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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
81

Ruído magnético de Barkhausen contínuo rotacional. / Continuous rotational magnetic Barkhausen noise.

Manuel Alfredo Caldas Morgan 10 May 2013 (has links)
Este trabalho apresenta os avanços no desenvolvimento de um novo método de ensaio não-destrutivo magnético. O método está baseado na técnica do Ruído Magnético de Barkhausen (RMB), particularmente em uma variante denominada Barkhausen Contínuo. O RMB é gerado devido à ação de um campo magnético variável magnetizante que produz mudanças abruptas e irreversíveis na estrutura magnética do material. Essas mudanças são influenciadas pela microestrutura e a distribuição de tensões dentro do mesmo. As medições podem ser usadas para construir uma distribuição bidimensional do RMB ao redor de um ponto fixo, cujo resultado irá refletir o nível de anisotropia magnética, usualmente indicando um eixo de fácil magnetização, parâmetro relevante dado que o comportamento da grande maioria de materiais ferromagnéticos de engenharia é usualmente anisotrópico. As mudanças no eixo de fácil magnetização podem indicar a presença de anomalias mecânicas ou abnormalidades no processo de fabricação e no caso da aplicação de uma tensão externa, podem refletir a magnitude e a direção da mesma. O presente trabalho descreve uma metodologia que faz uso de um campo magnético rotacional para obter sinais RMB relacionados ao angulo de giro, possibilitando a identificação da direção do eixo de fácil magnetização, ultrapassando as capacidades oferecidas pela técnica RMB convencional mediante o fornecimento de informação em tempo real, que permite a obtenção de um conjunto de parâmetros que quantificam a anisotropia magnética de uma amostra. A técnica foi usada para a detecção do eixo de fácil magnetização e o nível de anisotropia magnética em materiais diferentes devida aos efeitos do processo de fabricação. Posteriormente foi demonstrado que a técnica é capaz de monitorar a evolução da tensão uniaxial aplicada, obtendo curvas de calibração, sensíveis ao sentido de aplicação da tensão. Para o caso pouco estudado de amostras submetidas a tensões biaxiais, o uso da técnica do Barkhausen contínuo rotacional fez possível de verificar que as características morfológicas das medições de anisotropia magnética obtidas, guardam relação com a direção das tensões principais. Foi realizada uma avaliação do método aplicado para a medição dinâmica de anisotropia magnética em juntas soldadas, indicando estados de tensão e características microestruturais coerentes com as esperadas. O método tem a possibilidade de ser implementado para medições anisotropia magnética em alta resolução/alta velocidade. / This works presents the current advances on the development of a new method of magnetic non-destructive testing. The method is based on the magnetic Barkhausen noise (MBN), more specifically in one branch known as Continuous Barkhausen. MBN is produced due to the effect of a variable magnetic field, which causes abrupt and irreversible changes to the magnetic structure of the material. These changes are influenced by the microstructure of the material and the stress distributions within. Measurements can be used to construct a bi dimensional MBN distribution around a fixed point, which in turn will be a reflect of its magnetic anisotropy level, usually characterized by an easy axis of magnetization, an important parameter given that more often than not, the behavior of most engineering ferromagnetic materials is anisotropic. Variations of the easy axis could be the indication of mechanical anomalies or abnormalities that appear as a result of the fabrication process. If there is an external stress applied to the sample, it can provide information about its magnitude and direction. The present work describes a methodology which uses a precise rotating magnetic field in order to obtain MBN signals related to a given magnetization angle, making possible the finding of the easy axis, exceeding the limits of conventional MBN measurements by providing real time data which in turn will allow to infer a set of parameters that quantify the magnetic anisotropy of the sample. The proposed technique was successfully used to find both the easy axis and a quantitative level of magnetic anisotropy between different materials, consequence of the fabrication process. Subsequently, it was shown that the technique was able to perform a monitoring of the evolution of both uniaxial and biaxial applied stress, obtaining linear relationships (uniaxial case), sensitive to the direction of loading. In not so much studied case of biaxial loading, the use of the continuous rotational Barkhausen method made possible to observe that the morphologic characteristics of the magnetic anisotropy measurements bear a close resemblance to the direction of the principal stress field. An evaluation of the technique as a tool for the dynamic measurement of magnetic anisotropy on welded joints, indicating stress states and microstructural features coherent with the ones expected in this scenario. The method has the possibility of being implemented as a technique for high speed/high resolution measurements of magnetic anisotropy.
82

