<div>Inorganic metal chalcogenide materials are of great importance in the semiconducting field for various electronic applications such as photovoltaics, thermoelectrics, sensors, and many others. Compared to traditional vacuum processing routes, solution processing provides an alternate cost-effective route to synthesize these inorganic materials through its ease of synthesis and device fabrication, higher material utilization, mild processing conditions, and opportunity for roll-to-roll manufacturing. One such versatile solution chemistry involving a mixture of amine and thiol species has evolved in the past few years as a common solvent for various precursor dissolutions including metal salts, metal oxides, elemental metals, and chalcogens.</div><div><br></div><div>The amine-thiol solvent system has been used by various researchers for the fabrication of inorganic materials, but without the complete understanding of the chemistry involved in this system, utilizing its full potential, and overcoming any inherent limitations will be difficult. So, to identify the organometallic complexes and their reaction pathways, the precursor dissolutions in amine-thiol solutions, specifically for elemental metals like Cu, In and chalcogens like Se, Te were studied using X-ray absorption, nuclear magnetic resonance, infrared, and Raman spectroscopy along with electrospray ionization mass spectrometry techniques. These analyses suggested the formation of metal thiolate complexes in the solution with the release of hydrogen gas in the case of metal dissolutions confirming irreversibility of the dissolution. Insights gained for chalcogen dissolutions confirmed the formation of different species like monoatomic or polyatomic clusters when different amine-thiol pair is used for dissolution. Results from these analyses also identified the role of each component in the dissolution which allowed for tuning of the solutions by isolating the complexes to reduce their reactivity and corrosivity for commercial applications.</div><div><br></div><div>After identifying complexes in metal dissolution for Cu and In metals, the decomposition pathway for these complexes was studied using X-ray diffraction and gas chromatography mass spectrometry techniques which confirmed the formation of phase pure metal chalcogenide material with a release of volatile byproducts like hydrogen sulfide and thiirane. This allowed for the fabrication of impurity-free thin-film Cu(In,Ga)S2 material for use in photovoltaic applications. The film fabrication with reduced carbon impurity achieved using this solvent system yielded a preliminary promising efficiency beyond 12% for heavy alkali-free, low bandgap CuInSe2 material. Along with promising devices, by utilizing the understanding of the chalcogen complexation, a new method for CuInSe2 film fabrication was developed with the addition of selenide precursors and elemental selenium which enabled first-ever fabrication of a solution-processed CuInSe2 thin film with thickness above 2 μm and absence of any secondary fine-grain layer.</div><div><br></div><div>Along with thin-film fabrication, a room temperature synthesis route for lead chalcogenide materials (PbS, PbSe, PbTe) with controlled size, shape, crystallinity, and composition of nanoparticle self-assemblies was demonstrated. Micro-assemblies formed via this route, especially the ones with hollow-core morphology were subjected to a solution-based anion and cation exchange to introduced desired foreign elements suitable for improving the thermoelectric properties of the material. Adopting from traditional hot injection and heat up synthesis routes, a versatile synthesis procedure for various binary, ternary, and quaternary metal chalcogenide (sulfide and sulfoselenide) nanoparticles from elemental metals like Cu, Zn, Sn, In, Ga, and Se was developed. This new synthesis avoids the incorporation of impurities like O, Cl, I, Br arising from a traditional metal oxide, halide, acetate, or other similar metal salt precursors giving an opportunity for truly impurity-free colloidal metal chalcogenide nanoparticle synthesis.</div>

Soil carbon is the largest sink and source of the global carbon cycle and is disturbed by several natural, anthropogenic, and environmental factors. The global increase of atmospheric CO2 affects soil carbon cycling through varied biogeochemical processes. The first chapter is a compilation of current information on potential factors triggering soil acidification and weathering mechanisms under elevated CO2 and their consequences on soil inorganic carbon (SIC) pool and quality. Soil water content and precipitation were critical factors influencing elevated CO2 effects on the SIC pool. The second chapter examines a detailed column experiment in which six soils from the state of Mississippi, USA, representing acidic, neutral, and alkaline pH, were exposed to different CO2 enrichments (100%, 10%, and 1%) for 30 days. The leachates’ pH tended to attain an equilibrium state (neutral) with time under CO2 saturation. SIC increased under CO2 saturation, whereas cation exchange capacity (CEC) showed a decreasing pattern in all soils. In the third chapter, an eXplainable artificial intelligence (XAI) was performed to visualize the different forms of soil carbon variability across the Mississippi River Basin area. This model explains key insights and local discrepancies, suggesting a solution to the “Black-Box” issue. The best performing model, stack ensemble, showed improved RMSE (3 to 8%) and spatial variability for soil carbons than other ML models, especially after adding the residuals from regression analyses. Land cover type > soil pH > total nitrogen, > NDVI were identified as the top four crucial factors for predicting SOC when bulk density > precipitation, soil pH > mean annual temperature described SIC. The proposed automatic machine learning (AutoML) model with model agnostic interpolations might be a hallmark to mitigate the C loss under adverse climate change conditions and allow diverse knowledge groups to adopt a new interpretable ML algorithm more confidently. Findings from this study help predict the impact of elevated atmospheric CO2 on soil pH, acidification, and nutrient availability and develop strategies for sustainable land management practices under a changing climate.

