Η παρούσα διπλωματική εργασία πραγματεύεται τη μελέτη, την ανάλυση καθώς και την κατασκευή μιας νέας τοπολογίας για τη διασύνδεση φωτοβολταϊκών (Φ/Β) γεννητριών, μικρής ισχύος, με το ηλεκτρικό δίκτυο των αστικών περιοχών. Η εργασία αυτή εκπονήθηκε στο Εργαστήριο Ηλεκτρομηχανικής Μετατροπής Ενέργειας του Τμήματος Ηλεκτρολόγων Μηχανικών και Τεχνολογίας Υπολογιστών της Πολυτεχνικής Σχολής του Πανεπιστημίου Πατρών. Στόχος της διπλωματικής εργασίας είναι η συμβολή της στον τομέα των Φ/Β μονάδων διεσπαρμένης παραγωγής, με την κατασκευή μιας ηλεκτρονικής διάταξης, η οποία θα χρησιμοποιηθεί για τη διασύνδεση φωτοβολταϊκών (Φ/B) γεννητριών μικρής ισχύος, στο ηλεκτρικό δίκτυο χαμηλής τάσης. Συγκεκριμένα, διερευνάται και κατασκευάζεται ένας υψίσυχνος αντιστροφέας ρεύματος τοπολογίας Flyback, ο οποίος θα είναι κατάλληλος για εφαρμογές «Φωτοβολταϊκών Πλαισίων Εναλλασσόμενου Ρεύματος» (AC-PV Modules), δηλαδή Φ/Β διατάξεων, ηλεκτρικής ισχύος έως 300W, στις οποίες ενσωματώνεται ένας ηλεκτρονικός μετατροπέας συνεχούς τάσης σε μονοφασική εναλλασσόμενη (Micro-inverter). Ιδιαίτερα χαρακτηριστικά του αντιστροφέα που κατασκευάστηκε είναι ο μικρός βαθμός πολυπλοκότητας του κυκλώματος ισχύος με άμεση συνέπεια την υψηλή αξιοπιστία του, η γαλβανική απομόνωση που παρέχει ανάμεσα στη Φ/Β γεννήτρια και το ηλεκτρικό δίκτυο εναλλασσόμενου ρεύματος (Ε.Ρ.), η ικανότητα σημαντικής ανύψωσης της τάσης εισόδου του, ο υψηλός συντελεστής ισχύος, καθώς και ο υψηλός βαθμός απόδοσης (ο οποίος αγγίζει το 94,25%) για ένα ευρύ φάσμα λειτουργίας του. Ο μικρός όγκος και το μικρό βάρος (σε περίπτωση βιομηχανοποίησης), είναι επιπρόσθετα χαρακτηριστικά της συγκεκριμένης τοπολογίας. Αρχικά, αναλύεται διεξοδικά η λειτουργία του αντιστροφέα ρεύματος τοπολογίας Flyback, η οποία έχει αναπτυχθεί στη Διδακτορική Διατριβή του Αναστάσιου Χ. Κυρίτση, «Βέλτιστος Σχεδιασμός Υψίσυχνου Μονοφασικού Αντιστροφέα για τη Διασύνδεση Φωτοβολταϊκών Συστημάτων Μικρής Ισχύος με το Δίκτυο Χαμηλής Τάσης». Ταυτόχρονα, διερευνώνται δύο διαφορετικές τεχνικές ελέγχου, οι οποίες οδηγούν σε διαφορετικές καταστάσεις λειτουργίας (λειτουργία σε ασυνεχή αγωγή, DCM - λειτουργία στο όριο μεταξύ συνεχούς και ασυνεχούς αγωγής, BCM) και εξασφαλίζουν τη δημιουργία εναλλασσόμενου ημιτονοειδούς ρεύματος συμφασικού με την τάση του ηλεκτρικού δικτύου. Αναπτύσσονται τα κυκλώματα ελέγχου του αντιστροφέα, ενώ παρουσιάζεται ένας αποτελεσματικός τρόπος μέτρησης του υψίσυχνου διακοπτικού ρεύματος που διαρρέει τα τυλίγματα του μετασχηματιστή του αντιστροφέα. Τέλος, πραγματοποιείται η κατασκευή της διάταξης στο εργαστήριο, με σκοπό τη διεξαγωγή πειραματικών μετρήσεων για την επιβεβαίωση και αξιολόγηση της θεωρητικής ανάλυσης. / This degree thesis deals with the study, the analysis and the manufacture of a new topology that will be used for the interconnection of small photovoltaic (PV) generators with the electric network of urban regions. This work was conducted in the Laboratory of Electromechanical Energy Conversion, Department of Electrical and Computer Engineering, School of Engineering, University of Patras. The goal of the present thesis is to contribute in the sector of Dispersed Power Generation PV systems, with the development of an electronic device that will be used for the interconnection of small photovoltaic (PV) generators with the low voltage electric network. Specifically, a high frequency current source Flyback inverter is investigated and manufactured, that will be suitable for “Alternative Current Photovoltaic Modules” (AC-PV Modules) applications. An