Études des propriétés magnétiques d'assemblées de nanoparticules de Co, FeRh et FeAu / Study of magnetic properties on assemblies of Co, FeRh and FeAu nanoparticles

Hillion, Arnaud 05 October 2012 (has links)
Les nano-aimants se situent à la limite entre le complexe moléculaire et l’état massif. D’un point de vue fondamental, les effets dus à la taille réduite du système et en particulier les effets de surface sont susceptibles de faire apparaitre de nouvelles propriétés. Ces propriétés peuvent être à l’origine de nouvelles applications dans des domaines comme le stockage d’information magnétique, la catalyse, la biotechnologie, le diagnostic médical ou l’énergie. Dans ce travail, des nanoparticules de 1,5 à 5 nm de diamètre ont été synthétisés par low energy cluster beam deposition (LECBD) puis encapsulées dans différentes matrices. Dans un premier temps, des systèmes modèles à base de nanoparticules de Cobalt fortement diluées dans différentes matrice ont été synthétisés dans l’optique de remonter le plus précisément aux propriétés intrinsèques des nano-aimants. La suite de ce travail a consisté à augmenter la concentration en nanoparticules dans ces échantillons afin de caractériser l’influence des interactions sur le comportement magnétique macroscopique des particules. Enfin, après l’élaboration d’outils permettant de déterminer précisément les propriétés de systèmes modèles, ceux-ci ont été appliqués à des systèmes bimétalliques à fort intérêts théorique et applicatif (FeRh et FeAu). Nous avons montré que, après recuit sous ultra-vide, les nanoparticules d’alliage FeRh en matrice de carbone présentent une transition de phase A1 vers B2 sans trace de pollution ni de coalescence. Cette transition a été mise en évidence structurellement par microscopie électronique à transmission haute résolution et magnétiquement par magnétométrie à SQUID et dichroïsme magnétique de rayons X. / Nanomagnets are at the limit between a molecular complex and the bulk state. From a fundamental standpoint, the effects due to the small size of the system and particularly the increasing surface to volume ratio are likely to bring about new properties. Nanoparticles have found numerous applications in areas such as magnetic information storage, catalysis, biotechnology, medical diagnostics and energy. In this work, nanoparticles of 1.5 to 5 nm in diameter were synthesized by low energy cluster beam deposition (LECBD) and encapsulated in different matrices. As a first step, model systems based on cobalt nanoparticles strongly diluted in different matrices were fabricated in order to study more precisely the intrinsic properties of the nanomagnets. The continuation of this work consisted in increasing the concentration of nanoparticles in order to characterize the influence of interactions on the macroscopic magnetic behavior of the particles. Finally, after the development of tools to accurately determine the properties of model systems, these tools have been applied to bimetallic systems of significant theoretical and applicative interest (FeRh and FeAu). In particular, this work shows that after annealing under ultrahigh vacuum, the FeRh alloy nanoparticles in a carbon matrix show a phase transition A1 to B2 with no trace of pollution or coalescence. This transition has been demonstrated structurally by high resolution transmission electron microscopy (HRTEM) and magnetically by SQUID magnetometry and X-ray magnetic dichroism (XMCD).
83

Étude du couplage magnétique dans des nanoparticules bimétalliques de FeRh et de CoTb / Investigation of magnetic coupling in bimetallic nanoparticles of FeRh and CoTb

