CAPES / Vários estudos numéricos investigaram cavidades fechadas sob o efeito da convecção natural preenchidas com fluidos newtonianos generalizados (FNG) nos últimos anos pelas aplicações diretas em trocadores de calor compactos, no resfriamento de sistemas eletrônicos e na engenharia de polímeros. Neste trabalho é realizada a investigação numérica do processo de convecção natural de fluidos de lei de Potência e de Bingham em cavidades fechadas, aquecidas lateralmente e preenchidas com meios heterogêneos e bloco centrado. O meio heterogêneo é constituído de blocos sólidos, quadrados, desconectados e condutores de calor. Como parâmetros são utilizados a faixa de Rayleigh de 104 à 107, índice de potência n de 0, 6 à 1, 6, número de Bingham de 0, 5 até Bimax , sendo investigado da influência do número de Prandtl para cada modelo de fluido. Nas cavidades com meio heterogêneo são utilizadas as quantidades de blocos de 9, 16, 36 e 64, mantendo-se a razão entre a condutividade térmica do sólido e do fluido κ = 1. Para as cavidades com bloco centrado, são utilizados os tamanhos adimensionais de 0, 1 à 0, 9 com κ = 0, 1; 1 e 10. A modelagem matemática é realizada pelas equações de balanço de massa, de quantidade de movimento e de energia. As simulações são conduzidas no programa comercial ANSYS FLUENT R . Inicialmente são resolvidos problemas com fluidos newtonianos em cavidade limpa, seguida de cavidade preenchida com meio heterogêneo e posteriormente bloco centrado para validação da metodologia de solução. Na segunda etapa é realizada o estudo com os modelos de fluidos de lei de Potência e de Bingham seguindo a mesma sequência. Os resultados são apresentados na forma de linhas de corrente, isotermas e pelo número de Nusselt médio na parede quente. De maneira geral, a transferência de calor na cavidade é regida pelo número de Rayleigh, tamanho e condutividade térmica dos blocos, pelo índice de potência para o modelo de lei de Potência e do número de Bingham para o modelo de Bingham. O número de Prandtl tem grande influência nos dois modelos de fluidos. O meio heterogêneo reduz a transferência de calor na cavidade quando interfere na camada limite térmica para ambos os fluidos, sendo feita uma previsão analítica para o fluido de lei de Potência. Para bloco centrado, a interferência na camada limite com fluido de lei de Potência também foi prevista analiticamente. A transferência de calor aumentou com bloco de baixa condutividade térmica e pouca interferência e com bloco de alta condutividade térmica e grande interferência, para ambos os fluidos. / Many studies have been carried out in square enclosures with generalized Newtonian fluids with natural convection in past few years for directly applications in compact heat exchangers, cooling of electronics systems and polymeric engineering. The natural convection in square enclosures with differently heated sidewalls, filled with power-law and Bingham fluids in addition with heterogeneous medium and centered block are analyzed in this study. The heterogeneous medium are solid, square, disconnected and conducting blocks. The parameters used are the Rayleigh number in the range 104 - 107 , power index n range of 0, 6 - 1, 6, Bingham number range of 0, 5 - Bimax , being the influence of Prandtl number investigated for each fluid model. The number of blocks for heterogeneous medium are 9, 16, 36 and 64, keeping constant solid to fluid conductive ratio, κ = 1. For enclosures with centered block are used the nondimensional block size from 0, 1 to 0, 9, with solid to fluid conductive ratio in range κ = 0, 1; 1 and 10. Mathematical modeling is done by mass, momentum and energy balance equations. The solution of equations have been numerically solved in ANSYS FLUENT R software. Firstly, numerical solutions for validation with Newtonian fluids in clean enclosures are conducted, followed by enclosures with heterogeneous medium and centered block. Subsequently, numerical solutions of power-law and Bingham fluids with same enclosures configurations are conducted. The results are reported in the form of streamlines, isotherms and average Nusselt number at hot wall. In general, the heat transfer process in enclosure is governed by Rayleigh number, size and thermal conductivity of the blocks, power index n for power-law fluid and Bingham number for Bingham fluid. Both fluid models are very sensitive with Prandtl number changes. Heterogeneous medium decrease heat transfer in enclosure when affects thermal boundary layer for both fluid models. One analytical prediction was made for power-law fluid. An increase in heat transfer occurs with low thermal conductivity block and few interference and with high thermal conductivity block and great interference, for both fluids.

