Indiana University-Purdue University Indianapolis (IUPUI) / Consistent under-reporting of autism cases by Indiana physicians to the Indiana Birth Defects and Problems Registry (IBDPR) has made quality autism-related data very difficult to obtain (Indiana Birth Defects and Problems Registry [IBDPR], 2011). As a result, the Indiana State Department of Health (ISDH) currently also utilizes data from billing information that it receives from hospital discharges. However, such cases must be investigated further because autism is often merely suspected as a possibility in the discharge data. A chart auditor must therefore review the child’s chart to determine if the condition is confirmed. Meanwhile, the Indiana Department of Education (IDOE) has a different diagnostic procedure from physicians for determining whether a student has an Autism Spectrum Disorder (ASD), which qualifies him or her for special education. A physician diagnosis of autism does not guarantee that a child will receive special education from public schools. With all of these current complications surrounding autism, announced changes in the definition of autism by the American Psychiatric Association (APA) will likely have effects on both the special education field and the public health field. There is a possibility that children who had previously received special education could cease to maintain their eligibility and may find it difficult to obtain benefits. The IDOE may find it necessary to reevaluate their criteria for determining special education eligibility. Additionally, public health officials may see the definition changes affect the number of autism cases they perceive their populations to have, thus impacting community and policy decisions. This study was performed as an attempt to investigate and compare the sources used by the IBDPR to obtain autism data, and determine whether or not the resulting data creates an accurate depiction of the autistic population of Indiana. It was also performed to speculate whether a stricter definition of autism will result in a higher quality of data for the IBDPR and a more consistent view on the disorder between the ISDH and the IDOE. Perhaps from such consistency and simpler definitions, future recorded data will more closely resemble that of reality, enabling the ISDH to utilize the IBDPR to its full extent. Using current definitions for an exploratory analysis of data from the past five years, a discrepancy clearly exists between the IBDPR and the reality of the population of Indiana.

The productivity advances generated from lean manufacturing are self-evident. Plants that adopt lean are more capable of achieving high levels of quality, shorter lead times, and less waste in the system. While it seems logical that higher levels of productivity and quality, as is common in lean companies, should result in positive financial performance, the research community has failed to establish the financial profitability of lean. Those researchers who have studied the financial returns issue report varying results. The goal of this research was to determine if a connection exists between lean and financial success and to discover why so many researchers are finding mixed results. Information Velocity (IV) was theorized to provide the solidifying link between lean and financial performance. Measured by combining the environmental volatility with a company's leanness, IV measures how fast a company can transmit information from the market into a customer-satisfying product in the hands of the consumer. This study analyzed over 530 publicly-traded manufacturing companies to validate the following hypotheses: 1) there is a positive relationship between leanness and financial returns, 2) there is a negative relationship between environmental volatility and financial returns, and 3) there is a positive relationship between IV and financial returns. Regression models were run in various combinations to determine the effect of lean, environmental instability, environmental unpredictability, and IV on financial performance indicators such as return on sales (ROS), return on assets (ROA), and quarter-closing stock price. The outcome of this study showed that financial rewards do result from lean, which positively affected financial performance in almost all scenarios. Environmental instability always negatively correlated with financial returns, and IV mostly shows a positive effect, but with mixed results. Lastly, IV does not explain why researchers find mixed results on the profitability measures of lean. The results of this thesis highlight the significance of implementing lean manufacturing, especially in a dynamic environment. As the instability in the environment increases, profitability decreases. Therefore, an increase in leanness by boosting inventory turns can compensate for the volatility and create enhanced productivity measures and financial results.

<p dir="ltr">Seafood plays a pivotal role in global economies, livelihoods, and nutritional security. However, climate change and global pandemics pose significant threats to seafood harvests, production, supply chains, and marketing channels. The focus of my thesis is to understand the impact of external factors on our seafood resources and explore adaptive strategies in the face of uncertainties. We utilize economics techniques to study human-nature systems by zooming into social elements (government agencies, industry stakeholders, and fish farmers/fishermen) and aquatic resources. The three essays of my thesis delve into this inquiry from the perspectives of government, industry, and market, accordingly.</p><p dir="ltr">The first chapter in my thesis, <i>Climate Change and Snow Crab Harvest - Applying Random Effect Estimators with Instrumental Variable</i>, estimates the snow crab harvest function with unbalanced panel data of eastern Bering Sea snow crab, Canadian snow crab, Japanese snow crab, and Barents Sea snow crab. Specifically, we analyze the relationship between snow crab biomass, stock, and catch. To address the endogeneity of stock in the harvest function, climate change indicators are selected as instrumental variables. We identify that the Arctic Sea ice extent is effective in addressing the endogeneity and the random effects instrumental variable model with error components two stage least squares estimator performs the best to control heterogeneity. We find that a 1% increase in snow crab fishing effort is associated with a 0.42% increase in snow crab harvest, and a 1% increase in snow crab stock causes a 0.98% increase in snow crab harvest. The reported estimates indicate a large stock-harvest elasticity and provide supporting evidence for government fishery agencies to prioritize stock enhancement in policy designs.</p><p dir="ltr">The second chapter, <i>Online Media Sentiment Analysis of Shrimp and Salmon in the United States</i>, employs online media analytics on shrimp and salmon in the US to provide insights into consumer perceptions and potential demand signals for seafood. Search hits and mentions are quantified for top sources, domains, and prevalent terms. In addition, sentiment drivers and sentiment values are identified and calculated using natural language processing tools. The results reveal that the occurrence of peak mentions does not necessarily coincide with the peak of net sentiment, and farmed seafood consistently exhibits lower net sentiments compared to their wild counterparts. Autoregressive modeling is conducted to predict the dynamics of seafood’s net sentiments. The regional analysis demonstrates that public attitudes toward both farmed shrimp and salmon in the East North Central region exhibit a more positive net sentiment, while the New England and Middle Atlantic regions tend to have a lower net sentiment for farmed shrimp and salmon, respectively. The fitted forecast model serves as a supplementary tool for industry stakeholders to quickly respond to future public perceptions. Regional statistics also help the seafood industry tailor business strategies to different regions.</p><p dir="ltr">In the third chapter, <i>Comparative Case Study of Small-Scale Fish Processing for Local Seafood Supply</i><i>,</i> we examine the feasibility of utilizing a shared-use commercial kitchen and on-farm kitchen to support small-scale local fish processing, which helps diversify marketing channels in the US Midwest and supply seafood to local food systems. A case study of each facility type is assessed for economic viability for fish farmers. The financial analysis suggests farmers interested in processing tilapia or rainbow trout from 2,500 lbs to 5,000 lbs per year utilize rental commercial kitchens. A minimum of 15% markup and processing of 10,000 lbs/year tilapia is required to make the on-farm kitchen option more viable. For farmers who process rainbow trout, 10,000 lbs/year with a 10% markup using an on-farm kitchen is a better choice. Factoring in the stochastic variability of raw product prices, rental rates, and set-up costs, we provide simulated ranges for economic metrics including profitability index, payback period, and net present values. The reports of estimated costs, revenues, and breakeven prices, provide fish farmers with suggested selling prices, kitchen choices, and production levels to achieve optimum profits under risks.</p>

Dans l'écriture de l'histoire immédiate, la pression et l'expérience de l'actualité, les valeurs, les sentiments et les intérêts personnels d'un historien peuvent le conduire à transformer le passé. L'exemple de l'historien des guerres de Religion françaises Pierre Matthieu montre comment la gestion des vérités passées s'avère délicate lorsque les historiens doivent faire des «choix éditoriaux». L'étude de la représentation qu'il fait des chefs ligueurs, de la Ligue et d'Henri IV dans son Histoire des derniers troubles de France (1594-1606) permet de comprendre le poids du présent sur l'écriture de l'histoire récente et la perception arrangée et significative qui s'en dégage pour le présent. Ce mémoire s'intéresse aux fonctions auxquelles répond cette représentation dans le processus de réconciliation nationale lancé par le premier Bourbon. Il donne un indice de la difficulté séculaire d'être acteur et rédacteur de l'histoire et permet de se demander si le présent est «historicisable».

