A tese a ser defendida é a de que a autorregulação institucionalmente estruturada e legitimada pela regulação é um eficiente arranjo para tratar as falhas e riscos inerentes ao mercado de bolsa. O trabalho se inicia com a descrição da atual estrutura da autorregulação do mercado de bolsa, destacando seu novo formato institucional decorrente do processo de desmutualização e abertura de capital das entidades administradoras do mercado de bolsa e concluindo pela necessidade de adoção de novas perspectivas sobre o tema que transcendam o aparente antagonismo entre concepções liberais e intervencionistas. A partir dessa premissa, o trabalho apresenta uma visão panorâmica da evolução histórica da autorregulação do mercado de bolsa e considerações sobre os conceitos de autorregulação em outras áreas do conhecimento, a fim de identificar suas variações e seus elementos mais marcantes que constituirão a base a partir da qual serão apresentadas as novas perspectivas de análise do tema. As perspectivas propostas enfocam a natureza jurídica da autorregulação do mercado de bolsa como atividade paraestatal destinada a concretizar o modelo teórico neoclássico de justa formação dos preços segundo a livre atuação das forças de oferta e demanda e, também, melhorar os padrões de conduta praticados no mercado. Para tanto, o trabalho propõe que as decisões tomadas no âmbito da autorregulação se pautem por critérios materiais baseados nas premissas teóricas da concorrência perfeita e na exigência de cumprimento dos deveres derivados da boa-fé objetiva (informação, lealdade e proteção). Por fim, é apresentada uma especulação teórica, preliminar e não definitiva, denominada teoria palco-platéia, que visa situar o desenvolvimento da estrutura de autorregulação do mercado de bolsa como parte de uma questão essencial de interação entre indivíduo e sociedade representada nas diversas situações comunicativas envolvidas nos processos decisórios individuais e coletivos que modelam os padrões de conduta e as instituições públicas e privadas. / The thesis to be defended is that the institutionally structured self-regulation and legitimized by the regulation, is an efficient array to treat flaws and risks inherent of the exchange market. The paper begins with a description of the current self-regulation structure of the exchange market, highlighting its new institutional format, due to the demutualization process and IPO of the entities that manage the exchange market, and concluding with the need of the adoption of new perspectives regarding the subject-matter that transcend the apparent antagonism between liberal and interventionist conception. From this premise, the paper presents an overview of the history of self-regulation of the exchange market and considerations on the concepts of self-regulation in other areas of knowledge, for the purpose of identifying its variations and its most striking elements that will form the basis from which the new perspectives of analysis of the matter will be presented. The proposed views focus on the legal nature of the exchange markets self-regulation as a parastatal activity that seeks to achieve the neoclassic theoretical model of fair pricing, according to the free action of forces of supply and demand, and also improve the conduct standards in the market. Therefore, the paper proposes that decisions made within the self-regulation should be guided by material criteria based on theoretical postulations of perfect competition and in the requirement of the obligations derived from the objective good faith (information, loyalty and protection). Lastly, a preliminary and not final, theoretical speculation is presented, denominated stage-audience theory, which aims to situate the development of the self-regulation structure of the exchange market, as part of an essential matter of interaction between individual and society represented in various communication situations involved in individual and collective decision-making, which shape the standards of conduct, and public and private institutions.

