<p dir="ltr">Highway safety continues to pose a serious challenge to the social sustainability of transportation systems, and initiatives are being pursued at all levels of government to reduce the high fatality count of 42,000. At the same time, it is sought to ensure higher travel efficiency in order to increase economic productivity. The emergence of automated transportation provides great promise to mitigate these ills of the transportation sector that have persisted for so many decades. With regards to safety, such promise is rooted in the capability of autonomous vehicles to self-drive some or all of the time, thus reducing the impact of inherently errant human driving to which 95% of all crashes have been attributed. With regards to mobility, such promise is guided by the capability of the autonomous vehicle to carry out path planning, navigation, and vehicle controls in ways that are far more efficient than the human brain, thereby facilitating mobility and reducing congestion-related issues such as delay, emissions, driver frustration, and so on.</p><p dir="ltr">Unfortunately, the two key outcomes (safety and mobility) are reciprocal in the sense that navigation solutions that enhance safety generally tend to reduce mobility, and vice versa. As such, there is a need to assign values explicit to these performance criteria in order to develop balanced solutions for AV decisions. Most existing machine-learning-based path planning algorithms derive these weights using a learning approach. Unfortunately, the stability of these weights across time, individuals, and trip types, is not guaranteed. It is necessary to develop weights and processes that are trip situation-specific. Secondly, user trust in automation remains a key issue, given the relatively recent emergence of this technology and a few highly-publicized crashes, which has led to reservations among potential users.</p><p dir="ltr">To address these research questions, this thesis identifies various situational contexts of the problem, identifies the alternatives (the viable trajectories by fitting curves between the vehicle maneuver’s initial and final positions), develops the decision criteria (safety, mobility, comfort), carries out weighting of the criteria to reflect their relative significance, and scales the criteria to develop dimensionless equivalents of their raw values. Finally, a process for amalgamating the overall impacts of each driving decision alternative is developed based on the weighted and scaled criteria, to identify the best decision (optimal trajectory path). This multi-criteria decision making (MCDM) problem involves the collection of data through questionnaire surveys.</p><p dir="ltr">The weights obtained early in the MCDM process could be integrated into any one of two types of planning algorithms. First, they could be incorporated into interpolating curve-based planning algorithms, to identify the optimal trajectory based on human preferences. Additionally, they can be integrated into optimization-based planning algorithms to allocate weights to the various functions used.</p><p dir="ltr">Overall, this research aims to align the behavior of autonomous vehicles closely with human-driven vehicles, serving two primary purposes: first, facilitating their seamless coexistence on mixed-traffic roads and second, enhancing public acceptance of autonomous vehicles.</p>

Yes / Increasing reliance on digital technologies has led to a significant shift in how businesses operate, with many now relying heavily on digital platforms for effective planning, communication, sales, marketing, supply chain, and logistics management. In this context, knowledge sharing platforms enable academic–industry collaboration in which exchange of ideas, opinions, experience, and expertise brings collective intelligence in cooperative learning ecosystem thereby expediting decision making. However, establishing long-term commitment among the partners, allocation of time and resources for sharing tacit knowledge, collaboration among partners with different strategic priorities, and real-time knowledge sharing capabilities are essential for effective and rapid learning in knowledge sharing platforms. The present article will examine these benefits and challenges in knowledge sharing and its impact on supplier selection platforms in Asian automakers. The findings of this article will be helpful for researchers and practitioners intending to explore the role of cooperation in knowledge sharing and digital transformation amid competitive environment prevalent in the automotive industry. The potential supplier database is first examined for qualifying the capability requirements put forth in this article and further prioritized using a multicriteria decision-making technique and analytic hierarchy process. The article results reveal that the manufacturer has highly prioritized firms’ financial transparency for supplier evaluation followed by the suppliers’ cost control, quality control, and manufacturing capabilities. The article has significant theoretical and practical implications for developing robust supplier evaluation criteria for automobile industry and a digital ecosystem for original equipment manufacturers in making supplier related decisions.