Nanopartiklar är partiklar med storlekar i området 1 till 100 nm, och som uppvisar nanospecifika egenskaper. Egenskaperna kan variera helt mellan olika typer av nanopartiklar, även bland partiklarna och deras respektive material i bulk format på grund av deras unika storlekar, former och strukturer. I denna studie har vi analyserat storlekarna och den kolloidal stabiliteten på tre nanopartiklar, Co, Y2O3, CeO2 i färskvatten och färskvatten med naturligt organiskt material med hjälp av sonifikation, NTA, AAS och ICP analys. Nanopartiklarna lät vara utsatta i lösningarna i upp till six timmar, där analys med hand av NTA skedde efter den nollte, första och sjätte timmen. Partiklarna uppvisade olika egenskaper, och alla tre partiklar varierade i storlek under experimentet. Kobalt hade tendensen att minska i storlek i bägge lösningar, medan storlekarna på yttrium- och cerium oxid tenderade att variera. För att främja vår förståelse av nanopartiklar, behövs fler studier för att få en full förståelse för de unika egenskaperna hos dessa partiklar. / Nanoparticles are particles with sizes in the range of 1 to 100 nm, which also have nanospecific properties. Their properties vary wildly between different types of nanoparticles, even among nanoparticles and their respective particles in bulk format heeding to their highly individual shapes, sizes and structures. In this study we analyzed the sizes and colloidal stability of three different nanoparticles, Co, Y2O3 and CeO2 in freshwater and freshwater with natural organic matter solutions using sonication, NTA-, AAS-, and ICP analysis. The nanoparticles were exposed to the solutions for up to six hours, with analysis being performed at the zero, first and sixth hour. The particles indeed showed different properties, as all three particles varied in size throughout the experiment. Cobalt had the tendency to decrease in size as time progressed in both solutions, while the mean size of yttrium- and cerium oxide varied. To further our understanding of nanoparticles, more studies need to be performed to properly understand the individual properties of these nanoparticles.

Forskning om entreprenörskap fokuserar på framgång som ignorerar den höga felfrekvensen av Nya företag. Många nya företag misslyckas så hur entreprenörer hantera det när deras företag misslyckas? Framgångsrika entreprenörer prisar fördelarna med misslyckande som en värdefull lärare. Resultatet av misslyckande regelbundet fylld med ekonomiska, sociala, psykologiska och fysiska hälsoproblem. Syftet med denna forskning är att bedöma företagets misslyckande upplevelser för företagare, från det ögonblick resultatet genom att  återhämtningen för att hantera företagande fel och avsluta för påverkan av den slutna företag.  I denna forskning aspekter av livet som påverka av entreprenörs fel undersöka ekonomiskt, socialt och psykologiskt att belysa faktorer som kan påverka mängden av kostnaderna för ett misslyckande. Därefter beskriver forskningen hur entreprenörer lära av misslyckanden. Den presenterar på resultaten av företagets misslyckande, inklusive hantera fel och återhämtning tillsammans med kognitiva och beteendemässiga utfall. / Research on entrepreneurship focuses on success which ignores the high failure rate of new ventures. Many new ventures fail so how entrepreneurs deal with it when their venture    fails? Successful entrepreneurs praising the advantages of failure as a valuable teacher. The result of failure is regularly filled with economic, social, psychological, and physical health disorder. The aim of this research is to assessment venture failure experiences for entrepreneurs, from the instant result through to recovery for coping with entrepreneurial failure and exit for impact of the closed venture. In this research, aspects of life affected by entrepreneurial failure examine economically, socially and psychologically in highlighting factors that may influence the amount of costs of failure. Next, the research describes how entrepreneurs learn from failure. It presents on the outcomes of venture failure, including coping with failure and recovery together with cognitive and behavioral outcomes. The main objective of the research study is to understand the failure from entrepreneurs    who have experienced it and also to make a theoretical framework of failure based on entrepreneurial venture failure experiences. Every entrepreneur starts up a venture with high expectations of achieving success. Failure can be emotionally disturbing, devastating,  painful, distressing and costly for the entrepreneur who may have to aspect the stigma of failure and the loss of reputation. The entrepreneur can get involved in grief, heartache, anxiety, depression, shame, rejection and discouragement (Politis &amp; Gabrielsson, 2009). The purpose of the research is to investigate how entrepreneurs realize and react to venture  failure. Moreover, entrepreneurs are looking for positive aspects of failure as enhancing experiences that help their coping with entrepreneurial failure, learning from failure, the willingness to begin a new venture and also trigger changes in upcoming decision-making. The purpose of the research is to take a view of the existed experience of failure, taking into consideration impact from the entrepreneurship.

