Cette thèse se concentre sur des aspects multiorbitales des systèmes fermioniques fortement corrélés. En particulier, sur l'existence d'une différentiation orbitale dans laquelle la coexistence de caractère itinérant et localisé peut être associée à différentes orbitales. Cette problématique est examinée dans le contexte des atomes froids et des matériaux, offrant un pont entre les deux communautés.Dans la première partie de la thèse, nous donnons un aperçu du problème des corrélations fortes dans les matériaux, et nous introduisons le concept de 'transition de Mott sélective en orbitales'. Nous fournissons également les principaux outils pour comprendre comment les matériaux peuvent être simulés avec des atomes froids, et nous présentons des résultats importants liés à la transition métal-isolant de Mott. Les aspects techniques, basées sur la théorie du champ moyen dynamique sont également discutés, et la solution de deux principaux modèles de systèmes fermioniques fortement corrélés, à savoir le modèle d'Hubbard (HM) et le modèle de Falicov-Kimball (FKM), sont passés en revue.Ensuite, nous étudions en détail la physique de deux espèces fermioniques en interaction forte avec des masses différentes dans un réseau optique. Nous établissons les différentes phases (avec et sans ordre à longue portée) en termes de la force des interactions (U), du rapport des masses et de la température (T), et aussi nous discutons les variables thermodynamiques, qui sont pertinentes pour les expériences d'atomes froids. Nous montrons que dans la phase métallique (U inférieure à une valeur critique) et avec un certain degré de différence de masses, un 'crossover' apparaît entre un état métallique du type de liquide de Fermi à basse T, et un état avec différentiation orbital à haute T, où les fermions lourds se localisent tandis que les fermions légers restent itinérant. Par conséquent, nous proposons ce modèle minimal pour étudier la physique des systèmes qui présentent une différentiation orbitale avec des expériences d'atomes froids.Basé sur les propriétés du modèle étudié, nous proposons la 'chromatographie entropique' comme une nouvelle méthode pour refroidir des atomes fermioniques dans les réseaux optiques. Nous discutons son efficacité et ses limites, et fournissons quelques idées afin de les surmonter.Dans la dernière partie de la thèse, nous généralisons le modèle précédent aux matériaux corrélés à plusieurs bandes qui permet d'afficher la différentiation orbitale. Nous montrons que l'état de Mott sélectif en orbital peut être stable sous les distorsions du réseau, modélisées par une hybridation locale entre les orbitales. Cependant, l'état de Mott est caractérisé par un pseudo-gap, où les fluctuations de charge sont brusquement réduites, mais l'état reste compressible. En relation au modèle précédent, nous discutons le 'crossover' entre l'état métallique et l'état sélectif induit par des effets température, nous comparons nos résultats avec les expériences de photoémission, et nous prédisons ce qui se passerait dans les matériaux qui présentent une hybridation locale entre les bandes. / This thesis focuses on multiorbital aspects of strongly correlated fermionic systems. In particular, it focuses on the existence of orbital differentiation in which coexistence of itinerant and localized character can be associated to different orbitals. This subject is discussed in the context of cold atoms and materials, providing a bridge between both communities.In the first part of the thesis, we give an insight into the problem of strong correlations in materials, and we introduce the concept of 'orbital-selective Mott transition'. We also provide the main tools to understand how materials can be simulated with cold atoms experiments, and we present important related results in the context of the metal-Mott insulator transition. The technical aspects, based on dynamical mean-field theory are also discussed, and the solution of two key models of strongly correlated fermionic systems, i.e., the Hubbard model (HM) and the Falicov-Kimball model (FKM), are reviewed.Then we study in detail the physics of two interacting fermionic species with different masses in an optical lattice. We establish the different phases (with and without long-range order) in terms of the interactions strength (U), mass ratio and temperature (T), and also discuss the thermodynamic variables, which are relevant in cold atoms experiments. We show that in the metallic phase (U below a critical value) and for some degree of mass imbalance, a crossover appears between a Fermi-liquid metallic state at low T, and an 'orbital-selective' state at higher T, where the heavy fermions effectively localize while the light species remain itinerant. Hence, we propose this minimal model for addressing orbital-selective physics with cold atoms experiments.Based on the properties of the studied model, we propose the 'entropic chromatography' as a new method for cooling fermionic atoms in optical lattices. We discuss its efficiency and limitations, and provide some ideas in order to overcome them.In the last part of the thesis we generalize the previous model to a model relevant for multiband correlated materials that can display orbital differentiation. We show that the orbital-selective Mott state can be stable under lattice distortions modeled by local hybridization between the orbitals. However, the Mott state is characterized by a pseudogap, where charge fluctuations abruptly reduce, but the state remains compressible. In connection with the previous model, we discuss the temperature-induced orbital-selective crossover in this problem, we compare our results with photoemission experiments, and predict what would happen in materials that display local hybridization between the bands.

