Orientador: Ana Maria Rodrigues Cassiolato / Banca: Luiz Antonio Graciolli / Banca: Gilberto Colodro / Resumo: O solo é um meio que engloba diferentes substâncias químicas e colóides e uma alta diversidade biológica. Estes componentes apresentam íntima relação funcional para sustentabilidade dos ecossistemas e, sua degradação, geralmente causada pela ação antrópica, acarreta um grande prejuízos ambientais e socioeconômicos para as gerações atuais e um enorme risco para as gerações futuras. Para reverter um processo como este, são necessárias intervenções por meio de estratégias como a revegetação. O objetivo do trabalho foi avaliar crescimento e colonização micorrízica do pinhão manso em solo decaptado que recebeu inoculo de fungos micorrizicos arbusculares, hidrogel e materiais orgânicos. O experimento foi conduzido de maio de 2008 a maio 2009, na Fazenda de Ensino, Pesquisa e Extensão (FEPE) da UNESP - Universidade Estadual Paulista, Campus de Ilha Solteira, no município de Selvíria-MS. O delineamento experimental foi o em blocos casualizado, em esquema fatorial 4x2x2, ou seja, 3 tratamentos com material orgânico (aguapé, composto e aguapé+composto), 2 tratamentos com hidrogel (com e sem adição) e 2 tratamentos de inoculação (com e sem inoculação) empregando solo proveniente de uma área preservada de cerrado como fonte de microrganimos, incluíndo fungos micorrízicos arbusculares, com 4 repetições e 5 plantas por tratamentos. O composto foi preparado com materiais de poda e esterco de bovino. Avaliou-se: o crescimento das plantas em 7 épocas diferentes, a caracterização química e número de esporos em 4 épocas, além da porcentagem de colonização micorrízica, presença de flores, número de ramos e de folhas e peso fresco e seco da parte aérea. O tratamento com hidrogel não mostrou interferência no crescimento de plantas, mas, assim como o solo-inóculo, aumentou a esporulação, a colonização micorrízica e a produção de matéria seca... (Resumo completo, clicar acesso eletrônico abaixo) / Abstract: The soil is a medium that contain different chemical substances and colloids and a high biological diversity. These components have functional relationship on the sustainability of ecosystems and their degradation, usually caused by human action, which causes great socio-economic damage to the present generations and an enormous risk for the future generations. To reverse such process, action is needed using strategies, such as, revegetation. The objective of this study was to evaluate the growth and mycorrhiza colonization of Jatropha on decapitated soil that received organic materials and hydrogel. The experiment was conducted from May 2008 to May 2009, the Farm Education, Research and Extension (FEPE), UNESP - Univ. Estadual Paulista, Ilha Solteira Campus, located at Selvíria city-MS, Brazil. The experimental design was randomized blocks in factorial scheme 3x2x2, i.e., 3 treatments with organic materials (water hyacinth, compost and water hyacinth + compost), 2 hydrogel treatments (with and without addition) and 2 inoculations treatments (with and without inoculation) using natural soil from a preserved 'cerrado' area as a source of microorganisms, including mycorrhizal fungi, with 4 replications and 5 plants per each. The compound was prepared with materials pruning and cow dung. The growth of plants in 7 different times, the chemical characterization and number of spores in 4 times, and the percentage of mycorrhizal colonization, presence of flowers, branches and leaves and fresh and dry weight of air part was evaluated. Treatment with hydrogel showed no interference with the growth of plants; however, as well as the soilinoculum, they increased sporulation, root colonization and production of dry matter. The organic materials treatments positively altered the condition of the ground, plant growth, mycorrhizal colonization and sporulation; the improved performances... (Complete abstract click electronic access below) / Mestre

Made available in DSpace on 2014-06-11T19:29:42Z (GMT). No. of bitstreams: 0 Previous issue date: 2010-01-15Bitstream added on 2014-06-13T20:39:15Z : No. of bitstreams: 1 santos_aa_me_ilha.pdf: 676511 bytes, checksum: f49f6d1a9f6dfba6539f793f9e93426c (MD5) / Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES) / O solo é um meio que engloba diferentes substâncias químicas e colóides e uma alta diversidade biológica. Estes componentes apresentam íntima relação funcional para sustentabilidade dos ecossistemas e, sua degradação, geralmente causada pela ação antrópica, acarreta um grande prejuízos ambientais e socioeconômicos para as gerações atuais e um enorme risco para as gerações futuras. Para reverter um processo como este, são necessárias intervenções por meio de estratégias como a revegetação. O