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Understanding Drop-on-Demand Inkjet Process Characteristics in the Application of Printing Micro Solid Oxide Fuel CellsHill, Theresa Y. 29 August 2019 (has links)
No description available.
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Scandia And Ceria Stabilized Zirconia Based Electrolytes And Anodes For Intermediate Temperature Solid Oxide Fuel Cells: Manufacturing And PropertiesChen, Yan 01 January 2013 (has links)
Mesoscale optical phenomena occur when light interacts with a number of different types of materials, such as biological and chemical systems and fabricated nanostructures. As a framework, mesoscale optics unifies the interpretations of the interaction of light with complex media when the outcome depends significantly upon the scale of the interaction. Most importantly, it guides the process of designing an optical sensing technique by focusing on the nature and amount of information that can be extracted from a measurement. Different aspects of mesoscale optics are addressed in this dissertation which led to the solution of a number of problems in complex media. Dynamical and structural information from complex fluids—such as colloidal suspensions and biological fluids—was obtained by controlling the size of the interaction volume with low coherence interferometry. With this information, material properties such as particle sizes, optical transport coefficients, and viscoelastic characteristics of polymer solutions and blood were determined in natural, realistic conditions that are inaccessible to conventional techniques. The same framework also enabled the development of new, scale-dependent models for several important physical and biological systems. These models were then used to explain the results of some unique measurements. For example, the transport of light in disordered photonic lattices was interpreted as a scale-dependent, diffusive process to explain the anomalous behavior of photon path length distributions through these complex structures. In addition, it was demonstrated how specialized optical measurements and models at the mesoscale enable solutions to fundamental problems in cell biology. Specifically, it was found for the first time that the nature of cell motility changes markedly with the curvature of the substrate that the cells iv move on. This particular work addresses increasingly important questions concerning the nature of cellular responses to external forces and the mechanical properties of their local environment. Besides sensing of properties and modeling behaviors of complex systems, mesoscale optics encompasses the control of material systems as a result of the light-matter interaction. Specific modifications to a material’s structure can occur due to not only an exchange of energy between radiation and a material, but also due to a transfer of momentum. Based on the mechanical action of multiply scattered light on colloidal particles, an optically-controlled active medium that did not require specially tailored particles was demonstrated for the first time. The coupling between the particles and the random electromagnetic field affords new possibilities for controlling mesoscale systems and observing nonequilibrium thermodynamic phenomena
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Computational Fluid Dynamics Modelling of Solid Oxide Fuel Cell StacksNishida, Robert Takeo 02 October 2013 (has links)
Two computational fluid dynamics models are developed to predict the performance of a solid oxide fuel cell stack, a detailed and a simplified model. In the detailed model, the three dimensional momentum, heat, and species transport equations are coupled with electrochemistry. In the simplified model, the diffusion terms in the transport equations are selectively replaced by rate terms within the core region of the stack. This allows much coarser meshes to be employed at a fraction of the computational cost. Following the mathematical description of the problem, results for single-cell and multi-cell stacks are presented. Comparisons of local current density, temperature, and cell voltage indicate that good agreement is obtained between the detailed and simplified models, verifying the latter as a practical option in stack design. Then, the simplified model is used to determine the effects of utilization on the electrochemical performance and temperature distributions of a 10 cell stack. The results are presented in terms of fluid flow, pressure, species mass fraction, temperature, voltage and current density distributions. The effects of species and flow distributions on electrochemical performance and temperature are then analyzed for a 100 cell stack. The discussion highlights the importance of manifold design on performance and thermal management of large stacks. / Thesis (Master, Mechanical and Materials Engineering) -- Queen's University, 2013-09-30 15:55:18.627
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Untersuchungen zu den Eigenschaften der Anode der Festoxid-Brennstoffzelle (SOFC)Stübner, Ralph 25 May 2002 (has links) (PDF)
