Biological invasions are among the leading causes of species diversity loss; however, the impacts of invasion are context-dependent and can vary with the local environment. The mechanisms governing variation in impact and their relationship to specific abiotic and biotic factors remain largely unexplored. Recent local declines in native unionid mussels have been attributed to the invasion of North American lakes and rivers by the Eurasian zebra mussel ( Dreissena polymorpha), as a result of intense fouling of unionid shells by zebra mussels. My research investigated the role of abiotic and biotic factors in mediating the impact of zebra mussels on native mussels. I examined the impact of zebra mussels on unionids in a habitat thought to be suboptimal for zebra mussels and compared this to the impact observed in other invaded habitats. A predictive model relating fouling intensity to local environmental variables (calcium concentration, sediment particle size) was developed, and a predator-exclusion experiment was conducted to investigate the role of predation in mediating fouling intensity. Overall, I found that two abiotic factors of the local environment were significant predictors of fouling intensity and that relationships used to predict the impact of zebra mussels could be extended to a broader range of habitats.

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Haptic mice, computer mice modified to have a tactile display, have been developed to enable access to computer graphics by individuals who are blind or visually impaired. Although these haptic mice are potentially very helpful and have been frequently used by the research community, there are some fundamental problems with the mouse, limiting its acceptance. In this paper we have identified the problems and have suggested solutions using one haptic mouse, the VT Player. We found that our modified VT Player showed significant improvement both in terms of the odds of obtaining a correct responses and the time to perform the tasks.

N-Heterocyclic carbenes (NHCs) are good ligands to most transition metals forming stable complexes. Many of the NHC-metal complexes are now widely used catalysts. However, the usage of these catalysts encounters the general problems associated with homogeneous catalysis: the purification of the catalysis reaction products is often time-consuming and generates large amounts of waste. Moreover, the toxic or expensive catalysts are difficult to be separated, recycled, and reused. Chapters II and III of this dissertation focus on addressing these problems through the development of an easier and “greener” process to improve the usage of some NHC-metal complexes. Polymer-supported catalysts and polymer-supported sequestrants were prepared and used to facilitate the separation/recycling of catalysts and the purification of products. These polymer-supported ligands, catalysts, and sequestrants showed comparable reactivity to their low molecular weight counterparts and had different solubility properties due to the nature of polymers. Using these materials with the corresponding operations provides simple methods to separate deeply colored, metal-containing by-products from the reaction mixtures. Chapter IV of this dissertation aims at solving a fundamental question about the nature of NHC-silver(I) complexes. The NHC-silver(I) complex is an important synthetic intermediate as it can be used to prepare other NHC-metal complexes through transmetallation. The carbene carbon of an NHC-silver(I) complex in 13C NMR spectra was usually reported as a doublet of doublets or as a singlet in different cases. This phenomenon was explained with a ligand exchange mechanism proposed twelve years ago. However, few reports are available in the literature about the mechanism of the NHC ligand exchange processes at silver. In order to facilitate the study of the solution behaviors of NHC-silver(I) complexes, 13C-labeled NHC-silver(I) complexes were prepared and studied using variable temperature 13C NMR spectroscopy. This study could be useful for future applications of ligand transferring from silver to other metals for the preparation of NHC-metal complexes.

Circuit designers perform optimization procedures targeting speed and power during the design of a circuit. Gate sizing can be applied to optimize for speed, while Dual-VT and Dynamic Voltage Scaling (DVS) can be applied to optimize for leakage and dynamic power, respectively. Both gate sizing and Dual-VT are design-time techniques, which are applied to the circuit at a fixed voltage. On the other hand, DVS is a run-time technique and implies that the circuit will be operating at a different voltage than that used during the optimization phase at design-time. After some analysis, the risk of non-critical paths becoming critical paths at run-time is detected under these circumstances. The following questions arise: 1) should we take DVS into account during the optimization phase? 2) Does DVS impose any restrictions while performing design-time circuit optimizations?. This thesis is a case study of applying DVS to a circuit that has been optimized for speed and power, and aims at answering the previous two questions. We used a 45-nm CMOS design kit and flow. Synthesis, placement and routing, and timing analysis were applied to the benchmark circuit ISCAS?85 c432. Logical Effort and Dual-VT algorithms were implemented and applied to the circuit to optimize for speed and leakage power, respectively. Optimizations were run for the circuit operating at different voltages. Finally, the impact of DVS on circuit optimization was studied based on HSPICE simulations sweeping the supply voltage for each optimization. The results showed that DVS had no impact on gate sizing optimizations, but it did on Dual-VT optimizations. It is shown that we should not optimize at an arbitrary voltage. Moreover, simulations showed that Dual-VT optimizations should be performed at the lowest voltage that DVS is intended to operate, otherwise non-critical paths will become critical paths at run-time.

Today’s business’s more and more depend on information systems to give them edge on competition and keep double digit growth rates needed to satisfy shareholders. And information systems, serving their needs, have to keep up with changing business requirements. Business Rules Approach [10] seems to be the answer to their demands, but not many service and solution providers can satisfy their needs, because there is no standard based software engineering process to efficiently provide solution to customers. This works provides methodology of integrating business rules approach into existing and time proven software development process as well as providing needed infrastructure to creating solution specification and integrating externalized business rules with created system specification. This work concentrates on tasks: 1. Creating business rules management model; 2. Selecting software development process, adaptable to business rules approach; 3. Integrating business rules management model into selected software development process; 4. Relating externalized business rules with specification entities; 5. Providing comparison of unmodified software process with provided proposal.

