Detta är en studie om klimatpåverkan i samband med anläggandet av järnvägsbroar i syfte att ta fram nyckeltal (moment, material, mängder) för att effektivt kunna reducera utsläppen av växthusgaser. Till grund för studien har vi arbetat med Trafikverkets verktyg klimatkalkyl 2.0. Det har granskats utifrån användarvänlighet och riktighet i indata och emissionsomräkningsfaktorer. Det för att se till skillnaden mellan modellen och ett unikt anläggningsprojekt, var skiljer sig Trafikverkets typvärden mot de projektspecifika förutsättningarna samt vilka blir dess konsekvenser? Studien har kommit fram till att utan viss försiktighet vid arbete i klimatkalkyl 2.0 finns risk för inkorrekta resultat. Dessutom har studien påvisat tvivelaktiga standardvärden för betydande poster. Utöver dessa resultat har studien konstaterat att de mest betydande delarna för det unika anläggningsprojektets utsläpp är reduktion av mängden stål och betong samt att hitta leverantörer som kan bevisa låga emissionsfaktorer. Med relativt enkla åtgärder skulle det unika anläggningsprojektets totala utsläpp av koldioxidekvivalenter minskas med nästan 20%. / This is a study on the climate impacts associated with the construction of railway bridges in order to develop key performance indicators such as operation, material and amounts to effectively reduce greenhouse gas emissions. The basis of the study has been work in Trafikverkets tool klimatkalkyl 2.0. It has been reviewed on the basis of ease of use and accuracy of input data and emission conversion factors. That’s because we wanted to see the difference between the model and a unique project. What was different and why? This study has concluded that without some care and work in klimatkalkyl 2.0 is a risk of incorrect results. In addition the study demonstrated questionable defaults for significant items. In addition to these results the study found that the most significant parts of the unique projects emissions is reducing the amount of steel and concrete and to find suppliers who can demonstrate low emission factors. With relatively simple measures could the unique projects total carbon emissions be reduced by almost 20%

In recent decades, life cycle assessment (LCA) has become a commonly used approach worldwide when studying environmental impacts linked to waste management systems. These systems are of a complex nature which includes everything from technical solutions, the environmental influence, and various stakeholders. To facilitate studies within this area of research, different LCA models are often utilised. WAMPS is a software specifically developed for assessing the environmental and economic impacts for a waste management system. During recent years, the work to bring the model up to date has begun as the software has not been modernised since it was developed in the early 2000s. The purpose of this degree project is to propose new emission factors for recycling and virgin production of glass, aluminium, steel, and plastic. In addition to this, the study intends to investigate how the implementation of the new figures may affect the results obtained in WAMPS.  To fulfil the purpose of the thesis, LCI datasets were collected for each material and evaluated according to three DQIs (Temporal representativeness, geographical representativeness, and documentation). New emission factors were developed based on the evaluation and discussions within the project group, to ensure that all relevant activities of the studied life cycles were included. The implications from implementing the new emission factors were investigated through a comparison with the old values. This was conducted through comparing the obtained results from WAMPS per one tonne of material as well as for a simple scenario.  The evaluation of the collected LCI data shows that many of the datasets represent average production in countries within Europe and that the data were generally older than five years old. The results show that the datasets were primarily well documented according to the criterion utilised in this study. Processes from EcoInvent were mainly used to develop the proposed emission factors. The implementation of the new emission factors in WAMPS resulted in significant change in potential environmental impact per tonne of material. Especially for the impact category photooxidation formation. For the scenario, the results indicated that a significant change in potential environmental burden is received when implementing the new emission factors. A reduction in total impact was obtained for all categories where eutrophication showed the largest absolute difference.  