Robert, Anthony 18 December 2017 (has links)
L'enregistrement magnétique sur disque dur est aujourd'hui le moyen le plus fiable pour stocker l'information. L'enregistrement perpendiculaire magnétique a permis de multiplier par dix la densité de stockage par rapport à l'enregistrement longitudinal. Mais cette diminution de la taille des bits d'information se heurte à une limite physique, dite « limite superparamagnétique », qui correspond à une instabilité thermique de l'aimantation. Afin de repousser cette limite, il convient donc de fabriquer des bits avec une forte anisotropie. Mais plus les grains ont une grande anisotropie magnétique plus le champ nécessaire pour l'écriture doit être important. L'intérêt d'avoir un matériau aux propriétés magnétiques ajustables prend ainsi tout son sens. En utilisant des matériaux aux énergies d'anisotropies facilement modifiables, il n'est donc pas nécessaire de faire évoluer les têtes d'écriture. C'est dans cette optique que nous avons choisi d'étudier deux systèmes bimétalliques. Le premier est un alliage entre un métal de transition (Co) et une terre-rare lourde (Tb). Le deuxième système combine un métal de transition (Fe) et un métal magnétiquement polarisable (Rh). Dans ce travail, nous présenterons les résultats obtenus sur des nanoparticules de Co80Tb20 et de Fe50Rh50 de moins de 10 nm de diamètre, préparées par MS-LECBD (« Mass Selected Low Energy Cluster Beam Deposition »). Les échantillons, sous forme de multicouches, sont obtenus par dépôts séquentiels d'agrégats et de _lm de carbone. Dans un premier temps, une caractérisation structurale (dispersion de taille, morphologie, composition, structure cristallographique) par microscopie électronique a été réalisé pour les deux systèmes. Dans un second temps, nous avons étudié les propriétés magnétiques de ces agrégats par magnétométrie SQUID et dichroïsme magnétique circulaire (x-ray magnetic circular dichroism (XMCD)). Nous verrons, dans le cas du CoTb, que la réduction de taille entraine de profonds changements de ses propriétés par rapport au massif, notamment au niveau du couplage entre les sous-réseaux magnétiques de Co et de Tb. Dans le cas du FeRh, après avoir montré qu'un traitement thermique permet d'obtenir des agrégats chimiquement ordonnées B2, nous verrons l'influence des effets de taille sur la transition métamagnétique caractérisant cet alliage / The magnetic data storage is the most reliable way to store information. The perpendicular recording multiplied the storage density by ten with respect to the longitudinal recording. However, this reduction in the size of the information bits comes up against a physical limit, called the "superparamagnetic limit", which corresponds to a thermal instability of the magnetization. In order to push back this limit, it is therefore necessary to manufacture bits with strong anisotropy. But the more the grains have a large magnetic anisotropy the greater the field needed for writing must be. Thus, it's a great advantage of having a material with adjustable magnetic properties. By using materials with easily modifiable anisotropy energies, it is therefore not necessary to change the writing heads. It is with this in mind that we have chosen to study two bimetallic systems. The first is an alloy between a transition metal (Co) and a heavy earth-rare (Tb). The second system combines a transition metal (Fe) and a magnetically polarizable metal (Rh). In this work, we present results obtained on nanoparticles of Co80Tb20 and Fe50Rh50 of less than 10 nm in diameter, prepared by MS LECBD ("Mass Selected Low Energy Cluster Beam Deposition"). The samples, in the form of multilayers, are obtained by sequential deposition of nanoparticles and carbon _lm. First, a structural characterization (size dispersion, morphology, composition, crystallographic structure) by electron microscopy was carried out for both systems. Secondly, we have studied the magnetic properties of these nanoparticles by SQUID magnetometry and magnetic circular dichroism (XMCD). We will see, in the case of CoTb that the reduction in size leads to profound changes in its properties with respect to the massif, especially in the coupling between the magnetic sub-lattices of Co and Tb. In the case of FeRh, after having shown that a heat treatment makes it possible to obtain chemically ordered nanoparticles B2, we will see the influence of the size effects on the metamagnetic transition characterizing this alloy
84