Cette thèse est consacrée à l’analyse mathématique du problème du mouvement d’un nombre fini de corps rigides homogènes au sein d’un fluide visqueux incompressible homogène. Les fluides visqueux sont classés en deux catégories: les fluides newtoniens et les fluides non newtoniens. En premier lieu, nous considérons le système formé par les équations de Navier Stokes incompressible couplées aux lois de Newton pour décrire le mouvement de plusieurs disques rigides dans un fluide newtonien visqueux homogène dans l’ensemble de l’espace R^2. Nous montrons que ce problème est bien posé jusqu’à l’apparition de la première collision. Ensuite, nous éliminons tous les types de contacts pouvant survenir si le domaine fluide reste connexe à tout moment. Avec cette hypothèse, le système considéré est globalement bien posé. Dans la deuxième partie de cette thèse, nous montrons la non-unicité des solutions faibles au problème d’interaction fluide-solide 3D, dans le cas d’un fluide newtonien, après collision. Nous montrons qu’il existe des conditions initiales telles que nous pouvons étendre les solutions faibles après le temps pour lequel le contact a eu lieu de deux manières différentes. Enfin, dans la dernière partie, nous étudions le mouvement bidimensionnel d’un nombre fini de disques immergés dans une cavité remplie d’un fluide viscoélastique tel que des solutions polymériques. Les équations de Navier Stokes incompressible sont utilisées pour modéliser le solvant, dans lesquelles un tenseur de contrainte élastique supplémentaire apparaît comme un terme source. Dans cette partie, nous supposons que le tenseur de contrainte supplémentaire satisfait la loi différentielle d’Oldroyd ou sa version régularisée. Dans les deux cas, nous prouvons l’existence et l’unicité des solutions fortes locales en temps du problème considéré. / This thesis is devoted to the mathematical analysis of the problem of motion of afinite number of homogeneous rigid bodies within a homogeneous incompressible viscous fluid. Viscous fluids are classified into two categories: Newtonian fluids, and non-Newtonian fluids. First, we consider the system formed by the incompressible Navier-Stokes equations coupled with Newton’s laws to describe the movement of several rigid disks within a homogeneous viscous Newtonian fluid in the whole space R^2. We show the well-posedness of this system up to the occurrence of the first collision. Then we eliminate all type of contacts that may occur if the fluid domain remains connected at any time. With this assumption, the considered system is well-posed globally in time. In the second part of this thesis, we prove the non-uniqueness of weak solutions to the fluid-rigid body interaction problem in 3D in Newtonian fluid after collision. We show that there exist some initial conditions such that we can extend weak solutions after the time for which contact has taken place by two different ways. Finally, in the last part, we study the two-dimensional motion of a finite number of disks immersed in a cavity filled with a viscoelastic fluid such as polymeric solutions. The incompressible Navier–Stokes equations are used to model the flow of the solvent, in which the elastic extra stress tensor appears as a source term. In this part, we suppose that the extra stress tensor satisfies either the Oldroyd or the regularized Oldroyd constitutive differential law. In both cases, we prove the existence and uniqueness of local-in-time strongsolutions of the considered moving-boundary problem.