This diploma thesis is focused on introducing the mathematical and physical fundamentals of viskosity, density and refractive index of liquids and methods of its measurement. Based on available literatures specify review of areas in which the measurement of dynamic viscosity is used for evaluation the actual state of liquid materials. Discuss the possibility of using for example variables to determine the concentration of fat in milk and ethanol in alcoholic beverages. The sample of liquid to realize the practical measurements.

This study aims to present an alternative framework with which to view the phenomenon of parental divorce and its perceived consequences for adult children of divorce in committed relationships. Research done within the traditional Newtonian framework is reviewed and its limitations explicated. The epistemological presuppositions of the new epistemology are presented along with their implications for conducting research. The importance of description as research methodology is emphasised. Written descriptions from various adult children of divorce are presented. Metadescriptions, by the author, are presented. These metadescriptions, based on the presuppositions of the new epistemology, highlight the value of describing the patterns of organisation which characterise the committed relationships of adult children of divorce. It is concluded that an alternative approach, based on the new epistemology, enlarges our understanding of the adult child of divorce within the context of a committed relationship. / Psychology / M.A. (Psychology)

This thesis consists of four papers and focuses on function spaces related to first-order analysis in abstract metric measure spaces. The classical (i.e., Sobolev) theory in Euclidean spaces makes use of summability of distributional gradients, whose definition depends on the linear structure of Rn. In metric spaces, we can replace the distributional gradients by (weak) upper gradients that control the functions’ behavior along (almost) all rectifiable curves, which gives rise to the so-called Newtonian spaces. The summability condition, considered in the thesis, is expressed using a general Banach function lattice quasi-norm and so an extensive framework is built. Sobolev-type spaces (mainly based on the Lp norm) on metric spaces, and Newtonian spaces in particular, have been under intensive study since the mid-1990s. In Paper I, the elementary theory of Newtonian spaces based on quasi-Banach function lattices is built up. Standard tools such as moduli of curve families and the Sobolev capacity are developed and applied to study the basic properties of Newtonian functions. Summability of a (weak) upper gradient of a function is shown to guarantee the function’s absolute continuity on almost all curves. Moreover, Newtonian spaces are proven complete in this general setting. Paper II investigates the set of all weak upper gradients of a Newtonian function. In particular, existence of minimal weak upper gradients is established. Validity of Lebesgue’s differentiation theorem for the underlying metric measure space ensures that a family of representation formulae for minimal weak upper gradients can be found. Furthermore, the connection between pointwise and norm convergence of a sequence of Newtonian functions is studied. Smooth functions are frequently used as an approximation of Sobolev functions in analysis of partial differential equations. In fact, Lipschitz continuity, which is (unlike <img src="http://www.diva-portal.org/cgi-bin/mimetex.cgi?%5Cmathcal%7BC%7D%5E1" />-smoothness) well-defined even for functions on metric spaces, often suffices as a regularity condition. Thus, Paper III concentrates on the question when Lipschitz functions provide good approximations of Newtonian functions. As shown in the paper, it suffices that the function lattice quasi-norm is absolutely continuous and a fractional sharp maximal operator satisfies a weak norm estimate, which it does, e.g., in doubling Poincaré spaces if a non-centered maximal operator of Hardy–Littlewood type is locally weakly bounded. Therefore, such a local weak boundedness on rearrangement-invariant spaces is explored as well. Finer qualitative properties of Newtonian functions and the Sobolev capacity get into focus in Paper IV. Under certain hypotheses, Newtonian functions are proven to be quasi-continuous, which yields that the capacity is an outer capacity. Various sufficient conditions for local boundedness and continuity of Newtonian functions are established. Finally, quasi-continuity is applied to discuss density of locally Lipschitz functions in Newtonian spaces on open subsets of doubling Poincaré spaces.