objetivo do trabalho foi avaliar crescimento e colonização micorrízica do pinhão manso em solo decaptado que recebeu inoculo de fungos micorrizicos arbusculares, hidrogel e materiais orgânicos. O experimento foi conduzido de maio de 2008 a maio 2009, na Fazenda de Ensino, Pesquisa e Extensão (FEPE) da UNESP – Universidade Estadual Paulista, Campus de Ilha Solteira, no município de Selvíria-MS. O delineamento experimental foi o em blocos casualizado, em esquema fatorial 4x2x2, ou seja, 3 tratamentos com material orgânico (aguapé, composto e aguapé+composto), 2 tratamentos com hidrogel (com e sem adição) e 2 tratamentos de inoculação (com e sem inoculação) empregando solo proveniente de uma área preservada de cerrado como fonte de microrganimos, incluíndo fungos micorrízicos arbusculares, com 4 repetições e 5 plantas por tratamentos. O composto foi preparado com materiais de poda e esterco de bovino. Avaliou-se: o crescimento das plantas em 7 épocas diferentes, a caracterização química e número de esporos em 4 épocas, além da porcentagem de colonização micorrízica, presença de flores, número de ramos e de folhas e peso fresco e seco da parte aérea. O tratamento com hidrogel não mostrou interferência no crescimento de plantas, mas, assim como o solo-inóculo, aumentou a esporulação, a colonização micorrízica e a produção de matéria seca... / The soil is a medium that contain different chemical substances and colloids and a high biological diversity. These components have functional relationship on the sustainability of ecosystems and their degradation, usually caused by human action, which causes great socio-economic damage to the present generations and an enormous risk for the future generations. To reverse such process, action is needed using strategies, such as, revegetation. The objective of this study was to evaluate the growth and mycorrhiza colonization of Jatropha on decapitated soil that received organic materials and hydrogel. The experiment was conducted from May 2008 to May 2009, the Farm Education, Research and Extension (FEPE), UNESP - Univ. Estadual Paulista, Ilha Solteira Campus, located at Selvíria city-MS, Brazil. The experimental design was randomized blocks in factorial scheme 3x2x2, i.e., 3 treatments with organic materials (water hyacinth, compost and water hyacinth + compost), 2 hydrogel treatments (with and without addition) and 2 inoculations treatments (with and without inoculation) using natural soil from a preserved ‘cerrado’ area as a source of microorganisms, including mycorrhizal fungi, with 4 replications and 5 plants per each. The compound was prepared with materials pruning and cow dung. The growth of plants in 7 different times, the chemical characterization and number of spores in 4 times, and the percentage of mycorrhizal colonization, presence of flowers, branches and leaves and fresh and dry weight of air part was evaluated. Treatment with hydrogel showed no interference with the growth of plants; however, as well as the soilinoculum, they increased sporulation, root colonization and production of dry matter. The organic materials treatments positively altered the condition of the ground, plant growth, mycorrhizal colonization and sporulation; the improved performances... (Complete abstract click electronic access below)

In my master’s degree project in Design at Konstfack, completed and presented during the spring semester of 2022, I combine three of my competencies: Applied knowledge in industrial design, textile and pattern construction and textile materials science. The project was carried out in contact with many different actors, in the industrial design field as well as the textile field. 92% of the garments we wash, we wash unnecessarily. Many garments are washed after just one use. Washing less reduces the wear and tear of the fabric. If we extend the life of the garment by one year, we can reduce our carbon footprint by 25%. Sweat is one of the main reasons why we wash, although the whole fabric does not need to be cleaned. Based on the collected user data, the armpit was identified as one of the primary problem areas. I am developing an absorbent patch for the armpit. This product consists of circular textile materials, in symbiosis with function and shape. The product’s imprint is traceable, as well as transparent in manufacturing. With this absorbing patch, I want to contribute to a sustainable change in the fast-fashion industry by affecting design thinking, demand and consumerism. This project focuses on how we can practice washing less, by identifying behavior patterns, material research in textiles and circular design in product development. Last but not least it is a close study of a product category and how it can be developed. Hence the title: VETT. - “common sense”.

