Rapporté à la tonne de fret, le trafic maritime est un mode de transport relativement « propre ». Néanmoins, par l’intensification des échanges mondiaux, sa part dans les émissions de Gaz à Effet de Serre (GES) au niveau mondial est appelée à augmenter. Conscients des effets néfastes associés aux GES, les pays membres des nations unies, via l’organisation maritime internationale, imposent le cadre réglementaire pour que ce secteur, vital dans une économie mondialisée, demeure écologiquement acceptable. Des objectifs ambitieux sont établis à court (2020) et moyen terme (2050). Or, d’après l’hypothèse faible de Porter, fixer des objectifs environnementaux sans imposer les moyens à mettre en oeuvre favorise l’innovation. Aussi, dans l’industrie du « shipping », les solutions fleurissent au premier rang desquelles figure l’emploi du Gaz Naturel Liquéfié (GNL) en tant que combustible. D’un point de vue thermodynamique, les inévitables infiltrations thermiques à travers les parois des réservoirs cryogéniques entraînent une variation de la pression dans le réservoir et des fluctuations de la qualité du gaz à l’admission moteur. Selon le schéma d’exploitation navire, ces deux phénomènes impactent significativement la pertinence de l’option GNL. En réponse, cette thèse propose un ensemble de modèles 0D pour, à partir d’un profil opérationnel, évaluer :1. l’évolution de la pression dans les réservoirs ;2. l’évolution de la qualité du gaz à l’admission moteur.Dans une première partie, des modèles sont proposés pour simuler les infiltrations thermiques à travers le réservoir, l’évaporation du GNL, son vieillissement (altération des propriétés du gaz par évaporation différenciée des composés) et l’évolution du taux de méthane à l’admission moteur. Puis, les modèles sont assemblés à travers une étude de cas apportée par un acteur du transport maritime. / In proportion to the ton of cargo, shipping is a relatively “clean” transportation mode. Nevertheless, due to global trade intensification, its share in the global greenhouse gas (GHG) emissions should increase. Aware that GHG adverse effects are a major concern for humanity, united nation member states impose, via the international maritime organization, a regulatory framework so that this vital sector in a global economy remains sustainable. Short (2020) and medium (2050)-term goals are set. According to the weak version of Porter’s hypothesis, strict environmental regulations encourage innovations. Hence, in the shipping industry solutions flourish among which the use of Liquefied Natural Gas (LNG) as a fuel. On a thermodynamic basis, the unavoidable heat leaks into the cryogenic tanks cause variations of the tank pressure and the natural gas quality at engine inlet. Depending on the ship’s operational profile, those two phenomena will impact significantly the LNG as a fuel option relevance. One major bottleneck slowing the uptake of LNG as a marine fuel is the lack of methods and models to perform, at a concept design level, the feasibility study. In response, this thesis proposes 0D models to assess from the operational profile:1. the tank pressure evolution;2. the gas quality evolution at engine inlet.In the first part, models are proposed to simulate heat leaks into the tanks, LNG vaporization, ageing (the alteration of natural gas thermophysical properties by a differentiate vaporization of its compounds) and methane number evolution at engine inlet. Then, the models are put together and applied on a case study. The ship concept is proposed by a freight company.

The maritime industry must deal with several challenges and difficulties to tackle climate change. Organisations and companies are pursuing strategies to decarbonize the operations and provide an efficient and sustainable model for the shipping sector that would not damage the natural environment. The International Maritime Organisation (IMO) and the European Union have implemented a set of regulations to tackle the rapid increase of Greenhouse Gas emissions, researching and developing new marine fuel technologies. Decision-making processes have been usually used with the participation of several stakeholders, concluding on an eventual ranking of several alternatives. However, this master thesis assesses with the aid of a Multi-criteria Decision Analysis (MCDA) methodology, and the Distance To Target weighting scheme four marine fuels technologies. It takes into consideration science-based targets, especially the Planetary Boundaries framework and the United Nations Sustainable Development Goals, with the overall goal to assess the robustness of the results and compare them with other conducted analyses. The final results shows that hydrogen is defined as the most sustainable fuel, based on 5 selected criteria, followed by ammonia, LBG and LNG. However, there are differences between conventional MCDA and current research’s results when it comes to the weighting of the sustainability criteria, which is based on assumptions that have been made during the analysis. More accurate data on marine fuel technologies, and specific science-based targets for the maritime industry would assist decision-making methodologies, leading to objective outcomes.