Cette thèse est composée de deux parties indépendantes. La première est consacrée à l'étude de quelques problèmes elliptiques de type de Kirchhoff de la forme suivante : -M(ʃΩNul² dx) Δu = f(x, u) xЄΩ ; u(x) = o xЄƋΩ où Ω cRN, N ≥ 2, f une fonction de Carathéodory et M une fonction strictement positive et continue sur R+. Dans le cas où la fonction f est asymptotiquement linéaire à l’infini par rapport à l'inconnue u, on montre, en combinant une technique de troncature et la méthode variationnelle, que le problème admet au moins une solution positive quand la fonction M est non décroissante. Et si f(x, u) = |u|p-1 u + λg(x), où p >0, λ un paramètre réel et g une fonction de classe C1 et changeant de signe sur Ω, alors sous certaines hypothèses sur M, il existe deux réels positifs λ. et λ. tels que le problème admet des solutions positives si 0 < λ <λ. et n'admet pas de solutions positives si λ > λ.. Dans la deuxième partie, on étudie deux problèmes soulevés en dynamique des fluides. Le premier est une généralisation d'un modèle décrivant la propagation unidirectionnelle dispersive des ondes longues dans un milieu à deux fluides. En écrivant le problème sous la forme d'une équation de point fixe, on montre l'existence d'au moins une solution positive. On montre ensuite sa symétrie et son unicité. Le deuxième problème consiste à prouver l'existence de la vitesse, la pression et la température d'un fluide non newtonien, incompressible et non isotherme, occupant un domaine borné, en prenant en compte un terme de convection. L’originalité dans ce travail est que la viscosité du fluide ne dépend pas seulement de la vitesse mais aussi de la température et du module du tenseur des taux de déformations. En se basant sur la notion des opérateurs pseudo-monotones, le théorème de De Rham et celui de point fixe de Schauder, l'existence du triplet, (vitesse, pression, température) est démontré / This thesis consists of two independent parts. The first is devoted to the study of some elliptic problems of Kirchhoff-type in the following form : -M(ʃΩNul² dx) Δu = f(x, u) xЄΩ ; u(x) = o xЄƋΩ where Ω cRN, N ≥ 2, f is a Caratheodory function and M is a strictly positive and continuous function on R+. In the case where the function f is asymptotically linear at infinity with respect to the unknown u, we show, by combining a truncation technique and the variational method, that the problem admits a positive solution when the function M is nondecreasing. And if f(x, u) = |u|p-1 u + λg(x) where p> 0, λ a real parameter and g is a function of class C1 and changes the sign in Ω, then under some assumptions on M, there exist two positive real λ. and λ. such that the problem admits positive solutions if 0 < λ <λ., and no positive solutions if λ > λ.. In the second part, we study two problems arising in fluid dynamics. The first is a generalization of a model describing the unidirectional propagation of long waves in dispersive medium with two fluids. By writing the problem as a fixed point equation, we prove the existence of at least one positive solution. We then show its symmetry and uniqueness. The second problem is to prove the existence of the velocity, pressure and temperature of a non-Newtonian, incompressible and isothermal fluid, occupying a bounded domain, taking into account a convection term. The originality in this work is that the fluid viscosity depends not only on the velocity but also on the temperature and the modulus of deformation rate tensor. Based on the notion of pseudo-monotone operators, the De Rham theorem and the Schauder fixed point theorem, the existence of the triplet, (velocity, pressure, temperature) is shown