Tesis por compendio / [ES] Los métodos multicriterio proporcionan un enfoque analítico y estructurado para la toma de decisiones en la gestión de la cadena de suministro, que permiten evaluaciones basadas en múltiples criterios, esenciales para gestionar socios comerciales sostenibles. El objetivo de esta tesis es contribuir a la gestión sostenible de la cadena de suministro desarrollando nuevos modelos y técnicas multicriterio para evaluar proveedores y clientes. Se han diseñado modelos que incorporan las preferencias empresariales para tomar decisiones colaborativas en la selección y clasificación transparente de alternativas basadas en criterios sostenibles. También se han desarrollado métodos para clasificar las alternativas en grupos ordenados y evaluar su calidad. Tanto los modelos como los métodos se han validado mediante casos empíricos y comparado con enfoques alternativos. La metodología se basa en una profunda revisión bibliográfica y en el conocimiento experto de profesionales en la cadena de suministro. Los modelos multicriterio propuestos emplean técnicas como el Analytic Hierarchy Process (AHP), la Multi-Attribute Utility Theory (MAUT) y PROMETHEE. También se han desarrollado tres algoritmos para la clasificación de alternativas (nominal y ordenada). En primer lugar, se ha propuesto un modelo multicriterio híbrido y se ha validado con datos reales para homologar y seleccionar proveedores de tecnología, así como para su priorización y clasificación. Este modelo integra métodos compensatorios (AHP, MAUT) y no compensatorios (PROMETHEE, FlowSort) en una jerarquía con criterios de sostenibilidad. La validación del modelo en un contexto real y su comparación con un modelo alternativo ha demostrado su capacidad para proporcionar información relevante y transparente en la toma de decisiones para la evaluación sostenible de proveedores de tecnología en el sector bancario. En segundo lugar, se ha diseñado un nuevo algoritmo, denominado Global Local Net Flow sorting (GLNF sorting), que clasifica alternativas en grupos ordenados a partir de los flujos netos generados en búsquedas globales y locales con PROMETHEE. Adicionalmente, se ha diseñado el algoritmo SILhouette for Sorting (SILS) para calcular un índice de calidad en las clasificaciones. Ambos algoritmos se han validado empíricamente en la segmentación de proveedores y sus resultados se han comparado con otros métodos publicados. Por una parte, GLNF sorting destaca al mejorar la discriminación entre proveedores cercanos a los perfiles limitantes de los grupos, aprovechando el nivel de similitud preferencial entre alternativas. Por otra, SILS mejora la calidad de las asignaciones y permite un análisis detallado que facilita la toma de decisiones. En tercer lugar, se ha propuesto un sistema de segmentación de clientes B2B basado en transacciones y colaboración, aplicando AHP y GLNF sorting. Validado con 8,157 clientes de una multinacional, se ha evaluado con SILS y estadística descriptiva. Comparado con K-means, el modelo genera clasificaciones más homogéneas y robustas. Esta herramienta permite a las empresas automatizar decisiones y llevar a cabo análisis detallados para mejorar las relaciones con los clientes, alineándose con sus estrategias de colaboración y enfoques de mercado. En cuarto lugar, las búsquedas globales y locales se han utilizado para proponer un algoritmo de clasificación nominal basado dos dimensiones, que proporciona una matriz estratégica muy útil para los gestores de cadena de suministro. Por último, se ha desarrollado el paquete de software PrometheeTools en R, que automatiza la aplicación de PROMETHEE, GLNF sorting y SILS para resolver problemas multicriterio de priorización y clasificación de alternativas. Este paquete se ha validado con éxito y destaca por su eficiencia en PROMETHEE con miles de alternativas. Está disponible en acceso abierto en el repositorio CRAN para su utilización por investigadores y profesionales interesados en toma de decisiones multicriterio. / [CA] Els mètodes multicriteri proporcionen un enfocament analític i estructurat per a la presa de decisions en la gestió de la cadena de subministrament, que permeten avaluacions basades en múltiples criteris, essencials per a gestionar socis comercials sostenibles. L'objectiu d'aquesta tesi és contribuir a la gestió sostenible de la cadena de subministrament desenvolupant nous models i tècniques multicriteri per a avaluar proveïdors i clients. S'han dissenyat models que incorporen les preferències empresarials per a prendre decisions col·laboratives en la selecció i classificació transparent d'alternatives basades en criteris sostenibles. També s'han desenvolupat mètodes per a classificar les alternatives en grups ordenats i avaluar-ne la qualitat. Tant els models com els mètodes s'han validat mitjançant casos empírics i comparat amb enfocaments alternatius. La metodologia es basa en una profunda revisió bibliogràfica i en el coneixement expert de professionals en la cadena de subministrament. Els models multicriteri proposats empren tècniques com ara el procés analític jeràrquic (AHP), la teoria d'utilitat multiatribut (MAUT) i PROMETHEE. També s'han desenvolupat tres algoritmes per a la classificació d'alternatives (nominal i ordenada). En primer lloc, s'ha proposat un model multicriteri híbrid i s'ha validat amb dades reals per a homologar i seleccionar proveïdors de tecnologia, així com per a la seua priorització i classificació. Aquest model integra mètodes compensatoris (AHP, MAUT) i no compensatoris (PROMETHEE, FlowSort) en una jerarquia amb criteris de sostenibilitat. La validació del model en un context real i la seua comparació amb un model alternatiu n'ha demostrat la capacitat per a proporcionar informació rellevant i transparent en la presa de decisions per a l'avaluació sostenible de proveïdors