Submitted by Jorge Silva (jorgelmsilva@ufrrj.br) on 2018-11-29T17:41:33Z No. of bitstreams: 1 2013 - Emerson Dalla Chieza.pdf: 3379954 bytes, checksum: 59d75d0f24fddc7d958c8e981de2274a (MD5) / Made available in DSpace on 2018-11-29T17:41:33Z (GMT). No. of bitstreams: 1 2013 - Emerson Dalla Chieza.pdf: 3379954 bytes, checksum: 59d75d0f24fddc7d958c8e981de2274a (MD5) Previous issue date: 2013-10-25 / The objective of this study was to establish an organic management form of corn and Crotalaria juncea intercropping, which allows to optimize production "in situ" by fabaceae plant biomass with nitrogen input to the system, without the competition that presence of green manure can to exercise, follow to compromise the performance of cereal. Three experiments were conducted in the experimental field of Embrapa Agrobiology in Serop?dica - RJ, between of November 2010 to March 2012. The experimental design was randomized blocks with six treatments and four replications (Experiments 1 and 3) or three replicates (experiment 2). The first experiment took place between November 2010 and March 2011 and had the following treatments: T1 - C. juncea seeded seven days before corn crop and managed at 33 days after emergence (33 DAE), T2 ? C. juncea seeded at the same date of corn sowing (29 DAE), T3 - C. juncea seeded 14 days after corn sown (102 DAE), T4 - C. juncea seeded 28 days after corn sown (88 DAE), T5 and T6 - corn cropping alone. Experiment 2: T1 - C. juncea seeds seven days before the corn (43 DAE), T2 - C. juncea seeded at the same date of corn sowing (37 DAE), T3 - C. juncea seeded seven days after corn sown (74 DAE), T4 - C. juncea seeded 14 days after corn sown (67 DAE), T5 and T6 - corn cropping alone. To first and second experiments, T3, T4 and T6 had been received 70 kg ha-1 of nitrogen by castor bean pie. Treatments of the third experiment consisted: T1 and T2 - C. juncea seeded at the same date of corn sowing (30 DAE) at the single row, T3 and T4 ? corn cropping alone at the single row, T5 and T6 - C. juncea seeded at the same date of corn sowing (30 DAE) at the double rows. For T2 and T6 treatments the green manure was managed and removed from the area, and had been added castor bean pie (70 kg of N ha-1). Also T4 received castor bean pie as a N source for corn. Also in the first experiment, for T1 and T2 trataments proceeded up studies of decomposition and release of nutrients from waste C. juncea by litter bags with 8 intervals collections. For the third test is conducted studies agronomic performance of corn and nitrogen losses through ammonia volatilization to waste C. juncea, castor bean pie and cattle manure through static cameras semi open. When corn sown simultaneously, regardless of the time of sowing, C. juncea did not affect the yield of cereal, promoted the addition of nitrogen to the system able of promoting positive balances for this nutrient. When the green manure was sown 7 days before or 14 days after sowing corn in the summer period, exerted a negative influence on growth and yield of maize. The waste C. juncea showed high rates of decomposition and nutrient release, with half-life for N less than 14 days. Were found discrepant emission rates for ammonia and castor bean pie residue C. juncea, with accumulated losses of about 46 and 14 %, respectively. The arrangement in double rows corn planting did not influence the yield of cereal. The results post the consortium in corn and C. juncea sown simultaneously as a promising culture system, capable of producing corn grain above the average yield of Rio of Janeiro state. / O objetivo geral deste trabalho foi estabelecer uma forma de manejo org?nico do cons?rcio entre as culturas de milho e Crotalaria juncea, que possibilite otimizar a produ??o ?In situ? de biomassa vegetal pela fabaceae, com aporte de nitrog?nio ao sistema, sem que a presen?a do adubo verde exer?a competi??o capaz de comprometer o rendimento do cereal. Foram conduzidos tr?s experimentos no campo experimental da Embrapa Agrobiologia em Serop?dica ? RJ, entre os meses de novembro de 2010 e mar?o de 2012. O delineamento experimental utilizado foi o de blocos ao acaso, com seis tratamentos e quatro repeti??es (experimentos 1 e 3) ou tr?s repeti??es (experimento 2). O primeiro experimento ocorreu entre novembro de 2010 e mar?o de 2011 e teve os seguintes tratamentos: T1?C. juncea semeada sete dias antes da cultura do milho e manejada aos 33 dias ap?s emerg?ncia (33 DAE); T2?C. juncea semeada simult?nea ao milho (manejo aos 29 DAE); T3?C. juncea semeada 14 dias ap?s o milho (manejo aos 102 DAE) + 70 kg N ha-1; T4?C. juncea semeada 28 dias ap?s o milho (manejo aos 88 DAE) + 70 kg N ha-1; T5-milho em monocultivo e T6-milho em monocultivo + 70 kg N ha-1. Experimento 2 (abril a setembro de 2011): T1?C. juncea