[EN] The aim of this Thesis is to analyse furniture as a constituent part of the modern architectural project for "manufacturing the interior". The domestic space is analysed as a concrete study case, in an itinerary through several works from some authors that are essential to understand the evolution of the contemporary architecture. Although these pieces of furniture are autonomous objects with a defined formal structure, they form a consistent whole with the space where they are placed, because they have been generated from the same laws and with the same creative premises. This Thesis is formed by four parts: The first part studies the relation between the architecture and the furniture designed by a selection of architects from the historical avant-gardes of the 20th century. During this period, the bases of the contemporary furniture design were set. The avant-garde architecture discovers the need for a furniture in accordance with the new principles and available to all social classes. The economic and cultural context was not ready for the mass production of furniture, so these objectives couldn't be accomplished. The different positions taken regarding the relation between architecture and furniture are the antecedents for the rest of the study. In the second part, after World War II, the furniture designed by architects was finally mass-produced, due to the technical improvements and the new materials and, especially, with a new attitude of collaboration between architects and industry that made great achievements. The third part studies the contemporary relation between architecture and furniture from a multiple point of view. On one hand, industry has spread the contemporary design globally, taking it to wider sectors of the population, finally achieving the dream of the avant-gardes. On the other hand, architects go in depth into the relation between architecture and furniture, experimenting new forms according to new ways of dwelling. Part of the contemporary architecture voluntarily chooses to restrain the shapes and materials in order to allow the users a full sensorial approach to architecture and furniture. The forth part of the study describes the relation between architecture and furniture from the experience and the daily practice of the author's professional work. The author designs furniture from an architectural basis and is convinced that it needs to be developed in consistency with the surrounding space so architecture may display all its sensorial potential. Thus, this study wants to stress the importance of the relation between furniture and architecture, being furniture a linking element between the place and its inhabitant that enhances the experience of dwelling. / [ES] El propósito de este trabajo de investigación es analizar el mobiliario como parte constituyente del proyecto arquitectónico moderno en la ¿fabricación del interior¿ tomando como caso concreto de estudio el espacio doméstico, a través de un recorrido por diversas obras de autores imprescindibles para entender el devenir de la arquitectura contemporánea. Aunque esos muebles existan como objetos autónomos con una estructura formal definida, forman un conjunto coherente con el espacio en que se sitúan ya que se han generado desde las mismas leyes y con las mismas premisas proyectuales. La tesis está estructurada en cuatro partes: la primera parte de este trabajo estudia la relación entre la arquitectura y el mobiliario diseñado por una selección de arquitectos correspondientes a las vanguardias históricas del siglo XX. Es durante este periodo cuando se asientan las bases de lo que va a ser el diseño del mobiliario contemporáneo. Por un lado, la arquitectura de vanguardia detecta la necesidad de crear un mobiliario acorde con los nuevos principios y a su vez poder llegar a todas las clases sociales. Idea que, sin embargo, no llega a desarrollarse en toda su intensidad al no ser producido en serie ya que el contexto económico y cultural no están aún preparados. Las diferentes posiciones adoptadas respecto a la relación entre la arquitectura y el mobiliario en este primer capítulo servirán como antecedentes para el resto del trabajo. En la segunda parte, tras la Segunda Guerra Mundial, los muebles diseñados por arquitectos llegan a la producción en serie aprovechando los avances técnicos de la industria y los nuevos materiales y, sobre todo, con una nueva actitud y relación de colaboración entre ambos, produciendo grandes resultados. La tercera parte estudia la relación entre mobiliario y arquitectura en la actualidad desde una perspectiva múltiple. Por un lado, la industria ha globalizado el diseño contemporáneo y lo ha llevado a capas más amplias de la población, cumpliendo finalmente el sueño de las vanguardias. Por otro lado, los arquitectos continúan profundizando en la relación entre arquitectura y mobiliario experimentando nuevas formas acordes con nuevos modos de habitar. Una parte de la arquitectura actual opta voluntariamente por reducir las formas y los materiales utilizados para permitir una aproximación sensorial plena a la arquitectura y el mobiliario por parte de sus usuarios. La cuarta parte de este trabajo describe la relación entre arquitectura y mobiliario desde la experiencia y la práctica cotidiana del trabajo profesional del autor. Partiendo de la arquitectura, el autor aborda el diseño de mobiliario desde la convicción de que son necesarios unos muebles desarrollados coherentemente con el espacio que los acoge para que la arquitectura despliegue todo su potencial sensorial. Así pues, este estudio busca dejar patente la relación entre el mobiliario y la arquitectura de forma que éste actúa como elemento de enlace entre un lugar y la persona que lo vive amplificando la percepción de la experiencia de habitar. / [CA] L'objectiu d'aquest treball d'investigació és analitzar el mobiliari com a part constituent del projecte arquitectònic modern en la "fabricació de l'interior", prenent com a cas concret d'estudi l'espai domèstic a través d'un recorregut per distintes obres d'autors imprescindibles per entendre l'esdevenir de l'arquitectura contemporània. Encara que aquests mobles existeixin com objectes autònoms amb una estructura formal definida, formen un conjunt coherent amb l'espai en què es situen perquè s'han generat des de les mateixes lleis i amb les mateixes premisses de projecte. La tesi està estructurada en quatre parts: la primera part del treball estudia la relació entre l'arquitectura i el mobiliari dissenyat per una selecció d'arquitectes corresponents a les avantguardes històriques del segle XX. Al llarg d'aquest període es fixen les bases del que serà el disseny del mobiliari contemporani. Per un costat, l'arquitectura d'avantguarda detecta la necessitat de crear un mobiliari que estiga d'acord amb els nous principis i, al mateix temps, que puga arribar a totes les classes socials. Tanmateix, aquesta idea no arriba a desenvolupar-se amb tota la seu intensitat al no ser produïts en sèrie, donat que els contexts econòmic i cultural no estan encara preparats. Les diferents posicions adoptades respecte a la relació entre l'arquitectura i el mobiliari en aquest primer capítol serviran com antecedents per a la resta del treball. En la segona part, després de la Segona Guerra Mundial, els mobles dissenyats per arquitectes assoleixen la producció en sèrie tot aprofitant les millores tècniques de la indústria i els nous materials i, en primer lloc, amb una nova actitud i relació de col·laboració entre tots dos que produeix grans resultats. La tercera part estudia la relació entre l'arquitectura i el mobiliari en l'actualitat des d'una perspectiva múltiple. D'una banda, la indústria ha globalitzat el disseny contemporani i l'ha portat a estrats més amplis de la població, tot acomplint el somni de les avantguardes. D'una altra banda, els arquitectes continuen aprofundint en al relació entre arquitectura i mobiliari, experimentant noves formes d'acord amb nous modes d'habitar. Una part de l'arquitectura actual opta voluntàriament per reduir les formes i els materials utilitzats per a permetre una aproximació sensorial plena a l'arquitectura i el mobiliari per part dels seus usuaris. La quarta part d'aquest treball descriu la relació entre arquitectura i mobiliari des d'experiència i la pràctica quotidiana del treball professional de l'autor. A partir de l'arquitectura, l'autor aborda el disseny de mobiliari des de la convicció de què són necessaris uns mobles dissenyats de forma coherent amb l'espai que els acull per tal què l'arquitectura desplegue tot el seu potencial sensorial. Així doncs, aquest estudi vol fer palesa la relació entre el mobiliari i l'arquitectura de manera que el primer actua com a element d'enllaç entre un lloc i la persona que hi viu, tot amplificant l'experiència d'habitar. / Esteve Cambra, JR. (2016). La fabricación del interior. Arquitectura y mobiliario en la contemporaneidad [Tesis doctoral no publicada]. Universitat Politècnica de València. https://doi.org/10.4995/Thesis/10251/61779

No description available.

