified pFASTBACquad vector (pFBq). Several combinations of the genome segments were cloned to produce double-layered particles (DLP; pFBqVP2VP6) or triple-layered particles (TLP; pFBqVP2VP6VP7). In the current study, a ΔTLP (pFBqdVP2-VP8*VP6VP7) construct was generated. The first 92 amino acids of VP2 are not necessary for the conformation of recombinant RV-VLPs. The ORF of VP8*, which contains immune important epitopes, was fused to the 5’ end of the dVP2 coding region resulting in a dVP2-VP8* fused protein which was expressed in the presence of VP6 and VP7 to produce ΔTLPs. The Bac-to-Bac® Baculovirus Expression System and Spodoptera frugiperda (Sf) 9 insect cells were used for expression. All the proteins were successfully expressed. VP2, VP6, VP4 and the dVP2-VP8* fused protein were visible on Coomassie stained SDS-PAGE. Expression of VP7 could only be confirmed with western blot analysis. Particle formation, as assessed by transmission electron microscopy (TEM), was observed for DLPs. No TLPs of dVP2-8*/6/7 or VP2/6/7 were visualized due to the lower expression level of VP7 and the lack of calcium supplements during the assembly process. In conclusion, it was possible to produce RV-DLPs derived from the consensus sequence determined for a G9P[6] rotavirus directly from stool without prior propagation in cell culture or virus isolation. This strain contains both the G9 and P[6] genotypes that are currently prevalent in sub-Saharan Africa. / Thesis (MSc (Biochemistry))--North-West University, Potchefstroom Campus, 2013.
514

Towards Sustainable Aviation: Business Models for Sustainable Aviation Fuels / Mot Hållbart Flyg: Affärsmodeller för Hållbara Flygbränslen