de tecnologia en el sector bancari. En segon lloc, s'ha dissenyat un nou algoritme, denominat Global Local Net Flow sorting (GLNF sorting), que classifica alternatives en grups ordenats a partir dels fluxos nets generats en cerques globals i locals amb PROMETHEE. Addicionalment, s'ha dissenyat l'algoritme SILhouette for Sorting (SILS) per a calcular un índex de qualitat en les classificacions. Ambdós algoritmes s'han validat empíricament en la segmentació de proveïdors i els seus resultats s'han comparat amb altres mètodes publicats. D'una banda, GLNF sorting destaca en millorar la discriminació entre proveïdors pròxims als perfils limitants dels grups, que aprofita el nivell de similitud preferencial entre alternatives. De l'altra, SILS millora la qualitat de les assignacions i permet una anàlisi detallada que facilita la presa de decisions. En tercer lloc, s'ha proposat un sistema de segmentació de clients B2B basat en transaccions i col·laboració, aplicant AHP i GLNF sorting. Validat amb 8,157 clients d'una multinacional, s'ha avaluat amb SILS i estadística descriptiva. Comparat amb K-means, el model genera classificacions més homogènies i robustes. Aquesta eina permet a les empreses automatitzar decisions i portar a cap anàlisis detallades per a millorar les relacions amb els clients, que s'alineen amb les seues estratègies de col·laboració i enfocaments de mercat. En quart lloc, les cerques globals i locals s'han utilitzat per a proposar un algoritme de classificació nominal basat en dues dimensions, que proporciona una matriu estratègica molt útil per als gestors de la cadena de subministrament. Finalment, s'ha desenvolupat el paquet de programari PrometheeTools en R, que automatitza l'aplicació de PROMETHEE, GLNF sorting i SILS per a resoldre problemes multicriteri de priorització i classificació d'alternatives. Aquest paquet s'ha validat amb èxit i destaca per la seua eficiència en PROMETHEE amb milers d'alternatives. Està disponible en accés obert en el repositori CRAN per a la utilització per investigadors i professionals interessats en la presa de decisions multicriteri. / [EN] Multicriteria methods provide an analytical and structured approach to decision making in supply chain management. These techniques allow multicriteria evaluations, which are essential for choosing and managing sustainable business partners. The aim of this thesis is to contribute to sustainable supply chain management by developing new multicriteria models and techniques to assess suppliers and customers. Models have been designed in order to incorporate business preferences to make collaborative decisions in the transparent selection and ranking of alternatives based on sustainable criteria. New methods have also been developed to classify alternatives into ordered groups and to assess their quality. Both models and methods have been validated using empirical cases and compared with alternative approaches. The methodology is based on an in-depth literature review, as well as the expertise of supply chain professionals. The proposed multicriteria models integrate techniques such as the Analytical Hierarchical Process (AHP), Multi-Attribute Utility Theory (MAUT) and the PROMETHEE method. Three new algorithms have also been developed for classifying alternatives into nominal and ordered groups (sorting problem). Firstly, a hybrid multicriteria model has been proposed and validated with real data for technology supplier qualifying, selection and ranking. This model integrates compensatory (AHP, MAUT) and non-compensatory (PROMETHEE, FlowSort) methods in a hierarchy with sustainability criteria to evaluate products, suppliers and manufacturers. Validation of the model in a real context and its comparison with an alternative model has demonstrated its ability to provide relevant and transparent information for decision making in the sustainable evaluation of technology suppliers in the banking sector. Secondly, a new algorithm has been designed, called Global Local Net Flow sorting (GLNF sorting), which classifies alternatives into ordered groups based on the net flows generated in global and local searches with PROMETHEE. In addition, the SILhouette for Sorting (SILS) algorithm has been designed to calculate a quality index in the classifications. Both algorithms have been empirically validated in supplier segmentation and their results compared with other published methods. On the one hand, the GLNF sorting algorithm excels in improving the discrimination between suppliers close to the limiting profiles by exploiting the level of preference similarity between alternatives. On the other, SILS improves the quality of alternative assignments to groups, allows for a detailed analysis of suppliers and facilitates decision making. Thirdly, a customer segmentation model based on transactions and collaboration has been proposed in the Business to Business context, applying AHP and GLNF sorting. Validated with 8,157 customers of a multinational company, it has been assessed by SILS and descriptive statistics. This model generates more homogeneous and robust groups than the K-means cluster method. This tool enables companies to automate decisions and perform detailed analysis to improve customer relationships, aligning with their collaboration strategies and market approaches. Fourthly, global and local searches have been used to propose an algorithm for nominal classification based on two dimensions, which provides a very useful strategic matrix for supply chain managers. Finally, the PrometheeTools software package has been developed in R, which automates the implementation of PROMETHEE, GLNF sorting and SILS to solve multicriteria problems of alternatives ranking and classification. This package has been successfully validated and stands out for the efficiency in PROMETHEE and especially when solving problems with thousands of alternatives. It is available by open access in the CRAN repository for use by researchers and practitioners interested in multicriteria decision making. / Barrera Jimenez, IF. (2024). Multicriteria Techniques for Sustainable Supply Chain Management [Tesis doctoral]. Universitat Politècnica de València. https://doi.org/10.4995/Thesis/10251/202879 / Compendio

