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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
31

Modélisation, simulation et caractérisation de dispositifs TFET pour l'électronique à basse puissance / Modelling, simulation and characterization of tunnel-fet devices for ultra-low power electronics

Revelant, Alberto 15 May 2014 (has links)
Dans les dernières années, beaucoup de travail a été consacré par l’industrie électronique pour réduire la consommation d’énergie des composants micro-électroniques qui représente un fardeau important dans la spécification des nouveaux systèmes.Afin de réduire la consommation d’énergie, nombreuses stratégies peuvent être adoptées au niveau des systèmes micro-électroniques et des simples dispositifs nano-électroniques. Récemmentle Transistor Tunnel `a effet de champ (Tunnel-FET) s’est imposé comme un candidat possible pour remplacer les dispositifs MOSFET conventionnels pour applications de tr`es basse puissance à des tensions d’alimentation VDD < 0.5V. Nous présentons un modèle Multi-Subband Monte Carlo modifié (MSMC) qui a été adapté pour la simulation de TFET Ultra Thin Body Fully Depleted Seminconductor on Insulator (FDSOIUTB) avec homo- et hétéro-jonctions et des matériaux semi-conducteurs arbitraires. Nous prenons en considération la quantification de la charge avec une correction quantique heuristique mais précise, validée via des modèles quantiques complets et des résultats expérimentaux.Le modèle MSMC a été utilisé pour simuler et évaluer la performance de FD-SOI TFET sidéealisées avec homo- et hétéro-jonction en Si, alliages SiGe ou composés InGaAs. Dans la deuxième partie de l’activité de doctorat un travail de caractérisation à basse températurea été réalisé sur les TFETs en Si et SiGe homo- et hétéro-jonction fabriqués par le centre de recherche français du CEA -LETI. L’objectif est d’estimer la présence de l’effet Tunnel comme principal mécanisme d’injection et la contribution d’autres mécanismes d’injection comme le Trap Assisted Tunneling. / In the last years a significant effort has been spent by the microelectronic industry to reducethe chip power consumption of the electronic systems since the latter is becoming a majorlimitation to CMOS technology scaling.Many strategies can be adopted to reduce the power consumption. They range from thesystem to the electron device level. In the last years Tunnel Field Effect Transistors (TFET)have imposed as possible candidate devices for replacing the convential MOSFET in ultra lowpower application at supply voltages VDD < 0.5V. TFET operation is based on a Band-to-BandTunneling (BtBT) mechanism of carrier injection in the channel and they represent a disruptiverevolutionary device concept.This thesis investigates TFET modeling and simulation, a very challenging topic becauseof the difficulties in modeling BtBT accurately. We present a modified Multi Subband MonteCarlo (MSMC) that has been adapted for the simulation of Planar Ultra Thin Body (UTB)Fully Depleted Semiconductor on Insulator (FD-ScOI) homo- and hetero-junction TFET implementedwith arbitrary semiconductor materials. The model accounts for carrier quantizationwith a heuristic but accurate quantum correction validated by means of comparison with fullquantum model and experimental results.The MSMC model has been used to simulate and assess the performance of idealized homoandhetero-junction TFETs implemented in Si, SiGe alloys or InGaAs compounds.In the second part of the thesis we discuss the characterization of TFETs at low temperature.Si and SiGe homo- and hetero-junction TFETs fabricated by CEA-LETI (Grenoble,France) are considered with the objective to identify the possible presence of alternative injectionmechanisms such as Trap Assisted Tunneling. / Negli ultimi anni uno sforzo significativo `e stato speso dall’industria microelettronica per ridurreil consumo di potenza da parte dei sistemi microelettronici. Esso infatti sta diventando unadelle limitazioni pi`u significative per lo scaling geometrico della tecnologia CMOS.Diverse strategie possono essere adottate per ridurre il consumo di potenza considerando ilsistema microelettronico nella sua totalit`a e scendendo fino a giungere all’ottimizzazione delsingolo dispositivo nano-elettronico. Negli ultimi anni il transistore Tunnel FET (TFET) si`e imposto come un possibile candidato per rimpiazzare, in applicazioni a consumo di potenzaestremamente basso con tensioni di alimentazione inferiori a 0.5V, i transistori convenzionaliMOSFET. Il funzionamento del TFET si basa sul meccanismo di iniezione purament quantisticodel Tunneling da banda a banda (BtBT) e che dovrebbe permettere una significativa riduzionedella potenza dissipata. Il BtBT nei dispositivi convenzionali `e un effetto parassita, nel TFETinvece esso `e utilizzato per poter ottenere significativi miglioramenti delle performance sottosogliae pertanto esso rappresenta una nuova concezione di dispositivo molto innovativa erivoluzionaria.Questa tesi analizza la modellizazione e la simulazione del TFET. Questi sono argomenti moltocomplessi vista la difficolt`a che si hanno nel modellare accuratamente il BtBT. In questo lavoroviene presentata una versione modificata del modello di trasporto Multi Subband Monte Carlo(MSMC) adattato per la simulazione di dispositivi TFET planari Ultra Thin Body Fully DepletedSilicon on Insulator (UTB FD-SOI), implementati con un canale composto da un unicosemiconduttore (omogiunzione) o con differenti materiali semiconduttori (eterogiunzione). Ilmodello proposto tiene il conto l’effetto di quantizzazione dovuto al confinamento dei portatoridi carica, con un’euristico ma accurato sistema di correzione. Tale modello `e stato poivalidato tramite una comparazione con altri modelli completamente quantistici e con risultatisperimentali.Superata la fase di validazione il modello MSMC `e utilizzato per simulare e verificare le performancedi dispositivi TFET implementati come omo o eterogiunzione in Silicio, leghe SiGe,o composti semiconduttori InGaAs.Nella seconda parte della tesi viene illustrato un lavoro di caratterizazione di TFET planari abassa temperatura (fino a 77K). Sono stati misurati dispositivi in Si e SiGe a omo o eterogiuzioneprodotti nella camera bianca del centro di ricerca francese CEA-LETI di Grenoble. Tramite talimisure `e stato possibile identificare la probabile presenza di meccanismi di iniezione alternativial BtBT come il Tunneling assistito da trappole (TAT) dimostrando come questo effetto `e,con ogni probabilit`a, la causa delle scarse performance in sottosoglia dei dispositivi TFETsperimentali a temperatura ambiente.
32