A tese a ser defendida é a de que a autorregulação institucionalmente estruturada e legitimada pela regulação é um eficiente arranjo para tratar as falhas e riscos inerentes ao mercado de bolsa. O trabalho se inicia com a descrição da atual estrutura da autorregulação do mercado de bolsa, destacando seu novo formato institucional decorrente do processo de desmutualização e abertura de capital das entidades administradoras do mercado de bolsa e concluindo pela necessidade de adoção de novas perspectivas sobre o tema que transcendam o aparente antagonismo entre concepções liberais e intervencionistas. A partir dessa premissa, o trabalho apresenta uma visão panorâmica da evolução histórica da autorregulação do mercado de bolsa e considerações sobre os conceitos de autorregulação em outras áreas do conhecimento, a fim de identificar suas variações e seus elementos mais marcantes que constituirão a base a partir da qual serão apresentadas as novas perspectivas de análise do tema. As perspectivas propostas enfocam a natureza jurídica da autorregulação do mercado de bolsa como atividade paraestatal destinada a concretizar o modelo teórico neoclássico de justa formação dos preços segundo a livre atuação das forças de oferta e demanda e, também, melhorar os padrões de conduta praticados no mercado. Para tanto, o trabalho propõe que as decisões tomadas no âmbito da autorregulação se pautem por critérios materiais baseados nas premissas teóricas da concorrência perfeita e na exigência de cumprimento dos deveres derivados da boa-fé objetiva (informação, lealdade e proteção). Por fim, é apresentada uma especulação teórica, preliminar e não definitiva, denominada teoria palco-platéia, que visa situar o desenvolvimento da estrutura de autorregulação do mercado de bolsa como parte de uma questão essencial de interação entre indivíduo e sociedade representada nas diversas situações comunicativas envolvidas nos processos decisórios individuais e coletivos que modelam os padrões de conduta e as instituições públicas e privadas. / The thesis to be defended is that the institutionally structured self-regulation and legitimized by the regulation, is an efficient array to treat flaws and risks inherent of the exchange market. The paper begins with a description of the current self-regulation structure of the exchange market, highlighting its new institutional format, due to the demutualization process and IPO of the entities that manage the exchange market, and concluding with the need of the adoption of new perspectives regarding the subject-matter that transcend the apparent antagonism between liberal and interventionist conception. From this premise, the paper presents an overview of the history of self-regulation of the exchange market and considerations on the concepts of self-regulation in other areas of knowledge, for the purpose of identifying its variations and its most striking elements that will form the basis from which the new perspectives of analysis of the matter will be presented. The proposed views focus on the legal nature of the exchange markets self-regulation as a parastatal activity that seeks to achieve the neoclassic theoretical model of fair pricing, according to the free action of forces of supply and demand, and also improve the conduct standards in the market. Therefore, the paper proposes that decisions made within the self-regulation should be guided by material criteria based on theoretical postulations of perfect competition and in the requirement of the obligations derived from the objective good faith (information, loyalty and protection). Lastly, a preliminary and not final, theoretical speculation is presented, denominated stage-audience theory, which aims to situate the development of the self-regulation structure of the exchange market, as part of an essential matter of interaction between individual and society represented in various communication situations involved in individual and collective decision-making, which shape the standards of conduct, and public and private institutions.

No description available.

Avec l’usage intensif de dispositifs microélectroniques modernes, il existe un besoin croissant de mémoires non volatiles. La FeRAM (mémoire ferroélectrique à accès aléatoire) est une des mémoires de nouvelle génération les plus prometteuses en raison de sa faible consommation et de sa vitesse élevé de lecture/écriture. Parmi les différents matériaux ferroélectriques, le PZT (Pb (Zr1-x,Tix)O3) présente une polarisation rémanente élevée et un faible champ coercitif qui en font un candidat de choix pour les FeRAM.Dans cette thèse, la croissance épitaxiale de couches de PZT (52/48) d’épaisseurs variables (33 à 200 nm), sur un substrat de SrTiO3 et une électrode inférieure interfaciale de SrRuO3, a été réalisé par deux méthodes pour comparaison : pulvérisation cathodique