Uthman, Darwin, Danha, Jack January 2024 (has links)
The aviation sector is in a critical position where it must switch to environmentally friendly alternatives in order to lessen its impact on the environment. The implementation of Sustainable Aviation Fuel (SAF) in airline business models is thoroughly examined in this thesis, which uses the Business Model Canvas (BMC) and the Triple Layered Business Model Canvas (TLBMC) as its primary conceptual frameworks. A thorough examination of the airlines' SAF pricing tactics and business models has been conducted, considering the sustainability of the environment, the economy, and society. This has made it possible to identify strategies that will effectively encourage the use of sustainable jet fuel. Through the examination and evaluation of aviation industry dynamics, legislation, and technical advancements, this research provides useful information to help direct strategic planning and decision-making within the aviation industry. The findings indicate that innovation, sustainability, and cooperation are essential for industry players to embrace in order to steer the aviation sector toward a more resilient and environmentally friendly future. The integration of sustainable aviation fuel within the airlines' business models represents a decisive step towards sustainability in the aviation industry. In this thesis, the Triple Layered Business Model Canvas TLBMC has been used to complement the traditional Business Model Canvas BMC. Using these frameworks together offers a holistic analysis of the environmental, economic and social impacts of SAF implementation on airlines such as Scandinavian Airlines SAS and BRA Braathens Regional Airlines. Sustainable jet fuel is used as a temporary solution to reduce the aviation industry's environmental impact. However, analysis and review of the sustainable fuel's life cycle from production to consumption is needed to be able to evaluate its environmental and social benefits. From an economic perspective, sustainable jet fuel production and availability is a major challenge for airlines. In order to overcome this challenge, innovative pricing strategies and cost-sharing initiatives are required in which various stakeholders from the aviation industry are involved. In summary, this thesis contributes to increased knowledge in changing business models in the aviation industry as well as an analysis of current price strategies for sustainable aviation fuel. Leveraging the insights from the TLBMC analysis of business models and pricing strategies for SAF integration, this research aims to inform strategic decision-making in the aviation sector and accelerate the industry's transition towards a more sustainable and environmentally conscious future. / Flygindustrin befinner sig i en avgörande position där behov för övergång till hållbara alternativ för att minska dess miljöpåverkan finns. Denna avhandling utgör en omfattande utforskning av hållbara flygbränslen införande inom flygbolagens affärsmodeller, med användning av både Business Model Canvas (BMC) och Triple Layered Business Model Canvas (TLBMC) som huvudramverk för analys. En noggrann analys av flygbolagens prisstrategier för hållbart flygbränsle och affärsmodeller har genomförts med hänsyn till miljömässiga, ekonomiska och sociala hållbarhetsaspekter. Detta har möjliggjort identifiering av effektiva tillvägagångssätt för att främja införandet av hållbart flygbränsle. Genom att utföra analyser och granskning av flygindustrins dynamik, riktlinjer och tekniska framsteg, bidrar denna forskning med praktiska insikter som syftar till att vägleda beslutsfattande och strategisk planering inom flygsektorn. Resultaten har visat på att det är avgörande för industrins intressenter att ta till sig innovation, hållbarhet och samarbeta för att föra flygsektorn mot en grönare och mer motståndskraftig framtid. Integrationen av hållbara flygbränsle inom flygbolagens affärsmodeller representerar ett avgörande steg mot hållbarhet inom flygindustrin. I denna avhandling har Triple Layered Business Model Canvas TLBMC, använts för att komplettera den traditionella Business Model Canvas BMC. Användning av dessa ramverk tillsammans erbjuder en holistisk analys av de miljömässiga, ekonomiska och sociala effekterna av SAF införande på flygbolag som Scandinavian Airlines SAS och BRA Braathens Regional Airlines. Hållbart flygbränsle används som en tillfällig lösning för att minska flygindustrins miljöpåverkan. Dock behövs det analys och granskning av det hållbara bränslets livscykel från produktion till konsumtion för att kunna utvärdera dess miljö och sociala fördelar. Från ett ekonomiskt perspektiv utgör det hållbara flygbränsle produktionen och tillgängligheten en  stor utmaning för flygbolagen. För att övervinna denna utmaningen krävs det innovativaprissättningsstrategier och kostnadsdelning initiativ där olika intressenter från flygindustrin är involverade. Sammanfattningsvis bidrar denna avhandling till ökad kunskap inom förändring av affärsmodeller inom flygindustrin samt en analys av nuvarande prisstrategier för hållbart flygbränsle. Genom att utnyttja insikterna från TLBMC-analysen av affärsmodeller och prissättningsstrategier för SAF-integration, syftar denna forskning till att informera strategiskt beslutsfattande inom flygsektorn och påskynda branschens övergång mot en mer hållbar och miljömedveten framtid.
515

Coupled Boussinesq equations and nonlinear waves in layered waveguides

Moore, Kieron R. January 2013 (has links)
There exists substantial applications motivating the study of nonlinear longitudinal wave propagation in layered (or laminated) elastic waveguides, in particular within areas related to non-destructive testing, where there is a demand to understand, reinforce, and improve deformation properties of such structures. It has been shown [76] that long longitudinal waves in such structures can be accurately modelled by coupled regularised Boussinesq (cRB) equations, provided the bonding between layers is sufficiently soft. The work in this thesis firstly examines the initial-value problem (IVP) for the system of cRB equations in [76] on the infinite line, for localised or sufficiently rapidly decaying initial conditions. Using asymptotic multiple-scales expansions, a nonsecular weakly nonlinear solution of the IVP is constructed, up to the accuracy of the problem formulation. The asymptotic theory is supported with numerical simulations of the cRB equations. The weakly nonlinear solution for the equivalent IVP for a single regularised Boussinesq equation is then constructed; constituting an extension of the classical d'Alembert's formula for the leading order wave equation. The initial conditions are also extended to allow one to separately specify an O(1) and O(ε) part. Large classes of solutions are derived and several particular examples are explicitly analysed with numerical simulations. The weakly nonlinear solution is then improved by considering the IVP for a single regularised Boussinesq-type equation, in order to further develop the higher order terms in the solution. More specifically, it enables one to now correctly specify the higher order term's time dependence. Numerical simulations of the IVP are compared with several examples to justify the improvement of the solution. Finally an asymptotic procedure is developed to describe the class of radiating solitary wave solutions which exist as solutions to cRB equations under particular regimes of the parameters. The validity of the analytical solution is examined with numerical simulations of the cRB equations. Numerical simulations throughout this work are derived and implemented via developments of several finite difference schemes and pseudo-spectral methods, explained in detail in the appendices.
516

