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21	Análise dos efeitos da borracha moída de pneu e do resíduo de óleo de xisto sobre algumas propriedades mecânicas de misturas asfáticas densas / Analysis of the effects of crumb rubber and shale-oil residue on mechanical properties of asphalt mixtures Fernanda Pilati 27 March 2008 (has links) No Brasil, desde o início da década de 1990, vêm sendo desenvolvidas pesquisas sobre aplicação do asfalto-borracha visando tanto a diminuição dos problemas ambientais gerados pelo descarte de pneus inservíveis, como a melhoria das características dos ligantes produzidos. Dentro desse contexto, esta pesquisa teve por objetivo avaliar o desempenho mecânico de oito misturas asfálticas do tipo concreto asfáltico usinado a quente, produzidas com asfaltos convencional e convencional modificado com borracha de pneu e resíduo de óleo de xisto. Quanto ao ligante, foram utilizados 8 tipos, a saber: CAP 30/45 (referência); dois ligantes empregando teores diferentes de borracha moída de pneu; outros dois com teores distintos de resíduo de óleo de xisto e, por fim, mais três com combinações de teores de borracha e de resíduo de óleo de xisto. Os corpos-de-prova empregados nos ensaios foram moldados em cinco teores diferentes de ligantes asfálticos (4,5; 5,0, 5,5; 6,0 e 6,5%). Conseqüentemente, foram realizados ensaios Marshall, resistência à tração, módulo de resiliência e umidade induzida. Com base nos resultados dos ensaios realizados observou-se que tanto a borracha quanto o óleo reduzem a resistência à tração e o módulo de resiliência das misturas, no entanto, na recuperação retardada, os efeitos da borracha e do óleo são antagônicos, diminuindo e aumentando, respectivamente. Ademais, quanto à suscetibilidade à ação da água, as misturas com adição de óleo apresentaram menor suscetibilidade que as misturas com adição de borracha. Além disso, foi observado que todas as misturas estudadas, exceto aquelas com altas concentrações de óleo e de borracha, atenderam os requisitos estabelecidos pelas especificações, para as propriedades analisadas. Todavia, em alguns casos, considerando os efeitos antagônicos do óleo e da borracha, algumas combinações entre ambos podem ser realizadas, com a finalidade de alcançar os níveis desejados para as propriedades do ligante asfalto-borracha e das misturas asfálticas. / In Brazil, since the beginning of the 90\'s, have been developed researches on the application of asphalt-rubber seeking the reduction of environmental problems created by the used tires, and the improvement of the characteristics of the produced binder. Taking this into account, the purpose of this research is to evaluate the mechanical performance of eight hot mix asphalt concretes, produced with conventional asphalt and modified asphalt with crumb rubber and shale-oil residue. Eight types of binders were used: CAP 30/45 (reference); two binders using different crumb rubber contents, two with different shale-oil residue contents, and finally three more with the combination of crumb rubber and shale-oil residue contents. The specimens used in the laboratorial tests were compacted in five different binders contents (4.5; 5.0, 5.5; 6.0 e 6.5%). Hence, the tests performed are: Marshall test, indirect tension, resilient modulus and moisture induced. The results showed that the rubber and the shale oil reduce the indirect tension and resilience module of the mixtures, however, on the delayed recover, the effects of the rubber and of the shale oil are opposed, decreasing and increasing it, respectively. Moreover, for the moisture susceptibility, the mixtures with shale-oil residue exhibited less susceptibility to water than those with crumb rubber. Furthermore, all the studied mixtures, except those with high shale-oil residue and rubber concentrations, they got to attend the established requirements for the specifications, for the analyzed properties. Although, in some cases, considering the opposed effects of the shale oil and of the crumb rubber, some combinations between both can be accomplished, with the purpose of reach the levels wanted for the properties of the asphaltrubber binder and the asphalt mixtures. Also regression models were elaborated as for the analyzed properties. The results obtained of modeling were satisfactory. Asfalto-borracha Experimentos com misturas Misturas asfálticas densas Processo úmido Propriedades mecânicas Resíduo de óleo de xisto Crumb-rubber Experiments with mixtures Hot mix asphalt Mechanical properties Shale-oil residue Wet process
