“Idiomatic” expressions, usually called “idioms”, such as a dime a dozen, a busman’s holiday, or to have bats in your belfry are a curious part of any language: they usually have a fixed lexical (why a busman?) and structural composition (only dime and dozen in direct conjunction mean ‘common, ordinary’), can be semantically obscure (why bats?), yet are widely recognized in the speech community, in spite of being so rare that only large corpora can provide us with access to sufficient empirical data on their use. In this compilation thesis, four published studies focusing on idioms in corpora are presented. Study 1 details the creation of and data in the author’s medium-sized corpus from 1999, the 3.7 million word Coll corpus of online university student newspapers, with comparisons to data from standard corpora of the time. Study 2 examines the extent to which recognized idioms are to be found in the Coll corpus and how they can be varied. Study 3 draws upon the British National Corpus and a series of British and American newspaper corpora to see how idioms may be “anchored” in their contexts, primarily by the device of premodification via an adjective appropriate to the context, not to the idiom. Study 4 examines idiom-usage patterns in the Time Magazine corpus, focusing on possible aspects of diachronic change over the near-century Time represents. The introductory compilation chapter places and discusses these studies in their contexts of contemporary idiom and corpus research; building on these studies, it provides two specific examples of potential ways forward in idiom research: an examination of the idioms used in a specific subgenre of newspapers (editorials), and a detailed suggestion for teachers about how to examine multiple facets of a specific modern idiom (the glass ceiling) in the classroom. Finally, a summing-up includes suggestions for further research, particularly at the level of the patterning of individual idioms, rather than treating them as a homogeneous phenomenon.

In this thesis, two ultrasonic timing methods are used in order to investigate the accuracy and reliability of measurements for surface breaking cracks having different orientations and heights. Also the best applicable measurement technique is searched by comparing the received test results. These methods are the Time of Flight Diffraction (TOFD) Method using diffraction of longitudinal waves and another method using the reflection of shear waves from the crack tips. In order to simulate and measure the height of surface breaking cracks three sets of test blocks from steel, and two sets of wedges from plexiglas material are manufactured. Also several probes having frequencies of 2Mhz, 4Mhz, 5Mhz and angles of 45o and 70o are used. Some test procedures are created to make realistic comparisons between the test results and the ones found by previous studies in literature. The results are compared according to the standard deviations of errors in crack height measurements and it is found that the depth, orientation of defects and the frequency of probes have considerable affect on the results. With wider probe angles and higher frequencies of probes to some extent the errors are observed to be running low and the height of cracks could be measured closer to the original size. The amount of the errors is increased in measurements with the increasing angle of cracks. The results of both methods are found to be very satisfactory. A range of &plusmn / 0.5 mm for means of error from the original vertical crack heights is determined. The results agree with the previous studies.

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior / A Quebra Espontânea de Simetria (QES) tem sido discutida em muitos cenários, tendo resultados importantes na física Teórica de Partículas, sendo motivo de extensa pesquisa e com variadas aplicações. Neste trabalho, será apresentado um modelo alternativo baseado na Ação de Fujikawa usando quartetos BRST. No primeiro capítulo, todo o ferramental para a análise da QES é discutido partindo da definição em nível clássico e por fim no regime quântico, usando o conceito de ação efetiva. A técnica de quantização de campos de calibre no U(1), presente no eletromagnetismo, foi abordada, usando o cálculo dos propagadores e seus respectivos diagramas de Feynman. Foi estudado em conjunto com esse assunto, o conceito de campos fantasmas de Fadeev-Popov e Simetria-BRST. O mecanismo de Higgs é explorado em nível quântico, sendo feita um estudo dos rearranjos dos graus de liberdade do sistema. No segundo capítulo, as propriedades dos quartetos-BRST são estudadas, bem como suas considerações sobre simetria, quando aplicadas na ação de Fujikawa usando dois cenários: (i) quando a simetria não é quebrada. (ii) A simetria é quebrada. E por fim é feita uma análise sobre os graus de liberdade do sistema.

