Made available in DSpace on 2014-06-11T19:33:39Z (GMT). No. of bitstreams: 0 Previous issue date: 2009-05-29Bitstream added on 2014-06-13T20:25:30Z : No. of bitstreams: 1 durigan_mfb_dr_jabo.pdf: 3249388 bytes, checksum: 9f67b354f51854cbee43a06c30c8f27a (MD5) / Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES) / Gerbera jamesonii Bolus é uma espécie da família Compositae. O capítulo, com diâmetro de 8 – 14 cm, possui flores liguladas de cores vivas organizadas ao redor do centro, que contém os botões florais. Esta inflorescência é sustentada por uma haste longa e sem folhas. Atualmente é uma das dez flores mais comercializadas no Brasil e está entre as três principais flores de corte. A utilização de soluções conservantes, tratamentos de “pulsing”, ou fortalecimento, e baixas temperaturas de armazenamento visa prolongar a vida e manter por mais tempo a qualidade das flores cortadas. Neste contexto, este trabalho teve por objetivos avaliar o efeito de diferentes práticas de manejo na pós-colheita sobre a fisiologia e conservação de inflorescências de gérberas. Para os quatro primeiro experimentos foi utilizada a gérbera cv. Suzanne, de coloração laranja. Os experimentos foram conduzidos em delineamento inteiramente casualizado, em esquema fatorial. No primeiro experimento, as inflorescências permaneceram nas seguintes soluções de manutenção: 1) Água destilada; 2) Cloro a 100 mg.L-1; 3) 8-hidroxiquinolina (8-HQC) a 100 mg.L-1; 4) 8-HQC a 200 mg.L-1; e 5) 8- HQC a 400 mg.L-1, cujas hastes foram mantidas em condição controlada de laboratório (20°C; 70% UR). Este experimento possibilitou observar danos nas bases das hastes, causados pelos tratamentos com cloro a 100 mg.L-1 e com as doses mais elevadas de 8-HQC. A manutenção da boa qualidade foi observada no tratamento com 8-HQC a 200 mg.L-1. A longevidade média foi de 12 dias em vaso. No segundo experimento foram utilizadas, durante o armazenamento a 20°C e 70% UR, as soluções: 1) Água destilada; 2) Ácido cítrico a 64 g.L-1; 3) Cloro a 25 mg.L-1 4) Cloro a 50 mg.L-1 5) 8-HQC a 25 mg.L- 1 e 6) 8-HQC a 50 mg.L-1. Com os resultados verificou-se a baixa eficiência do... / Gerbera jamesonii belongs to the Compositae family. The inflorescence, with diameter of 8 – 14 cm, is a capitulum with ligules with vivid color organized around de center, that contain flower buds, which can be in a variety of colors. This colorful flower is supported by a long stem, without leaves. Nowadays it is one of the ten most commercialized flowers in Brazil and is one of the three main cut flowers. The use of keeping-quality solutions, pulsing treatments and low temperature during the vase life seeks to prolong vase life and to maintain the quality of cut flowers. In this context, this research was conducted, at FCAV-UNESP, Jaboticabal, SP, Brazil, to evaluate the effects of several handling techniques on postharvest physiology gerbera cut flowers. The experiments followed complete randomized design, in factorial arrangement. On the first one, the inflorescences remained in the following solutions: 1) Distilled water; 2) Chlorine at 100 mg.L-1; 3) 8-hydroxyquinolin (8-HQC) at 100 mg.L-1; 4) 8-HQC at 200 mg.L-1; and 5) 8-HQC at 400 mg.L-1, which the stems remained in environmental conditions (20°C; 70% RH). On this experiment, it was possible to observe the damage caused by the treatments using chlorine at 100 mg.L-1 and high dosage of 8-HQC. The good quality where kept by using 8-HQC at 200 mg.L-1 and the average longevity of the experiment was 12 days. On the second experiment, the gerberas remained, during storage, in the following solutions: 1) Distilled water; 2) Citric acid at 64 g.L-1; 3) Chlorine at 25 mg.L-14) Chlorine at 50 mg.L-1; 5) 8-HQC at 25 mg.L-1 ; and 6) 8-HQC at 50 mg.L-1. With the results it was possible to verify the low efficiency of the citric acid at the used concentration and the lower damage by lower concentrations of chlorine and 8-HQC than the usually recommended, which kept the good quality of the flowers for... (Complete abstract, click electronic access below)

