Abstract In this thesis, we have fabricated a novel poly-Si thin film transistor with self-aligned SiGe raised source/drain (SiGe-RSD TFT). The SiGe-RSD regions were grown selectively by ultra-high vacuum chemical vapor deposition (UHVCVD) at 550¢J. The resultant transistor structure features a thin active channel region and a self-aligned thick source/drain region, which is ideally suited for optimum performance. A significant improvement on the turn-on current in the transfer characteristics is observed, compared to the conventional TFT counterpart. While the conventional TFT depicts severe resistance-limited output characteristics, especially at high gate bias, due to large source and drain series resistance. The new device, in contrast, exhibits excellent output characteristics. Finally, with comparable leakage current in both structures, the on/off current ratio is approximately 2 order of magnitudes higher in the proposed SiGe-RSD TFTS

In this thesis, we propose a simple trench oxide layer polysilicon thin-film Transistor (TO TFT) process and the self-heating effects can be significantly reduced because of its structural advantages. According to the ISE-TCAD simulation results, our proposed TO TFT structure has novel features as follows: 1. The buried oxide and the isolation oxide are carried out simultaneously in order to achieve a goal of simple process. 2. The trench design is used to improve both the sensing current windows (~ 84%) and the retention time (~ 57%). 3. The thermal stability is drastically improved by its naturally formed source/drain tie. The above mentioned features help our proposed device structure to demonstrate the desired characteristics that are better than that of a conventional TFT. Additionally, the thermal instability is drastically improved which is good for long-term device operation.

In this thesis, a novel fully self-aligned bulk-Si device named dual-channel source/drain-tied (DC-SDT) MOSFET with extremely thin (ET) body is proposed. The process utilizes the multiple epitaxial growths of SiGe/Si layers, so the starting material is bulk-Si wafer instead of the SOI wafer. We have investigated the RF/analog performance, and the high temperature induced device stability degradation has also been also investigated. Moreover, we have compared this structure with the other similar transistors such as: body-tied MOSFET (DC-BT MOSFET) and conventional dual-channel MOSFET (DC-SOI MOSFET). Based on the simulation results, for the DC-BT MOSFET, our proposed DC-SDT MOSFET has improved the device performances such as: Ioff decreased 47.6%, switching speed increased 18.1%, S.S. improved 13%, and voltage gain increased 25%. Whereas for the DC-SOI MOSFET, our proposed DC-SDT MOSFET has also improved the device performances such as: Ion increased 11.3%, reduction of lattice temperature 35.7% and 35.5 in the top and bottom channels, voltage gain increased 15%. We not only compared with the above two similar transistors, but also compared to the other mainstream devices, such as: FinFET and Gate-all-around. After the comparisons, we confirm that the proposed DC-SDT MOSFET has better ON-state current and short-channel behaviors. For the scaling, DC-SDT MOSFET can truly become one of the strong candidates.