semeada sete dias antes da cultura do milho (manejo aos 43 DAE); T2?C. juncea semeada simult?nea ao milho (manejo aos 37 DAE); T3?C. juncea semeada sete dias ap?s o milho (manejo aos 74 DAE) + 70 kg N ha-1; T4?C. juncea semeada 14 dias ap?s o milho (manejo aos 67 DAE) + 70 kg N ha-1; T5- milho em monocultivo e T6?milho em monocultivo+ 70 kg N ha-1. Os tratamentos do 3? Experimento (novembro de 2011 a mar?o de 2012) consistiram em: T1-C. juncea semeada simult?nea ao milho em fila simples com manejo aos 30 DAE e a biomassa da C. juncea mantida na ?rea; T2?C. juncea semeada simult?nea ao milho em fila simples com manejo aos 30 DAE com remo??o da parte a?rea de C. juncea e aplica??o de 70 kg N ha-1 via torta de mamona; T3- milho monocultivo em fila simples; T4 ?milho monocultivo em fila simples + 70 kg N ha-1; T5- C. juncea semeada simult?nea ao milho em fila dupla com manejo aos 30 DAE e a biomassa da C. juncea mantida na ?rea; T6 ? C. juncea semeada simult?nea ao milho em fila dupla com remo??o da parte a?rea de C. juncea e aplica??o de 70 kg N ha-1. Para todos os experimentos, o nitrog?nio aplicado em cobertura teve como fonte a torta de mamona. Nos dois primeiros ensaios foram realizados estudos morfofisiol?gicos dos cultivos a partir da an?lise funcional do crescimento de plantas, al?m do balan?o monet?rio e balan?o aparente de nitrog?nio. Tamb?m no experimento I, para T1 e T2, procederam-se estudos de decomposi??o e libera??o de nutrientes dos res?duos de C. juncea via sacolas de decomposi??o, com 8 intervalos de coletas. Para o terceiro ensaio procederam-se estudos de desempenho agron?mico do milho, an?lise econ?mica e balan?o de nitrog?nio. Tamb?m foram feitos estudos das perdas de nitrog?nio via volatiliza??o de am?nia para res?duos de C. juncea, torta de mamona e esterco bovino, atrav?s de c?meras est?ticas semi abertas em oito intervalos de coleta. Quando semeada simultaneamente ao milho, independente da ?poca de semeadura, a C. juncea n?o comprometeu o rendimento do cereal, promoveu a adi??o de nitrog?nio ao sistema capaz de promover balan?os positivos para este nutriente. Quando o adubo verde foi semeado 7 dias antes ou 14 dias ap?s a semeadura do milho, no per?odo de ver?o, esse exerceu influ?ncia negativa no crescimento e na produ??o de gr?os do milho. Os res?duos de C. juncea apresentaram elevadas taxas de decomposi??o e libera??o de nutrientes, com tempo de meia vida para N de menos de 14 dias. Foram encontradas discrepantes taxas de emiss?o de am?nia para torta de mamona e res?duos de C. juncea, com perdas acumuladas de cerca de 46 e 14%, respectivamente. O arranjo em fileiras duplas de plantio de milho n?o influenciou no rendimento do cereal. Os resultados encontrados postam o cons?rcio em milho e C. juncea semeados simultaneamente como um promissor sistema de cultivo, capaz de proporcionar produ??o de gr?os de milho acima da m?dia produtiva do estado do Rio de Janeiro.

Made available in DSpace on 2014-12-17T15:07:04Z (GMT). No. of bitstreams: 1 MariaASM.pdf: 63217 bytes, checksum: 05be60dbf83ca4b7d547db7cb4c02508 (MD5) Previous issue date: 2008-04-14 / This work has as objective generality to make a multidimensional analysis in the genre journalistic assay, communicative genre that, beyond complex and multimodal, presents hybrid characteristics. Specifically, with the intention to propose defining criteria of the cited genre, this research looks for to establish differences and similarities between the assay and other genres of the same sphere, from the description and interpretation of used multimodal resources. The analysis of the formal, schematical and rhetorical resources identified in the formatting of the journalistic assay sample that the analyses are supported in the socio-semiotic and socio-rhetorical approaches. In the formal dimension, we contemplate elements that constitute design of the text, including the forms of representation from the typography, the colors, images, as well as the aspects communicative-linguistics: the modalization indices, the communicative operators and the category time; in the schematical dimension, we present the organizational structure, considering the rhetorical movements postulates for Swales (1990) and in the rhetorical dimension we observe the categories: who writes, for who it writes, on what it writes and where writes. The adopted methodologicals postulates are of qualitative nature and the procedure is documentary, data that in we are valid them written texts of this genre as analysis object. Corpus it is constituted by a composed sample for 14 extracted texts of a set of 173 propagated journalistic assays weekly for the magazine Veja, in the period between August of 2004 and January of 2008. The analysis of the data showed that the journalistic assay, object of