[pt] ESTUDO DE COMPLEXOS BINÁRIOS E TERNÁRIOS DE ALUMÍNIO(III) COM AMINOÁCIDOS E LIGANTES FOSFATADOS / [en] STUDY OF BINARY AND TERNARY COMPLEXES OF ALUMINUM(III) WITH AMINO ACIDS AND PHOSPHATE LIGANDS

07 December 2021 (has links)
[pt] Neste trabalho investigou-se a complexação entre o íon alumínio e ligantes como a adenosina 5-trifosfato, a fosfocreatina e aminoácidos pelas técnicas de titulação potenciométrica, espectroscopia Raman e cálculos teóricos em solução aquosa, para conhecer as características dos compostos formados. O estudo visou subsidiar o entendimento dos mecanismos de absorção e biodisponibilidade do alumínio. Tal compreensão poderia auxiliar as pesquisas clínicas relacionadas à prevenção e ao tratamento de doenças neurodegenerativas. O alumínio está presente na água e em vegetais, carnes, laticínios e aditivos alimentares. Soluções de nutrição parenteral, fórmulas infantis e medicamentos podem conter alumínio também. Em fluidos corporais, os nucleosídeos di e trifosfatos e os aminoácidos são bons ligantes para o íon alumínio. Biomoléculas da baixa massa molecular formam complexos que aumentam o pH de precipitação do íon e sua absorção gastrointestinal. Esta pesquisa analisou seis complexos formados com o íon alumínio em solução aquosa. Os compostos binários, tetraaquaadenosina5- trifosfato alumínio(III) e aquafosfocreatina alumínio(III), foram estudados por espectroscopia Raman e cálculos quantomecânicos. As análises dos complexos ternários, adenosina5-trifosfatodiaquacisteína aluminato(III), adenosina5-trifosfatotriaquametionina aluminato(III), aquacisteínafosfocreatina aluminato(III) e aquafosfocreatinametionina aluminato(III), envolveram ainda a potenciometria. Os cálculos computacionais usaram a teoria do funcional de densidade com o funcional híbrido (B3LYP), a base 6-311++G(d,p) e consideraram o efeito do solvente água pelo modelo de contínuo polarizável. Eles englobaram a obtenção de parâmetros geométricos, o cálculo do espectro Raman e a descrição da superfície de contorno do potencial eletrostático e do mapa do potencial eletrostático. No que tange os complexos binários, as análises ratificaram o comportamento bidentado da adenosina 5-trifosfato por um oxigênio do fosfato alfa e um oxigênio do fosfato beta. No complexo formado entre o íon alumínio e a fosfocreatina, o ligante atua como tridentado por um oxigênio do fosfato, um oxigênio do carboxilato e um nitrogênio. Os mapas do potencial eletrostático apontaram a presença de regiões neutras ao redor dos átomos e como as cargas totais das moléculas eram zero, elas devem ser solúveis em lipídios. Nos complexos ternários, os modos de coordenação da adenosina 5-trifosfato e da fosfocreatina adotados nos compostos binários se mantêm. A cisteína se comporta como bidentada por um oxigênio do carboxilato e um nitrogênio. Na espécie adenosina5-trifosfatotriaquametionina aluminato(III), a metionina atua como monodentada pelo oxigênio do carboxilato. A despeito da carga total negativa dos complexos, as moléculas não apresentam um potencial eletrostático tão negativo e possuem uma estrutura estável. Quatro outros sistemas ternários, o alumínio(III):adenosina 5-trifosfato:homocisteína, o alumínio(III):fosfocreatina:homocisteína, o alumínio(III):adenosina 5-trifosfato: penicilamina e o alumínio(III):fosfocreatina:penicilamina, foram examinados apenas por potenciometria. Ela mostrou a ocorrência de várias reações de complexação e diversos complexos são formados de acordo com o pH. Comumente, o alumínio(III) se torna insolúvel entre pH 2,5 a 5,5. Todavia, isso não ocorreu. Os resultados exibiram a variedade do comportamento dos ligantes na complexação com o íon alumínio. As pesquisas sugerem como podem estar formados alguns complexos nos organismos vivos. / [en] This thesis investigated complexation reactions between aluminum(III) and ligands such as adenosine 5-triphosphate, phosphocreatine and amino acids by potentiometry, Raman spectroscopy and theoretical calculations in aqueous solution, with the aim to know the proprieties of formed complexes. The study was important to improve the knowledge about absorption mechanisms and bioavailability of aluminum(III). This learning could help clinical researches about prevention and treatment of neurodegenerative diseases. Aluminum is present in water and in vegetables, animal products and food additives. Parenteral nutrition solutions, infant formulas and medications also contain aluminum. In fluids, di- and triphosphate nucleosides and amino acids are good ligands for aluminum(III). Low molecular mass biomolecules form complexes which increase the pH of precipitation of the metal ion and its gastrointestinal absorption. This study analyzed six complexes with aluminum ions in aqueous solution. The binary compounds tetraaquaadenosine 5-triphosphate aluminum(III) and aquaphosphocreatine aluminum(III) were studied by Raman spectroscopy and quantum mechanical calculations. The analysis of the ternary complexes adenosine5-triphosphatediaquacysteine aluminate(III), adenosine5’- triphosphatetriaquamethionine aluminate(III), aquacysteinephosphocreatine aluminate(III) and aquaphosphocreatinemethionine aluminate(III) also involved potentiometry. Computational calculations used density functional theory with the hybrid functional B3LYP and the 6-311++G(d,p) basis set regarding water solvent effects by the polarizable continuum model. They included the assessment of geometrical parameters, Raman spectrum calculations and the description of electrostatic potential contour surfaces and mapped electrostatic potential. Regarding the binary complexes, analyses confirmed the bidentate behavior of adenosine 5-triphosphate through one oxygen of the phosphate beta and one oxygen of the phosphate gamma. In the complex that formed between aluminum(III) and phosphocreatine, the ligand behaved as a tridentate, coordinated through one oxygen in the phosphate, one oxygen in the carboxylate and one nitrogen in the guanidine group. The electrostatic potential maps pointed out the presence of neutral regions around atoms and, as the total charge of these molecules was zero, they should be soluble in lipids. In the ternary complexes, the coordination modes of adenosine 5-triphosphate and phosphocreatine adopted in binary compounds remained. Cysteine behaved as a bidentate ligand through one carboxylate oxygen and nitrogen. In the adenosine5- triphosphatetriaquamethionine aluminate(III) species, methionine acted as a monodentate ligand via the carboxylate oxygen. Despite the negative net charge of the complexes, they did not exhibit a negative electrostatic potential and had stable structures. The four other ternary systems, aluminum(III):adenosine 5- triphosphate:homocysteine, aluminum(III):phosphocreatine:homocysteine, aluminum(III):adenosine 5-triphosphate:penicillamine and aluminum(III): phosphocreatine:penicillamine, were examined only by potentiometry. The results showed the occurrence of various complexation reactions, and several complexes are formed depending on the pH. Commonly, aluminum(III) becomes insoluble between pH 2.5 to 5.5. However, this did not occur. These results bring to light the multiplicity of ligand behaviors in complexation with aluminum(III). This research also suggests that some complexes may be formed in living organisms.
33