Magnetic and structural properties of size-selected FeCo nanoparticle assemblies / Propriétés magnétiques et structurales d’assemblées de nanoparticules de FeCo triées en taille

Khadra, Ghassan 25 September 2015 (has links)
Dans ce travail, nous nous sommes intéressés aux propriétés magnétiques intrinsèques (moments et anisotropie magnétiques) de nanoparticules bimétalliques fer-cobalt. Pour cela, des agrégats FeCo dans la gamme de taille 2-6 nm ont été préparés en utilisant la technique MS-LECBD (Mass Selected Low Energy Cluster Beam Deposition) et enrobés en matrice in − situ afin de les séparer, d'éviter leur coalescence pendant les recuits et de les protéger à leur sortie à l'air. Dans un premier temps, les propriétés structurales (dispersion de taille, morphologie, composition, structure cristallographique) ont été étudiées en vue de corréler directement les modifications des caractéristiques magnétiques des nanoparticules, à leur structure et à l'ordre chimique obtenu après traitement thermique haute température. D'autre part, pour mettre en évidence les effets d'alliages à cette échelle, des références d'agrégats purs de fer et de cobalt ont été fabriquées et étudiées en utilisant les mêmes techniques. Par microscopie électronique en transmission à haute résolution, diffraction anomale et absorption de rayons X (high resolution transmission electron microscopy (HRTEM), anomalous x-ray diffraction (AXD) and extended x-ray absorption fine structure (EXAFS), nous avons mis en évidence un changement structural depuis une phase A2 chimiquement désordonnée vers une phase B2 type CsCl chimiquement ordonnée. Cette transition a été validée par nos résultats obtenus par magnétomètrie SQUID et dichroïsme magnétique circulaire (x-ray magnetic circular dichroism (XMCD)) / Over the past few decades, use of nanostructures has become widely popular in the different field of science. Nanoparticles, in particular, are situated between the molecular level and bulk matter size. This size range gave rise to a wide variety physical phenomena that are still not quite understood. Magnetic nanoparticles are at their hype due to their applications in medical field, as a catalyst in a wide number of chemical reactions, in addition to their use for information storage devices and spintronics. In this work, we are interested in studying the intrinsic magnetic properties (magnetic moments and anisotropy) of FeCo nanoparticles. Thus, in order to completely understand their properties, mass-selected FeCo nanoparticles were prepared using the MS-LECBD (Mass Selected Low Energy Cluster Beam Deposition) technique in the sizes range of 2-6 nm and in − situ embedded in a matrix in order to separate them, to avoid coalescence during the annealing and to protect during transfer in air. From a first time, the structural properties (size, morphology, composition, crystallographic structure) of these nanopar- ticles were investigated in order to directly correlate the modification of the magnetic properties to the structure and chemical ordering of the nanoparticles after high temperature treatment. In addition to the bimetallic FeCo nanoparticles, reference Fe and Co systems were also fabricated and studied using the same techniques. The structural properties were investigated using high resolution transmission electron microscopy (HRTEM), anomalous x-ray diffraction (AXD) and extended x-ray absorption fine structure (EXAFS) where a phase transition from a disordered A2 phase to a chemically ordered CsCl B2 phase was observed and further validated from the magnetic findings using SQUID magnetometry and x-ray magnetic circular dichroism (XMCD)
85

Étude ab initio de molécules aimants à base d'ions lanthanides / Ab initio study of lanthanide-based single molecule magnets