本論文之要在探討多重準則決策（Multiple Criterion Decision Making）理論模式 及其相關應用。 ＭＣＤＭ問題可概括分為兩種類型：一是多屬性決策（Multiple Attribute Decisi- on Making ），一是多目標決策（Multiple Objective Decision Making）。 ＭＡＤＭ一般用於選項間之選擇；而ＭＯＤＭ則在設計構想中的最佳選項（Alterna- tive），一般ＭＣＤＭ法則須由下列三者組成：ヾ量化的目標函數；ゝ一組限制式； ゞ已知資訊的量化過程。線性規劃問題（Ｌ．Ｐ．）即是ＭＯＤＭ的一個例子。 ＭＡＤＭ問題通常包含了個數不多且事先決定的選項，此問題旨在經由屬性（Attri- bute）（或稱準則）之間的比較，對一群特定的選項做一個選擇。此類問題在各學科 都發展出特有的法則；例如：決策理論中的最大最小法則、事前機率、及效用理論； 經濟學中的Pareto最適性、社會福利函數；統計學中的多變量分析、因子分析；另外 在心理學方面也有應用。 本文偏重ＭＡＤＭ之剖析，對社會選擇論也有研討，主要研究動機在於探討各學者所 建立之理論模式，如何經由偏好現象尋取一個團體的共識；利用公設化系統誘導出審 慎的（Prudent ）結果，使得結果理性化（Rational）；我們的目的就在於尋求一個 能得到理性結果的法則。 本文結構計分四個部分： 第一部分：效用理論，偏好關係，投票行為。第二部分：Electre 法則，Hierarchy 法則，LINMAP法則以及其它相關法則概介。第三部分：多數決法則（Majority Meth- od），Borda Count ，Condocet法則排名公設、Kohler法則及Arrow-Raynaud's 法則 。第四部分：教育投資方面應用的討論及結論。

Ventilation is a critical task in underground mining operation. Lack of a good ventilation system causes accumulation of harmful gases, explosions, and even fatalities. A proper ventilation system provides adequate fresh air to miners for a safe and comfortable working environment. Fans, which provide air flow to different faces of a mine, have great impact in ventilation systems. Thus, selection of appropriate fans for a mine is the acute task. Unsuitable selection of a fan decreases safety and production rate, which increases capital and operational costs. Moreover, pitch angle of fans&rsquo / blades plays an important role in fan&rsquo / s efficiency. Therefore, selection of a fan and its pitch angle, which yields the maximum efficiency, is an emerging issue for an efficient mine ventilation. The main objective of this research study is to provide a decision making methodology for the selection of a main fan and its appropriate pitch angle for efficient mine ventilation. Nowadays, analytical hierarchy process as multi criteria decision making is used, and it yields outputs based on pairwise comparison. On the other hand, Fuzzy Logic as a soft computing method was combined with analytical hierarchy process and combined model did not yield appropriate results / because Fuzzy AHP increased uncertainty ratio in this study. However, fuzzy analytical hierarchy process might be inapplicable when it faces with vague and complex data set. Soft computing methods can be utilized for complicated situations. One of the soft computing methods is a Neuro-Fuzzy algorithm which is used in classification and DM issues. This study has two phases: i) selection of an appropriate fan using Analytical Hierarchy Process (AHP) and Fuzzy Analytical Hierarchy Process (Fuzzy AHP) and ii) selection of an appropriate pitch angle using Neuro-Fuzzy algorithm and Fuzzy AHP method. This study showed that AHP can be effectively utilized for main fan selection. It performs better than Fuzzy AHP because FAHP contains more expertise and makes problems more complex for evaluating. When FAHP and Neuro-Fuzzy is compared for pitch angle selection, both methodologies yielded the same results. Therefore, utilization of Neuro-Fuzzy in situation with complicated and vague data will be applicable.

都會區之主要幹道除為串連交通行為的空間外，更為眾多活動發生之場域，然在以機動車輛為主之道路空間規劃下，許多都市問題與亂象發生，由此1990年代提倡都市規劃應以「人」為本的新都市主義(New Urbanism)思潮出現，針對都市空間景觀倡導運用都市設計、永續運輸等策略，創造適宜人居之都市環境。而台北市為台灣首善之都，雖自民國80年起進行一連串都市空間檢討，然仍忽略主要幹道空間，而台北都會區大眾捷運網絡基本雛形已於民國89年底完成，路網設計多沿主要幹道興建，營運至今，民眾對公共運具之使用率確有增加並降低部分汽車使用量。由此，若能重新檢討並調整道路空間比例，基於人車共存之概念，綠美化主要幹道景觀，營造正面感受之環境意象，可提升市民對所居都市之認同感，亦可符合民眾日益昇高之生活環境品質要求，創造優質都市環境。 / 有鑑於此，本研究以台北都會區主要幹道為研究空間，忠孝東路、羅斯福路部份路段為實驗場域，進行幹道空間之檢討與空間改造計畫之評估，將「以人為主」之都市規劃理念導入交通規劃中，整合都市永續發展、都市設計及運輸相關理論，歸納出都會區主要幹道空間之規劃手法應包涵TOD之都市發展型態、塑造適宜之人行空間、調整幹道道路空間、結合都市設計之規範及永續運輸之交通規劃方式等五大項目。基此，考量人行、車行、幹道景觀、社會公平與幹道空間多樣化使用，在達成永續運輸之目標下，從「交通順暢性」、「步行親和性」、「景觀寧適性」、「場域複合性」等四大層面，建立適合研究範圍之「都會區主要景觀幹道最佳設計」評估架構。本研究應用模糊多準則評估方法，先透過專家德爾菲(Delphi)法確定評估架構後求取評估架構之權重值，並依所建立之評估架構計算忠孝東路與羅斯福路各幹道空間改造方案之績效值，以相對客觀的方式整合不同領域專家之價值判斷，應用模糊層級分析(Fuzzy AHP)法遴選研究範圍最適之幹道空間改造計畫，進行研究範圍最佳幹道空間改造方案之排序。 / 本研究評估結果發現最後遴選出之最適空間改造方案內容，均為調整道路路型、配置最大化人行空間之方案，將過去以汽車為主的幹道空間轉為對行人友善之場域，並強調綠化幹道景觀與多樣化使用。同時，由不同群體對各評估面向權重值之差異可發現學生群體著重幹道所提供之交通功能，學者及政府都市計劃單位著重幹道之人行空間，政府交通單位則並重幹道之車行與人行空間。此外，本研究亦根據評估結果研提相關改造計畫執行配套措施之建議，期所採行之幹道空間改造計畫評估方式，可供政府有關單位進行幹道空間檢討與改造評估時，一個相對客觀的決策進行過程與執行參考。 / The major arterials of a metropolis are places where not only connect traffic but lots of activities occurred. However, many urban problems came up under the roadway planning that according to mobile vehicles and resulted in an ideological trend named “New Urbanism” in 1990s. That promote urban planning should according to human beings and use strategies as urban design and sustainable transport for landscape to create a urban environment that is livable-in. / Taipei city is the biggest city of Taiwan at which we have reflected on urban space but have ignored review the major arterials since 1991. Then, the embryo network of mass rapid transit system of Taipei metropolitan area which was designed along major arterials has established in 2000. Since that, the using rate of public transportation has been increasing and decreasing part of quantity of private transportation. We can base on the construct “people-cars coexist”, therefore, review and regulate road -way scale to green the major arterials’ landscape, to shape a positive environmental image. It could promote townspeople’s identification of the city where they live in and conform to the increasing request for the quality of medium in the result of a high quality urban circumstance. / Base the above, this research chose Zong-Xiao