The following project has been carried out in collaboration with Abstracta AB (AAB), a company based in Lammhult with specialization in sound landscapes for indoor environments. The company manufactures different types of products with sound-absorbing properties where sustainability and design are in great focus. A new product idea of the company is based on developing an A-classified discreetly designed wall absorber that is considered more as a "wall" than a "wall with mounted absorbent on". The purpose of the project was to develop the following product on a conceptual level. A main research question with two underlying issues was developed that served as a support during the project. Question 1: How can an A-rated discreetly designed sound wall absorber be developed? 1.a: How can an A-rated sound wall absorber be developed? 1.b: How can a sound wall absorber achieve a discreetness in its design? The project followed a product development process where the mainly focus was on concept development and concept testing. The concept was developed based on data collected from a literature study and with the use of a sound absorption calculator. A sound absorption test and an examination form regarding the discrete modeling and design of the absorbent were performed for the final concept that the project resulted in. The project showed that an A-rated discreetly designed sound wall absorber can be developed through a process where design-critical specifications that affect the absorber's discrete design control how the object can be modeled. Via a sound absorption calculator, concepts can be designed that theoretically indicate an A-rate while the design-critical specifications are not exceeded. Based on the concept, a prototype is manufactured that can undergo a sound absorption test to determine the absorbent's actual sound absorption capacity. Finally, an examination is made to analyze whether the absorbent is considered a discrete alternative or not. Based on the project's results, the work process proved to be advantageous as the concept indicated a sound absorption capacity that exceeded the requirements of the A-rating and at the same time obtained a discreet design and modeling. This was achieved in connection with the manufacturing materials achieving their technical specifications and a square meter cost lower than expected. Based on the project's results, the work process proved to be advantageous as the concept indicated a sound absorption capacity that exceeded the requirements of the A-rating and at the same time obtained a discreet design and modeling. This was achieved in connection with the manufacturing materials achieving their technical specifications and a square meter cost lower than expected. In the further development of the final concept, a solution for how the absorbent is to be mounted on the wall must be developed as this was not focused on in the project based on its boundaries. To achieve a valid A-rate, an additional sound absorption test must also be performed where a larger object area of 10–12 m2 is tested. In future work, the concept's discrete modeling and design should also be examined based on physical treatment to review how the examination form's response results relate to this. / Följande projekt utförs i samarbete med Abstracta AB (AAB), ett företag som är stationerat i Lammhult och är specialiserade inom ljudlandskap för inomhusmiljöer. Företaget framställer olika typer av produkter med ljudabsorberande egenskaper där hållbarhet och design även är i stort fokus. En ny produktidé av företaget grundar sig i att utveckla en A-klassificerad diskret utformad väggabsorbent som betraktas mer som en ”vägg” än en ”vägg med uppmonterad absorbent på”. Syftet med projektet var att framta följande produkt på en konceptuell nivå. En huvudsaklig forskningsfråga med två underliggande frågeställningar togs fram som fungerade som ett stöd under projektets gång. Fråga 1: Hur kan en A-klassificerad diskret utformad ljudväggabsorbent utvecklas? 1.a: Hur kan en A-klassificerad ljudväggabsorbent utvecklas? 1.b: Hur kan en ljudväggabsorbent uppnå en diskrethet i sin design? Projektet följde en produktutvecklingsprocess där det största fokuset låg på konceptutvecklingen och koncepttestningen. Koncepten utvecklades utifrån insamlade data från en litteraturstudie och med användning av en ljudabsorptionskalkylator. Ett ljudabsorptionstest och ett undersökningsformulär gällande absorbentens diskreta utformning och design utfördes för det slutgiltiga konceptet som projektet resulterade i. Projektet visade att en A-klassificerad diskret utformad ljudväggabsorbent kan utvecklas genom en process där designkritiska specifikationer som berör absorbentens diskreta utformning styr hur objektet kan formges. Via en ljudabsorptionskalkylator kan koncept designas som teoretiskt indikerar en A-klassning samtidigt som de designkritiska specifikationerna ej överskrids. Utifrån konceptet tillverkas en prototyp som kan genomgå ett ljudabsorptionstest för att fastställa absorbentens verkliga ljudupptagningsförmåga. En undersökning görs slutligen för att analysera huruvida absorbenten betraktas som ett diskret alternativ eller ej. Utifrån projektets resultat visade sig arbetsprocessen vara fördelaktig då konceptet påvisade en ljudabsorptionsförmåga som överträffade A-klassningens krav och samtidigt erhöll en diskret utformning och design. Detta åstadkom i samband med att tillverkningsmaterialen uppnådde sina tekniska specifikationer och en kvadratmeterkostnad lägre än väntat. I fortsatt utveckling av det slutgiltiga konceptet måste en lösning till hur absorbenten ska monteras på väggen tas fram eftersom detta inte fokuserades på i projektet utifrån dess avgränsningar. För att en giltig A-klassificering ska nås måste även ytterligare ett ljudabsorptionstest utföras där en större objektarea på 10–12 m2 testas. I framtida arbete bör även konceptets diskreta utformning och design undersökas utifrån fysiska bemötanden för att granska hur undersökningsformulärets svarsresultat förhåller sig till detta.