In the framework of quantum theory the characteristics of synchrotron radiation (SR) are considered. In order to simplify theoretical description the process of radiation is restricted to single-photon emission. For arbitrary quantum transitions the spectral-angular distributions of SR power are given in exact analytical form. Scalar particles (bosons) and particles with spin $\\hbar/2$ (electrons) are treated separately. Special attention is given to the particular transitions, namely, to the transitions to first excited and ground states. It is shown that the components of linear polarization of radiation from electron switch places due to the orientation of spin when the electron jumps to the ground state. This fact can be considered an analytical proof for the presence of $\\pi$-component of quantum radiation in the plane of motion. The radiation emitted from weakly excited particles is thoroughly analysed. To describe the evolution of the profiles of angular distributions various functions are introduced both for two- and three-level systems. For quantum transitions from the first excited state to the ground state the comparative analysis of radiation from bosons and electrons is performed, which helps to estimate the influence of spin and its direction on the characteristics of radiation. The radiation from unpolarized electron is considered separately. Tracking the behavior of effective angles allows to discover the inconsistency of well-known classical conclusion about the concentration of total (summed over spectrum) ultrarelativistic radiation in the plane of motion. It is shown that the effective angles of quantum radiation tend to finite values and do not vanish in ultrarelativistic region. A brief review of classical theory includes an introduction of the new concept, $n$-part of spectrum. In order to find an adequate classical analogue for the radiation from weakly excited particles, the idea to reduce classical spectrum was developed. It turns out that the characteristics of radiation calculated for reduced classical spectrum stay in good quantitative and qualitative agreement with their quantum analogues, at least for single-harmonic and two-harmonic quantum spectra, and classical theory of a reduced spectrum can be claimed representational in this sense. The evolution of maximum in radiation spectrum is considered in separate chapter. A well-known approximation obtained for critical frequency in the framework of classical theory is invalid when quantum corrections enter the picture. But there appears a possibility to find the conditions for the maximum to shift to the highest harmonic of finite quantum spectrum. It is shown that the shifts occur successively starting with primary harmonic in non-relativistic case, and this result remains valid independently of spin. For a scalar particle there exists a fixed set of numbers, which are the critical values of external field, such that the shift of radiation maximum in the spectrum of boson can only happen when the intensity of external field is greater than certain critical value related to corresponding harmonic. If this condition is not satisfied, the position of maximum remains unchanged. It turns out that the presence of spin perturbs this picture, so that the critical values of field intensity depend on the number of initial level. / Consideramos as características da radiação sincrotron (RS) no âmbito da teoria quântica. Para simplificar a descrição teórica do processo de radiação restringimos à consideração da emissão de único fóton. Para transições quânticas arbitrárias, as distribuições espectrais e angulares da potência da RS são dadas de forma analítica exata. Tratamos separadamente partículas escalares (bósons) e com spin ½ (elétrons). Atenção especial é dada às transições particulares, a saber, as transições ao primeiro estado excitado e estado fundamental. É mostrado que os componentes de polarização linear da radiação de elétron se trocam em relação à orientação de spin quando o elétron passa para o estado fundamental. Este fato pode ser considerado como uma comprovação analítica para a presença de -componente da radiação quântica no plano de movimento. Analisamos minuciosamente a radiação emitida pela partícula fracamente excitada. Várias funções são introduzidas para descrever a evolução dos perfis de distribuições angulares para sistemas de dois e três níveis. Para transições quânticas do primeiro estado excitado ao estado fundamental a análise comparativa da radiação de bósons e elétrons é realizada, e isso ajuda à estimar a influência de spin e sua direção sobre as características da RS. A radiação de elétrons não polarizados é considerada separadamente. Observando o comportamento dos ângulos efetivos, é fácil perceber a inconsistência da conclusão clássica bem conhecida sobre a concentração de radiação ultra-relativista total no plano do movimento. Mostramos que os ângulos efetivos da radiação quântica tendem aos valores finitos e não desaparecem na região ultrarelativista. Uma revisão breve da teoria clássica inclui a introdução do conceito novo, isto é a n-parte do espectro. A fim de encontrar um análogo clássico adequado para a radiação das partículas fracamente excitados, a ideia de reduzir o espectro clássico foi desenvolvida. Constatamos que as características da radiação calculadas para o espectro clássico reduzido permanecem em boa concordância, tanto quantitativa quanto qualitativa, com os seus análogos quânticos, pelo menos no que diz respeito aos espectros quânticos de uma ou duas harmônicas. Neste sentido, a teoria clássica do espectro reduzido pode ser chamada de representativa. A evolução do máximo no espectro da radiação é considerada em capítulo separado. A aproximação, comumente considerada na teoria classica para frequência crítica, é inválida quando as correções quânticas entram em cena. Mas existe uma possibilidade de encontrar as condições para o máximo transferir-se à harmônica maior do espectro quântico. É mostrado que as transferências ocorrem sucessivamente, comecando com a harmônica principal no caso não relativístico, e este resultado permanece válido, independentemente de spin. Para uma partícula escalar existe um conjunto fixo dos valores críticos do campo externo, de tal modo que a transferência do máximo da radiação entre duas harmônicas específicas pode acontecer somente quando a intensidade do campo externo é maior do que o valor crítico associado com essas harmônicas. Se essa condição não for satisfeita, a posição do máximo permanece inalterada. Verificamos que a presença de spin perturba esta condição, no caso do elétron os valores críticos da intensidade do campo dependem de número do nível inicial.