Structural distortions in molecular-based quantum cellular automata: a minimal model based study

Santana Bonilla, Alejandro, Gutierrez, Rafael, Medrano Sandonas, Leonardo, Nozaki, Daijiro, Bramanti, Alessandro Paolo, Cuniberti, Gianaurelio 10 January 2020 (has links)
Molecular-based quantum cellular automata (m-QCA), as an extension of quantum-dot QCAs, offer a novel alternative in which binary information can be encoded in the molecular charge configuration of a cell and propagated via nearest-neighbor Coulombic cell–cell interactions. Appropriate functionality of m-QCAs involves a complex relationship between quantum mechanical effects, such as electron transfer processes within the molecular building blocks, and electrostatic interactions between cells. The influence of structural distortions of single m-QCA are addressed in this paper within a minimal model using an diabatic-to-adiabatic transformation. We show that even small changes of the classical square geometry between driver and target cells, such as those induced by distance variations or shape distortions, can make cells respond to interactions in a far less symmetric fashion, modifying and potentially impairing the expected computational behavior of the m-QCA.
34

New attempts for error reduction in lattice field theory calculations

Volmer, Julia Louisa 23 August 2018 (has links)
Gitter QCD ist ein erfolgreiches Instrument zur nicht-perturbativen Berechnung von QCD Observablen. Die hierfür notwendige Auswertung des QCD Pfadintegrals besteht aus zwei Teilen: Zuerst werden Stützstellen generiert, an denen danach das Pfadintegral ausgewertet wird. In der Regel werden für den ersten Teil Markov-chain Monte Carlo (MCMC) Methoden verwendet, die für die meisten Anwendungen sehr gute Ergebnisse liefern, aber auch Probleme wie eine langsame Fehlerskalierung und das numerische Vorzeichenproblem bergen. Der zweite Teil beinhaltet die Berechnung von Quark zusammenhängenden und unzusammenhängenden Diagrammen. Letztere tragen maßgeblich zu physikalischen Observablen bei, jedoch leidet deren Berechnung an großen Fehlerabschätzungen. In dieser Arbeit werden Methoden präsentiert, um die beschriebenen Schwierigkeiten in beiden Auswertungsteilen des QCD Pfadintegrals anzugehen und somit Observablen effizienter beziehungsweise genauer abschätzen zu können. Für die Berechnung der unzusammenhängenden Diagramme haben wir die Methode der exakten Eigenmodenrekonstruktion mit Deflation getestet und konnten eine 5.5 fache Verbesserung der Laufzeit erreichen. Um die Probleme von MCMC Methoden zu adressieren haben wir die rekursive numerische Integration zur Vereinfachung von Integralauswertungen getestet. Wir haben diese Methode, kominiert mit einer Gauß-Quadraturregel, auf den eindimensionalen quantenmechanischen Rotor angewandt und konnten exponentiell skalierende Fehlerabschätzungen erreichen. Der nächste Schritt ist eine Verallgemeinerung zu höheren Raumzeit Dimensionen. Außerdem haben wir symmetrisierte Quadraturregeln entwickelt, um das Vorzeichenproblem zu umgehen. Wir haben diese Regeln auf die eindimensionale QCD mit chemischem Potential angewandt und konnten zeigen, dass sie das Vorzeichenproblem beseitigen und sehr effizient auf Modelle mit einer Variablen angewendet werden können. Zukünftig kann die Effizienz für mehr Variablen verbessert werden. / Lattice QCD is a very successful tool to compute QCD observables non-perturbatively from first principles. The therefore needed evaluation of the QCD path integral consists of two parts: first, sampling points are generated at which second, the path integral is evaluated. The first part is typically achieved by Markov-chain Monte Carlo (MCMC) methods which work very well for most applications but also have some issues as their slow error scaling and the numerical sign-problem. The second part includes the computation of quark connected and disconnected diagrams. Improvements of the signal-to-noise ratio have to be found since the disconnected diagrams, though their estimation being very noisy, contribute significantly to physical observables. Methods are proposed to overcome the aforementioned difficulties in both parts of the evaluation of the lattice QCD path integral and therefore to estimate observables more efficiently and more accurately. For the computation of quark disconnected diagrams we tested the exact eigenmode reconstruction with deflation method and found that this method resulted in a 5.5-fold reduction of runtime. To address the difficulties of MCMC methods, we tested the recursive numerical integration method, which simplifies the evaluation of the integral. We applied the method in combination with a Gauss quadrature rule to the one-dimensional quantum-mechanical rotor and found that we can compute error estimates that scale exponentially to the correct result. A generalization to higher space-time dimensions can be done in the future. Additionally, we developed the symmetrized quadrature rules to address the sign-problem. We applied them to the one-dimensional QCD with a chemical potential and found that this method is capable of overcoming the sign-problem completely and is very efficient for models with one variable. Improvements of the efficiency for multi-variable scenarios can be made in the future.
35

Raman spectroscopic study and dynamic properties of chalcogenide glasses and liquids / Φασματοσκοπική μελέτη Raman και δυναμικές ιδιότητες χαλκογονούχων υάλων και υγρών

