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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
521

Design and Simulation of Digital Radial Piston Pumps Using Externally Actuated Cam Systems

Keith Scott Pate (13174803) 29 July 2022 (has links)
<p>Energy conservation is a growing topic of research within various fields.  Digital Hydraulics is a division of fluid power that focuses on using on/off technology to improve the performance and efficiency of fluid power systems. One significant benefit of Digital Hydraulics is that it has enabled additional control over fluid power systems, which helps achieve component and system level improvements. Conventional radial and inline piston pumps use positive sealing valves, which mitigate leakage losses, compared to port plates commonly seen in variable displacement pumps. By using digitally controlled positive sealing valves on radial and inline piston pumps, leakage losses can be mitigated to develop a more efficient variable displacement pump. This work focuses on the design, modeling, and simulation of a mechanically actuated valving system developed for a commercially available radial piston pump. The design uses a ball screw actuation method to phase the cam during operation, changing the displacement. Using a modeling and simulation software, GT-SUITE, a simulation model was created for the digital pump that shows close correlation to the manufacturer’s data at high pressure. The parameters simulated, 50 – 200 bar, showed that the system could achieve a peak efficiency drop of approximately 11.0% from 87.0% to 76.0% from 100 – 25% displacement simulated at 200 bar and 500rpm. Compared to a typical variable displacement axial piston pump unit, the digital pump showed increased efficiencies across the bandwidth of 35-83% displacement, with a lower overall drop in efficiency across most of its operating conditions. In the comparison used, the pump is outside of its operating range and has not been optimized; thus, the simulation model created in this thesis will be used in the future to optimize the system and evaluate the system's potential performance and feasibility for future prototyping and testing as a proof of concept.  </p>
522

Análisis termohidráulico de la instalación ATLAS. Aplicaciones de la metodología de escalado