Variotherme Spritzgießtechnologie zur Beeinflussung tribologischer Eigenschaften thermoplastischer Formteile / Variothermal injection moulding technology for influencing the tribological properties of thermoplastic mouldings

Bleesen, Christoph A. 25 July 2016 (has links) (PDF)
Im Rahmen der vorliegenden Arbeit wurde ein Spritzgießwerkzeug mit einem neuartigen Mehrschichtverbundheizsystem zur dynamischen Temperierung entwickelt und umgesetzt. Dabei wurde das ausgewählte Heiz‐ und Kühlsystem unter theoretischen und praktischen Gesichtspunkten betrachtet und für den variothermen Fertigungsprozess verifiziert. Aus den ersten durchgeführten praktischen Versuchen zeigte sich, dass dieses Heizsystem zur dynamischen Temperierung von Formwerkzeugen geeignet ist. Anschließend wurden mit dem realisierten Spritzgießwerkzeug Versuchskörper mit spezieller Oberflächenstrukturierung und variierenden Werkzeugwandtemperaturen angefertigt und untersucht. Ziel war es, über diese Strukturierung eine Beeinflussung der Glasfaserverteilung im Formteilrandbereich zu erreichen und die tribologischen Eigenschaften bei Kunststoff‐Kunststoff‐Gleitpaarungen hinsichtlich Reibung und Verschleiß zu verbessern. Mit einer kleinen Auswahl an Strukturen und entsprechenden thermoplastischen Polymermaterialien wurden praktische Versuche zur tribologischen Prüfung durchgeführt. / In the present work an injection mould was developed and implemented with a novel multilayer composite heating system for dynamic temperature control. Here the selected heating and cooling system was considered from a theoretical and practical point of view and verified for the variothermal manufacturing process. The first practical tests showed that this heating system is suitable for the dynamic temperature control of tools. Subsequently, with this injection mould, test specimens with a special surface structure and varying mould wall temperatures were produced and examined. The aim was to achieve through this structuring an impact on the distribution of glass fibres in the edge region of mouldings and improve the tribological properties of plastic‐plastic‐pairings in terms of friction and wear. With a small selection of structures and corresponding thermoplastic polymeric materials practical experiments for tribological testing were performed.
517

Error resilient video communications using high level M-QAM : modelling and simulation of a comparative analysis of a dual-priority M-QAM transmission system for H.264/AVC video applications over band-limited and error-phone channels

