Polymeric coatings are being used in a growing number of applications, contributing to protection against weather conditions and localized corrosion, reducing the friction and erosion wear on the substrate. In this study, various polypropylene (PP) coatings were applied onto steel substrates by compression molding. Chemical modification of PP has been performed to increase its adhesion to metallic surfaces by grafting of maleic anhydride (MAH) onto PP in the presence of dicumyl peroxide (DCP). Influence of different concentrations of MAH and DCP on the properties of resulting materials have been examined. The coated steel samples are characterized by scanning electron microscopy (SEM), shear adhesion testing, FTIR and tribometry. The coatings with 3 wt. % MAH have shown the maximum adhesion strength due to maximum amount of grafting. The wear rates increased with increasing the amount of MAH due to simultaneous increase in un-reacted MAH.

京都大学 / 0048 / 新制・課程博士 / 博士(理学) / 甲第18787号 / 理博第4045号 / 新制||理||1582(附属図書館) / 31738 / 京都大学大学院理学研究科物理学・宇宙物理学専攻 / (主査)教授 永江 知文, 教授 谷森 達, 准教授 成木 恵 / 学位規則第4条第1項該当 / Doctor of Science / Kyoto University / DGAM

Separatism movements are widespread across the world; however, the European continentcontains several regions who wish to become independent sovereign states. The autonomousregion of Catalonia is one of Europe's many separatist regions, where a separatism movementis present. This study analyses the active separatism of Catalonia, with an emphasis onregional Catalan as well as national Spanish political organization’s attitude towards aCatalan independent state, and also which argument they have regarding an independentCatalonia. The purpose is to describe the regional Catalan as well as the national Spanishpolitical organization’s position within the debate regarding a Catalan separation from Spain.The utilized method for this study is a describing analysis of ideas, in order to analyze andunderstand the empirical material.This essay implements, based on the essay's theoretical framework, two analytical tools inorder to analyze the empirical material of the political organization’s which are two idealtypes of the phenomena nationalism and separatism.The study concludes that the regional Catalan political organizations, CiU and ERC, havemore tendencies of separatism in their pro-independence rhetoric’s, and they have movedaway from their former nationalistic political platforms because of failed dialogs with theSpanish national government. Regarding the national Spanish political organizations, on theother hand, the study concludes that both PSOE and PP have strong tendencies of nationalismin their rhetoric against Catalan independence, much in due to their alignment to the Spanishconstitution and their political goal of a more united Spain.

We introduce the Partition Principle PP, an axiom introduced by Russell in the context of its similarities and differences with the Axiom of Choice AC. We start by proving some properties of PP, and AC, and show that AC, entails PP. To address the problem of whether the converse holds, we develop the Zermelo-Fraenkel ZF set theory and examine its consistency and build a model in which AC, fails. We follow this with a discussion of forcing, a technique introduced by Paul Cohen to build new models of set theory from existing ones, which have differing properties from the starting model. We conclude by examining candidate models called permutation models where AC, fails, which may be useful as candidate models for forcing a model in which PP, holds but AC, does not. We conjecture that such a model exists, and that PP, does not entail AC. / Thesis / Master of Science (MSc)