this study, materializes through multiple symbolic representations and multiple subjects that turn since a small episode of the daily facts of great social relevance in the present time, of historical and cultural nature, nationwide or international. Used for the first time by Montaigne in 1580, to assign, in saying of the proper author, written fast on its life and historical events, which could nor be remembered later , the term `assay' was enriched with other specifications, of form to enclose the one that if they call scientific assay today, academic assay, journalistic assay and other types of specific assays. These denominations have to see with the enrollment of the members of diverse of practices communities, in virtue of the multiplicity of activities carried through in these spheres. The conclusions the one that we arrive had been the following ones: 1. the discursive genre is not a pure entity, in virtue of the multiplicity of situations where the sorts if insert in the social actions; 2. the institutions define the configuration of one definitive genre, also its proper assignment, since for backwards of all discursive genre a voice exists to discipline - institutional voice, and in the case of the assays for analyzed us, the institutional voice if it presents, really, as a defining trace; 3. the journalistic assay, for its multiple symbolic representations, multiple subjects and for passing explicit or implicit opinions of its author, resembles it other genres, being able, therefore, to be inserted in a colony of opinionatives genres / Este trabalho tem como objetivo geral fazer uma an?lise multidimensional no g?nero ensaio jornal?stico, g?nero discursivo que, al?m de complexo e multimodal, apresenta caracter?sticas h?bridas. Especificamente, com o intento de propor crit?rios definidores do referido g?nero, esta pesquisa procura estabelecer diferen?as e semelhan?as entre o ensaio e outros g?neros da mesma esfera, a partir da descri??o e interpreta??o de recursos multimodais utilizados. A an?lise dos recursos formais, esquem?ticos e ret?ricos identificados na formata??o do ensaio jornal?stico mostra que as an?lises se enquadram nas abordagens s?cio-semi?ticas e s?cio-ret?ricas. Na dimens?o formal, contemplamos elementos que constituem o design do texto, incluindo as formas de representa??o a partir da tipografia, das cores, imagens, bem como os aspectos ling??stico-discursivos: ?ndices de modaliza??o, os operadores discursivos e a categoria tempo; na dimens?o esquem?tica, apresentamos a estrutura organizacional, considerando os movimentos ret?ricos postulados por Swales (1990) e na dimens?o ret?rica observamos as categorias: quem escreve, para quem escreve, sobre o que escreve e onde escreve. Os postulados metodol?gicos adotados s?o de natureza qualitativa e o procedimento ? documental, dado que nos valemos de textos escritos desse g?nero como objeto de an?lise. O corpus ? constitu?do por uma amostra composta por 14 textos extra?dos de um conjunto de 173 ensaios jornal?sticos veiculados semanalmente pela revista Veja, no per?odo entre agosto de 2004 e janeiro de 2008. A an?lise dos dados mostrou que o ensaio jornal?stico, objeto desse estudo, materializa- se atrav?s de m?ltiplas representa??es simb?licas e m?ltiplos temas que versam desde um pequeno epis?dio do cotidiano a fatos de grande relev?ncia social na atualidade, de natureza hist?rica e cultural, de ?mbito nacional ou internacional. Empregado pela primeira vez por Montaigne em 1580, para designar, no dizer do pr?prio autor, escritos ligeiros sobre sua vida e sobre acontecimentos hist?ricos, os quais poderiam nem ser lembrados depois , o termo ensaio foi enriquecido com outras especifica??es, de forma a abranger o que se denominam hoje ensaio cient?fico, ensaio acad?mico, ensaio jornal?stico e outros tipos de ensaios espec?ficos. Essas denomina??es t?m a ver com o engajamento dos membros de comunidades de pr?ticas diversas, em virtude da multiplicidade de atividades realizadas nessas est?ncias. As conclus?es a que chegamos foram as seguintes: 1. o g?nero discursivo n?o ? uma entidade pura, em virtude da multiplicidade de situa??es em que os g?neros se inserem nas a??es sociais; 2. as institui??es definem a configura??o de um determinado g?nero, inclusive a sua pr?pria designa??o, visto que por tr?s de todo g?nero discursivo existe uma voz disciplinar a voz institucional e, no caso dos ensaios por n?s analisados, a voz institucional se apresenta, realmente, como um tra?o definidor; 3. o ensaio jornal?stico, por suas m?ltiplas representa??es simb?licas, m?ltiplos temas e por passar opini?es expl?citas ou impl?citas do seu autor, assemelha-se a outros g?neros, podendo, portanto, ser inserido em uma col?nia de g?neros opinativos