Kostadinova, Ofeliya 19 January 2011 (has links)
Chalcogenide glasses (ChGs) are produced by alloying together a “chalcogen” element” (S, Se or Te) with other elements, generally from group V (Sb, As) or group IV (Ge, Si) to form covalently bonded solids. A variety of stable non-crystalline materials can be prepared in bulk, fiber, and thin film forms using melt-quenching, vacuum deposition, and other less common techniques. Being amorphous semiconductors, ChGs exhibit a variety of photo-induced phenomena when irradiated with proper light and therefore find a wide range of technological applications (optical data storage, telecommunications, IR optics, etc). As research in this field is strongly driven by the needs of high-tech industry, physical properties related to the applications are more systematically investigated than the atomic structure, which is ultimately related to the macroscopic properties. A shortcoming of not having yet established microstructure-properties relations in ChGs is the lack of a strategic design of new materials for specific applications. The present study is a systematic investigation of properties for various families of ChGs using experimental techniques that probe structure (near infrared Raman scattering, x-ray and neutron diffraction, EXAFS), dynamics (IR-Photon correlation spectroscopy), thermal properties (differential scanning calorimetry) and glass morphology (scanning electron microscopy). Particular emphasis is given on binary and pseudo-ternary ChGs, which are the basis of more complex multi-component glasses, such as As-Se, Sb-Se, As-Te, Ge-S, Ge-S-AgI, As-Se-AgI, As-Se-Ag, As-S-AgI, As-S-Ag etc. over a wide glass composition range. The binary systems are known for their significant optical properties while the Ag-doped glasses belong to the class of superionic conductors. Although some of these glass-forming systems have been extensively studied in the literature, several details concerning the atomic arrangement are still not fully understood, partly due to that some of these glasses are phase separated at the microscale; a fact that is usually overlooked in related studies. In the present study, using high-resolution off-resonant Raman conditions and a more elaborate analysis of the Raman spectra, in conjunction with thermal and morphological data, we have been able to obtain a better understanding of atomic structure and to advance structure-properties relations for both the homogeneous and phase separated glasses. / Μια κατηγορία υαλωδών υλικών, γνωστή ως χαλκογονούχες ύαλοι αρχίζει να κερδίζει σημαντικό έδαφος στον τομέα των εφαρμογών λόγω των φωτονικών ιδιοτήτων που διαθέτουν. Ως χαλκογονούχες ύαλοι θεωρούνται οι υαλώδεις ενώσεις στις οποίες ένα τουλάχιστον περιέχει ένα από τα στοιχεία χαλκογόνων S, Se, και Te. Η ανάμιξη των στοιχείων αυτών με στοιχεία όπως Sb, As, Ge, Si, κλ.π. οδηγεί στο σχηματισμό σταθερών ομοιοπολικών υαλωδών ενώσεων. Το γεγονός ότι οι χαλκογονούχες ύαλοι είναι άμορφοι ημιαγωγοί έχει ως αποτέλεσμα την εμφάνιση πλήθους φωτο-επαγόμενων φαινομένων όταν οι ενώσεις αυτές ακτινοβοληθούν με φως κατάλληλου μήκους κύματος (συγκρίσιμο με το ενεργειακό τους χάσμα). Οι φωτο-επαγόμενες αλλαγές απορρέουν από τις αλλαγές οι οποίες επέρχονται στην ατομική δομή του υλικού (φωτο-δομικές αλλαγές). Τα φωτο-επαγόμενα φαινόμενα είναι εκμεταλλεύσιμα σε πλήθος τεχνολογικών εφαρμογών, για παράδειγμα στην οπτική αποθήκευση πληροφορίας (DVD), σε οπτικά που λειτουργούν στο υπέρυθρο, στις τηλεπικοινωνίες κλπ. Καθώς η έρευνα πάνω στο εν λόγω επιστημονικό πεδίο καθορίζεται σε μεγάλο βαθμό από τις ανάγκες για βιώσιμες τεχνολογικές εφαρμογές, οι φυσικές ιδιότητες, οι οποίες σχετίζονται άμεσα με τις εφαρμογές, έχουν μελετηθεί εντατικότερα και πιο συστηματικά από την ατομική δομή η οποία είναι κατά βάση υπεύθυνη για τα φωτο-επαγόμενα φαινόμενα. Αυτό έχει ως μειονέκτημα την απουσία συσχετισμών μεταξύ μικροσκοπικών και μακροσκοπικών ιδιοτήτων με αποτέλεσμα την απουσία στρατηγικού σχεδιασμού νέων λειτουργικών υλικών με τις επιθυμητές ιδιότητες. Η παρούσα διατριβή περιλαμβάνει μια συστηματική μελέτη διαφόρων οικογενειών χαλκογονούχων υάλων με τη χρήση πειραματικών τεχνικών οι οποίες διερευνούν την ατομική δομή (σκέδαση Raman, περίθλαση ακτίνων-X και νετρονίων, EXAFS), τις θερμικές ιδιότητες (διαφορική θερμιδομετρία σάρωσης) και την μορφολογία των υάλων (ηλεκτρονική μικροσκοπία σάρωσης). Ιδιαίτερη έμφαση δόθηκε σε δυαδικά και ψευδο-δυαδικά συστήματα χαλκογονούχων υάλων τα οποία συμπεριλαμβάνουν As-Se, Sb-Se, As-Te, Ge-S, Ge-S-AgI, As-Se-AgI, As-Se-Ag, As-S-AgI, As-S-Ag κλπ. για μεγάλο εύρος συστάσεων της κάθε οικογένειας. Τα δυαδικά συστήματα είναι γνωστά για τις εξαίρετες οπτικές τους ιδιότητες ενώ οι ύαλοι με προσμίξεις Αργύρου ανήκουν στην κατηγορία των υπεριοντικών υάλων με αρκετά υψηλές ιοντικές αγωγιμότητες που χαρακτηρίζονται από μικροσκοπικό διαχωρισμό φάσεων σε συγκεκριμένες συγκεντρώσεις του Αργύρου. Παρά το γεγονός ότι ορισμένα από τα προαναφερθέντα άμορφα υλικά έχουν κατ’ επανάληψη μελετηθεί στο παρελθόν, ακριβείς πληροφορίες σχετικά με την ατομική δομή τους δεν είναι διαθέσιμες, εν μέρει εξ’ αιτίας της ελλιπούς πειραματικής προσέγγισης και εν μέρει λόγω του μικροσκοπικού διαχωρισμού φάσεων που χαρακτηρίζει τις υάλους με πρόσμιξη Αργύρου, γεγονός το οποίο συχνά αμελείται σε προγενέστερες μελέτες. Στην παρούσα διατριβή, χρησιμοποιώντας τη φασματοσκοπία σκέδασης Raman υψηλής ανάλυσης και μακριά από συνθήκες συντονισμού, σε συνδυασμό με θερμικά και μορφολογικά δεδομένα των υάλων, κατέστη δυνατό να αποκτηθεί μια πιο σφαιρική γνώσης σχετικά με την ατομικής κλίμακας δομή των υάλων και να προαχθούν συσχετισμοί δομής-ιδιοτήτων τόσο για ομοιογενή όσο και για ανομοιογενείς υάλους.
36