Die Dissertation besteht aus drei unabhängigen Essays zur Anwendung der kooperativen Spieltheorie auf den internationalen Erdgashandel. Das internationale Erdgasnetz wird von einem stilisierten quantitativen Modell dargestellt, welches aus den wichtigsten Produzenten, Verbrauchern, Pipelines und LNG-Terminals besteht. Die Koalitionsfunktion berücksichtigt wesentliche Merkmale des internationalen Gashandels und schildert die Abhängigkeiten zwischen den Akteuren. Das Spiel wird mit dem Shapley-Wert und dem Nukleolus gelöst, welche alternative Indizes für die Darstellung der Machtstruktur sind. Kapitel 1 versucht die Interessen der Spieler in drei Pipeline-Projekte, d.h. Nord Stream, South Stream und Nabucco, zu rationalisieren. Das Kapitel ordnet die Investitionen in die neuen Pipelines ihren Auswirkungen auf die Verhandlungsmacht der Akteure zu und zieht dabei Rückschlüsse auf die Aussagekraft der Lösungskonzepte. Der Shapley-Wert rechtfertigt die jüngsten Investitionen in die Pipelines als rationale Versuche, die Machtstruktur zu verändern. Im Gegensatz zum Shapley-Wert kann der Nukleolus die empirischen Beobachtungen nicht nachbilden. Kapitel 2 studiert Pipeline-Projekte im zentralasiatischen Raum. Die Ergebnisse erklären die Unterstützung der zentralasiatischen Länder für eine nach China verlaufende Pipeline statt einem nach Europa führenden Projekt, und zeigen, dass die Konkurrenz zwischen China und Europa für das zentralasiatische Erdgas vernachlässigbar ist. Kapitel 3 untersucht die bedeutendsten Entwicklungen in Angebot und Nachfrage im globalen LNG-Markt sowie deren Einfluss auf die Machtstruktur im eurasischen Erdgashandel. Die Entwicklungen kommen den europäischen Verbrauchern deutlich zugute, aber scheitern dabei, die Macht der etablierten Anbieter um Europa, beispielsweise Russlands, einzudämmen. / The dissertation contains three independent essays on the application of cooperative game theory on the international natural gas trade. The international natural gas network is represented by a stylized disaggregated quantitative model consisting of its major producers, customers, trunk-pipelines and LNG terminals. The value function considers essential characteristics of the international gas trade and characterizes the interdependencies between the major actors. The game is solved with the Shapley value and the nucleolus as alternative indexes for capturing the power of different players. Chapter 1 aims to rationalize players'' interest in the three pipeline projects, i.e., Nord Stream, South Stream, and Nabucco. The chapter relates the investments into the new pipelines to their impact on the power structure and thereby makes conclusions about the explanatory power of the solution concepts. While the Shapley value can explain the recent investments in the new pipelines as a rational attempt to alter the power structure in the network, the nucleolus, in contrast, fails to replicate the empirical evidence. Chapter 2 studies pipeline options of the Central Asian countries aimed at diversifying their transit routes and export markets. The results explain the Central Asian countries'' endorsement for an eastbound pipeline to China rather than a Europe-bound option, and show negligible demand competition between China and Europe for Central Asian supplies. Chapter 3 investigates major supply and demand developments in the global LNG market as well as their impact on the power structure in the Eurasian natural gas trade. The developments benefit European consumers significantly, but barely curtail the power of the established suppliers in close proximity to Europe, such as Russia.

