Orientador: Prof. Dr. Charles Morphy D. Santos / Dissertação (mestrado) - Universidade Federal do ABC, Programa de Pós-Graduação em Programa de Pós-Graduação em Ensino, História, Filosofia das Ciências e Matemática, 2014. / O Darwinismo Universal, conceito desenvolvido pelo biólogo evolucionista Richard Dawkins em 1983, responde positivamente à conjectura "Se existe vida fora da Terra, os organismos evoluem como evoluem os seres vivos da Terra?". No entanto, a complexidade adaptativa centrada na seleção natural, seria por si só, aqui ou em qualquer parte do Universo, suficiente para explicar toda a evolução orgânica? O próprio Charles Darwin defendia um pluralismo explicativo para a evolução. A proposta central do trabalho é discutir se uma definição geral de vida pode estar fundamentada na ideia de seleção natural ou se precisamos rediscutir e estender o conceito de Darwinismo Universal à luz de conceitos tais como a auto-organização, que poderia explicar a origem da ordem biológica a partir de características intrínsecas dos sistemas físico-químicos. Também faz parte do escopo do projeto apontar falhas e indevidas extrapolações do Darwinismo associadas a modelos cosmológicos, assim como a não universalidade do conceito frente a tradicional definição universal de vida. Pela falta de uma definição mais ampla do que é vida, a detecção de bioassinaturas ¿ atributos químicos, físicos ou fisiológicos que denotam, necessariamente, a presença de organismos ¿ torna-se limitada por se restringir apenas àquilo que, independentemente do lugar que ocupa no Universo, passa por um processo natural de seleção darwiniana. Tão logo, deve-se buscar uma compreensão universal da vida como um fenômeno emergente coerente. A expansão do conceito de Darwinismo Universal à luz de uma extensão (ou síntese estendida) da Teoria da Evolução ¿ no componente auto-organização ¿ servirá como arcabouço preliminar para uma filosofia da Biologia apta a abarcar a origem da ordem e diversificação de todas as formas de vida na Terra e para determinar diretrizes as buscas de bioassinaturas. / Universal Darwinism, a concept developed by the evolutionary biologist Richard Dawkins in 1983, responds positively to the conjecture "If life out of Earth exists, does it evolve as Earth¿s living beings do?". Nevertheless, the adaptative complex centered in Darwinian evolution and, therefore, in natural selection, would be by itself, here or at any part of the Universe, sufficient to explain all the organic evolution? Charles Darwin himself used to defend an explicative pluralism for evolution. The main purpose of the present work is to discuss if a general definition of life can be uniquely based on natural selection or whether a new discussion and understanding of the Universal Darwinism under the light of concepts like self-organization is required, which would be able to explain the origin of biological order from physicochemical systems intrinsic characteristics. It is also part of this project¿s scope to point out flaws and improper Darwinism extrapolations associated to cosmological models, as well as the concept¿s non-universality faced with life¿s traditional universal definition. By the lack of a broader definition of life, the detection of biosignatures ¿ chemical, physical or physiological attributes which betoken necessarily, the presence of organisms ¿ becomes limited by restricting only what, independently from where it is located in the universe, undergoes a Darwinian natural selection process. Therefore, it is necessary to search for a universal life comprehension as a coherent emerging phenomenon. The expansion of Universal Darwinism under the light of an extension (or extended synthesis) of the Evolutionary theory ¿ at the self-organization component ¿ will serve as preliminary scaffold for a philosophy of biology able to embrace the origin of order and the diversification of all life forms on Earth, and to determine guidelines for biosignatures searches.