Wind Energy facilities are becoming a more common occurrence among the U.S. landscape. The shift to renewable from non-renewable energy sources is an important agenda item for energy policy in the 21st century. Unlike other forms of energy, the unique visual aspects of wind energy provide opportunities to engage with and actually view the process of energy production. The sculptural element of turbines and their placement in highly visible areas, such as mountain ridges, provides opportunities of environmental interpretation and public interaction. Although existing security and safety precautions in the U.S. do not allow public use of these facilities, the integration of turbines into public places is becoming more common in other parts of the world. This creative project focuses on developing dynamic and unique cultural places that also serve as education spaces to celebrate wind and wind energy. Environmental art installations among the wind turbines serve as human-scaled interpretational guides to create meaningful, learning experiences between the user, the wind and the landscape.This project highlights the existing eleven-turbine (6MW) facility in the town of Searsburg in southern Vermont. This project includes inventory, analysis and site design of an existing wind facility. The methodology includes using GIS data and existing sight line data, as well as significant and environmental cultural points. Finally, general guidelines are included as a design foundation for other wind energy facilities. / Department of Landscape Architecture

Thin Film Transistors (TFTs) are widely used in large area electronics because they offer the advantage of low cost fabrication and wide substrate choice. TFTs have been conventionally used for switching applications in large area display arrays. But when it comes to designing a sensor actuator system on a flexible substrate comprising entirely of organic and inorganic TFTs, there are two main challenges – i) Fabrication of complementary TFT devices is difficult ii) TFTs have a drift in their threshold voltage (VT) on application of gate bias. Also currently there are no circuit simulators in the market which account for the effect of VT drift with time in TFT circuits. The first part of this thesis focuses on integrating the VT shift model in the commercially available AIM-Spice circuit simulator. This provides a new and powerful tool that would predict the effect of VT shift on nodal voltages and currents in circuits and also on parameters like small signal gain, bandwidth, hysteresis etc. Since the existing amorphous silicon TFT models (level 11 and level 15) of AIM-Spice are copyright protected, the open source BSIM4V4 model for the purpose of demonstration is used. The simulator is discussed in detail and an algorithm for integration is provided which is then supported by the data from the simulation plots and experimental results for popular TFT configurations. The second part of the thesis illustrates the idea of using negative feedback achieved via contact resistance modulation to minimize the effect of VT shift in the drain current of the TFT. Analytical expressions are derived for the exact value of resistance needed to compensate for the VT shift entirely. Circuit to realize this resistance using TFTs is also provided. All these are experimentally verified using fabricated organic P-type Copper Phthalocyanine (CuPc) and inorganic N-type Tin doped Zinc Oxide (ZTO) TFTs. The third part of the thesis focuses on building a robust amplifier using these TFTs which has time invariant DC voltage level and small signal gain at the output. A differential amplifier using ZTO TFTs has been built and is shown to fit all these criteria. Ideas on vertical routing in an actual sensor actuator interface using this amplifier have also been discussed such that the whole system may be “tearable” in any contour. Such a sensor actuator interface can have varied applications including wrap around thermometers and X-ray machines.

Accurate phase behavior modeling of hydrocarbon and aqueous mixtures plays a critical role in simulation of compositional flow in subsurface reservoirs, such as miscible gas flooding and CO2 sequestration. As Michelsen proposed his groundbreaking works in stability test and phase split calculation, PT flash calculation has been well developed in the past four decades and become the most popular flash technique. However, as research interests move to more complicated reservoir fluids, some inherent drawbacks of PT flash formulations show up and recent researches focus on a promising alternative called VT flash calculation. In this thesis, VT flash calculation is used in place of PT flash to model phase behaviors of hydrocarbon and aqueous mixtures. A dynamical model, together with a thermodynamically stable numerical algorithm, is developed to calculate equilibrium phase amounts and compositions with/without capillary effect to simulate phase behaviors of unconventional/conventional hydrocarbon mixtures. In order to model water-containing mixtures, the cubic equation of state is replaced by the Cubic-PlusAssociation equation of state, and a salt-based Cubic-Plus-Association model is developed to calculate phase behaviors of CO2-brine systems. The combination of VT flash calculation and the salt-based Cubic-Plus-Association model accurately estimate CO2 solubility in both single- and mixed-salt solutions, and it exhibits close prediction accuracy with a more sophisticated electrolyte Cubic-Plus-Association model. At the end, the ultimate goal is to develop an efficient two-phase VT-flash compositional flow algorithm. The multilayer nonlinear elimination method is used to remove locally high nonlinearities based on the feedback of intermediate Newton solutions. To further improve the computational efficiency, a modified shadow region method is used to bypass unnecessary stability tests. Although nonlinear elimination fails to fully resolve the convergence issue, which roots in the nondifferentiable equilibrium pressure at the points of phase boundary, the number of time refinements is significantly reduced and the improved VT-flash compositional flow algorithm with multilayer nonlinear elimination method successfully simulates a number of numerical examples with and without gravity.

The target of this work is to created balance comparIsion of versions of high speed and standard speed HP parts of steam turbine and for the more suitable version to make optimization. Optimization consists of flow part, choosen profile blades and construction calculations. Control calculations for rotor and pipeline were made in order to draw longitudinal section of HP part.