et sol – gel. Trois matériaux conducteurs différents (SrRuO3, Pt et ITO) ont été utilisés comme électrode supérieure. L’objectif a été une étude détaillée des propriétés électriques et ferroélectriques de ces structures MFM (métal-ferroélectrique-métal), avec une attention particulière sur l’influence des conditions d’élaboration et de la nature des électrodes sur le courant de fuite et la dynamique de basculement de domaines.Les capacités élaborées par pulvérisation ou sol-gel présentent des caractéristiques semblables : Au-delà d’une épaisseur minimum d’environ 100 nm, pour une structure capacitive à base de PZT de 100 × 100 μm2, elles montrent un faible courant de fuite, une permittivité relative maximale élevée (600 - 1300) et une polarisation rémanente élevée (30 - 40 μC/cm2). Les mécanismes dominants dans le courant de fuite ont été identifiés par un fit des résultats, manifestant différentes contributions en fonction du champ électrique. Des caractérisations par PFM (microscopie à force piézoélectrique) confirme l’existence de domaines ferroélectriques de directions opposées. Il est aussi montré que le champ coercitif dépend fortement de la fréquence de travail. D’autre part, les propriétés d’impression dépendent de l’électrode supérieure, de la nature du recuit et de l’épaisseur de l’électrode inférieure. / With the intensive use of modern microelectronic devices in numerous areas, there is an increasing demand for non-volatile memories. FeRAM (ferroelectric random access memory) is one of the most potential next-generation memories for its ultra-low power consumption and high read/write rate. Among various ferroelectrics, PZT (Pb(Zr1-x,Tix)O3) exhibits high remnant polarization and low coercive field, which make it a promising candidate for FeRAM.In this dissertation, PZT(52/48) layers of various thicknesses (from 33 nm to 200 nm) have been epitaxially grown on SrTiO3 substrate, with a SrRuO3 interlayer as bottom electrode, using two deposition methods for comparison: sol-gel and sputtering. Three different conductive materials (SrRuO3, Pt and ITO) have been deposited as top electrode. The objective was a detailed study of the electrical and ferroelectric properties of these MFM (metal-ferroelectric-metal) capacitors, with a particular investigation of the influence of elaboration conditions and electrode material on leakage currents and domain switching dynamics.Sputtered and sol-gel-derived PZT capacitors showed similar properties: Above a minimum workable thickness of about 100 nm for a 100 × 100 μm2 PZT capacitor, they showed low leakage current, high maximum relative permittivity (600 - 1300) and high remnant polarization (30 - 40 μC/cm2). The dominant leakage current mechanisms were identified by fitting the results, showing different contributions as a function of electric field. PFM (piezoresponse force microscopy) characterizations confirmed the existence of ferroelectric domains of opposite directions. Coercive field was found to be highly dependent on work frequency. Besides, imprint properties were found to be dependent on top electrode, annealing procedure and bottom electrode thickness.

Transparent glass-ceramics have been of industrial interest because of their multifarious applications. These are becoming increasingly important because of the flexibility that is associated with this route of fabricating intricate sizes and shapes as per the requirement. A number of glass-ceramics, based on well known ferroelectric crystalline phases (LiNbO3, LaBGeO5, SrBi2Nb2O9, Bi2WO6 etc.) were fabricated and their polar and electro-optic properties were reported. Keeping the potential applications of transparent glass-nano/microcrystal composites in view, attempts were made to fabricate SrBi2B2O7 and CaBi2B2O7 glasses and glass-nano/microcrystal composites. An attempt has been made to employ strontium bismuth borate SrBi2B2O7 (SBBO) as a reactive host glass matrix for growing the nanocrystals of ferroelectric oxides belonging to the Aurivillius family. The in situ nucleation and growth of SrBi2Nb2O9 (SBN) nanocrystals in a reactive SrBi2B2O7-Nb2O5 system and its influence on various physical (dielectric, pyroelectric and optical) properties were investigated. The strategy has been to visualize the formation of nanocrystalline SrBi2Nb2O9 as a result of the simple chemical reaction between glassy SrBi2B2O7 and Nb2O5. Indeed at lower concentrations of Nb2O5 transparent glasses were obtained which upon heat-treatment at appropriate temperatures yielded nanocrystalline SrBi2Nb2O9 phase in a transparent glass matrix. Textured SrBi2Nb2O9 ceramics were obtained by quenching the melts of SrBi2B2O7-Nb2O5 in equimolar ratio and their physical properties were studied. A strong anisotropy in physical properties (which are akin to single crystals) were demonstrated in the textured ceramics.