La présente thèse porte sur l’étude de l’auto-organisation induite par laser de nanoparticules (NPs) d’argent dans des couches minces de TiO2. Cette technique laser a été récemment mise au point pour fournir des solutions d'impression originales pour des applications comme l'imagerie polarimétrique, la sécurité ou le design. Ici, nous étudions expérimentalement et théoriquement les différents mécanismes impliqués dans la formation des NPs pour un meilleur contrôle de leur morphologie et de leur organisation. Dans le cas de lasers continus, nos résultats expérimentaux prouvent que la vitesse à laquelle le faisceau laser balaye la surface de l’échantillon est un paramètre crucial pour le contrôle de la taille finale des NPs, et de l’élévation de température induite dans la couche par le laser. La taille des NPs d’argent diminue aux basses vitesses d’écriture, alors que leur croissance est activée par effet thermique et apparait uniquement au-dessus d’un seuil de vitesse. La taille finale des NPs varie dans ce cas de façon non-monotone avec la vitesse de balayage alors que la hausse de température ne cesse de croître. Afin d'expliquer ces phénomènes contre-intuitifs, plusieurs modèles numériques ont été développés qui permettent de simuler la variation de la taille des NPs sous insolation laser dans le domaine spectral du visible. Les résultats théoriques concordent bien avec les observations expérimentales et révèlent que l’origine de ces phénomènes résulte d'interactions complexes entre les différents processus physico-chimiques impliqués dans la formation des NPs. Finalement, cette thèse démontre que l’auto-organisation des NPs à l’échelle sub-longueur d’onde peut être aussi réalisée avec des impulsions laser femto-secondes (fs), et une croissance anisotrope des NPs a été également observée pour une gamme particulière de paramètres laser. La comparaison avec les structures de NPs produites par lasers continus suggère que les impulsions laser fs offrent une meilleure maîtrise des effets thermiques et de la taille des NPs. L'usage de laser fs offre ainsi une nouvelle approche pour transférer ces technologies sur des supports souples comme les papiers ou les plastiques / This doctoral thesis focuses on the study of laser-induced self-organization of Ag nanoparticles (NPs) in TiO2 thin layers. This laser technique was recently developed to provide original printing solutions for applications like active color displays, security, or polarization imaging. Here, we investigate experimentally and theoretically the different mechanisms involved in the NPs formation for a better control of their morphology and organization. In the case of continuous-wave (cw) laser, our experimental results prove that the speed at which the laser scans the sample surface is a crucial parameter to control the NP size and the laser-induced temperature rise. Ag NPs shrink at low scan speed, whereas growth governed by a thermal effect only occurs above a speed threshold. Above this threshold, the size of grown Ag NPs changes in a non-monotonous way with scan speed, whereas laser-induced temperature rise increases with speed. In order to explain these counter-intuitive behaviors, several numerical models have been developed to simulate changes in the size distribution of Ag NPs induced by visible light. Simulation results are in good agreement with experimental observations and reveal the origin of the observed phenomena by collective interactions of various physico-chemical processes involved in the variation of NPs size. Finally, this thesis demonstrates that self-organization of NPs at sub-wavelength scale on large areas can also be performed with femtosecond (fs) laser pulses. Oriented anisotropic growth of NPs has also been observed using a proper selection of laser irradiation parameters. Compared with the cw laser induced structures, fs pulses offer better control of the thermal effect and NP size, which opens the way to transfer these technologies on plastic or paper substrates

The external competitive environments and internal group dynamics of organizations are increasing in complexity resulting in new challenges for organizational leaders to improve performance in underperforming teams. The purpose of this phenomenological study was to address what factors led to high-innovation outcomes in complex adaptive systems using a framework constructed from elements of complexity leadership theory and group dynamics research. An in-depth interviewing approach was used to collect data on the lived experience and meaning the participants attributed to their experiences regarding improved team performance. A total of 21 participants were selected from multiple business settings where their team experienced adaptive tension and improved group cohesion. Their stories were reduced into themes using an inductive process and later analyzed through the lens of complexity leadership theory. The factors that emerged in this study, leveraging tension in the group dynamics enabled through objectivity, roles, alignment, capability, execution, purpose, and work ethic that led to mutual respect, directness, and reliance, offer leaders an effective method for achieving sustained team performance. These factors can be used by organizational leaders to improve team performance and consistency in team outcomes over traditional command and control approaches with a work exchange that benefits individual team members. The findings from this study contribute to social change by improving not only team performance, but also member satisfaction. When leadership is viewed from the perspective of the whole system instead of from the perspective of the individual, the relationships between people emerge as the primary enabling factor for high-innovation outcomes.

