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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
291

Solar - Biomass hybrid system for process heat supply in medium scale hotels in Sri Lanka

Abeywardana, Asela Janaka January 2016 (has links)
This study aimed at evaluating and demonstrating the feasibility of using Concentrated Solar Thermal technology combined with biomass energy technology as a hybrid renewable energy system to supply the process heat requirements in small scale industries in Sri Lanka. Particularly, the focus was to apply the concept to the expanding hotel industry, for covering the thermal energy demand of a medium scale hotel. Solar modules utilize the rooftop area of the building to a valuable application. Linear Fresnel type of solar concentrator is selected considering the requirement of the application and the simplicity of fabrication and installation compared to other technologies. Subsequently, a wood-fired boiler is deployed as the steam generator as well as the balancing power source to recover the effects due to the seasonal variations in solar energy. Bioenergy, so far being the largest primary energy supply in the country, has a good potential for further growth in industrial applications like small hotels.  When a hotel with about 200-guests capacity and annual average occupancy of 65% is considered, the total annual CO2 saving is accounted as 207 tons compared with an entirely fossil fuel (diesel) fired boiler system. The annual operational cost saving is around $ 40,000 and the simple payback period is within 3-4 years. The proposed hybrid system can generate additional 26 employment opportunities in the proximity of the site location area.   This solar-biomass hybrid concept mitigates the weaknesses associated with these renewable technologies when employed separately. The system has been designed in such a way that the total heat demand of hot water and process steam supply is managed by renewable energy alone. It is thus a self-sustainable, non-conventional, renewable energy system. This concept can be stretched to other critical medium temperature applications like for example absorption refrigeration. The system is applicable to many other industries in the country where space requirement is available, solar irradiance is rich and a solid biomass supply is assured.
292

Analysis of Energy Saving Proposals at St. Louis County Jail

Lillesve, Peter January 2010 (has links)
<p>The goal of this project was to evaluate three main proposals, by the Property Management Department (PMD) of St. Louis County, which the department hoped would reduce energy consumption at their Duluth Jail facility. This particular facility was opened in 1995 and houses approximately 170 inmates. Despite its relatively new construction, the building produces some of the highest utility bills of all of the County’s buildings.</p><p>The proposals put forth by the PMD were the following: to reduce natural gas consumption by using solar water heating for the domestic hot water; to reduce heating and cooling costs by enclosing a light well which is currently open to the sky with a transparent, insulated roof; and to utilize a white roof to reduce cooling demand during the summertime.</p><p>The solar water heating proposal was evaluated by determining the energy the solar system could provide annually and comparing these energy- and monetary savings to the cost of the system. Two solar options were evaluated; one system with 20 collectors and another with 50. Both systems also included condensing boilers to provide supplementary heating during times of low solar output. The annual savings of the 20- and 50 collector systems were 128 and 173 MWh, respectively. This led to a payback period of approximately 17 years for the 20 collector system and 16 years for the 50 collector system.</p><p>Enclosing the open light well, which is an open area inside the perimeter of the building which is designed to give rooms on the inside of the building natural daylight, was evaluated by performing an energy flow analysis comparing the existing condition with one in which a roof topped the well. This involved calculating the U-values of the walls before the skyroof and then using heating and cooling degree days to determine the heat flows through the walls. The enclosed light well was evaluated by performing an energy balance on the well to determine the temperature of the enclosed well. This temperature could then be used to calculate the heat flow through the enclosed light well’s walls. The difference in these heat flows between the two options was then converted to an economic cost to evaluate a payback period. Two grades of Kalwall-brand insulation were evaluated; the “Nanogel” grade and a mid-range grade. The Nanogel-enclosed light well reduced the heating demand by 16 MWh but increased the cooling load by 9 MWh, while the mid-grade enclosed well decreased the heating load by 11 MWh but increased the cooling load by 4 MWh. These added up to net annual savings of $650 for the Nanogel roof and $470 for the mid-grade skyroof. However, the investment costs were so high that the payback periods were between 450 and 550 years.</p><p>Two white roofing options were considered and corresponded to a newly installed roof and one that had weathered for 3 years, thereby reducing its reflectivity. These options were evaluated by determining the mean monthly roof temperatures throughout a typical year and calculating the heat flows through the roofs based on these temperatures. The temperatures were determined by performing a heat balance on the roofs’ surfaces and considering the solar radiation incident on the roofs. The heat flows with the existing black colored roof and the proposed white roofs were thencompared and converted into heating and cooling costs. The white roofs led to summertime air-conditioning savings but created more wintertime heat losses and therefore caused net annual energy cost increases of $560 and $240 for the new and weathered roofs, respectively.</p><p>The recommendations therefore were to implement the solar thermal system but not the other two proposals. Other areas which might benefit from additional investigations include lighting efficiency improvements, water use reductions, and replacement of the existing boilers with either more efficient natural gas units or wood-pellet/biomass boilers.</p>
293