Before the reformation and the schism of the Catholic Church, it had always been the duty of the Church and not of the state, to undertake the seven corporal works of mercy; feed the hungry, give drink to the thirsty, welcome the stranger, clothe the naked, visit the sick, visit the prisoner, and bury the dead.¹ By dissolving these institutions, Henry had unwittingly created what would become a social disaster of biblical proportions. In essence, this act was rendering thousands of the poor and elderly without a home or shelter, it denied the country of much of the medical aid that has been offered by the church, it denied future generations of thousands of volumes of books and scriptures from the monastic libraries, as well as denied many an education who would have otherwise never received one without the help of the Church. The ultimate goal of my thesis is to prove my hypothesis that the dissolution of the monasteries by King Henry VIII was not merely a contributory factor in the need for the creation of poor laws, but the deciding factor (in a myriad of societal issues) for their creation. Footnote 1: Matthew 25 vv. 32-46.

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Through two books and a series of video documentations of live performances Mette Ingvartsen makes choreography into a territory of physical, artistic and social experimentation. The Artificial Nature Series focusses on how relations between human and non-human agency can be explored and reconfigured through choreography. By investigating and creating a ‘nonhuman theater’ questions regarding material agency, ecology, natural disasters, the Anthropocene and non-subjective performativity are posed. The resulting reflections are closely related to the poetic principles utilized to create the performances, while also drawing connections to territories outside theater. By contrast, 69 positions inscribes itself into a history of human performance with afocus on nudity, sexuality and how the body historically has been a site for political struggles. By creating a guided tour through sexual performances – from the naked protest actions of the 1960’s, through an archive ofpersonal performances into a reflection on contemporary sexual practice – this solo work rethinks audience participation and proposes a notion of soft and social choreography. The contrasting performative strategiesarticulate a twofold notion of expanded choreography: on the one hand movement is extended beyond the human body by including the agency of nonhuman performers, and on the other hand, movement is expanded into animaginary and virtual space thanks to ‘language choreography’. / <p>LINKS</p><p>https://vimeo.com/164552586</p><p>https://vimeo.com/164558381</p>

<p></p><p>This doctoral dissertation takes the reader through a journey where applied shear rheology and flow-velocimetry are used to understand the mesoscopic factors that control the flow behavior of three microstructured fluids. Three individual protocols that measure relative physical and mechanical properties of the flow are developed. Each protocol aims to advance the particular transformation of novel soft materials into a commercial product converging in the demonstration of the real the chemical, physical and thermodynamical factors that could potentially drive their successful transformation. </p> <p> </p> <p>First, this dissertation introduces the use of rotational and oscillatory shear rheometry to quantify the solvent evaporation effect on the flow behavior of polymer solutions used to fabricate isoporous asymmetric membranes. Three different A-B-C triblock copolymer were evaluated: polyisoprene-<i>b</i>-polystyrene-<i>b</i>-poly(4-vinylpyridine) (ISV); polyisoprene-<i>b</i>-polystyrene-<i>b</i>-poly(<i>N</i>,<i>N</i>-dimethylacrylamide) (ISD); and polyisoprene-<i>b</i>-polystyrene-<i>b</i>-poly(<i>tert</i>-butyl methacrylate) (ISB). The resulting evaporation-induced microstructure showed a solution viscosity and film viscoelasticity strongly dependent on the chemical structure of the triblock copolymer molecules. </p> <p> </p> <p>Furthermore, basic shear rheometry, flow birefringence, and advanced flow-velocimetry are used to deconvolute the flow-microstructure relationships of concentrated surfactant solutions. Sodium laureth sulfate in water (SLE₁S) was used to replicate spherical, worm-like, and hexagonally packed micelles and lamellar structures. Interesting findings demonstrated that regular features of flow curves, such as power-law shear thinning behavior, resulted from a wide variety of experimental artifacts that appeared when measuring microstructured fluids with shear rheometry.</p> <p> </p> <p>Finally, the successful integration of shear rheometry to calculate essential parameters to be used in a cost-effective visualization technique (still in development) used to calculate the dissolution time of polymers is addressed. The use of oscillatory rheometry successfully quantify the viscoelastic response of polyvinyl alcohol (PVA) solutions and identify formulations changes such as additive addition. The flow behavior of PVA solutions was correlated to dissolution behavior proving that the developed protocol has a high potential as a first screening tool.</p><br><p></p>