Ανάπτυξη μοντέλου πρωτονιακής αγωγιμότητας στηριζόμενο στο κβαντομηχανικό φαινόμενο σήραγγος και διερεύνηση του φαινομένου της ηλεκτροχημικής ενίσχυσης της κατάλυσης σε αντιδραστήρες κελιού καυσίμου υψηλών και χαμηλών θερμοκρασιών

Τσαμπάς, Μιχαήλ 09 March 2011 (has links)
Στην παρούσα διατριβή αναπτύχθηκε ένα μοντέλο βασιζόμενο σε πρώτες αρχές με σκοπό την περιγραφή και την πρόβλεψη της πρωτονιακής αγωγιμότητας των πλήρως ενυδατωμένων μεμβρανών Nafion (το κυριότερο υλικό που χρησιμοποιείται ως ηλεκτρολύτης στις κυψέλες καυσίμου τύπου PEM) και των ιδιαίτερων χαρακτηριστικών αυτής, όπως τη γραμμική εξάρτηση από το πάχος της μεμβράνης, το δυναμικό του κελιού και τη μερική πίεση του υδρογόνου. Το μοντέλο εστιάζει στη μετανάστευση των πρωτονίων που είναι συνδεδεμένα στις σουλφονομάδες και χρησιμοποιεί την κατανομή φορτίου Poisson-Boltzmann γύρω από κάθε πρωτόνιο, σε συνδυασμό με την εξίσωση Gamow, που δίνει την πιθανότητα να συμβεί το φαινόμενο σήραγγος σε παραβολικό φράγμα δυναμικού. Προτείνεται ότι το μήκος που διανύεται κατά την πραγματοποίηση του φαινομένου σήραγγος ισούται με το μήκος κύματος του πρωτονίου και ότι κάθε πρωτόνιο περιβάλλεται από το νέφος Debye-Hückel. Το μοντέλο, που δεν εμπεριέχει προσαρμόσιμες παραμέτρους, λύνεται αναλυτικά και οι προβλέψεις του είναι σε ημιποσοτική συμφωνία με το πείραμα. Στις προβλέψεις αυτές συμπεριλαμβάνεται η τάξη μεγέθους της αγωγιμότητας, η γραμμική εξάρτηση της αγωγιμότητας με το πάχος της μεμβράνης, η εκθετική εξάρτηση από το δυναμικό και η ισχυρή εξάρτηση με τη μερική πίεση του υδρογόνου. Μελετήθηκε η κινητική, οι ταλαντώσεις και η ηλεκτροχημική ενίσχυση της οξείδωσης του CO σε καταλυτικό υμένιο Pt εναποτεθειμένο σε YSZ, χρησιμοποιώντας ως βάση την απόλυτη κλίμακα του ηλεκτροδίου του οξυγόνου. Βρέθηκε ότι η ηλεκτροχημική ενίσχυση είναι μικρή (ρ<3, Λ~300) όταν οι τιμές του δυναμικού του καταλύτη, UWR, είναι ανάμεσα σε 0.2 και 0.4 V και πολύ σημαντική (ρ~9, Λ~1500) όταν το UWR υπερβαίνει την τιμή 0.4 V. Η απότομη αλλαγή που παρατηρείται κατά την μετάβαση στην έντονη ηλεκτροχημική ενίσχυση συνοδεύεται και από απότομη αλλαγή στην κινητική της αντίδρασης και στο δυναμικό του καταλύτη. Μέσω της σύγκρισης των πειραματικών αποτελεσμάτων του κεφαλαίου και ανεξάρτητων μετρήσεων του έργου εξόδου μεταβάλλοντας το δυναμικό του καταλύτη για το ίδιο σύστημα, βρέθηκε ότι η μετάβαση οφείλεται στην έντονη μετανάστευση προωθητικών ειδών, Ο2-, από τη YSZ στην επιφάνεια του καταλύτη και την συνεπαγόμενη δημιουργία μιας πυκνής αποτελεσματικής διπλοστιβάδας στη διεπιφάνεια του καταλύτη με τα αέρια αντιδρώντα. Τέλος εξετάστηκε μια τροποποιημένη κυψέλη καυσίμου τύπου PEM η οποία λειτουργεί σε συνθήκες δηλητηρίασης από CO κατά την τριοδική λειτουργία. Στο τριοδικό κελί καυσίμου τύπου PEM εκτός της ανόδου και της καθόδου εισάγεται ένα τρίτο ηλεκτρόδιο το οποίο δημιουργεί ένα επιπλέον βοηθητικό κύκλωμα το οποίο λειτουργεί με ηλεκτρολυτικά ρεύματα και επιτρέπει τη λειτουργία της κυψέλης σε δυναμικά μεταξύ της ανόδου και της καθόδου ανέφικτα κατά τη συμβατική λειτουργία. Βρέθηκε ότι είναι δυνατό να ενισχυθεί η συνολική θερμοδυναμική ενεργειακή απόδοση όταν χρησιμοποιείται ως καύσιμο μίγμα αναμόρφωσης μεθανόλης που αντιστοιχεί σε συνθήκες έντονης δηλητηρίασης από CO. / In the present work a first principles model was developed to describe and predict the protonic conductivity of fully hydrated Nafion membranes and its peculiar non-linear dependence on membrane thickness, potential and PH2. The model focuses on the surface migration of protons between adjacent sulfonate groups and utilizes the Poisson-Boltzmann charge distribution around each proton combined with the basic Gamow equation of quantum mechanics for proton tunneling, for parabolic potential barrier. It was shown that the proton tunneling distance equals the proton wavelength and that each proton surrounded by its Debye-Hückel cloud behaves as a leaking nanobattery. The model, which contains no adjustable parameters, is solved analytically and its predictions are in semiquantitative agreement with experiment, including the magnitude of the conductivity, its linear increase with membrane thickness, its exponential increase with potential and its strong dependence on partial pressure of hydrogen. Moreover it was investigated the kinetics, rate oscillations and electrochemical promotion of CO oxidation on Pt deposited on YSZ using a standard oxygen reference electrode. It was found that electropromotion is small (ρ<3) when the catalyst potential UWR, is between 0.2 and 0.4V and very pronounced (ρ~9, Λ~1500) when UWR exceeds 0.4V. This sharp transition in the electropromotion behavior is accompanied by an abrupt change in reaction kinetics and in catalyst potential. It was shown via comparison with independent catalyst potential–catalyst work function measurements that the transition corresponds to the onset of extensive O2- spillover from YSZ onto the catalyst surface, and concomitant establishment of an effective double layer at the catalyst-gas interface, which is the cause of the highly active electropromoted state Furthermore it was studied a modified PEM fuel cell running in CO poisoning conditions by the triode operation. In addition to the anode and cathode, the triode PEM fuel cell introduces a third electrode together with an auxiliary circuit which is run in the electrolytic mode and permits fuel cell operation under previously inaccessible anode-cathode potential differences. It was found that it is possible to enhance the overall thermodynamic efficiency when it is used a methanol reformate mixture as a fuel, which corresponds to intense CO poisoning conditions.
37