The developed emission factors are considered appropriate based on the design of this thesis. However, it is concluded that these have several limitations that are important to take into account if these were to be implemented in WAMPS in the future. In addition, it is considered established that an update may be considered reasonable based on the result obtained. / Under de senaste decennierna har livscykelanalys (LCA) blivit ett vanligt tillvägagångssätt världen över vid analyser av potentiella miljöeffekter kopplade till avfallshanteringssystem. Dessa system är av komplex natur och inkluderar allt från teknologiska lösningar, miljöpåverkan samt flera intressenter. För att underlätta dessa studier används idag ofta olika LCA-modeller. WAMPS är ett program som är särskilt utvecklad för att bedöma både miljömässiga- och ekonomiska konsekvenser kopplat till avfallshanteringssystem. Under de senaste åren har arbetet med att uppdatera modellen påbörjat eftersom programvaran inte har uppdaterats sedan början av 2000-talet. Syftet med detta examensarbete är att föreslå nya emissionsfaktorer för återvinning och jungfrulig produktion av glas, aluminium, stål, och plast. Utöver detta avser studien att studera hur implementeringen av de nya siffrorna inverkar på resultatet som erhålls i WAMPS.  För att uppfylla tesen av detta arbete samlades LCI data in för varje material och utvärderades enligt tre DQI:er (Temporal representativitet, geografisk representativitet och dokumentation). Nya utsläppsfaktorer utvecklades baserat på utvärderingen och genom diskussioner inom projektgruppen. Framförallt för att säkerhetsställa att alla relevanta aktiviteter i de studerade livscyklerna är inkluderade. Konsekvenserna av implementeringen av utsläppsfaktorerna undersöktes genom en jämförelse av resultat som erhölls i WAMPS då de nya samt de tidigare faktorerna nyttjas. Detta gjordes både per ton material samt genom ett enkelt scenario.  Utvärderingen av den insamlade LCI datan påvisar att många av dataseten representerar genomsnittlig produktion inom Europa och att datan generellt var insamlad för minst 5 år sedan. Resultatet påvisar att dataseten är väldokumenterad enlig indikatorn som ställts upp i denna studie. Främst användes processer från EcoInvent för att utveckla de nya emissionsfaktorerna. Implementeringen av emissionsfaktorerna i WAMPS resulterade i signifikanta skillnader i potentiell miljöpåverkan per ton material, främst för bildning av fotooxid. För fallet med scenariot indikerade studiens resultat att en betydande förändring av den potentiella miljöbelastningen erhålls när de nya utsläppsfaktorerna implementeras. Dessutom påvisades en minskning av miljöeffekterna för alla kategorier varav eutrofiering visade den största absoluta skillnaden.  Slutligen anses de utvecklade emissions faktorerna vara lämpliga utifrån utformningen av denna tes. Dock dras slutsatsen att dessa har flertalet begränsningar som är viktiga att ta i hänsyn ifall dessa implementeras i WAMPS i framtiden. Dessutom anses det vara fastställt att en fortsatt uppdatering kan anses rimlig utifrån det erhållna resultatet.

The basic objective of this study was to evaluate the environmental performance of two abrasives Copper Slag and Barshot in terms of productivity (in terms of area cleaned- ft2/hr), consumption and or used-abrasive generation rate (of the abrasive- ton/2000ft2; lb/ft2) and particulate emissions (mg/ft2; mg/lb; lb/lb; lb/kg; lb/ton). This would help in evaluating the clean technologies for dry abrasive blasting and would help shipyards to optimize the productivity and minimize the emissions by choosing the best combinations reported in this study to their conditions appropriately. This project is a joint effort between the Gulf Coast Region Maritime technology Center (GCRMTC) and USEPA. It was undertaken to simulate actual blasting operations conducted at shipyards under enclosed, un-controlled conditions on plates similar to steel plates commonly blasted at shipyards.

Transport of wastewater in sewer networks causes potential problems associated with gases which include ammonia, carbon dioxide, carbon monoxide, hydrogen sulfide and methane, in regard to odor nuisance, irritation, toxicity, and microbially induced corrosion. The extent of these problems depends on the emission rates of gases in the sewer atmosphere. To limit these kinds of problems an estimate of the gases emitted from the sewer network is to be known. In consideration to the above mentioned problems, a research has been taken up to estimate the two gases, namely, carbon dioxide and hydrogen sulfide from sewer wet wells. In this method, using Landtec GEM-2000 plus a multi-gas analyzer, the sample gases were collected from the wet well of pump stations for five days. Using the collected samples the emission rates of carbon dioxide and hydrogen sulfide are estimated.