The nonlinear simulation model of an unmanned aerial vehicle (UAV) in MATLAB&reg / /Simulink&reg / environment is developed by taking into consideration all the possible major system components such as actuators, gravity, engine, atmosphere, wind-turbulence models, as well as the aerodynamics components in the 6 DOF equations of motion. Trim and linearization of the developed nonlinear model are accomplished and various related analyses are carried out. The model is validated by comparing with a similar UAV data in terms of open loop dynamic stability characteristics. Using two main approaches / namely, classical and optimal, linear controllers are designed. For the classical approach, Simulink Response Optimization (SRO) tool of MATLAB&reg / /Simulink&reg / is utilized, whereas for the optimal controller approach, linear quadratic (LQ) controller design method is implemented, again by the help of the tools put forth by MATLAB&reg / . The controllers are designed for control of roll, heading, coordinated turn, flight path, pitch, altitude, and airspeed, i.e., for the achievement of all low-level control functions. These linear controllers are integrated into the nonlinear model, by carrying out gain scheduling with respect to airspeed and altitude, controller input linearization regarding the perturbed states and control inputs, and anti integral wind-up scheme regarding the possible wind-up of the integrators in the controller structures. The responses of the nonlinear model controlled with the two controllers are compared based on the military flight control requirements. The advantages and disadvantages of these two frequently used controllers in industry are investigated and discussed. These results are to be evaluated by the designers themselves based on the design criteria of a project that is worked on.

There was a fame time for silicon in condensed matter physics, then the graphene era came and now topological insulators are gaining lot of attention, but magnetism in condensed matter physics has remained always fascinating starting from the ancient days up to now and it will remain as one of the core topic in basic or applied physics. The improvement in the modern techniques allows one to explore magnetism in different length scales as well as in different time scales. As an effect of the improvement in experimental techniques, different magnetic anomalies are unearthed. As a result theories are getting refined and the area of magnetism progresses. From the material point of view, oxides carry the most diverse nature in condensed matter starting from high temperature superconductivity (HTS), colossal magnetoresistance, metal insulator transition etc. to ferromagnetism (FM), anti-ferromagnetism (AFM), spin glass (SG) and so on. Among this list, SG and HTS are one of the least understood topics in magnetism till today. A large research community is involved in understanding the underlying physics behind these two, especially in transition metal oxides. It has drawn attention not only due to fundamental aspects but also due to various applications in day to day life. This thesis is an attempt to understand these two phenomena in transition metal oxides. As the title of this thesis suggest, it is all about magnetic and magneto-transport properties of certain transition metal oxide (crystalline) addressing the interplay between two competing order parameters to understand the underlying physics behind it from an experimental point of view. We have studied two different kinds of competing interactions: (i) the FM/AFM interplay either in bulk or at the interface of the two layers in thin films; (ii) the interplay between FM and superconductivity (SC) in superconductor (S)/ferromagnet (F) heterostructures. Basically both of these two kinds lead to non-equilibrium phenomena in these oxides. One of such competition is between FM and AFM leading to slow dynamics (glassy physics). Disorder and frustrations are the key ingredients for such slow dynamics. The spin frustration arises either due to geometry or due to competing interactions. For example, in a triangular antiferromagnet due to the triangular geometry spins gets frustrated. Now, if it prevails spin disorder as well then it satisfies both the criteria for a spin glass and hence it gives birth to glassiness. Another kind of competition is the interplay among SC and FM. It is known that SC and FM are two antagonistic