L’empire de Constantinople, après un siècle (969-1085) de domination sur de vastes portions de l’Orient (Cilicie, Chypre, Syrie du Nord et Djézireh), et de rayonnement au-delà jusqu’à Jérusalem, dut reconstituer sa présence dans cet espace à partir de la fin du XIe siècle. L’arrivée de nouveaux acteurs chrétiens autonomes, Francs et Arméniens, compliqua l’équation politique de l’Empire, qui ne devait plus uniquement reconstruire sa domination sur ses anciens sujets, mais aussi compter avec ces forces. L’empire de Romanie vécut en Orient, parallèlement aux Croisades, une intense phase de redéfinition de sa réalité régionale, de ses modalités de fonctionnement et de son rôle politique. Cependant, cette expérience, qui se prolongea sur près de deux siècles, ne saurait se limiter à une simple projection de puissance de Constantinople sur cette périphérie. Malgré les bouleversements qui frappèrent le cœur de l’Empire de 1081 à 1289, la référence impériale se maintint en Orient sous les Comnènes, les empereurs latins et nicéens, puis sous les premiers Paléologues. Le processus ne fut durable que grâce à la redéfinition progressive de l’identité impériale locale. Ses contours varièrent par l’adjonction d’éléments hétérogènes, contribuant à complexifier l’empreinte de l’empire de Romanie en Orient. La Romanie orientale fut une solution à l’équation politique des pouvoirs locaux (la principauté d’Antioche, le comté de Tripoli et les royaumes de Chypre et d’Arménie principalement) pour réussir leur intégration régionale en la conjuguant avec un héritage impérial constantinopolitain, incluant l’Orient helléno-arabe. / The empire of Constantinople, after a century (969-1085) of domination over large part of oriental territories (Cilicia, Cyprus, North Syria and Djezireh) during which it exerted its influence over Jerusalem, had to restore its influence in this space from the end of the eleventh century. The arrival of new autonomous Christian players, Francs and Armenians, complicated the empire’s political equation, which had not just to rebuild his domination over its old subjects, but also had to allow for these forces.The empire of Romanie lived in the East, at the same time of the Crusades, an intense period of redefinition of its regional reality, of its modes of running and of its political role. However, this experience, which lasted for two centuries, can’t be confined to a simple projection of Constantinople’s powerful onto this periphery.Despite the disruptions which hit the heart of the empire, from 1081 to 1289, the imperial reference persisted in the East under the Comneni, the Latin and Nicene emperors, and under the firsts Paleologues.The process was lasting because of the gradual redefinition of regional imperial identity. Its contours were varied by the addition of heterogenic elements, which contributed to complicate the imperial mark in the East.Oriental Romania was a solution to the political equation of local authorities (Principality of Antioch, the County of Tripoli and the kingdoms of Cyprus and Armenia mainly) to succeed in their regional integration, combined with an imperial Constantinopolitan heir, including the Hellenic and Arabic East.

<p>Cilj&nbsp; ove&nbsp; doktorske&nbsp; disertacije&nbsp; je&nbsp; bio&nbsp; razvoj&nbsp; brzih&nbsp; i&nbsp; pouzdanih&nbsp; voltametrijskih&nbsp; metoda zasnovanih na primeni jednostavnih i savremenih elektroda/senzora na bazi ugljeničnih materijala (ugljenične&nbsp; paste&nbsp; napravljene&nbsp; od&nbsp; grafitnog&nbsp; praha&nbsp; i&nbsp; parafinskog&nbsp; ulja&nbsp; i&nbsp; &scaron;tampanih&nbsp; ugljeničnih elektroda)&nbsp; za&nbsp; određivanje&nbsp; H ₂O₂u&nbsp; odabranim&nbsp; složenim&nbsp; model&nbsp; i&nbsp; realnim&nbsp; uzorcima.&nbsp; U&nbsp; tu&nbsp; svrhu, ispitana je primenljivost različitih radnih elektroda. Amperometrijska&nbsp; metoda&nbsp; zasnovana&nbsp; na&nbsp; elektrodi&nbsp; od&nbsp; ugljenične&nbsp; paste&nbsp; (CPE)&nbsp; zapreminski modifikovane&nbsp; sa&nbsp; 5%&nbsp; (m:m)&nbsp; MnO2 je,&nbsp; pri&nbsp; optimizovanim&nbsp; uslovima&nbsp; i&nbsp; pri&nbsp; radnom&nbsp; potencijalu&nbsp; od 0,40 V&nbsp; u&nbsp; odnosu&nbsp; na&nbsp; zasićenu&nbsp; kalomelovu&nbsp; elektrodu&nbsp; (ZKE)&nbsp; u&nbsp; fosfatnom&nbsp; puferu&nbsp; pH&nbsp; 7,50&nbsp; kao pomoćnom elektrolitu, omogućila kvantifikaciju H ₂O₂ u opsegu koncentracija od 1,4 do 65 &micro;g mL -1 sa&nbsp; relativnom&nbsp; standardnom&nbsp; devijacijom&nbsp; (RSD)&nbsp; manjom&nbsp; od&nbsp; 10%.&nbsp; Ova&nbsp; metoda&nbsp; je&nbsp; primenjena&nbsp; za određivanje sadržaja H ₂O₂u uzorcima podzemne vode iz centralnog Banata (Pokrajina Vojvodina, Srbija)&nbsp; tretirane&nbsp; Fentonovim&nbsp; (Fe²⁺ i&nbsp; H ₂O₂ )&nbsp; i&nbsp; Fentonu-sličnim&nbsp; (Fe ³⁺ i&nbsp; H ₂O₂ )&nbsp; reagensima&nbsp; u&nbsp; cilju uklanjanja&nbsp; prirodnih&nbsp; organskih&nbsp; materija&nbsp; (POM)&nbsp; pri&nbsp; čemu&nbsp; su&nbsp; kori&scaron;ćene&nbsp; različite&nbsp; početne koncentracije&nbsp; gvožđa&nbsp; i&nbsp; različiti&nbsp; odnosi&nbsp; molarnih&nbsp; koncentracija&nbsp; gvožđa&nbsp; i&nbsp; H ₂O₂ .&nbsp; Utvrđeno&nbsp; je&nbsp; da oksidaciono&nbsp; stanje&nbsp; gvožđe&nbsp; (Fe²⁺ ili&nbsp; Fe ³⁺)&nbsp; i&nbsp; molarni&nbsp; odnos&nbsp; jona&nbsp; Fe&nbsp; i&nbsp; H₂O₂ utiču&nbsp; na&nbsp; stepen potro&scaron;nje/razgradnje&nbsp; H₂O₂<br />u&nbsp; podzemnoj&nbsp; vodi&nbsp; sa&nbsp; visokim&nbsp; sadržajem&nbsp; POM.