Neste trabalho investigamos os efeitos do magnetismo orbital sobre o gás de elétrons tridimensional e sobre íons de camadas abertas em matrizes metálicas. Derivamos uma expressão analítica fechada para a energia de troca do gás de elétrons tridimensional na presença de fortes campos magnéticos, incluindo contribuições do segundo nível de Landau e polarização de spin arbitrária. Esse cálculo generaliza e corrige resultados anteriores disponíveis na literatura. Em seguida, realizamos um cálculo numérico da energia de troca do gás de elétrons tridimensional na presença de campos magnéticos, permitindo a ocupação de um número ilimitado de níveis de Landau, possibilitando assim a obtenção da energia de troca para quaisquer valores de campo magnético e densidade. Em uma abordagem independente, usamos as aproximações de Thomas-Fermi e Thomas-Fermi-Dirac para construir modelos simples para a função dielétrica do gás de elétrons tridimensional no regime de campos magnéticos muito fortes (apenas o primeiro nível de Landau ocupado). Finalmente, estabelecemos vínculos entre os tratamentos fenomenológicos e de primeiros princípios do magnetismo orbital em íons de camadas abertas em matrizes metálicas. Esses vínculos forneceram um embasamento teórico para o uso dos termos de polarização orbital em cálculos Kohn-Sham e levaram à obtenção de expressões aproximadas para os funcionais de troca-correlação da teoria do funcional da densidade de corrente. / In this work, we investigate the effects of orbital magnetism in the three-dimensional electron gas and in open-shell ions in a solid. We derive a closed analytical expression for the exchange energy of the three-dimensional electron gas in strong magnetic fields including the contribution of the second Landau level and arbitrary spin polarization. This calculation generalizes and corrects earlier results available in the literature. Next, we perform a numerical calculation of the exchange energy of the three-dimensional electron gas in a magnetic field, allowing several Landau levels to be occupied, to obtain the exchange energy for arbitrary values of magnetic field and density. In an independent approach, we use the Thomas-Fermi and Thomas-Fermi-Dirac approximations to construct simple model dielectric functions for the three-dimensional electron gas in the strong magnetic field regime (where only the lowest Landau level is occupied). Finally, we establish links between the phenomenological and the first-principles treatment of orbital magnetism in open-shell ions in solids. These links provide a theoretical foundation for the use of orbital polarization terms in Kohn-Sham calculations and allow to obtain approximations to the exchange-correlation functionals of current-density functional theory.

Le thème de cette thèse est la théorie spatiale des valeurs extrêmes, et les objets principalement étudiés sont les processus max-stables à trajectoires continues. Nous commençons par déterminer la convergence des maximums de processus stochastiques indépendants, en utilisant la convergence de mesures empiriques vers des processus ponctuels de Poisson. Ensuite, nous déterminons les lois conditionnelles des processus max infiniment divisibles (max-i.d). La représentation des processus max-i.d par des processus ponctuels de Poisson permet l'introduction de notions telles que les fonctions extrémales et le hitting scénario qui permettent d'aboutir au résultat. Les processus max-stables étant des processus max-i.d, nous proposons un algorithme de simulation conditionnelle pour les champs max-stables puis nous l'utilisons pour des applications avec des données de précipitations autour de Zurich et de températures en Suisse. Nous trouvons aussi, une majoration du coefficient de β-mélange entre les restrictions d'un processus max-i.d sur deux sous-ensembles fermés et disjoints d'un espace métrique localement compact. Cette majoration permet d'obtenir de nouveaux critères pour le théorème de la limite central des processus stationnaires mélangeant. Enfin, nous terminons en démontrant qu'un processus stationnaire max-stable vérifiant la propriété de Markov est, quitte à renverser le temps, un processus max-autorégressif d’ordre 1. / The theme of this thesis is spatial extreme value theory and we focus on continuous max-stable processes. We begin with the convergence of the maximum of independent stochastic processes, by using the convergence of empirical measures to Poisson point processes. After that, we determine the regular conditional distributions of max infinitely divisible (max-i.d) processes. The representation of max-i.d. processes by Poisson point processes allows us to introduce the notions of extremal functions and hitting scenario. Our result relies on these new notions. Max-stable processes are max-i.d. processes, so we give an algorithm for conditional sampling and give an application to extreme precipitations around Zurich and extreme temperatures in Switzerland. We also find a upper bound for the β-mixing coefficient between the restrictions of a max-i.d. process on two disjoint closed subsets of a locally compact metric space. This entails a central limit theorem for stationary max-i.d processes. Finally, we prove that the class of stationary maxstable processes with the Markov property is equal, up to time reversal, to the class of stationary max-autoregressive processes of order 1.