quantum phenomena thus in a single material SC (singlet pairing) and FM does not co-exist. However one can realize this by making F/S heterostructures and observe the battle between these two competing order parameters. The spin polarized quasiparticle injection from F creates non equilibrium spin density inside S and thereby suppressing the order parameter of S. Also by choosing an appropriate ferromagnet the vortex motion inside S can be arrested to certain extent which can enhance the critical current density of S. Thus FM/SC interplay has become an alternative way to look at the high temperature superconductivity. This thesis is categorized into nine chapters. The summary of each chapter is as follows: Chapter: 1 contains certain concepts of magnetism and superconductivity which is useful to understand the topics and experiments described in this thesis. Chapter: 2 gives the underlying principles of the various experimental techniques used in this thesis. Chapter: 3 describes the magnetic properties of successfully synthesized five compositions of LixNi(2-x)O2 (0.67<x<0.99) which has five distinct ground states namely antiferromagnet (AF), spin glass (SG), cluster glass (CG), re-entrant spin glass (RSG) and ferromagnet (FM). The SG and CG ground state has been well described by the frequency dependent peak shift. From the power-law divergence of critical slowing down the estimated value of relaxation time indicates the presence of interacting macro spins (spin cluster) rather than individual spins in certain LixNi(2-x)O2 samples possessing CG ground state which is also supported by the Arrhenius law. The shift in the spin freezing temperature with the application of dc field obeys Almeida-Thouless line. It also exhibits memory effect which is generic to the slow dynamics. The remnant magnetization relaxation follows logarithmic decay. Interestingly, the sample having RSG ground state shows memory effect up-to 50K and behaves like a FM above that temperature. FC-ZFC M(T) curve shows a splitting at the ordering temperature. The critical analysis across the ferromagnetic-paramagnetic phase transition yields a self-consistent γ, β and δ value and the spin-spin interaction in this material follows long range mean field model. The critical exponents obey Widom scaling law: δ = 1 + γ β −1. The universality class of the scaling relations is also verified where the scaled m and scaled h collapses into two branches. Finally the magnetic phase diagram illustrates a vivid picture of the gradual evolution of ferromagnetism in LixNi(2-x)O2 through a glassy state. As a concluding remark, we think, the present study of glassy physics in magnetic insulator/semiconductor sets an example to compare them with the conventional metallic spin glass system. Chapter: 4 exhibits the results of the structural, magnetic and transport measurements to elucidate some of the most striking unusual physical responses of bulk SrRuO3. Two set of polycrystalline SrRuO3 samples with unique ordering temperature have been synthesized. In one case, we have taken the stoichiometric weight ratio of precursors that eventually resulted in Ru-deficient SrRuO3(SROD). In the other case, we have taken extra 2% wt. RuO2 deliberately to form stoichiometric SrRuO3(SRO). Both the samples are found to crystallize in orthorhombic crystal structure with Pnma space group. The low temperature magnetization is found to be well described by the Bloch T3/2 law and the magnetization near Tc is found to follow the scaling law; M~(Tc-T)β with β=0.35 and β=0.30 for SRO and SROD respectively, apparently showing the 3D Ising behaviour. This aspect will be elaborated in the next chapter. The magnetic ac susceptibility study exhibits a broad hump far below the ferromagnetic ordering temperature and the frequency dependence of this hump position exhibits the characteristics of multiple relaxations. Most strikingly, we notice a low temperature glassy magnetic behaviour clearly demonstrated by the time dependent memory effect. This is very surprising and unlikely to happen in systems, which have itinerant ferromagnetic character. However, we conjecture that slow domain growth and spin canting could be the cause for such effect. The transport study evidences a crossover from Fermi liquid (FL) to non-Fermi liquid (NFL) behaviour around 40 K and a slope change in dρ/dT vs. T plot in the vicinity of that temperature. Astonishingly, we observe two