In the present thesis, two positive sense single-stranded RNA viruses have been used as models to understand the structure and function of viral-encoded proteins. One of them, Pepper Vein Banding Virus (PVBV; genus Potyvirus; family Potyviridae) is a flexuous, rod-shaped virus that encodes for a polyprotein of size ~340 kDa. The polyprotein undergoes proteolytic processing by viral-encoded proteases, of which Nuclear Inclusion-a Protease (NIa-Pro) is the major protease. It is a serine-like cysteine protease which cleaves between a Q/A or Q/S, present in the context of the heptapeptide recognition sequence. The temporal regulation of intermediates and mature proteins released by NIa-Pro cleavage is crucial for a successful infection. In the present study, histidine-tagged NIa-Pro, Viral Protein genome-linked (VPg), and the cleavage site mutant (E191A) VPg-Pro were over-expressed in E. coli and purified. The protease activity of NIa-Pro was monitored using an HPLC-based protease assay developed using a peptide substrate. NIa-Pro protease activity was found to get modulated upon interaction with VPg and upon undergoing phosphorylation. Both these events have been found to involve the face of NIa-Pro which contains the solvent-exposed Trp143. Mutational studies and molecular dynamics analyses provide evidence that this residue is buried upon interaction of NIa-Pro with VPg, and any perturbation of its orientation influences the active site Cys151 via an extensive interaction network. This interaction was found to enhance the velocity of NIa-Pro protease activity, especially if the two domains were present in trans (VPg+Pro). In addition, the main-chain –NH2 group of Trp143 was found to be hydrogen-bonded to the side chain –OH group of Ser129, the residue which was identified to undergo phosphorylation by host plant kinases. Interestingly, when the two domains were present in cis (E191A VPg-Pro), no phosphorylation was observed. Mutations of Ser129 (to phosphorylation-mimic Asp or phosphorylation-deficient Ala residues) which affected this H-bond were found to disturb Trp143 and Cys151 orientation, which drastically reduced the protease activity of NIa-Pro. Within the polyprotein, VPg is present at the N-terminus of NIa-Pro and the cleavage site between them is suboptimal (E/A). In the present study, VPg-Pro was shown to be covalently linked to the genomic RNA present in the virions. Interestingly, during purification, VPg could only be purified from the soluble when it was expressed at the N-terminus of NIa-Pro. A series of bioinformatics and biophysical analysis of VPg showed that PVBV VPg, like other potyviral VPgs, exists as a molten-globule. Moreover, while VPg was shown to harbour the Walker motifs, it was found to exhibit an ATPase activity only when it was present with the NIa-Pro (especially in cis). Lys47 and Asp88:Glu89 were found crucial for optimal activity. Over all the results demonstrated that there is a reciprocal modulation of structure and function of the VPg and NIa-Pro domains. These results can explain the possible significance of an impeded cleavage rate between the two domains of VPg-Pro during PVBV infection. The precursor, VPg-Pro, could offer the advantage of evading the inhibitory phosphorylation of NIa-Pro by the host, as well as drive certain viral processes by virtue of its ATPase activity. And subsequent cleavage of the domains and their trans interaction could offer a higher turnover rate which might assist sufficient CP production required for viral morphogenesis. Another virus, Tobacco Streak Virus (TSV) that belongs to the Ilarvirus genus of the Bromoviridae family is a spherical virus which forms pleiomorphic icosahedral virus particles. It has a tripartite genome and each RNA is encapsidated individually. In the present thesis, TSV was used as a model to understand the properties of its structural protein-the coat protein (CP), with the aim of deciphering TSV assembly process. Thus, the CP gene from TSV RNA 3 was cloned and over-expressed in E. coli. The coat protein thus expressed formed virus-like particles (VLPs), which could be disassembled into dimers using high CaCl2 concentrations. Reassembly of VLPs was possible from dimers even in the absence of any nucleic acid. Mutational analysis of the N-terminal disordered domain showed that 26 amino acid residues from the amino-terminus could be crucial for capsid heterogeneity while, zinc-binding domain was essential for assembly. Overall, the present study shows that the flexible W-C loop of PVBV NIa-Pro, the disordered N-terminal region of PVBV VPg and the disordered N-terminal region of TSV CP harbour residues crucial for regulation of protein function. Such regulatory elements would ultimately allow viruses to maintain a smaller protein number, and thus a smaller genome size.