Muitos são os benefícios provenientes da arborização de vias públicas, como aumento da vida útil do asfalto por meio do sombreamento, filtragem de poluentes, absorção de CO2, interceptação da água da chuva e da radiação solar e mitigação de ilhas de calor; porém, por questões culturais, é considerada muitas vezes pela população como algo negativo, cujas folhas entopem calhas, raízes destroem calçadas, troncos e folhas atrapalham fiação elétrica e, principalmente, elas estão susceptíveis às quedas. A pesquisa teve como objetivo estudar o comportamento das quedas de árvores no município de Piracicaba/SP, Brasil, com atenção especial ao regime de ventos na cidade, baseado em dados fornecidos pelo Corpo de Bombeiros de Piracicaba, Secretaria de Defesa do Meio Ambiente de Piracicaba (SEDEMA) e Estação Meteorológica da Escola Superior de Agricultura \"Luiz de Queiroz\" (ESALQ). De caráter inédito, o principal resultado foi a relação direta entre quedas e zonas urbanizadas, que, em constantes alterações no uso do solo, acabam por danificar a sustentação das árvores (raízes), fato justificado pela alta concentração de quedas na parte central (36,7%), com destaque para as estações da primavera e do verão, ou seja, ventos e chuvas, na qual, juntas, somaram 78,0% do total. O período de retorno esperado para ventos superiores a 75 km h-1, classificados como temporais na Escala de Vento de Beaufort, foi de 2,8 eventos por ano. Enquanto verificou-se o predomínio de ventos alísios de sudeste, pertencentes ao quarto quadrante, a direção das rajadas de vento teve maior variação e, assim, com predomínio daqueles ventos, é recomendável instalações de parques industriais nas zonas norte, noroeste e oeste, haja vista a importância de evitar que os poluentes adentrem a cidade. As espécies de maior vulnerabilidade foram: Pachira aquatica Aubl. (monguba), Handroanthus sp. (ipê roxo) e Tipuana tipu (Benth.) Kuntze (tipuana). Por meio de simulação microclimática computacional, utilizando o programa ENVI-met versão 3.1, em dois estudos de caso, sendo um em bairro residencial e outro na Praça José Bonifácio, foi possível identificar locais de maior atenção quanto às quedas de árvores, em função da rugosidade do local, capaz de alterar a velocidade e a direção do vento. / There are many benefits from public roads afforestation, such as longer pavement life through shading, filtering pollutants, CO2 absorption, intercepting rainfall and solar radiation and mitigating heat islands; however, due cultural issues, is often regarded by the population as something negative, whose leaves clog gutters, roots destroy sidewalks, stems and leaves disrupt electrical wiring and, mainly, they are susceptible to falls. The research aimed to study the behavior of falling trees in Piracicaba/SP, Brazil, with special attention to the wind regime in the city, based on data provided by the Piracicaba Fire Department, Secretariat of Defense of the Environment of Piracicaba (SEDEMA) and Meteorological Station Luiz de Queiroz College of Agriculture (ESALQ). From unedited character, the main result was the direct relationship between falls and urbanized areas, which, in constant changes in land use, end up damaging the support of trees (roots), a fact explained by the high concentration of falls in the central part (36.7%), highlighted to the spring and summer seasons, i.e., winds and rains, which, together, totaling 78.0% of the total cases. The payback period expected to winds who exceeding 75 km h-1, classified as storms in the Beaufort Wind Scale, was 2.8 events per year. While there was a predominance of trade winds from the Southeast, belonging to the fourth quadrant, the direction of the gusts of wind had greater variation and, thus, with those predominant winds, it recommend installation of industrial parks in North, Northwest and West areas, since the importance of avoiding that pollutants enter into the city. The most vulnerable species were: Pachira aquatica Aubl. (Guiana Chestnut), Handroanthus sp. (Purple Ipe) and Tipuana tipu (Benth.) Kuntze (Tipuana). Through computational microclimate simulation, using the software ENVI-met version 3.1, in two case studies, being one in a residential area and another in the José Bonifácio Square, it was possible to identify locals of more attention as the falling trees, based on the local roughness, able to change the speed and direction of the wind.