distinct dips (one around ferromagnetic ordering temperature and the other far below the ferromagnetic ordering temperature) in the temperature dependent MR response. In addition, we also observe the signature of an unusual dip in the temperature dependent coercive field towards low temperature side. The emergence of such unusual magnetic and transport response is strongly believed to be connected with hidden magnetic interactions. Our effort on neutron diffraction study has been able to trace the cause of such cryptic magnetic interaction. The findings of neutron diffraction study evidence the change in the unit cell lattice parameters around 75 K and that could be the central cause behind such anomalous low temperature magnetic responses. It also demonstrates that the octahedral tilt freezes around the FM transition and has a minimum around the low temperature glass transition temperature. Most remarkably we observe a decline in the total integrated magnetic intensity towards the low temperature side indicating the presence of antiferromagnetic like interaction in SrRuO3. Chapter: 5 resolves the ambiguity in determining the crritical exponents in SrRuO3. Most remarkably, the application of scaling law in the FC magnetization leads a systematic change in the values of critical exponent with the measuring field in SRO. The β value changes from 0 to o.44 to to 0.29 (corresponds to mean field to Ising) with the increase in the measurement field from 10 to 2500 Oe. However, the H→0 extrapolation fields β=0.5. In order to substantiate the actual nature, the critical behavior is studied across the phase transition from the M-H isotherms. The critical analysis yields a self-consistent β, γ and δ values and the spin-spin interaction follows long range mean field δ=γ β model 1+. The critical exponents also obey Widom scaling law: δ = 1 + γ β-1 The universality class of the scaling relations is verified where the scaled m and scaled h collapses into two branches. We have also found that Ru deficiency does not affect the nature of the spin-spin interaction (though ferromagnetism gets reduced). Further the directional dependence of the critical exponent reflects the isotropic nature of the magnetic interaction. In other words the spin-spin interaction found to be: i) three dimensional, ii) long range, iii) mean field type and iv) isotropic in SrRuO3. We have also found magnetocaloric effect (calculated from the M-H isotherms) that across the phase transition. The specific heat measurements find sharp jump at the ferromagnetic transition due to the magnetic contribution of the specific heat. Chapter: 6 describes the magnetism at the SrRuO3 (SRO)/LaAlO3 (LAO) interface where SRO is an itinerant ferromagnet (FM) and LAO is non-magnetic (NM) (rather diamagnetic). Most surprisingly SRO/LAO exhibits pronounced exchange bias (EB) effect realized by observing a shift in the field cooled M-H hysteresis. Further investigation results an increasing trend of the strength of the EB with the decreases in the thickness of ferromagnetic layer. This system also displays the training effect which essentially confirms that this effect is due to EB. EB arises due to the uncompensated spins at the FM/AFM interface hence the EB effect in SRO/LAO system is unconventional. However, the origin of such AFM interaction (responsible for EB effect in FM/NM system) at SRO/LAO interface is realized and explained through the temperature dependence of the EB effect. Further, we have extensively investigated EB effect in other analogous ferromagnets, FM/FM bilayers and FM/FM superlattices. We found that La0.7Sr0.3MnO3 (LSMO) grown on LAO exhibits the signature of EB. In contrast to that La0.5Sr0.5CoO3 (LSCO) does not show any signature of EB. All the bilayers (LSMO/SRO, LSMO/LSCO and LSCO/SRO) exhibit EB and have similar kind of temperature dependence. In order to gain more insight we have grown a (LSMO/SRO)8 superlattice and observed a complex magnetic behaviour. It exhibits partial inverted magnetic hysteresis. But the system shows EB effect characterized by the shift in the FC hysteresis and training effect. All these observations essentially demonstrate that the magnetic nature of various ferromagnetisms at the interfaces can be changed by choosing a proper partner (acts like adding perturbations into one of those system which lies close to the instability region). Chapter: 7 presents the magneto-transport properties