Submitted by Biblioteca de Pós-Graduação em Geoquímica BGQ (bgq@ndc.uff.br) on 2017-09-18T16:28:16Z No. of bitstreams: 1 Dissertação - Renato Ribeiro (Mestrado em Geoquímica Ambient.pdf: 1758942 bytes, checksum: 2ab97e8d9839edbd110b4bfbbc94fdc9 (MD5) / Made available in DSpace on 2017-09-18T16:28:16Z (GMT). No. of bitstreams: 1 Dissertação - Renato Ribeiro (Mestrado em Geoquímica Ambient.pdf: 1758942 bytes, checksum: 2ab97e8d9839edbd110b4bfbbc94fdc9 (MD5) / Conselho Nacional de Desenvolvimento Científico e Tecnológico / Fundação de Amparo a Pesquisa do Estado do Rio de Janeiro / Universidade Federal Fluminense. Instituto de Química. Programa de Pós-Graduação em Geoquímica, Niterói, RJ / O óxido nitroso (N2O) é um dos principais gases do efeito estufa e a principal fonte de óxido nítrico na estratosfera, contribuindo de forma indireta para o consumo do ozônio estratosférico. O tratamento de esgotos é uma fonte antrópica de N2O, cuja contribuição é quantitativamente considerada de menor relevância, entretanto, pouco se sabe sobre a real contribuição dessas emissões em virtude da grande variabilidade reportada nos fatores de emissão (FEs), balizados na carga de nitrogênio total (NT) afluente, tanto oriundo de estudos realizados em escala real quanto laboratorial. As diretrizes de 2006 do Painel Intergovernamental sobre Mudanças Climáticas para inventários nacionais de gases do efeito estufa propõem como FE 3,2 (2-8) g N2O pessoa-1 ano-1 para o caso de Estações de Tratamento de Esgotos (ETEs) com processos de nitrificação e desnitrificação controlados. O objetivo do presente estudo foi avaliar a relação entre alguns parâmetros operacionais, tais como concentração de NT afluente à ETE (especialmente NH4+), demanda química de oxigênio (DQO) e concentração de oxigênio dissolvido (OD), com as emissões de N2O do tanque de aeração de uma ETE localizada na região metropolitana do Rio de Janeiro. O processo de tratamento de esgotos empregado é o sistema de lodos ativados convencional com aeração realizada de forma diferenciada por zonas. As emissões de N2O foram determinadas mensalmente, sempre na parte da manhã, no período de janeiro a junho de 2010 ao longo das seis zonas dos quatro tanques de aeração que a ETE possui em funcionamento. A média das emissões de N2O determinada durante o período de estudo foi 1,11 kg N dia-1, o que corresponde a 0,02% da carga de NT afluente. As emissões de N2O foram menores no período de verão do que no inverno e positivamente correlacionadas (r = 0,90; n = 6; P < 0,01) com as concentrações de NH4+ afluente à ETE. Em relação às concentrações de DQO e OD, as maiores emissões de N2O ocorreram em regiões de baixas concentrações de DQO e concentrações de OD superiores a 2,0 mg L-1, sendo a maior emissão média de N2O determinada em OD próximo a 3,0 mg L-1. A redução da carga orgânica ao longo das zonas e o aumento gradual da concentração de OD contribuem de forma direta para as maiores emissões de N2O, em razão da maior disponibilidade de OD para ambas as reações de oxidação da matéria orgânica e nitrificação e, consequentemente, maior produção e emissão de N2O. As eficiências de remoção de demanda bioquímica de oxigênio (DBO), DQO e NT foram 97%, 93% e 80%, respectivamente. O FE médio, balizado na população atendida, foi 2,5 vezes menor do que o proposto pelas diretrizes de 2006 do Painel Intergovernamental sobre Mudanças Climáticas para inventários de emissões de N2O em ETEs com processos de nitrificação e desnitrificação controlados. Portanto, os resultados sugerem que o processo de lodos ativados convencional empregado na ETE de estudo é bastante eficiente na remoção da carga orgânica e NT e, além disso, no