Ce travail porte sur la synthèse et l’évaluation de systèmes pi-conjugués en tant matériaux actifs pour des dispositifs opto(électroniques). Un premier chapitre décrit une série d’oligothiophènes cruciformes et leur évaluation dans des dispositifs électrochromes. Le second chapitre décrit la synthèse d’accepteurs moléculaires à base de benzodithiophène et l’analyse de leur potentialités comme matériaux accepteurs dans des cellules solaires organiques. La plus large part du travail porte sur l’analyse des relations structure-propriétés d’une série de petites molécules push-pull comportant un groupe donneur triphénylamine (TPA) relié à un groupe accepteur par un espaceur thiényl. Une première étape a consisté à remplacer l’un des cycles phényles de la TPA par des groupes aromatiques tels que p-fluorophényle, anthryle et naphtyle. Ces modifications ont peu d’influence sur les propriétés électroniques de la molécule mais induisent de large variations des propriétés de transport de charge et de conversion photovoltaïque des matériaux correspondants. Au cours d’une seconde étape l’un des groupes phényles de la TPA a été remplacé par des chaînes alkyle, perfluoroalkyle et oligo(oxyethylene). Les résultats de diffraction X, spectroscopie d’absorption et de fluorescence, génération de second harmonique et électrochimie démontrent que certaines de ces molécules présentent des propriétés d’émission contrôlées par agrégation tandis que les matériaux correspondants se réorganisent spontanément à l’état solide sous forme d’agrégats H ou J dotés de propriétés de transport de charges et de conversion photovoltaïque fortement améliorées et de propriétés d’absorption, d’émission et de génération de second harmonique mécaniquement modulables. / This work deals with the design, synthesis and evaluation of molecular pi-conjugated systems as active materials for (opto)electronics devices. A short first chapter describes three X-shaped oligothiophenes, thecharacterization of their structure and properties and a first evaluation of their performances in electrochromic devices. The second chapter describes the synthesis of molecular acceptors based on a benzodithiophene and the analysis of their potentialities when combined with molecular donors in organic solar cells.The major part of the work is focused on the analysis of structure-properties relationships of a series of smallpush-pull molecules involving di- or tri-arylamine donorblocks linked to an acceptor group by a thienyl bridge. In a first step, a phenyl ring of triphenylamine (TPA) is replaced by p-fluorophenyl, anthryl and naphtyl groups.Optical and electrochemical results show that substitution has little effect at the molecular level but can markedly affect solid-state properties with in particular an improvement of charge-transport and short-circuit current density of solar cells based on these donor materials.In a second step, a phenyl ring of TPA is replaced by alkyl, perfluoroalkyl and oligo(oxyethylene) chains. Results of X-ray diffraction, absorption and photoluminescence spectroscopies, second harmonic generation, and electrochemistry demonstrate that some of these molecules under go aggregation controlled photoluminescence emission wave length while the corresponding materials spontaneous lyre organize in the solid-state to form either H or Jaggregates with enhanced charge mobility, photovoltaic conversion efficiency and mechanically-induced chromism, fluorochromism and NLO-chromism.

Dans de nombreuses métropoles, il n'existe pas de transports collectifs centralisés, publics ou privés. Des solutions alternatives se sont développées grâce à des systèmes de transports artisanaux qui reposent sur l'éclatement de la propriété et l'autonomie des équipages de véhicules. Leur mode d'organisation permet aux transports artisanaux de s'adapter à la demande de manière dynamique. Nous proposons d'analyser les caractéristiques de ces systèmes grâce à la modélisation multi-agents et les théories de l'auto-organisation. A travers plusieurs modèles, nous verrons comment les structures et les dynamiques de ces systèmes dépendent des stratégies individuelles et de la structure urbaine. A travers la question de l'adaptabilité du transport en commun, les transports artisanaux nous amènent à nous interroger sur les dimensions urbaines de la mobilité collective mais également sur la flexibilisation des services de transport. / Several metropolises have not any centralized collective transport system, neither private nor public. Alternative solutions appeared, their caracteristics are principally that the ownership is spread out and the vehicle crew is self-directed. The mode of organization of these transports allows them to adapt dynamically to the demand.We propose to analyse the caracteristics of these systems by means of multi-agents modeling and self-organization theory. Using several models, we show how structures and dynamics of these systems are linked to individual strategies and urban structure.Through the question of adaptability of collective transport, small-scale transports led to concern about urban dimensions of collective mobility and flexibilisation of transport services.