Lorduy Alós, María 21 March 2022 (has links)
[ES] Ante el desafío que implica la reducción de los efectos del cambio climático, la industria nuclear se ha postulado como una buena alternativa para sustituir la producción de energía eléctrica a partir de combustibles fósiles. No obstante, debe constatar la seguridad de las centrales, para lo que resulta indispensable poder predecir su comportamiento ante escenarios operacionales y accidentales. A tal efecto, y dada la imposibilidad de disponer de datos de planta para analizar estos transitorios, se generan bases de datos en instalaciones a escala reducida a partir de experimentos, siendo necesarios métodos y estrategias de escalado que permitan extrapolar los comportamientos termohidráulicos. Pese a la relevante contribución que suponen los experimentos al campo de la seguridad nuclear, en ocasiones se cuestiona la validez de sus resultados para reproducir el comportamiento de las centrales. Este hecho motiva la ejecución de test counterpart entre distintas instalaciones, que contribuyen a abordar la problemática del escalado, así como a demostrar la adecuación de los códigos termohidráulicos para predecir una respuesta realista de los sistemas. La presente tesis doctoral explora la posibilidad de aumentar el número de experimentos counterpart a partir de la definición de nuevos escenarios y su simulación con el código termohidráulico TRACE5. Con este fin, se han desarrollado modelos de las instalaciones ATLAS y LSTF, y se han estudiado y simulado experimentos counterpart ya existentes entre dichas instalaciones. La identificación de los fenómenos termohidráulicos más significativos, y el análisis de su escalado y distorsión, configuran la base de conocimientos para abordar el diseño de los nuevos test. En la tesis, en particular, se plantea un escenario tipo station blackout para LSTF partiendo de las condiciones iniciales y de contorno de un test previo en ATLAS. La simulación del experimento confirma la idoneidad de ATLAS y LSTF para realizar experimentos counterpart, en los que la fenomenología relevante es similar, y pone de manifiesto algunas limitaciones de estas instalaciones en cuanto a la extrapolabilidad de ciertos fenómenos, debido a las distorsiones originadas por la diferencia de escala y tecnología. / [CA] Davant del desafiament que implica la reducció dels efectes del canvi climàtic, la indústria nuclear s'ha postulat com una bona alternativa per a substituir la producció d'energia elèctrica a partir de combustibles fòssils. No obstant això, ha de constatar la seguretat de les centrals, per al que resulta indispensable poder predir el seu comportament davant d'escenaris operacionals i accidentals. A aquest efecte, i donada la impossibilitat de disposar de dades de planta per a analitzar aquests transitoris, es generen bases de dades en instal·lacions a escala reduïda a partir d'experiments, sent necessaris mètodes i estratègies d'escalat que permeten extrapolar els comportaments termohidràulics. Malgrat la rellevant contribució que suposen els experiments al camp de la seguretat nuclear, de vegades es qüestiona la validesa dels seus resultats per a reproduir el comportament de les centrals. Aquest fet motiva l'execució de test counterpart entre distintes instal·lacions, que contribuïxen a abordar la problemàtica de l'escalat, així com a demostrar l'adequació dels codis termohidràulics per a predir una resposta realista dels sistemes. La present tesi doctoral explora la possibilitat d'augmentar el nombre d'experiments counterpart a partir de la definició de nous escenaris i la seua simulació amb el codi termohidràulic TRACE5. Amb aquest fi, s'han desenvolupat models de les instal·lacions ATLAS i LSTF, i s'han estudiat i simulat experiments counterpart ja existents entre les dites instal·lacions. La identificació dels fenòmens termohidràulics més significatius, i l'anàlisi del seu escalat i distorsió, configuren la base de coneixements per a abordar el disseny dels nous test. En la tesi, en particular, es planteja un escenari tipus station blackout per a LSTF partint de les condicions inicials i de contorn d'un test previ en ATLAS. La simulació de l'experiment confirma la idoneïtat d'ATLAS i LSTF per a realitzar experiments counterpart, en els que la fenomenologia rellevant és semblant, i posa de manifest algunes limitacions d'aquestes instal·lacions quant a l'extrapolabilitat de certs fenòmens, a causa de les distorsions originades per la diferència d'escala i tecnologia. / [EN] Faced with the challenge of reducing the effects of climate change, the nuclear industry has been postulated as a good alternative to replace the production of electricity from fossil fuels. However, it must verify the safety of the plants, for which it is essential to be able to predict their behavior in operational and accidental scenarios. To this end, and given the impossibility of having plant data to analyze these transients, databases are generated in reduced-scale facilities from experiments, being necessary scaling methods and strategies that allow the extrapolation of thermohydraulic behaviors. Despite the relevant contribution that experiments make to the field of nuclear safety, the validity of their results to reproduce the behavior of plants is sometimes questioned. This fact motivates the execution of counterpart tests between different facilities, which contribute to addressing scaling issues, as well as to demonstrate the adequacy of the thermal-hydraulic codes to predict a realistic response of the systems. This Ph.D. Thesis explores the possibility of increasing the number of counterpart experiments based on the definition of new scenarios and their simulation with the TRACE5 thermal-hydraulic code. In order to achieve this goal, models of the ATLAS and LSTF facilities have been developed, and counterpart experiments already existing between these facilities have been studied and simulated. The identification of the most significant thermal-hydraulic phenomena and the analysis of their scaling and distortion, configure the knowledge basis to approach the design of the new tests. In the Thesis, in particular, a station blackout scenario for LSTF based on the initial and boundary conditions of a previous test in ATLAS is proposed. The simulation of the experiment confirms the suitability of ATLAS and LSTF to perform counterpart experiments, in which the relevant phenomenology is similar. Moreover, it reveals some limitations of these facilities in terms of the extrapolability of certain phenomena, due to the distortions caused by the difference in scale and technology. / Lorduy Alós, M. (2022). Análisis termohidráulico de la instalación ATLAS. Aplicaciones de la metodología de escalado [Tesis doctoral]. Universitat Politècnica de València. https://doi.org/10.4995/Thesis/10251/181700
523

