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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
631

Coverage Manifold Estimation in Cellular Networks via Conditional GANs

Veni Goyal (18457590) 29 April 2024 (has links)
<p dir="ltr">This research introduces an approach utilizing a novel conditional generative adversarial network (cGAN) tailored specifically for the prediction of cellular network coverage. In comparison to state-of-the-art method convolutional neural networks (CNNs), our cGAN model offers a significant improvement by translating base station locations within any Region-of-Interest (RoI) into precise coverage probability values within a designated region-of-evaluation (RoE). </p><p dir="ltr">By leveraging base station location data from diverse geographical and infrastructural landscapes spanning regions like India, the USA, Germany, and Brazil, our model demonstrates superior predictive performance compared to existing CNN-based approaches. Notably, the prediction error, as quantified by the L1 norm, is reduced by two orders of magnitude in comparison to state-of-the-art CNN models.</p><p dir="ltr">Furthermore, the coverage manifolds generated by our cGAN model closely resemble those produced by conventional simulation methods, indicating a substantial advancement in both prediction accuracy and visual fidelity. This achievement underscores the potential of cGANs in enhancing the precision and reliability of cellular network performance prediction, offering promising implications for optimizing network planning and deployment strategies.</p>
632

Impact of Device Parametric Tolerances on Current Sharing Behavior of a SiC Half-Bridge Power Module

Watt, Grace R. 22 January 2020 (has links)
This paper describes the design, fabrication, and testing of a 1.2 kV, 6.5 mΩ, half-bridge, SiC MOSFET power module to evaluate the impact of parametric device tolerances on electrical and thermal performance. Paralleling power devices increases current handling capability for the same bus voltage. However, inherent parametric differences among dies leads to unbalanced current sharing causing overstress and overheating. In this design, a symmetrical DBC layout is utilized to balance parasitic inductances in the current pathways of paralleled dies to isolate the impact of parametric tolerances. In addition, the paper investigates the benefits of flexible PCB in place of wire bonds for the gate loop interconnection to reduce and minimize the gate loop inductance. The balanced modules have dies with similar threshold voltages while the unbalanced modules have dies with unbalanced threshold voltages to force unbalanced current sharing. The modules were placed into a clamped inductive DPT and a continuous, boost converter. Rogowski coils looped under the wire bonds of the bottom switch dies to observe current behavior. Four modules performed continuously for least 10 minutes at 200 V, 37.6 A input, at 30 kHz with 50% duty cycle. The modules could not perform for multiple minutes at 250 V with 47.7 A (23 A/die). The energy loss differential for a ~17% difference in threshold voltage ranged from 4.52% (~10 µJ) to -30.9% (~30 µJ). The energy loss differential for a ~0.5% difference in V_th ranged from -2.26% (~8 µJ) to 5.66% (~10 µJ). The loss differential was dependent on whether current unbalance due to on-state resistance compensated current unbalance due to threshold voltage. While device parametric tolerances are inherent, if the higher threshold voltage devices can be paired with devices that have higher on-state resistance, the overall loss differential may perform similarly to well-matched dies. Lastly, the most consistently performing unbalanced module with 17.7% difference in V_th had 119.9 µJ more energy loss and was 22.2°C hotter during continuous testing than the most consistently performing balanced module with 0.6% difference inV_th. / Master of Science / This paper describes the design, construction, and testing of advanced power devices for use in electric vehicles. Power devices are necessary to supply electricity to different parts of the vehicle; for example, energy is stored in a battery as direct current (DC) power, but the motor requires alternating current (AC) power. Therefore, power electronics can alter the energy to be delivered as DC or AC. In order to carry more power, multiple devices can be used together just as 10 people can carry more weight than 1 person. However, because the devices are not perfect, there can be slight differences in the performance of one device to another. One device may have to carry more current than another device which could cause failure earlier than intended. In this research project, multiple power devices were placed into a package, or "module." In a control module, the devices were selected with similar properties to one another. In an experimental module, the devices were selected with properties very different from one another. It was determined that the when the devices were 17.7% difference, there was 119.9 µJ more energy loss and it was 22.2°C hotter than when the difference was only 0.6%. However, the severity of the difference was dependent on how multiple device characteristics interacted with one another. It may be possible to compensate some of the impact of device differences in one characteristic with opposing differences in another device characteristic.
633