Analysis of Energy Saving Proposals at St. Louis County Jail

Lillesve, Peter January 2010 (has links)
The goal of this project was to evaluate three main proposals, by the Property Management Department (PMD) of St. Louis County, which the department hoped would reduce energy consumption at their Duluth Jail facility. This particular facility was opened in 1995 and houses approximately 170 inmates. Despite its relatively new construction, the building produces some of the highest utility bills of all of the County’s buildings. The proposals put forth by the PMD were the following: to reduce natural gas consumption by using solar water heating for the domestic hot water; to reduce heating and cooling costs by enclosing a light well which is currently open to the sky with a transparent, insulated roof; and to utilize a white roof to reduce cooling demand during the summertime. The solar water heating proposal was evaluated by determining the energy the solar system could provide annually and comparing these energy- and monetary savings to the cost of the system. Two solar options were evaluated; one system with 20 collectors and another with 50. Both systems also included condensing boilers to provide supplementary heating during times of low solar output. The annual savings of the 20- and 50 collector systems were 128 and 173 MWh, respectively. This led to a payback period of approximately 17 years for the 20 collector system and 16 years for the 50 collector system. Enclosing the open light well, which is an open area inside the perimeter of the building which is designed to give rooms on the inside of the building natural daylight, was evaluated by performing an energy flow analysis comparing the existing condition with one in which a roof topped the well. This involved calculating the U-values of the walls before the skyroof and then using heating and cooling degree days to determine the heat flows through the walls. The enclosed light well was evaluated by performing an energy balance on the well to determine the temperature of the enclosed well. This temperature could then be used to calculate the heat flow through the enclosed light well’s walls. The difference in these heat flows between the two options was then converted to an economic cost to evaluate a payback period. Two grades of Kalwall-brand insulation were evaluated; the “Nanogel” grade and a mid-range grade. The Nanogel-enclosed light well reduced the heating demand by 16 MWh but increased the cooling load by 9 MWh, while the mid-grade enclosed well decreased the heating load by 11 MWh but increased the cooling load by 4 MWh. These added up to net annual savings of $650 for the Nanogel roof and $470 for the mid-grade skyroof. However, the investment costs were so high that the payback periods were between 450 and 550 years. Two white roofing options were considered and corresponded to a newly installed roof and one that had weathered for 3 years, thereby reducing its reflectivity. These options were evaluated by determining the mean monthly roof temperatures throughout a typical year and calculating the heat flows through the roofs based on these temperatures. The temperatures were determined by performing a heat balance on the roofs’ surfaces and considering the solar radiation incident on the roofs. The heat flows with the existing black colored roof and the proposed white roofs were thencompared and converted into heating and cooling costs. The white roofs led to summertime air-conditioning savings but created more wintertime heat losses and therefore caused net annual energy cost increases of $560 and $240 for the new and weathered roofs, respectively. The recommendations therefore were to implement the solar thermal system but not the other two proposals. Other areas which might benefit from additional investigations include lighting efficiency improvements, water use reductions, and replacement of the existing boilers with either more efficient natural gas units or wood-pellet/biomass boilers.
294

Modeling of Heat Transfer

Wahlberg, Tobias January 2011 (has links)
Modeling of heat transfer using Dymola. In this report a evaporator, economizer and superheater where modeled. The report describes how the models where modeled and what input was most suitable for a accurate model.
295

Caracterização de cinzas de queima de bagaço de cana-de-açúcar e prospecção de sua utilização como adsorvente / Characterization of sugarcane bagasse ashes and prospecting its use as adsorbent