Modeling and Simulation for Power Loss Estimation in Electrified Drill Rigs

Chit, Ali January 2024 (has links)
This master's thesis aims to establish a foundation for model-based engineering of drill rigs through the development, evaluation, and utilization of simulation models. Specifically, the project focused on creating a simulation model of the hydraulic tramming system in the SmartRoc D65 surface drill rig. The uncalibrated model was validated against physical tests conducted on the SmartRoc T35 drill rig, and the results provided accurate predictions with some room for improvement. The model sets a basis for identifying power losses and future potential optimization through electrification. A modeling methodology was developed to aid in the development of other simulation models representing a physical system. The thesis highlights the strengths and limitations of a quasi-static model when applied to dynamic systems. The findings suggest areas for future improvement and underscore the importance of continuous model refinement to enhance calculation accuracy.
524

The design of reactor cores for civil nuclear marine propulsion

Alam, Syed Bahauddin January 2018 (has links)
Perhaps surprisingly, the largest experience in operating nuclear power plants has been in nuclear naval propulsion, particularly submarines. This accumulated experience may become the basis of a proposed new generation of compact nuclear power plant designs. In an effort to de-carbonise commercial freight shipping, there is growing interest in the possibility of using nuclear propulsion systems. Reactor cores for such an application would need to be fundamentally different from land-based power generation systems, which require regular refueling, and from reactors used in military submarines, as the fuel used could not conceivably be as highly enriched. Nuclear-powered propulsion would allow ships to operate with low fuel costs, long refueling intervals, and minimal emissions; however, currently such systems remain largely confined to military vessels. This research project undertakes computational modeling of possible soluble-boron-free (SBF) reactor core designs for this application, with a view to informing design decisions in terms of choices of fuel composition, materials, core geometry and layout. Computational modeling using appropriate reactor physics (e.g. WIMS, MONK, Serpent and PANTHER), thermal-hydraulics etc. codes (e.g. COBRA-EN) is used for this project. With an emphasis on reactor physics, this study investigates possible fuel assembly and core designs for civil marine propulsion applications. In particular, it explores the feasibility of using uranium/thorium-rich fuel in a compact, long-life reactor and seek optimal choices and designs of the fuel composition, reactivity control, assembly geometry, and core loading in order to meet the operational needs of a marine propulsion reactor. In this reactor physics and 3D coupled neutronics/thermal-hydraulics study, we attempt to design a civil marine reactor core that fulfills the objective of providing at least 15 effective full-power-years (EFPY) life at 333 MWth. In order to unleash the benefit of thorium in a long life core, the micro-heterogeneous ThO2-UO2 duplex fuel is well-positioned to be utilized in our proposed civil marine core. Unfortunately, A limited number of studies of duplex fuel are available in the public domain, but its use has never been examined in the context of a SBF environment for long-life small modular rector (SMR) core. Therefore, we assumed micro-heterogeneous ThO2-UO2 duplex fuel for our proposed marine core in order to explore its capability. For the proposed civil marine propulsion core design, this study uses 18% U-235 enriched micro-heterogeneous ThO2-UO2 duplex fuel. To provide a basis for comparison we also evaluate the performance of homogeneously mixed 15% U-235 enriched all-UO2 fuel. This research also attempts to design a high power density core with 14 EFPY while satisfying the neutronic and thermal-hydraulics safety constraints. A core with an average power density of 100 MW/m3 has been successfully designed while obtaining a core life of 14 years. The average core power density for this core is increased by ∼50% compared to the reference core design (63 MW/m3 and is equivalent to Sizewell B PWR (101.6 MW/m3 which means capital costs could be significantly reduced and the economic attractiveness of the marine core commensurately improved. In addition, similar to the standard SMR core, a reference core with a power density of 63 MW/m3 has been successfully designed while obtaining a core life of ∼16 years. One of the most important points that can be drawn from these studies is that a duplex fuel lattice needs less burnable absorber than uranium-only fuel to achieve the same poison performance. The higher initial reactivity suppression and relatively smaller reactivity swing of the duplex can make the task of reactivity control through BP design in a thorium-rich core easier. It is also apparent that control rods have greater worth in a duplex core, reducing the control material requirements and thus potentially the cost of the rods. This research also analyzed the feasibility of using thorium-based duplex fuel in different cases and environments to observe whether this fuel consistently exhibit superior performance compared to the UO2 core in both the assembly and whole-core levels. The duplex fuel/core consistently exhibits superior performance in consideration of all the neutronic and TH constraints specified. It can therefore be concluded from this study that the superior performance of the thorium-based micro-heterogeneous ThO2-UO2 duplex fuel provides enhanced confidence that this fuel can be reliably used in high power density and long-life SBF marine propulsion core systems, offering neutronic advantages compared to the all-UO2 fuel. Last, but not least, considering all these factors, duplex fuel can potentially open the avenue for low-enriched uranium (LEU) SBF cores with different configurations. Motivated by growing environmental concerns and anticipated economic pressures, the overall goal of this study is to examine the technological feasibility of expanding the use of nuclear propulsion to civilian maritime shipping and to identify and propose promising candidate core designs.
525