Μελέτη της ρόφησης υδατικών συμπλόκων του νικελίου στην επιφάνεια του οξειδίου του τιτανίου

Σταυρόπουλος, Ιωάννης 15 February 2012 (has links)
Βασικός στόχος της παρούσας διατριβής είναι η αποσαφήνιση του τρόπου της διεπιφανειακής εναπόθεσης του νικελίου στην επιφάνεια της τιτάνιας, η οποία λαμβάνει χώρα στη διεπιφάνεια “τιτάνιας / ηλεκτρολυτικού διαλύματος”. Ο στόχος αυτός επιτεύχθηκε μέσω μιας κατάλληλης θεωρητικής και υπολογιστικής επεξεργασίας δεδομένων, που προέρχονται από την εφαρμογή ηλεκτροχημικών και φασματοσκοπικών τεχνικών, την εκτέλεση πειραμάτων προσρόφησης, καθώς επίσης και σε ab – initio υπολογισμούς για την εξακρίβωση της δομής των συμπλόκων εσωτερικής σφαίρας τα οποία σχηματίζονται και των συγκεντρώσεών τους στη διεπιφάνεια. Δείγματα βιομηχανικής τιτάνιας (Degussa, P 25) πλούσιας σε ανατάση χρησιμοποιήθηκαν για το σκοπό αυτό. Η μελέτη πραγματοποιήθηκε για μια ευρεία περιοχή παραμέτρων εμποτισμού και πιο συγκεκριμένα τιμές pH, ιονικής ισχύος και συγκέντρωσης του υδατικού συμπλόκου [Ni(H2O)6]2+ στο διάλυμα. Μεταβάλλοντας τις παραμέτρους αυτές ρυθμίστηκε η επιφανειακή συγκέντρωση των ιόντων Ni(II). Χρησιμοποιήθηκε μια πληθώρα μεθοδολογιών στηριγμένες σε δεδομένα εναπόθεσης, μετρήσεις τιμών pH, ποτενσιομετρικές τιτλοδοτήσεις μάζας και πειράματα μικροηλεκτροφόρησης σε συνδυασμό με φασματοσκοπία διάχυτης ανάκλασης (DRS). Ο συνδυασμός όλων των παραπάνω φαίνεται πως υποδεικνύει το σχηματισμό μονοπυρηνικών / ολιγοπυρηνικών συμπλόκων εσωτερικής σφαίρας κατά την εναπόθεση των ιόντων [Ni(H2O)6]2+ στη διεπιφάνεια “τιτάνιας / ηλεκτρολυτικού διαλύματος”. Η μοντελοποίηση της διαδικασίας εναπόθεσης η οποία βασίστηκε στα προαναφερθέντα πειραματικά αποτελέσματα, αποκάλυψε την ακριβή δομή αυτών των επιφανειακών συμπλόκων και κατέστησε δυνατό τον προσδιορισμό της κατανομής των εναποτιθέμενων ειδών και ειδικότερα των σχετικών τους συγκεντρώσεων για διάφορες τιμές της επιφανειακής συγκέντρωσης Ni(II). Στο συμπαγές τμήμα της διεπιφάνειας “τιτάνιας / ηλεκτρολυτικού διαλύματος” σχηματίζονται τρία μονοπυρηνικά σύμπλοκα εσωτερικής σφαίρας: ένα μονο - υποκατεστημένο, δι - υδρολυμένο σύμπλοκο πάνω από τις ακραίες οξο - ομάδες ανταλλάσοντας ένα υδατικό υποκαταστάτη με ένα επιφανειακό άτομο οξυγόνου (διαμόρφωση TiO), ένα δι - υποκατεστημένο, δι - υδρολυμένο σύμπλοκο πάνω από δύο ακραίες γειτονικές οξο - ομάδες ανταλλάσοντας δύο υδατικούς υποκαταστάτες με δύο επιφανειακά άτομα οξυγόνου (διαμόρφωση TiO - TiO) και ένα δι - υποκατεστημένο μη υδρολυμένο σύμπλοκο πάνω από μία ακραία και μία γεφυρωμένη οξο - ομάδα (διαμόρφωση Ti2O - TiO). Επιπρόσθετα, σχηματίζονται ένα διπυρηνικό και ένα τριπυρηνικό σύμπλοκο εσωτερικής σφαίρας κατά την εναπόθεση των ιόντων [Ni(H2O)6]2+ στο συμπαγές τμήμα της διεπιφάνειας “τιτάνιας / ηλεκτρολυτικού διαλύματος”. Στην πρώτη περίπτωση η θέση υποδοχής συμπεριλαμβάνει μία γεφυρωμένη και δύο ακραίες οξο - ομάδες (διαμόρφωση Ti2O-TiO—TiO), ενώ στη δεύτερη περίπτωση δύο γεφυρωμένες και τρεις ακραίες οξο - ομάδες (διαμόρφωση Ti2O-TiO—TiO—TiO-Ti2O). Η διαμόρφωση TiO κυριαρχεί σε όλο το εύρος της περιοχής επιφανειακών συγκεντρώσεων το οποίο μελετήθηκε. Η συνεισφορά των διαμορφώσεων TiO - TiO και Ti2O - TiO είναι επίσης σημαντική σε πολύ χαμηλές τιμές επιφανειακής συγκέντρωσης Ni(II), μειώνεται όμως σε μεγάλο βαθμό καθώς αυτή αυξάνεται. Οι σχετικές επιφανειακές συγκεντρώσεις των διαμορφώσεων Ti2O-TiO--TiO και Ti2O-TiO—TiO--TiO-Ti2O αρχικά αυξάνουν με την επιφανειακή συγκέντρωση Ni(II) και μετά μένουν πρακτικά σταθερές. Η προαναφερθείσα κατανομή των εναποτιθέμενων ειδών στη διεπιφάνεια εξηγήθηκε με τη χρήση στερεοχημικών όρων. Επιπρόσθετα, η δομή των επιφανειακών συμπλόκων εσωτερικής σφαίρας και η κατανομή αυτή είναι σε γενική συμφωνία