Cacuro, Thiago Aguiar 29 March 2016 (has links)
Submitted by Milena Rubi (milenarubi@ufscar.br) on 2017-08-08T18:02:30Z No. of bitstreams: 1 CACURO_Thiago_2016.pdf: 32188052 bytes, checksum: 4ea1d6b1518db8bbf23e24ea2e2a94d7 (MD5) / Approved for entry into archive by Milena Rubi (milenarubi@ufscar.br) on 2017-08-08T18:03:10Z (GMT) No. of bitstreams: 1 CACURO_Thiago_2016.pdf: 32188052 bytes, checksum: 4ea1d6b1518db8bbf23e24ea2e2a94d7 (MD5) / Approved for entry into archive by Milena Rubi (milenarubi@ufscar.br) on 2017-08-08T18:03:16Z (GMT) No. of bitstreams: 1 CACURO_Thiago_2016.pdf: 32188052 bytes, checksum: 4ea1d6b1518db8bbf23e24ea2e2a94d7 (MD5) / Made available in DSpace on 2017-08-08T18:03:21Z (GMT). No. of bitstreams: 1 CACURO_Thiago_2016.pdf: 32188052 bytes, checksum: 4ea1d6b1518db8bbf23e24ea2e2a94d7 (MD5) Previous issue date: 2016-03-29 / Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES) / The ashes resulting from the burning of sugarcane bagasse is a heterogeneous material and has various applications as an adsorbent. To enhance and assist in prospecting new applications is critical to better understand the properties of the material. In this work, its morphological, spectroscopic and elemental characterization of the ashes of sugarcane bagasse from three different plants and two different harvests and the prospect of its use as an adsorbent. The particles of the ash were separated according to their density and in order to characterize, FTIR was used in the investigation of chemical groups present in the samples, additionally to the SEM and EDS elemental and morphological characterization of the particles present in the samples. Cenospheres, spherical particles present in ash, were identified as coreshell structure, where the core is a mixed metal oxide and the shell is a layer of silicon dioxide. The correlation between the ratio of the relative abundance between the carbonyl and hydroxyl groups and the mass distribution of the granulometric extracts were used as indirect measure of the level of oxidation of the samples. The ashes’ adsorption capacity showed affinity for the methylene blue dye with an adsorption capacity of 39 mg of dye per gram of ash used, in contrast to the low adsorption of potassium chromate solution, 1.2 mg per gram of ash. / As cinzas oriundas do processo de queima do bagaço de cana-de-açúcar são um material heterogêneo e com diversas aplicações, como a adsorção. Para potencializar e auxiliar na prospecção de novas aplicações é fundamental conhecer melhor as propriedades do material. Neste trabalho foi feita esta caracterização morfológica, espectroscópica e elementar das cinzas do bagaço da cana-de-açúcar provenientes de três diferentes usinas e duas diferentes safras e a prospecção de seu uso como adsorvente. As partículas das cinzas foram separadas de acordo com sua densidade e para a caracterização foi utilizada a técnica de FTIR na investigação dos grupos químicos presentes nas amostras e MEV juntamente com o EDS para a caracterização morfológica e elementar. As cenosferas, partículas esféricas presentes nas cinzas, foram identificadas como estruturas coreshell onde o core é composto por um misto de óxidos metálicos e o shell composto por dióxido de silício. A correlação entre a razão da abundância relativa entre os grupos de carbonila e hidroxila e a distribuição mássica dos extratos granulométricos, foi usada como medida indireta do nível de oxidação das diferentes amostras. Quanto à sua capacidade de adsorção, as cinzas mostraram afinidade na adsorção do corante azul de metileno com uma capacidade de adsorção de 39mg de corante por grama de cinza usada em contraste com a baixa adsorção apresentada para a solução de cromato de potássio com 1,2 mg por grama de cinza.
296

Um modelo de otimização para as operações de produção de vapor em caldeiras industriais: um estudo de caso na indústria de alimentos