Generative Approach For Multivariate Signals

Sawant, Vinay, Bhende, Renu January 2024 (has links)
In this thesis, we explored the generative adversarial network called uTSGAN to generate patterns from multivariate CAN bus time series dataset. Since the given data is unlabelled, unprocessed and highly imbalanced containing large amount of missing values, we have to define and discard a few timestamps and limit the focus of the study to the reduced subset involving patterns of the 10-second window size, which are categorised and clustered into majority and minority classes. To generate such an imbalanced set, we have used image based time series GAN called uTSGAN which transforms a time sequence into a spectrogram image and back to a time sequence within the same GAN framework. For the comparison, we also prepared a resampled (balanced) dataset from the imbalanced set to use in alternative experiments. This comparison evaluates the results of the conventional resampling approach against the baseline as well as our novel implementations. We propose two new methods using "cluster density based" and "sample loss based" techniques. Throughout the experimentation, the "cluster density based" GANs consistently achieved better results on some common and uncommon evaluations for multivariate and highly imbalanced sample sets. Among some regular evaluation methods, classification metrics such as balanced accuracy and precision provide a better understanding of experimentation results. The TRTS balanced accuracy and precision from "cluster density based" GAN achieves over 82% and 90% with an improvement of 20-30% and 14-18% respectively from that of baseline; the TSTR balanced accuracy of "cluster density based" increased by 10.6% from that of baseline and it show slightly better precision with respect to that of the baseline when compared on generated results from univariate experiments. Secondly, the alternative "resampling based" implementations show similar values to that of the baseline in TRTS and TSTR classifications. Simultaneously, More distinguished results are seen using a quantitative metric called Earth Mover’s Distance(EMD). We have used this distance measure to calculate the overall mean EMD and clusterwise mean EMD between real samples and fake (i.e. generated) samples. During their evaluations, "cluster density based" experiments showed significantly better results for not only majority but also minority clusters as compared to the results of baseline and "resampling based" experiments. At the end, we have opened a discussion on how one can utilize our findings in MAR problem aswell as improve the results by taking some precautionary measures.
634

Analyse d’image geometrique et morphometrique par diagrammes de forme et voisinages adaptatifs generaux / Geometric and morphometric image analysis by shape diagrams and general adaptive neighborhoods

Rivollier, Séverine 05 July 2010 (has links)
Les fonctionnelles de Minkowski définissent des mesures topologiques et géométriques d'ensembles, insuffisantes pour la caractérisation, des ensembles différents pouvant avoir les mêmes fonctionnelles. D'autres fonctionnelles de forme, géométriques et morphométriques, sont donc utilisées. Un diagramme de forme, défini grâce à deux fonctionnelles morphométriques, donne une représentation permettant d'étudier les formes d'ensembles. En analyse d'image, ces fonctionnelles et diagrammes sont souvent limités aux images binaires et déterminés de manière globale et mono-échelle. Les Voisinages Adaptatifs Généraux (VAG) simultanément adaptatifs avec les échelles d'analyse, structures spatiales et intensités des images, permettent de pallier ces limites. Une analyse locale, adaptative et multi-échelle des images à tons de gris est proposée sous forme de cartographies des fonctionnelles de forme à VAG.Les VAG, définis en tout point du support spatial d'une image à tons de gris, sont homogènes par rapport à un critère d'analyse représenté dans un modèle vectoriel, suivant une tolérance d'homogénéité. Les fonctionnelles de forme calculées pour chaque VAG de l'image définissent les cartographies des fonctionnelles de forme à VAG. Les histogrammes et diagrammes de ces cartographies donnent des distributions statistiques des formes des structures locales de l'image contrairement aux histogrammes classiques qui donnent une distribution globale des intensités de l'image. L'impact de la variation des critères axiomatiques des VAG est analysé à travers ces cartographies, histogrammes et diagrammes. Des cartographies multi-échelles sont construites, définissant des fonctions de forme à VAG. / Minkowski functionals define set topological and geometrical measurements, insufficient for the characterization, because different sets may have the same functionals. Thus, other shape functionals, geometrical and morphometrical are used. A shape diagram, defined thanks to two morphometrical functionals, provides a representation allowing the study of set shapes. In quantitative image analysis, these functionals and diagrams are often limited to binary images and achieved in a global and monoscale way. The General Adaptive Neighborhoods (GANs) simultaneously adaptive with the analyzing scales, the spatial structures and the image intensities, enable to overcome these limitations. The GAN-based Minkowski functionals are introduced, which allow a gray-tone image analysis to be realized in a local, adaptive and multiscale way.The GANs, defined around each point of the spatial support of a gray-tone image, are homogeneous with respect to an analyzing criterion function represented in an algebraic model, according to an homogeneity tolerance. The shape functionals computed on the GAN of each point of the spatial support of the image, define the so-called GAN-based shape maps. The map histograms and diagrams provide statistical distributions of the shape of the gray-tone image local structures, contrary to the classical histogram that provides a global distribution of image intensities. The impact of axiomatic criteria variations is analyzed through these maps, histograms and diagrams. Thus, multiscale maps are built, defining GAN-based shape functions.
635