22	Evaluation of the fatigue performance of fine aggregate matrices prepared with reclaimed asphalt pavements and shale oil residue / Avaliação do dano por fadiga em matrizes de agregado fino preparadas com misturas asfálticas fresadas e resíduo de óleo de xisto Andrise Buchweitz Klug 22 August 2017 (has links) The incorporation of recycled asphalt pavements (RAP) in the production of new asphalt mixtures is a useful alternative to the use of virgin materials, leading to economic and environmental savings. Pavement recycling created a sustainable cycle of reuse of nonrenewable natural resources, reducing the demand for new mineral aggregate and binder. However, the addition of RAP, especially at higher percentages, increases the stiffness of the asphalt mixture, because of the high stiffness of the aged binder. High stiffness makes the asphalt mixtures more prone to fatigue cracking. In order to overcome such limitation and allow the incorporation of higher percentages of RAP, soften binders or rejuvenating agents are added to the mixture. The former act to reduce the high stiffness of the aged binder and the latter act to restore the aged binder properties to those required by the binder specifications. The shale oil residue is one of the most used rejuvenating agents in Brazil, and, according to the literature, its performance is comparable to other commercial rejuvenating agents, with the advantage of presenting higher rejuvenating potential, what is due to its higher aromaticity. The fatigue cracking process starts as micro cracks in the fine aggregate matrix (FAM) of the full asphalt mixture. One approach to investigate the fatigue process of the asphalt mixtures is based on the viscoelastic continuum damage theory (VECD), in which the process of micro cracking of a material can be represented by internal state variables associated with the reduction of the material integrity. In this study, tests on FAM samples were performed in order to evaluate the fatigue performance, and the results were analyzed by means of the VECD theory. The objective of this research was to evaluate the fatigue performance of FAMs produced with three RAP contents (20, 40 and 100%), two binders of different performance grades (PG 64-22 and PG 58-16), and the combination of new binder (PG 64-22) and rejuvenating agent (shale oil residue) at different binder/agent rates (100/0, 50/50 and 0/100). Out of the FAMs prepared with RAP, two presented fatigue performance superior to the control mixture (compounded with only new materials): the FAM prepared with 40% of RAP and PG 64-22 and the FAM prepared with 20% of RAP and PG 58-16. The shale oil residue did not play its role of rejuvenating the aged binder for most cases, probably because of the low diffusion rate of the material into the aged binder. / A incorporação de misturas asfálticas fresadas na produção de misturas asfálticas novas é uma alternativa útil à utilização de materiais novos, gerando benefícios econômicos e ambientais. A reciclagem de pavimentos criou um ciclo sustentável de reuso de recursos naturais não-renováveis, reduzindo a demanda por agregado mineral e asfalto novos. No entanto, a adição do material fresado, especialmente em proporções altas, provoca aumento na rigidez da mistura asfáltica, causado pela alta rigidez do asfalto envelhecido. Uma elevada rigidez pode tornar a mistura asfáltica mais propensa ao trincamento por fadiga. Para contornar tal desvantagem e permitir a adição de maiores quantidades de material fresado, asfaltos de baixa consistência e agentes de rejuvenescimento podem ser adicionados à mistura. Os asfaltos de baixa consistência atuam para reduzir a rigidez do asfalto envelhecido e os agentes de rejuvenescimento atuam para restaurar as propriedades originais do asfalto envelhecido, aproximando-as das exigidas pelas especificações para asfaltos virgens. O resíduo de óleo de xisto é um dos agentes rejuvenescedores mais utilizados no Brasil e, segundo a literatura, resulta em desempenho comparável ao desempenho de outros agentes rejuvenescedores comerciais, com a vantagem de apresentar maior poder de rejuvenescimento devido à sua maior aromaticidade. O