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The use of plastic materials has changed the packaging industry, the construction industry, the automotive industry, and many others drastically. Plastics are also abundant in our everyday life. However, its downsides in the society are undeniable and are starting to get attention from law makers, the general public and industries alike. Because of their reliance on fossil feedstock and persistence in nature, efforts are being made to make plastics biobased as well as improving recycling of the material. However, the recycling process is complicated, unoptimized and also differs depending on the product and the country. The differences include the techniques and technology used for sorting, the plastics which are prioritized, and where they end up. This project investigated the recyclability of Renol®, a biopolymer based on lignin, a residual product from the forest industry. To do this, first it was established the most interesting viable thermoplastic resin for the Renol was PP. This was because one of the uses for Renol is in plastic packaging, where PP is one of the most recycled materials. Different compositions of the PP/Renol blend were then produced, containing 5, 10, 20, 30 and 50wt% Renol. Density testing and infrared spectroscopy were then used to determine the highest percentage by weight of Renol that could be included for the material to still be detected as PP in a plastics recycling station. For density, the highest concentration was determined to be 46wt% and 27wt%, for sorting methods using 1.00g/cm3 and 0.95g/cm3 as their thresholds, respectively. Using near-infrared technology and computer algorithms by TOMRA (the European company leading the industry in sorting materials), this value decreased to 20wt%. The quality of recycled polypropylene with Renol (Ren25 and Ren50) and without (rPP) was then measured using the tests stated in the RecyClass protocol for PP containers. It was found that both Ren25 and Ren50 had an elongation at break which was too low compared to rPP. There was a woody smell in the materials Ren25 and Ren50. This was reflected in the measurement for volatiles, where the materials were inserted into a 180°C oven and Ren50 lost the most mass out of the three materials. If the material were to be sent to an official recyclability test, it would most likely fail with the elongation at break, the smell and the volatile substances. In a packaging context it would most likely be sorted and recycled as colored PP at a maximum of 20wt% Renol and for other products with PP, most likely at a maximum of 46wt% Renol. / Användandet av plaster har drastiskt förändrat, bland många andra, förpacknings-, bygg- och bilindustrin. Plaster är också oerhört vanliga i vårt vardagliga liv. Dock är deras negativa egenskaper uppmärksammade av allmänheten, industrier samt lagstiftare. På grund av att traditionellt ha varit beroende av icke-förnybara fossila råmaterial samt dess långsamma nedbrytning i naturen studeras möjligheter till att producera biobaserade plaster samt att förbättra återvinningsprocessen för plaster. I praktiken är återvinningen dock komplex och skiljer sig från land till land och produkt till produkt. Teknologier som fungerar på en typ av plast och produkt fungerar inte nödvändigtvis på en annan. Detta projekt undersökte återvinningsgraden av Renol®, en biopolymer baserad på lignin, en restprodukt från skogsindustrin, och en syntetisk polymer. För detta syfte var det polypropen (PP) som valdes som blandpolymer, då PP är en av de mest återvunna polymererna samt att ett av användningsområden av Renol är förpackningar. Olika blandningar av Renol/PP blandningen producerades, med 5, 10, 20, 30 och 50 viktprocent (wt%) Renol vardera. Tester av de olika blandningars densitet samt analys med hjälp av infraröd spektroskopi användes sedan för att bestämma högsta procenthalten Renol materialet kan innehålla och fortfarande detekteras som PP i en återvinningsstation. Genom densitetsproven fastställdes maxkoncentrationen Renol till 46wt% och 27wt%, för sorteringsmetoder som använder 1.00g/cm3 respektive 0.95g/cm3 som tröskelvärden för PP. Genom infraröd teknologi och datoralgoritmer från TOMRA (europeiska ledare i materialsortering) blev maxvärdet fastställt till 20wt%.  Kvaliteten av återvunnen PP (rPP) jämfördes sedan med den av blandningar av rPP och Renol för att se hur deras egenskaper skiljer sig. Materialtester gjordes med hänvisning till de tester RecyClass-protokollet föreslog för PP-förpackningar. Många tester låg inom toleransen, dock var töjningen vid brott lägre hos Renolblandningen. Renol har också en speciell lukt som inte hittas hos ren rPP samt att den ger av mer volatila ämnen än rPP. Skulle materialet alltså skickas till ett officiellt återvinningstest hos RecyClass, skulle det troligen misslyckas på grund av en lägre töjning vid brott, dess lukt samt dess volatila substanser. Skulle materialet användas i en förpackning skulle den med stor sannolikhet sorteras som färgad PP vid en maxhalt av 20wt% Renol och för andra PP-produkter vid ett max av 46wt% Renol. / El uso de materiales plásticos ha cambiado drásticamente la industria de los envases, la de la construcción, la del automóvil y muchas otras. Los plásticos también abundan en nuestra vida cotidiana. Sin embargo, sus desventajas en la sociedad son innegables y están empezando a llamar la atención de los legisladores, el público en general y las industrias por igual. El proceso de reciclaje de plásticos no es sencillo, ya que requiere limpieza, clasificación y compradores dispuestos. También varía según el producto y el país. En este proyecto se investigó la reciclabilidad del Renol®, un biopolímero a base de lignina, un producto residual de la industria forestal. Para ello, primero se estableció que la resina termoplástica viable más interesante para el Renol era el polypropyleno (PP). Esto se debió a que uno de los usos del Renol es en los envases de plástico, donde el PP es uno de los materiales más reciclados. A continuación, se produjeron diferentes composiciones de la mezcla Renol/PP, que contenían 5, 10, 20, 30 y 50wt% de Renol. A continuación, se utilizaron las pruebas de densidad y la espectroscopia de infrarrojos para determinar el mayor porcentaje en peso de Renol que podía incluirse para que el material siguiera detectándose como PP en una estación de reciclaje de plásticos. En cuanto a la densidad, se determinó que la concentración más alta era del 46wt% y del 27wt%, para los métodos de clasificación que utilizan 1,00g/cm3 y 0,95g/cm3 como umbrales, respectivamente. Utilizando la tecnología de infrarrojo cercano y los algoritmos informáticos de TOMRA (la empresa europea líder en el sector de la clasificación de materiales), este valor se redujo al 20wt%. A continuación, se comparó la calidad del PP reciclado (rPP) con mezclas con rPP y Renol para comprobar que el Renol no empeora la calidad de material reciclado. Los ensayos se decidieron en base al protocol RecyClass para envases de PP. Varias propiedades estuvieron dentro de la tolerancia del protocolo, sin embargo el alargamiento de rotura fue menor en la mezcla Renol. El Renol también tenía un olor particular que no se encuentra en el rPP puro y al final libera más sustancias volátiles que el rPP. Por lo tanto, si el material se enviara a una prueba oficial de reciclaje en RecyClass, probablemente fallaría debido a una menor elongación a la rotura, su olor y sus sustancias volátiles. En caso de que el material se utilice en envases, lo más probable es que se clasifique como PP de color con un contenido máximo de 20wt% de Renol y para otros productos de PP con un máximo de 46wt% de Renol.