Hardware-in-the-Loop Simulation of Aircraft Actuator

Braun, Robert January 2009 (has links)
<p>Advanced computer simulations will play a more and more important role in future aircraft development and aeronautic research. Hardware-in-the-loop simulations enable examination of single components without the need of a full-scale model of the system. This project investigates the possibility of conducting hardware-in-the-loop simulations using a hydraulic test rig utilizing modern computer equipment. Controllers and models have been built in Simulink and Hopsan. Most hydraulic and mechanical components used in Hopsan have also been translated from Fortran to C and compiled into shared libraries (.dll). This provides an easy way of importing Hopsan models in LabVIEW, which is used to control the test rig. The results have been compared between Hopsan and LabVIEW, and no major differences in the results could be found. Importing Hopsan components to LabVIEW can potentially enable powerful features not available in Hopsan, such as hardware-in-the-loop simulations, multi-core processing and advanced plotting tools. It does however require fast computer systems to achieve real-time speed. The results of this project can provide interesting starting points in the development of the next generation of Hopsan.</p>
526

Wastewater treatment in constructed wetlands : Effects of vegetation, hydraulics and data analysis methods

Bodin, Hristina January 2013 (has links)
Degradation of water resources has become one of the most pressing global concerns currently facing mankind. Constructed Wetlands (CWs) represent a concept to combat deterioration of water resources by acting as buffers between wastewater and receiving water bodies. Still, constructing wetlands for the sole purpose of wastewater treatment is a challenging task. To contribute to this research area, the fundamental question raised in this doctorate thesis was: how do factors such as vegetation and residing water movements (hydraulics) influence wastewater treatment in CWs? Also, effects of different data analysis methods for results of CW hydraulics and wastewater treatment were investigated. Research was focused on  phosphorus (P), ammonium-nitrogen (NH4+-N) and solids (TSS) in wastewater and o n P in macrophyte biomass. Studies were performed in pilot-scale free water surface (FWS) CW systems in Kenya (Chemelil) and Sweden (Halmstad) and as computer simulations. Results from the Chemelil CWs demonstrated that meeting effluent concentration standards simultaneously for all water quality parameters in one CW was difficult. Vegetation harvest, and thus nutrient uptake by young growing macrophytes, was important for maintaining low effluents of NH4+-N and P, especially during dry seasons. On the other hand, mature and dense vegetation growing for at least 4 months secured meeting TSS standards. Phosphorus in above-ground green biomass accounted for almost 1/3 of the total P mass removal, demonstrating high potential for P removal through macrophyte harvest in CWs. Also, results suggested that harvest should be species-specific to achieve high P removal by macrophytes and overall acceptable wastewater treatment in CWs. Still, different methods to estimate evapotranspiration (ET) from the Chemelil CWs showed that water balance calculations greatly impacted estimations of wastewater treatment results. Hydraulic tracer studies performed in the Chemelil and Halmstad CWs showed that mature and dense emergent vegetation in CWs could reduce effective treatment volumes (e-values), which emphasized the importance of regulating this type of vegetation. Also, it was shown that hydraulic tracer studies with lithium chloride performed in CWs with dense emergent vegetation had problems with low tracer recoveries. This problem could be reduced by promoting the distribution of incoming tracer solution into the CW using a barrier near the CW inlet pipe. Computer simulation results showed that the choice of tracer data analysis method greatly influenced quantifications of CW hydraulics and pollutant removal. The e-value could be 50% higher and the pollutant removal 13% higher depending upon used method. Moreover, unrealistic evalues (above 100%) in published literature could to some extent be explained