Sontech International AB är ett företag som är specialiserade på ljudabsorbenter i metall och skum. De har tagit fram en ljudabsorbent i kartong med slitsar som går längs arket med ett avstånd på max 5 mm mellan dem. Denna produceras idag med en CNC-maskin och det tar 17 minuter per kvadratmeter att producera absorbenten med 5 mm mellan slitsarna. För att produkten ska vara lönsam behöver produktionstiden ned på en minut per kvadratmeter. Det är ett relativt litet företag med stora kunder och har därför inte tid eller resurser att lägga på att utveckla produktionen av den. Därför har författarna fått i ansvar att som examensarbete inom maskinteknik försöka utveckla och till sist presentera en färdig modell på en maskin för lösningen. Efter skisser, prototyper och val mellan tre färdiga modeller på föll valet på maskinen vid namn Krattan. Krattan drivs med två pneumatiska cylindrar som lyfter upp arket och drar vad som kallas krattan som består av 199 knivar tvärs över det. Produktionstiden uppskattas ha sjunkit till ca 20 sekunder per kvadratmeter kartongark. / Sontech International AB is a company that specializes in sound absorbents made of metal and foam. They have a new product that is a sound absorbent made of cardboard with cuts along the sheet of cardboard with a maximum distance between the cuts of 5 mm. This product is made with a CNC-machine and it takes 17 minutes per square meter to produce a sheet with 5 mm between each cut. To make the product viable the production time needs to come down to a minute per square meter. Sontech is are latively small company which is why they have not been able to spare the resources to develop a solution for manufacturing this product. The writers have based their thesis paper in mechanical engineering on developing and presenting a complete model of a machine as a method of production. After many sketches, prototypes and a selection between three different solutions they picked a machine that they refer to as ‘‘The rake’’. ‘’The rake’’ is powered by two pneumatic cylinders. One cylinder lifts the sheet of cardboard and either pushes or pulls ‘’the rake’’ part of the machine that is made of 199 blades. The production time is estimated to be about twenty seconds per square meter of cardboard.

Incontinence diapers or disposable absorbent pads provide essential help to people having such a physical difficulty. However, during prolonged used of these products in daily life, the skin inside pad area may get fragile and damaged which are difficult to recover in old ages. Therefore a skin friendly sensor can be added to the inner layer of pad that would monitor the skin condition and signal any abnormalities to the wearer. Smart materials which can change color upon variation of skin pH were incorporated with synthetic nonwoven layers of the pad. Among various incorporation methods of these materials, ‘sol-gel’ coating technique was found to be successfulfor applications on optical sensor and on fewother fabric types. Thus ‘sol-gel’ method with modified recipe for different dye and chemical combinations were experimented in this project.Several developed samples showed color change (e.g. yellow to red) that can be easily detected by wearers’ eyes.Additionally, the methods and materials involved showed no adverse effect on health and environment. Thus this study succeeds to provide with a mean for skin health monitor based on nonwoven textiles by incorporation of color changing materials.