AC-PV Module is the combination of a single PV module (whose power production varies under 300W) and a single-phase power electronic micro-inverter in a single electrical device. Special characteristics of the inverter are the simple power electronic circuit structure, having high reliability as an immediate consequence, the electrical isolation provided between the PV generator and the electric network, the high power factor and the high efficiency (reaching 94.25%) for a wide range of its power. Moreover, small volume and weight are particular characteristics, attributes very important considering its applications (incorporation in PV generators that will be placed in aspects or roofs of buildings). For this topology - whose theory is in the Ph.D. thesis of A. Ch. Kyritsis “Optimum Design of a High Frequency Singe - Phase Inverter for the Interconnection of Small Power PV Systems with the Low Voltage Network” developed - two different control techniques were investigated, leading to different operation modes (Discontinuous Conduction Mode - DCM, Boundary between Continuous and Discontinuous Mode - BCM) and ensuring alternative sinusoidal current, in phase with the electric network voltage. Simultaneously, their suitability is studied for different power levels. Moreover, the control circuits of the inverter were developed and an effective way of measuring the high - frequency switching currents of the inverter’s transformer is presented. Last but not least, the design of the whole system is completed in the laboratory, in order to carry out the experimental measurements required, to confirm and evaluate the studied theory.

La délivrance contrôlée de médicaments constitue un enjeu thérapeutique de première importance pour le milieu médical. Elle doit, en effet, permettre de diminuer la toxicité du médicament en limitant sa concentration dans l'organisme et en ciblant son lieu de délivrance. Ce projet de recherche a conduit à la réalisation de nouveaux nano-vecteurs particulaires utilisables pour la délivrance de médicaments par hyperthermie locale. Ces objets sont constitués d'un cœur de polynorbornène et d’une écorce de poly (oxyde d’éthylène) et sont synthétisés par polymérisation par ouverture de cycle de type métathèse (ROMP) en dispersion. L’acide salicylique est encapsulé dans ces particules en tant que molécule modèle. L'originalité de ce sujet pluridisciplinaire réside : dans la nature de la particule, qui permet une libération du principe actif à partir de 35-45°C et dans la technique d'imprégnation des particules par la voie fluide supercritique. / Controlled release systems are attracting increasing interest because of their potential application in biomedical field. Indeed, such systems should enable to lower toxicity of medicines by targeting the therapeutic action and by limiting the concentration of drugs in the organism. In this research project, new nanoparticles have been developed for a thermosensitive control of drugs’ delivery. These particles consist of a polynorbornene core and a polyethylene oxide shell and are developed by dispersion ring opening metathesis polymerization. As a model drug, salicylic acid has been encapsulated in those core-shell materials. This multidisciplinary project is original for two reasons. On the one hand, the nature of the particle which enables to release the drug from 35-45°C. On the other hand, the encapsulation technique that has been chosen is the impregnation under supercritical carbon dioxide.