Liquefied Natural Gases (LNG) has been an alternative fuel in the marine industry for several years, but lately, the amount of ships that have been powered by methane has increased a lot. Some of the reasons for this is because LNG does not contain any sulfur and releases less nitrogen oxides than traditional maritime fuels. In this essay, LNG will be compared to diesel from an environmental perspective with focus on CO2 emissions and its equivalents. International Maritime Organization (IMO) implemented Energy Efficiency Design Index (EEDI) requirements that adjusts how much CO2 is allowed in the exhaust gas per produced kilowatt-hour (kWh). However, these requirements will increase in intervals in the future, the next one is coming 2022 for specific ship types. The method that is used to compare the fuels is Mole-calculations for LNG as well as diesel, then calculate the amount of carbon dioxide (CO2) and its equivalents they release. The results show that under optimal conditions, LNG was the superior choice. However, the maritime industry might have a problem with the requirements that will be introduced to greenhouse gas (GHG) emissions in 2050. / Flytande Naturgas (LNG) har under flera år funnits som ett alternativt bränsle inom sjöfarten, men på senare tid så har skeppen som drivs av metan ökat markant. En anledning till detta är att LNG innehåller inget svavel samt släpper ut mindre NOX jämfört med traditionella bränslen. I denna uppsats så kommer LNG att jämföras mot diesel ur ett klimatperspektiv med fokus på koldioxidutsläpp och dess ekvivalenter. International Maritime Organisation (IMO) har infört Energy Efficiency Design Index (EEDI) krav som justerar hur mycket CO2 man får släppa ut per kilowattimme (kWh), dessa krav kommer dessutom att öka i flertalet intervaller i framtiden, varav nästa intervall redan sker i 2022 för speciella fartygstyper. Metoden som användes för att jämföra bränslena var att beräkna mol-innehållet för både LNG samt diesel, sen från den beräknade data se hur mycket koldioxid (CO2) inklusive ekvivalenter de släppte ut. Resultatet visade att under optimala förutsättningar så var LNG ett klart bättre alternativ än diesel. Däremot så kan sjöfarten ha ett problem inom framtiden från de krav som berör växthusgaser som kommer att ställas från och med 2050.

A method of producing steel that is not used in Sweden today is direct reduction using natural gas, a method which could has enormous potential in the future of steelmaking. Historically, steelmaking prioritized productivity and profitability. However, other aspects such as safety, sustainability, and environmentally friendliness have become increasingly important to Swedish steelmakers. This study evaluates the usage of natural gas to  directly reduce iron ore into the porous form known as iron sponge, then finally processing that sponge into crude steel. The technology available today is assessed through a literature review, then two calculative data-based model: using DRI sponge in a traditional integrated steelmaking line or replacing steel scrap with it in an electric arc furnace. While this technology is used in many regions where natural gas is plentiful, it has not yet been used in Sweden. Now, when the Swedish natural gas network is expanding and the vehicular transportation of liquid natural gas is becoming more and more viable, it is a prime situation to evaluate direct reduction in Sweden. While models require assumptions and estimations, they suggest that DRI will absolutely be a viable option in the years to come. Integrated plant operators can reduce their immense carbon emissions for a reasonable price, while DRI sponge melting in an electrical arc furnace can either help steelmakers escape the volatile scrap market or be used to replace the blast furnace as a whole in the future. / En metod för att producera stål som inte används i Sverige idag är direkt reduktion med hjälp av naturgas, en metod som har en enorm potential i framtida ståltillverkning. Historiskt har ståltillverkningen prioriterat produktivitet och vinst, men säkerhet, hållbarhet, och miljövänlighet har blivit områden mer och mer viktiga för svenska ståltillverkare. Den här studien utvärderar användningen av naturgas för att direkt reducera järnmalm till den porösa formen känd som järnsvamp, och sen bearbeta den till primärt stål. Teknologin som flnns idag utvärderas genom en litteraturstudie, vars data beräknas till två scenariomodeller: användningen av järnsvamp i ett traditionellt integrerat stålverk eller genom att ersätta stålskrot med järnsvamp i ljusbågsungen. Den här teknologin används redan idag i regioner där naturgas är lättillgängligt, men har hittills inte använts i Sverige. Men nu när Sveriges naturgasnät byggs ut och fordonstransporterad flytande naturgas blir mer och mer kostnadseffektiv så är det lämpligt att utvärdera direkt reduktion i Sverige. Modellerna kräver antaganden och uppskattningar, men de pekar på att direkt reducering av järnmalm kommer att vara en genomförbar metod för ståltillverkning i en nära framtid. Integrerade masugnslinjer kan minska sina enorma koldioxidutsläpp till ett rimligt pris, och järnsvampssmältning i ljusbågsugn kan hjälpa ståltillverkare att undanfly den instabila stålskrotsmarknaden eller användas för att helt ersätta masugnsproduktion i framtiden.