Det overordnede målet med denne avhandling var å få en oversikt over ulike forstyrrelser i de nedre urinveier hos gamle. Dernest var målet å beskrive oppfatninger og barrierer som influerte på personalets muligheter for å gi riktig inkontinenspleie til beboere i sykehjem. Avhandlingen består av en kvantitativ studie (artikkel I, II, III), og en kvalitativ studie (artikkel IV). Artikkel I var en tverrsnittstudie. Artikkel II og III var en prospektiv tidsdesignstudie med en oppfølgingsperiode på ett år. 183 beboere fra seks sykehjem deltok i den kvantitative studien. I artikkel I ble prevalensen av urininkontinens hos norske sykehjembeboere evaluert. I tillegg ble det forsøkt å identifisere faktorer som var assosiert med urininkontinens i denne populasjonen. I artikkel II ble det undersøkt om residualurin var en risiko for å utvikle urinveisinfeksjon hos gamle på sykehjem. I artikkel III ble det undersøkt om bleiebruk per døgn er en pålitelig metode for å kvantifisere urininkontinens hos sykehjemsbeboere. Det ble også studert om det var sammenheng mellom urinveisinfeksjon, bleiebruk per døgn og væskeinntak. I den kvalitative studien var målet å identifisere oppfatninger og barrierer som influerte på pleiernes muligheter for å gi riktig inkontinenspleie. Fem avdelingsledere, fem sykepleiere og fem hjelpepleiere ble intervjuet i til sammen tre fokusgruppeintervjuer.Analysen i artikkel I viste at 122 beboere (69 %) var inkontinent for urin og 144 (83 %) brukte bleier. 14 % brukte bleier for sikkerhets skyld. Lav ADL-skår, demens og urinveisinfeksjon var assosiert med urininkontinens (P = <0.01). I artikkel II hadde 98 beboere (63.3 %) residualurin mindre enn 100 ml, og 52 (34.7 %) hadde residualurin på 100 ml eller større. I løpet av oppfølgingsperioden hadde 51 beboere (34 %) utviklet en eller flere urinveisinfeksjoner. Forekomsten av urinveisinfeksjon var høyere hos kvinnene enn hos mennene (40.4 % versus 19.6 %; P = 0.02). Det ble ikke funnet noen signifikant forskjell i gjennomsnittlig residualurin mellom beboere som utviklet og som ikke utviklet urinveisinfeksjon (79 versus 97 ml, P = 0.26). Residualurin på 100 ml eller større var ikke assosiert med større risiko for utvikling av urinveisinfeksjon.I artikkel III brukte 118 (77 %) av beboerne bleier. Bleiebruk per døgn er et upålitelig mål på urininkontinens hos beboere i sykehjem. Beboere som brukte bleier hadde en økende risiko for å utvikle urinveisinfeksjon sammenlignet medvibeboere som ikke brukte bleier (41 versus 11 %; P = 0.001). Daglig væskeinntak var ikke assosiert med urinveisinfeksjoner (P = 0.46). Antall bleieskift viste ingen korrelasjon med risikoen for utvikling av urinveisinfeksjon (P = 0.62). Bleiene som beboerne brukte per døgn, viste stor variasjon i inkontinensvolum. I den kvalitative studien ledet innholdsanalysen fram til tre emner og åtte kategorier. Det første emnet, Oppfatninger og barrierer assosiert med beboerne, inneholdt en kategori ”fysiske og kognitive problemer”. Det andre emnet, Oppfatninger og barrierer assosiert med personalet, inneholdt tre kategorier: ”manglende kunnskaper”, ”holdninger og tro” og ”manglende tilgjengelighet”. Det tredje emnet, Oppfatninger og barrierer assosiert med den organisatoriske kulturen, inneholdt fire kategorier: ”rigide rutiner”, manglende ressurser”, ”manglede dokumentasjon” og ”svakt lederskap”. Resultatene i denne avhandlingen viser at forekomsten av urininkontinens i sykehjem er høy. Absorberende produkter er hyppig brukt uten en kjent historie av urininkontinens. Fysisk svekkelse, demens og urinveisinfeksjon er assosiert med urininkontinens. Residualurin er vanlig hos beboere i sykehjem. Det ble ikke funnet noen sammenheng mellom residualurin og urinveisinfeksjon. Bruk av absorberende bleier er assosiert med økt risiko for utvikling av urinveisinfeksjon. Bleiebruk per døgn og væskeinntak var ikke korrelert med økt risiko for utvikling av urinveisinfeksjon. Bleiebruk per døgn er et upålitelig mål på urininkontinens hos beboere i sykehjem. Funnene fra den kvalitative studien viser at det er mange barrierer som influerer på personalets evne til å gi riktig inkontinenspleie til beboere i sykehjem. Det kan likevel se ut som om personalets oppfatninger og holdninger, samt manglende kunnskaper om urininkontinens, er de viktigste barrierene for å gi riktig inkontinenspleie. / The overall