In the last decade, a large number of studies have been devoted to the peculiarities of correlated physics found in the quasi-two-dimensional square lattice iridium oxides. It was shown that this 5d family of transition metal oxides has strong structural and electronic similarities to the famous 3d family of copper oxides. Moreover, a delicate interplay of on-site spin-orbit coupling, Coulomb repulsion and crystalline electric field interactions is expected to drive various exotic quantum states. Many theoretical proposals were made in the last decade including the prediction of possible superconductivity in square-lattice iridates emerging as a sister system to high-Tc cuprates, which however met only limited experimental confirmation. One can, therefore, raise a general question: To what extent is the low-energy physics of the quasi-two-dimensional square-lattice iridium oxides different from other transition metal oxides including cuprates? In this thesis we investigate some of the effects which are usually neglected in studies on iridates, focusing on quasi-two-dimensional square-lattice iridates such as Sr2IrO4 or Ba2IrO4. In particular, we discuss the role of the electron-phonon coupling in the form of Jahn-Teller interaction, electron-hole asymmetry introduced by the strong correlations and some effects of coupling scheme chosen to calculate multiplet structure for materials with strong on-site spin-orbit coupling. Thus, firstly, we study the role of phonons, which is almost always neglected in Sr2IrO4, and discuss the manifestation of Jahn-Teller effect in the recent data obtained on Sr2IrO4 with the help of resonant inelastic x-ray scattering. When strong spin-orbit coupling removes orbital degeneracy, it would at the same time appear to render the Jahn-Teller mechanism ineffective. We show that, while the Jahn-Teller effect does indeed not affect the antiferromagnetically ordered ground state, it leads to distinctive signatures in the spin-orbit exciton. Second, we focus on charge excitations and determine the motion of a charge (hole or electron) added to the Mott insulating, antiferromagnetic ground-state of square-lattice iridates. We show that correlation effects, calculated within the self-consistent Born approximation, render the hole and electron case very different. An added electron forms a spin-polaron, which closely resembles the well-known cuprates, but the situation of a removed electron is far more complex. Many-body configurations form that can be either singlets and triplets, which strongly affects the hole motion. This not only has important ramifications for the interpretation of angle-resolved photoemission spectroscopy and inverse photoemission spectroscopy experiments of square lattice iridates, but also demonstrates that the correlation physics in electron- and hole-doped iridates is fundamentally different. We then discuss the application of this model to the calculation of scanning tunneling spectroscopy data. We show that using scanning tunneling spectroscopy one can directly probe the quasiparticle excitations in Sr2IrO4: ladder spectrum on the positive bias side and multiplet structure of the polaron on the negative bias side. We discuss in detail the ladder spectrum and show its relevance for Sr2IrO4 which is in general described by more complicated extended t-J -like model. Theoretical calculation reveals that on the negative bias side the internal degree of freedom of the charge excitation introduces strong dispersive hopping channels encaving ladder-like features. Finally, we discuss how the choice of the coupling scheme to calculate multiplet structure can affect the theoretical calculation of angle-resolved photoemission spectroscopy and scanning tunnelling spectroscopy spectral functions.