Thesis (MScEng)--Stellenbosch University, 2014. / ENGLISH ABSTRACT: South Africa presently faces a serious and much-acknowledged energy capacity deficit. The Department of Energy are determined to address this capacity crisis by creating several new power plants between 2010 and 2030, as stipulated in the “Integrated Resource Plan 2010”. A Combined Cycle Gas Turbine (CCGT) power plant is proposed to add 2370 MW of capacity to the national grid. The “new-build” CCGT plant will use natural gas as a feedstock for energy generation. The plant is destined to begin energy generation by 2019, and will ramp up to full capacity by 2030. Following a review of the existing natural gas sources and the nascent gas network in South Africa, Liquefied Natural Gas (LNG) has been identified as the most suitable immediate source of natural gas feedstock for the CCGT. LNG fuel must be imported into South Africa aboard large, special purpose LNG Carrier (LNGC) vessels. LNGC vessels require a designated marine import terminal in order to offload the super-cooled and potentially flammable cargo. Saldanha Bay, located on the South West coast of South Africa, has been selected by Transnet as a preferred location for LNG terminal development. A review of LNG technology reveals the need for mandatory onshore LNG storage and regasification facilities, land area requirements, demands of different LNGC types and the characteristics of dedicated LNG jetties and terminals. Floating, offshore and traditional LNG terminals are discussed. The objective of this thesis is to review potential terminal sites and conceptual layouts in Saldanha Bay, and via a Multi Criteria Analysis, to present three distinct LNG terminal layout options for further consideration. The conceptual layouts will address technical concerns such as berth orientation and layout, safe navigational access to the terminal, mandatory onshore infrastructure and optimisation of berth operations. Saldanha Bay as a port location is studied and the importance of local environmental features is highlighted. Potential terminal development sites are identified following a review of nautical and terrestrial restrictions. Four conceptual site layouts are proposed, providing jetty locations and orientations in the Bay. The sites are located in North Bay, Hoedjiespunt, and two in Big Bay. Several Key Design Parameters (KDP’s) are identified as having a critical bearing on the ultimate layout, operation and feasibility of an LNG terminal in Saldanha Bay. The sensitivity and influence of the KDP’s at each of the four conceptual sites is investigated. Analysis of KDP effects leads to the development of design variation options at the sites. Twelve terminal layout schemes are ultimately derived. A Multi Criteria Analysis (MCA) is performed to rank the 12 terminal layout schemes in terms of technical efficacy. A sensitivity study is conducted to justify the selection of MCA parameter weights. The three top-scoring schemes are recommended for more detailed pre-feasibility investigation. The three terminal layout schemes, located in Big Bay and Hoedjiespunt, make use of both standard trestle jetties and floating LNG technologies. The thesis has shown that a number of viable sites and layouts for LNG terminals exist in Saldanha Bay and demonstrates a systematic analysis of design issues leading to preferred options. The thesis concludes by outlining the next steps in the process towards a final terminal scheme selection. / AFRIKAANSE OPSOMMING: Suid-Afrika ervaar huidig ‘n drastiese energie kapasiteit verlies. Die Departement van Energie is vasbeslote om die energie krisis aan te spreek deur verskeie nuwe kragstasies tussen 2010 en 2030 op te rig, soos beskryf in die “Integrated Resource Plan 2010”. ‘n Gekombineerde Siklus Gas Turbine (GSGT) kragstasie is voorgestel om ‘n verdere 2370 MW by te voeg tot die nasionale krag netwerk. Die “nuut-geboude” GSGT kragstasie sal natuurlike gas as brandstof vir kragopwekking gebruik. Die kragstasie is beplan om teen 2019 krag op te wek, en sal teen 2030 volle kapasiteit loop. Na ‘n ondersoek van die bestaande natuurlike gas bronne en gas netwerke in Suid Afrika, is Vloeibare Natuurlike Gas (VNG) geïdentifiseer as die huidiglike beskikbare bron van brandstof vir die GSGT. VNG moet ingevoer word aanboord spesiaal geboude VNG vaartuie. VNG vaartuie benodig ‘n spesifieke mariene invoer terminaal om die vlambare vloeistof mee af te laai. Saldanhabaai, aan