Les objectifs de notre travail étaient : (i) de proposer un nouveau cadre conceptuel pour l’entraînement bimanuel chez les patients hémiplégiques (ii) de concevoir et tester une nouvelle approche de rééducation basée sur l’équilibre entre les différentes contraintes. Afin d’atteindre ces objectifs, nous avons adopté une approche du type preuve-de-concept.La première partie de ce document est consacrée à une revue critique de la littérature. La deuxième partie présente le travail expérimental qui était mené pour explorer ce concept, chez des sujets sains et des patients hémiparétiques. La première étude a exploré le comportement unimanuel dans une tâche de pointage discret pour une large gamme de d’indices de difficulté (ID). Dans la seconde étude, nous avons exploré l’effet de l’asymétrie bimanuelle induite par la tâche sur l’expression du couplage. La troisième étude aborde la problématique des asymétries induites par l’AVC et par la tâche chez des patients soufrant de déficits plus ou moins graves. Globalement, les résultats expérimentaux ont corroboré nos hypothèses initiales. Ainsi, ils nous ont permis de concevoir une nouvelle stratégie de rééducation bimanuelle. Cette stratégie de rééducation, avec le protocole de recherche clinique en cours, ont été présentés dans la troisième partie de la thèse. Notre approche a fourni une preuve de concept sur l’importance de l’équilibre entre couplage et rupture de symétrie dans le comportement bimanuel du patient hémiplégique. Elle a permis également d’envisager la manière dont les asymétries devraient être prises en compte dans la rééducation. Les perspectives futures ont été discutées dans la dernière partie du manuscrit. / In the present work we aimed at: (i) setting new conceptual foundations for bimanual movement training in stroke, and (ii) providing practical guidelines to appropriately design and test a comprehensive constraint-led bimanual rehabilitation strategy. In order to achieve these stated objectives, we adopted a proof-of-concept approach.The first part of the current manuscript includes a critical review of BMT literature on the basis of the theoretical principles and empirical findings of the dynamical systems approach. The second part reports the experimental work that was conducted to investigate this concept in healthy and in hemiparetic subjects. The first study investigated unimanual discrete rapid aiming, under different task conditions and for a wide range ID values. In the second study, the effect of task-induced inter-limb asymmetry on the expression of bimanual coupling was explored. The third study, addressed the issue of task- and stroke-induced asymmetries in patients with different degrees of impairments. Overall, experimental findings corroborated our initial hypotheses. It permitted the design of a new BMT strategy to (re)train stroke patient. This rehabilitation strategy and the on-going clinical protocol were presented in the third part of the thesis.Though voluntarily qualitative, our approach provided a preliminary proof of concept on how CVA- and task-induced inter-limb asymmetries should be taken into account in rehabilitation. The conclusions of our work along with the opened perspectives were discussed at the end of the manuscript.

The site of initial metal-carbonyl bond-breaking during ligand-exchange reactions in a series of octahedral metal carbonyls of the type (L2)M(CO)4 (M = Cr, Mo, W; L2 = diphos, phen, dipy) has been determined employing infrared spectroscopy and Fourier transform nuclear magnetic resonance spectroscopy. The results of this study reveal, for all metal carbonyl complexes of the type mentioned above, that loss of CO occurs exclusively at an axial position (cis to the bidentate ligand, I^)• The dynamic nature of the five-coordinate intermediates, such as (diphos)Mo(CO)3, (phen)M(CO)3 (M = Cr, Mo, W), and (dipy)Cr(CO)3, which are generated in solution upon CO dissociation, is reported and discussed. The results of this investigation confirm that these intermediates are fluxional on the time scale of CO-exchange process. A mechanism which describes the site of initial metal-carbonyl bond-breaking and the fluxionality of the five-coordinate intermediate during ligand-exchange reactions in the complexes (L2)M(CO)4 is proposed. A kinetic study of reactions of W(CO)6 with pseudo-halide anions (NCS-, NCO-, CN-) has been initiated. The results indicate that these reactions proceed via a bimolecular path, which involves initial attack of the pseudo-halide anion at a carbonyl carbon of W(CO)6,