This thesis investigates the electrical and electrochemical properties and the long-term stability of anodes of the solid oxide fuel cell (SOFC). A model is suggested, which describes the impedance spectra of symmetrical anode cells. According to this, the series resistance in the spectra is caused by the resistance of the electrolyte (YSZ), ohmic parts of the anodes, which are described as porous electrodes, and by the partial contacting of the anodes. A major contribution to it is provided by the nickel matrix in the anodes. The high frequency relaxation in the spectra is assigned to the transfer reaction, the low frequency to a gas diffusion inhibition along the gas supply channels. The degradation of the symmetrical anode cells, which has been observed in long-term experiments, is ascribed to a degradation of the electrolyte material, of the transfer reaction, of the nickel matrix in the anodes and of the contact resistance between the anodes and the current collecting nickel grids. The degradation rate of the last two depends on the gas composition. A model for the observed behaviour in time is presented. / Diese Arbeit untersucht die elektrischen und elektrochemischen Eigenschaften und die Langzeitbeständigkeit der Anoden von Festoxid-Brennstoffzellen (SOFC). Ein Modell wird vorgestellt, mit dem die Impedanzspektren symmetrischer Anodenzellen beschrieben werden können. Demnach ist der Serienwiderstand in den Spektren verursacht durch den Widerstand des Elektrolyten (YSZ), ohmsche Anteile in den Anoden, die als poröse Elektroden beschrieben werden, und durch die partielle Kontaktierung der Anoden. Maßgebliche Beiträge liefert hier die Nickelmatrix in den Anoden. Die hochfrequente Relaxation in den Spektren wird der Durchtrittsreaktion, die niederfrequente einer Gasdiffusionshemmung entlang der Gasversorgungskanäle zugeordnet. Die in Langzeitversuchen beobachtete Degradation der symmetrischen Anondenzellen wird zurückgeführt auf eine Degradation des Elektrolytmaterials, der Durchtrittsreaktion, der Nickelmatrix in den Anoden und des Kontaktwiderstandes zwischen den Anoden und den stromabnehmenden Nickelnetzen. Die Degradation der beiden letzteren ist in ihrer Rate abhängig von der Gaszusammensetzung. Ein Modell für das beobachtete zeitliche Verhalten wird vorgestellt.
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Stabilité et vieillissement des études de nickelates base praséodyme comme cathodes pour oxyde solide piles à combustible / Stability and ageing studies of praseodymium-based nickelates as cathodes for Solid Oxide Fuel CellsVibhu, Vaibhav 12 February 2016 (has links)
Ce travail de thèse est consacré à l’étude des nickelates La2-xPrxNiO4+δ, comme nouveaux matériauxde cathodes pour piles à combustible haute température, SOFC, et en particulier à la caractérisationde leur stabilité chimique et leur comportement en fonctionnement. En effet, du fait de leurpropriété de conduction mixte ionique et électronique, MIEC, les nickelates de structure typeK2NiF4, Ln2NiO4+δ (Ln = La, Pr, Nd), correspondant au terme n = 1 de la série de Ruddlesden-Popper (An+1MnO(3n+1)), sont des matériaux prometteurs pour des fonctionnements à températureintermédiaire, IT-SOFC (T < 800 °C). Compromis entre la stabilité chimique de La2NiO4+δ et lestrès bonnes performances électrochimiques de Pr2NiO4+δ, les phases La2-xPrxNiO4+δ, ont étésynthétisées et leurs propriétés physico-chimiques, de transport et électrochimiques ont étédéterminées. L’étude approfondie des caractéristiques des électrodes par spectroscopied’impédance en cellules symétriques a été réalisée à courant nul et sous polarisation anodique etcathodique sur des périodes d’un mois. De façon surprenante, même après la dissociation complètede Pr2NiO4+δ en PrNiO3-δ, Pr4Ni3O10+δ et Pr6O11, la résistance de polarisation ne montre pas dechangement significatif. L’étude de PrNiO3-δ et Pr4Ni3O10+δ, comme matériau de cathode pour pilesà combustible, démontre l’excellent comportement de la phase Pr4Ni3O10+δ et ceci en cellulesymétrique (Rp (Pr4Ni3O10+δ) = Rp (Pr2NiO4+δ) = 0.15 Ω.cm² à 600 ° C) et cellule complète (1.6W.cm-2 at 800 °C). / This PhD work is dedicated to stability and ageing studies of Praseodymium based nickelates ascathodes for Solid Oxide Fuel Cells (SOFCs). With this respect Ln2NiO4+δ (Ln=La, Pr or Nd)compounds with the K2NiF4 type structure act as alternative cathode materials for IT-SOFC due totheir mixed ionic and electronic conductivity (i.e. MIEC properties). Pr2NiO4+δ shows excellentelectrochemical properties at intermediate temperature (i.e. low polarization resistance Rp value, Rp= 0.03 Ω.cm² at 700 °C), while La2NiO4+δ exhibits higher chemical stability. So, the properties ofLa2-xPrxNiO4+δ nickelates were investigated with the aim to find best compromise between chemicalstability and electrochemical performances. After synthesis, the physical and chemical properties aswell as their transport and electrochemical properties have been determined. Measurements of thepolarization resistance of symmetrical half-cells have been carried out by impedance spectroscopy.Then, the chemical stability and the electrochemical performance of the materials have been studiedfor duration up to one month. As an interesting point, even after complete dissociation of Pr2NiO4+δinto PrNiO3-δ,Pr4Ni3O10+δ and Pr6O11, the polarization resistance does not show significant change.So finally, two new materials PrNiO3-δ and Pr4Ni3O10+δ were investigated as SOFCs cathodeshowing very promising results for Pr4Ni3O10+δ in symmetrical cell (Rp (Pr4Ni3O10+δ) = Rp(Pr2NiO4+δ) = 0.15 Ω.cm² à 600 ° C) and complete cell (1.6 W.cm-2 at 800 °C).