Rocco, Cleber Damião 11 February 2011 (has links)
Made available in DSpace on 2016-06-02T19:51:48Z (GMT). No. of bitstreams: 1 3491.pdf: 1251165 bytes, checksum: 650dd47d0fec8bae05ba378f445f91dc (MD5) Previous issue date: 2011-02-11 / Universidade Federal de Sao Carlos / The aim of this work was to develop and apply a mathematical optimization model to support some key decisions in the steam production operation system with multiple industrial boilers. In the food industry, key decisions into this system are, normally, taken based on people experience, not through decision support tools based on operations research. The proposed model approaches the fuel replenishment decisions, fuel transportation and fuel inventory management. The model also determines the start-up and shutdown moments for each boiler, as well as, which of them will produce steam. An algebraic modeling language was used to implement computationally the model, which was solved by an optimization software. The adjustments and model validation were performed through a case study carried out in a large scale food industry localized in Goiania (GO). In computational experiments conducted with company s data, the results obtained by the model showed better economic performance than those from the company. In face of the good outcomes obtained by applying the model and the lack of protocols or decision tools for the studied system, this model presents itself as a feasible alternative to be considered to support some key-decisions in the steam production system with industrial boilers. / O objetivo deste trabalho foi desenvolver e aplicar um modelo matemático de otimização para apoiar algumas das principais decisões na operação de produção de vapor em múltiplas caldeiras industriais. Em indústrias de alimentos, essas decisões, em geral, são tomadas com base na experiência dos envolvidos e não com ferramentas de auxílio à tomada de decisão apoiadas pela pesquisa operacional. O modelo proposto contempla as decisões de aquisições de combustíveis dos fornecedores, o transporte para fábrica e o gerenciamento dos estoques dos combustíveis adquiridos no sistema. O modelo também determina os momentos de acionamento e desligamento das caldeiras, bem como em quais delas haverá produção de vapor. Uma linguagem de modelagem algébrica foi utilizada para implementar computacionalmente o modelo, que foi resolvido por meio de um software de otimização. Os ajustes e a validação do modelo ocorreram por meio de um estudo de caso realizado em uma indústria de alimentos de grande porte localizada em Goiânia (GO). Nos experimentos realizados com os dados fornecidos pela empresa, os resultados obtidos com o modelo apresentaram melhores desempenhos econômicos do que aqueles praticados pela operação real. Diante dos bons resultados alcançados na aplicação do modelo em situações reais e da ausência de protocolos ou ferramentas para apoiar as decisões no sistema estudado, o modelo proposto apresenta-se como uma alternativa viável para apoiar algumas das principais decisões na operação de produção de vapor em caldeiras industriais.
297

Estudo da queima do lodo secundário da indústria de celulose em caldeira de leito fluidizado / Study of cellulose industry secondary sludge burning in fluidized bed boiler

Guaitolini, Maxwel 28 July 2014 (has links)
Made available in DSpace on 2015-03-26T14:01:17Z (GMT). No. of bitstreams: 1 texto completo.pdf: 719250 bytes, checksum: 88cbe0bf2708fae3d37f97ecb94a5554 (MD5) Previous issue date: 2014-07-28 / The lack of physical space to lay out waste generated by the process is one of the major is a residue derived from pulping, bleaching of cellulosic fibers, and papermaking process; originally having the composting practice as final disposition method. High financial resources are involved to this disposition practice, including sludge transporting costs to a suitable place. Thus, the objective of this work is to provide technical support for burning a waste generated by the pulp and papermaking process at Fibria-MS, the secondary sludge from effluent treatment station, in a high pressure steam generation fluidized bed boiler. In this study, the burst test of a biomass mixture and biological sludge in a fluidized bed boiler presented the following trends, when compared to a control period (burning biomass only): reduction of dry sample content; reduction of the calorific value as such; maintenance of the value of calorific value for the dry sample; increased boiler air flow; reduction of the recirculated air flow in the boiler; bed temperature maintenance, however with greater data variability; increase in particulate matter and TRS emissions of the boiler, yet, showing acceptable values, according to Conama resolution. It was possible to conclude that the burning of treatment station biological sludge in fluidized bed boiler presents itself as an attractive practice to the pulp and paper industry, contributing to reduced occupancy of the landfill. / O setor de Celulose e Papel está em claro processo de expansão, crescimento este ocasionado pela criação de novas unidades fabris bem como pelo aumento de produção das unidades já existentes. No caso do aumento de produção em unidades já existentes, a falta de espaço físico para dispor os resíduos gerados pelo processo é um dos grandes problemas dessa indústria. Dentre os vários tipos de resíduos gerados, destaca-seo lodo biológico da estação de tratamento de efluentes, o qual é um resíduo derivado dos processos de polpação e branqueamento das fibras celulósicas e dos processos de refino e formação da folha de papel, tendo, originalmente, a prática de compostagem para sua disposição final. Para este tipo de disposição final, incluindo os custos de transporte do lodo até o local adequado, recursos financeiros elevados estão envolvidos. Desse modo, o objetivo deste trabalho é fornecer subsídios técnicos para queima de um resíduo gerado no processo de fabricação de papel e celulose da indústria Fibria-MS, o lodo secundário da estação de tratamento de efluentes, em uma caldeira de leito fluidizado de geração de vapor de alta pressão. No presente trabalho, o teste da queima de uma mistura de biomassa e lodo biológico em uma caldeira de leito fluidizado apresentou as seguintes tendências, quando comparado a um período controle (queima apenas de biomassa): redução do teor seco da amostra; redução do valor do poder calorífico tal qual; manutenção do valor de poder calorífico para a amostra seca; aumento da vazão de ar primário da caldeira; redução da vazão de ar recirculado na caldeira; manutenção da temperatura do leito, porém com maior variabilidade dos dados; aumento das emissões de material particulado e TRS da caldeira, entretanto, apresentando valores aceitáveis, segundo resolução do Conama. Foi possível concluir que a queima de lodo biológico da estação de tratamento em caldeira de leito fluidizado apresenta-se como uma prática atrativa à indústria de Celulose e Papel, contribuindo para a redução de ocupação do aterro sanitário.
298