processo de trincamento por fadiga principia nas microtrincas presentes na matriz de agregado fino (MAF) da mistura asfáltica. Uma abordagem para avaliar o comportamento à fadiga das misturas asfálticas é baseada na teoria do dano contínuo em meio viscoelástico, pela qual o processo de trincamento do material é representado por variáveis de estado interno associadas à redução na integridade do material. Neste estudo, ensaios em amostras de MAF foram feitos para caracterizar o desempenho à fadiga, e os dados foram analisados utilizando a teoria do dano contínuo em meio viscoelástico. O objetivo da pesquisa foi avaliar o desempenho à fadiga de MAFs produzidas com três proporções de material fresado (20, 40 e 100%), dois asfaltos com diferentes graus de desempenho (PG 64-22 e PG 58-16), e três combinações (100/0, 50/50, 0/100) de asfalto PG 64-22 e agente de rejuvenescimento (resíduo de óleo de xisto). Dentre as MAFs preparadas com material fresado, duas apresentaram desempenho à fadiga superior à mistura de controle (composta apenas com materiais novos): a MAF composta com 40% de material fresado e PG 64-22 e a MAF composta com 20% de material fresado e PG 58-16. O resíduo de óleo de xisto não atuou como rejuvenescedor do asfalto envelhecido, para a maioria dos casos avaliados, provavelmente devido à baixa taxa de difusão do material no asfalto envelhecido. Matrizes de agregado fino Misturas asfálticas fresadas Resíduo de óleo de xisto Fine aggregate matrices Reclaimed asphalt pavements Shale oil residue
23	Pressure Normalization of Production Rates Improves Forecasting Results Lacayo Ortiz, Juan Manuel 16 December 2013 (has links) New decline curve models have been developed to overcome the boundary-dominated flow assumption of the basic Arps’ models, which restricts their application in ultra-low permeability reservoirs exhibiting long-duration transient flow regimes. However, these new decline curve analysis (DCA) methods are still based only on production rate data, relying on the assumption of stable flowing pressure. Since this stabilized state is not reached rapidly in most cases, the applicability of these methods and the reliability of their solutions may be compromised. In addition, production performance predictions cannot be disassociated from the existing operation constraints under which production history was developed. On the other hand, DCA is often carried out without a proper identification of flow regimes. The arbitrary application of DCA models regardless of existing flow regimes may produce unrealistic production forecasts, because these models have been designed assuming specific flow regimes. The main purpose of this study was to evaluate the possible benefits provided by including flowing pressures in production decline analysis. As a result, it have been demonstrated that decline curve analysis based on pressure-normalized rates can be used as a reliable production forecasting technique suited to interpret unconventional wells in specific situations such as unstable operating conditions, limited availability of production data (short production history) and high-pressure, rate-restricted wells. In addition, pressure-normalized DCA techniques proved to have the special ability of dissociating the estimation of future production performance from the existing operation constraints under which production history was developed. On the other hand, it was also observed than more consistent and representative flow regime interpretations may be obtained as diagnostic plots are improved by including MBT, pseudovariables (for gas wells) and pressure-normalized rates. This means that misinterpretations may occur if diagnostic plots are not applied correctly. In general, an improved forecasting ability implies greater accuracy in the production performance forecasts and more reliable reserve estimations. The petroleum industry may become more confident in reserves estimates, which are the basis for the design of development plans, investment decisions, and valuation of companies’ assets. Flow regime identification boundary-dominated flow boundary dominated flow transient flow regime unconventional reservoirs rate transient analysis shale gas shale oil production forecasting reserves estimation hindcasting hindcasts low permeability tight sands high pressure rate controlled unstable flowing conditions.