east road and Roosevelt road of Taipei metropolis as the survey area to review the roadway landscape and evaluate spatial transforming schemes. We blended the new urbanism into transport planning and integrated with theories of sustainable development, urban design and transportation to generalize the medium of the major arterials area planning should contain five contents: TOD, mold a pedestrian-friendly area, adjust the allotment ratio of arterial, combine methods of urban design and sustainable transportation. Therefore, we took pedestrian, vehicles, arterial’s landscape, arterial space using diversification into account and under the goal, which achieve sustainable transportation established evaluative framework with four objectives: ” traffic smooth”, pedestrian-friendly” , “elegant and comfortable landscape”, and ”space complexity”. By utilizing fuzzy-MCDM approach, first, depended on fuzzy-Delphi method to ascertain that evaluative framework then counted the weights of criteria. According to the evaluative framework established by this research calculated the results of spatial transforming schemes of Zong-Xiao East road and Roosevelt road. Then adopting fuzzy-AHP method to integrate experts’ judgements of different domains, all proposed spatial schemes are reviewed and best arterial landscape transforming scheme were generated. / Evaluation result found that the best scheme with maximum pedestrian space shows the concepts of transforming the arterial area to be a pedestrian-friendly space and emphasizing green landscape, mixed land use. Furthermore, divergent preference of different groups were analyzed and found that students concentrate the transportation capability of arterial, experts and government planning departments focus on the pedestrian space of arterial, government’s transportation departments emphasize both on the car-lanes and pedestrian space. Research result construct a objective framework and review process for evaluating major arterial and also generate a best transforming scheme of those two roads, can be as a reference basis for urban re-design work of city government.

Human hair profiling is an integral part of a forensic investigation but it is one of the most technically difficult subjects in forensic science. This thesis describes the research and development of a novel approach for the rapid identification of unknown human and other related keratin fibres found at a crime scene. The work presented here is developed systematically and considers sample collection, sample preparation, analysis and interpretation of spectral data for the profiling of hair fibres encountered in criminal cases. Spectral comparison of fibres was facilitated with the use of chemometrics methods such as PCA, SIMCA and Fuzzy Clustering, and the less common approach of multi-criteria decision making methodology (MCDM). The aim of the thesis was to investigate the potential of some vibrational spectroscopy techniques for matching and discrimination of single keratin hair fibres in the context of forensic evidence. The first objective (chapter 3) of the thesis was to evaluate the use of Raman and FT-IR micro-spectroscopy techniques for the forensic sampling of hair fibres and to propose the preferred technique for future forensic hair comparisons. The selection of the preferred technique was based on criteria such as spectral quality, ease of use, rapid analysis and universal application to different hair samples. FT-IR micro-spectroscopy was found to be the most appropriate technique for hair analysis because it enabled the rapid collection of spectra from a wide variety of hair fibres. Raman micro-spectroscopy, on the other hand, was hindered with fluorescence problems and did not allow the collection of spectra from pigmented fibres. This objective has therefore shown that FT-IR micro-spectroscopy is the preferable spectroscopic technique for forensic analysis of hair fibres, whilst Raman spectroscopy is the least preferred. The second objective (chapter 3) was to investigate, through a series of experiments, the effect of chemical treatment on the micro-environment of human hair fibres. The effect of bleaching agents on the hair fibres was studied with some detail at different treatment times and the results indicate a significant change in the chemical environment of the secondary structure of the hair fibre along with changes in the C-C backbone structure. One of the most important outcomes of this research was the behaviour of the fÑ-helix during chemical treatment. The hydrogen bonding in the fÑ-helix provides for the stable structure of the fibre and therefore any disruption to the fÑ-helix will inevitably damage the molecular structure of the fibre. The results highlighted the behaviour of the fÑ-helix, which undergoes a significant decrease in content during oxidation, and is partly converted to a random-coil structure, whilst the fÒ-sheet component of the secondary structure remains unaffected. The reported investigations show that the combination of FT-IR and Raman micro-spectroscopy can provide an insight and understanding into the complex chemical properties and reactions within a treated hair fibre. Importantly, this work demonstrates that with the aid of chemometrics, it is possible to investigate simultaneously FT-IR and Raman micro-spectroscopic information from oxidised hair fibres collected from one subject and treated at different times. The discrimination and matching of hair fibres on the basis of treatment has potential forensic applications. The third objective (chapter 4) attempted to expand the forensic application of FT-IR micro-spectroscopy to other keratin fibres. Animal fibres are commonly encountered in crime scenes and it thus becomes important to establish the origin of those fibres. The aim of this work was to establish