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Coupling fluid flow, heat and mass transfer with thermo-mechanical process : application to cracked solid oxide fuel cell / Couplage d'écoulement fluide, de transfert de masse et de chaleur avec des processus thermo-mécaniques : application aux piles à combustible Oxyde Solide fissurées (SOFC)Shao, Qian 24 March 2015 (has links)
Au cours des dernières décennies, les piles à combustible à oxyde solide sont devenues un dispositif prometteur de conversion d’énergie. Ceci est dû principalement à leur efficacité de conversion d’énergie, leur flexibilité du choix du carburant et leurs faibles émissions de polluants. Cependant, la température de fonctionnement élevée de cette variante de piles à combustible induit divers problèmes d’endommagement et de fissuration. Par conséquent, l’optimisation de leur durée de vie reste un problème à résoudre. Dans cette thèse, une approche numérique combinant la méthode des éléments finis (FEM) et la méthode des éléments finis étendus (XFEM) est développée. Le but est de modéliser le problème multi-physique comportant: l’écoulement du fluide, le transfert de la chaleur, le transfert de masse, les réactions électrochimiques et thermomécanique dans une unité de pile à combustible. Dans un premier temps, pour prédire la distribution de la température et des espèces dans le milieu poreux des électrodes, un modèle de Darcy-Brinkman (DB) couplant l’écoulement du gaz, le transfert de chaleur et le transport de masse est développé. Ensuite, la méthode XFEM est introduite pour modéliser la présence des fissures dans les électrodes. Le modèle DB-XFEM combiné est utilisé par la suite pour étudier l’effet de l’écoulement du fluide, le transfert de chaleur et des propriétés thermomécaniques du matériau sur la nucléation et la propagation des fissures. Enfin, un modèle électrochimique (EC) est développé et combiné avec le modèle DB pour étudier les performances de conversion d’énergie dans la cellule de la pile à combustible. / Over the last few decades, Solid Oxide Fuel Cell (SOFC) has been a promising energy conversion device that has drawn a lot of attention due to its high energy conversion efficiency, fuel flexibility and low pollutant emission. However, as the high operating temperature leads to complex material problems in the SOFC, the energy conversion efficiency and life expectancy optimization remain as the challenging issues regarding the design and manufacturing of fuel cells. In this thesis, a numerical approach based on a combination of Finite Element (FEM) and eXtended Finite Element (XFEM) methods is developed to model the coupled fluid flow, heat and mass transfer as well as the electrochemical reactions with thermo-mechanical process in the SOFC unit. At first, to predict the temperature and species distribution within the porous electrodes of a SOFC unit, a Darcy-Brinkman (DB) model coupling the gas flow, heat and mass transport in porous media is developed. Then, the XFEM is introduced to deal with the presence of crack in the porous electrodes. The combined DB-XFEM model is used to investigate the effect of fluid flow, heat transfer, porous material properties and the material anisotropy on the onset of crack growth and the propagation path in the SOFC unit. At last, an electrochemistry (EC) model is developed and combined with the DB model to couple the electrochemical reactions to energy and mass transfer in the SOFC. With the DB-EC model, the cell energy conversion performances are studied.