&nbsp; Takođe,&nbsp; u&nbsp; slučaju Fentonu-sličnog&nbsp; procesa,&nbsp; za&nbsp; sve&nbsp; početne&nbsp; koncentracije&nbsp; Fe ³⁺ i&nbsp; H ₂O_{2 ,}&nbsp; signifikantna&nbsp; količina&nbsp; H ₂O₂ostaje&nbsp; neiskori&scaron;ćena,&nbsp; &scaron;to&nbsp; ukazuje&nbsp; na&nbsp; nižu&nbsp; efikasnost&nbsp; ovakvog&nbsp; sistema u&nbsp; poređenju&nbsp; sa&nbsp; Fentonovim procesom.&Scaron;tampana&nbsp; ugljenična&nbsp; elektroda&nbsp; (SPCE)&nbsp; zapreminski&nbsp; modifikovana&nbsp; sa&nbsp; MnO 2 kao medijatorom&nbsp; je&nbsp; primenjena&nbsp; za&nbsp; određivanje&nbsp; sadržaja&nbsp; H₂O₂ u&nbsp; toku&nbsp; Fentonovog&nbsp; (Fe ²⁺ ,&nbsp; H₂O₂ )&nbsp; i vidljivom&nbsp; svetlo&scaron;ću&nbsp; potpomognutog&nbsp; foto-Fentonovog&nbsp; (Fe²⁺,&nbsp; H ₂O₂,&nbsp; h&nu;)&nbsp; procesa&nbsp; uklanjanja neonikotinoidnog&nbsp; insekticida&nbsp; acetamiprida&nbsp; (ACT).&nbsp; Pri&nbsp; optimizovanim&nbsp; uslovima&nbsp; (radni&nbsp; potencijal 0,40&nbsp; V&nbsp; u&nbsp; odnosu&nbsp; na&nbsp; ZKE,&nbsp; fosfatni&nbsp; pufer&nbsp; pH&nbsp; 7,50&nbsp; kao&nbsp; pomoćni&nbsp; elektrolit)&nbsp; amperometrijskog određivanja&nbsp; H ₂O₂ ,&nbsp; postignuta&nbsp; je&nbsp; linearnost&nbsp; u&nbsp; opsegu&nbsp; koncentracija&nbsp; 0,01&ndash;1,24&nbsp; mmol&nbsp; L-1(0,34&ndash; 42,2 &micro;g mL -1<br />) i vrednost RSD nije prelazila 4,2%. U ispitivanimuzorcima (nakon odgovarajućeg<br />pode&scaron;avanja pH vrednosti od 2,8 do 7,5 odmah nakon&nbsp; uzorkovanja radi stopiranja ili maksimalnog usporavanja&nbsp; procesa&nbsp; oksidacije,&nbsp; filtriranja,&nbsp; zamrzavanja&nbsp; i&nbsp; odmrzavanja&nbsp; neposredno&nbsp; pre&nbsp; merenja) sadržaj&nbsp; H ₂O₂ je&nbsp; određen&nbsp; metodom&nbsp; standardnog&nbsp; dodatka&nbsp; analiziranjem&nbsp; odgovarajućih amperometrijskih&nbsp; krivi.&nbsp; Paralelna&nbsp; HPLC-DAD&nbsp; merenja&nbsp; su&nbsp; vr&scaron;ena&nbsp; u&nbsp; cilju&nbsp; praćenja koncentracije/uklanjanja ACT. U slučaju foto-Fentonovog procesa (početne koncentracije 0,31; 2,0 i 3,0 mmol L -1 (70,0; 111,7 i 102,1 &micro;g mL -1 ) za ACT, Fe<br />²⁺ i H ₂O₂, redom) nakon 10 min H ₂O₂je izreagovao, a može se smatrati da je ACT uklonjen nakon 5 min. U toku Fentonovog procesa ACT je&nbsp; uklonjen&nbsp; nakon&nbsp; 20&nbsp; min&nbsp; tretmana&nbsp; i&nbsp; oko&nbsp; 10%&nbsp; početne&nbsp; koncentracije&nbsp; H ₂O₂ je&nbsp; ostalo&nbsp; u&nbsp; sistemu<br />neiskori&scaron;ćeno.CPE&nbsp; je&nbsp; povr&scaron;inski&nbsp; modifikovane&nbsp; kompozitom&nbsp; na&nbsp; bazi&nbsp; nanočestica&nbsp; Pt&nbsp; (&lt;&nbsp; 5&nbsp; nm)&nbsp; i grafitizovanog&nbsp; ugljenika&nbsp; (Pt-C,&nbsp; 10%&nbsp; Pt&nbsp; na&nbsp; Vulkanu&nbsp; XC72)&nbsp;&nbsp; etodom&nbsp; nano&scaron;enja&nbsp; kapi. Nemodifikovana&nbsp; CPE&nbsp; i&nbsp; modifikovana&nbsp; (Pt-C/CPE)&nbsp; su&nbsp;&nbsp; okarakterisane&nbsp; primenom&nbsp; SEM/EDS&nbsp; i&nbsp; CV merenja.&nbsp; Pt-C/CPE&nbsp; je&nbsp; pokazala&nbsp; izuzetne&nbsp; elektrokatalitičke&nbsp; osobine&nbsp; u&nbsp; pogledu&nbsp; elektrohemijskeredoks&nbsp; reakcije&nbsp; H<br />₂O₂ u&nbsp; poređenju&nbsp; sa&nbsp; nemodifikovanom&nbsp; CPE&nbsp; u&nbsp; fosfatnom&nbsp; puferu&nbsp; (0,1 mol&nbsp; L -1 ;<br />pH 7,50),&nbsp; a&nbsp; takođe&nbsp; i&nbsp; u&nbsp; acetatnom&nbsp; puferu&nbsp; (0,1&nbsp; mol&nbsp; L -1 ;&nbsp; pH&nbsp; 4,50)&nbsp; kao&nbsp;&nbsp; pomoćnim&nbsp; elektrolitima. Prilikom&nbsp; amperometrijskog&nbsp; određivanja&nbsp; H ₂O₂ primenom&nbsp; Pt-C/CPE&nbsp; u&nbsp; model&nbsp; sistemima, zadovoljavajuća linearnost je postignuta u koncentracionom opseguH₂O₂od 0,15 do 1,45 &micro;g mL -1 ,dok su vrednosti GO iznosile 0,06 &micro;g mL -1 (pH 7,50, radni potencijal 0,20 V) i 0,10 &micro;g mL -1 (pH<br />4,50,&nbsp; radni&nbsp; potencijal&nbsp; 0,50&nbsp; V).&nbsp; Optimizovane&nbsp; analitičke&nbsp; metode&nbsp; su&nbsp; primenjene&nbsp; za&nbsp; određivanje sadržaja H ₂O₂ u komercijalno dostupnim proizvodima za ličnu negu: rastvoru za dezinfekciju (pH 7,50)&nbsp; i&nbsp; rastvoru&nbsp; za&nbsp; či&scaron;ćenje&nbsp; kontaktnih&nbsp; sočiva&nbsp; (pH&nbsp; 4,50).&nbsp; Amperometrijski&nbsp; dobijeni&nbsp; rezultati&nbsp; su&nbsp; u dobrom&nbsp; slaganju&nbsp; sa&nbsp; rezultatima&nbsp; dobijenim&nbsp; primenom&nbsp; tradicionalne&nbsp; spektrofotometrijske&nbsp; metode bazirane&nbsp; na&nbsp; titanijum-sulfatu&nbsp; kao&nbsp; reagensu&nbsp; sa&nbsp; određenim&nbsp; koncentracijama&nbsp; 2,91%&nbsp; i&nbsp; 2,94%&nbsp; za<br />dezinfekcioni rastvor i 3,04% i 3,17% za rastvor zakontaktna sočiva, redom. RSD je bila manja od 2%.