In the last decade, a large number of studies have been devoted to the peculiarities of correlated physics found in the quasi-two-dimensional square lattice iridium oxides. It was shown that this 5d family of transition metal oxides has strong structural and electronic similarities to the famous 3d family of copper oxides. Moreover, a delicate interplay of on-site spin-orbit coupling, Coulomb repulsion and crystalline electric field interactions is expected to drive various exotic quantum states. Many theoretical proposals were made in the last decade including the prediction of possible superconductivity in square-lattice iridates emerging as a sister system to high-Tc cuprates, which however met only limited experimental confirmation. One can, therefore, raise a general question: To what extent is the low-energy physics of the quasi-two-dimensional square-lattice iridium oxides different from other transition metal oxides including cuprates? In this thesis we investigate some of the effects which are usually neglected in studies on iridates, focusing on quasi-two-dimensional square-lattice iridates such as Sr2IrO4 or Ba2IrO4. In particular, we discuss the role of the electron-phonon coupling in the form of Jahn-Teller interaction, electron-hole asymmetry introduced by the strong correlations and some effects of coupling scheme chosen to calculate multiplet structure for materials with strong on-site spin-orbit coupling. Thus, firstly, we study the role of phonons, which is almost always neglected in Sr2IrO4, and discuss the manifestation of Jahn-Teller effect in the recent data obtained on Sr2IrO4 with the help of resonant inelastic x-ray scattering. When strong spin-orbit coupling removes orbital degeneracy, it would at the same time appear to render the Jahn-Teller mechanism ineffective. We show that, while the Jahn-Teller effect does indeed not affect the antiferromagnetically ordered ground state, it leads to distinctive signatures in the spin-orbit exciton. Second, we focus on charge excitations and determine the motion of a charge (hole or electron) added to the Mott insulating, antiferromagnetic ground-state of square-lattice iridates. We show that correlation effects, calculated within the self-consistent Born approximation, render the hole and electron case very different. An added electron forms a spin-polaron, which closely resembles the well-known cuprates, but the situation of a removed electron is far more complex. Many-body configurations form that can be either singlets and triplets, which strongly affects the hole motion. This not only has important ramifications for the interpretation of angle-resolved photoemission spectroscopy and inverse photoemission spectroscopy experiments of square lattice iridates, but also demonstrates that the correlation physics in electron- and hole-doped iridates is fundamentally different. We then discuss the application of this model to the calculation of scanning tunneling spectroscopy data. We show that using scanning tunneling spectroscopy one can directly probe the quasiparticle excitations in Sr2IrO4: ladder spectrum on the positive bias side and multiplet structure of the polaron on the negative bias side. We discuss in detail the ladder spectrum and show its relevance for Sr2IrO4 which is in general described by more complicated extended t-J -like model. Theoretical calculation reveals that on the negative bias side the internal degree of freedom of the charge excitation introduces strong dispersive hopping channels encaving ladder-like features. Finally, we discuss how the choice of the coupling scheme to calculate multiplet structure can affect the theoretical calculation of angle-resolved photoemission spectroscopy and scanning tunnelling spectroscopy spectral functions.