με εκείνες οι οποίες προβλέφθηκαν με την εκτέλεση ημιεμπειρικών κβαντομηχανικών υπολογισμών για την εναπόθεση του Ni στο TiO2. Το μοντέλο εναπόθεσης το οποίο αναπτύχθηκε περιέγραψε πολύ καλά τις adsorption edges, τις τιτλοδοτήσεις “πρωτονίου - ιόντος” και τις ισόθερμες εναπόθεσης, ενισχύοντας επιπλέον την αξιοπιστία και ορθότητά του. / The main goal of this work is the elucidation of the mode of interfacial deposition of nickel on the surface of titania, which takes place in the “titania / electrolytic solution” interface. This goal was achieved through the use of several methodologies combined with spectroscopic techniques, as well as ab – initio calculations in order to determine the structure of the inner sphere complexes formed as well as their relative interfacial concentrations. Samples of titania (Degussa, P 25) rich in anatase were used for this purpose. The study was performed over a quite wide range of impregnation parameters namely pH, ionic strength and concentration of the [Ni(H2O)6]2+ aqua complex in the solution. By changing these parameters, the Ni(II) surface concentration was regulated. Several methodologies based on deposition data, pH measurements, potentiometric mass titrations and microelectrophoresis have been used in conjunction with diffuse reflectance spectroscopy. These suggested the formation of mono - nuclear / oligo - nuclear inner sphere complexes upon deposition of the [Ni(H2O)6]+2 ions at the “titania / electrolytic solution” interface. The modelling of the deposition process based on the aforementioned experimental results revealed the exact structure of these surface complexes and allowed the determination of their relative concentrations at various values of Ni(II) surface concentration (interfacial speciation). Three mono-nuclear inner sphere complexes are formed at the compact layer of the “titania / electolytic solution” interface; one mono - substituted, di - hydrolyzed complex above the terminal oxo - groups by exchanging one water ligand with a surface oxygen atom (TiO configuration), a di - substituted, di - hydrolyzed complex above two terminal adjacent oxo - groups by exchanging two water ligands with the two surface oxygen atoms (TiO-TiO configuration) and one di - substituted, non - hydrolyzed complex above one terminal and one bridging adjacent oxo - groups ( Ti2O-TiO configuration). One binuclear and one three - nuclear complex are formed, in addition, at the compact layer. In the first case the receptor site involves one bridging and two terminal oxo- groups (Ti2O-TiO--TiO configuration) whereas in the second case the receptor site involves two bridging and three terminal oxo - groups (Ti2O-TiO--TiO--TiO-Ti2O configuration). The TiO configuration predominates in the whole range of the surface concentration studied. The contribution of the TiO-TiO and Ti2O-TiO configurations is also important at very low Ni(II) surface concentration, but this contribution is rapidly decreased as the Ni(II) surface concentration increases. The relative surface concentrations of the Ti2O-TiO--TiO and Ti2O-TiO--TiO--TiO-Ti2O configurations initially increase with the Ni(II) surface concentration and then remain practically constant. The aforementioned interfacial speciation was explained in stereochemical terms. Moreover, the structure of the inner sphere surface complexes and the interfacial speciation are in general agreement with those predicted by performing semi-empirical quantum chemical calculations of the deposition process. The deposition model developed has described the ‘adsorption edges’, the ‘proton–ion titration curves’ and the deposition isotherms well, further corroborating its validity.
38