Dynamics of free and bound excitons in GaN nanowires

Hauswald, Christian 17 March 2015 (has links)
GaN-Nanodrähte können mit einer hohen strukturellen Perfektion auf verschiedenen kristallinen und amorphen Substraten gewachsen werden. Sie bieten somit faszinierende Möglichkeiten, sowohl zur Untersuchung von fundamentalen Eigenschaften des Materialsystems, als auch in der Anwendung in optoelektronischen Bauteilen. Obwohl bereits verschiedene Prototypen solcher Bauteile vorgestellt wurden, sind viele grundlegende Eigenschaften von GaN-Nanodrähten noch ungeklärt, darunter die interne Quanteneffizienz (IQE), welche ein wichtiges Merkmal für optoelektronische Anwendungen darstellt. Die vorliegende Arbeit präsentiert eine detaillierte Untersuchung der Rekombinationsdynamik von Exzitonen, in selbst-induzierten und selektiv gewachsenen GaN Nanodraht-Proben, welche mit Molekularstrahlepitaxie hergestellt wurden. Die zeitaufgelösten Photolumineszenz (PL)-Experimente werden durch Simulationen ergänzt, welche auf Ratengleichungs-Modellen basieren. Es stellt sich heraus, dass die Populationen von freien und gebundenen Exzitonen gekoppelt sind und zwischen 10 und 300 K von einem nichtstrahlenden Kanal beeinflusst werden. Die Untersuchung von Proben mit unterschiedlichem Nanodraht-Durchmesser und Koaleszenzgrad zeigt, dass weder die Nanodraht-Oberfläche, noch Defekte als Folge von Koaleszenz diesen nichtstrahlenden Kanal induzieren. Daraus lässt sich folgern, dass die kurze Zerfallszeit von Exzitonen in GaN-Nanodrähten durch Punktdefekte verursacht wird, welche die IQE bei 10 K auf 20% limitieren. Der häufig beobachtete biexponentiellen PL-Zerfall des Donator-gebundenen Exzitons wird analysiert und es zeigt sich, dass die langsame Komponente durch eine Kopplung mit Akzeptoren verursacht wird. Motiviert durch Experimente, welche eine starke Abhängigkeit der PL-Intensität vom Nanodraht-Durchmesser zeigen, wird die externen Quanteneffizienz von geordneten Nanodraht-Feldern mit Hilfe numerischer Simulationen der Absorption und Extraktion von Licht in diesen Strukturen untersucht. / GaN nanowires (NWs) can be fabricated with a high structural perfection on various crystalline and amorphous substrates. They offer intriguing possibilities for both fundamental investigations of the GaN material system as well as applications in optoelectronic devices. Although prototype devices based on GaN NWs have been presented already, several fundamental questions remain unresolved to date. In particular, the internal quantum efficiency (IQE), an important basic figure of merit for optoelectronic applications, is essentially unknown for GaN NWs. This thesis presents a detailed investigation of the exciton dynamics in GaN NWs using continuous-wave and time-resolved photoluminescence (PL) spectroscopy. Spontaneously formed ensembles and ordered arrays of GaN NWs grown by molecular-beam epitaxy are examined. The experiments are combined with simulations based on the solution of rate equation systems to obtain new insights into the recombination dynamics in GaN NWs at low temperatures. In particular, the free and bound exciton states in GaN NWs are found to be coupled and affected by a nonradiative channel between 10 and 300 K. The investigation of samples with different NW diameters and coalescence degrees conclusively shows that the dominating nonradiative channel is neither related to the NW surface nor to coalescence-induced defects. Hence, we conclude that nonradiative point defects are the origin of the fast recombination dynamics in GaN NWs, and limit the IQE of the investigated samples to about 20% at cryogenic temperatures. We also demonstrate that the frequently observed biexponential decay for the donor-bound exciton originates from a coupling with the acceptor-bound exciton state in the GaN NWs. Motivated by an experimentally observed, strong dependence of the PL intensity of ordered GaN NW arrays on the NW diameter, we perform numerical simulations of the light absorption and extraction to explore the external quantum efficiency of these samples.
636