The continuous and aggressive downscaling of conventional CMOS devices has been driving the vast growth of ICs over the last few decades. As the CMOS downscaling approaches the fundamental limits, novel device architectures such as metallic source/drain Schottky barrier MOSFET (SB-MOSFET) and SB-FinFET are probably needed to further push the ultimate downscaling. The ultimate goal of this thesis is to integrate metallic Ni1-xPtx silicide (x=0~1) source/drain into SB-MOSFET and SB-FinFET, with an emphasis on both material and processing issues related to the integration of Ni1-xPtx silicides towards competitive devices. First, the effects of both carbon (C) and nitrogen (N) on the formation and on the Schottky barrier height (SBH) of NiSi are studied. The presence of both C and N is found to improve the poor thermal stability of NiSi significantly. The present work also explores dopant segregation (DS) using B and As for the NiSi/Si contact system. The effects of C and N implantation into the Si substrate prior to the NiSi formation are examined, and it is found that the presence of C yields positive effects in helping reduce the effective SBH to 0.1-0.2 eV for both conduction polarities. In order to unveil the mechanism of SBH tuning by DS, the variation of specific contact resistivity between silicide and Si substrates by DS is monitored. The formation of a thin interfacial dipole layer at silicide/Si interface is confirmed to be the reason of SBH modification. Second, a systematic experimental study is performed for Ni1-xPtx silicide (x=0~1) films aiming at the integration into SB-MOSFET. A distinct behavior is found for the formation of Ni silicide films. Epitaxially aligned NiSi2-y films readily grow and exhibit extraordinary morphological stability up to 800 oC when the thickness of deposited Ni (tNi) <4 nm. Polycrystalline NiSi films form and tend to agglomerate at lower temperatures for thinner films for tNi≥4 nm. Such a distinct annealing behavior is absent for the formation of Pt silicide films with all thicknesses of deposited Pt. The addition of Pt into Ni supports the above observations. Surface energy is discussed as the cause responsible for the distinct behavior in phase formation and morphological stability. Finally, three different Ni-SALICIDE schemes towards a controllable NiSi-based metallic source/drain process without severe lateral encroachment of NiSi are carried out. All of them are found to be effective in controlling the lateral encroachment. Combined with DS technology, both n- and p-types of NiSi source/drain SB-MOSFETs with excellent performance are fabricated successfully. By using the reproducible sidewall transfer lithography (STL) technology developed at KTH, PtSi source/drain SB-FinFET is also realized in this thesis. With As DS, the characteristics of PtSi source/drain SB-FinFET are transformed from p-type to n-type. This thesis work places Ni1-xPtx (x=0~1) silicides SB-MOSFETs as a competitive candidate for future CMOS technology. / QC20100708 / NEMO, NANOSIL, SINANO

A new shallow junction formation process, based on selective silicon etching followed by selective growth of in situ B-doped SiGe, is presented. The approach is advantageous compared to conventional ion implantation followed by thermal activation, because perfectly abrupt, low resistivity junctions of arbitrary depth can be obtained. In B-doped SiGe layers, the active doping concentration can exceed the solid solubility in silicon because of strain compensation. In addition, the compressive strain induced in the Si channel can improve drivability through increased hole mobility. The process is integrated by performing the selective etching and the selective SiGe growth in the same reactor. The main advantage of this is that the delicate gate oxide is preserved. The silicon etching process (based on HCl) is shown to be highly selective over SiO2 and anisotropic, exhibiting the densely packed (100), (311) and (111) surfaces. It was found that the process temperature should be confined between 800 ºC, where etch pits occur, and 1000 ºC, where the masking oxide is attacked. B-doped SiGe layers with a resistivity of 5×10-4 Ωcm were obtained. Well-behaved pMOS transistors are presented, yet with low layer quality. Therefore integration issues related to the epitaxial growth, such as selectivity, loading effect, pile-up and defect generation, were investigated. Surface damage originating from reactive-ion etching of the sidewall spacer and nitride residues from LOCOS formation were found to degrade the quality of the SiGe layer. Various remedies are discussed. Nevertheless, high-quality selective epitaxial growth could not be achieved with a doping concentration in the 1021 cm-3 range. The maximum doping level resulting in a high-quality layer, with the loading effect taken into account, was 6×1020 cm-3. After this careful process optimization, a high-quality layer was obtained in the recessed areas. Finally, Ni mono-germanosilicide was investigated as a material for contact formation to the epitaxial SiGe layers in the recessed source and drain areas. The formation temperature is 550 ºC and it is stable up to 700 ºC. The observation of a recessed step and lateral growth of the silicide led to a detailed treatment of the contact resistivity of the NiSi0.8Ge0.2/Si0.8Ge0.2 interface using 2-D as well as 3-D modeling. Different values were obtained for square shaped and rounded contacts, 5.0x10-8 Ωcm2 and 1.4x10-7 Ωcm2, respectively. / QC 20101028

