<h2>BIOGAS POTENTIAL IN GRASSES FROM WETLANDS</h2><p><em>Marvin Martins</em></p><p>The purpose of this study has been to survey wetlands that are suitable for mowing and to analyze the biogas potential in the harvested grasses. A preformed investigation showed that there are suitable wetlands, which can be harvestable, namely those mowed formerly in traditional haymaking. The practice of traditional haymaking is dying out in Sweden today but there are several good reasons why it should to be reconsidered. Nature- and cultural values are obvious, also the unutilized energy in the grass.</p><p>The suitable types of wetland that were specifically studied were the productive wetlands; meadow marshes and wet meadows. These wetlands are represented in the Swedish meadow- and pasture inventory database; (TUVA) and the Swedish national wetland inventory (VMI). Going through the databases showed that they largely complement each other. A geographical mapping was also carried out of wetlands in relation to areas of interest for the future establishment of biogas plants, so called “hotspots”. The geographical survey shows that there is ample amount of grass from wetlands within a 30-kilometer radius that can supplement the plants main substrate, manure. The map layer Swedish Ground Cover Data (SMD) together with GIS software was used to analyze the extent of overgrowth for the older VMI objects in Uppsala County, with the result that half of the VMI objects are no longer of interest. They have become either woodland and bogs, or reed beds.</p><p>There is very little information on wetland-grasses and methane production. Instead, a theory was evaluated regarding the possibility of transforming nutritional values for grass and sedges into biogas potentials. It was shown that this method does not capture the total biogas potential, but offers a minimum value that can be considered rather reliable. The energy transformation showed that late harvested grasses from wetlands has a biogas potential about 0, 21Nm³methane/ (kg, DM) which is about 60 % of the biogas potential for grass-legume forages. The gas yield after 20 days is also relatively low. It could though be favorable to try grasses from wetlands in methane production, because co-digestion with these grasses and other suitable materials could produce a higher net gas yield for the plant, than using the materials solely by themselves. The derived biogas potential showed that there is at least 4, 4 GWh biogas energy in grasses from wetlands in Uppsala county at a low estimate. Harvesting costs were however shown to be too high in the present to achieve a plus result.</p> / <h2>BIOGASPOTENTIAL HOS VÅTMARKSGRÄS</h2><p><em>Marvin Martins</em></p><p>Syftet med detta arbete har varit att kartlägga våtmarker i Biogas Östs region lämpliga att skörda samt att undersöka biogaspotentialen i detta våtmarksgräs. Undersökningen visar att det finns lämpliga våtmarker, så kallade slåtterängar, i den undersökta regionen. Traditionell slåtter är en utdöende företeelse i Sverige men det finns flera goda argument till varför den borde återupptas. Natur- och kulturvärden är givna sådana men även den outnyttjade energin i gräset.<em></em></p><p>Våtmarkstyper som specifikt har studerats är de produktiva våta slåtterängarna; fuktängar, strandängar och mader. Dessa våtmarker finns representerade i Ängs- och betesmarksinventeringens databas; TUVA och våtmarksinventeringens VMI. En genomgång av databaserna visade att de i stor utsträckning kompletterar varandra. En geografisk kartläggning har även utförts på slåttermarker i förhållande till intressanta områden för framtida biogasanläggningar, så kallade ”hotspots”. Kartläggningen visar att det finns gott om våtmarksgräs inom en tremilsradie som kan komplettera anläggningarnas huvudsubstrat, gödsel. Kartskiktet Svenska Marktäckedata (SMD) tillsammans med GIS-programvara har använts för att analysera hur mycket de äldre VMI-objekten i Uppsala län har växt igen, med resultatet att hälften av VMI-våtmarkerna är inaktuella i dagsläget. De har antingen växt igen med mossor och träd eller blivit vassbälten.</p><p>Det finns ytterst begränsat med information kring rötdata på våtmarksgräs. Istället utvärderades en teori, om fodervärden för ett par gräs- och starrarter kan omvandlas till biogaspotentialer. Det visade sig att denna metod inte ger den maximala biogaspotentialen men ett minimivärde erhålls som kan betraktas som ganska tillförlitligt. Energiomvandlingen visar att sent slåttat våtmarksgräs har en biogaspotential runt 0,21 Nm³ metan/(kg, TS) vilket är omkring 60 % av den odlade åkervallens biogaspotential. Gasutbytet efter 20 dagars rötning är också relativt lågt. Trots detta kan det vara fördelaktigt att röta våtmarksgräs, eftersom samrötning mellan detta och annat lämpligt material kan ge ett högre nettogasutbyte för anläggningen än rötning av de enskilda materialen var för sig. Den framtagna biogaspotentialen visar att det finns minst 4,4 GWh biogasenergi i våtmarksgräs från till exempel Uppsala län, lågt räknat. Slåtterkostnaderna har dock visat sig vara för höga för att få det att gå ihop ekonomiskt i dagsläget.</p>