Le chapitre 1 introduit les modèles et donne les principaux résultats obtenus. Dans le chapitre 2, on présente des simulations numériques d'un modèle macroscopique en deux dimensions. La méthode de discrétisation par éléments finis utilisée est décrite. Pour le cas test de l'écoulement autour d'un cylindre, les phénomènes en jeu dans les fluides vieillissants sont observés. Le chapitre 3 concerne l'étude mathématique de la version unidimensionnelle du système d'équations aux dérivées partielles utilisé pour les simulations. On montre que le problème est bien posé et on examine le comportement en temps long de la solution. Dans le dernier chapitre, des équations macroscopiques sont dérivées à partir d'une équation mésoscopique. L'analyse mathématique de cette équation mésoscopique est également menée / This thesis is devoted to the modelling, the mathematical analysis and the simulation of non-Newtonian fluids. Some fluids in an intermediate liquid-solid phase are particularly considered: aging fluids. Modelling scales are macroscopic and mesoscopic. In Chapter 1, we introduce the models and give the main results obtained. In Chapter 2, we present numerical simulations of a macroscopic two-dimensional model. The finite element method used for discretization is described. For the flow past a cylinder test-case, phenomena at play in aging fluids are observed. The Chapter 3 contains a mathematical analysis of the one-dimensional version of the system of partial differential equations used for the simulations. We show well-posedness and investigate the longtime behaviour of the solution. In the last chapter, macroscopic equations are derived from a mesoscopic equation. The mathematical analysis of this mesoscopic equation is also carried out

The author presents some generalized Burgers' equations for incompressible and isothermal flow of viscous non-Newtonian fluids based on the Cross model, the Carreau model, and the Power-Law model and some simple assumptions on the flows. The author numerically solves the traveling wave equations for the Cross model, the Carreau model, the Power-Law model by using industrial data. The author proves existence and uniqueness of solutions to the traveling wave equations of each of the three models. The author also provides numerical estimates of the shock thickness as well as maximum strain $\varepsilon_{11}$ for each of the fluids.

Die vorliegende Arbeit beschreibt eine experimentelle Untersuchung der Schichtbildung von nichtnewtonschen Flüssigkeiten im Tiefdruckverfahren auf nicht saugfähigen Substraten. Das fluiddynamisch bedingte „viscous fingering“ beim Farbspaltungsprozess soll mittels Hydrophobieren der Druckform gehemmt werden. Ziel ist es, möglichst homogene sowie wellenfreie Schichten zu erzeugen. Um ein direkt miteinander vergleichbares Druckergebnis zu erhalten, wird der Druckstoff parallel mit einer unbehandelten und hydrophobierten Form bedruckt. Als Druckstoff werden anstelle von Druckfarbe funktionale Materialien (vorzugsweise PEDOT:PSS) verwendet und variiert, wobei die elektrischen und geometrischen Schichteigenschaften, beispielsweise der elektrische Widerstand und die Rauheit, zur Ermittlung der gesetzten Ziele untersucht wurden. Hiermit und mittels Nutzung einer hydrophobierten Druckform kann eine deutliche Minderung der Wellenbildung (viscous fingering) bei vielen Druckstoffarten beobachtet werden. Die Minderung des viscous fingering im Farbspaltungsprozess und eine nahezu vollständige Leerung der hydrophobierten Tiefdruckform haben einen wesentlichen Nutzwert für den künftigen Einsatz nicht nur für die „gedruckte Elektronik“. / In this work is described experimental research about layer forming from non-Newtonian fluids in gravure printing on non-porous substrates. The viscous fingering, caused through fluid dynamics at splitting of printed material should be decreased by hydrophobic-surface modification of gravure printing form. The aim was to print wave-free homogenous layers. To achieve comparable results, modified and pure form were used simultaneously to print the same material. The printed material was mainly PEDOT:PSS and other, which is used in printed electronics. The properties (surface tension, viscosity) of printed materials were varied by additives. Printing conditions were varied too. The characteristic of printed layers were studied: resistivity, roughness, density, etc. The results shows decreasing of waviness, roughness and viscous fingering in final layer through use of hydrophobic gravure printing form, compared to print results with common printing form. This can be applied not only in the field of printed electronics.