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Structure and Properties Investigations of the La2Co1+z(Ti1-xMgx)1-zO6 Perovskite System / Struktur och Egenskapsundersökningar av La2Co1+z(Ti1-xMgx)1-zO6 Perovskit SystemetShafeie, Samrand January 2011 (has links)
Perovskite based materials have great potentials for various energy applications and the search for new materials for uses in SOFCs has largely been concentrated to this class of compounds. In this search, we have studied perovskite phases in the system La2Co1+z(Ti1-xMgx)1-zO6, with 0 x 0.9 and z = 0.0, 0.2, 0.4, 0.6. Crystal structures were characterized by XRD and, for selected compositions, also by NPD and SAED. They exhibit with increasing x, as well as increasing z, a progressive increase in symmetry from monoclinic to orthorhombic to rhombohedral. The main focus in this work has been on the investigation of structure-property relations for compositions with 0.0 x 0.5 and z = 0. The nominal oxidation state of Co increases for these with increasing x, from Co2+ for x = 0 to Co3+ for x = 0.5. Magnetic measurements and XANES studies showed that the average spin state of Co changes linearly with increasing x, up to x = 0.5, in accordance with varying proportions of Co with two fixed oxidation states, i.e. Co2+ and Co3+. The data suggests that the Co3+ ions have an IS spin state or a mixture of LS and HS spin states for all compositions with nominally only Co2+ and Co3+ ions, possibly with the exception of the composition with x = 0.1, 0.2 and z = 0, for which the data indicate that the spin state might be HS. The XANES data indicate furthermore that for the perovskite phases with z = 0 and x > 0.5, which in the absence of O atom vacancies contain formally Co4+, the highest oxidation state of Co is Co3+, implying that the substitution of Ti4+ by Mg2+ for x ³ 0.5 effects an oxidation of O2- ions rather than an oxidation of Co3+ ions. The thermal expansion was found to increase nearly linearly with increasing oxidation state of Co. This agrees well with findings in previous studies and is attributable to an increase in the ionic radius of Co3+ ions with increasing temperature, due to a thermal excitation from a LS to IS or LS/HS spin states. High temperature electronic conductivity measurements indicate that the electronic conductivity increases with an increase of both relative and absolute amount of Co3+. The latter can be attributed to an increase in the number of Co-O-Co connections. Additional high temperature magnetic measurements for selected samples, whose susceptibilities did not follow a Curie law behaviour up to room temperature, showed effective magnetic moments that did approach plateaus even at high temperatures (900 K). Interpretations of these data are, however, hindered by the samples losing oxygen during the applied heating-cooling cycle. The present study has shown that the investigated system is suitable for further studies, of more fundamental character, which could provide further insight of the structure-property relationships that depend on the oxidation state of Co. / Studies of cobalt based perovskites for cathode materials in solid oxide fuel cells.
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Untersuchungen zu den Eigenschaften der Anode der Festoxid-Brennstoffzelle (SOFC)Stübner, Ralph 16 January 2002 (has links)
This thesis investigates the electrical and electrochemical properties and the long-term stability of anodes of the solid oxide fuel cell (SOFC). A model is suggested, which describes the impedance spectra of symmetrical anode cells. According to this, the series resistance in the spectra is caused by the resistance of the electrolyte (YSZ), ohmic parts of the anodes, which are described as porous electrodes, and by the partial contacting of the anodes. A major contribution to it is provided by the nickel matrix in the anodes. The high frequency relaxation in the spectra is assigned to the transfer reaction, the low frequency to a gas diffusion inhibition along the gas supply channels. The degradation of the symmetrical anode cells, which has been observed in long-term experiments, is ascribed to a degradation of the electrolyte material, of the transfer reaction, of the nickel matrix in the anodes and of the contact resistance between the anodes and the current collecting nickel grids. The degradation rate of the last two depends on the gas composition. A model for the observed behaviour in time is presented. / Diese Arbeit untersucht die elektrischen und elektrochemischen Eigenschaften und die Langzeitbeständigkeit der Anoden von Festoxid-Brennstoffzellen (SOFC). Ein Modell wird vorgestellt, mit dem die Impedanzspektren symmetrischer Anodenzellen beschrieben werden können. Demnach ist der Serienwiderstand in den Spektren verursacht durch den Widerstand des Elektrolyten (YSZ), ohmsche Anteile in den Anoden, die als poröse Elektroden beschrieben werden, und durch die partielle Kontaktierung der Anoden. Maßgebliche Beiträge liefert hier die Nickelmatrix in den Anoden. Die hochfrequente Relaxation in den Spektren wird der Durchtrittsreaktion, die niederfrequente einer Gasdiffusionshemmung entlang der Gasversorgungskanäle zugeordnet. Die in Langzeitversuchen beobachtete Degradation der symmetrischen Anondenzellen wird zurückgeführt auf eine Degradation des Elektrolytmaterials, der Durchtrittsreaktion, der Nickelmatrix in den Anoden und des Kontaktwiderstandes zwischen den Anoden und den stromabnehmenden Nickelnetzen. Die Degradation der beiden letzteren ist in ihrer Rate abhängig von der Gaszusammensetzung. Ein Modell für das beobachtete zeitliche Verhalten wird vorgestellt.