BIOGAS POTENTIAL IN GRASSES FROM WETLANDS Marvin Martins The purpose of this study has been to survey wetlands that are suitable for mowing and to analyze the biogas potential in the harvested grasses. A preformed investigation showed that there are suitable wetlands, which can be harvestable, namely those mowed formerly in traditional haymaking. The practice of traditional haymaking is dying out in Sweden today but there are several good reasons why it should to be reconsidered. Nature- and cultural values are obvious, also the unutilized energy in the grass. The suitable types of wetland that were specifically studied were the productive wetlands; meadow marshes and wet meadows. These wetlands are represented in the Swedish meadow- and pasture inventory database; (TUVA) and the Swedish national wetland inventory (VMI). Going through the databases showed that they largely complement each other. A geographical mapping was also carried out of wetlands in relation to areas of interest for the future establishment of biogas plants, so called “hotspots”. The geographical survey shows that there is ample amount of grass from wetlands within a 30-kilometer radius that can supplement the plants main substrate, manure. The map layer Swedish Ground Cover Data (SMD) together with GIS software was used to analyze the extent of overgrowth for the older VMI objects in Uppsala County, with the result that half of the VMI objects are no longer of interest. They have become either woodland and bogs, or reed beds. There is very little information on wetland-grasses and methane production. Instead, a theory was evaluated regarding the possibility of transforming nutritional values for grass and sedges into biogas potentials. It was shown that this method does not capture the total biogas potential, but offers a minimum value that can be considered rather reliable. The energy transformation showed that late harvested grasses from wetlands has a biogas potential about 0, 21Nm3 methane/ (kg, DM) which is about 60 % of the biogas potential for grass-legume forages. The gas yield after 20 days is also relatively low. It could though be favorable to try grasses from wetlands in methane production, because co-digestion with these grasses and other suitable materials could produce a higher net gas yield for the plant, than using the materials solely by themselves. The derived biogas potential showed that there is at least 4, 4 GWh biogas energy in grasses from wetlands in Uppsala county at a low estimate. Harvesting costs were however shown to be too high in the present to achieve a plus result. / BIOGASPOTENTIAL HOS VÅTMARKSGRÄS Marvin Martins Syftet med detta arbete har varit att kartlägga våtmarker i Biogas Östs region lämpliga att skörda samt att undersöka biogaspotentialen i detta våtmarksgräs. Undersökningen visar att det finns lämpliga våtmarker, så kallade slåtterängar, i den undersökta regionen. Traditionell slåtter är en utdöende företeelse i Sverige men det finns flera goda argument till varför den borde återupptas. Natur- och kulturvärden är givna sådana men även den outnyttjade energin i gräset. Våtmarkstyper som specifikt har studerats är de produktiva våta slåtterängarna; fuktängar, strandängar och mader. Dessa våtmarker finns representerade i Ängs- och betesmarksinventeringens databas; TUVA och våtmarksinventeringens VMI. En genomgång av databaserna visade att de i stor utsträckning kompletterar varandra. En geografisk kartläggning har även utförts på slåttermarker i förhållande till intressanta områden för framtida biogasanläggningar, så kallade ”hotspots”. Kartläggningen visar att det finns gott om våtmarksgräs inom en tremilsradie som kan komplettera anläggningarnas huvudsubstrat, gödsel. Kartskiktet Svenska Marktäckedata (SMD) tillsammans med GIS-programvara har använts för att analysera hur mycket de äldre VMI-objekten i Uppsala län har växt igen, med resultatet att hälften av VMI-våtmarkerna är inaktuella i dagsläget. De har antingen växt igen med mossor och träd eller blivit vassbälten. Det finns ytterst begränsat med information kring rötdata på våtmarksgräs. Istället utvärderades en teori, om fodervärden för ett par gräs- och starrarter kan omvandlas till biogaspotentialer. Det visade sig att denna metod inte ger den maximala biogaspotentialen men ett minimivärde erhålls som kan betraktas som ganska tillförlitligt. Energiomvandlingen visar att sent slåttat våtmarksgräs har en biogaspotential runt 0,21 Nm3 metan/(kg, TS) vilket är omkring 60 % av den odlade åkervallens biogaspotential. Gasutbytet efter 20 dagars rötning är också relativt lågt. Trots detta kan det vara fördelaktigt att röta våtmarksgräs, eftersom samrötning mellan detta och annat lämpligt material kan ge ett högre nettogasutbyte för anläggningen än rötning av de enskilda materialen var för sig. Den framtagna biogaspotentialen visar att det finns minst 4,4 GWh biogasenergi i våtmarksgräs från till exempel Uppsala län, lågt räknat. Slåtterkostnaderna har dock visat sig vara för höga för att få det att gå ihop ekonomiskt i dagsläget.