Single photon detection based devices and techniques for pulsed time-of-flight applications

Hallman, L. (Lauri) 08 December 2015 (has links)
Abstract In this thesis, a new type of laser diode transmitter using enhanced gain-switching suitable for use with a single photon avalanche diode (SPAD) detector was developed and tested in the pulsed time-of-flight laser range finding (lidar) application. Several laser diode versions were tested and the driving electronics were developed. The driving electronics improvements enabled a pulsing frequency of up to 1 MHz, while the maximum laser output power was about 5–40 W depending on the laser diode dimensions. The large output power is advantageous especially in conditions of strong photon noise emerging from ambient light outdoors. The length of the laser pulse matches the jitter of a typical SPAD detector providing several advantages. The new laser pulser structure enables a compact rangefinder for 50 m distance measurement outdoors in sunny conditions with sub-centimeter precision (σ-value) at a valid distance measurement rate of more than 10 kHz, for example. Single photon range finding techniques were also shown to enable a char bed level measurement of a recovery boiler containing highly attenuating and dispersing flue gas. In addition, gated single photon detector techniques were shown to provide a rejection of fluorescent photons in a Raman spectroscope leading to a greatly improved signal-to-noise ratio. Photonic effects were also studied in the case of a pulsed time-of-flight laser rangefinder utilizing a linear photodetector. It was shown that signal photon noise has an effect on the optimum detector configuration, and that pulse detection jitter can be minimized with an appropriate timing discriminator. / Tiivistelmä Tässä työssä kehitettiin uudentyyppinen, tehostettua "gain-switchingiä" hyödyntävä laserdiodilähetin käytettäväksi yksittäisten fotonien avalanche-ilmaisimien (SPAD) kanssa, ja sitä testattiin pulssin lentoaikaan perustuvassa laseretäisyysmittaussovelluksessa. Useita laserdiodiversioita testattiin ja ohjauselektroniikkaa kehitettiin. Ohjauselektroniikan parannukset mahdollistivat jopa 1 MHz pulssitustaajuuden, kun taas laserin maksimiteho oli noin 5–40 W riippuen laserdiodin dimensioista. Suuri lähtöteho on edullinen varsinkin vahvoissa taustafotoniolosuhteissa ulkona. Laserpulssin pituus vastaa tyypillisen SPAD-ilmaisimen jitteriä tarjoten useita etuja. Uusi laserpulssitinrakenne mahdollistaa esimerkiksi kompaktin etäisyysmittarin 50 m mittausetäisyydelle ulkona aurinkoisessa olosuhteessa mm–cm -mittaustarkkuudella (σ-arvo) yli 10 kHz mittaustahdilla. Yksittäisten fotonien lentoaikamittaustekniikan osoitettiin myös mahdollistavan soodakattilan keon korkeuden mittauksen, jossa on voimakkaasti vaimentavaa ja dispersoivaa savukaasua. Lisäksi portitetun yksittäisten fotonien ilmaisutekniikan osoitettiin hylkäävän fluoresenssin synnyttämiä fotoneita Raman-spektroskoopissa, joka johtaa selvästi parempaan signaali-kohinasuhteeseen. Fotoni-ilmiöitä tutkittiin myös lineaarista valoilmaisinta hyödyntävän pulssin kulkuaikamittaukseen perustuvan lasertutkan tapauksessa. Osoitettiin, että signaalin fotonikohina vaikuttaa optimaaliseen ilmaisinkonfiguraatioon, ja että pulssin ilmaisujitteri voidaan minimoida sopivalla ajoitusdiskriminaattorilla.
299