In dieser Veröffentlichung soll untersucht werden, ob vorhandene Methoden aus dem Bereich der sozio-technischen Systeme (STS) genutzt werden können, um Mensch-Roboter-Kollaborationen (MRK) hinsichtlich ihrer Ergonomie zu optimieren. [... aus der Einleitung]

Byggsektorn tenderar idag att välja material med låg miljöpåverkan och bygga energi- och tidseffektiva konstruktioner. Att öka användningen av träprodukter är en del av lösningen. Korslimmat trä (KL-trä) är ett byggmaterial som har blivit mer och mer populärt att använda i byggbranschen. I Sverige har KL-trä använts sedan slutet på 90- talet och användandet ökar för varje år som går. Materialet är relativt nytt och vid monteringen av KL-trä finns det utrymme för förbättringar. Syftet med arbetet är att undersöka och analysera hur dagens infästning av KL-element utförs och hur dessa kan effektiviseras. Målet är att undersöka om det går att korta ner monteringstiden av KL- trästommar. Detta görs genom beräkningar, fältstudie och experiment. I arbetet undersöks möjligheten att reducera skruvning för det vanligast använda vägg till golv anslutningarna och om det finns tid att spara i montaget med hjälp av förborrning. Resultatet av rapporten visar att det finns en potentiell tid motsvarande ca 40 % tidsvinst att spara med förborrade bjälklag från fabrik och andra kvalitétsfördelar som förborrning kan medföra, medan reducering av skruv är möjligt men inte optimerad för dagens mest tillämpade infästningslösningar. / The construction sector today tends to choose material with a low environmental impact and build energy- and time-efficient structures. Increasing the use of wood products is part of the solution. Cross laminated timber (CLT) is a building material that has become more and more popular to use in the construction industry. In Sweden, CLT has been used since the late 90 and its use is increasing every year. The material is relatively new and especially for mounting CLT element, there are still potentials for improvement. The purpose of the work is to investigate and analyze how todays attachment of CLT elements is carried out and how these can be made more efficient. The aim is to investigate whether it is possible to shorten the assembly time of CLT elements. The study was carried out through calculations, study visit and experiments. The work investigates the possibility of reducing screwing for the most commonly used wall to floor joints and showed there is a potential time efficiency of about 40% to be gained with pre-drilled floor element from the factory and other quality benefits that pre-drilling can bring, while the study also showed reducing fasteners under construction phase is possible but not an optimal solution.

This research aims to develop and evaluate a design framework for creating digital devices that support the exploration of animal behaviors in the wild. In order to carry out this work, it both studies ethology’s foundational ideas through literature and also examines the contemporary principles at a rainforest field station through on-site ethnographies, workshops, design projects, and interactive performances. Based upon these personal and practical investigations, this research then synthesizes a framework to support digital-ethological practice. Finally, this framework is utilized to design additional ethological expeditions and activities in order to assess the framework itself. The resulting framework encourages digital technology that supports four key concepts. Technological Agency pushes for devices that promote understanding of their own internal functions. The tenet of Contextual Crafting leads designers and ethologists to create devices in close proximity to their intended use. Behavioral Immersion promotes visceral interactions between the digital and organismal agents involved. Finally, Open-Endedness challenges researchers to create adaptable tools which strive to generate questions rather than answering them. Overall, this research, referred to as Digital Naturalism, explores a developing design space for computers in the wild.

<p></p><p>I dagens samhälle tas miljöfrågor allt oftare upp i den allmänna och politiska debatten och ett aktivt miljöarbete är något som i allt högre grad krävs av företag från bland annat myndigheter och miljöorganisationer. Stålindustrin är inget undantag och får därför ofta kritik för att de åtgärder som vidtas inte är tillräckliga.</p><p>Inom stålindustrin genomför företag ofta investeringar för att minska sin miljöpåverkan trots att avkastning på det investerade kapitalet uteblir. Den institutionella organisationsteorin förklarar dessa handlingar som direkta konsekvenser av likriktning. Det fenomen som studeras i studien är spridningen av miljömedvetenhet eftersom denna anses ligga till grund för investeringarna i miljöåtgärder inom den svenska stålindustrin. Formatet för studien är en fallstudie där den empiriska datainsamlingen skett genom tryckt material och intervjuer.</p><p>Det kan konstateras att det studerade företagets miljöarbete påverkas i stor utsträckning av andra aktörer inom det organisatoriska fält som företaget tillhör. Inverkan på det studerade företagets miljöarbete och således spridningen av miljömedvetenhet varierar mycket mellan olika aktörer. Det är framförallt aktören <em>politiker och myndigheter</em> som genom tvingande mekanismer styr företagets miljöarbete. Beroende på rådande situation kan dock även influenserna från övriga aktörer påverka företagets miljöarbete och spridningen av miljömedvetenhet.