aim of this thesis was to get an overview over different dysfunction in the lower urinary tract in the elderly. Also, we wanted to describe the perceptions and barriers that influence the nursing staff`’s ability to provide appropriate incontinence care in nursing home residents. The thesis includes one quantitative study (paper I, II, III), and one qualitative study (paper IV). Paper I was a cross-sectional study. Paper II and III were a prospective surveillance with a follow-up period of 1 year. 183 residents from six Norwegian nursing homes participated. In paper I, the prevalence of urinary incontinence in Norwegian nursing home residents was evaluated. The factors possibly associated with urinary incontinence were also studied. In paper II, we investigated whether residual urine was a risk factor for developing urinary tract infections in the elderly in nursing homes. In paper III, the objective was to determine whether pads per day usage is a reliable measure of urinary incontinence in nursing home residents. Furthermore, we wanted to study the association between urinary tract infections, pads per day usage and fluid intake. In the qualitative study, the aim was to identify perceptions and barriers that influence the ability of nursing staff to provide appropriate incontinence care. Five charge nurses, five registered nurses and five certified nursing assistants participated in the focus group interviews.The analysis in paper I, showed that 122 (69 %) of the resident were incontinent for urine and 144 used absorbent pads (83 %). 14 % of residents used absorbent pads ‘just to make sure’. They did not have a history of urinary incontinence. Low ADL score, dementia and urinary tract infection were significantly associated with incontinence for urine (P = <0.01). In paper II, 93 of the residents (65.3 %) had postvoid residual urine (PVR) < 100 mL and 52 residents (34.7 %) had a PVR 100 mL. During the follow-up period, 51 residents (34.0 %) had one or more urinary tract infections (UTI). The prevalence of UTI among females was higher than among men (40.4 % versus. 19.6 %; P = 0.015). There was no significant difference in mean PVR among residents that did or did not develop UTI (79 mL versus 97mL; P = 0.26). A PVR 100 mL was not associated with an increased risk of developing UTI`s (P = 0.59).In paper III, 118 (77 %) used absorbent pads. Residents that used absorbent pads were at increased risk of developing UTIs compared to residents that did notviiiuse pads (41 % versus 11 %; P = 0.001). Daily fluid intake was not associated with UTIs (P = 0.46). The number of pad shifts had no relation with the risk of developing UTIs (P = 0.62). Residents with a given pad per day (PPD) presented a wide range of incontinence volumes.In paper IV, three topics and eight categories were identified. The first topic, Perceptions and barriers associated with residents, consisted of one category: ‘physical and cognitive problems’. The second topic, Perceptions and barriers associated with nursing staff, consisted of three categories: ‘lack of knowledge’, ‘attitudes and beliefs’ and ‘lack of accessibility’. The third topic, Perceptions and barriers associated with organizational culture, consisted of four categories: ‘rigid routines’, ‘lack of resource’, ‘lack of documentation’ and ‘lack of leadership’.The results of the thesis show that the prevalence of urinary incontinence in nursing homes is high. Absorbent products are frequently used without a history of urinary incontinence. Physical impairment, dementia and urinary tract infections are associated with urinary incontinence. is common in nursing home residents. No association between PVR and UTI was found. The use of absorbent pads is associated with an increased risk of developing UTIs. PPD and daily fluid intake are not correlated with the risk of developing UTIs. PPD is an unreliable measure of urinary incontinence in nursing home residents. The findings from the qualitative study shows that there are many barriers that might influence the possibilities of nursing staff to provide appropriate incontinence care to residents in nursing homes. However, it can nevertheless seem like opinions and the attitude of nursing staff, together with a lack of knowledge about urinary incontince, are the most important barriers to provide appropriate incontinence care.