[pt] O presente trabalho apresenta um modelo simplificado baseado na teoria de lubrificação e conceito de viscosidade equivalente para estudar o escoamento dos fluidos de perfuração através de um espaço anular excêntrico com rotação da coluna de perfuração. Em razão do comportamento não Newtoniano destes fluidos, é significativa a influência da rotação da coluna na perda de carga, já que a viscosidade dos fluidos varia com a taxa de deformação imposta. Uma completa análise deste problema requer uma solução tridimensional da equação de conservação de quantidade de movimento de fluidos não Newtonianos, cuja solução é extremamente cara computacionalmente, tornando necessário o desenvolvimento de modelos simplificados que descrevam bem os principais fenômenos observados nestes escoamentos. No modelo proposto, as equações que governam o escoamento são simplificadas pela teoria da lubrificação em coordenadas cilíndricas. Desta forma, o escoamento tridimensional é descrito por uma única equação diferencial bidimensional para o campo de pressão. O comportamento mecânico do fluido é avaliado através do método da Viscosidade Newtoniana Equivalente. O modelo proposto foi validado a partir de soluções numéricas para o modelo completo, disponíveis na literatura, avaliando a precisão das simplificações adotadas. Os resultados mostram o intervalo no qual o modelo simplificado é preciso e apresentam o efeito das propriedades dos fluidos, da geometria do poço e da rotação da coluna na perda de carga do escoamento.O presente trabalho apresenta um modelo simplificado baseado na teoria de lubrificação e conceito de viscosidade equivalente para estudar o escoamento dos fluidos de perfuração através de um espaço anular excêntrico com rotação da coluna de perfuração. Em razão do comportamento não Newtoniano destes fluidos, é significativa a influência da rotação da coluna na perda de carga, já que a viscosidade dos fluidos varia com a taxa de deformação imposta. Uma completa análise deste problema requer uma solução tridimensional da equação de conservação de quantidade de movimento de fluidos não Newtonianos, cuja solução é extremamente cara computacionalmente, tornando necessário o desenvolvimento de modelos simplificados que descrevam bem os principais fenômenos observados nestes escoamentos. No modelo proposto, as equações que governam o escoamento são simplificadas pela teoria da lubrificação em coordenadas cilíndricas. Desta forma, o escoamento tridimensional é descrito por uma única equação diferencial bidimensional para o campo de pressão. O comportamento mecânico do fluido é avaliado através do método da Viscosidade Newtoniana Equivalente. O modelo proposto foi validado a partir de soluções numéricas para o modelo completo, disponíveis na literatura, avaliando a precisão das simplificações adotadas. Os resultados mostram o intervalo no qual o modelo simplificado é preciso e apresentam o efeito das propriedades dos fluidos, da geometria do poço e da rotação da coluna na perda de carga do escoamento.O presente trabalho apresenta um modelo simplificado baseado na teoria de lubrificação e conceito de viscosidade equivalente para estudar o escoamento dos fluidos de perfuração através de um espaço anular excêntrico com rotação da coluna de perfuração. Em razão do comportamento não Newtoniano destes fluidos, é significativa a influência da rotação da coluna na perda de carga, já que a viscosidade dos fluidos varia com a taxa de deformação imposta. Uma completa análise deste problema requer uma solução tridimensional da equação de conservação de quantidade de movimento de fluidos não Newtonianos, cuja solução é extremamente cara computacionalmente, tornando necessário o desenvolvimento de modelos simplificados que descrevam bem os principais fenômenos observados nestes escoamentos. No modelo proposto, as equações que governam o escoamento são simplificadas pela teoria da lubrificação em coordenadas cilíndricas. Desta forma, o escoamento tridimensional é descrito por uma única equação diferencial bidimensional para o campo de pressão. O comportamento mecânico do fluido é avaliado através do método da Viscosidade Newtoniana Equivalente. O modelo proposto foi validado a partir de soluções numéricas para o modelo completo, disponíveis na literatura, avaliando a precisão das simplificações adotadas. Os resultados mostram o intervalo no qual o modelo simplificado é preciso e apresentam o efeito das propriedades dos fluidos, da geometria do poço e da rotação da coluna na perda de carga do escoamento. / [en] In this work a simplified model based on the Lubrication Theory and on the equivalent viscosity is presented to study the drilling fluid flow dynamics through an eccentric annular space with rotation of the drilling column. As a result of the non-Newtonian behavior of the fluid, the rotation of the column has a significant impact on the pressure drop since the viscosity of the fluids is a function of the strain rate applied. A complete analysis of this problem requires a tridimensional solution of the equation of momentum conservation, which makes the solution computationally expensive. For such, simplified accurate models that describe the main phenomena observed have to be developed. On the proposed model, the flow dynamics equations are simplified by the Lubrication Theory in cylindrical coordinates. Therefore, the tridimensional flow is described by one single two dimensional equation for the pressure field. The mechanical behaviour of the fluid is evaluated through the Equivalent Newtonian Viscosity method. The proposed model, as well as the accuracy of the simplifications used, was validated by comparison with numerical solutions of the complete set of equations available on the literature. The results show the range in which the proposed simplified model is accurate and presents the effects of the fluids properties, well geometry and column rotation on the pressure loss.