que tange as menores emissões de N2O quando comparado a outros sistemas empregados nas ETEs estudadas no Brasil e em estudos desenvolvidos no exterior. Sugere-se que tal eficiência esteja relacionada à utilização de aeração suficiente e diferenciada por zonas, que proporciona condições favoráveis aos processos microbiológicos de oxidação da matéria orgânica e aos processos de nitrificação completos, mesmo nas condições de elevadas concentrações de DBO, DQO e de NT (especialmente NH4+), como observado no período de inverno. / Nitrous oxide (N2O) is a major greenhouse gas and the main source of nitric oxide in the stratosphere, contributing indirectly to consumption of the stratospheric ozone. Wastewater treatment is an anthropogenic source of N2O, whose contribution is considered to be quantitatively of minor importance. However, little is known about the actual contribution of these emissions due to the wide variability reported in the emission factors (EFs), based on amount of N2O emitted relative to the influent total nitrogen (TN) load, both from full-scale and laboratory-scale studies. The 2006 guidelines of the Intergovernmental Panel on Climate Change for national inventories of greenhouse gases as proposed EF 3.2 (2-8) g N2O person-1 yr-1 for the case of advanced centralized wastewater treatment plants (WWTPs) with controlled nitrification and denitrification steps. The aim of this study was to evaluate the relationship between some operational parameters, such as TN concentration (especially NH4+), chemical oxygen demand (COD) and dissolved oxygen (DO) concentrations, on N2O emissions from the aeration tank of a WWTP located in the metropolitan region of Rio de Janeiro, Southeast Brazil. The wastewater treatment employed is conventional activated sludge process with a differentiated aeration system. The entire aeration system consists of four adjacent aeration tanks with six zones each. N2O emissions were measured monthly in the period from January to June 2010, always in the morning, over the six zones of the four aeration tanks. The average N2O emission was 1.11 kg N day-1 corresponding to 0.02% of the influent TN load. N2O emissions were lower in summer than winter and were positively related (r = 0.90; n = 6; P < 0.01) with influent NH4+ concentrations. Regarding the COD and DO concentrations, the highest N2O emissions occurred in regions of low concentrations of COD and DO concentrations above 2.0 mg L-1, with the highest average emission of N2O in DO concentration close to 3.0 mg L-1. The reduction of the organic load along the zones and gradually increase the DO concentration, contributes directly to higher N2O emissions, due to the greater availability of DO for both the oxidation of organic matter and nitrification, and consequently higher production and emission of N2O. The removal efficiencies of biological oxygen demand (BOD), COD and TN were 97%, 93% and 80%, respectively. The average EF calculated from population served was 2.5 lower than that proposed by the IPCC for N2O emission inventories in WWTPs with controlled processes of nitrification and denitrification. Therefore, the results suggest that the process employed in the WWTP study is very efficient in removing the organic load and TN, and in addition, with smaller N2O emissions when compared to other systems studied in Brazil and those available in literature. It is suggested that this efficiency is related to the use of aeration sufficiently to promote conditions favorable for the microbial oxidation of organic matter and complete nitrification, even under conditions of high BOD, COD and TN concentrations (especially NH4+), as observed during winter.