Both theatre and drama were imported to Canada from European colonizing nations, and as such the canonical master-texts of European drama, particularly the works of Shakespeare, have always occupied a prominent place in Canadian theatre. This presents a challenge for living Canadian playwrights, whose most revered role model is also their most dangerous competition, and whose desire to represent the spectrum of contemporary Canadian experience on stage is often at odds with the preferences of many producers and spectators for the “classics.” Since the 1990s, a number of Canadian playwrights have attempted to challenge the role of canonical plays and the values they represent by appropriating and critiquing them in plays of their own, creating a body of work which disturbs conventional distinctions between “adaptations” and “originals.” This study describes and analyzes the adaptive dramaturgies used by recent Canadian playwrights to appropriate canonical plays, question the privileged place they occupy in Canadian culture, expose the exclusionary hierarchies they legitimate, and claim centre stage for Canadian perspectives which have hitherto been waiting in the wings. It examines how playwrights challenge, usurp, or exploit the cultural capital of the canon by “re-citing” old plays in new works, how they or their producers attempt to frame the reception of their plays in order to address cultural biases against adaptation, and how audiences respond. This study draws from and builds upon contemporary theories of adaptation and particularly (Canadian) Shakespeare adaptation, seeking an understanding of adaptation based on the motives, tactics, and efficacy of adaptation. Simultaneously, it challenges the dominance of “Shakespeare,” in critical as well as theatrical practice, by comparing appropriations of Shakespeare to appropriations of Chekhov which exhibit similar tactics and motives.

Both theatre and drama were imported to Canada from European colonizing nations, and as such the canonical master-texts of European drama, particularly the works of Shakespeare, have always occupied a prominent place in Canadian theatre. This presents a challenge for living Canadian playwrights, whose most revered role model is also their most dangerous competition, and whose desire to represent the spectrum of contemporary Canadian experience on stage is often at odds with the preferences of many producers and spectators for the “classics.” Since the 1990s, a number of Canadian playwrights have attempted to challenge the role of canonical plays and the values they represent by appropriating and critiquing them in plays of their own, creating a body of work which disturbs conventional distinctions between “adaptations” and “originals.” This study describes and analyzes the adaptive dramaturgies used by recent Canadian playwrights to appropriate canonical plays, question the privileged place they occupy in Canadian culture, expose the exclusionary hierarchies they legitimate, and claim centre stage for Canadian perspectives which have hitherto been waiting in the wings. It examines how playwrights challenge, usurp, or exploit the cultural capital of the canon by “re-citing” old plays in new works, how they or their producers attempt to frame the reception of their plays in order to address cultural biases against adaptation, and how audiences respond. This study draws from and builds upon contemporary theories of adaptation and particularly (Canadian) Shakespeare adaptation, seeking an understanding of adaptation based on the motives, tactics, and efficacy of adaptation. Simultaneously, it challenges the dominance of “Shakespeare,” in critical as well as theatrical practice, by comparing appropriations of Shakespeare to appropriations of Chekhov which exhibit similar tactics and motives.

No description available.