<p>A new shallow junction formation process, based on selective silicon etching followed by selective growth of in situ B-doped SiGe, is presented. The approach is advantageous compared to conventional ion implantation followed by thermal activation, because perfectly abrupt, low resistivity junctions of arbitrary depth can be obtained. In B-doped SiGe layers, the active doping concentration can exceed the solid solubility in silicon because of strain compensation. In addition, the compressive strain induced in the Si channel can improve drivability through increased hole mobility. The process is integrated by performing the selective etching and the selective SiGe growth in the same reactor. The main advantage of this is that the delicate gate oxide is preserved. The silicon etching process (based on HCl) is shown to be highly selective over SiO₂ and anisotropic, exhibiting the densely packed (100), (311) and (111) surfaces. It was found that the process temperature should be confined between 800 ºC, where etch pits occur, and 1000 ºC, where the masking oxide is attacked. B-doped SiGe layers with a resistivity of 5×10-⁴ Ωcm were obtained. Well-behaved pMOS transistors are presented, yet with low layer quality. Therefore integration issues related to the epitaxial growth, such as selectivity, loading effect, pile-up and defect generation, were investigated. Surface damage originating from reactive-ion etching of the sidewall spacer and nitride residues from LOCOS formation were found to degrade the quality of the SiGe layer. Various remedies are discussed. Nevertheless, high-quality selective epitaxial growth could not be achieved with a doping concentration in the 1021 cm-3 range. The maximum doping level resulting in a high-quality layer, with the loading effect taken into account, was 6×10²⁰cm-³. After this careful process optimization, a high-quality layer was obtained in the recessed areas. Finally, Ni mono-germanosilicide was investigated as a material for contact formation to the epitaxial SiGe layers in the recessed source and drain areas. The formation temperature is 550 ºC and it is stable up to 700 ºC. The observation of a recessed step and lateral growth of the silicide led to a detailed treatment of the contact resistivity of the NiSi₀.₈Ge_0.2/Si_0.8Ge_0.2 interface using 2-D as well as 3-D modeling. Different values were obtained for square shaped and rounded contacts, 5.0x10^-8 Ωcm² and 1.4x10^-7 Ωcm², respectively.</p>

As scaling of CMOS technology continues, the control of parasitic source/drain (S/D) resistance (RSD) is becoming increasingly challenging. In order to control RSD, metallic source/drain MOSFETs have attracted significant attention, due to their low resistivity, abrupt junction and low temperature processing (≤700 °C). A key issue is reducing the contact resistance between metal and channel, since small Schottky barrier height (SBH) is needed to outperform doped S/D devices. A promising method to decrease the effective barrier height is dopant segregation (DS). In this work several relevant aspects of Schottky barrier (SB) contacts are investigated, both by simulation and experiment, with the goal of improving performance and understanding of SB-MOSFET technology:First, measurements of low contact resistivity are challenging, since systematic error correction is needed for extraction. In this thesis, a method is presented to determine the accuracy of extracted contact resistivity due to propagation of random measurement error.Second, using Schottky diodes, the effect of dopant segregation of beryllium (Be), bismuth (Bi), and tellurium (Te) on the SBH of NiSi is demonstrated. Further study of Be is used to analyze the mechanism of Schottky barrier lowering.Third, in order to fabricate short gate length MOSFETs, the sidewall transfer lithography process was optimized for achieving low sidewall roughness lines down to 15 nm. Ultra-thin-body (UTB) and tri-gate SB-MOSFET using PtSi S/D and As DS were demonstrated. A simulation study was conducted showing DS can be modeled by a combination of barrier lowering and doped Si extension.Finally, a new Schottky contact model was implemented in a multi-subband Monte Carlo simulator for the first time, and was used to compare doped-S/D to SB-S/D for a 17 nm gate length double gate MOSFET. The results show that a barrier of ≤ 0.15 eV is needed to comply with the specifications given by the International Technology Roadmap for Semiconductors (ITRS). / QC 20111206