Objetivo: Avaliar o efeito da oxigenoterapia hiperbárica na cicatrização da anastomose esôfagojejunal em ratos gastrectomizados. Material e Métodos: Foram operados 40 ratos Wistar, adultos machos, com peso entre 322g e 506g. Os animais foram divididos aleatoriamente em dois grupos. No grupo A (controle), 20 ratos foram submetidos à gastrectomia total. No grupo B, 20 ratos foram igualmente gastrectomizados e receberam tratamento pósoperatório com oxigenoterapia hiperbárica por 90 minutos/dia durante sete dias. Todos os ratos foram sacrificados no oitavo dia de pós-operatório e avaliados de acordo com as seguintes variáveis em estudo:a) presença ou não de fístula anastomótica; b) avaliação da cicatrização da anastomose esôfagojejunal através da medida da força de ruptura à tração na linha da sutura segundo Hendriks & Mastboom; c) determinação da concentração de colágeno na anastomose, pelos critérios de Kovács. Para análise estatística comparativa entre os grupos foi utilizado o teste t de Student, considerando-se como significativo p <0,05. Resultados: Houve 20% de óbitos na amostra, sendo cerca de 60% no grupo A e os 40% restantes no grupo B (p=N.S.) . Ocorreu apenas uma fístula anastomótica em cada grupo, sendo que em ambos não houve morbidade relacionada ou óbito. As medidas de força de ruptura à tração na linha da sutura entre os grupos (p=0,528) e a determinação da concentração de colágeno na anastomose esôfagojejunal (p=0,89) não mostraram diferença estatisticamente significativa nos dois grupos. Conclusões: Utilizando parâmetros clínicos, mecânicos e bioquímicos para avaliar a anastomose esôfagojejunal, concluímos que no presente estudo a oxigenoterapia hiperbárica não interferiu no processo de cicatrização desta anastomose. / Purpose: To evaluate the effect of the hyperbaric oxygen therapy on the healing of the esophagojejunal anastomosis in gastrectomized rats. Material and Methods: 40 Wistar rats male adults with weighing between 322g to 506g were operated. The animals were divided in two ramdom groups.20 rats from group A (control group), were submitted to total gastrectomy. In group B, 20 rats were equally gastrectomized and received postoperative treatment with hyperbaric oxygen for 90 minutes/day during seven days. All rats were sacrificed on the eighth postoperative day and evaluated according to the following study variables :a) whether there were any anastomotic fistula or not; b) evaluating esophagojejunal anastomosis healing by measuring breaking strength at the suture line as per Hendriks & Mastboom; c) determining of the collagen concentration on the anastomosis, as per Kovács criteria. For the comparative statistical analyses between the groups, Student’s “t” test was used, whereas p<0,05 was significant. Results: There was a 20% rate of deceasing in the sample, whereas 60% occurred in group A and 40% in group B (p=N.S.). There was only one anastomotic fistula in each group, and in neither one occurred any morbidity or deaths related. Breaking strength measured at the suture line (p=0,528) and collagen concentration determined at the esophagojejunal anastomosis (p=0,89) did not present any significant statistical difference in either group. Conclusions: By using clinical, mechanical and biochemical parameters to evaluate the esophagojejunal anastomosis, it was possible to conclude that, in this study, hyperbaric oxygen therapy did not interfere with the healing process of the anastomosis.