El presente trabajo de investigación tiene como finalidad medir el impacto financiero de la aplicación de las definiciones establecidas de la NIA 315 (Identificación y valoración de los riesgos de incorrección material mediante el conocimiento de la entidad y de su entorno), en el proceso de cobranzas de las compañías de Seguros de Salud, en el distrito de San Isidro, en el año 2018. Durante el transcurso del presente trabajo, se ha aplicado una investigación mixta (cualitativa y cuantitativa). Asimismo, para el desarrollo de la metodología cualitativa se realizaron entrevistas a profundidad a especialistas sobre el tema, y para el desarrollo de la metodología cuantitativa se realizaron encuestas basadas en escalas de Likert y análisis de casos relacionados como complemento y refuerzo hacia nuestro tema. Con respecto a la validación de la hipótesis general y específica, se realizaron trabajos de campo, realizando encuestas dentro de las empresas del sector seguros de salud (EPS), localizadas en el distrito de San isidro; además, se tuvo que contactar y entrevistar a expertos. Finalmente, se desarrolló y aplicó un caso práctico para evaluar el impacto financiero del presente trabajo. Con los resultados obtenidos se llegó a la conclusión de que el procedimiento de la NIA 315 (Identificación y valoración de los riesgos de incorrección material mediante el conocimiento de la entidad y de su entorno), genera un impacto financiero positivo en el proceso de cobranzas. / The objective of this research is to determine the financial impact of the application of the concepts of the IAS 315 (Identification and assessment of material misstatement risks through knowledge of the entity and its environment) in the collection process of Health Insurance companies, in the district of San Isidro, during the year 2018. For the development of this investigation paper, we have conducted a mixed research (quantitative and qualitative). For which we used the Surveys with Likert Scales and the Case Analysis, while for the qualitative work we used the In-Depth Interviews to experts in the Field. To validate our general hypothesis and specific hypotheses, field work was carried out conducting surveys of people working in companies in the health insurance sector (EPS), located in the district of San Isidro; In addition, experts had to be contacted and interviewed. Finally, we developed a practical case to examine the financial impact of this investigation on the financial statements and it is concluded that the praxis of IAS 315 causes a positive financial impact. / Tesis

There is concern about the indoor environment in aircraft but few stud-ies exist on self-rated health (SRH) and respiratory symptoms among pilots. Occupational and non-occupational risk factors for SRH, respira-tory symptoms and other symptoms among commercial pilots were investigated in this thesis. One cohort study and one prevalence study were performed among pilots in one Scandinavian airline company. Fungal DNA, furry pet allergens and volatile organic compounds of microbial origin (MVOC) were measured on board. Cat (fel d1), dog (Can f1) and horse (Ecu cx) allergens were found in all dust samples and allergen levels were 27-75 times higher in aircraft with textile seats as compared to leather surfaces. The sum of MVOCs in the cabin air was 3.7 times higher than in homes in Uppsala and 2-methyl-1-butanol and 3-methyl-1-butanol concentrations were 15-17 times higher. Asper-gillus/Penicillium DNA and Aspergillus versicolor DNA were more common in aircraft with textile seats. One fifth reported SRH as poor or fair, 62% had fatigue, 46% overweight/obesity and 71% insomnia. Poor or fair SRH was associated with overweight/obesity, lack of exercise, insomnia, low sense of coherence (SOC) and high work demand. Re-covery from work was worse among those with insomnia and low social support at work. Fatigue was more common among young or female pilots and related to insomnia and high work demand. Pilots flying MD80 or Saab 2000 aircraft had less fatigue. Pilots exposed to environmental tobacco (ETS) on board had more eye symptoms and fatigue which were reduced after the ban of smoking (in 1997). Pilots with increased work demand developed more rhinitis, dermal symptoms and fartigue and those with decreased work control developed more eye symptoms. The incidence of doctors’ diagnosed asthma and atopy were 2.4 and 16.6 per 1000 person years, respectively. Pilots changing type of flight got more airway infections. Those reporting decreased work control had a higher incidence of atopy. Risk factors in the home environment included ETS, dampness or mould, window pane condensation in winter and living in houses built after 1975. In conclusion, SRH and respiratory health among pilots are associated with specific occupational and non-occupational risk factors.