The objectives of this study are to measure the non-methane volatile organic carbon (NMVOC&#039 / s) emissions from passenger cars in Turkey having gasoline engines, to determine emission factors of these vehicles for BTEX compounds and comparison of emission factors obtained in this study with the emission factors of the other countries. This study was conducted in two parts: The first part was to determine the categories of passenger cars widely used in Turkey, and also to determine the average carbon monoxide (CO) and hydrocarbon (HC) emissions at idle condition for these car types based on the exhaust emission measurements of Ankara &Ccedil / evre Koruma Vakfi (AN&Ccedil / EVA). The second part of the study was to analyze the gas composition of exhaust gasses at different road conditions for BTEX components by using gas chromatography. The results of the study have shown that the cars named under &lsquo / &lsquo / Tofas&rsquo / &rsquo / constitute 31.5% and &lsquo / &lsquo / Fiat&rsquo / &rsquo / 13.1% of the total cars in Turkey and they are manufactured by the same company. Therefore, studies have been performed with &lsquo / &lsquo / Tofas/Fiat&rsquo / &rsquo / cars. The highest emission factors among hydrocarbons investigated in this study were found for toluene and m-xylene. Generally, as driving speed increases the emissions of HC&rsquo / s are found to decrease in concentration. It was interesting to note that the highest emissions occur at 30 km/hr speed which is the mostly used speed in crowded streets and busy intersections. Therefore, it was concluded that it is very important to take measures for emissions in the city traffic. Cold start emissions were also found to be higher than the hot start emissions.

Den pågående klimatkrisen kan otvivelaktigt förklaras av antropogena aktiviteter på jorden. Växthusgaserna som orsakar den globala uppvärmningen uppstår huvudsakligen genom förbränning av fossila ämnen och mätningar visar på exceptionella koncentrationer av växthusgaser i atmosfären – för koldioxid de högsta på 800 000 år. Planetens medeltemperatur har rubbats och lämnar idag inte någon del av planeten oberörd. Den globala uppvärmningen och klimatförändringarna bekämpas genom globala överenskommelser, så som Parisavtalet, om drastiskt minskade nettoutsläpp av växthusgaser. Sveriges krav på utsläppsminskningar genom EU ligger på 50 procent fram till 2030. Näringslivet har en väsentlig och ansvarsfull roll för en hållbar utveckling, den gröna omställningen och genomförandet av de globala klimatmålen. GHG-protokollet är en icke-vinstdrivande organisation som etablerades i slutet av 1990-talet utifrån det ökande behovet av ett globalt standardiserat ramverk för redovisning och rapportering av växthusgasutsläpp. Enligt GHG-protokollet sorteras utsläppen som direkta eller indirekta i tre scope: scope 1 (direkta), 2 (indirekta) och 3 (indirekta, som uppstår i värdekedjan utanför företagets grindar). Genom en fallstudie på Ramudden, ett företag inom bygg- och anläggningssektorn, utför den här studien klimatberäkningar inom scope 3 på ett trafikprojekt gällande en tunnelavstängning. Studiens utförande baseras på primär datainsamling från Ramudden, sekundär datainsamling från internationellt erkända databaser och med metodstöd genom GHG-protokollet. Målsättningen med studien är att utreda var de största växthusgasutsläppen uppstår i tunnelavstängningen, inom områdena material, transport och avfall, och var utsläppen kan minskas. Resultatet visar att de största utsläppen härrör från området transport, specifikt förbränning av diesel. Störst utsläppsreducering anses kunna uppnås inom området transport genom undvikande av nyinköpt material och byte från fossila bränslen till förnybara. Slutsatserna som dras är att inköp av nya produkter följer med höga växthusgasutsläpp genom transporten av dem. Vidare ger fossil diesel (miljöklass 1) sex gånger större växthusgasutsläpp än fossilfri diesel i form av HVO. / The current climate crisis can undoubtedly be explained by anthropogenic activities on Earth. The greenhouse gases enter the atmosphere through the burning of fossil fuels and cause global warming. Measurements show exceptional concentrations of greenhouse gases – for carbon dioxide the highest in 800 000 years. The planet´s average temperature has been thrown out of balance and does not leave any part of the planet unaffected.  Global warming and climate change are combated through global agreements, such as The Paris Agreement, with demands on drastically reduced net emissions of greenhouse gases. Sweden´s requirement within the EU is a 50 percent emission reduction until 2030. The business sector has an essential and responsible role for sustainable development, the green transition, and the implementation of global climate goals. The GHG protocol is a non-profit organization established in the late 1990s that arose out of the growing need for a globally standardized framework for accounting and reporting greenhouse gas emissions. The GHG protocol classifies emissions as direct or indirect emissions, into three scopes: scope 1 (direct), 2 (indirect) and 3 (indirect emissions that occur in the value chain and are not included in scope 2). Through a case study on Ramudden, a company in the building and construction sector, this study performs scope 3 climate calculations on a traffic project regarding a tunnel closure. The execution of the study is based on primary data collection from Ramudden, secondary data from international databases and a methodological guidance from the GHG protocol. The aim of this study is to examine where the largest greenhouse gas emissions occur within the project, in the areas of material, transport and waste, and identify where the emissions most effectively can be reduced. The result shows that the greatest emissions come from the transport area, specifically diesel emissions. The greatest emission reductions are achievable by avoiding purchases of new equipment and therefore avoiding its transportation emissions, and by switching from fossil fuels to renewable. The conclusions are that the purchase of new equipment generates large emissions from the equipment transportation. Furthermore, fossil diesel (environmental class 1) produces six times greater greenhouse gas emissions than fossil-free diesel (HVO).