the forensic applications of FT-IR micro-spectroscopy to animal fibres and to investigate any fundamental molecular differences between these fibres. The results established a discrimination between fibres consisting predominantly of fÑ-helix and those containing mainly a fÒ-sheet structure. More importantly, it was demonstrated through curve-fitting and chemometrics, that each keratin fibre contains a characteristic secondary structure arrangement. The work presented here is the first detailed FT-IR micro-spectroscopic study, utilising chemometrics as well as MCDM methods, for a wide range of keratin fibres, which are commonly, found as forensic evidence. Furthermore, it was demonstrated with the aid of the rank ordering MCDM methods PROMETHEE and GAIA, that it is possible to rank and discriminate keratin fibres according to their molecular characteristics obtained from direct measurements together with information sourced from the literature. The final objective (chapter 5) of the thesis was to propose an alternative method for the discrimination and matching of single scalp human hair fibres through the use of FT-IR micro-spectroscopy and chemometrics. The work successfully demonstrated, through a number of case scenarios, the application of the technique for the identification of variables such as gender and race for an unknown single hair fibre. In addition, it was also illustrated that known hair fibres (from the suspect or victim) can be readily matched to the unknown hair fibres found at the crime scene. This is the first time that a substantial, systematic FT-IR study of forensic hair identification has been presented. The research has shown that it is possible to model and correlate individual¡¦s characteristics with hair properties at molecular level with the use of chemometrics methods. A number of different, important forensic variables of immediate use to police in a crime scene investigation such as gender, race, treatment, black and white hair fibres were investigated. Blind samples were successfully applied both to validate available experimental data and extend the current database of experimental determinations. Protocols were posed for the application of this methodology in the future. The proposed FT-IR methodology presented in this thesis has provided an alternative approach to the characterisation of single scalp human hair fibres. The technique enables the rapid collection of spectra, followed by the objective analytical capabilities of chemometrics to successfully discriminate animal fibres, human hair fibres from different sources, treated from untreated hair fibres, as well as black and white hair fibres, on the basis of their molecular structure. The results can be readily produced and explained in the courts of law. Although the proposed relatively fast FT-IR technique is not aimed at displacing the two slower existing methods of hair analysis, namely comparative optical microscopy and DNA analysis, it has given a new dimension to the characterisation of hair fibres at a molecular level, providing a powerful tool for forensic investigations.

Cette thèse vise à contribuer à la compréhension des cycle de vie d’une opération humanitaire (HOLC). Gestion de la chaîne d'approvisionnement humanitaire (HSCM) dans un contexte de mise en perspective et dans l’objectif de proposer un modèle décisionnel qui s'applique aux phases de HOLC lors d’une situation réelle. Cela inclut la mise en oeuvre du modèle proposé pour concevoir et développer un outil d'aide à la décision afin d'améliorer les performances de la logistique humanitaire tant dans les opérations de secours nationaux qu’internationaux.Cette recherche est divisée en trois phases. La première partie vise à présenter le sens de l'étude ; la zone de recherche prise en compte pour la gestion de la chaîne d'approvisionnement (SCM) doit être clairement définie. La première phase consiste à clarifier et définir le HSCM HL, la gestion de la chaîne d'approvisionnement commerciale (CSCM) et le SCM, ainsi que la relation entre ces différents éléments. La gestion du cycle de vie du projet (PLCM) et les différentes approches sont également présentés. La compréhension de la différence entre la gestion du cycle de vie du projet (PLM) et la PLCM est également nécessaire, cela ne peut être abordé dans la phase de cycle de vie de l'opération humanitaire. De plus, les modèles Multiple-Criteria Decision Making (MCDM) et l’aide à la décision concernant le HL sont analysés pour établir le fossé existant en matière de recherche. Les approches MCDM qui mettent en oeuvre le système d'aide à la décision (DSS) et la manière dont le MAS a été utilisé dans le contexte HSCM sont étudiées.La deuxième phase consiste en la proposition d’un modèle décisionnel fondé sur l’approche MCDM à l'appui de la décision du décideur avant qu'il/elle prenne des mesures. Ce modèle prévoit le classement des alternatives concernant l'entrepôt, le fournisseur et le transport au cours des phases de HOLC. Le modèle décisionnel proposé est réalisée en 3 scénarios. I. La décision en 4phases HOLC – opération de secours internationale de la Croix-Rouge Française (CRF). II. La décision en3phases HOLC – opération nationale dela Croix-Rouge thaïlandaise (TRC). III. La décision au niveau de la phase de réponse HOLC – opération internationale du TRC dans quatre pays. Dans cette phase, le scénario I et II sont réalisés étape par étape au travers de calculs numériques et formules mathématiques. Le scénario III sera présenté dans la troisième phase. Pour établir trois scénarios, les données internes recueillies lors des entretiens avec le chef de la logistique de la Croix-Rouge Française, et le vice-président de la fondation de la Coix-Rouge thaïlandaise, seront utilisées. Les données externes proviennent de chercheurs qui sont des experts dans le