Properties of Zincblende GaN and (In,Ga,Al)N Heterostructures grown by Molecular Beam Epitaxy

Müllhäuser, Jochen R. 17 June 1999 (has links)
Während über hexagonales (alpha) GaN zum ersten Mal 1932 berichtet wurde, gelang erst 1989 die Synthese einer mit Molekularstrahlepitaxie (MBE) auf 3C-SiC epitaktisch gewachsenen, metastabilen kubischen (eta) GaN Schicht. Die vorliegende Arbeit befaßt sich mit der Herstellung der Verbindungen eta-(In,Ga,Al)N mittels RF-Plasma unterstützter MBE auf GaAs(001) und den mikrostrukturellen sowie optischen Eigenschaften dieses neuartigen Materialsystems. Im Vergleich zur hexagonalen bietet die kubische Kristallstruktur auf Grund ihrer höheren Symmetrie potentielle Vorteile für die Anwendung in optischen und elektronischen Bauelementen. Viele wichtige Materialgrößen der kubischen Nitride sind jedoch noch gänzlich unbekannt, da sich die Synthese einkristalliner Schichten als sehr schwierig erweist. Das Ziel dieser Arbeit ist es daher erstens, die technologischen Grenzen der Herstellung von bauelementrelevanten kubischen (In,Ga,Al)N Heterostrukturen auszuweiten und zweitens, einen Beitrag zur Aufklärung der bis dato wenig bekannten optischen und elektronischen Eigenschaften des GaN und der Mischkristalle In GaN zu leisten. Zunächst wird ein optimierter MBE Prozess unter Einsatz einer Plasmaquelle hohen Stickstofflusses vorgestellt, welcher nicht nur die reproduzierbare Epitaxie glatter, einphasiger GaN Nukleationsschichten auf GaAs ermöglicht. Vielmehr können damit auch dicke GaN. Schichten mit glatter Oberflächenmorphologie hergestellt werden, welche die Grundlage komplizierterer eta-(In,Ga,Al)N Strukturen bilden. An einer solchen GaN Schicht mit einer mittleren Rauhigkeit von nur 1.5 nm werden dann temperaturabhängige Reflexions- und Transmissionsmessungen durchgeführt. Zur Auswertung der Daten wird ein numerisches Verfahren entwickelt, welches die Berechnung des kompletten Satzes von optischen Konstanten im Spektralgebiet 2.0 = 0.4 wären grün-gelbe Laserdioden. Zusammenfassung in PostScript / While the earliest report on wurtzite (alpha) GaN dates back to 1932, it was not until 1989 that the first epitaxial layer of metastable zincblende (eta) GaN has been synthesized by molecular beam epitaxy (MBE) on a 3C-SiC substrate. The present work focuses on radio frequency (RF) plasma-assisted MBE growth, microstructure, and optical properties of the eta-(In,Ga,Al)N material system on GaAs(001). Due to their higher crystal symmetry, these cubic nitrides are expected to be intrinsically superior for (opto-) electronic applications than the widely employed wurtzite counterparts. Owing to the difficulties of obtaining single-phase crystals, many important material constants are essentially unknown for the cubic nitrides. The aim of this work is therefore, first, to push the technological limits of synthesizing device-relevant zincblende (In,Ga,Al)N heterostructures and, second, to determine the basic optical and electronic properties of GaN as well as to investigate the hardly explored alloy InGaN. An optimized MBE growth process is presented which allows not only the reproducible nucleation of smooth, monocrystalline GaN layers on GaAs using a high-nitrogen-flow RF plasma source. In particular, thick single-phase GaN layers with smooth surface morphology are obtained being a prerequisite for the synthesis of ternary eta-(Ga,In,Al)N structures. Temperature dependent reflectance and transmittance measurements are carried out on such a GaN film having a RMS surface roughness as little as 1.5 nm. A numerical method is developed which allows to extract from these data the complete set of optical constants for photon energies covering the transparent as well as the strongly absorbing spectral range (2.0 -- 3.8 eV). Inhomogeneities in the refractive index leading to finite coherence effects are quantitatively analyzed by means of Monte Carlo simulations. The fundamental band gap EG(T) of GaN is determined for 5 < T < 300 K and the room temperature density of states is investigated. Systematic studies of the band edge photoluminescence (PL) in terms of transition energies, lineshapes, linewidths, and intensities are carried out for both alpha- and GaN as a function of temperature. Average phonon energies and coupling constants, activation energies for thermal broadening and quenching are determined. Excitation density dependent PL measurements are carried out for both phases in order to study the impact of nonradiative recombination processes at 300 K. A recombination model is applied to estimate the internal quantum efficiency, the (non)radiative lifetimes, as well as the ratio of the electron to hole capture coefficients for both polytypes. It is seen that the dominant nonradiative centers in the n-type material investigated act as hole traps which, however, can be saturated at already modest carrier injection rates. In summary, despite large defect densities in GaN due to highly mismatched heteroepitaxy on GaAs, band edge luminescence is observed up to 500 K with intensities comparable to those of state-of-the-art alpha-GaN. For the first time, thick InGaN films are fabricated on which blue and green luminescence can be observed up to 400 K for x=0.17 and x=0.4, respectively. Apart from bulk-like InGaN films, the first coherently strained InGaN/GaN (multi) quantum wells with In contents as high as 50 % and abrupt interfaces are grown. This achievement shows that a ternary alloy can be synthesized in a metastable crystal structure far beyond the miscibility limit of its binary constituents despite the handicap of highly lattice mismatched heteroepitaxy. The well widths of these structures range between 4 and 7 nm and are thus beyond the theoretically expected critical thickness for the strain values observed. It is to be expected that even higher In contents can be reached for film thicknesses below 5 nm. The potential application of such InGaN/GaN multi quantum wells with x >= 0.4 would thus be diode lasers operating in the green-yellow range. abstract in PostScript
637