Master of Science / Department of Biological & Agricultural Engineering / Ronaldo G. Maghirang / Large cattle feedlots in Kansas are often considered to be large sources of particulate matter (PM), including PM with equivalent aerodynamic diameter of 10 micrometers or less (PM[subscript]10). To control PM emissions from cattle feedlots, water sprinkler systems can be implemented; however, limited data are available on their PM control efficiency. This research was conducted to determine the control efficiency of a water sprinkler system in reducing PM[subscript]10 emission from a cattle feedlot. This was accomplished by monitoring the PM[subscript]10 concentrations, with tapered element oscillating microbalance (TEOM™) PM[subscript]10 monitors, at the upwind and downwind boundaries of a cattle feedlot (KS1) from January 2006 to July 2009. The feedlot was equipped with a sprinkler system that can apply up to 5 mm of water per day. It had approximately 30,000 head of beef cattle and total pen area of approximately 50 ha. The control efficiency of the sprinkler system was determined by considering the PM[subscript]10 data during sprinkler on/off events, i.e., the sprinkler system was operated (on) for at least one day and either followed or preceded by at least one day of no water sprinkling (off). For each of the selected sprinkler on/off events, the percentage reduction in net PM[subscript]10 concentration was calculated and considered to be a measure of the control efficiency. Net PM[subscript]10 concentration was defined as the difference between downwind and upwind PM[subscript]10 concentrations. The control efficiency for PM[subscript]10 ranged from 32% to 80%, with an overall mean of 53% based on 24-h PM[subscript]10 values for 10 sprinkler on/off events. In general, the effect of the water sprinkler system in reducing net PM[subscript]10 concentration lasted for one day or less. The percentage reduction in net PM[subscript]10 concentration at KS1 due to rainfall events was also determined using a similar approach. In addition, a second cattle feedlot (KS2) that was not equipped with a sprinkler system and with approximately 25,000 head of beef cattle and 68 ha pen area was considered. Percentage reductions in net PM[subscript]10 concentrations due to rainfall events were mostly in the range of 60% to almost 100% for both feedlots, with overall means of 75% for KS1 and 74% for KS2. The effects of rainfall events (with rainfall amounts > 10 mm/day) lasted for three to seven days, depending on rainfall amount and intensity. Limited data are also available on PM[subscript]10 emission rates from cattle feedlots in Kansas. This research quantified PM[subscript]10 emission rates from the two feedlots (KS1 and KS2) and a third cattle feedlot (KS3) in Kansas by using inverse dispersion modeling with the AMS/EPA Regulatory Model (AERMOD), which is the US EPA preferred regulatory atmospheric dispersion model. PM[subscript]10 emission rates were back-calculated using the resulting PM[subscript]10 concentrations modeled by AERMOD, together with measured PM[subscript]10 concentrations (24 months of data for KS1 and KS2, 6 months of data for KS3). Overall mean PM[subscript]10 emission fluxes for the 2-year period were 1.29 g/m[superscript]2-day (range: 0.04 – 4.98 g/m[superscript]2-day) for KS1, 1.03 g/m[superscript]2-day (range: 0.07 – 4.52 g/m[superscript]2-day) for KS2, and 2.48 g/m[superscript]2-day (6-months; range: 0.05 – 5.00 g/m[superscript]2-day) for KS3. The corresponding mean PM[subscript]10 emission factors were 21, 29, and 48 kg/1,000 hd-day for KS1, KS2, and KS3, respectively. The emission factors for KS1 and KS2 were considerably smaller than the published US EPA emission factor for cattle feedlots (i.e., 42 kg/1000 hd-day). The emission factor for KS3 was slightly greater than the US EPA emission factor; however, it was a biased estimate because it was based only on a six-month period.