<p>The magnetospheric cusps are two funnel-like regions of Earth's magnetosphere where solar wind plasma can have direct access to the ionosphere. The cusps are very dynamic regions where wave-particle interactions continuously take place and redistribute energy among different particle populations. In this thesis, both low and high frequency plasma waves in the cusp have been studied in detail using data from the Cluster spacecraft mission. The waves were studied with respect to frequency, Poynting flux and polarization. Wavelengths have also been estimated using multi-spacecraft techniques. At low frequencies, kinetic Alfvén waves and nonpotential ion cyclotron waves are identified and at high frequencies, electron cyclotron waves, whistler waves, upper-hybrid and RX-waves are observed. A common generation mechanism called the shell-instability is proposed for several of the wave modes present in the cusp, both at low and high frequencies. </p><p>The plasma in the cusp is shown to be strongly inhomogeneous. In an inhomogeneous low-frequency magnetoplasma, kinetic Alfvén waves couple to drift-waves. Such drift-kinetic Alfvén waves have long been believed to nonlinearly self-interact and form coherent structures in the form of drift-kinetic Alfvén vortices. In this thesis the first unambiguous direct measurements confirming the existence of such vortices in a turbulent space plasma are presented. Some of the crucial parameters such as the vortex radius are determined. </p><p>Plasma theory is electrodynamics applied to a large collection of charged particles. In this thesis a new way of looking at the fundamental Maxwell tensor is presented. A covariant spectral density tensor containing information on electromagnetic waves is formed. This tensor is then decomposed into irreducible components by using the spinor formalism for an arbitrary metric. The obtained fundamental tensors are shown to correspond both to well known tensors in Maxwell's theory, as well as several physically interesting new tensors.</p>

A training method utilized in a few martial arts was found to agree strongly with current cognitive psychology theory. Further study extracted a procedural model for learning a complex set of whole-body, dyadic motor skills involving high-speed, interactive, continuous situation assessment and decision making. A broader literature survey found relevance in several fields of research, supporting the definition of four performance dimensions in the activity. Data collected from one experienced student partnering with each of ten students of various experience levels was analyzed on these four dimensions. These dimensions were found sufficient to show both individual differences and changes across an instructional intervention. Strong correlations found under linear regression were supportive of anecdotal evidence from the model??s long empirical history in training. Data provided evidence of a self-organizing dynamic emerging from the interaction of a dyad participating in this activity, and of individual differences in cognitive resource management dynamically setting allocation priorities among specific aspects of a complex motor/cognitive activity. Highly individual responses demonstrate a mechanism for insight into students that are difficult to read. Numerous comparisons and contrasts show interactivity of performance dimensions. Impact is foreseen for research, training and testing in motor learning fields, as well as situation awareness, decision making and military tactical training. Further research is recommended to replicate these findings, test hypotheses derived from them, and to extend testing of the drill-network model into other fields of learning.

The magnetospheric cusps are two funnel-like regions of Earth's magnetosphere where solar wind plasma can have direct access to the ionosphere. The cusps are very dynamic regions where wave-particle interactions continuously take place and redistribute energy among different particle populations. In this thesis, both low and high frequency plasma waves in the cusp have been studied in detail using data from the Cluster spacecraft mission. The waves were studied with respect to frequency, Poynting flux and polarization. Wavelengths have also been estimated using multi-spacecraft techniques. At low frequencies, kinetic Alfvén waves and nonpotential ion cyclotron waves are identified and at high frequencies, electron cyclotron waves, whistler waves, upper-hybrid and RX-waves are observed. A common generation mechanism called the shell-instability is proposed for several of the wave modes present in the cusp, both at low and high frequencies. The plasma in the cusp is shown to be strongly inhomogeneous. In an inhomogeneous low-frequency magnetoplasma, kinetic Alfvén waves couple to drift-waves. Such drift-kinetic Alfvén waves have long been believed to nonlinearly self-interact and form coherent structures in the form of drift-kinetic Alfvén vortices. In this thesis the first unambiguous direct measurements confirming the existence of such vortices in a turbulent space plasma are presented. Some of the crucial parameters such as the vortex radius are determined. Plasma theory is electrodynamics applied to a large collection of charged particles. In this thesis a new way of looking at the fundamental Maxwell tensor is presented. A covariant spectral density tensor containing information on electromagnetic waves is formed. This tensor is then decomposed into irreducible components by using the spinor formalism for an arbitrary metric. The obtained fundamental tensors are shown to correspond both to well known tensors in Maxwell's theory, as well as several physically interesting new tensors.