by tracer data analysis method. Hence, to obtain more reliable hydraulic data and wastewater treatment results from CWs, more attention should be paid to the choice of tracer data analysis method. / Konstruerade våtmarker representerar ett koncept för möjligheten att nå en hållbar vattenresurshantering genom att agera som ”filter” mellan föroreningskälla och viktiga vattenresurser såsom sjöar och hav. Mycket kunskap saknas däremot om hur man konstruerar våtmarker med en optimal och pålitlig vattenreningskapacitet. Den här avhandlingen undersöker därför hur vegetation och vattnets väg genom våtmarken (hydrauliken) påverkar avloppsvattenrening i våtmarker. Dessutom undersöktes hur valet av dataanalysmetod av insamlad data påverkar resultaten. Studier genomfördes i Kenya och Sverige i experimentvåtmarker (ca. 40-60 m2) och inkluderadedatainsamling av vattenkvalité, hydraulik (spårämnesexperiment) samt biomassa och fosfor i biomassan av två olika våtmarksväxter. Dessutom genomfördes datorsimuleringar. Resultaten från Kenya visade att växtskörd och efterföljande näringsupptag av nyskördade växter var viktig för att uppnå låga utgående koncentrationer av fosfor och ammonium i en tropisk våtmark, speciellt under torrsäsongen. Däremot var en välutvecklad och tät vegetation viktig för reningen av partiklar. Fosfor i grön växtbiomassa representerade cirka 1/3 av våtmarkernas totala fosforrening, vilket påvisade potentialen i att genom skörd ta bort fosfor från avloppsvatten m.h.a. konstruerade våtmarker. Resultaten pekade också på att skörden bör vara art-specifik för att uppnå en hög fosforrening och generellt bra vattenreningsresultat. Dock visade olika beräkningsmetoder att vattenbalansen i en tropisk våtmark markant kan påverka vattenreningsresultaten. Resultaten från spårämnesexperimenten demonstrerade att den effektiva våtmarksvolymen för vattenrening blev mindre vid hög täthet av övervattensväxter. Detta pekade på att regelbunden växtskörd var viktig för att uppnå god vattenrening i våtmarker. Experiment med spårämnet litium visade att man kan få felaktiga resultat p.g.a. att en del spårämne fasthålls på botten i våtmarken om denna har mycket övervattensväxter. Därför bör spridningen av spårämnet i sådana våtmarker underlättas m.h.a. en spridningsbarriär nära inloppsröret. Simuleringar visade också att valet av dataanalysmetod av spårämnesdata starkt kan påverka resultaten och därmed också vår tolkning av en våtmarks hydraulik och reningskapacitet. Den effektiva volymen kunde vara 50% högre och reningseffekten 13% högre beroende på vilken metod som användes. Likaså kan valet av dataanalysmetod ha bidragit till överskattade och orealistiska effektiva volymer (över 100%) i artiklar publicerade de senaste 25 åren. Genom att fokusera mer på valet av dataanalysmetod och t.ex. jämföra resultaten från två olika metoder kan man minimera risken för bristfälliga resultat och därmed felaktiga slutsatser om en våtmarks vattenreningskapacitet.
527

Hardware-in-the-Loop Simulation of Aircraft Actuator

Braun, Robert January 2009 (has links)
Advanced computer simulations will play a more and more important role in future aircraft development and aeronautic research. Hardware-in-the-loop simulations enable examination of single components without the need of a full-scale model of the system. This project investigates the possibility of conducting hardware-in-the-loop simulations using a hydraulic test rig utilizing modern computer equipment. Controllers and models have been built in Simulink and Hopsan. Most hydraulic and mechanical components used in Hopsan have also been translated from Fortran to C and compiled into shared libraries (.dll). This provides an easy way of importing Hopsan models in LabVIEW, which is used to control the test rig. The results have been compared between Hopsan and LabVIEW, and no major differences in the results could be found. Importing Hopsan components to LabVIEW can potentially enable powerful features not available in Hopsan, such as hardware-in-the-loop simulations, multi-core processing and advanced plotting tools. It does however require fast computer systems to achieve real-time speed. The results of this project can provide interesting starting points in the development of the next generation of Hopsan.
528