Foi analisada, através de simulação Monte Carlo, a probabilidade de que um gap de rapidez seja observado na produção do boson de Higgs por fusão de bosons vetoriais com massa (W), no LHC (Large Hadron Collider). Foi analisada, também através do uso de Monte Carlo, a possibilidade de que a existência ou não de um gap de rapidez seja usada na distinção de um Higgs produzido por fusão de bosons vetoriais W de outro produzido por fusão de gluons. Os diferentes modelos para tratamento de processos não perturbativos dos códigos Monte Carlo DTUJET e PYTHIA foram comparados. / The gap survival probability for a higgs boson produced by W fusion at the LHC (Large Hadron Collider) is analyzed through Monte Carlo simulation. The possibility of distinguishing between two higgs production mechanisms, W and gluon fusion is studied using Monte Carlo simulation. The two different models for non pertubative processes, used by DTUJET and PYTHIA are compared.

Diese Arbeit beschäftigt sich mit der Untersuchung der starken Kopplung und Laseremission in Strukturen, die ZnO, ZnCdO oder organische Moleküle als aktives Material enthalten. Die ZnCdO basierten Vielfachquantengräben erreichen ihre Laserschwelle durch optische Ruckkopplung an streuenden Luftlöchern. Diese Emitter nennt man random laser. Die Dynamik ihrer Emission unter quasi-stationären Bedingungen ist der hier gezeigte Fokus. Hoch reproduzierbare Anregungen werden verwendet um sowohl die Dynamik eines einzelnen Beschusses aber auch die Unterschiede verschiedener Anregungen zu untersuchen. Die experimentellen Daten werden durch numerische Simulation qualitativ reproduziert und mit Methoden der Netzwerktheorie interpretiert. Die verbreitetere optische Rückkopplung durch einen Resonator wird in der Untersuchung des Moleküls L4P und seiner Spiro-derivate benutzt. Zwei identische Braggspiegel umschließen die aktive Schicht aus L4P-SP2, das in eine Polymermatrix eingebettet ist, eine Dicke von 12 Mikrometer hat und in einer einzelnen Mode lasert (schwache Kopplung). Durch Verringerung der aktiven Schicht auf die Hälfte der Resonanzwellenlänge wird das System in den Bereich der starken Kopplung gebracht. Eine Rabi-Aufspaltung von 90 meV wird zu beiden vibronischen Resonanzen beobachtet. Die energetische Position in Resonanz zu ZnO macht dieses Molekül zu einem guten Kandidaten für die Fertigung einer hybriden Mikrokavität im Bereich der starken Kopplung. Dies wurde in einer teilweise epitaktisch gewachsenen Mikrokavität angewandt, die aus einem ZnMgO basierten Braggspiegel und sechs Quantengräben besteht. Darauf folgt eine aufgeschleuderte Schicht von L4P in der Polymermatrix. Der Resonator wird mit einem dielektrischen Spiegel fertiggestellt. Tieftemperatur Reflektion zeigt eine deutlichen ausweichen und eine gleichverteilte Mischung der drei Resonanz im mittleren Polaritonzweig. / This thesis presents the investigation of strong coupling and lasing in structures using ZnO, ZnCdO or organic molecules as active material. The ZnCdO based multi quantum well structures reach the lasing threshold by using scattering at air holes as the optical feedback. Such emitters are called random lasers. The dynamics of their emission under quasi-stationary condition is the point of interest presented. Highly reproducible excitations are used to investigate the single shot dynamics and their shot to shot differences. The experimental data is qualitatively reproduced by numerical simulation and interpreted by means of network theory. The more common optical feedback by a cavity is applied in the investigation of the molecule L4P and its spiro-derivatives. Using two identical SiO2/ZrO2 based Bragg reflectors surrounding an active layer of L4P-SP2 in a polymer matrix of approximately 12 microns thickness reached single mode lasing (weak coupling). Reducing the active layer thickness to half the resonance wavelength pushes the system into the strong coupling regime. Angular resolved reflectivity shows the anticrossing of the tuned cavity resonance to two vibronic transitions of the molecule. The Rabi-splitting to both vibronic resonances reaches around 90 meV. The energetic position in resonance to ZnO makes this molecule a promising candidate for a hybrid inorganic/organic microcavity in the strong coupling regime. This is used in a partially epitaxially grown microcavity composed of a ZnMgO based Bragg reflector (alternating layers of different Mg content) and six quantum wells. This is followed by a spincoated layer of L4P in a polymer matrix. The cavity is finished by a dielectric mirror. Low temperature reflectivity shows a clear anticrossing reaching an equal mixing of all resonances for the middle branch.

