Foram medidas as seções de choque de eletrofissão para os elementos Ta, Au e 182W de 35 MeV a 250 MeV e, através do formalismo dos fótons virtuais, as correspondentes seções de choque de fotofissão foram obtidas por desconvolução. Um método original para extração da energia média de excitação do núcleo composto é apresentado utilizando-se, como dados de entrada, apenas a seção de choque experimental de fotofissão e a probabilidade de fissão calculada. Da energia de excitação foi possível obter-se informações sobre o caminho livre médio do píon, a seção de choque píon-núcleon e o termo complexo do potencial óptico do méson no Au, Ta e 182W. / The electrofission cross sections of Au, Ta and 182W were measured in the energy range 35 - 250 MeV, and the corresponding photofission cross sections were deconvoluted by means of the virtual photon formalism. An original data analysis method was developed which allowed obtaining the excitation energy, using the experimental photofission cross sections and the calculated fission probabilities as inputs. From the excitation energy, plus an approach for the pion-nucleon interaction, the photopion mean free path in Au, Ta and 182W was deduced, along with the main characteristics of the pion-nucleon optical potential.

Estimation of the Radar Cross Section of large inhomogeneous scattering objects such as composite aircrafts, ships and biological bodies at high frequencies has posed large computational challenge. The detection of scattering from wake vortex leading to detection and possible identification of low observable aircrafts also demand the development of computationally efficient and rigorous numerical techniques. Amongst the various methods deployed in Computational Electromagnetics, the Method of Moments predicts the electromagnetic characteristics accurately. Method of Moments is a rigorous method, combined with an array of modeling techniques such as triangular patch, cubical cell and tetrahedral modeling. Method of Moments has become an accurate technique for solving electromagnetic problems from complex shaped homogeneous and inhomogeneous objects. One of the drawbacks of Method of Moments is the fact that it results into a dense matrix, the inversion of which is a computationally complex both in terms of physical memory and compute power. This has been the prime reason for the Method of Moments hitherto remaining as a low frequency method. With recent advances in supercomputing, it is possible to extend the range of Method of Moments for Radar Cross Section computation of aircraft like structures and radiation characteristic of antennas mounted on complex shaped bodies at realistic frequencies of practical interest. This thesis is a contribution in this direction. The main focus of this thesis is development of parallel Method of Moments solvers, applied to solve real world electromagnetic wave scattering and radiation problems from inhomogeneous objects. While the methods developed in this thesis are applicable to a variety of problems in Computational Electromagnetics as shown by illustrative examples, in specific, it has been applied to compute the Radar Cross Section enhancement due to acoustic disturbances and flow inhomogeneities from the wake vortex of an aircraft, thus exploring the possibility of detecting stealth aircraft. Illustrative examples also include the analysis of antenna mounted on an aircraft. In this thesis, first the RWG basis functions have been used in Method of Moments procedure, for solving scattering problems from complex conducting structures such as aircraft and antenna(s) mounted on airborne vehicles, of electrically large size of about 45 and 0.76 million unknowns. Next, the solver using SWG basis functions with tetrahedral and pulse basis functions with cubical modeling have been developed to solve scattering from 3D inhomogeneous bodies. The developed codes are validated by computing the Radar Cross Section of spherical homogeneous and inhomogeneous layered scatterers, lossy dielectric cylinder with region wise inhomogeneity and high contrast dielectric objects. Aerodynamic flow solver ANSYS FLUENT, based on Finite Volume Method is used to solve inviscid compressible flow problem around the aircraft. The gradients of pressure/density are converted to dielectric constant variation in the wake region by using empirical relation and interpolation techniques. Then the Radar Cross Section is computed from the flow inhomogeneities in the vicinity of a model aircraft and beyond (wake zone) using the developed parallel Volume Surface Integral Equation using Method of Moments and investigated more rigorously. Radar Cross Section enhancement is demonstrated in the presence of the flow inhomogeneities and detectability is discussed. The Bragg scattering that occurs when electromagnetic and acoustic waves interact is also discussed and the results are interpreted in this light. The possibility of using the scattering from wake vortex to detect low visible aircraft is discussed. This thesis also explores the possibility of observing the Bragg scattering phenomenon from the acoustic disturbances, caused by the wake vortex. The latter sets the direction for use of radars for target identification and beyond target detection. The codes are parallelized using the ScaLAPACK and BiCG iterative method on shared and distributed memory machines, and tested on variety of High Performance Computing platforms such as Blue Gene/L (22.4TF), Tyrone cluster, CSIR-4PI HP Proliant 3000 BL460c (360TF) and CRAY XC40 machines. The parallelization speedup and efficiency of all the codes has also been shown.