domaine HL ou le champ du HSCM, de la littérature, et de sources issues des organismes humanitaires (documents d’ateliers, rapports, informations publiées sur leurs sites officiels).Dans la troisième phase, une application Internet multi-critères (decision support system MCDSS WB) mettant en oeuvre le modèle proposé est élaborée. Afin d'atteindre une décision appropriée en temps réel, le WB-MCDSS est développé sur la base d’un protocole client-serveur et est simple à utiliser. Le dernier mais non le moindre ; une application de validation du modèle est réalisée à l'aide de l'approche de l'analyse de sensibilité. / This thesis aims to contribute to the understanding of HOLC in context of the HSCM and to propose a decision model which applies to the phases of HOLC the decision making regarding a real situation . This include the implementation of the proposed model to design and develop a decision support tool in order to improve the performance of humanitarian logistics in both national and international relief operations.This research is divided into three phases; the first phase is to clarify and define HL among HSCM, commercial supply chain management (CSCM) and SCM and their relationship. Project Life Cycle Management (PLCM) approaches are also presented. The difference between project life cycle management (PLM) and PLCM is also required to distinguish a clear understanding which can be addressed in the phase of humanitarian operation life cycle. Additionally, the literature of Multiple-Criteria Decision Making (MCDM) models and existing decision aid system for HL are analyzed to establish the research gap. The MCDM approaches which implement the decision support system (DSS) and lastly how DSS has been used in the HSCM context.The second phase is to propose a decision model based on MCDM approaches to support the decision of the decision maker before he/she takes action. This model provides the ranking alternatives to warehouse, supplier and transportation over the phases of HOLC. The proposed decision model is conducted in 3 scenarios; I. The decision in 4-phase HOLC, international relief operation of French Red Cross (FRC). II. The decision on 3-phase HOLC, national operation by the Thai Red Cross (TRC). III. The decision on response phase HOLC, international operation by the FRC in four countries. In this phase, the scenario I and II are performed step by step though numerical calculation and mathematical formulas. The scenario III will be presented in the third phase.In the third phase, an application of web-based multi-criteria decision support system (WB-MCDSS) which implement the proposed model is developed. The web-based multi-criteria decision support system is developed based on the integration of analytical hierarchy process (AHP) and TOPSIS approaches. In order to achieve an appropriate decision in a real time response, the WB-MCDSS is developed based on server-client protocol and is simple to operate. Last but not least, a validation application of the model is performed using the sensitivity analysis approach.

This thesis describes the role of cost effective maintenance in achieving competitive advantages. It explores by means of a survey which maintenance practices are used, and how maintenance policies are selected in Swedish industries. Also, it suggests a model for selecting the most cost effective maintenance policy, and how to improve the effectiveness of condition based maintenance decision-making. Finally it discusses how to assess the impact of maintenance practices on business strategic objectives. The main results achieved in the thesis are 1) A better understanding of maintenance organisation, management, systems and maintenance status in Swedish industry. For example, it was found that about 70% of Swedish companies still consider maintenance as a cost centre. Preventive and predictive maintenance approaches are also emphasised. 2) Most Swedish firms, i.e. about 81%, use the accumulated knowledge and experience within the company as a method for maintenance selection. Besides, about 31% use a method based on modelling the time to failure and optimisation. About 10% use failure mode effect and criticality analysis (FMECA) and decision trees and only 2% use multiple criterion decision-making (MCDM). However, the most used maintenance selection method is not the one most satisfactory to its users. Furthermore, about 30% use a combination of at least two methods. 3) A practical model for selecting and improving the most cost effective maintenance policy was developed. It is characterised by incorporating all the strengths of the four methods used in industry. 4) A mechanistic model for predicting the value of vibration level was verified both at the lab and in a case study. 5) A model for identifying, assessing, monitoring and improving the economic impact of maintenance was developed and tested in a case study. Thus it was proved that maintenance is no longer a cost centre, but could be a profit-generating function. To achieve competitive advantages, companies should do the right thing, e.g. use the most cost effective maintenance policy, and they should do it right, e.g. ensure that they have the right competence. Furthermore, they should apply the never-ending improvement cycle, i.e. Plan-Do-Check-Act, which requires identifying problem areas by assessing the savings and profits generated by maintenance and monitoring the economic impact of the applied maintenance policy. Thus, they would know where investments should be allocated to eliminate the basic reasons for losses and increase savings. The major conclusion is that proper maintenance would improve the quality, efficiency and effectiveness of production systems, and hence enhances company competitiveness, i.e. productivity and value advantages, and long-term profitability.