Jung, Julie 25 September 2015 (has links)
Les ions lanthanide sont employés avec succès pour la synthèse de molécules-aimants caractérisées par une relaxation lente du moment magnétique d’origine purement moléculaire. Ces propriétés sont principalement liées à la forte anisotropie intrinsèque de ces ions, ainsi qu’à leur moment magnétique intense. Dans le cas de complexes contenant plusieurs porteurs de spin (métaux 3d, 4f ou radicaux organiques), la proximité de ces centres peut induire entre ces derniers une interaction de couplage aussi appelée échange magnétique. La rationalisation de telles propriétés est notamment rendue possible par l’approche ab initio. / Lanthanide ions have been used successfully in the synthesis of single molecule magnets for more than a decade. This particular class of molecules shows slow relaxation of their magnetization from purely molecular origin. This property come mainly from the strong single ion anisotropy of these ions, and from their high magnetic moment. In the case of complexes with more than one spin carrier (3d, 4f metal or organic radical), coupling interactions can arise. These are called magnetic exchange. In this framework, ab initio calculations are a useful tool for magneto-structural correlations.
86

Co(II) Based Magnetic Systems. Part I Spin Crossover Systems and Dendritic Frameworks. Part II Co(II) Single Molecule Magnets.

Farghal, Ahmed M. S. January 2012 (has links)
This work comprises two main parts. The first part outlines our efforts to expand on the recent work of Gütlich et.al. by synthesizing Co(II) based spin crossover systems within a dendritic framework. We wanted to investigate the possibility of synthesizing different first generation, triazole containing dendrimers using “click” type reactions and their coordination ability with Co(II) ions. To this end we have had limited success mainly due to the numerous challenges in synthesizing a pure dendrimer product. The second part details our efforts in the synthesis of a mononuclear Co(II) based single molecule magnet. This comes as an extension to recent reports by Chang and Long where they have successfully obtained mononuclear Fe(II) single molecule magnets by inducing structural distortions within the complexes to amplify the spin-orbit coupling. We postulated that the use of Co(II) in conjunction with a bulky ligand framework would lead to desirable magnetic properties. We chose the known bis(imino)pyridine ligand scaffold due to its rich chemistry and its interesting and unexpected coordination behaviour, as we have seen in previous research efforts by our lab. To this end we were successful in isolating and characterizing 4 compounds, and we have carried out detailed magnetic measurements on the two most magnetically interesting species.
87

Etudes des relations magnéto-structurales dans les composés à base moléculaire par diffusion des neutrons : des molécules individuelles aux nanoparticules / Studies of magneto-structural relationships in molecule-based compounds by neutron diffusion : from individual molecules to nanoparticles