Submitted by PPG Comunica??o Social (famecos-pg@pucrs.br) on 2018-04-24T10:42:22Z No. of bitstreams: 1 RAFAEL_ROSINATO_VALLES_TES.pdf: 4997803 bytes, checksum: 305c1c0d476913fdfc9c6514f3196432 (MD5) / Approved for entry into archive by Sheila Dias (sheila.dias@pucrs.br) on 2018-05-07T18:51:24Z (GMT) No. of bitstreams: 1 RAFAEL_ROSINATO_VALLES_TES.pdf: 4997803 bytes, checksum: 305c1c0d476913fdfc9c6514f3196432 (MD5) / Made available in DSpace on 2018-05-07T19:29:39Z (GMT). No. of bitstreams: 1 RAFAEL_ROSINATO_VALLES_TES.pdf: 4997803 bytes, checksum: 305c1c0d476913fdfc9c6514f3196432 (MD5) Previous issue date: 2018-03-19 / Coordena??o de Aperfei?oamento de Pessoal de N?vel Superior - CAPES / This thesis carries out a study of the diary in the work of Jonas Mekas, throughout three formats: the written diary, the diary-film and the video diary. The aim is to analyze how Mekas?s work contributes to an understanding of the diary as a narrative form, and how the author constructs his process of self-representation by means of the diaries. This work seeks to establish a definition for the diary, by means of theoretical references related to the spheres of literature (Braud, 2006; Simonet-Tenant, 2004; Girard, 1986; Lejeune, 2015; Blanchot, 2005) and of audiovisual work (James, 2013; Renov, 1996). As object of study, we analyze the book I had nowhere to go (1991), the diary-films Lost Lost Lost (1976), Walden ? Diaries, Sketches & Notes (1969), Reminiscences of a Journey to Lithuania (1972), and video diaries from the 365 Day Project (2007). This thesis takes weavings (Daney, 2007; Benjamin, 1994) and rends (Daney, 2007; Didi-Huberman, 2014, 2015) as its methodology, grounding itself on the way in which Mekas elaborates his narrative choices and his historical condition. We conclude that Mekas?s work points to an understanding of the diary not solely as literary genre, but as a narrative that affirms itself in a plurality of forms, following the shifts done by the author in his relation to time, space, and the use of different technical devices. We also conclude that Mekas, in his diaries, builds an intrinsic relation between narrating the lived and living the narrated, which reveals how the diaries not only document a certain socio-historical context, but are also themselves part of that context and of the subjectivity built by their author. / Esta tese realiza um estudo sobre o di?rio, que aparece na obra do cineasta Jonas Mekas em tr?s formatos: o di?rio escrito, o filme-di?rio e o v?deo-di?rio. O objetivo ? analisar como essa obra contribui para um entendimento sobre o di?rio enquanto forma narrativa e como o autor constr?i o seu processo de autorrepresenta??o por meio dos di?rios. Este trabalho procura construir uma defini??o de di?rio, a partir de referenciais te?ricos relacionados ao ?mbito liter?rio (Braud, 2006; Simonet-Tenant, 2004; Girard, 1986; Lejeune, 2015; Blanchot, 2005) e audiovisual (James, 2013; Renov, 1996). Como objetos de estudo, s?o analisados o livro I had nowhere to go (1991), os filmes-di?rio Lost Lost Lost (1976), Walden ? Diaries, Sketches & Notes (1969), Reminisc?ncias de uma viagem para a Litu?nia (1972) e os v?deos-di?rio pertencentes a 365 Day Project (2007). Esta tese assume como metodologia os conceitos de teceduras (Daney, 2007; Benjamin, 1994) e rasgaduras (Daney, 2007; Didi-Huberman, 2014, 2015), a partir da forma como Mekas realiza as suas escolhas narrativas e apresenta a sua condi??o hist?rica. Este trabalho conclui que a obra em pauta aporta um entendimento sobre o di?rio n?o somente como um g?nero liter?rio, mas como uma narrativa que se afirma na sua pluralidade de formas, de acordo com os deslocamentos que o autor efetua na sua rela??o com o tempo, com o espa?o e com o uso de diferentes dispositivos t?cnicos. Tamb?m conclui que Mekas constr?i, nos seus di?rios, uma rela??o intr?nseca entre narrar o vivido e viver o narrado, o que revela como os registros documentam um determinado contexto s?cio-hist?rico e, ainda, como esses registros fazem parte do pr?prio contexto e da subjetividade constru?da pelo seu autor.

Made available in DSpace on 2014-12-17T15:42:01Z (GMT). No. of bitstreams: 1 EdissonMJ.pdf: 6565731 bytes, checksum: 5d6fdd6db6fc25a30c6100d96fff1edc (MD5) Previous issue date: 2007-08-24 / TiTanate NanoTubes (TTNT) were synthesized by hydrothermal alkali treatment of TiO2 anatase followed by repeated washings with distinct degrees of proton exchange. TTNT samples with different sodium contents were characterized, as synthesized and after heattreatment (200-800?C), by X-ray diffraction, scanning and transmission electron microscopy, electron diffraction, thermal analysis, nitrogen adsorption and spectroscopic techniques like FTIR and UV-Vis diffuse reflectance. It was demonstrated that TTNTs consist of trititanate structure with general formula NaxH2−xTi3O7?nH2O, retaining interlayer water in its multiwalled structure. The removal of sodium reduces the amount of water and contracts the interlayer space leading, combined with other factors, to increased specific surface area and mesopore volume. TTNTs are mesoporous materials with two main contributions: pores smaller than 10 nm due to the inner volume of nanotubes and larger pores within 5-60 nm attributed to the interparticles space. Chemical composition and crystal structure of TTNTs do not depend on the average crystal size of the precursor TiO2-anatase, but this parameter affects significantly the morphology and textural properties of the nanostructured product. Such dependence has been rationalized using a dissolution-recrystallization mechanism, which takes into account the dissolution rate of the starting anatase and its influence on the relative rates of growth and curving of intermediate nanosheets. The thermal stability of TTNT is defined by the sodium content and in a lower extent by the crystallinity of the starting anatase. It has been demonstrated that after losing interlayer water within the range 100-200?C, TTNT transforms, at least partially, into