die Suid-Westerlike kus van Suid Afrika, is as verkose area vir die VNG terminaal ontwikkeling geïdentifiseer deur Transnet. ‘n Oorsig van VNG tegnologie bevind dat VNG stoorplek en vergassings fasiliteite, land area, verskeie VNG vaartuie en karakteristieke van VNG terminale benodig word. Verskeie VNG terminale word bespreek in hierdie studie. The doel van hierdie tesis is om die potensiële terminaal bou-terrein en konseptuele ontwerpe in Saldanhabaai, deur middel van ‘n multi-kriteria analise (MKA), in drie verskillende ontwerp moontlikhede voor te stel. Saldanhabaai, as hawe, is bestudeer en belangrike omgewings aspekte is geïdentifiseer. Potensiële terminaal bou-terrein is geïdentifiseer na aanleiding van seevaart en land beperkings. Vier konseptuele bou-terreine is voorgestel wat jetty posisies en orientasies aandui. Die bou-terreine is in Noordbaai, Hoedjiespunt, en twee in Big Bay. Verskeie Sleutel Ontwerp Parameters (SOP’s), wat ‘n kritieke rol speel in die uiteindelike orientasie, werking en effektiwiteit van die VNG terminaal in Saldanhabaai, is geïdentifiseer. Die sensitiwiteit van die SOP’s by elk van die vier voorgestelde moontlikhede, is ondersoek. ‘n Ontleding van die effek van die SOP’s het variasie in die ontwerp moontlikhede by die verskillende bouterrein tot gevolg. Twaalf terminaal orientasie skemas is voorgestel. ‘n MKA is uitgevoer om ‘n ranglys van opsies te produseer in terme van tegniese effektiwiteit. Dit is voorgestel dat die top drie opsies verder ondersoek moet word. Die drie terminaal orientasie skemas, wat voorgestel word vir die Big Bay en Hoedjiespunt areas, maak gebruik van standaard jetties en drywende VNG tegnologie. Hierdie tesis bevind dat ‘n aantal uitvoerbare bouterreine en orientasies in Saldanhabaai moontlik is. ‘n Sistematiese analise van ontwerps kwessies wat na verkose opsies lei, word ook in die tesis ge-adresser. Die voorgestelde stappe in die besluitneming van ‘n finale terminaal skema vorm die slot van die tesis.

As Canada’s courts recognize and redefine the scope of Aboriginal title and rights in the country, alliances between Indigenous communities and environmental groups are playing an increasingly central role in the fight to stop fossil fuel infrastructure projects and address the global threats of climate change. Recognizing the importance of relationships between environmental non-governmental organizations (ENGO) and Indigenous peoples to environmental campaigns in Canada, and the need to include land-politics into the national conversation of reconciliation, this research project aims to investigate the role of reconciliation efforts in environmental campaigns in BC. Indigenous-ENGO relationships offer important opportunities to learn how actions and language of reconciliation are (or are not) being expressed in environmental campaigns, and to learn how ENGOs are approaching their work with Indigenous communities in an era of reconciliation. Using two campaigns as my case studies I explore these topics by interviewing ENGO staff and Indigenous peoples working collaboratively on the Site C Dam campaign in the Peace River region of Treaty 8 in northeast BC, and the Pacific Northwest liquid natural gas (LNG) terminal project in the Skeena River watershed region in the traditional territories of the Tsimshian, Gitxsan, and Wet’suwet’en nations of northwest BC. Informed by Indigenous and anti-colonial research methodologies, a principle of relational accountability is used to center relationships with land as a foundation for reconciliation, and for recommendations on how Indigenous-ENGO relationships can be improved. / Graduate

This thesis contains the results of optical flame emission measurements of the Vulcain 2.1engine and the plasma emission spectroscopy of the Lumen Project engine. The plume spectroscopyis analyzed, ordered and studied in detail to offer the best possible molecular composition.The main focus relied on the hydroxide radical, blue radiation and other moleculesanalysis of the intensities encountered during the tests. The plasma emission spectroscopy isfocused on the determination of the plasma temperature value in LIBS measurements. Thehydrogen plasma temperature determination of the local thermodynamic equilibrium, followedby the carbon and sequentially oxygen plasma is obtained. The quality of the LTE isto be determined to judge the truthworthness of the determined temperatures. Both the testsare analyzed