Ridier, Karl 17 November 2014 (has links)
Un des enjeux majeurs dans le domaine du magnétisme moléculaire est de mieux comprendre et prévoir, dans les composés à base moléculaire, les corrélations qui existent entre les propriétés structurales (modulables à partir de méthodes de synthèse de type « bottom-up ») et les propriétés magnétiques. En particulier, la compréhension et la maîtrise de l’anisotropie magnétique à l’échelle locale est primordiale, notamment en vue de concevoir des molécules-aimants avec de plus hautes températures de blocage. Dans ce contexte, ce travail de thèse s’organise autour de deux grands axes. La première partie se concentre sur la détermination et la caractérisation de l’anisotropie magnétique locale dans des complexes moléculaires d’ions de transition de faible nucléarité. La diffraction de neutrons polarisés (PND) nous a permis, pour la première fois, de mettre clairement en évidence le tenseur de susceptibilité magnétique locale dans un complexe moléculaire mononucléaire de Fe3+ Bas-Spin ainsi que dans deux complexes, mononucléaire et dinucléaire, de Co2+ Haut-Spin. Cette approche novatrice mène à l’établissement de relations magnéto-structurales claires et directes, en reliant les directions magnétiques locales propres à l’environnement de coordination des ions métalliques et en particulier aux axes locaux de distorsion. Nous avons également mené l’étude originale d’un complexe à transition de spin thermo-induite de Mn3+ par diffusion inélastique de neutrons (INS) dans les deux phases Haut-Spin (HS) et Bas-Spin (BS). Cette étude nous a conduits à la proposition d’un modèle d’hamiltonien de spin anisotrope dans les deux états HS et BS, en relation avec la structure du complexe. Dans une seconde partie plus exploratoire de la thèse, nous avons mené une étude complète des propriétés structurales et magnétiques de nanoparticules ferromagnétiques d’analogue du bleu de Prusse CsNiCr, par diffusion de neutrons aux petits angles (SANS). Les effets de taille, d’organisation et de concentration sur leurs propriétés superparamagnétiques ont ainsi été clairement mis en évidence. En particulier, nous avons mis en exergue, pour les particules de plus petite taille (5 nm de diamètre), une contribution magnétique qui résulte de la manifestation d’un phénomène collectif, tandis que celles de plus grande taille (28 nm de diamètre) apparaissent être dans un état complètement multidomaine. / One of the major issues in the field of molecular magnetism is to better understand and predict the correlations between the structural properties of molecule-based compounds and their magnetic properties, all of which may be tunable using “bottom-up” synthesis methods. In particular, the understanding and control of the magnetic anisotropy at the atomic scale is essential, especially with the aim to design Single-Molecule Magnets (SMM) with higher blocking temperatures. In this context, this thesis work is focused on two mains subjects. The first part deals with the determination and the characterization of the local magnetic anisotropy in low-nuclearity molecular complexes based on transition ions. Polarised neutron diffraction (PND) allows us, for the first time, to directly access the local susceptibility tensor in a Low-Spin Fe3+ mononuclear complex as well as in two, mononuclear and dinuclear, High-Spin Co2+ complexes. This innovative approach leads to the establishment of unique and direct magneto-structural correlations, by relating the local magnetic principal directions with the coordination environment of the metallic ions and, in particular, with the local distortion axes. We have also carried out an original investigation by inelastic neutron scattering (INS) of a Mn3+ thermo-induced spin-transition compound in both High-Spin (HS) and Low-Spin (LS) states. On the basis of this study, we were able to propose an anisotropic spin-Hamiltonian model in both HS and LS phases, and their relationships with the structure of the molecule are discussed. In a second more exploratory part of the thesis, we have carried out by small-angle neutron scattering (SANS) a complete study of the structural and magnetic properties of Prussian blue analogues (PBA) ferromagnetic nanoparticles CsNiCr. The effects of size, organization and concentration on their superparamagnetic properties have been clearly highlighted. In particular, a strong magnetic contribution has been observed for the smallest particles (5 nm diameter) which results from the manifestation of a collective process, while the biggest (28 nm diameter) appear to be in a multi-domain state.
88

Syntheses, Crystal Structures and Characterizations of Mono- and Polynuclear Ni- and Co-based Molecular Magnets / Synthèses, structures cristallines et caractérisations d'aimants moléculaires mono- et polynucléaires à base de Ni et de Co