Bien que l’écologie de la truite (Salmo trutta) ait déjà été bien étudiée, les processus expliquant la dynamique spatio-temporelle des populations restent à caractériser. L’objectif de cette thèse était d’identifier les processus démographiques (ex. survie ou déplacements) et l’influence des processus biotiques (interactions entre individus) et abiotiques (conditions environnementales) qui structurent dans le temps et dans l’espace les différentes classes d’âge (alevins, juvéniles et adultes) de ces populations. J’ai étudié l’influence sur la survie apparente de (1) la densité-dépendance et (2) des conditions environnementales vécues directement par les truites (habitat hydraulique et température de l’eau). Pour évaluer la transférabilité des résultats, j’ai évalué (3) l’échelle spatiale (globale ou locale) à laquelle opéraient les processus et (4) si ces processus variaient entre populations (approche hiérarchique). J’ai considéré la dynamique de 45 populations de truites dont 22 sont situées à l’aval d’un ouvrage hydroélectrique. A large échelle, il est apparu que le recrutement de populations séparées par des distances allant jusqu’à 75km peut être synchronisé par de fortes crues lors de l’émergence des alevins ou des déplacements du substrat de ponte. Nous avons synthétisé les résultats de l’application d’un modèle déterministe de dynamique de population, calibrés localement sur neuf stations aux conditions environnementales bien caractérisées. Cette synthèse a montré que des processus locaux influençaient directement la dynamique des populations. Enfin, la construction d’un modèle hiérarchique a montré le rôle structurant de la mortalité densité-dépendante des juvéniles et des adultes, dont l’intensité augmentait en l’absence d’abris (<2% de la surface) ou variait avec la température de l’eau (diminution pour les juvéniles et augmentation pour les adultes). Ce travail fournit des bases scientifiques aux gestionnaires d’ouvrages hydro-électriques pour leur permettre de limiter leur influence sur les populations de poissons et répondre ainsi aux demandes réglementaires / Brown trout (Salmo trutta) ecology was largely studied. However, the process structuring the spatiotemporal patterns of population dynamics remains unclear. The objective of this thesis was to identify the demographic processes (e.g. survival or displacements) and the influence of biotic (between-individuals interactions) and abiotic (environmental conditions) processes structuring the age-stages (fry, juveniles and adults) of these populations in time and space.I studied (1) the role of density-dependence on survival and (2) the influence of environmental conditions experienced by trouts (hydraulics and water temperature). To assess the results’ transferability, I studied (3) the spatial scale (global or local) of influence of the processes and (4) if those processes varied among populations (hierarchical approach).I considered the dynamics of 45 trout populations, 22 being located downstream a hydropower facility. At a large scale, the recruitment of distant populations (up to 75 km apart) may be synchronized by large floods during emergence of fry or by spawning substratum displacements. We summarized the results of a determinist population dynamics models, locally calibrated on nine reaches showing well-described environmental conditions. This summary revealed the influence of various local drivers on population dynamics. Finally, a hierarchical model showed that density-dependent mortality among juveniles and adults was a key biotic process. The strength of the competition was greater in absence of shelter (<2% of the surface) and varied with water temperature (decreasing for juveniles and increasing for adults).The results of this work will provide scientific basis to hydropower facility managers. This will help them to reduce their influence on trout populations and respond to regulatory demands

The thesis contains four essays covering topics in the field of macroeconomic forecasting.<p><p>The first two chapters consider factor models in the context of real-time forecasting with many indicators. Using a large number of predictors offers an opportunity to exploit a rich information set and is also considered to be a more robust approach in the presence of instabilities. On the other hand, it poses a challenge of how to extract the relevant information in a parsimonious way. Recent research shows that factor models provide an answer to this problem. The fundamental assumption underlying those models is that most of the co-movement of the variables in a given dataset can be summarized by only few latent variables, the factors. This assumption seems to be warranted in the case of macroeconomic and financial data. Important theoretical foundations for large factor models were laid by Forni, Hallin, Lippi and Reichlin (2000) and Stock and Watson (2002). Since then, different versions of factor models have been applied for forecasting, structural analysis or construction of economic activity indicators. Recently, Giannone, Reichlin and Small (2008) have used a factor model to produce projections of the U.S GDP in the presence of a real-time data flow. They propose a framework that can cope with large datasets characterised by staggered and nonsynchronous data releases (sometimes referred to as “ragged edge”). This is relevant as, in practice, important indicators like GDP are released with a substantial delay and, in the meantime, more timely variables can be used to assess the current state of the economy.