Le Système Électrique est soumis ces dernières années à plusieurs évolutions, depuis la dérégulationdu marché d'énergie à l'intégration de plus en plus importante de Générateurs Dispersés (GED). Ainsi,dans le cadre du concept de Smart Grid, les nouvelles technologies de l'information et de lacommunication (NTIC) offrent de nouvelles perspectives pour la gestion et l'exploitation des réseauxde distribution.Dans ce contexte, de nouveaux outils sont étudiés. Encore appelés Fonctions Avancéesd’Automatisation (FAA), le but principal de ces outils est d’utiliser tous les composants du réseau dedistribution de manière coordonnée en vue de les rendre plus actifs, flexibles et d’augmenter leurefficacité opérationnelle. Dans notre cas, nous avons étudié les fonctions associées à la reconfigurationen régime normal, du réglage de la tension et l’hybridation de ces deux derniers, tout en tenant comptede la présence des GED. En partant du comportement physique inhérent aux composants du réseau,plusieurs modèles ont été proposés. Certains sont tirés de la théorie des graphes et d’autres sur l’outilpuissant de la reformulation mathématique pour « convexifier » nos modèles. Cette modélisationadoptée répond à la fois à la nécessité de prendre en compte tous les moyens de réglages qui peuventêtre discrets (prises des transformateurs avec régleurs en charge ou des gradins de condensateurs),binaires (état de connectivité des composants) et continues (puissance réactive de la DG) et par lechoix des outils et des algorithmes d'optimisation mixte. En effet, la complexité de ces problèmes sonttelles que nous avons exploré à la fois des algorithmes méta-heuristiques (ACF : Algorithme desColonies de Fourmis) que déterministes (Décomposition de Benders Généralisée, Algorithme duBranch and Cut). / The Electric Power System is undergoing a lot of evolutions in recent years, including the energymarket deregulation and the increasing integration of Dispersed Generators (DG). Therefore, withinthe framework of Smart Grid concept, the New Information and Communication Technologies (NICT)provide new perspectives to manage and operate distribution networks.In this context, new tools, called Advanced Distribution Automation functions (ADA, are beingstudied). The main objective of these tools is to use all the distribution network components in acoordinated manner to make them more active and flexible, in addition to increasing their operationalefficiency. In our case, we studied the functions associated with the reconfiguration problem, thevoltage control problem and the hybridization of these two, while taking into account the presence ofthe DG. Based on the inherent components of network physical models, several models have beenproposed. Some are derived from the graph theory and others use powerful mathematicalreformulation to make our models convex. The adopted models answer to the necessity of taking intoaccount all regulation means, which can be discrete (On Load Tap-Changer and capacitor banks),binary (components connectivity such as lines or transformers) and continuous (DG reactive power ),and by the choice of tools and algorithms of mixed optimization. Indeed, the complexity of theseproblems is such that we have explored both algorithms: meta-heuristic (ACA, Ant Colony Algorithm)and deterministic (Generalized Benders Decomposition, Branch and Cut Algorithm).

This study concerns frequency relays and voltage relays applied to the protection of synchronous distributed generators operating in reactive power control mode without a frequency regulation function. The effect of active and reactive powers combination, load power factor, and reactive power imbalance are investigated for their implication for the anti-islanding setting of the frequency relay. Results reveal that the effect of these factors must be considered when setting the relay for islanding detection. For the voltage relay, results reveal that the effect of active and reactive powers combination, load power factor, and active power imbalance must be considered when setting the relay for islanding detection. The effect of multi-stage tripping on the frequency relay ability to detect island was also investigated. Results show that multistage tripping can improve the anti-islanding performance of the frequency relay. / Electrical Engineering / M. Tech. (Electrical Engineering)