Polar organic compounds (POCs) are chemicals with polar functional groups in their structure. The functional groups make the compounds hydrophilic and less prone to partition with biota. However, the knowledge of their fate is limited due to difficulties associated with their measurements. Although, the persistence of POCs in the environment is generally low, they are considered to be semi-persistent compounds due to their continuous introduction to the environment via wastewater. Studies have shown that complex mixtures of POCs of different classes may have synergistic toxic effects on biota at environmental concentration levels. Therefore, it is important to develop analytical methods in order to establish the occurrence and fate of POCs in aquatic environments. In Study I, a positive correlation between the sorption of a novel poly(ethylene-co-vinyl acetate-co-carbon monoxide) (PEVAC) material and the theoretical logarithmic dissociation partition coefficient (Log D) for seven POCs was observed. The PEVAC material showed an enhanced sorption of the POCs compared to the silicone material. Study II, demonstrated that the PEVAC sampler assess the freely dissolved concentration of POCs in aquatic environments. The results showed that the PEVAC polymer is an attractive alternative to silicone for mimicing the biological uptake of POCs in aquatic environments. Additionally, Study II showed that total extraction is appropriate for determination of the freely dissolved concentration of uncharged POCs with Log KOW < 2.67 in natural water. In study III, a novel bag-solid phase extraction (bag-SPE) technique was compared to a conventional SPE-technique. Despite that the extraction efficiencies for POCs in wastewater were lower using the bag-SPE method, the two methods showed similar detection limits due to the lower ion-suppression experienced with the bag-SPE. In study IV the bag-SPE method was further developed with the aim of lowering the detection limits for POCs. Detection limits (LOD) below 13 ng/L showed that the bag-SPE method was suitable for determination of POCs in surface sea water. / This research was financially supported by European Union (European Commission, FP6 Contract No. 003956) “Novel Methods for Integrated Risk Assessment of Cumulative Stressors in the Environment” (NoMiracle) and by the Swedish research council Formas.

In dieser Dissertation wird ein Prozess für die absorptive CO2-Abtrennung aus Gasströmen vorgestellt, der durch die Nutzung des neu entwickelten Waschmittels GenosorbN in einem Postcombustion-Prozess einen geringeren Energiebedarf als bisher bekannte Verfahren aufweist. Für die Nachrüstung bereits vorhandener Kraftwerke ist der Postcombustion-Prozess vorteilhaft, da er im Vergleich zum IGCC- oder dem Oxyfuel-Verfahren die geringsten Änderungen im Kraftwerksprozess selbst erfordert. Die bisher für die CO2-Abtrennung diskutierten Absorptionsmittel, wie z. B. MEA (Mono-Ethanol-Amin), haben allerdings vor allem in der Regeneration einen sehr hohen Energiebedarf, der vom Kraftwerk zusätzlich zur Verfügung gestellt werden muss. In Zusammenarbeit zwischen dem Institut für Verfahrenstechnik und Umwelttechnik der TU Dresden und der Clariant GmbH wurde das Absorptionsmittel GenosorbN (chemische Bezeichnung: Poly(methyldiglykol)amin) entwickelt. GenosorbN weist als Hybrid-Waschmittel gegenüber CO2 sowohl physikalische als auch chemische Bindungseigenschaften auf. Ausgehend von der Löslichkeitscharakteristik dieses Absorptionsmittels für CO2 und wichtigen Stoffwerten (z. B. Wärmekapazität und Lösungswärme von CO2) wurden mit Hilfe eines umfangreichen Versuchsprogramms an einer Technikumsanlage Betriebsparameter für einen energetisch günstigen technischen Einsatz ermittelt. Dabei hat sich herausgestellt, dass der Absorptionsprozess mit unverdünntem GenosorbN gegenüber einer MEA-Wäsche bei einem CO2-Abscheidegrad von ca. 90 % einen um ca. 20 - 27 % geringeren Energiebedarf in der Waschmittelregeneration aufweisen kann. Außerdem ist für die Desorption ein energetisch minderwertiger Heizdampf mit geringerem Temperatur- bzw. Druckniveau als bei dem MEA-Prozess ausreichend, da die Regenerationstemperatur um 40 - 50 K niedriger ist. Eine zusätzliche Druckabsenkung auf 400 mbar Absolutdruck im Desorber begünstigt die Regeneration deutlich. / This dissertation presents a process for the absorptive CO2-separation from gas streams, which shows a lower energy requirement than established methods by using the newly developed absorption liquid GenosorbN in a postcombustion-process. To retrofit an already existing power plant, the postcombustion-process is advantageous, because it needs the least changes in the power plant-process itself compared to the IGCC- or the Oxyfuel-process. The absorbents discussed for the CO2-separation up to now, for example MEA (mono-ethanol-amine), cause a high energy requirement mainly in the solvent regeneration, which has to be provided additionally from the power plant. The solvent GenosorbN (chemical notation: poly(methyldiglycol)amine) was developed in cooperation between the Institute of Process Engineering and Environmental Engineering of the Technical University of Dresden and the Clariant GmbH. GenosorbN is a hybrid-absorbent and therefore it shows both physical and chemical bonding forces. Based on the solvents characteristic of solubility for CO2 and important data on chemical media (for example heat capacity and enthalpy of solution) operating parameters for an energetic advantageous technical application were identified by a lot of test series at a pilot plant. The measurements show that the absorption process with the undiluted GenosorbN has a circa 20 - 27 % lower energy demand for the solvent regeneration compared to the MEA-process to reach a degree of separation of 90 %. Furthermore a low-value heating steam with lower temperature and therefore lower pressure level suffices because of the significant lower (40 - 50 K) regeneration temperature. An additional pressure reduction to 400 mbar absolute pressure in the regeneration column favours the solvent regeneration considerably.