En raison de la demande croissante d’énergie dans le monde et des nombreux dommages causés par l’utilisation des énergies fossiles, la contribution des énergies renouvelables a augmenté de manière significative dans le mix énergétique global dans le but de progresser vers un développement plus durable. Dans ce contexte, ce travail vise à l’élaboration d’une méthodologie générale pour la conception de systèmes photovoltaïques, basée sur les principes d’écoconception, en tenant compte simultanément des considérations technico-économiques et environnementales. Afin d’évaluer la performance environnementale des systèmes PV, une technique d’évaluation environnementale basée sur l’Analyse du Cycle de Vie (ACV) a été utilisée. Le modèle environnemental a été couplé d’une manière satisfaisante avec le modèle de conception d’un système PV connecté au réseau pour obtenir un modèle global, apte à un traitement par optimisation. Le modèle de conception du système PV résultant a été développé en faisant intervenir l’estimation du rayonnement solaire reçu dans une zone géographique concernée, le calcul de la quantité annuelle d’énergie produite à partir du rayonnement solaire reçu, les caractéristiques des différents composants et l’évaluation des critères technico-économiques à travers le temps de retour énergétique et le temps de retour sur investissement. Le modèle a ensuite été intégré dans une boucle d’optimisation multi-objectif externe basée sur une variante de l’algorithme génétique NSGA-II. Un ensemble de solutions du Pareto a été généré représentant le compromis optimal entre les différents objectifs considérés dans l’analyse. Une méthode basée sur une Analyse en Composantes Principales (ACP) est appliquée pour détecter et enlever les objectifs redondants de l’analyse sans perturber les caractéristiques principales de l’espace des solutions. Enfin, un outil d’aide à la décision basé sur M- TOPSIS a été utilisé pour sélectionner l’option qui offre un meilleur compromis entre toutes les fonctions objectifs considérées et étudiées. Bien que les modules photovoltaïques à base de silicium cristallin (c-Si) ont une meilleure performance vis-à-vis de la production d’énergie, les résultats ont montré que leur impact environnement est le plus élevé des filières technologiques de production de panneaux. Les technologies en « couches minces » présentent quant à elles le meilleur compromis dans tous les scénarios étudiés. Une attention particulière a été accordée aux processus de recyclage des modules PV, en dépit du peu d’informations disponibles pour toutes les technologies évaluées. La cause majeure de ce manque d’information est la durée de vie relativement élevée des modules photovoltaïques. Les données relatives aux procédés de recyclage pour les technologies basées sur CdTe et m-Si sont introduites dans la procédure d’optimisation par l’écoconception. En tenant compte de la production d’énergie et du temps de retour sur énergie comme critères d’optimisation, l’avantage de la gestion de fin de vie des modules PV a été confirmé. Une étude économique de la stratégie de recyclage doit être considérée et étudiée afin d’avoir une vision plus globale pour la prise de décision. / Because of the increasing demand for the provision of energy worldwide and the numerous damages caused by a major use of fossil sources, the contribution of renewable energies has been increasing significantly in the global energy mix with the aim at moving towards a more sustainable development. In this context, this work aims at the development of a general methodology for designing PV systems based on ecodesign principles and taking into account simultaneously both techno-economic and environmental considerations. In order to evaluate the environmental performance of PV systems, an environmental assessment technique was used based on Life Cycle Assessment (LCA). The environmental model was successfully coupled with the design stage model of a PV grid-connected system (PVGCS). The PVGCS design model was then developed involving the estimation of solar radiation received in a specific geographic location, the calculation of the annual energy generated from the solar radiation received, the characteristics of the different components and the evaluation of the techno-economic criteria through Energy PayBack Time (EPBT) and PayBack Time (PBT). The performance model was then embedded in an outer multi-objective genetic algorithm optimization loop based on a variant of NSGA-II. A set of Pareto solutions was generated representing the optimal trade-off between the objectives considered in the analysis. A multi-variable statistical method (i.e., Principal Componet Analysis, PCA) was then applied to detect and omit redundant objectives that could be left out of the analysis without disturbing the main features of the solution space. Finally, a decision-making tool based on M-TOPSIS was used to select the alternative that provided a better compromise among all the objective functions that have been investigated. The results showed that while the PV modules based on c-Si have a better performance in energy generation, the environmental aspect is what makes them fall to the last positions. TF PV modules present the best trade-off in all scenarios under consideration. A special attention was paid to recycling process of PV module even if there is not yet enough information currently available for all the technologies evaluated. The main cause of this lack of information is the lifetime of PV modules. The data relative to the recycling processes for m-Si and CdTe PV technologies were introduced in the optimization procedure for ecodesign. By considering energy production and EPBT as optimization criteria into a bi-objective optimization cases, the importance of the benefits of PV modules end-of-life management was confirmed. An economic study of the recycling strategy must be investigated in order to have a more comprehensive view for decision making.