A Dredging Knowledge-Base Expert System for Pipeline Dredges with Comparison to Field Data

Wilson, Derek Alan 2010 December 1900 (has links)
A Pipeline Analytical Program and Dredging Knowledge{Base Expert{System (DKBES) determines a pipeline dredge's production and resulting cost and schedule. Pipeline dredge engineering presents a complex and dynamic process necessary to maintain navigable waterways. Dredge engineers use pipeline engineering and slurry transport principles to determine the production rate of a pipeline dredge system. Engineers then use cost engineering factors to determine the expense of the dredge project. Previous work in engineering incorporated an object{oriented expert{system to determine cost and scheduling of mid{rise building construction where data objects represent the fundamental elements of the construction process within the program execution. A previously developed dredge cost estimating spreadsheet program which uses hydraulic engineering and slurry transport principles determines the performance metrics of a dredge pump and pipeline system. This study focuses on combining hydraulic analysis with the functionality of an expert{system to determine the performance metrics of a dredge pump and pipeline system and its resulting schedule. Field data from the U.S. Army Corps of Engineers pipeline dredge, Goetz, and several contract daily dredge reports show how accurately the DKBES can predict pipeline dredge production. Real{time dredge instrumentation data from the Goetz compares the accuracy of the Pipeline Analytical Program to actual dredge operation. Comparison of the Pipeline Analytical Program to pipeline daily dredge reports shows how accurately the Pipeline Analytical Program can predict a dredge project's schedule over several months. Both of these comparisons determine the accuracy and validity of the Pipeline Analytical Program and DKBES as they calculate the performance metrics of the pipeline dredge project. The results of the study determined that the Pipeline Analytical Program compared closely to the Goetz eld data where only pump and pipeline hydraulics a ected the dredge production. Results from the dredge projects determined the Pipeline Analytical Program underestimated actual long{term dredge production. Study results identi ed key similarities and di erences between the DKBES and spreadsheet program in terms of cost and scheduling. The study then draws conclusions based on these ndings and o ers recommendations for further use.
529

Desenvolvimento de um elemento combustível instrumentado para o reator de pesquisa IEA-R1 / Development of an instrumented fuel assembly for the IEA-R1 research reactor

UMBEHAUN, PEDRO E. 21 December 2016 (has links)
Submitted by Marco Antonio Oliveira da Silva (maosilva@ipen.br) on 2016-12-21T17:48:50Z No. of bitstreams: 0 / Made available in DSpace on 2016-12-21T17:48:50Z (GMT). No. of bitstreams: 0 / Após o aumento de potência do reator IEA-R1 de 2 MW para 5 MW observou-se um aumento da taxa de corrosão nas placas laterais de alguns elementos combustíveis e algumas dúvidas surgiram com relação ao valor de vazão utilizada nas análises termo-hidráulicas. A fim de esclarecer e medir a distribuição de vazão real pelos elementos combustíveis que compõe o núcleo do reator IEA-R1, um elemento combustível protótipo, sem material nuclear, chamado DMPV-01 (Dispositivo para Medida de Pressão e Vazão), em escala real, foi projetado e construído em alumínio. A vazão no canal entre dois elementos combustíveis é muito difícil de estimar ou ser medida. Esta vazão é muito importante no processo de resfriamento das placas laterais. Este trabalho apresenta a concepção e construção de um elemento combustível instrumentado para medir a temperatura real nestas placas laterais para melhor avaliar as condições de resfriamento do combustível. Quatorze termopares foram instalados neste elemento combustível instrumentado. Quatro termopares em cada canal lateral e quatro no canal central, além de um termopar no bocal de entrada e outro no bocal de saída do elemento. Existem três termopares para medida de temperatura do revestimento e um para a temperatura do fluido em cada canal. Três séries de experimentos, para três configurações distintas, foram realizadas com o elemento combustível instrumentado. Em dois experimentos uma caixa de alumínio foi instalada ao redor do núcleo para reduzir o escoamento transverso entre os elementos combustíveis e medir o impacto na temperatura das placas externas. Dada a tamanha quantidade de informações obtidas e sua utilidade no projeto, melhoria e capacitação na construção, montagem e fabricação de elementos combustíveis instrumentados, este projeto constitui um importante marco no estudo de núcleos de reatores de pesquisa. As soluções propostas podem ser amplamente utilizadas para outros reatores de pesquisa. / Tese (Doutorado em Tecnologia Nuclear) / IPEN/T / Instituto de Pesquisas Energéticas e Nucleares - IPEN-CNEN/SP
530