Dentre os atuais desafios do direito societário brasileiro, a estrutura da propriedade acionária das sociedades por ações de capital aberto e a identificação daqueles que as comandam merecem destaque. O aquecimento das transações realizadas via mercado de capitais e a consolidação dos segmentos especiais de governança corporativa no Brasil resultaram no chamado fenômeno de dispersão acionária, que evidenciou certa ruptura na tradicional estrutura de propriedade acionária exclusivamente concentrada, até então predominante nas companhias brasileiras. Diante desse cenário contrastante, de mudanças no perfil do poder de controle sobre as companhias brasileiras, o presente trabalho apresentará em seu capítulo terceiro, após breve análise das estruturas de capital identificadas em diferentes economias e de retrospectiva sobre a propriedade acionária das companhias brasileiras (a serem apresentadas em seu segundo capítulo), extensa pesquisa empírica realizada com o propósito de identificar a atual estrutura de propriedade acionária predominante entre as companhias brasileiras listadas no segmento especial do Novo Mercado da BMF&BOVESPA (Novo Mercado), e com o objetivo de averiguar a existência do chamado controle societário minoritário entre tais companhias, conforme detalhado nos apêndices desta dissertação. Referida pesquisa empírica representa, ainda, rico processamento da base de dados e informações divulgadas à Comissão de Valores Mobiliários (CVM) pelas companhias listadas no Novo Mercado, e serve de base para a avaliação da necessidade de eventuais mudanças nos conceitos adotados pelo Direito Societário pátrio, tendo em vista entendimento divergente identificado na doutrina e em julgados da CVM no âmbito da possibilidade de existência de um controle societário exercido por acionista ou grupo de acionistas não detentores da maioria do capital social votante, conforme detalhado no quarto capítulo deste estudo. Por fim, serão apresentadas, no quinto e último capítulo, as considerações finais à análise proposta, com destaque para as principais conclusões obtidas na elaboração dos capítulos terceiro e quarto descritos acima, dentre elas a existência do controle societário interno não majoritário (controle minoritário) entre companhias listadas no Novo Mercado, bem como os reflexos dessa constatação no âmbito da prática do Direito Societário. / Among the current challenges of the Brazilian Corporate Law, the structure of the capital ownership of the corporations and the identification of those who exercises control over it remains an important aspect to be taken into consideration when analyzing the main aspects of the Brazilian capital market. The heat up of the transactions carried out through the capital market, and the consolidation of the special corporate governance segments in Brazil resulted in the so called phenomenon of the dispersed ownership, which revealed a rupture from the traditional structure of extremely concentrated ownership, that was prevailing until now among the Brazilian corporations. Given such contrasting scenario of changes in the profile of corporate power over Brazilian corporations, these thesis, after describing, over its first two chapters, the structures of capital ownership existent in different economies and providing a retrospective on the capital ownership of Brazilian corporations, presents, in its third chapter, an extensive empirical research performed with the purposes of identifying the current structure of capital ownership prevailing among the Brazilian companies listed in the Novo Mercado, special segment of the Brazilian Exchange BMF&BOVESPA (the New Market), as well as ascertaining the existence of minority corporate control among such companies, as detailed in the appendixes hereto. The referred empirical research presents, furthermore, detailed data processing in connection with the information disclosed by such companies to the Brazilian Stock Exchange Commission, the Comissão de Valores Mobiliários (CVM), and is also used as basis for reviewing the need of eventual changes in the concepts embodied by the Brazilian Corporate Law, in view of the divergent understanding identified in the Brazilian doctrine and judgments issued by the CVM in connection with the existence of a corporate control exercised by a shareholder or group of shareholders owner of shareholding not representative of the majority of the voting capital stock, as detailed in the fourth chapter of these thesis. Finally, the fifth and last chapter of these study presents the final considerations in connection with the review proposed hereto, highlighting the main conclusions obtained through the elaboration of the third and fourth chapters described above, among them the existence of a not majority internal control (minority control) in companies listed in the New Market, as well as the effects of such conclusion in the light of the practice of corporate law.