&nbsp; Postignuti&nbsp; rezultati&nbsp; su&nbsp; u&nbsp; dobrom&nbsp; slaganju&nbsp; sa&nbsp; sadržajem&nbsp; H<br />₂O₂deklarisanim&nbsp; od&nbsp; strane proizvođača (3%) u oba ispitivana uzorka. Pt-C/CPE je takođe testirana za praćenje koncentracije H₂O₂ u rastvoru za kontaktna sočiva u toku procesa njegove neutralizacije/razgradnje. Nakon 6 h procesa neutralizacije, 24,68&nbsp; &micro;g mL -1 je bila određena koncentracija H ₂O_{2 ,} &scaron;to je ispod dozvoljene<br />H₂O₂koncentracije u rastvoru za kontaktna sočiva imajući u vidu granicu koja izaziva iritaciju oka. CPE&nbsp; je&nbsp; povr&scaron;inski&nbsp; modifikovana&nbsp; vi&scaron;ezidnim&nbsp; ugljeničnim&nbsp; nanocevima&nbsp; (MWCNT)&nbsp; i kompozitima MnO 2 -MWCNT ili Pt-MWCNT metodom nano&scaron;enja kapi radi pripreme jednostavnih, osetljivih i pouzdanih voltametrijskih senzora za&nbsp; određivanje H ₂O₂u odabranom uzorku. Rezultati SEM/EDS&nbsp; analize&nbsp; kompozitnih&nbsp; materijala&nbsp; su&nbsp; potvrdili da&nbsp; su&nbsp; medijatori,&nbsp; čestice&nbsp; MnO 2 i&nbsp; Pt, nasumično&nbsp; raspoređeni na povr&scaron;ini MWCNT i zastupljeni sa blizu 5% (m:m) u kompozitu izraženo<br />preko Mn i Pt. CV merenja su vr&scaron;ena sa pripremljenim radnim elektrodama u acetatnom (pH 4,50), fosfatnom&nbsp; (pH&nbsp; 7,50)&nbsp; i&nbsp; boratnom&nbsp; (pH&nbsp; 9,18)&nbsp; puferu&nbsp; kako&nbsp; bi&nbsp; se&nbsp; okarakterisalo&nbsp; osnovno elektrohemijsko&nbsp; pona&scaron;anje&nbsp; H ₂O₂i&nbsp; odabrali&nbsp; pogodni&nbsp; radni&nbsp; potencijali&nbsp; za&nbsp; amperometrijsko određivanje ovog ciljnog analita. Pt- WCNT/CPE je primenljiva za rad kako u fosfatnom puferu pH&nbsp; 7,50&nbsp; tako&nbsp; i&nbsp; u&nbsp; acetatnom&nbsp; puferu&nbsp; pH&nbsp; 4,50&nbsp; V&nbsp; kako&nbsp; pri&nbsp; negativnim&nbsp; tako&nbsp; i&nbsp; pri&nbsp; pozitivnim&nbsp; radnim<br />potencijalima, pri&nbsp; čemu su vrednosti RSD uglavnom ispod 2,5%. U slučaju MnO 2<br />-MWCNT/CPE, na&nbsp; potencijalu&nbsp; 0,30&nbsp; V&nbsp; i&nbsp; vi&scaron;im&nbsp; vrednostima,&nbsp; oksidacioni&nbsp; signali&nbsp; H<br />₂O₂ su&nbsp; signifikantni&nbsp; u&nbsp; blago alkalnoj sredini (pH 7,50), pri pH 4,50 ova elektroda pokazuje nezadovoljavajuće pona&scaron;anje, dok&nbsp; pri pH 9,18 ima prihvatljive performanse. Granice određivanja (GO) su bile u oblasti &micro;g mL -1 . H ₂O₂ je&nbsp; određen&nbsp; u&nbsp; spajkovanom&nbsp; uzorku&nbsp; mleka&nbsp; metodom&nbsp; standardnog&nbsp; dodatka&nbsp; nakon&nbsp; odgovarajuće pripreme&nbsp; uzorka&nbsp; (pH&nbsp; pode&scaron;avanje&nbsp; i&nbsp; centrifugiranje)&nbsp; i&nbsp; primenom&nbsp; optimizovane&nbsp; amperometrijske procedure (acetatni pufer pH 4,50, radni&nbsp; potencijal-0,75 V) koristeći Pt-MWCNT/CPE kao radnu elektrodu. RSD za tri&nbsp; ponovljena merenja je iznosila 2,5%, dok je prinos metode bio ne&scaron;to veći od 71%.<br />Kompozitni materijali koji se sastoje od MWCNT i&nbsp; čestica na bazi Pd (Pd-MWCNT) ili Pt (Pt-MWCNT) su primenjeni za pripremu zapreminski modifikovanih SPCE (Pd-MWCNT-SPCE i Pt-MWCNT-SPCE)&nbsp; i&nbsp; povr&scaron;inski&nbsp; modifikovane&nbsp; SPCE&nbsp; (Pd-MWCNT/SPCE).&nbsp; Ove&nbsp; elektrode,&nbsp; kao&nbsp; i nemodifikovana&nbsp; SPCE&nbsp; i&nbsp; MWCNT-SPCE,&nbsp; su&nbsp; okarakterisane primenom&nbsp; CV&nbsp; i&nbsp; amperometrije&nbsp; u fosfatnom puferu pH 7,50 radi određivanja H ₂O₂ . Pd-MWCNT-SPCE i Pd-MWCNT/SPCE su se pokazale&nbsp; pogodnim&nbsp; za&nbsp; određivanje&nbsp; H ₂O₂ na&nbsp; radnim&nbsp; potencijalima&nbsp; između&nbsp; -0,50&nbsp; i&nbsp; 0,50&nbsp; V,&nbsp; a&nbsp; PtMWCNT-SPCE na ispitivanim radnim potencijalima od -0,80 do 0,70 V. Ove&nbsp; elektrode su zatim modifikovane&nbsp; enzimom&nbsp; glukoza&nbsp; oksidazom&nbsp; (GOx)&nbsp; metodom&nbsp; nano&scaron;enja&nbsp; kapi&nbsp; rastvora&nbsp; GOx&nbsp; i Nafion &reg; -a&nbsp; na&nbsp; njihovu&nbsp; povr&scaron;inu,&nbsp; pri&nbsp; čemu&nbsp; je&nbsp; optimizovana&nbsp; količina&nbsp; nanetog&nbsp; biofilma.&nbsp; GOx/PdMWCNT-SPCE&nbsp; je&nbsp; pokazala&nbsp; bolje&nbsp; analitičke&nbsp; performanse&nbsp; za&nbsp; određivanje&nbsp; glukoze&nbsp; u&nbsp; poređenju&nbsp; sa GOx/Pd- WCNT/SPCE.&nbsp; Kao&nbsp; optimalan&nbsp; radni&nbsp; potencijal&nbsp; GOx/Pd-MWCNT-SPCE&nbsp; je&nbsp; odabrana<br />vrednost&nbsp; potencijala&nbsp; -0,40&nbsp; V&nbsp; u&nbsp; odnosu&nbsp; na&nbsp; ZKE,&nbsp; sa&nbsp; zadovoljavajućom&nbsp; linearno&scaron;ću&nbsp; u&nbsp; ispitivanom opsegu&nbsp; koncentracija&nbsp; glukoze&nbsp; od&nbsp; 0,16&nbsp; do&nbsp; 0,97&nbsp; mmol&nbsp; L -1 (od&nbsp; 29,1&nbsp; do&nbsp; 174&nbsp; &micro;g&nbsp; mL -1),&nbsp; dok&nbsp; je&nbsp; GO iznosila 0,14 mmol L -1 (25 &micro;g mL<br />-1 ). Optimizovana metoda zasnovana na GOx/Pd-MWCNT-SPCE je&nbsp; uspe&scaron;no&nbsp; primenjena&nbsp; za&nbsp; određivanje&nbsp; glukoze&nbsp; u&nbsp; uzorku&nbsp; livadskog&nbsp; meda.&nbsp; Dobijeni&nbsp; rezultati&nbsp; su&nbsp; u dobroj&nbsp; saglasnosti&nbsp; sa&nbsp; onima&nbsp; dobijenim&nbsp; primenom&nbsp; komercijalno&nbsp; dostupnog&nbsp; aparata&nbsp; za&nbsp; merenje glukoze. Pogodan radni potencijal za GOx/Pt-MWCNT-SPCE je bio -0,50 V u odnosu na ZKE, pri čemu je zadovoljavajuća linearnost postignuta u ispitivanom opsegu koncentracija glukoze od 65,8 do 260,6 &micro;g mL -1 , sa GO 35 &micro;g mL -1 . Optimizovana metoda zasnovana na GOx/Pt-MWCNT-SPCE je&nbsp; uspe&scaron;no&nbsp; primenjena&nbsp; za&nbsp; određivanje&nbsp; glukoze&nbsp; u&nbsp; u&nbsp; uzorku&nbsp; belog&nbsp; grožđa&nbsp; i&nbsp; uzorku&nbsp; tableta (Traubenzucker-bonbons),&nbsp; pri&nbsp; čemu&nbsp; su&nbsp; dobijeni&nbsp; rezultati&nbsp; u&nbsp; dobroj&nbsp; saglasnosti&nbsp; sa&nbsp; rezultatima dobijenim primenom Accu-Chek aparata.<br />Na&nbsp; osnovu&nbsp; dobijenih&nbsp; rezultata&nbsp; može&nbsp; se&nbsp; zaključiti&nbsp; da&nbsp; su&nbsp; razvijene&nbsp; analitičke&nbsp; metode&nbsp; pre svega jednostavne, pouzdane i pogodne za dobijanje brzih informacija o sadržaju H ₂O₂ u različitim tipovima&nbsp; uzoraka.