New adsorption and oxidation-based approaches for water and wastewater treatment:studies regarding organic peracids, boiler-water treatment, and geopolymers

Luukkonen, T. (Tero) 12 January 2016 (has links)
Abstract This thesis examines three different areas of water treatment technology: the application of organic peracids in wastewater treatment; the removal of organic residues from boiler make-up water; and the use of geopolymers as sorbents. The main advantages of peracids as alternative wastewater disinfectants are their effective antimicrobial properties and high oxidation power, as well the absence of harmful disinfection by-products after their use. Performic, peracetic and perpropionic acids were compared in laboratory-scale disinfection, oxidation and corrosion experiments. From the techno-economical point of view, performic acid proved to be the most effective disinfectant against E. coli and fecal enterococci. However, in the bisphenol-A oxidation experiments, no advantages compared to hydrogen peroxide use were observed. It was also determined that corrosion rates on stainless steel 316L were negligible, while carbon steel seemed unsuitable in terms of corrosion for use with peracids even in low concentrations. Organic compounds in the boiler plant water-steam cycle thermally decompose and form potentially corrosive species. Activated carbon filtration was confirmed to be a suitable method for the removal of organic residue from deionized boiler make-up water. No significant differences in terms of treatment efficiency between commercial activated carbons were observed. However, acid washing as a pre-treatment reduced the leaching of impurities from new carbon beds. Nevertheless, a mixed-bed ion exchanger was required to remove leached impurities, such as silica and sodium. Geopolymers, or amorphous analogues of zeolites, can be used as sorbents in the treatment of wastewater. Metakaolin and blast-furnace-slag geopolymers showed positive potential in the treatment of landfill leachate (NH4+ ) and mine effluent (Ni, As, Sb). / Tiivistelmä Tämä väitöskirja käsittelee kolmea erillistä vedenkäsittelyteknologian osa-aluetta: orgaanisten perhappojen käyttöä jäteveden käsittelyssä, orgaanisten jäämien poistoa suolavapaasta kattilalaitoksen lisävedestä ja geopolymeerien sovelluksia vedenkäsittelysorbentteina. Orgaanisten perhappojen pääasialliset edut verrattuna kilpaileviin tekniikoihin ovat hyvä desinfiointiteho, korkea hapetuspotentiaali ja desinfioinnin sivutuotteiden muodostumattomuus. Permuurahais-, peretikka- ja perpropaanihapon vertailu osoitti permuurahaishapon olevan kemikaaleista tehokkain E. coli - ja enterokokkibakteerien inaktivoinnissa kustannus- ja teknisistä näkökulmista. Hapetuksessa, jossa käytettiin bisfenoli-A:ta malliaineena, ei kuitenkaan havaittu etua verrattuna edullisempaan vetyperoksidiin. Ruostumattoman teräksen (316L) pinnalla ei havaittu merkittävää korroosiota, kun taas hiiliteräs ei sovellu käytettäväksi perhappojen kanssa. Orgaaniset jäämät kattilalaitoksen vesi-höyrykierrossa hajoavat termisesti pienen moolimassan hapoiksi ja aiheuttavat korroosioriskin. Aktiivihiilisuodatuksen todettiin olevan soveltuva menetelmä orgaanisten jäämien poistoon lisävedestä. Aktiivihiililaatujen välillä ei havaittu merkittäviä eroja, mutta happopesu aktiivihiilen esikäsittelynä vähensi hiilestä liukenevien epäpuhtauksien määrää. Geopolymeerit ovat zeoliittien amorfisia analogeja ja niiden ioninvaihtokykyä voidaan hyödyntää vedenkäsittelysovelluksissa. Metakaoliini- ja masuunikuonapohjaisten geopolymeerien todettiin olevan lupaavia materiaaleja malliliuosten, kaatopaikan suotoveden ja kaivoksen purkuveden käsittelyssä poistettaessa ammoniumia, nikkeliä, arseenia ja antimonia.
300