of three SRO films grown on LAO (100) of thicknesses of 12, 24 and 48 nm are studied extensively. For a one to one comparison one of the sample is also grown on STO(100). The coercivity vs. temperature in SRO(48 nm)/LAO exhibits a plateau at ~40 K. The dR/dT exhibits the low temperature hump in all the samples which very much replicates with the bulk scenario that we observed in SRO. Most strikingly the 12 nm SRO sample exhibits NFL behaviour throughout the temperature range of measurement (10-150 K). Our careful investigation reveals a cross-over from FL to NFL in all SRO thin films. The cross-over temperature increases with the increase in thickness and eventually shifts towards the bulk cross-over value. It is apt to remind that in bulk SRO we have demonstrated (by employing temperature dependent neutron diffraction) that there is a presence of antiferromagnetic like interaction at low temperature giving birth to glassiness in bulk SRO. Further, an attempt is made to understand the low temperature magneto-transport anomaly by looking into the spin fluctuation through the low frequency 1/f noise measurements. It conveys a message that there are two types of magnetic ordering present in SRO giving rise to two peaks in the temperature dependence of the relative variance. Application of magnetic field suppresses both the peaks in the relative variance. This certainly indicates that the origin of such peak is caused by the spin fluctuations and thereby it is of magnetic origin. Further we have looked into the Hall effect of a structured (Hall patterned) SRO thin film and observed regular Hall effect (RHE) as well as anomalous Hall effect (AHE) in it. Most remarkably the temperature dependence of the RHE coefficient changes its sign close to the ferromagnetic transition temperature of SRO. This implies a change of the type of the carrier as the temperature is varied. Based on these results, the carrier concentration of SRO as a function of temperature is determined. Chapter: 8 is about the magnetic and magnetotransport studies on the successfully grown high quality S/F heterostructures. The oxygen content plays a vital role in superconductivity of oxide materials thus for studying FM/SC interplay in oxides we have discussed how to achieve a high quality sample (oxygen stoichiometric). We have observed a great influence of a FM in suppressing the superconductivity in YBa2Cu3O(7-δ) (YBCO) in FM/SC heterostructures. The analysis of the out of plane M-H hysteresis reveals a significant reduction of the critical fields (HC1 and HC2) of the SC (in SRO/YBCO bilayer) which might have a great significance to understand the superconductivity in a better way (from both the perspectives: theory and experiments). Most remarkably we have found 40% enhancement of the critical current density of YBCO in SRO/YBCO bilayer. We have demonstrated that in order to see the effect of spin polarizes quasiparticle (SPQP) injection into YBCO, one should not apply more than 20mA current since Joule heating contribution wins over pair breaking effect. The SPQP injection from SRO into YBCO exhibits pair breaking effect as the TC (of the SC) shift follows I2/3 law. The resistive transitions under various applied magnetic fields and the field dependence of the activation energy confirms that the vortices are in the 2D regimes (it follows power law, U0~Hα withα=0.5) in SRO/YBCO. To get a better insight into the FM/SC interplay we have looked into two of the FM/YBCO combinations (LSCO/YBCO and LSMO/YBCO). We observe that the degree of the spin polarizations of the FMs scales with the suppression of superconductivity in YBCO which means more the spin polarization more is the suppression. We have also found out that spin polarization is not the sole parameter in suppressing superconductivity in SRO/YBCO bilayers. It also depends upon the state of magnetization of the ferromagnet. Further, we observed a significant reduction (one order) of the activation energy in LSCO/YBCO compared to SRO/YBCO which clearly indicates that the vortex dynamics might depend on other aspects as well (of the FM). It also reveals the formation of decoupled pancake vortices (pure 2D regime) in LSCO/YBCO and LSMO/YBCO bilayers whereas in case of YBCO and SRO/YBCO it is of 2D coupled type. Chapter: 9 summarizes the whole work presented in this thesis. It also discusses about few research problems which one need to look at in future.