Growth and investigation of AlN/GaN and (Al,In)N/GaN based Bragg reflectors

Ive, Tommy 06 January 2006 (has links)
Die Synthese von AlN/GaN- und (Al,In)N/GaN-Braggreflektoren wird untersucht. Die Strukturen wurden mittels plasmaunterstützter Molekularstrahlepitaxie auf 6H-SiC(0001)-Substraten abgeschieden. Ferner wurde der Einfluß der Si-Dotierung auf die Oberflächenmorphologie sowie die strukturellen und elektrischen Eigenschaften der AlN/GaN-Braggreflektoren untersucht. Es wurden rißfreie Braggreflektoren mit einer hohen Reflektivität (R>99%) und einem bei 450 nm zentrierten Stopband erhalten. Die Si-dotierten Strukturen weisen eine ohmsche I-V-Charakteristik im gesamten Meßbereich sowie einen spezifischen Widerstand von 2-4 mOhmcm2 auf. Die Ergebnisse der (Al,In)N-Wachstumsversuche wurden in einem Phasendiagramm zusammengefaßt, welches den optimalen Parameterraum für (Al,In)N klar aufzeigt. / We study the synthesis of AlN/GaN and (Al,In)N/GaN Bragg reflectors. The structures were grown by plasma-assisted molecular beam epitaxy (MBE) on 6H-SiC(0001) substrates. In addition, we study the impact of Si-doping on the surface morphology and the structural and electrical properties of the AlN/GaN Bragg reflectors. Crack-free and high-reflectance (R>99%) Bragg reflectors were achieved with a stopband centered at 450 nm. The Si-doped structures exhibit ohmic I-V behavior in the entire measurement range. The specific series resistance is 2-4 mOhmcm2. The results of the (Al,In)N growth experiments are summarized in a phase diagram which clearly shows the optimum growth window for (Al,In)N.
638