&nbsp; Svakako&nbsp; odabir&nbsp; pogodne&nbsp; radne&nbsp; elektrode,&nbsp; kao&nbsp; i&nbsp; optimizacija&nbsp; eksperimentalnih uslova su ključni faktori za uspe&scaron;no određivanje H ₂O₂</p> / null / <p>The aim of this doctoral dissertation was the development of fast and reliable voltammetric methods&nbsp; based&nbsp; on&nbsp; the&nbsp; application&nbsp; of&nbsp; simple&nbsp; and&nbsp; contemporary&nbsp; electrodes/sensors&nbsp; based&nbsp; on carbonaceous materials (carbon paste made of graphite powder and paraffin oil and screen printed carbon electrodes) for the determination of H <span id="cke_bm_571S" style="display: none;">&nbsp;</span>₂<span id="cke_bm_571E" style="display: none;">&nbsp;</span>O₂ in the selected complex model and real samples.For this purpose, applicability of different working electrodes was investigated.The&nbsp; amperometric&nbsp; method&nbsp; based&nbsp; on&nbsp; carbon&nbsp; paste&nbsp; electrode&nbsp; (CPE)&nbsp; bulk- modified&nbsp; &nbsp;&nbsp; with 5% (m:m) MnO 2 , under optimized conditions, with a working potential of 0.40 V vs. the saturated calomel&nbsp; elect<span id="cke_bm_572E" style="display: none;">&nbsp;</span>rode&nbsp; (SCE)&nbsp; and&nbsp; a&nbsp; phosphate&nbsp; buffer&nbsp; solution&nbsp; (pH&nbsp; 7.50)&nbsp; as&nbsp; supporting&nbsp; electrolyte, enabled the quantitation of H <span id="cke_bm_577S" style="display: none;">&nbsp;</span>₂<span id="cke_bm_577E" style="display: none;">&nbsp;</span>O₂in the concentration interval from 1.4 to 65 &micro;g mL &minus;1 with a relative standard deviation (RSD) of less than 10%. This meth<span id="cke_bm_578E" style="display: none;">&nbsp;</span>od was applied for the determination of the H<span id="cke_bm_583S" style="display: none;">&nbsp;</span>₂<span id="cke_bm_583E" style="display: none;">&nbsp;</span>O₂consumption&nbsp; in&nbsp; samples&nbsp; of&nbsp; groundwater&nbsp; fro<span id="cke_bm_584E" style="display: none;">&nbsp;</span>m&nbsp; the&nbsp; Central&nbsp; Banat&nbsp; region&nbsp; (Province&nbsp; of Vojvodina, Serbia) treated by the Fenton (Fe ²⁺and H ₂O₂ ) and Fenton-&nbsp; like (Fe ³⁺and H ₂O₂ ) reagents to remove natural organic matter (NOM) at&nbsp; differentinitial concentrations of iron species, and of their molar ratios to the initial concentration of H₂O₂ . It was found that the form of Fe (Fe ²⁺ or Fe ³⁺ )and the molar&nbsp; ratio to H ₂O₂influenced the degree of the H₂O₂ decomposition in the groundwater with high NOM content. Besides, in the case of the Fenton-like process, for all initial doses of Fe ³⁺ and H<span id="cke_bm_604S" style="display: none;">&nbsp;</span>₂<span id="cke_bm_604E" style="display: none;">&nbsp;</span>O₂, a sign<span id="cke_bm_605E" style="display: none;">&nbsp;</span>ificant amount of H<span id="cke_bm_610S" style="display: none;">&nbsp;</span>₂<span id="cke_bm_610E" style="display: none;">&nbsp;</span>O₂ remained unused, whi<span id="cke_bm_611E" style="display: none;">&nbsp;</span>ch also indicates a lower efficiency of such system compared to the Fenton process. Screen&nbsp; printed&nbsp; carbon&nbsp; electrode&nbsp; (SPCE)&nbsp; bulk-modified&nbsp; with&nbsp; MnO&nbsp;₂ as&nbsp; a&nbsp; mediator&nbsp; was applied&nbsp; for&nbsp; amperometric&nbsp; determination&nbsp; of&nbsp; the&nbsp; H <span id="cke_bm_617S" style="display: none;">&nbsp;</span>₂<span id="cke_bm_617E" style="display: none;">&nbsp;</span>O₂ content&nbsp; during&nbsp; the&nbsp; Fenton&nbsp; (Fe ²⁺ ,&nbsp; H <span id="cke_bm_624S" style="display: none;">&nbsp;</span>₂<span id="cke_bm_624E" style="display: none;">&nbsp;</span>O₂)&nbsp; and <span id="cke_bm_625E" style="display: none;">&nbsp;</span>visible&nbsp; light-assisted<span id="cke_bm_618E" style="display: none;">&nbsp;</span>,&nbsp; photo-Fenton&nbsp; (Fe ^2+&nbsp; ,&nbsp; H <span id="cke_bm_631S" style="display: none;">&nbsp;</span>₂<span id="cke_bm_631E" style="display: none;">&nbsp;</span>O₂ ,&nbsp; h&nu;)<span id="cke_bm_632E" style="display: none;">&nbsp;</span>&nbsp; based&nbsp; removal&nbsp; of&nbsp; neonicotinoid&nbsp; insecticide acetamiprid (ACT). Under&nbsp; optimized conditions (working potential of 0.40 V vs. SCE, phosphate buffer&nbsp; pH&nbsp; 7.50&nbsp; as&nbsp; supporting&nbsp; electrolyte)&nbsp; amperometric&nbsp; determination&nbsp; of&nbsp; H <span id="cke_bm_637S" style="display: none;">&nbsp;</span>₂<span id="cke_bm_637E" style="display: none;">&nbsp;</span>O₂showed&nbsp; a&nbsp; linear dynamic range from 0.01 to 1.24 mmol L -1 (from 0.34 to 42.2 &micro;g mL -1) and the RSD did not exceed 4.2%. In the investigated samples (after appropriate pH adjustment from 2.8 to 7.5 instantly after the sampling<span id="cke_bm_638E" style="display: none;">&nbsp;</span> to stop or maximum decelerate the oxidation processes, filtering, and storage of the deep- frozen sample with defrosting immediately before the measurements) the H <span id="cke_bm_643S" style="display: none;">&nbsp;</span>₂<span id="cke_bm_643E" style="display: none;">&nbsp;</span>O₂&nbsp; contents were determined by the standard addition method by analyzing the corresponding amperometric curves. Parallel HPLC-DAD measurements were performed to monito<span id="cke_bm_644E" style="display: none;">&nbsp;</span>r the concentration/removal of ACT. In the case of the photo- Fenton process (initial concentrations: 0.31; 2.0 and 3.0 mmol L -1 (70.0; 111.7 and 102.1 &micro;g mL -1 ) of ACT, Fe²⁺ and H <span id="cke_bm_650S" style="display: none;">&nbsp;</span>₂<span id="cke_bm_650E" style="display: none;">&nbsp;</span>O₂, respec<span id="cke_bm_651E" style="display: none;">&nbsp;</span>tively) after 10 min of irradiation H <span id="cke_bm_656S" style="display: none;">&nbsp;</span>₂<span id="cke_bm_656E" style="display: none;">&nbsp;</span>O₂ was&nbsp; consumed&nbsp; and&nbsp; it&nbsp; can&nbsp; be&nbsp; consi<span id="cke_bm_657E" style="display: none;">&nbsp;</span>dered&nbsp; that&nbsp; ACT&nbsp; was&nbsp; removed&nbsp; after&nbsp; 5&nbsp; min.