Wang, Yiting 26 July 2019 (has links)
L’objectif consistant à élaborer des «aimants par conception» peut être atteint en adaptant les structures moléculaires des complexes de coordination. Les molécules conçues devraient présenter les caractéristiques requises pour des applications spécifiques, qui résultent de leur riche diversité structurale. Des complexes mononucléaires à base de Ni avec une grande anisotropie magnétique et des molécules polynucléaires à base de Ni et de Co sont préparés et étudiés dans cette thèse. Les synthèses, les études magnétiques et les propriétés électrochimiques des complexes contenant un ligand pontant non innocent sont étudiées. Les complexes mononucléaires Ni(II) à géométrie bipyramide trigonale sont préparés avec des ligands axiaux et les contre-anions différents. L'effet de la nature des ligands axiaux et du changement structural induit par les contre-anions sur l'anisotropie magnétique est étudié expérimentalement et analysé à l'aide de calculs théoriques. Des molécules organiques sont utilisées pour concevoir des complexes trinucléaires à grande anisotropie magnétique et à couplage d'échange faible. Plusieurs complexes polynucléaires à base de Ni et de Co où le TTC³⁻ agit comme un ligand pontant innocent et le HHTP³⁻ comme un ligand non innocent typique sont cristallisés avec diverses structures (TTC = Trithiocyanurate; HHTP = Hexahydroxytriphénylène). Pour les complexes contenant le ligand non innocent (HHTP), les anions radicalaires sont produits par électrochimie. La combinaison de la spectro-électrochimie et de la spectroscopie à résonance paramagnétique électronique couplée à des études d'électrochimie permet d'étudier la délocalisation des électrons sur les radicaux organiques générés et le couplage d'échange entre les ions métalliques. / The objective of elaborating “magnets by design” can be achieved by tailoring the molecular structures of coordination complexes. The designed molecules are expected to exhibit the characteristics required for specific applications, virtually resulting from their rich structural diversity. Mononuclear Ni-based complexes with large magnetic anisotropy and polynuclear Ni- and Co-based molecules are designed in this dissertation. The syntheses, magnetic studies, and electrochemical properties of the complexes containing non-innocent bridge ligand are investigated. The Ni(II) mononuclear complexes with trigonal bipyramid geometry are prepared by tuning the axial ligands and the counter anions. The effect of the nature of the axial ligands and the structural change induces by the counter anions on magnetic anisotropy is studied experimentally and analyzed with the help of theoretical calculations. Large organic molecules are used to design trinuclear complexes with large magnetic anisotropy and weak exchange coupling. Several polynuclear Ni- and Co-based complexes with TTC³⁻ acting as an innocent bridging ligand and HHTP as a typical non-innocent ligand, are crystallized with various structures (TTC = Trithiocyanurate; HHTP = Hexahydroxytriphenylene). For the complexes containing the non-innocent ligand (HHTP), radical anions are produced by electrochemistry. The combination of spectroelectrochemical and Electron Paramagnetic Spectroscopy coupled to electrochemistry studies allow investigating the delocalization of the electrons on the generated organic radicals and the exchange coupling among the metal ions.
89

Fyzika rozhraní v magnetických nanostrukturách / Physics of interfaces in magnetic nano structures

Ohnoutek, Lukáš January 2017 (has links)
Modification of interfaces in nanostructures can significantly influence their overall properties. Magneto-optical spectroscopy and spectroscopic ellipsometry are ideal for studying these phenomena thanks to their in-depth sensitivity and contactless measurements. Two methods of nonreversible modification of magnetic properties, especially the magnetic anisotropy, are investigated. The measured spectral dependence of magneto-optical Kerr effect is compared to a theoretical calculation in order to determine the profile of the samples for different levels and methods of modification. In addition to this, ellipsometric measurements are performed on a device whose optical properties change by voltage application.
90

Magnetické a magnetoelastické vlastnosti f-d intermetalik s vysokým obsahem 3d kovů / Magnetic and magnetoelastic properties of f-d intermetallics with high content of 3d-metal

Gorbunov, Denis January 2014 (has links)
Fundamental magnetic properties have been studied in RFexAl12-x (R - heavy rare-earth element) compounds with the tetragonal crystal structure of the ThMn12 type. In the homogeneity range 4 ≤ x ≤ 6, exchange interactions and magnetocrystalline anisotropy of the Fe sublattice are significantly modified as found in LuFexAl12-x with non-magnetic Lu. With increasing Fe content, antiferromagnetic exchange interactions weaken and ferromagnetic strengthen. The change of the type of magnetic ordering occurs in the vicinity of x = 5. The Fe sublattice displays an easy-plane magnetic anisotropy that weakens with growing Fe concentration. RFe5Al7 compounds with magnetic R are highly anisotropic ferrimagnets with Curie temperatures from 193 to 262 K. Spontaneous and field-induced magnetic phase transitions of anisotropic and exchange nature have been found in RFe5Al7 by measurements of magnetization and sound propagation. The transitions provide quantitative information on the R-Fe inter-sublattice exchange. A correlation between the R element and the fundamental magnetic properties has been found for RFe5Al7. The Fe magnetic moment is near 8 µB per formula unit. The compounds with R - Tb, Dy, Ho and Er have a compensation of the rare- earth and iron sublattice magnetizations. The compensation point and Curie...

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