Growth of GaN nanowire ensembles in molecular beam epitaxy: Overcoming the limitations of their spontaneous formation

Zettler, Johannes Kristian 14 March 2018 (has links)
Dichte Ensembles aus GaN-Nanodrähten können in der Molekularstrahlepitaxie mithilfe eines selbstinduzierten Prozesses sowohl auf kristallinen als auch amorphen Substraten gezüchtet werden. Aufgrund der Natur selbstgesteuerter Prozesse ist dabei die Kontrolle über viele wichtige Ensembleparameter jedoch eingeschränkt. Die Arbeit adressiert genau diese Einschränkungen bei der Kristallzucht selbstinduzierter GaN-Nanodrähte. Konkret sind das Limitierungen bezüglich der Nanodraht-Durchmesser, die Nanodraht-Anzahl-/Flächendichte, der Koaleszenzgrad sowie die maximal realisierbare Wachstumstemperatur. Für jede dieser Einschränkungen werden Lösungen präsentiert, um die jeweilige Limitierung zu umgehen oder zu verschieben. Als Resultat wurde eine neue Klasse von GaN Nanodrähten mit bisher unerreichten strukturellen und optischen Eigenschaften geschaffen. Mithilfe eines Zwei-Schritt-Ansatzes, bei dem die Wachstumstemperatur während der Nukleationsphase erhöht wurde, konnte eine verbesserte Kontrolle über die Flächendichte, den Durchmesser und den Koaleszenzgrad der GaN-Nanodraht-Ensembles erreicht werden. Darüber hinaus werden Ansätze präsentiert, um die außerordentlich lange Inkubationszeit bei hohen Wachstumstemperaturen zu minimieren und damit wesentlich höhere Wachstumstemperaturen zu ermöglichen (bis zu 905°C). Die resulierenden GaN-Nanodraht-Ensembles weisen schmale exzitonische Übergänge mit sub-meV Linienbreiten auf, vergleichbar zu denen freistehender GaN-Schichten. Abschließend wurden Nanodrähte mit Durchmessern deutlich unterhalb von 10 nm fabriziert. Mithilfe eines Zersetzungsschrittes im Ultrahochvakuum direkt im Anschluss an die Wachstumsphase wurden reguläre Nanodraht-Ensembles verdünnt. Die resultierenden ultradünnen Nanodrähte weisen dielektrisches Confinement auf. Wir zeigen eine ausgeprägte exzitonische Emission von puren GaN-Nanodrähten mit Durchmessern bis hinab zu 6 nm. / In molecular beam epitaxy, dense arrays of GaN nanowires form spontaneously on crystalline as well as amorphous substrates. Due to the nature of spontaneous formation, the control over important parameters is limited. This thesis addresses the major limitations of spontaneous nanowire formation, namely the nanowire diameter, number density, and coalescence degree but also the maximum achievable growth temperature, and presents approaches to overcome the same. Thereby, we have fabricated a new class of nanowires with unprecedented structural and optical properties. We find that a two-step growth approach, where the substrate temperature is increased during the nucleation stage, is an efficient method to gain control over the area coverage, average diameter, and coalescence degree of GaN nanowire ensembles. Furthermore, we present growth approaches to minimize the long incubation time that precedes nanowire nucleation at elevated temperatures and to thus facilitate significantly higher growth temperatures (up to 905°C). The GaN nanowire ensembles grown at so far unexplored substrate temperatures exhibit excitonic transitions with sub-meV linewidths comparable to those of state-of-the-art free-standing GaN layers grown by hydride vapor phase epitaxy. Finally, we fabricate nanowires with diameters well below 10 nm, the lower boundary given by the nucleation mechanism of spontaneously formed nanowires. Here, regular nanowire arrays are thinned in a post-growth decomposition step in ultra-high vacuum. In situ monitoring the progress of decomposition using quadrupole mass spectrometry enables a precise control over the diameter of the thinned nanowires. These ultrathin nanowires show dielectric confinement, which is potentially much stronger than quantum confinement. We demonstrate intense excitonic emission from bare GaN nanowires with diameters down to 6 nm.
639