Cette thèse se situe dans un des axes principaux de l'INL qui a pour objectif de développer des procédés de fabrication de films minces d'oxydes monocristallins, épitaxiés sur silicium. Ces oxydes pourraient remplacer les oxydes de grille amorphes de type SiOxNy ou HfSixOyNz et répondre au cahier des charges de la « Road Map » de l'ITRS dans les futures filières CMOS sub 22nm. L'intérêt de maîtriser l'épitaxie d'oxydes sur silicium va bien au-delà de l'application au CMOS. Un tel savoir faire serait une brique technologique essentielle pour pouvoir développer des filières d'intégration monolithique sur silicium.<br /><br />Dans ce contexte, l'objectif principal de ma thèse a été de mener une étude approfondie des propriétés physicochimiques et structurales de couches fines d'oxydes élaborées par Epitaxie par Jets Moléculaires (EJM) sur substrat silicium ou oxyde, en utilisant la spectroscopie de photoélectrons (XPS) et la diffraction de photoélectrons (XPD).<br /><br />Nous avons étudié dans un premier temps la relaxation de films minces de LaAlO3 et de BaTiO3 épitaxiés sur des substrats de SrTiO3(001). Nous avons montré qu'au-dessous d'une certaine épaisseur critique ces deux oxydes sont contraints de façon pseudomorphiques sur SrTiO3(001). De plus nous avons clairement mis en évidence une forte augmentation de la déformation ferroélectrique pour une couche contrainte de BaTiO3.<br /><br />Dans un deuxième temps, nous avons aussi étudié la croissance de LaAlO3 sur Si(001). LaAlO3 est amorphe pour des températures de croissance en dessous de 500°C. Pour des températures supérieures il y a formation de silicates à l'interface qui empêche la cristallisation. Pour surmonter cette difficulté, des procédés d'ingénierie d'interface ont été développés pour limiter les réactions interfaciales et réussir la croissance épitaxiale. Ils sont basés sur l'utilisation de couches tampons interfaciales d'oxydes comme SrO, SrTiO3 et Al2O3.<br /><br />Enfin, nous avons comparé les modes de croissance et la stabilité d'interface d'Al2O3 et de Gd2O3 épitaxiés sur Si(111) et Si(001). Les résultats prouvent que la croissance de ces deux oxydes sur Si(111) a une orientation suivant [111]. Par contre sur Si(001) le mécanisme de croissance est plus complexe avec des relations d'épitaxie et des orientations inhabituelles.

<p>  </p> <p>A school safety team collaborates with stakeholders to promote and maintain a physically and psychologically safe school environment. Together they must identify safety deficits and prioritize initiatives and practices. This phenomenological qualitative case study examined how a school safety team makes decisions and determines safety outcomes. Individual interviews and a focus group discussion explored how they calibrate what a safety concern is to help prevent violence. Four emergent themes were identified: (1) severity and impact, (2) safety-minded culture, (3) communication and collaboration, and (4) leadership. In addition, the study explored whether one of Bronfenbrenner’s ecological systems has more influence over the others when validating a concern. This study suggests that the Microsystem is most influential. From these findings, three assertions were proposed to help the school safety team, and building leaders promote safe school practices: (1) The safety team must establish collaborative relationships with stakeholders and develop convenient reporting systems to collect concerns; (2) A school safety team judges a safety concern by the severity and potential impact on the school environment; and (3) Leadership is vital for the school safety team to prepare for, respond to, and address safety concerns. These findings aim to help stakeholders promote and maintain a safe learning environment as they evaluate perceived safety concerns by highlighting areas to focus on to improve the calibration process. Though a school safety team may never know how many times they were right in calibrating a concern, a single error will be well known.</p>

Desire for low-power, high performance computing has been at core of the symbiotic union between digital circuits and CMOS scaling. While digital circuit performance improves with device scaling, analog circuits have not gained these benefits. As a result, it has become necessary to leverage increased digital circuit performance to mitigate analog circuit deficiencies in nanometer scale CMOS in order to realize world class analog solutions. In this thesis, both circuit and system enhancement techniques to improve performance of clock generators are discussed. The following techniques were developed: (1) A digital PLL that employs an adaptive and highly efficient way to cancel the effect of supply noise, (2) a supply regulated DPLL that uses low power regulator and improves supply noise rejection, (3) a digital multiplying DLL that obviates the need for high-resolution TDC while achieving sub-picosecond jitter and excellent supply noise immunity, and (4) a high resolution TDC based on a switched ring oscillator, are presented. Measured results obtained from the prototype chips are presented to illustrate the proposed design techniques. / Graduation date: 2013 / Access restricted to the OSU Community at author's request from July 16, 2012 - July 16, 2014