Ein neuer numerischer ab initio Ansatz wurde entwickelt und zur Lösung der zeitabhängigen Schrödingergleichung für zweiatomig Moleküle mit zwei Elektronen (z.B. molekularer Wasserstoff), welche einem intensiven kurzen Laserpuls ausgesetzt sind, angewandt. Die Methode basiert auf der Näherung fester Kernabstände und der nicht-relativistischen Dipolnäherung und beabsichtigt die genaue Beschreibung der beiden korrelierten Elektronen in voller Dimensionalität. Die Methode ist anwendbar für eine große Bandbreite von Laserpulsparamtern und ist in der Lage, Einfachionisationsprozesse sowohl mit wenigen als auch mit vielen Photonen zu beschreiben, sogar im nicht-störungstheoretischen Bereich. Ein entscheidender Vorteil der Methode ist ihre Fähigkeit, die Reaktion von Molekülen mit beliebiger Orientierung der molekularen Achse im Bezug auf das linear polarisierte Laserfeld in starken Feldern zu beschreiben. Dementsprechend berichtet diese Arbeit von der ersten erfolgreichen orientierungsabhängigen Analyse der Multiphotonenionisation von H2, welche mit Hilfe einer numerischen Behandlung in voller Dimensionalität durchgeführt wurde. Neben der Erforschung des Bereichs weniger Photonen wurde eine ausführliche numerische Untersuchung der Ionisation durch ultrakurze frequenzverdoppelte Titan:Saphir-Laserpulse (400 nm) präsentiert. Mit Hilfe einer Serie von Rechnungen für verschiedene Kernabstände wurden die totalen Ionisationsausbeuten für H2 und D2 in ihren Vibrationsgrundzuständen sowohl für parallele als auch für senkrechte Ausrichtung erhalten. Eine weitere Serie von Rechnungen für 800nm Laserpulse wurde benutzt, um ein weitverbreitetes einfaches Interferenzmodel zu falsifizieren. Neben der Diskussion der numerischen ab initio Methode werden in dieser Arbeit verschiedene Aspekte im Bezug auf die Anwendung der Starkfeldnäherung für die Erforschung der Reaktion eines atomaren oder molekularen Systems auf ein intensives Laserfeld betrachtet. / A novel ab initio numerical approach is developed and applied that solves the time-dependent Schrödinger equation describing two-electron diatomic molecules (e.g. molecular hydrogen) exposed to an intense ultrashort laser pulse. The method is based on the fixed-nuclei and the non-relativistic dipole approximations and aims to accurately describe both correlated electrons in full dimensionality. The method is applicable for a wide range of the laser pulse parameters and is able to describe both few-photon and many-photon single ionization processes, also in a non-perturbative regime. A key advantage of the method is its ability to treat the strong-field response of the molecules with arbitrary orientation of the molecular axis with respect to the linear-polarized laser field. Thus, this work reports on the first successful orientation-dependent analysis of the multiphoton ionization of H2 performed by means of a full-dimensional numerical treatment. Besides the investigation of few-photon regime, an extensive numerical study of the ionization by ultrashort frequency-doubled Ti:sapphire laser pulses (400 nm) is presented. Performing a series of calculations for different internuclear separations, the total ionization yields of H2 and D2 in their ground vibrational states are obtained for both parallel and perpendicular orientations. A series of calculations for 800nm laser pulses are used to test a popular simple interference model. Besides the discussion of the ab initio numerical method, this work considers different aspects related to the application of the strong-field approximation (SFA) for investigation of a strong-field response of an atomic and molecular system. Thus, a deep analysis of the gauge problem of SFA is performed and the quasistatic limit of the velocity-gauge SFA ionization rates is derived. The applications of the length gauge SFA are examined and a recently proposed generalized Keldysh theory is criticized.