Electron Filed Emission Studies of Nanostructured Carbon Materials

Ivaturi, Sameera January 2012 (has links) (PDF)
Field emission is the emission of electrons from a solid under an intense electric field, of the order of 109 V/m. Emission occurs by the quantum mechanical tunneling of electrons through a potential barrier to vacuum. Field emission sources offer several attractive features such as instantaneous response to field variation, resistance to temperature fluctuation and radiation, a high degree of focusing ability in electron optics, good on/off ratio, ballistic transport, and a nonlinear current-voltage relationship. Carbon nanotubes (CNTs) are potential candidates as field emitters since they possess high aspect ratio and are chemically inert to poisoning, and physically inert to sputtering during field emission. They can carry a very high current density and do not suffer field-induced tip sharpening like metallic tips. In addition, the CNT field emitters have the advantage of charge transport through 1D channels and electron emission at the sharp tips due to large enhancement. But the injection of electrons from the back contact remains a technical challenge which requires binding of CNT emitters to metallic substrate. Also, detachment of the CNT from the substrate tends to occur with time. The electrically conducting mixtures of CNTs and polymer can provide an alternative route to address these issues in the field emission of CNTs. The composites can be casted on any substrate in desired shape and the polymer matrix provides necessary support. The research work reported in this thesis includes the preparation of high quality multiwall carbon nanotubes (MWCNTs), MWCNT-polystyrene (PS) composites, and experimental investigation on field emission properties of MWCNT¬PS composites in two different configurations. Electrical conductivity and percolation threshold of the MWCNT-PS composites are also investigated to ensure their high quality prior to the field emission studies. The study has been further extended to reduced graphene oxide (rGO) coated on polymer substrate. The main results obtained in present work are briefly summarized below. This thesis contains eight chapters. Chapter 1 provides an overview of basics of field emission, and the potential of CNT and CNT-polymer composites as field emitters. Chapter 2 deals with the concise introduction of various structural characterization tools and experimental techniques employed in this study. Chapter 3 describes the synthesis of MWCNTs and characterization by using electron microscopy and Raman spectroscopy. MWCNTs are synthesized by chemical vapor deposition (CVD) of toluene [(C6H5) CH3] and ferrocene [(C5H5)2 Fe] mixture at 980 °C. Here toluene acts as carbon source material and ferrocene provides catalytic iron (Fe) particles. The MWCNT formation is based on the thermal decomposition of the precursor mixture. Scanning electron microscopy (SEM) characterization shows that the MWCNTs are closely packed and quite aligned in one direction. The average length of MWCNTs is about 200 μm and outer diameter lies in the range of 50-80 nm. The high quality of as-prepared MWCNT sample is confirmed by Raman spectroscopy. The as-grown MWCNTs are encapsulated with catalytic Fe nanoparticles, revealed by transmission electron microscopy. The Fe nanoparticles trapped within the MWCNT serve as fantastic system for studying the magnetic properties. Three types of MWCNT samples filled with Fe nanoparticles of different aspect ratio (~10, 5 and 2) are synthesized by varying the amount of ferrocene in the precursor material, and their magnetic properties are investigated. Enhanced values of coercivity (Hc) are observed for all samples, Hc being maximum (~2.6 kOe) at 10 K. The enhancement in Hc values is attributed to the strong shape anisotropy of Fe nanoparticles and significant dipolar interactions between Fe nanoparticles. Chapter 4 deals with the field emission studies of MWCNT-PS composites in the parallel configuration. By incorporating as-prepared MWCNTs in PS matrix in a specific ratio, composites with varying loading from 0.01-0.45 weight (wt.) fraction are prepared using solution mixing and casting. High degree of dispersion of MWCNTs in PS matrix without employing any surfactant is achieved by ultrasonication. Low percolation threshold (~0.0025 wt. fraction) in the MWCNT-PS composites ensures the good connectivity of filler in the fabricated samples. Field emission of MWCNT¬PS composites is studied in two different configurations: along the top surface of the film (parallel configuration) and along the cross section of the sample (perpendicular configuration). In this chapter field emission results of the MWCNT-PS composites in parallel configuration are presented. The effect of charge transport in limiting the field emission of MWCNT-PS composite is discussed. Field emission results of MWCNT-PS composites in parallel configuration indicate that the emission performance can be maximized at moderate wt. fraction of MWCNT (0.15). The obtained current densities are ~10 µA/cm2 in the parallel configuration. Chapter 5 presents the study of field emission characteristics of MWCNT¬PS composites of various wt. fractions in the perpendicular configuration. Till date most studies using nanotube composites tend to have the nanotubes lying in two dimensional plane, perpendicular to the applied electric field. In the perpendicular configuration, the nanotubes are nearly aligned parallel to the direction of the applied electric field which results in high field enhancement, and electron emission at lower applied fields. SEM micrographs in cross-sectional view reveal that MWCNTs are homogeneously distributed across the thickness and the density of protruding tubes can be scaled with wt. fraction of the composite film. Field emission from composites has been observed to vary considerably with density of MWCNTs in the polymer matrix. High emission current density of 100 mA/cm2 is achieved at a field of 2.2 V/µm for 0.15 wt. fraction. The field emission is observed to follow the Fowler– Nordheim tunneling mechanism, however, electrostatic screening plays a role in limiting the current density at higher wt. fractions. Chapter 6 highlights the field emission response of rGO coated on a flexible PS film. Field emission of rGO coated PS film along the cross section of the sample is studied in addition to the top film surface of the film. The effect of geometry on the improved field emission efficiency of rGO coated polymer film is demonstrated. The emission characteristics are analyzed by Fowler–Nordheim tunneling for field emission. Low turn-on field (~0.6 V/µm) and high emission current (~200 mA/cm2) in the perpendicular configuration ensure that rGO can be a potential field emitter. Furthermore, stability and repeatability of the field emission characteristics are also presented. Chapter 7 deals with the synthesis, characterization, and field emission of two different kinds of hybrid materials: (1) MWCNT coated with zinc oxide (ZnO) nanoparticles (2) ZnO/graphitic carbon (g-C) core-shell nanowires. The field emission from the bucky paper is improved by anchoring ZnO nanoparticles on the surface of MWCNT. A shift in turn on field from 3.5 V/µm (bucky paper) to 1.0 V/µm is observed by increasing the ZnO nanoparticle loading on the surface of MWCNT with an increase in enhancement factor from 1921 to 4894. Field emission properties of a new type of field emitter ZnO/g-C core-shell nanowires are also presented in this chapter. ZnO/g-C core/shell nanowires are synthesized by CVD of zinc acetate at 1300 °C. Overcoming the problems of ZnO nanowire field emitters, which in general possess high turn on fields and low current densities, the core-shell nanowires exhibit excellent field emission performance with low turn on field of 2.75 V/µm and high current density of 1 mA/cm2. Chapter 8 presents a brief summary of the important results and future perspectives of the work reported in the thesis.
39

THE EFFECT OF MOLECULAR DESIGN ON SPIN DENSITY LOCALIZATION AND RADICAL-INITIATED DEGRADATION OF CONJUGATED RADICAL CATIONS

Kaelon Athena Jenkins (16613448) 19 July 2023 (has links)
<p> Radical species are essential in modern chemistry. In addition to fundamental chemistry, their unique chemical bonding and distinct physicochemical features serve critical functions in materials science in the form of organic electronics. Due to their high reactivity, radicals of the main group element are often transient. In recent years, remarkably stable radicals are often stabilized by π-delocalization, sterically demanding side groups, carbenes, and weakly coordinating anions. The impacts of modifications such as electron-donating, electron-withdrawing, and end-capping on the spin density distribution and thermodynamic and kinetic stability of archetypal radical-driven processes such as dimerization are not well understood. This dissertation aims to track the perturbation of spin density from EDG and EWG modifications, provide mechanistic insight into the radical-initiated reactions of conjugated radical cations, and establish correlations between molecular design and thermochemical properties and their resulting kinetic stability by computationally evaluating these characteristics against experimental data. The disclosed connections give useful new recommendations for the rational design of thermodynamically and kinetically stable novel materials.</p>

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