<p><p>The first chapter of the thesis entitled “A look into the factor model black box: publication lags and the role of hard and soft data in forecasting GDP” is based on joint work with Gerhard Rünstler and applies the framework of Giannone, Reichlin and Small (2008) to the case of euro area. In particular, we are interested in the role of “soft” and “hard” data in the GDP forecast and how it is related to their timeliness.<p>The soft data include surveys and financial indicators and reflect market expectations. They are usually promptly available. In contrast, the hard indicators on real activity measure directly certain components of GDP (e.g. industrial production) and are published with a significant delay. We propose several measures in order to assess the role of individual or groups of series in the forecast while taking into account their respective publication lags. We find that surveys and financial data contain important information beyond the monthly real activity measures for the GDP forecasts, once their timeliness is properly accounted for.<p><p>The second chapter entitled “Maximum likelihood estimation of large factor model on datasets with arbitrary pattern of missing data” is based on joint work with Michele Modugno. It proposes a methodology for the estimation of factor models on large cross-sections with a general pattern of missing data. In contrast to Giannone, Reichlin and Small (2008), we can handle datasets that are not only characterised by a “ragged edge”, but can include e.g. mixed frequency or short history indicators. The latter is particularly relevant for the euro area or other young economies, for which many series have been compiled only since recently. We adopt the maximum likelihood approach which, apart from the flexibility with regard to the pattern of missing data, is also more efficient and allows imposing restrictions on the parameters. Applied for small factor models by e.g. Geweke (1977), Sargent and Sims (1977) or Watson and Engle (1983), it has been shown by Doz, Giannone and Reichlin (2006) to be consistent, robust and computationally feasible also in the case of large cross-sections. To circumvent the computational complexity of a direct likelihood maximisation in the case of large cross-section, Doz, Giannone and Reichlin (2006) propose to use the iterative Expectation-Maximisation (EM) algorithm (used for the small model by Watson and Engle, 1983). Our contribution is to modify the EM steps to the case of missing data and to show how to augment the model, in order to account for the serial correlation of the idiosyncratic component. In addition, we derive the link between the unexpected part of a data release and the forecast revision and illustrate how this can be used to understand the sources of the<p>latter in the case of simultaneous releases. We use this methodology for short-term forecasting and backdating of the euro area GDP on the basis of a large panel of monthly and quarterly data. In particular, we are able to examine the effect of quarterly variables and short history monthly series like the Purchasing Managers' surveys on the forecast.<p><p>The third chapter is entitled “Large Bayesian VARs” and is based on joint work with Domenico Giannone and Lucrezia Reichlin. It proposes an alternative approach to factor models for dealing with the curse of dimensionality, namely Bayesian shrinkage. We study Vector Autoregressions (VARs) which have the advantage over factor models in that they allow structural analysis in a natural way. We consider systems including more than 100 variables. This is the first application in the literature to estimate a VAR of this size. Apart from the forecast considerations, as argued above, the size of the information set can be also relevant for the structural analysis, see e.g. Bernanke, Boivin and Eliasz (2005), Giannone and Reichlin (2006) or Christiano, Eichenbaum and Evans (1999) for a discussion. In addition, many problems may require the study of the dynamics of many variables: many countries, sectors or regions. While we use standard priors as proposed by Litterman (1986), an<p>important novelty of the work is that we set the overall tightness of the prior in relation to the model size. In this we follow the recommendation by De Mol, Giannone and Reichlin (2008) who study the case of Bayesian regressions. They show that with increasing size of the model one should shrink more to avoid overfitting, but when data are collinear one is still able to extract the relevant sample information. We apply this principle in the case of VARs. We compare the large model with smaller systems in terms of forecasting performance and structural analysis of the effect of monetary policy shock. The results show that a standard Bayesian VAR model is an appropriate tool for large panels of data once the degree of shrinkage is set in relation to the model