The thesis entitled “Exploring Diverse Facets of Small Molecules by NMR Spectroscopy” consists of six chapters. The main theme of the thesis is to exploit one and two dimensional NMR methodologies for understanding the diverse facets of small organic molecules, such as, weak intra- and inter- molecular interactions, chiral discrimination, quantification of enantiomeric excess and assignment of absolute configuration. Several new pulse sequences have also been designed to solve specific chemical problems, in addition to extensive utility of existing one and two dimensional NMR experiments. The results obtained on different problems, are discussed under six chapters in the thesis. The brief summary of each of these chapters is given below. Chapter 1 begins with the discussion on the importance of small molecules and their various facets, the analytical techniques available in the literature to study them. The role of NMR spectroscopy as powerful analytical technique to understand the diverse facets of organic molecules and their importance is set out in brief. A short introduction to the basic principles of NMR, the interaction parameters, the commonly employed one and two dimensional homo- and herero- nuclear NMR experiments are also given. The basic introduction to product operators essential for understanding the spin dynamics in the developed pulse sequences is given. The application of diffusion ordered spectroscopy (DOSY), the general problems encountered in the analysis of combinatorial mixtures and the matrix assisted method in circumventing such problems are discussed. Chapter 2 focuses on the chiral discrimination and the measurement of enatiomeric excess. The NMR approach to discriminate enantiomers using chiral auxiliaries such as, solvating agents, derivatizing agents, lanthanide shift reagents, the choice of such auxiliaries and the limitations are discussed in detail. The in-depth discussion on the new protocols developed using both the solvating and derivatizing agents for enantiomeric discrimination of chiral amines, hydroxy acids and diacids are discussed. The new three-component protocols that serve as chiral derivatizing agents for the discrimination of primary amines, diacids and hydroxy acids are discussed. Also the role of organic base such as DMAP in the chiral discrimination is explored for discrimination of acids using BINOL as a chiral solvating agent. Accordingly the discussion is classified into two sections. In the first section the protocol developed utilizing an enantiopure mandelic acid, a primary amine substrate and 2-formylphenylboronic acid that is ideally suited for testing the enantiopurity of chiral primary amines is discussed. The broad applicability of the protocols for testing enantiopurity has been demonstrated on number of chiral molecules using 1H and 19F NMR. The second section contains the results on the new concept developed for discrimination of hydroxy acids. The strategy involves the formation of three component protocol using chiral hydroxy acid, R-alphamethylbenzylamine and 2-formylphenylboronic acid for 1H-NMR discrimination of diacids. The section also includes the utility of ternary ion-pair complex for the discrimination of acids. The ternary ion-pair not only permitted the testing of enantiopurity of chiral acids, but is also found useful for the measurement of enantiomeric excess. Chapter 3 discusses the utilization of the developed three-component protocols for the assignment of absolute configurations of molecules of different functionality. The protocols for the assignments of absolute configuration of primary amines using 2-formylphenylboronic acid and mandelic acid yielded the substantial chemical shift differences between diastereomers. The consistent trend in the direction of change of chemical shifts of the discriminated proton(s) gave significant evidence for employing them as parameters for the assignment of spatial configuration of primary amines. Another protocol using 2-formylphenylboronic acid, hydroxy acids and enantiopure alphamethylbenzylamine permitted their configurational assignment. In the second section a novel solvating agent, obtained by the formation of an ion-pair complex among enantiopure BINOL, DMAP and chiral hydroxy acid for the assignment of the spatial configuration of hydroxy acids is discussed. Chapter 4 focuses on the development of novel NMR methodologies, and also the utility of existing two-dimensional experiments for addressing certain challenging problems. This chapter has been divided into three sections. In Section-I the utilization of well-known homonuclear 2D-J-resolved methodology for unravelling the overlapped NMR spectra of enantiomers, an application for chiral discrimination and the measurement of enantiomeric excess is discussed. The utilization of the chiral auxiliaries, such as, chiral derivatizing agents, chiral solvating agents and lanthanide shift reagents permits enantiodiscrimination and the measurement of excess of one form over the other. Nevertheless many a times one encounters severe problems due to small chemical shift difference, overlap of resonances, complex multiplicity pattern because of the presence of number of interacting