Diese Doktorarbeit behandelt quantentheoretische Aspekte von Typ II Superstringtheorien in AdS5xS5- und AdS4xCP3-Hintergründen für die AdS/CFT Korrespondenz. Dabei werden perturbative Methoden und Verfahren der Gitterfeldtheorie benutzt. Die Konstruktion des Supercoset-Sigma-Modell für Strings im AdS5xS5wird skizziert, während die generelle Quantendynamik des Superstring in AdS4xCP3 mit Hilfe einer dimensionaler Reduktion der Supermembrane-Wirkung in AdS4xS7 beschrieben wird. Ein manifest kovarianter Formalismus zur semi-klassischen Quantisierung von Strings um beliebige Minimalflächen in AdS5xS5 wird präsentiert, der durch die Darstellung der Fluktuationsoperatoren in Form von intrinsischen und extrinsischen Varianten der Hintergrundgeometrie erreicht wird. Eine Verallgemeinerung der Lame-Differentialgleichung zur 4. Ordnungwird mit Hilfe der Spektralmethode exakt gelöst. Dadurch konnten in 1-Schleifennäherung die Energie des String im SU(2)-Sektor, im Grenzfall beschrieben durch ein Quantum-Landau-Lifshitz-Modell, und der bosonische Beitrag zur Energie des in AdS5 und S5 rotierenden String bestimmt werden. In ähnlicher Weise erhält man in 1-Schleifennäherung den ¼-BPS-Latitude Wilson-Loop in N=4-SYM-Theorie normiert durch den ½-BPS-Loop. Das Regularisierungsschema reproduziert die Vorhersage aus supersymmetrischer Lokalisierung bis auf einen Rest, welcher diskutiert wird. Außerdem wird die Wirkung des AdS4xCP3-String, entwickelt um den null-cusp Hintergrund, studiert und die Cusp-Anomalie in 2-Schleifennäherung berechnet. Das Ergebnis stimmt mit dem vermuteten exakten Ausdruck, der ABJM-Interpolationsfunktion, überein. Schließlich wird die AdS5xS5-Superstringtheorie in AdS-Lichtkegel-Eichung diskretisiert und mit Monte-Carlo-Algorithmen Gittersimulationen bei endlicher Kopplung durchgeführt. Dabei werden die Stringwirkung, aus der mit Hilfe von AdS/CFT die null-cusp anomale Dimension von N=4 SYM extrahiert werden kann, und die Masse einer AdS Anregung bestimmt. / This thesis discusses quantum aspects of type II superstring theories in AdS5xS5 and AdS4xCP3 backgrounds relevant for the AdS/CFT correspondence, using perturbative methods at large string tension and lattice field theory techniques inspired by a work of Roiban and McKeown. We review the construction of the supercoset sigma-model for strings in the AdS5xS5 background, whereas the general quantum dynamics of the superstring in AdS4xCP3 is described by a double dimensional reduction of the supermembrane action in AdS4xS7. We present a manifestly covariant formalism for semiclassical quantization of strings around arbitrary minimal-area surfaces in AdS5xS5, expressing the fluctuation operators in terms of intrinsic and extrinsic invariants of the background geometry. We exactly solve the spectral problem for a fourth-order generalization of the Lame'' differential equation with doubly periodic coefficients in a complex variable. This calculates the one-loop energy of the (J1,J2)-string in the SU(2) sector in the limit described by a quantum Landau-Lifshitz model and the bosonic contribution to the energy of the (S,J)-string rotating in AdS5 and S5. Similar techniques calculate the 1/4-BPS latitude Wilson loops in N=4 SYM theory at one loop, normalized to the 1/2-BPS circular loop. Our regularization scheme reproduces the next-to-leading order predicted by supersymmetric localization, up to a remainder function that we discuss upon. We also study the AdS4xCP3 string action expanded around the null cusp background and compute the cusp anomaly up to two loops. This agrees with an all-loop conjectured expression of the ABJM interpolating function. We finally discretize the AdS5xS5 superstring theory in the AdS light-cone gauge and perform lattice simulations at finite coupling with a Monte Carlo algorithm. We measure the string action, from which we extract the null cusp anomalous dimension of N=4 SYM as derived from AdS/CFT, as well as the mass of an AdS excitation.