On s'intéresse dans ce travail au problème de propagation acoustique dans des guides à parois traitées avec des matériaux absorbants à réaction localisée ou non localisée en présence d'écoulement. En effet, dans les systèmes industriels comme les turboréacteurs d'avions, les silencieux d'échappement et les systèmes de ventilation, le bruit est le plus souvent canalisé vers l'extérieur par des guides de géométries plus ou moins complexes. Une étude des guides d'ondes permet donc de prédire et de comprendre les phénomènes physiques tels que la réfraction, la convection, l'absorption et l'atténuation des ondes. Dans l'étude des guides d'ondes, on considère souvent qu'ils sont infiniment longs afin de s'affranchir de certains phénomènes (réflexion par exemple) à leurs extrémités. Résoudre le problème de propagation dans les guides infinis par la méthode des éléments finis nécessite de tronquer le domaine infini par des frontières artificielles sur lesquelles des conditions limites transparentes doivent être écrites. Dans ce travail, les conditions limites transparentes sont écrites sous forme d'un opérateur Dirichlet-to-Neumann (DtN) basé sur une décomposition de la pression acoustique sur la base des modes propres du guide étudié tout en prenant en compte l'influence des paramètres comme l'écoulement et le traitement acoustique avec des matériaux absorbants. La propagation acoustique dans le guide est régie par un modèle scalaire basé sur l'équation de Helmholtz et les matériaux absorbants utilisés sont des matériaux absorbants d'impédance locale Z et des matériaux poreux. Nous nous sommes intéressés en particulier aux matériaux poreux ? squelette rigide que l'on modélise par un fluide équivalent car la propagation acoustique dans ces matériaux est aussi gouvernée par l'équation de Helmholtz comme dans un milieu fluide. Des résultats d'étude de la propagation acoustique dans des guides rectilignes uniformes traités en présence d'un écoulement uniforme ont permis de valider la méthode développée pour tronquer les domaines infinis. L'étude a aussi été menée avec succés pour des guides non uniformes traités en présence d'un écoulement potentiel. / Our concern in this work is the problem of acoustic propagation in guides lined with locally or non locally reacting materials with the presence of mean fluid flow. In several industrial systems such as aircraft jet engines, mufflers exhaust and ventilation systems, noise is mostly channeled outside by guides of more or less complex geometries. A study of waveguides makes it possible to predict and understand the physical phenomena such as refraction, convection, absorption and wave attenuation. In waveguides studies, guides are often considered infinitely long to get rid of some phenomena (reflection for example) at their ends. Solving the problem of acoustic propagation in infinite guides by finite element method requires to truncate the infinite domain by artificial boundaries on which transparent boundary conditions must be written. In this work, the transparent boundary conditions are written as a Dirichlet-to-Neumann (DtN) operators based on sound pressure decomposition on the eigenmodes basis of the studied guide by taking into account the influence of parameters such as flow and acoustic liners in the guide walls. Acoustic propagation in the guide is governed by a model based on the scalar Helmholtz equation and the used liners are locally reacting materials of local impedance Z and porous materials. In this study, we focused particularly rigid porous materials modelized by an equivalent fluid because the acoustic propagation in these materials is also governed by the Helmholtz equation as in a fluid medium. Results of studies of acoustic propagation in uniform straight lined guides with a uniform flow allowed to validate the method developed to truncate infinite domains. The study was also done successfully for non uniform lined guides with a potential mean flow.