O escoamento líquido-líquido, em especial o escoamento óleo-água, vem atraindo a atenção de pesquisadores devido à alta demanda pelo combustível fóssil no atual cenário petrolífero mundial e nacional. Os desafios tecnológicos colocados pelas descobertas de reservas de óleos pesados e altamente viscosos consideram, em especial, a preocupação por minimizar as perdas energéticas nas linhas. Emulsões inversas ou dispersões óleo-em-água, na qual o óleo se encontra disperso de maneira uniforme em água, caracteriza-se pela baixa viscosidade aparente, tornando-se um tipo de emulsão desejável em algumas etapas do transporte de petróleo. Esses fatos tornam essencial o estudo deste tipo de padrão para o dimensionamento e operação ótima de dutos de produção de petróleo. Contudo, não existe ainda um número abrangente de trabalhos sobre padrão disperso líquido-líquido, ao comparar com escoamento em fases separadas. Trabalhos sobre dispersões têm reportado redução de atrito sem a adição de substâncias químicas em regime turbulento. No entanto, não há ainda um entendimento satisfatório do fenômeno. Na maioria dos trabalhos, sendo quase todos realizados com óleos leves e pouco viscosos, a redução é reportada em dispersões água-em-óleo, com escassos trabalhos reportando o fenômeno em dispersões óleo-em-água. A pesquisa realizada tratou do estudo experimental e teórico de dispersões óleo-em-água em tubulações. O escoamento foi caracterizado a partir da obtenção de dados de holdup, gradiente de pressão por fricção, distribuição das fases e padrão de escoamento. Uma teoria foi proposta para explicar a redução de atrito detectada neste trabalho, baseada na existência de um filme fino de água que escoa em contato com a parede do tubo, a baixos números de Reynolds, evitando o contato direto do núcleo turbulento (mistura bifásica) com a parede do tubo. O referido filme líquido foi detectado e quantificado utilizando-se técnica visual. Além disso, um modelo dinâmico baseado na teoria de lubrificação hidrodinâmica foi desenvolvido como tentativa de explicar a formação do filme líquido parietal no escoamento turbulento de dispersões óleo-água. / Liquid-liquid flow, especially oil-water flow, has attracted the attention of researchers due to the high demand for petroleum in the current global scenario. The discovery of reserves of heavy and highly viscous oils creates new challenges which are mainly concerned with reducing the significant pressure drop in pipes. Inverse emulsion or oil-in-water dispersions in which the oil is dispersed in water is characterized by its low effective viscosity, making it a desirable type of emulsion in some steps of oil production. These facts make the study of dispersed liquid-liquid flow essential for the design and optimal operation of oil pipelines. However, the studies on such flow pattern are scanty in comparison to those on separate flows, as stratified and annular flow patterns. Drag reduction in oil-water turbulent flow without the addition of any chemical substance has been reported in some studies. This phenomenon has received increasing attention in recent years, because there is not a satisfactory understanding of its dynamics yet. Most studies, almost all using light oils, report drag reduction in dispersion of water-in-oil, with few studies reporting the phenomenon in oil-in-water dispersions. This research comprises an experimental and theoretical study on oil-in-water dispersions in pipes. Pressure gradient, holdup, phase distribution and flow patterns data were obtained to characterize the two-phase flow. A theory was proposed to explain the drag reduction detected in this work, based on the existence of a thin water film flowing in contact with the pipe wall at low Reynolds numbers, avoiding contact between the turbulent core (mixture) and the pipe wall. The liquid film was detected and quantified using visual technique. In addition, a dynamic model based on the hydrodynamic lubrication theory was developed as an attempt to explain the formation of the liquid film.

Submitted by Renata Lopes (renatasil82@gmail.com) on 2017-04-26T12:14:24Z No. of bitstreams: 1 gabrielazevedofogli.pdf: 13619054 bytes, checksum: d260cb2571f242e43eab89132a03d62c (MD5) / Approved for entry into archive by Adriana Oliveira (adriana.oliveira@ufjf.edu.br) on 2017-04-26T12:26:45Z (GMT) No. of bitstreams: 1 gabrielazevedofogli.pdf: 13619054 bytes, checksum: d260cb2571f242e43eab89132a03d62c (MD5) / Made available in DSpace on 2017-04-26T12:26:45Z (GMT). No. of bitstreams: 1 gabrielazevedofogli.pdf: 13619054 bytes, checksum: d260cb2571f242e43eab89132a03d62c (MD5) Previous issue date: 2014-03-19 / CAPES - Coordenação de Aperfeiçoamento de Pessoal de Nível Superior / Esta dissertação apresenta um estudo de conexão de um grupo gerador-diesel (GMG) trifásico em uma rede secundária de distribuição de energia elétrica. A integração do GMG é feita por uma unidade de processamento de energia (PPU) composta por um retificador trifásico não controlado conectado em série com um conversor fonte de tensão (VSC) modulado com uma estratégia de modulação por largura de pulso. O GMG pode operar de duas maneiras distintas: (i) modo standby (interligado) ou (ii) modo isolado. O conversor de saída da PPU pode ser controlado para injetar potência ativa na rede CA, ou como um filtro ativo de potência (FAP) compensando potência reativa e correntes harmônicas nos terminais