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Phase formation and structural transformation of strontium ferrite SrFeOxSchmidt, Marek, Wojciech, Marek.Schmidt@rl.ac.uk January 2001 (has links)
Non-stoichiometric strontium iron oxide is described by an abbreviated formula SrFeOx (2.5 ≤ x ≤ 3.0) exhibits a variety of interesting physical and chemical properties over a broad range of temperatures and in different
gaseous environments. The oxide contains a mixture of iron in the trivalent and the rare tetravalent state. The material at elevated temperature is a mixed oxygen conductor and it, or its derivatives,can have practical
applications in oxygen conducting devices such as pressure driven oxygen
generators, partial oxidation reactors in electrodes for solid oxide fuel cells
(SOFC).
¶
This thesis examines the behaviour of the material at ambient and elevated temperatures using a broad spectrum of solid state experimental
techniques such as: x-ray and neutron powder diffraction,thermogravimetric and calorimetric methods,scanning electron microscopy and Mossbauer
spectroscopy. Changes in the oxide were induced using conventional thermal
treatment in various atmospheres as well as mechanical energy (ball milling).
The first experimental chapter examines the formation of the ferrite from
a mixture of reactants.It describes the chemical reactions and phase transitions that lead to the formation of the oxide. Ball milling of the reactants prior to annealing was found to eliminate transient phases from the reaction route and to increase the kinetics of
the reaction at lower temperatures.
Examination of the thermodynamics of iron oxide (hematite) used for the
reactions led to a new route of synthesis of the ferrite frommagnetite and
strontium carbonate.This chapter also explores the possibility of synthesis
of the material at room temperature using ball milling.
¶
The ferrite strongly interacts with the gas phase so its behaviour was studied under different pressures of oxygen and in carbon dioxide.The changes in ferrite composition have an equilibrium character and depend on temperature and oxygen concentration in the
atmosphere. Variations of the oxygen
content x were described as a function of temperature and oxygen partial
pressure, the results were used to plot an equilibrium composition diagram.
The heat of oxidation was also measured as a function of temperature and oxygen partial pressure.
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Interaction of the ferrite with carbon dioxide below a critical temperature
causes decomposition of the material to strontium carbonate and SrFe12O19 .
The critical temperature depends on the partial pressure of CO2 and above
the critical temperature the carbonate and SrFe12O19 are converted back into
the ferrite.The resulting SrFe12O19 is very resistant towards carbonation and
the thermal carbonation reaction does not lead to a complete decomposition
of SrFeOx to hematite and strontium carbonate.
¶
The thermally induced oxidation and carbonation reactions cease at room
temperature due to sluggish kinetics however,they can be carried out at ambient temperature using ball milling.The reaction routes for these processes are different from the thermal routes.The mechanical oxidation induces two
or more concurrent reactions which lead to samples containing two or more
phases. The mechanical carbonation on the other hand produces an unknown
metastable iron carbonate and leads a complete decomposition of the ferrite
to strontiumcarbonate and hematite.
¶
Thermally and mechanically oxidized samples were studied using Mossbauer
spectroscopy. The author proposes a new interpretation of the Sr4Fe4O11
(x=2.75) and Sr8Fe8O23 (x=2.875)spectra.The interpretation is based
on the chemistry of the compounds and provides a simpler explanation of
the observed absorption lines.The Mossbauer results froma range of compositions
revealed the roomtemperature phase behaviour of the ferrite also
examined using x-ray diffraction.
¶
The high-temperature crystal structure of the ferrite was examined using
neutron powder diffraction.The measurements were done at temperatures
up to 1273K in argon and air atmospheres.The former atmosphere protects
Sr2Fe2O5 (x=2.5) against oxidation and the measurements in air allowed
variation of the composition of the oxide in the range 2.56 ≤ x ≤ 2.81.
Sr2Fe2O5 is an antiferromagnet and undergoes phase transitions to the paramagnetic
state at 692K and from the orthorhombic to the cubic structure
around 1140K.The oxidized formof the ferrite also undergoes a transition
to the high-temperature cubic form.The author proposes a new structural
model for the cubic phase based on a unit cell with the Fm3c symmetry.
The new model allows a description of the high-temperature cubic form of
the ferrite as a solid solution of the composition end members.The results
were used to draw a phase diagramfor the SrFeOx system.
¶
The last chapter summarizes the findings and suggests directions for further research.
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