A atividade de mudança do uso da terra na Amazônia vem sendo apontada como principal fonte de CO2 para a atmosfera em função das emissões de C e N provenientes do solo. A prática de manejo adotada pode influenciar significativamente nos estoques de C e N do solo funcionando como dreno ou fonte de C e N para a atmosfera. Além disso, podem ser alterados: a fertilidade e a densidade do solo bem como as frações e a origem da MOS. Com o objetivo de avaliar o impacto das mudanças de uso da terra na região leste da Amazônia foram coletadas amostras de terra nos principais usos da terra na região de Santarém-PA, em três profundidades: 0-10, 10-20 e 20-30 cm. Através das amostras foi realizada a caracterização físico-química das áreas e foram determinados os teores de C e N do solo e os isótopos ? 13C e ? 15N com a finalidade de quantificar os estoques de C e N do solo e avaliar a dinâmica e origem da MOS. Para um subconjunto de amostras foi realizado o fracionamento físico da MOS e a determinação do C da biomassa microbiana para compreender como a mudança de uso da terra interferiu nessas frações. Somado a essas determinações foi realizada a estimativa dos fatores de emissão com base na metodologia descrita pelo IPCC. Através da caracterização físicoquímica as áreas de estudo são caracterizadas por solos argilosos a muito argilosos. Os maiores valores de pH, macronutrientes, CTC, SB e V% foram observados nas áreas de agricultura (AGR) sugerindo que a utilização de práticas como adubação e calagem, são capazes de alterar os padrões de fertilidade do solo na Amazônia, aumentando seus índices de fertilidade. Para os estoques de C e N pode-se dizer que a mudança de uso da terra na região estudada está contribuindo para as perdas de C e N do solo, principalmente quando a conversão é realizada para áreas de agricultura (AGR) e pastagem (PA) sendo que os estoques de C observados na camada de 0-30 cm nessas áreas foram 49,21 Mg C ha-1 (PA) e 48,60 Mg C ha-1 (AGR). O maior valor de ? 13C foi encontrado nas áreas de pastagens, -25,08?, sugerindo que para as áreas de PA existe diluição isotópica e que parte do C do solo ainda é remanescente da floresta. As frações da MOS apresentaram alterações na quantidade de C e na proporção das frações leve e oclusa, principalmente nos usos AGR e PA. A fração lábil da MOS (C da biomassa microbiana) também apresentou grande diferença entre os usos FLO e AGR (526,21 e 296,78 ?g g-1de solo seco), indicando que a AGR foi o uso que mais alterou os estoques de C e N do solo e também as frações da MOS. Os fatores de emissão calculados confirmam todos os resultados observados em relação a conversão de FLO para AGR, sendo que para esse uso o fator de emissão foi de 0,93 ± 0,033, sendo então o uso que mais emitiu C. Com base nos resultados conclui-se que a introdução de áreas agrícolas na região de Santarém, é a principal causa de perda de C e N do solo e consequentemente é o uso que mais contribui com as emissões de gases do efeito estufa. / The land use change in the Brazilian Amazon has been identified as the main source of CO2 to the atmosphere due to emissions of soil carbon and nitrogenl. The management practice adopted can strongly influence the soil C and N stocks and may works like a sink or source of C and N to the atmosphere. Furthermore, can be changed: the soil fertility and bulk density as well as the SOM fractions and C source of the SOM. With the objective of evaluate the impact of the land use change in eastern Amazonia soil samples were collected in the main land uses in Santarém region, Para State of Brazil, at three depths: 0-10, 10-20 and 20-30 cm. Through the samples was performed the physicochemical characterization of the areas and were determined the soil C and N contents as well the isotopes ? 13C and ? 