das cargas. O VSC de interface é controlado no modo de corrente (CMC), sendo seus controladores projetados a partir de funções de transferência obtidas com o modelo matemático do sistema elétrico nas coordenadas dq0. Esses controladores são projetados com múltiplos integradores para garantir a qualidade da forma de onda da corrente injetada na rede CA. Dependendo do modo de operação é utilizada uma malha adicional para regular a tensão do barramento CC do conversor de interface. Para validar o modelo matemático e o algoritmo de controle são realizadas simulações digitais no programa PSIM. Resultados experimentais, obtidos com um protótipo de laboratório, cujos controladores foram implementados em um processador digital de sinais TMS320F28335 da Texas Instruments, são usados para validar as estratégias de controle propostas. / This dissertation presents a study about the connection of a three-phase Diesel Genset (DG) to a secondary distribution network. The integration of DG is done by a Power Processing Unit (PPU) composed of a three-phase rectifier connected in series with a Pulse Width Modulated Voltage Source Converter (VSC). The DG can operate in two distinct modes: (i) standby (interconnected) or (ii) islanding. The PPU’s output converter can be controlled to inject active power into AC electric grid, or as an Active Power Filter (APF), compensating the reactive power and harmonics currents at the load terminals. The VSC is controlled employing the current mode control (CMC), and its compensators are designed based on the electrical system transfer function in dq0 coordinates. Multiple rotating synchronous reference frame integrators (PI-MRI) are used to ensure the quality of the generated power. Depending on the operating mode, an additional loop is used to regulate the DC bus voltage. In order to validate the mathematical model and the control algorithm, digital simulations using PSIM are performed. Experimental results obtained with the prototype, which controllers were implemented in a TMS320F28335 of Texas Instruments are used to validate the proposed control strategies.

Dans une première partie, une nouvelle méthodologie, précise et hautement sensible de caractérisation des paramètres thermiques de liquides par radiométrie photothermique est ici présentée. Deux configurations expérimentales sont proposées. Elles ont été testées et validées avec des matériaux liquides usuels aux paramètres thermiques connus. Par la suite, cette démarche a été utilisée pour l'étude de polymères dispersés dans des cristaux liquides. Les propriétés thermiques dynamiques de chaque échantillon ont été mesurées en fonction de l'amplitude du champ électrique appliqué à une fréquence donnée aussi bien qu'en fonction de la fréquence du champ électrique à une amplitude fixe. Cette étude a montré que les propriétés thermiques étaient sujettes aux effets du champ de dépolarisation aux basses fréquences. La seconde partie de ce manuscrit décrit la nouvelle technique photothermique basée sur l'effet thermoélectrique. Cette technique est utile pour caractériser thermiquement les matériaux thermoélectriques sans avoir à recourir à un capteur extérieur pour mesurer le changement de température. Une étude théorique et expérimentale est présentée. Ces expériences ont été réalisées avec des composites polyaniline/nanotubes de carbone par mesure de la tension générée par l'échantillon thermoélectrique chauffé par un faisceau laser. Des mesures additionnelles à l'aide de la radiométrie infrarouge sur ces mêmes échantillons ont été entreprises et les résultats sont en bon accord avec ceux précédemment trouvés. Enfin, la possibilité d'utiliser les matériaux thermoélectriques comme capteur photothermique au travers d'une cavité résonnante à ondes thermiques est évoquée. / Primarily, newly developed, high sensitive and accurate methods for thermal characterization of liquids using photothermal radiometry are presented. Two experimental configurations are suggested, tested and validated with usual liquid materials. These methods are used to study polymer dispersed liquid crystal samples. Dynamic thermal properties of samples are analysed verses amplitude varying applied electric field with constant frequency as well as versus frequency varying electric field with constant amplitude. Our results clearly show the thermal properties of the samples are prone to depolarizing field effects at the lower frequencies of the applied electric field. The experimental results are modeled against existing theories to predict electric properties of the sample composites. Second part of the manuscript describes the development of a novel photothermal technique based on thermoelectric effect. This technique is particularly useful for thermally characterizing thermoelectric materials without using a separate sensor for measuring induced temperature changes. A theoretical and experimental study is presented. The experiments are done on polyaniline - carbon nanotube composite pellets by measuring Seebeck voltage generated by the samples upon heating by a modulated laser beam. Additional infrared radiometry experiments are done on the same samples and the results are in good agreement with those previously found. Later on, the possibility of photothermoelectric materials to be used as sensors for finding thermal transport properties of materials with a thermal wave resonant cavity is suggested.