24	Kurz- und langfristige Angebotskurven für Rohöl und die Konsequenzen für den Markt Schlothmann, Daniel 20 April 2016 (has links) (PDF) In dieser Arbeit wurden Angebotskurven für 22 bedeutende Ölförderländer ermittelt und anschließend zu globalen Angebotskurven aggregiert. Gemäß den ermittelten Angebotskurven sind nahezu alle gegenwärtig in der Förderphase befindlichen Ölprojekte in den Untersuchungsländern auch beim aktuellen Ölpreis von 35 bis 40 US-$ je Barrel unter Berücksichtigung der kurzfristigen Grenzkosten rentabel. Sollte der Ölpreis jedoch in den kommenden Jahren auf diesem Niveau verharren, wird es bis zum Jahr 2024 zu einem Angebotsengpass auf dem globalen Ölmarkt kommen, da zur Deckung der zukünftigen Nachfrage die Erschließung kostenintensiver, unkonventioneller Lagerstätten und von Lagerstätten in tiefen und sehr tiefen Gewässern notwendig ist. Damit es bis zum Jahr 2024 nicht zu einem solchen Angebotsengpass kommt, ist gemäß des ermittelten langfristigen Marktgleichgewichts ein Ölpreis von mindestens 80 (2014er) US-$ je Barrel notwendig. Ölmarkt Ölangebot Ölpreis Angebotskurven Grenzkosten Ölförderung Ölprojekte konventionelle Ölförderung unkonventionelle Ölförderung Schweröl. Schwerstöl Ölsand Schieferöl Ölschiefer Tight Oil Offshore Onshore Tiefwasser Fördermethoden in-situ mining Tagebau Fracking EOR Enhanced Oil Recovery hydraulic fracturing Exploration Erschließung Förderung OPEC Algerien Angola Ecuador Iran Irak Libyen Nigeria Katar Kuwait Saudi-Arabien Vereinigte Arabische Emirate Venezuela USA Kanada Mexiko Brasilien Großbritannien Norwegen Aserbaidschan Kasachstan Russland China oil market oil supply supply curves marginal costs oil production oil projects conventional oil unconventional oil extra heavy oil oil sands tight oil shale oil oil shale offshore onshore pre-salt in-situ mining hydraulic fracturing EOR enhanced oil recovery exploration development production OPEC Algeria Angola Ecuador Iran Iraq Libya Qatar Kuwait Saudi Arabia United Arab Emirates Venezuela United States Canada Mexico Brazil United Kingdom Norway Azerbaijan Kazakhstan Russia China ddc:330 rvk:QR 534 Welt Erdöllagerstätte Erdölproduktion Fördermenge Erdölangebot Erdölpreis Erdölweltmarkt Grenzkosten Marktgleichgewicht Preissteigerung Erdölbohrung Tagebau Fracking Ölsand Schieferöl
25	Kurz- und langfristige Angebotskurven für Rohöl und die Konsequenzen für den Markt Schlothmann, Daniel 08 March 2016 (has links) In dieser Arbeit wurden Angebotskurven für 22 bedeutende Ölförderländer ermittelt und anschließend zu globalen Angebotskurven aggregiert. Gemäß den ermittelten Angebotskurven sind nahezu alle gegenwärtig in der Förderphase befindlichen Ölprojekte in den Untersuchungsländern auch beim aktuellen Ölpreis von 35 bis 40 US-$ je Barrel unter Berücksichtigung der kurzfristigen Grenzkosten rentabel. Sollte der Ölpreis jedoch in den kommenden Jahren auf diesem Niveau verharren, wird es bis zum Jahr 2024 zu einem Angebotsengpass auf dem globalen Ölmarkt kommen, da zur Deckung der zukünftigen Nachfrage die Erschließung kostenintensiver, unkonventioneller Lagerstätten und von Lagerstätten in tiefen und sehr tiefen Gewässern notwendig ist. Damit es bis zum Jahr 2024 nicht zu einem solchen Angebotsengpass kommt, ist gemäß des ermittelten langfristigen Marktgleichgewichts ein Ölpreis von mindestens 80 (2014er) US-$ je Barrel notwendig.:1. Einleitung 2. Rohöl - Eine naturwissenschaftliche Einführung 3. Charakteristika von Rohölprojekten 4. Historie der Ölindustrie 5. Ökonomik von Rohölprojekten 6. Fallstudien zu den bedeutendsten Förderländern 7. Ermittlung regionaler und globaler Angebotskurven 8. Zusammenfassung info:eu-repo/classification/ddc/330 ddc:330

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