Abdurrhman, Ahmed B. M. January 2010 (has links)
An experimental investigation of an M level (M = 16, 64 and 256) Quadrature Amplitude Modulation (QAM) transmission system suitable for video transmission is presented. The communication system is based on layered video coding and unequal error protection to make the video bitstream robust to channel errors. An implementation is described in which H.264 video is protected unequally by partitioning the compressed data into two layers of different visual importance. The partition scheme is based on a separation of the group of pictures (GoP) in the intra-coded frame (I-frame) and predictive coded frame (P frame). This partition scheme is then applied to split the H.264-coded video bitstream and is suitable for Constant Bit Rate (CBR) transmission. Unequal error protection is based on uniform and non-uniform M-QAM constellations in conjunction with different scenarios of splitting the transmitted symbol for protection of the more important information of the video data; different constellation arrangements are proposed and evaluated to increase the capacity of the high priority layer. The performance of the transmission system is evaluated under Additive White Gaussian Noise (AWGN) and Rayleigh fading conditions. Simulation results showed that in noisy channels the decoded video can be improved by assigning a larger portion of the video data to the enhancement layer in conjunction with non-uniform constellation arrangements; in better channel conditions the quality of the received video can be improved by assigning more bits in the high priority channel and using uniform constellations. The aforementioned varying conditions can make the video transmission more successful over error-prone channels. Further techniques were developed to combat various channel impairments by considering channel coding methods suitable for layered video coding applications. It is shown that a combination of non-uniform M-QAM and forward error correction (FEC) will yield a better performance. Additionally, antenna diversity techniques are examined and introduced to the transmission system that can offer a significant improvement in the quality of service of mobile video communication systems in environments that can be modelled by a Rayleigh fading channel.
518

Analysis and Construction of Engaging Facial Forms and Expressions: Interdisciplinary Approaches from Art, Anatomy, Engineering, Cultural Studies, and Psychology

Kim, Leejin 19 November 2013 (has links)
The topic of this dissertation is the anatomical, psychological, and cultural examination of a human face in order to effectively construct an anatomy-driven 3D virtual face customization and action model. In order to gain a broad perspective of all aspects of a face, theories and methodology from the fields of art, engineering, anatomy, psychology, and cultural studies have been analyzed and implemented. The computer generated facial customization and action model were designed based on the collected data. Using this customization system, culturally-specific attractive face in Korean popular culture, “kot-mi-nam (flower-like beautiful guy),” was modeled and analyzed as a case study. The “kot-mi-nam” phenomenon is overviewed in textual, visual, and contextual aspects, which reveals the gender- and sexuality-fluidity of its masculinity. The analysis and the actual development of the model organically co-construct each other requiring an interwoven process. Chapter 1 introduces anatomical studies of a human face, psychological theories of face recognition and an attractive face, and state-of-the-art face construction projects in the various fields. Chapter 2 and 3 present the Bezier curve-based 3D facial customization (BCFC) and Multi-layered Facial Action Model (MFAF) based on the analysis of human anatomy, to achieve a cost-effective yet realistic quality of facial animation without using 3D scanned data. In the experiments, results for the facial customization for gender, race, fat, and age showed that BCFC achieved enhanced performance of 25.20% compared to existing program Facegen , and 44.12% compared to Facial Studio. The experimental results also proved the realistic quality and effectiveness of MFAM compared with blend shape technique by enhancing 2.87% and 0.03% of facial area for happiness and anger expressions per second, respectively. In Chapter 4, according to the analysis based on BCFC, the 3D face of an average kot-mi-nam is close to gender neutral (male: 50.38%, female: 49.62%), and Caucasian (66.42-66.40%). Culturally-specific images can be misinterpreted in different cultures, due to their different languages, histories, and contexts. This research demonstrates that facial images can be affected by the cultural tastes of the makers and can also be interpreted differently by viewers in different cultures.
519

Study and Development of Nonwovens made of Electrospun Composite Nanofibers / Etude et développement de non-tissés fait en nanofibres composites obtenues par électrofilage