Upgrading Biogas to Biomethane Using Absorption / Aufbereitung von Biogas zu Biomethan mittels Absorption

Dixit, Onkar 08 December 2015 (has links) (PDF)
Questions that were answered in the dissertation: Which process is suitable to desulphurize biogas knowing that chemical absorption will be used to separate CO2? Which absorption solvent is suitable to separate CO2 from concentrated gases such as biogas at atmospheric pressure? What properties of the selected solvent, namely aqueous diglycolamine (DGA), are already known? How to determine solvent properties such as equilibrium CO2 solubility under absorption and desorption conditions using simple, but robust apparatuses? What values do solvent properties such as density, viscosity and surface tension take at various DGA contents and CO2 loadings? How do primary alkanolamine content and CO2 loading influence solvent properties? What is the optimal DGA content in the solvent? What is the optimal desorption temperature at atmospheric pressure? How can equilibrium CO2 solubility in aqueous DGA solvents be simulated? What is the uncertainty in the results? How to debottleneck an absorber and increase its gas-treating capacity? How to determine the optimal lean loading of the absorption solvent? What are the characteristics of the absorption process that uses aqueous DGA as the solvent to separate CO2 from biogas and is more energy efficient and safer than the state-of-the-art processes? How to quantitatively compare the hazards of absorption solvents? What is the disposition of the German population towards hazards from biogas plants? What are the favourable and adverse environmental impacts of biomethane? / Fragen, die in der Dissertation beantwortet wurden: Welches Verfahren ist zur Entschwefelung von Biogas geeignet, wenn die chemische Absorption zur CO2-Abtrennung genutzt wird? Welches Absorptionsmittel ist geeignet, um CO2 aus konzentrierten Gasen, wie Biogas, bei atmosphärischem Druck abzutrennen? Welche Eigenschaften des ausgewählten Absorptionsmittels, wässriges Diglykolamin (DGA), sind bereits bekannt? Wie wird die CO2-Gleichgewichtsbeladung unter Absorptions- und Desorptionsbedingungen mit einfachen und robusten Laborapparaten bestimmt? Welche Werte nehmen die Absorptionsmitteleigenschaften wie Dichte, Viskosität und Oberflächenspannung bei verschiedenen DGA-Gehalten und CO2-Beladungen? Wie werden die Absorptionsmitteleigenschaften durch den Primäramin-Gehalt und die CO2-Beladung beeinflusst? Was ist der optimale DGA-Gehalt im Absorptionsmittel? Was ist die optimale Desorptionstemperatur bei atmosphärischem Druck? Wie wird die CO2-Gleichgewichtsbeladung im wässrigen DGA simuliert? Welche Ungenauigkeit ist zu erwarten? Wie wird eine Absorptionskolonne umgerüstet, um die Kapazität zu erweitern? Wie wird die optimale CO2-Beladung des Absorptionsmittels am Absorbereintritt (im unbeladenen Absorptionsmittel) bestimmt? Was sind die Prozesseigenschaften eines Absorptionsverfahrens, das wässriges DGA als Absorptionsmittel nutzt sowie energieeffizienter und sicherer als Verfahren auf dem Stand der Technik ist? Wie kann das Gefahrenpotenzial von Absorptionsmittel quantitativ verglichen werden? Wie werden Gefahren aus einer Biogasanlage durch die deutsche Bevölkerung wahrgenommen? Welche positive und negative Umweltauswirkung hat Biomethan?

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