In this dissertation, I critically evaluate the VAT treatment of common partnership transactions that are encountered during the life of a partnership. Of great significance, is that at common law a partnership is not regarded as a person, but for VAT purposes it is treated as a separate person. This creates a strong dichotomy between the general legal nature, and the VAT character of a partnership transaction. The partnership and the VAT law dichotomy, is an important theme that runs through most of the thesis. Only once I have established the nature of the transaction for VAT purposes – whether in keeping with or differing from the common law – do I apply the relevant provisions of the VAT Act to determine the VAT implications of the transaction. An important general principle is that what is supplied or acquired by the body of persons who make up the partnership, within the course and scope of its common purpose, is for VAT purposes, supplied or acquired by the partnership as a separate person. I conclude that there are difficulties and uncertainties regarding the application of the provisions of the VAT Act to various partnership transactions. For the sake of certainty and simplicity, I propose amendments to the current provisions that are relevant to partnership transactions, and also propose additional provisions. The proposed amendments seek to align with the purpose of the VAT Act and the principles upon which it is based, and also to adhere to internationally accepted principles for a sound VAT system. I also pinpoint those aspects of the VAT Act that can be clarified by the SARS in an interpretation statement. I further identify issues that require more research, eg issues arising from a partnership’s participation in cross-border trade. / Mercantile Law / LL. D.

Les problèmes de complémentarité interviennent dans de nombreux domaines scientifiques : économie, mécanique des solides, mécanique des fluides. Ce n'est que récemment qu'ils ont commencé d'intéresser les chercheurs étudiant les écoulements et le transport en milieu poreux. Les problèmes de complémentarité sont un cas particulier des inéquations variationnelles. Dans cette thèse, on offre plusieurs contributions aux méthodes numériques pour résoudre les problèmes de complémentarité. Dans la première partie de cette thèse, on étudie les problèmes de complémentarité linéaires 0 6 x ⊥ (Mx+q) > 0 où, x l'inconnue est dans Rn et où les données sont q, un vecteur de Rn, et M, une matrice d'ordre n. L'existence et l'unicité de ce problème est obtenue quand la matrice M est une P-matrice. Une méthode très efficace pour résoudre les problèmes de complémentarité est la méthode de Newton-min, une extension de la méthode de Newton aux problèmes non lisses.Dans cette thèse on montre d'abord, en construisant deux familles de contre-exemples, que la méthode de Newton-min ne converge pas pour la classe des P-matrices, sauf si n= 1 ou 2. Ensuite on caractérise algorithmiquement la classe des P-matrices : c'est la classe des matrices qui sont telles que quel que, soit le vecteur q, l'algorithme de Newton-min ne fait pas de cycle de deux points. Enfin ces résultats de non-convergence nous ont conduit à construire une méthode de globalisation de l'algorithme de Newton-min dont nous avons démontré la convergence globale pour les P-matrices. Des résultats numériques montrent l'efficacité de cet algorithme et sa convergence polynomiale pour les cas considérés. Dans la deuxième partie de cette thèse, nous nous sommes intéressés à un exemple de problème de complémentarité non linéaire concernant les écoulements en milieu poreux. Il s'agit d'un écoulement liquide-gaz à deux composants eau-hydrogène que l'on rencontre dans le cadre de l'étude du stockage des déchets radioactifs en milieu géologique. Nous présentons un modèle mathématique utilisant des conditions de complémentarité non linéaires décrivant ces écoulements. D'une part, nous proposons une méthode de résolution et un solveur pour ce problème. D'autre part, nous présentons les résultats numériques que nous avons obtenus suite à la simulation des cas-tests proposés par l'ANDRA (Agence Nationale pour la gestion des Déchets Radioactifs) et le GNR MoMaS. En particulier, ces résultats montrent l'efficacité de l'algorithme proposé et sa convergence quadratique pour ces cas-tests