15N in order to quantify the soil C and N stocks and understand the SOM dynamics and evaluate the SOM origin. For a subset of samples were performed the physical fractionation of SOM and the determination of microbial biomass C to understand how the land use change may interfere in these fractions. Added to these determinations were estimated the emission factors based on the methodology described by the IPCC. Through the physicochemical characterization study areas can be characterized as a clayey loamy soils. The highest values of pH, macronutrients, CEC , sum of bases and base saturation were observed in croplands (CP), suggesting that the use of practices such as fertilization and liming are able to change the soil fertility patterns in the Amazon, increasing their fertility. For C and N stocks can be said that the land use change in the study area is contributing to the loss of soil C and N, especially when the conversion is done for croplands (CP) and grasslands (GS) areas and the value observed for soil C stocks in the 0-30 cm layer in these areas were 49.21 Mg C ha-1 (GS) and 48.60 Mg C ha-1 (CP). The highest ? 13C value was found in GS, -25.08 ?, suggesting that for these areas is occurring an isotope dilution and that part of the soil C is still remaining from forest. The SOM fractions showed changes in the amount of C and in the proportion of light and occluded fractions, especially in the uses CP and GS. The labile SOM fractions (microbial biomass) also showed a large difference between the UF and CP uses (526.21 and 296.78 mg g-1 of dry soil), indicating that CP affects the soil C and N stocks and also the SOM fractions. The emission factors calculated confirm all results observed for the conversion of UF for CP, and for this use the emission factor was 0.93 ± 0.033, and then this was the use that emitted more C. Based on the results we conclude that the introduction of croplands in Santarem region is the main cause of soil C and N loss and consequently contributes more to the greenhouse gases emission.

<p>The uncertainty of the climate and health effects of aerosols is still large, one important reason being lack of knowledge of the primary emissions. This thesis combines laboratory and field experiments, and process modelling in an effort to better quantify the submicrometre aerosol emissions and to understand some of the processes in the atmosphere.</p><p>A parameterisation was derived for the source flux of sea salt particles (particles m^-2s^-1) in the size range 0.02-2.8 µm dry diameter (D_p), it is the first parameterisation to almost cover two full decades of the submicrometre sea salt aerosol production, and to include the effect of water temperature. This sea salt parameterisation was validated for temperate water in the 0.1-1.1 μm D_p range using in situ size resolved emissions of marine aerosol particles, which were measured with the eddy covariance (EC) method. For periods sampled air was heated to 300ºC in order to evaporate semi-volatile organics and isolate the sea salt fraction. Comparisons with the total aerosol emissions suggest that in these emissions organic carbon and sea salt are internally mixed in the same particles. Finally an aerosol dynamics model was modified for marine conditions. In the model parameterised emissions of sea salt was included together with aerosol dynamics, chemistry and clouds representative for the marine boundary layer. The sea salt emissions are together with secondary sulphate, and cloud processing able to reproduce a typical marine aerosol size distribution and cloud condensation nuclei population.</p><p>Measurements with the EC method of the road traffic related aerosol source number flux for D_p>0.011 µm show that the major part of the aerosol fluxes is due to road traffic emissions. Both an emission factor for the whole fleet mix in Stockholm (1.4x10¹⁴ vehicle^-1 km^-1) and separate emission factors for light- and heavy-duty vehicles (HDV) were deduced. The result shows that during weekdays 70-80% of the emissions come from HDV.</p>