Optimisation de chaufferies collectives multi-energies : dimensionnement et commande de systèmes de stockage thermique par hydro-accumulation

Labidi, Mouchira 30 April 2015 (has links)
Les travaux présentés dans ce manuscrit portent sur l’optimisation d’une chaufferie collective multi-énergie en l’équipant d’un système de stockage thermique de type hydro-accumulation. L’efficacité de ce dernier dépend de sa capacité à conserver son énergie initiale. Ainsi, pour minimiser les pertes thermiques, le système de stockage doit être correctement isolé. Un modèle de ballon d’hydro-accumulation stratifié est développé et validé expérimentalement. Une étude paramétrique est menée afin d’étudier l’impact, sur les pertes thermiques, de paramètres géométriques et météorologiques. Ensuite, une approche de dimensionnement, fondée sur une stratégie de gestion séquentielle et une étude paramétrique est proposée. Plusieurs critères énergétiques et économiques peuvent ainsi être évalués pour différents volumes de stockage thermique. L’approche de dimensionnement proposée a été appliquée à plusieurs sites exploités par Cofely GDF-Suez, notre partenaire industriel. Les résultats obtenus montrent que le dimensionnement optimal du système de stockage et la gestion intelligente du procédé permettent d'optimiser le fonctionnement d’un site. Des économies énergétiques et financières importantes peuvent ainsi être réalisées. La stratégie de gestion séquentielle proposée n’anticipe pas les besoins du réseau de chaleur. C’est pourquoi une stratégie fondée sur la commande prédictive (MPC pour Model Predictive Control) est susceptible d’améliorer le fonctionnement et les performances d’une chaufferie collective équipée d’un système d’hydro-accumulation. Afin de mettre en œuvre un tel contrôleur, la puissance thermique demandée par le réseau de chaleur doit être correctement prédite. Par conséquent, une méthode de prédiction a été développée. Elle s’appuie sur une analyse multi-résolution par transformée en ondelettes discrète et sur l’utilisation de réseaux de neurones artificiels de type perceptron multicouche. La stratégie séquentielle (non prédictive) et la stratégie prédictive ont été appliquées à une chaufferie collective mixte située dans une commune du nord de la France. Pour ce cas d’étude, la stratégie prédictive est plus efficace. De plus, les résultats montrent que, quelle que soit la stratégie utilisée, équiper la chaufferie d’un système d’hydro-accumulation correctement dimensionné est un investissement rentable. Il permet de minimiser la consommation d’énergie fossile et, par conséquent, le coût économique et les émissions de CO2. / The present work deals with optimizing a multi-energy district boiler by adding to the plant a thermal water storage tank. The effectiveness of such a system depends on how long the stored energy can be kept without considerable degradation. The storage tank should be properly insulated to reduce the rate of heat loss. Thus, firstly, a stratified water thermal storage model is developed and experimentally validated. A parametric study is carried out to determine the influence of geometric and meteorological parameters on heat loss. Next, a reliable sizing method based on a sequential management strategy and a parametric study is proposed. Various energy and economic criteria have been evaluated for a range of thermal storage sizes. The proposed methodology has been applied to many plants managed by Cofely GDF-Suez, our industrial partner. Results highlight the ability of a thermal storage tank (optimally sized and managed) to improve the operation of a multi-energy district boiler and realize significant energy and economic savings. The main drawback of the proposed sequential management strategy lies in not taking into account the future power demand. That is why a strategy based on a Model Predictive Controller (MPC) is likely to improve operation and performance. In order to implement such a controller, the power demand has to be accurately forecasted. As a consequence, a short-term forecast method, based on wavelet-based Multi-Resolution Analysis (MRA) and multilayer Artificial Neural Networks (ANN) is proposed. Both the sequential and the predictive strategies are applied to a northeast France multi-energy district boiler selected as a case study. The main result to retain is that the efficiency of water thermal storage tank is mainly related to its design and the way it is managed. For this case study, the predictive strategy regardless the size of the storage tank, the predictive strategy is more reliable. Furthermore, in all cases an adequately sized and managed thermal storage tank is a profitable investment. It allows the fossil energy consumption to be significantly reduced. The same remark applies to the functioning costs and CO2 emissions.

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