</p><p> </p> / <p></p><p>In society today environmental issues more often appear on both the public and the political agenda and an active environmental awareness is increasingly often demanded from companies by regulative authorities and environmental organisations. The steel industry is no exception and therefore receives criticism that they do not undertake the necessary actions to prevent further pollution.</p><p>Companies within the steel industry often invest in different measures to reduce their environmental impact although it seldom generates a profit. Institutional theory explains these actions as direct consequences of conformity. The phenomenon of interest is the spread of environmental awareness because it is considered to be the reason behind investments in environmental impact reduction within the Swedish steel industry. The study is preformed as a case study where the empirical data is collected through written sources and interviews.</p><p>It is established that the environmental work of the focal company is largely affected by the other actors within the organizational field of interest. Among these actors the level of impact on the focal company’s environmental work and therefore also the spreading of environmental awareness varies a lot. <em>Politicians and government authorities are</em> the actor which first and foremost through coercive actions affects the environmental work in the studied company. Although, depending on the situation at hand the other actors can also play very important parts in affecting the studied company and the spread of environmental awareness.</p><p> </p>

Background: The literature suggests a consensus that individuals can become traumatised through listening to another’s trauma. Much of this research, however, has focused on individuals who have had direct, face-to-face contact with the primary victims of trauma. It therefore appears that there is a paucity of research looking at contact which is less direct, such as telephone contact. Aims: The current research aimed to explore the levels of secondary traumatic stress and posttraumatic stress disorder in a sample of Samaritan telephone volunteers, with a view to understanding some of the correlates of trauma. It also aimed to explore the personal construct systems of a sub-sample of Samaritan telephone volunteers, and explore any relationships between personal construct systems and trauma. Method: A cross-sectional design was employed. Questionnaires were used to assess levels of secondary traumatic stress and posttraumatic stress in Samaritan telephone volunteers spread across the United Kingdom. Repertory grid technique was used with a sub-sample of Samaritan telephone volunteers to elicit bipolar constructs comparing themselves and others. Results: 299 Samaritan telephone volunteers completed or partially completed the questionnaires, and of these 50 volunteers completed the repertory grids. Levels of secondary trauma (as determined by the Modified Secondary Trauma Scale) correlated with discrepancy in construing of the current and ideal self, levels of posttraumatic stress and exposure to potentially traumatic events. The Samaritans were not found to be suffering with secondary trauma. Degree of elaboration of self-construing reduced after the named traumatic event, and there was a significant difference in degree of elaboration for ‘self after traumatic event’ on the emergent poles of constructs. Conclusions: This research appears to be the first dedicated to assessing secondary trauma in telephone crisis line volunteers, lending some support to Sewell and Cromwell’s (1990) personal construct model of posttraumatic stress. The findings of this study challenge crisis lines to think about secondary trauma, and to implement some teaching and training around this area. Additionally, it reinforces that further research in the area is needed, and highlights the relative merits of employing a repertory grid methodology alongside questionnaires in understanding trauma.

The socio-musical practice of sampling is closely associated with the re-use of pre-existing sound recordings and the technological processes of looping. These practices, based on appropriation and repetition, have been particularly common within the genres of hip-hop and Electronic Dance Music (EDM). Yet early digital sampling instruments such as the Fairlight Computer Musical Instrument (CMI) were not designed for these purposes. The technologists at Fairlight Instruments in Australia were primarily interested in the use of digital synthesis to imitate the sounds of acoustic instruments; sampling was a secondary concern. In the first half of the thesis, I follow digital sampling instruments like the Fairlight CMI and the E-mu Emulator by drawing on interviews with their designers and users to trace how they were used to sample the sounds of everyday life, loop sequenced patterns of sampled sounds, and sample extracts from pre-existing sound recordings. The second half of the thesis consists of case studies that follow the users of digital sampling technologies across a range of socio-musical worlds to examine the diversity of contemporary sampling practices. Using concepts from the field of Science and Technology Studies (STS), this thesis focuses on the ‘user-technology nexus’ and continues a shift in the writing of histories of technologies from a focus on the designers of technologies towards the contexts of use and ‘the co-construction’ or ‘mutual shaping’ of technologies and their users. As an example of the ‘interpretative flexibility’ of music technologies, digital sampling technologies were used in ways unimagined by their designers and sampling became synonymous with re-appropriation. My argument is that a history of digital sampling technologies needs to be a history of both the designers and the users of digital sampling technologies.