size. <p><p>The fourth chapter entitled “Forecasting euro area inflation with wavelets: extracting information from real activity and money at different scales” proposes a framework for exploiting relationships between variables at different frequency bands in the context of forecasting. This work is motivated by the on-going debate whether money provides a reliable signal for the future price developments. The empirical evidence on the leading role of money for inflation in an out-of-sample forecast framework is not very strong, see e.g. Lenza (2006) or Fisher, Lenza, Pill and Reichlin (2008). At the same time, e.g. Gerlach (2003) or Assenmacher-Wesche and Gerlach (2007, 2008) argue that money and output could affect prices at different frequencies, however their analysis is performed in-sample. In this Chapter, it is investigated empirically which frequency bands and for which variables are the most relevant for the out-of-sample forecast of inflation when the information from prices, money and real activity is considered. To extract different frequency components from a series a wavelet transform is applied. It provides a simple and intuitive framework for band-pass filtering and allows a decomposition of series into different frequency bands. Its application in the multivariate out-of-sample forecast is novel in the literature. The results indicate that, indeed, different scales of money, prices and GDP can be relevant for the inflation forecast.<p> / Doctorat en Sciences économiques et de gestion / info:eu-repo/semantics/nonPublished

Abstract : Deterioration of concrete structures reinforced with steel bars can be seen daily in regions with aggressive weather as steel-corrosion problems worsen. Fiber-reinforced-polymers (FRP) reinforcement has proven its feasibility through different civil structural elements. Present guidelines for FRP structures in North-America and Europe have not yet handled axially loaded members, due to the lack of research and experiments. This research takes charge of providing experimental database as well as extensive analyses and design recommendations of circular concrete columns reinforced totally with different FRP bars and spirals/hoops (FRP-RC columns). Full-scale columns were tested under monotonic loading with different levels of eccentricity. Test variables included the eccentricity-to-diameter ratio (e/D); reinforcement type (GFRP and CFRP vs. steel); concrete strength; longitudinal and transverse reinforcement ratio; and confinement configuration. All specimens measured 305 mm diameter and 1500 mm height. Test results indicated that specimens reinforced with glass-FRP (GFRP) or carbon-FRP (CFRP) reached their peak strengths with no damages to GFRP or CFRP rebar on either side of specimens. Specimens with CFRP reinforcement (CFRP-RC) behaved very similarly to their steel counterparts, and achieved almost the same nominal axial forces. Specimens with GFRP reinforcement (GFRP-RC) exhibited, however, reduced stiffness and achieved lower nominal axial forces than their steel or CFRP counterparts. Failure of GFRP-RC and CFRP-RC specimens was dominated by concrete crushing at low levels of eccentricity (e/D ratios of 8.2% and 16.4%). Experimental strain results revealed that GFRP bars developed high levels of strains and stresses on the compression and tension sides and hence the GFRP-RC specimens could sustain constant axial load after peak for some time up to the limit of concrete crushing at higher levels of eccentricity (e/D ratios of 8.2% and 16.4%), which help to delay the full damage. At these levels, flexural–tension failure initiated in the GFRP-RC specimens resulting from large axial and lateral deformations and cracks on the tension side until secondary compression failure occurred due to strain limitations in concrete and degradation of the concrete compressive block. The failure of CFRP-RC specimens at higher levels of eccentricity (e/D ratios of 8.2% and 16.4%) was characterized as flexural–compression in which it took place in a less brittle manner. On the other hand, this research also included different studies to analyze the test results, evaluate rebar efficiency, and provide recommendations for analysis and design. It was, therefore, indicated that the axial and flexural capacities of the tested FRP-RC specimens could be reasonably predicted using plane sectional analysis, utilizing the equivalent rectangular stress block (ERSB) parameters given by the ACI 440.1R-15 or CSA S806-12. All predictions underestimated the actual strength with variable levels of conservatism ranged between 1.05 to 1.25 for the GFRP-RC specimens and between 1.20 to 1.40 for the CFRP-RC specimens. These levels were noticeably reduced to critical limits in specimens with high-strength concretes. An elaborate review was made to the available ERSB parameters in the present steel and FRP design standards and guidelines. Modified expressions of the ERSB given in ACI 440.1R-15 and CSA S806-12 were developed. The results indicated good correlation of predicted and measured strength values with enhanced levels of conservatism. Additionally, sets of axial force–bending moment (P-M) interaction diagrams and indicative bar charts