spins, and enormous line broadening due to paramagnetic nature of the metal complex. This section is focused on combating such problems utilizing 2D-J-1JNH resolved spectroscopy where a 450 tilting of the spectrum in the F2 dimension, yielded the pure shift NMR spectrum. The method circumvents several problems involved in chiral discrimination and allows the accurate measurement of enantiomeric excess. In Section-II, the development of novel NMR experimental methodology cited in the literature as C-HetSERF and its application for the study of symmetric molecules, such as, double bonded cis- and trans- isomers, and extraction of magnitudes and signs of long range homo- and hetero- nuclear scalar couplings among chemically equivalent protons in polycylic aromatic hydrocarbons is discussed. The extensive utility of the new pulse sequence has been demonstrated on number of symmetric molecules, where the conventional one dimensional experiment fails to yield spectral parameters. In section III, yet another novel pulse sequence called RES-TOCSY developed for unravelling of the overlapped NMR spectrum of enantiomers and the measurement of enantiomeric contents, has been utilized for the accurate measurement of magnitudes and signs of 1H-19F couplings in fluorine containing molecules. The method has distinct advantages as the strengths of the couplings and their relative signs could be extracted on diverse situations, such as, couplings smaller than line widths, the spectrum where the coupling fine structures are absent. Chapter 5 covers the study of nature of intra- and inter- molecular hydrogen bond in amide and its derivative. The chapter is accordingly divided into two sections. In the first section the study of acid and amide hydrogen bonding is discussed and the hydrogen bonded interactions are probed by extensive utility of 1H, 13C and 15N-NMR. The temperature perturbation experiments, measurements of the variation in the couplings, monitoring of diffusion coefficients and the association constants, detection of through space correlation have given unambiguous evidence for the hydrogen bond formation. The results were also supported by DFT calculations. Similar interaction in the solid state has also been derived by obtaining the crystal structure of complex phenylacetic acid with benzamide. In the second section of the chapter the hydrogen bond interaction of organic fluorine in trifluoromethyl derivatives of benzanilides has been explored and the involvement of CF3 group in the hydrogen bonding has been detected. The evidence for the participation of CF3 group in hydrogen bond has been confirmed by number of experiments, such as, the detection of through space couplings, viz., 1hJFH, 1hJFN, and 2hJFF , where the spin polarization between the interacting spins is transmitted through hydrogen bond, the temperature and solvent dependent studies, variation in the 1JNH and two dimensional heteronuclear correlation experiments. In an interesting example of a molecule containing two CF3 groups situated on two phenyl rings of benzanilide, the simultaneous participation of fluorines of two CF3 groups in hydrogen bond has been detected. The confirmatory evidence for such an interaction, where hydrogen bond mediated couplings are not reflected in the NMR spectrum, has been derived by 19F−19F NOESY. Significant deviations in the strengths of 1JNH, in addition to variable temperature, and the solvent induced perturbation studies yielded additional evidence. The NMR results are corroborated by both DFT calculations and MD simulations, where the quantitative information on different ways of involvement of fluorine in two and three centered hydrogen bonds, their percentage of occurrences, and geometries have been obtained. The hydrogen bond interaction energies have also been calculated. The study revealed the rare observation and the first example of the C-F…H-N hydrogen bond in solution state in the molecules containing CF3 groups. Chapter 6 focuses on the mixture analysis using the diffusion ordered spectroscopy (DOSY). High Resolution-DOSY works when the NMR spectrum is well resolved and the diffusion coefficients of the combinatorial mixtures are substantially different from each other. DOSY technique fails when the mixture contains the molecules of nearly identical weights and similar hydrodynamic radii. Thus, the positional isomers, enantiomers consequent to their nearly identical rates of diffusion, are not differentiated. Some of these problems can be overcome by Matrix-Assisted Diffusion Order Spectroscopy (MAD-spectroscopy), where an external reagent acts as a matrix and aids in their diffusion edited separation, provided the molecules embedded in it possess differential binding abilities with the matrix. Such different binding properties of the matrix are the basis for resolution of many isomeric species. In the present study three different novel auxiliaries, micelles-reverse micelles, crown ether and cyclodextrin are introduced for the resolution of positional isomers, double bonded isomers, viz., fumaric acid and maleic acid and also enantiomers. Accordingly, the results of each of these studies are discussed in three different sections.