Neste trabalho estudou-se o comportamento reológico e morfológico da mistura polimérica imiscível de polipropileno e poliamida. Como resultado deste estudo obtiveram-se valores de tensão interfacial entre 10mN/m e 13mN/m. A tensão interfacial diminuiu em até 87% quando a mistura é compatibilizada com polipropileno maleado. A análise morfológica no regime de viscoelasticidade linear quando avaliada uma morfologia de emulsão de poliamida em polipropileno revelou diâmetro médio da fase dispersa entre 1,5µm e 20µm. O diâmetro das gotas da fase dispersa diminuiu com a adição de polipropileno maleado chegando a reduções de até 98%, mantendo-se constante a concentração da fase dispersa. No regime de viscoelasticidade não linear foram testados modelos para avaliar o comportamento da mistura em fluxos de cisalhamento e extensão, sendo que somente para os fluxos de extensão foi obtida boa correlação dos resultados experimentais com as previsões teóricas. / Rheological and morphological behaviour of polypropylene and polyamide polymer blend was studied. The values of interfacial tension were obtained between 10mN/m and 13mN/m. The interfacial tension decreased in 87% for compatibilized blend. Morphology analysis for linear viscoelastic regime shows dispersed drop diameter between 1,5µm and 20µm. The diameter of the drops decreased with the addition of maleic polypropylene reducing until 98%, keeping constant the concentration of the disperse phase. In non linear viscoelastic regime different models were tested to evaluate the behavior of the blends in shear and elongacional flows. However, only the elongacional flow results were acquired with theoretical - experimental corroboration.

In dieser Arbeit studieren wir Lorentz-Mannigfaltigkeiten mit spezieller Holonomie, d.h. ihre Holonomiedarstellung wirkt schwach-irreduzibel aber nicht irreduzibel. Aufgrund der schwachen Irreduzibilität lässt die Darstellung einen ausgearteten Unterraum invariant und damit also auch eine lichtartige Linie. Geometrisch hat dies zur Folge, dass wir zwei parallele Unterbündel (die Linie und ihr orthogonales Komplement) des Tangentialbündels erhalten. Diese Arbeit nutzt diese und weitere Objekte um zu beweisen, dass kompakte Lorentzmannigfaltigkeiten mit Abelscher Holonomie geodätisch vollständig sind. Zudem werden Lorentzmannigfaltigkeiten mit spezieller Holonomie und nicht-negativer Ricci-Krümung auf den Blättern der Blätterung, induziert durch das orthogonale Komplement der parellelen Linie, und maximaler erster Bettizahl untersucht. Schließlich werden vollständige Ricci-flache Lorentzmannigfaltigkeiten mit vorgegebener voller Holonomie konstruiert. / In the present thesis we study dimensional Lorentzian manifolds with special holonomy, i.e. such that their holonomy representation acts indecomposably but non-irreducibly. Being indecomposable, their holonomy group leaves invariant a degenerate subspace and thus a light-like line. Geometrically, this means that, since being holonomy invariant, this line gives rise to parallel subbundles of the tangent bundle. The thesis uses these and other objects to prove that Lorentian manifolds with Abelian holonomy are geodesically complete. Moreover, we study Lorentzian manifolds with special holonomy and non-negative Ricci curvature on the leaves of the foliation induced by the orthogonal complement of the parallel light-like line whose first Betti number is maximal. Finally, we provide examples of geodesically complete and Ricci-flat Lorentzian manifolds with special holonomy and prescribed full holonomy group.