thanks to the use of spectrographs, cameras and dedicated software for opticalapplications. The results related to the Vulcain 2.1 LOX/LH2 engine showed the evolutionof the plume in different ROF or pressure variations. Furthermore, the results of the LumenProject LOX/methane engine led to the determination of the plasma temperatures and a firstestimation of the LTE quality. / Die vorliegende Arbeit präsentiert die Ergebnisse der Abgasstrahlspektroskopie des H2/LOXVulcain 2.1 Triebwerks und der Zündplasma Spektroskopie des CH4/LOX Triebwerks desLUMEN Projektes. Die Abgasstrahlspektroskopie wurde analysiert und im Detail untersuchtum die am besten passende molekulare Zusammensetzung herauszuarbeiten. DasHauptaugenmerk liegt dabei auf dem Hydroxyl- Radikal, der Blauen Strahlung und molekularerIntensitätsanalyse. Bei der Zündplasmaanalyse liegt der Fokus auf der Bestimmungdes LTE Zustands (Lokales thermodynamisches Gleichgewicht) in LIBS. Die Temperaturdes Wasserstoff-, Kohlenstoff und Sauerstoffplasmas wird herangezogen, um die Qualitätdes LTE Zustands zu beurteilen. Für die Testdurchführung wurden Spektrographen, Kamerasund bestimmte Auswertungstools für optische Anwendungen benutzt. Das Verhaltendes Vulcain 2.1 Abgasstrahls abhängig von verschiedenen ROF und Druckstufen ist in denErgebnissen beschrieben. Für das LUMEN Triebwerk konnten erste Zündplasmatemperaturenbestimmt werden und geben einen Rückschluss auf die Qualität des LTE.

Magistro baigiamajame darbe išanalizuotas pasaulinės gamtinių dujų rinkos veikimo modelis, suskystintų gamtinių dujų terminalų technologijos įtaka pasaulinei gamtinių dujų rinkai bei atskiriems pasaulio regionams priklausomai nuo išvystytos dujų transportavimo infrastruktūros, sukurtas ekonominis SGDT teikiamų valstybės reguliuojamų paslaugų kainų nustatymo modelis Lietuvoje, iškeltos SGDT funkcionavimo ekonominio poveikio gamtinių dujų kainų pokyčiams Lietuvoje (izoliuotoje rinkoje) problemos bei pagal atliktus empirinio tyrimo rezultatus pateikti siūlymai rinkos dalyviams bei kitiems suinteresuotiems asmenims dėl galimų veiksmų pradėjus veikti SGDT 2014 m. gruodžio mėn. Lietuvoje. Pirmajame skyriuje sudaromas pasaulinės gamtinių dujų rinkos veikimo modelis, nagrinėjami ryšiai tarp pagrindinių jo sudedamųjų dalių (gavyba, transportavimas, vartojimas vidaus rinkoje), naujai atrandamų technologijų įtaka kiekvienai iš jų. Antroje dalyje analizuojama Lietuvos gamtinių dujų rinka ir ją supanti teisinė, ekonominė bei politinė aplinkos, aptariamos SGD galimos perspektyvos Lietuvoje. Trečioje dalyje analizuojamas autoriaus kartu su Valstybinės kainų ir energetikos kontrolės komisijos specialistais parengtas ekonominis SGDT teikiamų paslaugų kainos skaičiavimo modelis, aptariama importo kainos prognozavimo metodika, įvertinami pasirinktos metodikos trūkumai ir privalumai, aprašomi kt. metodai, kuriais remiantis ketvirtoje dalyje atliekamas empirinis tyrimas šiame darbe iškeltai... [toliau žr. visą tekstą] / This Master thesis contains: presentation of global natural gas market functioning model and LNGT technology impact on this market, as well as regions according to their infrastructure of gas transportation; creation of economic model for calculating natural gas import prices forecasts and forecasts for prices of regulated LNGT services in Lithuania; presentation of economic problems of LNGT impact on natural gas prices in Lithuania (as an isolated market) and considering the results of empirical research, suggestions of possible actions for market players and third parties after Lithuanian LNGT begins its operations in December, 2014. The first part of the thesis includes examination of global natural gas market functioning, the relations between its main components (extraction, transportation, consumption in domestic markets) and influence of the new technologies for each of them. The second part analyses Lithuanian natural gas market: its legal, economic and political environment, as well as presents LNG perspectives in Lithuania. The third part consists of introducing the economic LNGT services’ price model which was created by author of this thesis in collaboration with specialists of National control commission for prices and energy, also the methodology of calculating forecasts for natural gas import prices, its advantages and disadvantages, as well as other methods which were employed to solve the main problem of the Master thesis in the last part of this work.