Transmission electron microscopy studies of GaN/gamma-LiAlO 2 heterostructures

Liu, Tian-Yu 15 June 2005 (has links)
Die vorliegende Arbeit beschaeftigt sich mit dem strukturellen Aufbau von (1-100) M-plane GaN, das mit plasmaunterstuetzter Molekularstrahlepitaxie auf gamma-LiAlO2(100) Substraten gewachsen wurde. Die heteroepitaktische Ausrichtung einerseits, sowie die Mikrostruktur und die Erzeugungsmechanismen der Defekte andererseits, wurde mit der Transmissionselektronenemikroskopie (TEM) systematisch untersucht. Das gamma-LiAlO2 Substrat reagiert heftig im Mikroskop unter Bestrahlung mit hochenergetischen Elektronen. Waehrend dieser Strahlenschaedigung verliert das Material seine urspruengliche kristalline Struktur und vollzieht eine Phasentransformation, die anhand einer Serie von Feinbereichsbeugungsdiagrammen nachgewiesen werden konnte. Die atomare Grenzflaechenstruktur zwischen epitaktisch gewachsenem alpha-GaN(1-100) und tetragonalem gamma-LiAlO2 Substrat ist mittels HRTEM untersucht worden. Die neuartige Epitaxiebeziehung ist mit Elektronenbeugung bestaetigt worden und lautet folgendermassen: (1-100)GaN liegt parallel zu (100)gamma-LiAlO2 und [11-20]GaN ist parallel zu [001]gamma-LiAlO2. Die Realstruktur der M-plane GaN Schichten, die auf (100)gamma-LiAlO2 gewachsen werden, unterscheidet sich erheblich von der in C-plane Orientierung hergestellten Epischichten. Ausfuehrliche TEM Untersuchungen zeigen, dass die M-plane Schichten vor allem intrinsische (I1 und I2) und extrinsische (E) Stapelfehler in der Basalebene enthalten. Der vorherrschende I2 Stapelfehler besitzt keine Komponente des Verschiebungsvektors senkrecht zur Ebene und ist damit nicht geeignet, epitaktische Dehnung entlang der [11-20] Richtung abzubauen. Darueberhinaus ist eine komplexe Grenze in der (10-10) Prismen- flaeche entdeckt worden, die zur Grenzflaeche geneigt verlaeuft. Die Defekte in den M-plane GaN Epischichten werden waehrend der anfaenglichen Keimbildungsphase erzeugt. Atomare Stufen entlang der [001] Richtung auf dem LiAlO2 Substrat fuehren zur Bildung von Stapelfehlern vom Typ I2. / In this work the structure of (1-100)M-plane GaN epitaxially grown on gamma-LiAlO2(100) by using plasmaassisted molecular beam epitaxy (PAMBE) is studied. The heteroepitaxial alignment and the microstructure of M-plane GaN as well as the defect formation in the layer are systematically investigated by using transmission electron microscopy (TEM). The gamma-LiALO2 substrate reacts under irradiation of high-energy electrons in the TEM (200-300 keV).The material looses its original crystalline structure during this process undergoing irradiation damage followed by a phase transformation as it is verified by a series of selected area diffraction patterns taken under constant electron dose. The result is a structural phase transformation from the tetragonal gamma to the trigonal alpha phase. The atomic interface structure of epitaxially grown hexagonal alpha-GaN(1-100) layers on tetragonal gamma-LiAlO2 (100) substrates is investigated by means of HRTEM. The novel epitaxial orientation relationship verified by electron diffraction is given by (1-100)GaN parallel to (100)gamma-LiAlO2 and [11-20]GaN parallel to [001]gamma-LiAlO2. The defect structure of M-plane GaN epilayers grown on gamma-LiAlO2(100) substrates is different to that of C-plane GaN. Our detailed TEM studies reveal that the M-plane layers mainly contain intrinsic I1 and I2 and extrinsic E basal plane stacking faults. The dominant I2 stacking fault has no out-of-plane displacement vector component and is thus not qualified for epitaxial strain relief along the [11-20] axis. Beyond this, a complex type of planar defect is detected in the (10-10) prism plane which is inclined with respect to the interface. The study of nucleation samples shows that the surface morphology is directly correlated to the generation of the dominant planar defects. Atomic steps along the [001] direction in the gamma-LiAlO2 substrate result in the formation of basal plane stacking faults I2.
640

Control of the emission wavelength of gallium nitride-based nanowire light-emitting diodes