are introduced, and recommendations drawn. The compressive-strength contribution of FRP reinforcement was thoroughly reviewed and discussed. The minimum GFRP and CFRP reinforcement ratios to avoid rebar rupturing were broadly examined. Finally, the flexure stiffness (EI) of the tested specimens was analytically determined and compared with the available expressions using experimental and analytical M-ψ responses. Proposed equations are developed and validated against the experimental results to represent the stiffness of GFRP-RC and CFRP-RC columns at service and ultimate levels. / La détérioration des structures en béton armé avec des barres d’armature d’acier peut être observée quotidiennement dans les régions à climat agressif. Le renforcement interne en polymères renforcés de fibres (PRF) a démontré sa faisabilité grâce à différents éléments structuraux en génie civil. Les lignes directrices actuelles pour les structures en béton armé de PRF en Amérique du Nord et en Europe n'ont pas encore gérées les sections soumises à des efforts axiaux excentrique, en raison du manque de recherches et d'expériences. Cette recherche permet d’augmenter la base de données expérimentales ainsi établir des analyses approfondies et des recommandations de conception pour les colonnes circulaires en béton armé complètement renforcées de PRF (barres et spirales). Des grandeur-nature colonnes ont été testées sous charge monotone avec différents niveaux d'excentricité. Les variables de test comprenaient le rapport excentricité / diamètre (e/D) ; le type de renfort (PRFV et PRFC comparativement à l’acier); la résistance du béton en compression; le taux d’armature longitudinal et transversal; et la configuration de l’armature de confinement. Tous les échantillons mesuraient 305 mm de diamètre et 1500 mm de hauteur. Les résultats des tests ont indiqué que les spécimens renforcés avec des PRF de verre ou des PRF de carbone atteignaient leur résistance maximale sans endommager les barres d’armature. Des deux types de renforcement, les spécimens de PRFCCFRP se comportaient de manière très similaire à leurs homologues en acier et atteignaient presque les mêmes résistances axiales. Cependant, les spécimens avec renforcement en PRFV ont présenté une rigidité réduite et des forces axiales nominales inférieures à celles de leurs homologues en acier ou en PRFC. Le mode de rupture des spécimens de PRFC et de PRFV a été dominé par l’écrasement du béton à de faibles niveaux d'excentricité (rapports e/D de 8,2% et 16,4%). Les résultats ont révélé que les barres de PRFV ont développé des niveaux élevés de déformations et de contraintes sur les faces en compression et en tension et, par conséquent, les spécimens de PRFVC pourraient supporter une charge axiale constante après la résistance ultime pendant un certain temps jusqu'à la limite de la rupture en compression du béton du noyau à des niveaux supérieurs d'excentricité (rapport e/D de 8,2% et 16,4%), ce qui contribue à retarder la dégradation. À ces niveaux, une rupture en tension a été initiée dans les spécimens de PRFV résultant à de grandes déformations axiales et latérales et des fissures du côté de la face en tension jusqu'à ce que la rupture en compression du béton. La rupture des spécimens de PRFC à des niveaux supérieurs d'excentricité (rapport e/D de 8,2% et 16,4%) a été caractérisé comme étant en compression du béton dans laquelle il s'est déroulé de manière moins fragile. D'autre part, cette recherche comprenait également différentes études pour analyser les résultats des tests, évaluer l'efficacité des barres d'armature et fournir des recommandations pour l'analyse et la conception. Il a donc été indiqué que les capacités axiales et de flexion des spécimens en PRF testées pourraient être raisonnablement prédites en utilisant une analyse en section plane, en utilisant les paramètres du bloc de contrainte rectangulaire équivalent (BCRE) donnés par l'ACI 440.1R-15 ou la CSA S806- 12. Toutes les prédictions ont sous-estimé la résistance réelle avec des niveaux de variabilité conservateur entre 1,05 et 1,25 pour les spécimens de PRFC et entre 1,20 et 1,40 pour les spécimens de PRFC. Ces niveaux ont été nettement réduits à des limites critiques dans les spécimens avec des bétons à haute résistance. Un examen approfondi a été effectué sur les paramètres du BCRE disponibles dans les normes et les directives de conception actuelles en acier et en PRF. Les expressions modifiées du BCRE fournies dans ACI 440.1R-15 et CSA S806-12 ont été développées. Les résultats indiquent une bonne corrélation entre les valeurs de résistance prédites et mesurées avec des niveaux accrus de conservatisme. La contribution de la résistance à la compression du renforcement en PRF a été soigneusement examinée et discutée. Le taux d’armature minimum de PRFV et de PRFC pour éviter la rupture de l'armature ont été largement examinés. Enfin, la rigidité en flexion (EI) des spécimens testés a été déterminée de manière analytique et comparée aux expressions disponibles dans la littérature en utilisant les réponses expérimentales et analytiques M-ψ. Les expressions modifiées de la rigidité en flexion EI apportées dans l’ACI 440.1R ont été développées et validées.