&nbsp; During&nbsp; the&nbsp; Fenton process ACT was removed after 20 min of treatment and around 10% of the initial concentration of the H 2O2 remained still unused.<br />CPE&nbsp; was&nbsp; surface&nbsp; modified&nbsp; with&nbsp; a&nbsp; composite&nbsp; of&nbsp; Pt&nbsp; nanoparticles&nbsp; (&lt;&nbsp; 5&nbsp; nm)&nbsp; on&nbsp; graphitized carbon (Pt-C, 10% Pt on Vulcan XC72) by simply dropcoating method. The unmodified CPE and the&nbsp; modified&nbsp; one&nbsp; (Pt-C/CPE)&nbsp; were&nbsp; characterized&nbsp; by&nbsp;&nbsp; EM/EDS&nbsp; and&nbsp; CV&nbsp; measurements.&nbsp; The&nbsp; PtC/CPE showed remarkable electrocatalytic propertiestoward the electrochemical redox reaction of H<span id="cke_bm_662S" style="display: none;">&nbsp;</span>₂<span id="cke_bm_662E" style="display: none;">&nbsp;</span>O₂ compared to&nbsp; modified CPE in phosphate buffer (0.1 mol L -1 ; pH 7.50), as well in acetatebuffer&nbsp; (0.1 mol&nbsp; L -1 ; pH .50) supporting&nbsp; electrolytes. Amperometry of&nbsp; H2O2 in the concentration range from 0.15 to 1.45 &micro;g mL -1 with the Pt-C/CPE showed acceptable linearity, while the obtained values of LOQs were 0.06 &micro;g mL -1&nbsp; (pH 7.50, working potential 0.20 V) and 0.10 &micro;g mL -1 (pH 4<span id="cke_bm_663E" style="display: none;">&nbsp;</span>.50, working potential 0.50 V). The proposed analytical&nbsp; methods were applied to the determination of the H 2O2 content in commercially available personal care products; i.e., disinfection (pH 7.50) and contact lens cleaning solutions (pH 4.50). The obtained amperometric results are in good agreement with those measured by traditional titanium sulfatereagent based spectrophotometric method with determined concentrations as 2.91% and 2.94%&nbsp; for the disinfection product, and 3.04% and 3.17% for the contact lens solution, respectively. RSD was lower than 2%. The obtained results are in a good agreement with the amounts of the H<span id="cke_bm_668S" style="display: none;">&nbsp;</span>₂<span id="cke_bm_668E" style="display: none;">&nbsp;</span>O₂declared by producers (3%) in the both investigated samples. The Pt-C/CPE was also tested for monitoring of the H<span id="cke_bm_674S" style="display: none;">&nbsp;</span>₂<span id="cke_bm_674E" style="display: none;">&nbsp;</span>O₂ residual concentration in contact lens&nbsp; solution&nbsp; during&nbsp; its&nbsp; neutralization/decomposition&nbsp; rocess.&nbsp; At&nbsp; 6&nbsp; h&nbsp; of<span id="cke_bm_675E" style="display: none;">&nbsp;</span>&nbsp; neutralization&nbsp; treatment 24.68 &micro;g mL -1 of the H <span id="cke_bm_680S" style="display: none;">&nbsp;</span>₂<span id="cke_bm_680E" style="display: none;">&nbsp;</span>O₂was&nbsp; determined which is almost half of the allowedH2<span id="cke_bm_681E" style="display: none;">&nbsp;</span>O2 concentration in the case of the contact lens solution concerningthe limit of eye irritation. CPE&nbsp; was&nbsp; surface&nbsp;&nbsp; modified&nbsp; with&nbsp; multiwalled&nbsp; carbon&nbsp; nanotubes&nbsp; (MWCNT)&nbsp; and&nbsp; with composites of MnO₂-MWCNT or Pt-MWCNT by drop coating method to prepare simply, sensitive and reliable volta<span id="cke_bm_669E" style="display: none;">&nbsp;</span>mmetric sensors for the determination of H <span id="cke_bm_687S" style="display: none;">&nbsp;</span>₂<span id="cke_bm_687E" style="display: none;">&nbsp;</span>O₂in selected sample. The results of the&nbsp; SEM/<span id="cke_bm_688E" style="display: none;">&nbsp;</span>EDS&nbsp; analysis&nbsp; of&nbsp; composite&nbsp; materials&nbsp; have&nbsp; confirmed&nbsp; that&nbsp; the&nbsp; mediators,&nbsp; MnO ₂ and&nbsp; Pt&nbsp; articles, are randomly distributed on the surface of MWCNT and represent nearly 5% (m:m) of the composite expressed as Mn and Pt. CV measurements were performed&nbsp; with prepared electrodes in acetate&nbsp; (pH&nbsp; 4.50),&nbsp; phosphate&nbsp; (pH&nbsp; 7.50)&nbsp; and&nbsp; borate&nbsp; (pH&nbsp; 9.18)&nbsp; buffers&nbsp; to&nbsp; characterize&nbsp; the&nbsp; basic electrochemical&nbsp; behavior&nbsp; of&nbsp; H <span id="cke_bm_694S" style="display: none;">&nbsp;</span>₂<span id="cke_bm_694E" style="display: none;">&nbsp;</span>O₂ and&nbsp; to&nbsp; select&nbsp; the&nbsp; working&nbsp; potentials&nbsp; suitable&nbsp; for&nbsp; amperometric determination&nbsp; of&nbsp; this&nbsp; target&nbsp; analyte.