Wölz, Martin 12 June 2013 (has links)
Halbleiter-Nanosäulen (auch -Nanodrähte) werden als Baustein für Leuchtdioden (LEDs) untersucht. Herkömmliche LEDs aus Galliumnitrid (GaN) bestehen aus mehreren Kristallschichten auf einkristallinen Substraten. Ihr Leistungsvermögen wird durch Gitterfehlpassung und dadurch hervorgerufene Verspannung, piezoelektrische Felder und Kristallfehler beschränkt. GaN-Nanosäulen können ohne Kristallfehler auf Fremdsubstraten gezüchtet werden. Verspannung wird in Nanosäulen elastisch an der Oberfläche abgebaut, dadurch werden Kristallfehler und piezoelektrische Felder reduziert. In dieser Arbeit wurden GaN-Nanosäulen durch Molukularstrahlepitaxie katalysatorfrei gezüchtet. Eine Machbarkeitsstudie über das Kristallwachstum von Halbleiter-Nanosäulen auf Metall zeigt, dass GaN-Nanosäulen in hoher Kristallqualität ohne einkristallines Substrat epitaktisch auf Titanschichten gezüchtet werden können. Für das Wachstum axialer (In,Ga)N/GaN Heterostrukturen in Nanosäulen wurden quantitative Modelle entwickelt. Die erfolgreiche Herstellung von Nanosäulen-LEDs auf Silizium-Wafern zeigt, dass dadurch eine Kontrolle der Emissionswellenlänge erreicht wird. Die Gitterverspannung der Heterostrukturen in Nanosäulen ist ungleichmäßig aufgrund des Spannungsabbaus an den Seitenwänden. Das katalysatorfreie Zuchtverfahren führt zu weiteren statistischen Schwankungen der Nanosäulendurchmesser und der Abschnittlängen. Die entstandene Zusammensetzung und Verspannung des (In,Ga)N-Mischkristalls wird durch Röntgenbeugung und resonant angeregte Ramanspektroskopie ermittelt. Infolge der Ungleichmäßigkeiten erfordert die Auswertung genaue Simulationsrechnungen. Eine einfache Näherung der mittleren Verspannung einzelner Abschnitte kann aus den genauen Rechnungen abgeleitet werden. Gezielte Verspannungseinstellung erfolgt durch die Wahl der Abschnittlängen. Die Wirksamkeit dieses allgemeingültigen Verfahrens wird durch die Bestimmung der Verspannung von (In,Ga)N-Abschnitten in GaN-Nanosäulen gezeigt. / Semiconductor nanowires are investigated as a building block for light-emitting diodes (LEDs). Conventional gallium nitride (GaN) LEDs contain several crystal films grown on single crystal substrates, and their performance is limited by strain-induced piezoelectric fields and defects arising from lattice mismatch. GaN nanowires can be obtained free of defects on foreign substrates. In nanowire heterostructures, the strain arising from lattice mismatch can relax elastically at the free surface. Crystal defects and piezoelectric fields can thus be reduced. In this thesis, GaN nanowires are synthesized in the self-induced way by molecular beam epitaxy. A proof-of-concept study for the growth of semiconductor nanowires on metal shows that GaN nanowires grow epitaxially on titanium films. GaN of high crystal quality is obtained without a single crystal substrate. Quantitative models for the growth of axial (In,Ga)N/GaN nanowire heterostructures are developed. The successful fabrication of nanowire LED devices on silicon wafers proves that these models provide control over the emission wavelength. In the (In,Ga)N/GaN nanowire heterostructures, strain is non-uniform due to elastic relaxation at the sidewalls. Additionally, the self-induced growth leads to statistical fluctuations in the diameter and length of the GaN nanowires, and in the thickness of the axial (In,Ga)N segments. The (In,Ga)N crystal composition and lattice strain are analyzed by x-ray diffraction and resonant Raman spectroscopy. Due to the non-uniformity in strain, detailed numerical simulations are required to interpret these measurements. A simple approximation for the average strain in the nanowire segments is derived from the detailed numerical calculation. Strain engineering is possible by defining the nanowire segment lengths. Simulations of resonant Raman spectra deliver the experimental strain of (In,Ga)N segments in GaN nanowires, and give a proof of this universal concept.

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