A method is described for preset-count irradiations between 1 and 100 ions singling-out individual ions from an ion beam with more than a billion ions arriving per second. The ion tracks are etched in a conductometric system with real-time evaluation of the acquired data. The etch process can be interrupted when reaching a preset channel diameter. Cylindrical channels are obtained by adding surfactants to the etch solution forming a self-assembled barrier between etching medium and polymer. Asymmetric etching of single ion tracks leads to pH sensitive conical pores with diode-like properties. Using etched channels as template, homogeneous and multilayer magnetic single-wires are electrodeposited. The magnetoresistivity of the wires is studied. Single-track applications comprise critical apertures (cylindric, conic, necked), asymmetric pores (pH sensitive, biospecific), Giant Magneto Resistance sensors, and spintronic devices. On the basis of studies with individual ion tracks we tackled tilted multiporous systems such as ion beam lithography with a masked ion beam leading to micro-structures with inclined walls and anisotropic superhydrophobic ion track textures, analogous to biological shingle structures on butterfly wings. We demonstrated qualitatively, that the asymmetry of the texture translates into motion under ultrasonic agitation. This could lead to the development of rotary drives.

Das stäbchenförmige Bakterium Escherichia coli teilt sich in zwei gleich große Tochterzellen. Dies ist nur möglich, wenn sich die Zelle in der Mitte teilt. Bei E. coli wird die Zellteilung durch den Zusammenschluss der FtsZ-Proteine an der Membran zum Z-Ring eingeleitet. Topologische Regulierung des Z-Ringes erfolgt durch räumlich-zeitliche Oszillationen von Min-Proteinen zwischen den beiden Zellpolen. MinC, MinD und MinE binden an und lösen sich von der Membran unter Hydrolyse von ATP und in antagonistischer Art und Weise, was zu einer alternierenden Ansammlung von MinC und MinD an den Zellpolen führt. Gemittelt über die Zeit ergibt sich somit ein MinD-Verteilungsprofil, das maximale Konzentration an den Zellpolen und ein Minimum in der Zellmitte aufweist. MinC bindet an MinD und folgt somit seiner Verteilung. Der Zusammenschluss von FtsZ-Proteinen wird durch MinC unterbunden, und somit kann sich der Z-ring nur an einer Position herausbilden, die ein Minimum an MinC aufweist - der Zellmitte. Das Min-system wurde in der Vergangenheit auch mit einem in-vitro-Ansatz untersucht, indem Min-Proteine in künstliche, aufliegende Lipiddoppelschichten (supported lipid bilayers, SLB) rekonstitutiert wurden. Dabei bildeten die Min-Proteine kein oszillierendes Muster aus, sondern organisierten sich vielmehr in parallelen und propagierenden Wellen (Loose, 2008, Science, 320). In diesen in-vitro-Experimenten war das Membransubstrat wesentlich größer als die Wellenlänge der Min-Proteinwellen. In vivo hingegen ist die Länge der Zelle in der gleichen Größenordnung wie die charakteristische Länge des Oszillationsmusters der Min-Proteine. Daher war es das Ziel dieser Arbeit, den Einfluß einer beschränkten Fläche und geometrischer Formgebung der künstlichen Lipiddoppelschichten auf die Wellenpropagation der Min-Protein zu untersuchen. Flächige Beschränkung künstlicher Membranen erfolgte durch Mikrostrukturtechnologie. Deckglässchen wurden mit einer Goldschicht und mikroskopischen Aussparungen unterschiedlicher geometrischer Formen strukturiert. Funktionale SLBs bildeten sich nur auf Glasflächen ohne Goldbeschichtung aus. Nach der Rekonstitution der Min-Proteine, organisierten sich diese auf den Membranstücken in parallele Wellen. Dabei bestimmte die flächige Beschränkung der künstlichen Membranen die Ausbreitungsrichtung der Min-Proteinwellen. Min-Proteinwellen konnten entlang gekrümmter Membranstreifen, in Ring- und sogar in Slalomstrukturen geleitet werden. In geraden, länglichen Strukturen richteten sich die Wellen entlang der längsten Achse aus. Kopplung von Proteinwellen auf räumlich getrennten Membranstücken in Abhängigkeit des Abstandes und des sogenannten Molecular Crowdings in der wässrigen Lösung konnte ebenfalls beobachtet