&nbsp; The&nbsp; Pt-MWCNT/CPE&nbsp; performs&nbsp; well&nbsp; in&nbsp; phosphate&nbsp; buffer pH .50 and acetate buffer solution pH 4.50 in the&nbsp; negative as well as in the positive polarization range with RSD mainly lower than 2.5%. In case of MnO₂-MWCNT/CPE at <span id="cke_bm_695E" style="display: none;">&nbsp;</span>0.30 V and above the H<span id="cke_bm_701S" style="display: none;">&nbsp;</span>₂<span id="cke_bm_701E" style="display: none;">&nbsp;</span>O₂oxidation signal is rem<span id="cke_bm_702E" style="display: none;">&nbsp;</span>arkable in slightly alkaline media (pH 7.50), at pH 4.50 this electrode showed poor behavior and at pH 9.18 offered acceptable performance. LOQs were in the &micro;g mL -1 concentration&nbsp; range.&nbsp; H<span id="cke_bm_707S" style="display: none;">&nbsp;</span>₂<span id="cke_bm_707E" style="display: none;">&nbsp;</span>O₂was&nbsp; determined&nbsp; in&nbsp; a&nbsp; spiked&nbsp; milk&nbsp; sample&nbsp; by&nbsp; standard addition&nbsp; method after&nbsp; appropriate&nbsp; sample&nbsp; preparation&nbsp; (pH&nbsp; adjustment and&nbsp; centrifugation)&nbsp; and&nbsp; using&nbsp; optimized amperometric p<span id="cke_bm_708E" style="display: none;">&nbsp;</span>rocedure (acetate buffer pH 4.50, working potential -0.75 V) by Pt-MWCNT/CPE as a working electrode. RSD for three repeated measurements was 2.5%, while the recovery of the method was a bit higher than 71%. The&nbsp; composite&nbsp; materials&nbsp; consisting&nbsp; of&nbsp; MWCNT&nbsp; and&nbsp; Pd&nbsp; (Pd-MWCNT)&nbsp; or&nbsp; Pt&nbsp; containing particles&nbsp; (Pt-WCNT)&nbsp; were&nbsp; applied&nbsp; to&nbsp; the&nbsp; preparation&nbsp; of&nbsp; bulk- modified&nbsp; SPCEs&nbsp; (Pd-MWCNTSPCE and Pt-MWCNT-SPCE) and surface modifiedSPCE (Pd- MWCNT/SPCE). These electrodes, as well as unmodified SPCE and MWCNT-SPCE,&nbsp; were characterized by CV and&nbsp; amperometry&nbsp; in phosphate&nbsp; buffer&nbsp; solution&nbsp; of&nbsp; pH&nbsp; 7.50&nbsp; for&nbsp; the&nbsp; H<span id="cke_bm_713S" style="display: none;">&nbsp;</span>₂<span id="cke_bm_713E" style="display: none;">&nbsp;</span>O₂determination.&nbsp; Pd-MWCNT-SPCE&nbsp; and&nbsp; PdMWCNT/SPCEare convenient for the etermination of H 2O2 at working potentials from -0.50 to 0.50 V, and Pt-MWCNT-SPCE at investigated working potentials in the range from -0.80 to 0.70 V. These electrodes were then modified with glucose&nbsp; oxidase (GOx) by drop coating a solution of GOxand Nafion &reg; on their surface, whereby the applied amount of biococktail was optimized. GOx/PdMWCNT-SPCE&nbsp; showed&nbsp; better&nbsp; analytical&nbsp; performance&nbsp; for&nbsp; glucose&nbsp; determination&nbsp; in&nbsp; comparison with&nbsp; GOx/Pd-MWCNT/SPCE.&nbsp; The&nbsp; optimal&nbsp; working&nbsp; potential&nbsp; for&nbsp; GOx/Pd-MWCNT- SPCE&nbsp; was -0.40 V vs. SCE and <span id="cke_bm_714E" style="display: none;">&nbsp;</span>satisfactory linearity was obtained in the investigated glucose concentration range from 0.16 to 0.97 mmol L -1 (from 29.1 to 174&nbsp; &micro;g mL -1 ), hile the LOQ was 0.14 mmol L -1 (25 &micro;g mL -1 ). The optimized method based on GOx/Pd-MWCNT-SPCE was successfully applied to the determination of glucose in multifloral honey sample.&nbsp; The results are in a good agreement with those&nbsp; obtained by commercially available equipment for determination of glucose. Optimal working potential&nbsp; for&nbsp; GOx/Pt-MWCNT-SPCE&nbsp; was&nbsp; -0.50&nbsp; V&nbsp; vs.&nbsp; SCE,&nbsp; and&nbsp; the&nbsp;&nbsp; satisfactory&nbsp; linearity&nbsp; was obtained in the investigated concentration range ofglucose from 65.8 to 260.6&nbsp; &micro;g mL -1 , with LOQ of 35&nbsp; &micro;g mL -1 . The optimized method based on GOx/Pt- MWCNT-SPCE was successfully applied for determination of glucose in white grape and glucose tablets (Traubenzucker-bonbons) samples, whereby&nbsp; the&nbsp; obtained&nbsp; results&nbsp; were&nbsp; in&nbsp; a&nbsp; good&nbsp; agreement&nbsp; with&nbsp; the&nbsp; results&nbsp; obtained&nbsp; by&nbsp; Accu-Chek device. Based on the results, the developed analytical methods are first of all simple, reliable and suitable&nbsp; for&nbsp; obtaining&nbsp; fast&nbsp; information&nbsp; about&nbsp; the&nbsp; content&nbsp; of&nbsp; H ₂O₂ in&nbsp; different&nbsp; types&nbsp; of&nbsp; samples. Certainly the selection of a suitable working electrode, as well as the optimization of experimental conditions are key factors for the successful determination of H₂O₂.</p>

Text in German / An drei Stellen im Römerbrief verweist Paulus auf die Vergangenheit Israels: auf Abraham in Röm 4,1–25, auf Abrahams Nachkommen, Mose und Pharao in Röm 9,6–18 und auf Elija in Röm 11,1–10. Gegenstand der Untersuchung ist die Bedeutung dieser Verweise auf die Vergangenheit Israels für die Argumentation des Römerbriefs. Nach der Analyse der rhetorischen Situation und der Einordnung der relevanten Stellen in die rhetorische Makrostruktur des Briefs werden alttestamentlicher Kontext und frühjüdische Rezeption der rezipierten Ereignisse untersucht. Auf diesem Hintergrund werden die drei Passagen detailliert betrachtet, indem der Argumentationsgang untersucht und die mögliche rhetorische Wirkung auf die Adressaten aus sechs unterschiedlichen Perspektiven analysiert wird: mit hoher Schriftkenntnis, mit geringer Schriftkenntnis, aus jüdischer, nichtjüdischer, christlicher und stadtrömischer Perspektive. Auf diese Weise können unterschiedliche Aspekte der leserseitigen Rezeption differenziert wahrgenommen werden, bevor sie zu einem Gesamtbild zusammengeführt werden. / New Testament

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