an intermediate hexatitanate NaxH2−xTi6O13 still retaining the nanotubular morphology. Further thermal transformation of the nanostructured tri- and hexatitanates occurs at higher or lower temperature and follows different routes depending on the sodium content in the structure. At high sodium load (water washed samples) they sinter and grow towards bigger crystals of Na2Ti3O7 and Na2Ti6O13 in the form of rods and ribbons. In contrast, protonated TTNTs evolve to nanotubes of TiO2(B), which easily convert to anatase nanorods above 400?C. Besides hydroxyls and Lewis acidity typical of titanium oxides, TTNTs show a small contribution of protonic acidity capable of coordinating with pyridine at 150?C, which is lost after calcination and conversion into anatase. The isoeletric point of TTNTs was measured within the range 2.5-4.0, indicating behavior of a weak acid. Despite displaying semiconductor characteristics exhibiting typical absorption in the UV-Vis spectrum with estimated bandgap energy slightly higher than that of its TiO2 precursor, TTNTs showed very low performance in the photocatalytic degradation of cationic and anionic dyes. It was concluded that the basic reason resides in its layered titanate structure, which in comparison with the TiO2 form would be more prone to the so undesired electron-hole pair recombination, thus inhibiting the photooxidation reactions. After calcination of the protonated TTNT into anatase nanorods, the photocatalytic activity improved but not to the same level as that exhibited by its precursor anatase / Titanatos nanoestruturados, particularmente TiTanatos NanoTubulares (TTNT), foram sintetizados por tratamento hidrot?rmico alcalino de TiO2-anat?sio seguido de repetidas lavagens com diversos graus de troca prot?nica. Amostras de TTNT com diferentes teores de s?dio foram caracterizadas na forma de p? seco e ap?s calcina??o (200-800?C) por difra??o de raios-X, microscopia eletr?nica de varredura e transmiss?o, difra??o de el?trons, an?lise t?rmica, adsor??o de nitrog?nio e t?cnicas espectrosc?picas de infravermelho e de reflet?ncia difusa no UV-Vis?vel. Demonstrou-se que tais materiais de paredes multilamelares s?o trititanatos de f?rmula geral NaxH2−xTi3O7?nH2O, retendo ?gua entre as lamelas. A remo??o de s?dio da estrutura reduz a quantidade de ?gua contraindo o espa?o interlamelar levando, combinado a outros fatores, ao aumento da ?rea e do volume de poros espec?ficos. Os TTNTs s?o materiais mesoporosos com duas contribui??es principais: poros menores que 10 nm devido ao volume interno dos nanotubos e poros entre 5 e 60 nm devido aos espa?os interpart?cula. A composi??o qu?mica e a estrutura cristalina do TTNT n?o dependem do tamanho de cristalito do TiO2-anat?sio precursor, todavia este par?metro afeta significativamente a morfologia e as caracter?sticas texturais do produto nanoestruturado. Tal depend?ncia foi racionalizada atrav?s de um mecanismo de dissolu??o-recristaliza??o que leva em conta a velocidade de dissolu??o do TiO2 de partida e sua influ?ncia sobre a taxa de crescimento de nanofolhas intermedi?rias em rela??o ? taxa de seu curvamento a nanotubos. A estabilidade t?rmica do TTNT ? definida pelo teor de s?dio e em pequena extens?o pelo tipo de anat?sio de partida. Foi demonstrado que o TTNT ap?s perder a ?gua intercalada entre 100 e 200?C se transforma pelo menos parcialmente num hexatitanato NaxH2−xTi6O13 intermedi?rio ainda nanotubular. A transforma??o t?rmica do tri- e hexatitanato nanoestruturados ocorre em maior ou menor temperatura e segue diferentes rotas dependendo do teor de s?dio. No caso de alto s?dio sinterizam e crescem at? grandes cristais de Na2Ti3O7 e Na2Ti6O13 na forma de bast?es e fitas acima de 600?C. No caso da amostra protonizada evoluem para nanotubos de TiO2(B) que facilmente se convertem em nanobast?es de anat?sio acima de 400?C. Al?m de hidroxilas e acidez de Lewis t?picos dos ?xidos de tit?nio, os TTNTs apresentam uma pequena contribui??o de acidez prot?nica capaz de se coordenar com a piridina a 150?C, e que ? perdida ap?s sua calcina??o e transforma??o ? anat?sio. O ponto isoel?trico do TTNT variou dentro da faixa 2,5- 4,0, indicando o comportamento de um ?cido fraco. Apesar de se revelar um semicondutor exibindo banda de absor??o t?pica no espectro de UV-vis?vel com energia de bandgap ligeiramente superior ao do respectivo TiO2-anat?sio precursor, os TTNTs apresentaram baixo desempenho fotocatal?tico na degrada??o de corantes cati?nico e ani?nico. Concluiu-se que a causa fundamental reside em sua estrutura de titanato lamelar que, em rela??o ? forma TiO2, apresentaria maior probabilidade de recombina??o do par el?tron-lacuna (e-/h+), inibindo as rea??es de fotoxida??o. A transforma??o do TTNT prot?nico ? nanobast?es de anat?sio melhorou a atividade fotocatal?tica, por?m ainda sem atingir o mesmo desempenho do TiO2-anat?sio precursor