werden. Diese Kopplung ist ein Indiz für inhomogene Proteinverteilungen in der Lösung oberhalb der Membran. Desweiteren konnten Min-Proteinwellen auch in diversen dreidimensionalen künstlichen Membranen rekonstitituiert werden. Im Wildtyp von E. coli ähneln die Min-Proteindynamiken der einer Oszillation mit einer charakteristischen Länge von 5 µm. Auf SLBs, bilden Min-Proteine Wellen mit einer Wellenlänge aus, die ca. zehnmal größer ist als in vivo. Dieser Unterschied zwischen der in-vivo- und der in-vitro-Welt wurde untersucht und diskutiert. In vitro konnte die Wellenlänge um 50 % durch Erhöhung des Molecular Crowding in der Lösung sowie um 33 % durch Temperaturerhöhung verkleinert werden. Das oszillierende Muster könnte dahingegen eine Folge der Kompartimentierung sein. Erste Versuche, das Min-System in geschlossene Membrankompartimente zu rekonstitutieren, wurden getestet. / Escherichia coli, a rod-like bacterium, divides by binary fission. Cell division into two daughter cells of equal size requires that fission takes place at a midcell position. In E. coli, cell division is initiated by assembly of the FtsZ-proteins at the inner membrane to the Z-ring. Topological regulation of the Z-ring is achieved by spatiotemporal pole-to-pole oscillations of Min-proteins. MinC, MinD and MinE bind to and detach from - under hydrolysis of ATP - the membrane in an antagonistic manner leading to an alternating accumulation of MinC and MinD at the cell poles. Averaged over time, the distribution profile of MinD exhibits maximal concentration at the cell poles and a minimum at the cell center. MinC binds to MinD and thus follows its distribution. FtsZ assembly is inhibited by MinC and therefore the Z-ring can only form at a cell position low in MinC - at the cell center. In the past, the Min-system was also investigated in an in vitro approach by reconstitution of Min-proteins into a supported lipid bilayer (SLB). Here, Min-proteins did not self-organize into an oscillatory pattern but into parallel and propagating waves (Loose, 2008, Science, 320). In this in vitro assay, the membrane substrate was infinitely large compared to the wavelength. However, in vivo, the cell length is on the same order of magnitude as the respective length scale of the oscillatory pattern of Min-proteins. Therefore, we wished to investigate the effect of lateral confinement and geometric structuring of artificial lipid bilayers on the Min-protein wave propagation. Lateral confinement of artificial membranes was achieved by microfabrication technology. Glass slides were patterned by a gold coating with microscopic windows of different geometries, and functional SLBs were only formed on uncoated areas. Upon reconstitution, Min-proteins organized into parallel waves on the geometric membrane patches. Confinement of the artificial membranes determined the direction of propagation of Min-protein waves. Min-protein waves could be guided along curved membrane stripes, in rings and even along slalom-geometries. In elongated membrane structures, the protein waves always propagate along the longest axis. Coupling of protein waves across spatially separated membrane patches was observed, dependent on gap size and level of molecular crowding of the aqueous media above the bilayer. This indicates the existence of an inhomogeneous and dynamic protein gradient in the solution above the membrane. Furthermore, reconstitution of Min-protein waves in various three-dimensional artificial membranes was achieved. In wild-type E. coli, Min-protein dynamics resemble that of an oscillation with a characteristic length scale of 5 µm. On supported lipid bilayers, Min-proteins self-organize into waves with a wavelength approximately 10-fold larger than in vivo. These discrepancies between the in vivo and in vitro world were investigated and discussed. In vitro, the wavelength could be decreased by a factor of 50 % by increase of the molecular crowding in solution and by 33 % through temperature increase. The oscillatory pattern is thought to be a consequence of compartmentalization and first attempts to encapsulate the Min-system in closed bilayer compartments are presented.