Cette thèse s'appuie sur la spectroscopie de NiH établie à la fin des années 1980 et au début des années 1990, principalement par le groupe du Pr. R. W. Field au MIT. Les mesures expérimentales ont amélioré de manière significative les travaux antérieurs, tant en spectroscopie en champ nul qu'en spectroscopie Zeeman. Le radical NiH est obtenu avec une source à décharge à température ambiante (310 K). Les radicaux formés dans la décharge sont excités par un laser continu à colorant et étudiés soit en spectroscopie d'excitation laser soit en fluorescence dispersée. Un circuit magnétique à aimants permanents (NdFeB) fournit un champ magnétique statique (0.4 – 0.9 T). En champ nul, les spectres de fluorescence par transformée de Fourier ont élargi les observations de l'état électronique fondamental jusqu'à 6000 cm-1, pour 58NiH et 60NiH. Les énergies sont modélisées avec un Hamiltonien effectif obtenu à partir du formalisme du modèle du 3d9 supermultiplet développé par le groupe de Field. Les mesures Zeeman se sont principalement concentrées sur l'étude des états Ω=3/2. Les facteurs de Landé effectifs ont été déterminés pour chaque niveau ro-vibrationnel pour les états de basse énergie et les états excités de 58NiH. L'inhabituelle dépendance en J des facteurs de Landé obtenus pour les états de basse énergie est expliquée par le modèle du supermultiplet, quantifiant alors l'ampleur des mélanges spin-orbite présents dans les états inférieurs. Les transitions étudiées ont un intérêt astrophysique depuis que plusieurs transitions d'hydrure métallique ont été observées dans les spectres d'étoiles froides et les taches solaires. / This thesis builds on the spectroscopy of NiH established in the late 1980s and early 1990s, principally by Pr. R. W. Field's group at MIT. Experimental measurements significantly extend earlier work, both in field-free and Zeeman spectroscopy. The NiH radical is obtained with a room-temperature metal-hydride discharge source (310 K). Radicals formed in the discharge are excited by a single-mode, continuous wave dye laser and can be conveniently studied either in laser excitation or in dispersed fluorescence. A magnetic circuit with permanent magnets (NdFeB) provides a static magnetic field (0.4 – 0.9 T). In the field-free regime, Fourier transform resolved fluorescence spectra have extended the range of observations up to 6000 cm-1 above v=0 of the electronic ground state, for 58NiH and 60NiH. Energies are modeled with an effective Hamiltonien matrix using the 3d9 supermultiplet formalism developed by Field's group. Zeeman measurements have focused mainly on the range of states studied by including transitions involving the Ω=3/2 excited states. Effective Landé factors have been determined for individual ro-vibrational levels of low-lying and excited states of 58NiH. The unusual J-dependence of the Landé factors obtained for low-lying states are explained by the 3d9 supermultiplet model, quantifying the extent of spin-orbit mixing present in the lower states. The transitions are of potential astrophysical interest since several transition metal hydrides have been observed in the spectra of cool stars and sunspots.

The diploma thesis deals with dispersed generation (production). The small electric power sources are connected into distribution networks. Types and principles of the small electric power sources are studied. The legislation framework concerning renewable energy sources utilization is described. These power plants have impact into distribution networks and therefore techniques for the source connection to distribution network are included in the thesis. The impact of the specific small source of electricity must be studied.