Made available in DSpace on 2014-12-17T15:46:59Z (GMT). No. of bitstreams: 1 PauloHAS_TESE.pdf: 9268945 bytes, checksum: 08c0c5f93ed7b964b99c6df2ee26ab1b (MD5) Previous issue date: 2011-12-19 / Coordena??o de Aperfei?oamento de Pessoal de N?vel Superior / The Car Rental Salesman Problem (CaRS) is a variant of the classical Traveling Salesman Problem which was not described in the literature where a tour of visits can be decomposed into contiguous paths that may be performed in different rental cars. The aim is to determine the Hamiltonian cycle that results in a final minimum cost, considering the cost of the route added to the cost of an expected penalty paid for each exchange of vehicles on the route. This penalty is due to the return of the car dropped to the base. This paper introduces the general problem and illustrates some examples, also featuring some of its associated variants. An overview of the complexity of this combinatorial problem is also outlined, to justify their classification in the NPhard class. A database of instances for the problem is presented, describing the methodology of its constitution. The presented problem is also the subject of a study based on experimental algorithmic implementation of six metaheuristic solutions, representing adaptations of the best of state-of-the-art heuristic programming. New neighborhoods, construction procedures, search operators, evolutionary agents, cooperation by multi-pheromone are created for this problem. Furtermore, computational experiments and comparative performance tests are conducted on a sample of 60 instances of the created database, aiming to offer a algorithm with an efficient solution for this problem. These results will illustrate the best performance reached by the transgenetic algorithm in all instances of the dataset / O Problema do Caixeiro Alugador (CaRS) ? uma variante ainda n?o descrita na literatura do cl?ssico Problema do Caixeiro Viajante onde o tradicional tour de visitas do caixeiro pode ser decomposto em caminhos cont?guos e que podem ser realizados em diferentes carros alugados. O problema consiste em determinar o ciclo hamiltoniano que resulte em um custo final m?nimo, considerando o custo da rota adicionado ao custo de uma prov?vel penaliza??o paga em cada troca de ve?culos na rota, penaliza??o devida ao retorno do carro descartado at? a sua cidade base. Sem perda para a generalidade do caso, os custos do aluguel do carro podem ser considerados embutidos nos custos da rota do carro. O presente trabalho introduz o problema geral e o exemplifica, caracterizando igualmente algumas variantes associadas. Uma an?lise geral da complexidade desse problema combinat?rio ? descrita, visando justificar sua classifica??o na classe NP-dif?cil. Um banco de inst?ncias para o problema ? apresentado, descrevendo-se a metodologia de sua constitui??o. O problema proposto tamb?m ? objeto de um estudo algor?tmico experimental baseado na aplica??o de seis metaheur?sticas de solu??o, representando adapta??es do melhor do estado da arte em programa??o heur?stica. Novas vizinhan?as, procedimentos construtivos, operadores de busca, agentes evolucion?rios, coopera??o por multiferom?nios, s?o criados para o caso. Experimentos computacionais comparativos e testes de desempenho s?o realizados sobre uma amostra de 60 inst?ncias, visando oferecer um algoritmo de solu??o competitivo para o problema. Conclui-se pela vantagem do algoritmo transgen?tico em todos os conjuntos de inst?ncias

Made available in DSpace on 2014-12-17T15:46:59Z (GMT). No. of bitstreams: 1 LauraEASS_TESE.pdf: 2447411 bytes, checksum: 3e442431965058383423623bc7751de0 (MD5) Previous issue date: 2012-02-02 / Conselho Nacional de Desenvolvimento Cient?fico e Tecnol?gico / Traditional applications of feature selection in areas such as data mining, machine learning and pattern recognition aim to improve the accuracy and to reduce the computational cost of the model. It is done through the removal of redundant, irrelevant or noisy data, finding a representative subset of data that reduces its dimensionality without loss of performance. With the development of research in ensemble of classifiers and the verification that this type of model has better performance than the individual models, if the base classifiers are diverse, comes a new field of application to the research of feature selection. In this new field, it is desired to find diverse subsets of features for the construction of base classifiers for the ensemble systems. This work proposes an approach that maximizes the diversity of the ensembles by selecting subsets of features using a model independent of the learning algorithm and with low computational cost. This is done using bio-inspired metaheuristics with evaluation filter-based criteria / A aplica??o tradicional da sele??o de atributos em diversas ?reas como minera??o de dados, aprendizado de m?quina e reconhecimento de padr?es visa melhorar a acur?cia dos modelos constru?dos com a base de dados, ao retirar dados ruidosos, redundantes ou irrelevantes, e diminuir o custo computacional do modelo, ao encontrar um subconjunto representativo dos dados que diminua sua dimensionalidade sem perda de desempenho. Com o desenvolvimento das pesquisas com comit?s de classificadores e a verifica??o de que esse tipo de modelo possui melhor desempenho que os modelos individuais, dado que os classificadores base sejam diversos, surge uma nova aplica??o ?s pesquisas com sele??o de atributos, que ? a de encontrar subconjuntos diversos de atributos para a constru??o dos classificadores base de comit?s de classificadores. O presente trabalho prop?e uma abordagem que maximiza a diversidade de comit?s de classificadores atrav?s da sele??o de subconjuntos de atributos utilizando um modelo independente do algoritmo de aprendizagem e de baixo custo computacional. Isso ? feito utilizando metaheur?sticas bioinspiradas com crit?rios de avalia??o baseados em filtro

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