O trabalho apresentado investiga as contribuições da pesquisa em ensino de ciências para a promoção da educação científica em atividades a serem desenvolvidas por laboratórios ativos de pesquisa. Apoiado nos debates sobre o ensino em espaços não formais, procura situar o ambiente de trabalho desses centros e suas possibilidades de interlocução com a escola básica e o público em geral. Tal perspectiva localiza as limitações desses laboratórios, reconhecendo a não intencionalidade própria dos espaços envolvidos, ao contrário do que se observa, por exemplo, em museus ou exposições científicas. Por outro lado, identifica sua singularidade, enquanto ambiente privilegiado para apresentar os processos de produção científica, enfatizando os aspectos sociais de seu fazer, pouco explorados no contexto escolar. Com esse intuito, foram analisadas as possíveis contribuições de reflexões sobre Alfabetização Científica e Ciência- Tecnologia-Sociedade (CTS), a fim de inserir articulações entre os aspectos do conhecimento científico presentes nos laboratórios e as demandas de visitantes. Em particular, investiga-se o acelerador de partículas Pelletron, do Departamento de Física Nuclear do IFUSP, analisando diferentes estratégias associadas a visitas, desenvolvidas ao longo de seis anos de trabalho, com a finalidade de promover a educação científica. Nessas análises, foi possível identificar que os diferentes protagonistas, sejam eles alunos, professores, cientistas ou técnicos, manifestam interesses nem sempre convergentes. Isso conduziu ao questionamento da centralidade atribuída ao conhecimento físico conceitual, procurando ampliar a ideia de conhecimento de forma a incluir outras dimensões do fazer científico. Nessa direção, discute-se o potencial de dimensões do conhecimento relacionadas à produção da ciência e sua função social. Propõe-se, assim, que o conhecimento físico se articule com situações da dinâmica da vida do laboratório e com as questões de inserção da ciência no conjunto da sociedade, ampliando a compreensão dos visitantes acerca da ciência. / The present study investigates the contributions of research in science learning to promote science education activities to be developed by operational research laboratories. Supported by discussions regarding the non-formal education, this study aims to situate the work environment of these laboratories and their potentialities of communication with elementary schools and the general public. This endeavor must recognize the limitations of these laboratories, since they have a different purpose when compared to museums and science exhibitions, for instance. On the other hand, it is possible to identify the uniqueness of such places as a privileged environment to present the science production process and the social aspects of this process, that is little explored in the school context. In addition, we analyzed the possible contributions of reflections on Scientific Literacy and Science- Technology-Society (STS), in order to insert links between aspects of scientific knowledge in the laboratories and the demands of visitors. In particular, we investigate the Pelletron particle accelerator, from the Department of Nuclear Physics of the Institute of Physics from the University of São Paulo (IFUSP), analyzing different strategies associated with the visits developed over six years of work, in order to promote science education. In these analyses, it was possible to identify that the different actors, such as students, teachers, scientists or technicians, express different interests that do not always converge. This led to challenge the central role attributed to conceptual physical knowledge, seeking the broadening of the idea of knowledge in order to include other dimensions of scientific work. In this sense, we discuss the possible dimensions of knowledge related to the production of science and its social function. Therefore, we propose that the physical knowledge must be linked to other aspects of the laboratory dynamics and to issues regarding the insertion of science in the society, expanding visitors\' understanding about it.