[pt] Um resultado clássico da teoria de grupos de Lie garante que as órbitas da ação adjunta de um grupo de Lie compacto interceptam um toro máximo ortogonalmente. Esta ação é um exemplo das chamadas ações polares. Ações polares são ações de grupos compactos de isometrias que admitem seções (subvariedades totalmente geodésicas que interceptam as órbitas ortogonalmente). Ações polares e subvariedades isoparamétricas são casos particulares das chamadas folheações riemannianas singulares com seções,assunto que é estudado nesta tese. Além de apresentarmos resultados sobre essas folheações singulares apresentamos também resultados sobre as chamadas aplicações transnormais (generalizações das aplicações isoparamétricas) destacando como estes objetos estão relacionados. / [en] It follows from the classical Lie group theory that the orbits of an adjoint action of a compact Lie group intercept a maximal toru in a orthogonal way. This is an example of the so called Polar Action. A compact isometric action is said to be Polar if it admits sections, i.e. totally geodesic submanifolds that intercept the orbits orthogonally. Polar Actions and isoparametric manifolds are examples of a more general structure, the so called singular Riemannian Foliation with Section, the main subject of the thesis. Besides the results about these singular foliations we show also some results about transnormal maps (generalization of isoparametric maps) and stress the its connections with the singulare riemannian foliation with section.

A detailed reactor core modeling of the LOVIISA-2 PWR and FORSMARK-3BWR was performed in the Serpent 2 Continuous Energy Monte-Carlocode.Both models of the reactors were completed but the approximations ofthe atomic densities of nuclides present in the core differedsignificantly.In the LOVIISA-2 PWR, the predicted atomic density for the nuclidesapproximated by Chebyshev Rational Approximation method (CRAM)coincided with the corrected atomic density simulated by the Serpent2 program. In the case of FORSMARK-3 BWR, the atomic density fromCRAM poorly approximated the data returned by the simulation inSerpent 2. Due to boiling of the moderator in the core of FORSMARK-3,the model seemed to encounter problems of fission density, whichyielded unusable results.The results based on the models of the reactor cores are significantto the FANCSEE Nuclear fuel cycle simulator, which will be used as adataset for the nuclear fuel cycle burnup in the reactors. / FANCSEE

Philosophiae Doctor - PhD / The study outlines five areas of intervention in the development of women studies and politics on the continent. Firstly, it examines the problematic construction and the inclusion of women in the narratives of the liberation struggle in South Africa. Secondly, the study identifies the sphere of intellectual debates as one of the crucial sites in the production of historical knowledge about the legacies of liberation struggles on the continent. Thirdly, it traces the intellectual trajectory of Charlotte Maxeke as an embodiment of the intellectual contributions of women in the struggle for liberation in South Africa. In this regard, the study traces Charlotte Maxeke as she deliberated and engaged on matters pertaining to the welfare of the Africans alongside the prominent intellectuals of the twentieth century. Fourthly, the study inaugurates a theoretical departure from the documentary trends that define contemporary studies on women and liberation movements on the continent. Fifthly, the study examines the incorporation of Maxeke's legacy of active intellectual engagement as an integral part of gender politics in the activities of the Women's Section of the African National Congress. In the areas identified, the study engages with the significance of the intellectual inputs of Charlotte Maxeke in South African history. / South Africa

Magister Legum - LLM / Crime victims once played a prominent role in the criminal justice system. Historically, victims who sought to bring their wrongdoers to justice conducted their own investigations and argued their own cases or employed others to do so. As time passed, a distinction was drawn between offences against the social order and disputes between individuals. Crime control became a function of government and the state increased its responsibility for the investigation and punishment of criminal conduct. Gradually, the victim was removed from the proceedings and relegated to serving as a witness for the state. The assumption was that the state, whilst representing the interests of society, would