FARIAS, R. R. de. Campo de Bumblebee em um espaço de Schwarzschild. 2017. 50 f. Dissertação (Mestrado em Física) – Centro de Ciências, Universidade Federal do Ceará, Fortaleza, 2017. / Submitted by Giordana Silva (giordana.nascimento@gmail.com) on 2017-04-18T17:43:12Z No. of bitstreams: 1 2017_dis_rrdfarias.pdf: 1718443 bytes, checksum: 9a06da2d884c3d3904afd2c830e42bce (MD5) / Approved for entry into archive by Giordana Silva (giordana.nascimento@gmail.com) on 2017-04-18T17:44:06Z (GMT) No. of bitstreams: 1 2017_dis_rrdfarias.pdf: 1718443 bytes, checksum: 9a06da2d884c3d3904afd2c830e42bce (MD5) / Made available in DSpace on 2017-04-18T17:44:06Z (GMT). No. of bitstreams: 1 2017_dis_rrdfarias.pdf: 1718443 bytes, checksum: 9a06da2d884c3d3904afd2c830e42bce (MD5) Previous issue date: 2017 / The objective of this work is apply bumblebee model, a spontaneously Lorentz symmetry breaking model due to a non-vanishing vacuum expectation value vector field, to a vacuum space. Results are presented for a radial/temporal Lorentz symmetry breaking in a Schwarzschild space. Also, it is verified an incompatibility between the hypothese of the universe to be homogenous in the absence of massive ordinary matter and the imposition of a parallelly transported bumblebee field in radial direction. / O objetivo deste trabalho é aplicar o modelo de bumblebee, um modelo de quebra de simetria espontânea de Lorentz gerada por um quadri-vetor de valor esperado de vácuo não-nulo, a um espaço de vácuo. Apresentamos resultados para quebra de simetria de Lorentz radial/temporal em um espaço de Schwarzschild. Além disso, é verificada uma incompatibilidade entre a hipótese de o universo ser homogêneo quando não há presença de matéria massiva ordinária e a imposição de um campo de bumblebee paralelamente transportado na direção radial.

Une large gamme de problèmes physiques, des petites molécules aux étoiles géantes, contiennent des symétries de rotation et sont sujets à des oscillations azimutales ou transverses. Quand cette symétrie est rompue, le système peut devenir instable. Dans cette thèse, les brisures de symétries sont étudiées dans les chambres de combustion annulaires, sujettes à des instabilités thermo-acoustiques azimutales. En premier lieu, deux types de brisures sont obtenus analytiquement : la première en répartissant des bruleurs différents le long de la chambre et la seconde provoquée par le champ moyen lui-même. Ces ruptures de symétries entraînent une séparation des fréquences, fixe la structure du mode et peut déstabiliser le système. De plus, une approche Quantification d’Incertitudes (UQ) permet d’évaluer l’effet de la rupture de symétries provoquée par les incertitudes sur la description ou le comportement des flammes. Pour compléter cette théorie, des Simulations aux Grandes Echelles (SGE) sont réalisées sur un mono-secteur ainsi que sur une configuration complète 360° de l’expérience annulaire de Cambridge. Les résultats numériques sont comparés aux données expérimentales et montrent un bon accord. En particulier, un mode instable à 1800 Hz croît dans les deux cas. Cependant, la SGE, limitée par son coût important, ne permet pas l’étude du cycle limite s’établissant après plusieurs centaines de millisecondes. Pour pallier à ce problème, une nouvelle approche, appelée AMT, est développée : les résultats d’une théorie ou d’un solveur acoustique sont injectés dans une simulation SGE. Cette approche permet d’étudier les brisures de symétries, la nature et la dynamique des modes acoustiques, ainsi que d’évaluer l’amortissement dans des configurations réalistes. / A large range of physical problems, from molecules to giant stars, contains rotating symmetry and can exhibit azimuthal waves or vibrations. When this symmetry is broken, the system can become unstable with chaotic behaviors. Symmetry breaking is investigated in annular combustors prone to azimuthal thermo-acoustic instabilities. First, theories reveal that two types of symmetry breaking exist : due to different burner types distributed along the chamber or due to the flow itself . It leads to frequency splitting, fixes the mode structure and can destabilize the configuration. A UQ analysis is also performed to quantify the symmetry breaking effect due to uncertainties of flame descriptions or behaviors. To complete theory, Large Eddy Simulations are performed on a single-sector as well as on a complete 360° configuration of the annular experiment of Cambridge. Numerical results are compared to experimental data showing a good agreement. In particular, an unstable azimuthal mode at 1800 Hz grows in both LES and experiment. However, LES cannot investigate the limit cycle because of its extreme cost. To tackle this problem, a new methodology is developed, called AMT, where theory or Helmholtz solver predictions are injected into LES or DNS. This method allows to study symmetry breaking, mode nature and dynamics as well as evaluating damping in realistic annular configurations.