Au cours de cette thèse, un modèle LBM MPMC avec échanges thermiques est développé. Des tests d'assimilation de données et des mesures par flot optique sont réalisés en vue d'une validation. Le cadre d'application de cette thèse est celui du mélange d'un fluide cryogénique avec l'eau. Dans une première partie, un travail bibliographique rappelant l'équation de Boltzmann, ses diverses hypothèses et simplifications, ainsi que l'aspect algorithmique de la LBM sont exposés. Une comparaison entre opérateur de collision SRT et MRT est réalisée, et une simulation de phénomènes turbulents à différents nombres de Reynolds est étudiée, notamment avec le benchmark de l'instabilité de Von Karman. Dans une seconde partie, le modèle MPMC de Shan & Cehn est rappelé puis étendu au cas où les échanges thermiques entre composants sont présents. Des validations quantitatives sont faites, notamment avec le benchmark du fluide de Couette à deux phases ou à deux composants, du test de cohérence vis-à-vis de la loi de Laplace, ou encore par rapport à un benchmark faisant intervenir la conduction thermique. Des tests qualitatifs de condensation en milieu multicomposants sont proposés pour valider l'aspect des échanges thermiques entre composants en présence d'une transition de phase. Dans la troisième partie de cette thèse, une méthode de validation par assimilation de données est introduite, avec le filtrage de Kalman d'ensemble. Un test d'estimation d'état d'un fluide di-phasique est réalisé, et la compatibilité du filtrage de Kalman d'ensemble par rapport au modèle LBMMPMC est évaluée. Pour la validation du comportement du modèle d'un point de vue de la présence de deux composants, un fluide de substitution (non-cryogénique) au GNL, le butane, a été choisi pour permettre des observations dans des conditions expérimentales accessibles. Puis, une plateforme expérimentale d'injection de butane liquide dans une colonne d'eau sous pression est présentée. Des images d'ombroscopie issues d'expériences de remontée de butane liquide dans de l'eau sont exposées et un algorithme de calcul de flot optique est appliqué à ces images. Une évaluation qualitative des champs de vitesses obtenus par application de cet algorithme est réalisée. / In this thesis, a LBM MPMC model with heat exchange is developed. Data assimilation tests and optical flow measurements are made in order to validate the model. The application context of this thesis is the mixture of a cryogenic fluid with water. In the first part, a bibliographical work reminding the Boltzmann equation and its various assumptions and simplifications, as well as the algorithmic aspect of the LBM are exposed. A comparison between SRT and MRT collision operator is performed, and a simulation of turbulent phenomena at different Reynolds numbers is studied, especially with the benchmark of the instability from Von Karman. In the second part, the MPMC model from Shan & Chen is reminded and extended to the case of the inter-component heat exchanges. Quantitative validations are made, especially with the benchmark of a two-phase or two-component Couette fluid. Consistency is tested against Laplace's law rule, or against a benchmark involving heat conduction. Qualitative testing of condensations in a multi-component medium are proposed to validate the heat exchange between components in the presence of a phase transition. In the third part of this thesis, a validation method for data assimilation is introduced, with the ensemble Kalman filter. A state estimation test of a bi-phase fluid is realized, and compatibility of the ensemble Kalman filtering to the LBM MPMC model is assessed. For validation of the behavior of the model for a two-component case, a substitution fluid (non-cryogenic) for LNG, butane, was selected to permit observations in experimental conditions which are accessible. Then, an experimental platform of injection of liquid butane in a pressurised water column is presented. Shadowgraph images from liquid butane experiments in water are exposed and an optical flow calculation algorithm is applied to these images. A qualitative assessment of the velocity field obtaines by application of this algorithm is performed.