Almuhamed, Sliman 14 December 2015 (has links)
L’électrofilage est actuellement la méthode la plus utilisée pour la production de nanofibres grâce à sa simplicité, sa reproductibilité et la possibilité d’être industrialisée. Grâce à leurs propriétés particulières telles qu’un grand rapport surface-volume, une porosité inter-fibre élevée et une grande capacité d’adsorption, les nanofibres électrofilées sont de bons candidats pour de nombreuses applications telles que la filtration, les masques respiratoires, les matériaux composites, etc. Cependant, certaines applications particulières, telles que les capteurs, les systèmes d'administration contrôlée de médicaments ou les super condensateurs, exigent que les nanofibres doivent présenter des propriétés complémentaires telles que la conductivité électrique, la porosité de surface de nanofibres, l’hydrophobicité, ou d’autres propriétés particulières. Certains nanomatériaux comme les nanotubes de carbone, la silice mésoporeuse ordonnée, les argiles, ont des propriétés particulières comme la conductivité électriques élevée des nanotubes de carbone, la porosité des matériaux de silice mésoporeuse ordonnée ou de l’argile. Ces propriétés des nanomatériaux peuvent être les fonctions complémentaires cherchées. Dans notre étude, des non-tissés composés de nanofibres de polyacrylonitrile chargées par nanotubes de carbone à multi-parois (MWNT), de la montmorillonite sodique (MMT-Na) ou de la silice mésoporeuse ordonnée (de type SBA-15), sont produits par électrofilage. Les résultats montrent que l’insertion de MWNT rend le non-tissé conducteur en augmentant la conductivité électrique volumique par six ordres de grandeur (de ~ 2×10-12 à ~ 3×10-6 S/m) avec un très faible seuil de percolation de 0.5 % massique. Lorsque le non-tissé est soumis à une compression, la conductivité électrique volumique augmente en augmentant la pression (jusqu’à ~ 2 kPa). Ces non-tissés conducteurs sont très intéressants pour le développement des capteurs à faible amplitude. Les résultats montrent aussi que l’accessibilité des pores des particules inorganiques (c’est-à-dire, les mésopores de SBA-15 et l’espace interfoliaire de MMT-Na) insérées dans la structure nano fibreuse est encore possible. Il a été trouvé que plus de 50% des mésopores de SBA-15 insérées sont encore accessibles quelles que soit les conditions de l’électrofilage et la fraction massique de SBA-15. En outre, l’insertion de ces particules inorganiques apporte plus de stabilité thermique aux nanofibres composites. / Electrospinning is the most common method for the production of nanofibres due to its simplicity, repeatability, and the ability to be scaled up. Owing to their advanced properties like the high surface-to-volume ratio, high interfibrous porosity, high adsorption capacity, etc. electrospun nanofibers are good candidates for many applications such as filtration, respiratory masks, composite materials and others. However, some specific applications including sensors, controlled drug delivery systems, supercapacitors, etc. still require complimentary functions that do not exist in pristine nanofibers in their basic structure like the electrical conductivity, surface porosity of the nanofibers, hydrophobicity, and others.Nanomaterials like carbon nanotubes, ordered mesoporous silica, layered silicate, etc. are characterized by particular properties like the high electrical conductivity of carbon nanotubes, the porosity of ordered mesoporous silica or layered silicate. These particular properties of nanomaterials can fulfill of the targeted functions.In our study, nonwovens made from nanofibers of polyacrylonitrile incorporated with multiwalled carbon nanotubes (MWNT), layered silicate type Na-montmorillonite (Na-MMT) or ordered mesoporous silica type SBA-15 are successfully produced by electrospinning.Results reveal that the incorporation of MWNT altered the electrical state of the nonwoven from insolent to conductor where the volume electrical conductivity increased by six order of magnitude (from ~ 2×10-12 to ~ 3×10-6 S/m) with a very low percolation threshold of about 0.5 wt%. The application of mechanical pressure to the conductive nonwoven causes an increase in the volume electrical conductivity with the increase of the applied pressure (up to ~ 2 kPa). Such conductive nonwoven is very interesting for the development of sensor with low amplitude.Results also show that accessibility of the pores of the inorganic particles (i.e. mesopores of SBA-15 and interlayer space of Na-MMT) incorporated into the nanofibers is still possible. It is found that at least 50% of SBA-15 mesopores are still accessible whatever is the electrospinning conditions and SBA-15 mass fraction. In addition, the incorporation of the studied inorganic particles yields higher thermal stability for the composite nanofibers.
520