A short (11 page) plain language summary is available under the filename "Research Summary_Peer Support Institutionalization - Troubling Everyday Work.pdf" / This study explores how the everyday work of peer supporters working within institutionalized settings are shaped by institutional forces (“ruling relations”), through a series of four (peer support) focus groups and interviews with five peer support workers in Ontario. I explore peer supporters’ approaches to writing, reading, and verbally sharing information about their peers (“documentation work”), and reveal how their experiences and “felt troubles” relating to documentation are shaped by ideas of (clinical) confidentiality constructed in the Personal Health Information Protection Act (2004). I also explore how both lived experience and peer support are devalued through the ways organizations and clinicians determine and describe the value of healthcare roles (“de/valuing work”), and reveal how peer supporters’ experiences of being (de)valued are shaped by discourses of “professional/ism” which equate being a professional to having a post-secondary education and working through clinical frameworks. I describe the work that peer supporters, clinicians, and organizations (can) engage in to ground peer support workers within peer values and approaches (“values work”) through accessing peer community and fostering environments of peer culture. I draw on these suggestions and the findings of the study to provide recommendations for peer support workers, organizations and clinical workers, the peer support sector as a whole, and research/ers. / Thesis / Master of Social Work (MSW)

No description available.

In this dissertation, I articulate what I call a personal-is-political ethics, suggesting that the realm of human affairs long called ethics is inseparable from that which is today normatively called psychology. Further, I suggest that these names for this shared realm are situated in different discursive traditions which, therefore, provide different parameters for possible action and understanding. In my exploration of what it is to be human, I strategically centre ethical transgressions, particularly those that are mappable onto systemic forms of oppression. I explore personal-is-political enactments of sexism, ableism, racism, colonization, classism, ageism, and geopolitics, including situations in which several of these intersect with one another and those in which therapeutic, pedagogical, or parenting hierarchies also intersect with them. Without suggesting this is ‘the whole story,’ I closely read people’s narrations of ethical transgressions that they – that we – commit. I claim that such narrations shape our possibilities for harming others, for taking responsibility, and for intervening in others’ lives in an attempt to have them take responsibility (e.g., therapy with abuse perpetrators and critical pedagogy). I work to demonstrate the ethical and political importance of: the impossibility of exhaustive knowledge, the illimitable and contingent power relations that are ever-present and give shape to what we can know, and the ways our possibilities in life are constituted through particular contact with others. I explore ethical transgressions I have committed, interrogating these events in conversation with explorations of resonant situations in published texts, as well as with research conversations with friends about their ethical transgressions and how they make sense of them. I tentatively advocate for, and attempt to demonstrate, ways of governing ourselves when we are positioned ‘on top’ of social hierarchies – in order to align our responses and relationships more closely with radical political commitments.

In this dissertation, I articulate what I call a personal-is-political ethics, suggesting that the realm of human affairs long called ethics is inseparable from that which is today normatively called psychology. Further, I suggest that these names for this shared realm are situated in different discursive traditions which, therefore, provide different parameters for possible action and understanding. In my exploration of what it is to be human, I strategically centre ethical transgressions, particularly those that are mappable onto systemic forms of oppression. I explore personal-is-political enactments of sexism, ableism, racism, colonization, classism, ageism, and geopolitics, including situations in which several of these intersect with one another and those in which therapeutic, pedagogical, or parenting hierarchies also intersect with them. Without suggesting this is ‘the whole story,’ I closely read people’s narrations of ethical transgressions that they – that we – commit. I claim that such narrations shape our possibilities for harming others, for taking responsibility, and for intervening in others’ lives in an attempt to have them take responsibility (e.g., therapy with abuse perpetrators and critical pedagogy). I work to demonstrate the ethical and political importance of: the impossibility of exhaustive knowledge, the illimitable and contingent power relations that are ever-present and give shape to what we can know, and the ways our possibilities in life are constituted through particular contact with others. I explore ethical transgressions I have committed, interrogating these events in conversation with explorations of resonant situations in published texts, as well as with research conversations with friends about their ethical transgressions and how they make sense of them. I tentatively advocate for, and attempt to demonstrate, ways of governing ourselves when we are positioned ‘on top’ of social hierarchies – in order to align our responses and relationships more closely with radical political commitments.