represent the interests of the victim also. This fallacy provided the foundation for a criminal justice which, until recently, encourage victim exclusion. In recent years, there has been a clear trend towards re-introducing the right of victims to participate in the criminal justice process. This international trend has been labelled the „return of the victim‟. In South Africa, the Constitution and, in particular, the Bill of Rights contained therein underscore the move towards procedural rights for victims of crime. Moreover, the South African government has taken significant legislative steps to ensure that victims have formal rights in criminal justice proceedings. However, to date, comparatively little attention has been paid to the question of whether or not victims should be allowed a meaningful role in the process of plea and sentence negotiations. One of the aims of this study is to determine whether victims‟ rights are properly understood, defined and implemented within the criminal justice system. In particular, this study aims to clarify the rights of victims who find themselves affiliated with a specific stage of criminal prosecution, namely, negotiated justice.

A study of defects in semiconductors is vital as defects tend to influence device operation by modifying their electrical and optoelectronic properties. This influence can at times be desirable in the case of fast switching devices and sometimes undesirable as they may reduce the efficiency of optoelectronic devices. ZnO is a wide bandgap material with a potential for fabricating UV light emitting diodes, lasers and white lighting devices only after the realization of reproducible p-type material. The realization of p-type material is greatly affected by doping asymmetry. The self-compensation behaviour by its native defects has hindered the success in obtaining the p-type material. Hence there is need to understand the electronic properties, formation and annealing-out of these defects for controlled material doping. Space charge spectroscopic techniques are powerful tools for studying the electronic properties of electrically active defects in semiconductors since they can reveal information about the defect “signatures”. In this study, novel Schottky contacts with low leakage currents of the order of 10-11 A at 2.0 V, barrier heights of 0.60 – 0.80 eV and low series resistance, fabricated on hydrogen peroxide treated melt-grown single crystal ZnO samples, were demonstrated. Investigations on the dependence of the Schottky contact parameters on fabrication techniques and different metals were performed. Resistive evaporation proved to produce contacts with lower series resistance, higher barrier heights and low reverse currents compared to the electron-beam deposition technique. Deep level transient spectroscopy (DLTS) and Laplace-DLTS have been employed to study the electronic properties of electrically active deep level defects in ZnO. Results revealed the presence of three prominent deep level defects (E1, E2 and E3) in the as-received ZnO samples. Electron-beam deposited contacts indicated the presence of the E1, E2 and E3 and the introduction of new deep level defects. These induced deep levels have been attributed to stray electrons and ionized particles, present in the deposition system during contact fabrication. Exposure of ZnO to high temperatures induces deep level defects. Annealing samples in the 300°C – 600°C temperature range in Ar + O2 induces the E4 deep level with a very high capture cross-section. This deep level transforms at every annealing temperature. Its instability at room temperature has been demonstrated by a change in the peak temperature position with time. This deep level was broad, indicating that it consists of two or more closely spaced energy levels. Laplace-DLTS was successfully employed to resolve the closely spaced energy levels. Annealing samples at 700°C in Ar and O2 anneals-out E4 and induces the Ex deep level defect with an activation enthalpy of approximately 160 – 180 meV. Vacuum annealing performed in the 400°C – 700°C temperature range did not induce any deep level defects. Since the radiation hardness of ZnO is crucial in space applications, 1.6 MeV proton irradiation was performed. DLTS revealed the introduction of the E4 deep level with an activation enthalpy of approximately 530 meV, which proved to be stable at room temperature and atmospheric pressure since its properties didn’t change over a period of 12 months. / Thesis (PhD)--University of Pretoria, 2013. / Physics / unrestricted