Structural and electrical characterization of novel layered intergrowth compounds

Grosse, Corinna 11 February 2016 (has links)
Die untersuchten Ferekristalle sind neuartige Verwachsungs-Schichtverbindungen aus m Monolagen von Niobdiselenid (NbSe2), die wiederholt mit n atomaren Bilagen von Bleiselenid (PbSe) oder Zinnselenid (SnSe) geschichtet sind. Niobdiselenid als Volumenmaterial besitzt eine Schichtstruktur und ist ein Supraleiter. Aufgrund ihrer gezielt einstellbaren atomar geschichteten Struktur können Ferekristalle als Modellsysteme für geschichtete Supraleiter dienen. In dieser Arbeit werden ihre strukturellen und elektrischen Eigenschaften untersucht. Mittels Transmissionselektronenmikroskopie wird ihre turbostratisch ungeordnete, nanokristalline Struktur nachgewiesen. Die atomare Struktur innerhalb der einzelnen Schichten ist ähnlich wie in den Volumenmaterialien NbSe2, PbSe und SnSe, wobei die kristallographischen c-Achsen parallel zur Stapelrichtung der Ferekristalle zeigen. Eine quantitative Analyse unter Verwendung eines Zwei-Schicht-Modells für den spezifischen Widerstand, Hall-Koeffizienten und Magnetwiderstand liefert ähnliche Ladungsträgersorten, -dichten und –beweglichkeiten in den NbSe2-Schichten, wie sie für isolierte Einzellagen von NbSe2 berichtet wurden. Diese unterscheiden sich von denen des Volumenmaterials NbSe2. Erstmals wurde ein Übergang der Ferekristalle in den supraleitenden Zustand nachgewiesen. Die Sprungtemperaturen sind dabei in etwa auf die Hälfte der Sprungtemperaturen der jeweiligen nicht turbostratisch ungeordneten Misfit-Schichtverbindungen reduziert. Diese Reduzierung kann der turbostratischen Unordnung der Ferekristalle zugeordnet werden. Das Verhältnis zwischen der schichtsenkrechten Ginzburg-Landau-Kohärenzlänge und dem Abstand zwischen den supraleitenden Schichten ist bei den Ferekristallen kleiner als bei den nicht ungeordneten Misfit-Schichtverbindungen, was Ferekristalle zu vielversprechenden Kandidaten für (quasi-)zweidimensionale Supraleiter macht. / The investigated ferecrystals are novel layered intergrowth compounds consisting of m monolayers of niobium diselenide (NbSe2) stacked repeatedly with n atomic bilayers of lead selenide (PbSe) or tin selenide (SnSe). Bulk NbSe2 is a layered compound showing superconductivity. Due to their artificially atomic-scale layered structure, which is tunable on the atomic scale, ferecrystals can serve as model systems for layered superconductors. In this study, their structural and electrical properties are investigated. Using transmission electron microscopy their turbostratically disordered, nanocrystalline structure is revealed. The atomic structure within the individual layers is similar as for bulk NbSe2, PbSe and SnSe, with the crystallographic c-axes parallel to the stacking direction in the ferecrystals. A quantitative analysis using a two-layer model fit for the electrical resistivity, Hall coefficient and magnetoresistance yields a similar carrier type, density and mobility in the NbSe2 layers as reported for isolated NbSe2 monolayers. These values differ from those of bulk NbSe2. For the first time, a normal-to-superconducting transition has been detected in ferecrystals. The transition temperatures of the ferecrystals are reduced to about a half of those of analogous non-disordered misfit layer compounds. This reduction in transition temperature can be correlated to the turbostratic disorder in ferecrystals. The ratio between the cross-plane Ginzburg-Landau coherence length and the cross-plane distance between the NbSe2 layers for the ferecrystals is lower than for non-disordered misfit layer compounds, making ferecrystals promising candidates for (quasi-)two-dimensional superconductors.

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