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior / Este trabalho apresenta um estudo sobre o espalhamento W+W+ e W&#8722;W&#8722; para os primeiros anos de tomada de dados do experimento CMS do LHC, no CERN. O processo de espalhamento de bósons vetoriais, dentre os quais se inclui o espalhamento WW, é um processo chave para elucidação do mecanismo de quebra de simetria eletrofraca. Previsões teóricas mostram que as características cinemáticas do espalhamento de bósons vetoriais na escala T e V de energia devem depender significativamente do mecanismo que quebra a simetria eletrofraca. Este processo será analisado com dois objetivos principais: estudar a viabilidade de medi-lo em altas energias no CMS, e mostrar a sua sensibilidade ao mecanismo da quebra de simetria eletrofraca. Esta sensibilidade será mostrada através da análise de duas amostras de eventos correspondentes a dois cenários distintos: o modelo padrão com a presença de um bóson de Higgs de massa 500 GeV e o modelo padrão sem a presença do bóson de Higgs. Estas amostras foram geradas com o gerador de eventos PHASE, cuja principal importância para o estudo do espalhamento de bósons vetoriais em altas energias e a sua capacidade de calcular o elemento de matriz completo em ordem dominante O(&#945;6). Para se analisar a viabilidade de se medir o espalhamento WW no CMS, foi feita uma simulação do detector utilizando as amostras dos processos de sinal e dos principais processos de fundo através do pacote de simulação rápida do CMS, o FAMOS. Os processos de fundo, WW+N jatos, WZ+N jatos, ZZ+N jatos, W+N jatos e tt+N jatos, foram estudados e suprimidos através de seleções de regiões cinemáticas. A análise dos dados mostra que a observação do espalhamento WW na fase inicial do LHC será muito difícil, sendo necessária uma luminosidade maior, além de aprimoramento da análise. / This work presents a study of W+W+ and W&#8722;W&#8722; scattering for the first years of the CMS experiment data-taking at LHC, CERN. Vector boson scattering, including WW, is a key processes for probing electroweak symmetry breaking. Theoretical predictions show that kinematics characteristics of vector boson scattering at T e V scale must strongly depend on the electroweak symmetry breaking mechanism. This process is analyzed with two main objectives: viability study of performing this measurement at CMS and show its dependence on the electroweak symmetry breaking mechanism. This dependence is shown through an analysis with two event samples corresponding to two distinct scenarios: the standard model with the presence of a 500 GeV massive Higgs boson and the standard model without presence of a Higgs boson. These samples were generated by the Monte-Carlo generator PHASE, whose main importance for vector boson scattering at high energies is its characteristic of calculating the complete matrix elements in leading order O(&#945;6). To analyze the viability of measuring the WW scattering at CMS, the simulated signal and background events were submitted to the CMS fast detector simulation, FAMOS. Background processes, WW+N jets, WZ+N jets, ZZ+N jets, W+N jets and tt+N jets, were studied and suppressed through kinematics region selection. Data analysis shows that the measurement of WW scattering in early stages of LHC will be very difficult, being necessary a larger luminosity, besides improvements on the analysis.

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior / A Quebra Espontânea de Simetria (QES) tem sido discutida em muitos cenários, tendo resultados importantes na física Teórica de Partículas, sendo motivo de extensa pesquisa e com variadas aplicações. Neste trabalho, será apresentado um modelo alternativo baseado na Ação de Fujikawa usando quartetos BRST. No primeiro capítulo, todo o ferramental para a análise da QES é discutido partindo da definição em nível clássico e por fim no regime quântico, usando o conceito de ação efetiva. A técnica de quantização de campos de calibre no U(1), presente no eletromagnetismo, foi abordada, usando o cálculo dos propagadores e seus respectivos diagramas de Feynman. Foi estudado em conjunto com esse assunto, o conceito de campos fantasmas de Fadeev-Popov e Simetria-BRST. O mecanismo de Higgs é explorado em nível quântico, sendo feita um estudo dos rearranjos dos graus de liberdade do sistema. No segundo capítulo, as propriedades dos quartetos-BRST são estudadas, bem como suas considerações sobre simetria, quando aplicadas na ação de Fujikawa usando dois cenários: (i) quando a simetria não é quebrada. (ii) A simetria é quebrada. E por fim é feita uma análise sobre os graus de liberdade do sistema.