Cette thèse présente une étude expérimentale du problème de mélange dans les fluides complexes, étude menée en partenariat avec l’entreprise Sanofi Pasteur. Le mélange est un acte des plus fréquents dans la vie courante et aussi dans l’activité industrielle. On trouve dans la littérature de nombreuses études s’intéressant aux cuves de mélange pour en améliorer les performances à partir d’observations faites à grande échelle. Par contre, à notre connaissance, il y a peu de recherche sur l’hydrodynamique du mélange dans les fluides complexes. Dans notre travail, on étudie des fluides non-Newtoniens formés de solutions diluées de polymères caractérisés par leurs propriétés rhéofluidifiante et viscoélastique. Il s’agit de solutions aqueuses de Polyacrylamide (PAA) ou de la gomme de Xanthan (XG). Afin d’identifier la différence de comportement avec les fluides Newtoniens, une étude expérimentale avec de l’eau est effectuée dans les mêmes conditions que celles pour les fluides non-Newtoniens. Cette étude a été menée, en premier, sur un modèle réduit d’une cuve de mélange de Sanofi Pasteur. Les résultats obtenus, non représentés dans ce mémoire de thèse, nous ont amenés à mettre en place une étude fondamentale de l’écoulement dans un mélangeur de géométrie plus simple. Il s’agit alors de pouvoir contrôler les conditions initiales et de s’affranchir des effets secondaires de l’agitation pour ne s’intéresser qu’au mélange. Pour cela, la géométrie retenue est celle d’un mélangeur en T avec deux entrées perpendiculaires. L’exploration en 2D des champs de vitesse et de concentration de scalaire dans cette jonction en T est assurée simultanément aux moyens des techniques optiques (PIV et PLIF). Les observations montrent un effet non négligeable sur l’hydrodynamique et le mélange lié à la présence de polymères dans l’écoulement. De plus, les résultats obtenus permettent de calculer la tension de Reynolds uv et les flux de masse vc et uc. Ils seront utilisés par la suite pour vérifier leur conformité avec le modèle k epsilon couramment utilisé dans l’industrie. / This thesis presents an experimental study of the mixing in complex fluids which is conducted in partnership with Sanofi Pasteur. The mixture is one of the most common act in everyday life and also in industrial activities. We found in the literature many studies focusing on the mixing tanks with objective to improve performance based on observation of large scale. By cons, in our knowledge, there is few or no research on the hydrodynamics of a mixture in complex fluides. In our work, we study non-Newtonian fluids formed of diluted solution of polymer which characterized by their viscoelastic and shear thinning properties. We used in this study aqueous solutions of polyacrylamide (PAA) or xanthan gum (XG). To identify the difference in behavior with Newtonian fluid, an experimental study with water is carried out under the same conditions as those non-Newtonian fluids. At first, this study was on a reduced mixing tank of Sanofi Pasteur. The results, which not shown in this thesis, led us to develop a fundamental study of flow in a mixer with a simple geometry. The objective is to be able to control the initial conditions and to avoid the side effects of agitation to focus on the mixture. For this, we chose a mixer in a T shape with two perpendicular inputs. Exploring 2D velocity and scalar concentration fields in this T-junction is provided simultaneously of optical techniques (PIV and PLIF). Observations show a significant effect on the hydodynamic and mixture related to the presence of polymers in the flow. In addition, results are used to calculate the Reynolds stress uv and the scalar flux vc and uc. They will be used to check their compliance with the k epsilon model that commonly used in industry.