Heutzutage werden bereits klein- bis mittelformatige Fassadenplatten aus Textilbeton mit Flächen bis zu 6 m² im Bauwesen verwendet. Dabei werden die ca. 25 mm dicken Elemente mit netzartigen technischen Textilien aus AR-Glas bewehrt. In einem kürzlich abgeschlossenen Forschungsprojekt wurde eine großformatige Fassadenplatte aus Textilbeton mit einer Elementfläche von 12,2 m² entwickelt, die eine Plattendicke von nur 30 mm aufweist. Die Platte wurde mit zwei rückseitigen monolithisch verbundenen Betonstegen ausgesteift. Durch die Beschichtung der Textilien mit Epoxidharz konnten formstabile und formbare Bewehrungsstrukturen entwickelt werden, die Textilspannungen von bis zu 1400 N/mm² aufweisen. In einem Pilotprojekt wurden die Ergebnisse des Forschungsprojektes angewendet und ihre Praxistauglichkeit nachgewiesen. Der Artikel beschreibt das architektonische Konzept, gibt Hinweise zur konstruktiven Durchbildung und beschreibt Herstellverfahren der textilen Bewehrung und Fassadenplatte.

Articular cartilage which covers the surfaces of synovial joints is designed to allow smooth contact between long bones and to absorb shock induced during joint movement. Tissue engineering, a means of combining cells, biomaterials, bioreactors and bioactive agents to produce functional tissue replacements suitable for implantation, represents a potential long-term strategy for cartilage repair. The interplay between environmental factors, however, gives rise to complex culture conditions that influence the development of tissue-engineered constructs. A fibrous capsule that is composed of abundant type I collagen molecules and resembles fibrocartilage usually forms at the outer edge of neocartilage, yet the understanding of its modulation by environmental cues is still limited. Therefore, this dissertation was aimed to characterize the capsule formation, development and function through manipulation of biochemical parameters present in a hydrodynamic environment while a chemically reliable media preparation protocol for hydrodynamic cultivation of tissue-engineered cartilage was established. To this end, a novel wavy-wall bioreactor (WWB) that imparts turbulent flow-induced shear stress was employed as the model system and polyglycolic acid scaffolds seeded with bovine primary chondrocytes were cultivated under varied biochemical conditions. The results demonstrated that tissue morphology, biochemical composition and mechanical strength of hydrodynamically engineered cartilage were maintained as the serum content decreased by 80% (from 10% to 2%). Transient exposure of the low-serum constructs to exogenous insulin-like growth factor-1 (IGF-1) or transforming growth factor-β1 (TGF-β1) further accelerated their development in comparison with continuous treatment with the same bioactive molecules. The process of the capsule formation was found to be activated and modulated by the concentration of serum which contains soluble factors that are able to induce fibrotic processes and the capsule development was further promoted by fluid shear stress. Moreover, the capsule formation in hydrodynamic cultures was identified as a potential biphasic process in response to concentrations of fibrosis-promoting molecules such as TGF-β. Comparison between the capsule-containing and the capsule-free constructs, both of which had comparable tissue properties and were produced by utilizing the WWB system in combination with IGF-1 and TGF-β1, respectively, showed that the presence of the fibrous capsule at the construct periphery effectively improved the ability of engineered cartilage to integrate with native cartilage tissues, but evidently compromised its tissue homogeneity. Characterization of the fibrous capsule and elucidation of the conditions under which it is formed provide important insights for the development of tissue engineering strategies to fabricate clinically relevant cartilage tissue replacements that possess optimized tissue homogeneity and properties while retaining a minimal capsule thickness required to enhance tissue integration.

Electrically conductive adhesives (ECA) are an alternative to tin/lead solders for attaching Surface Mount Devices (SMD) in electronic assemblies. ECAs are mixtures of a polymer binder (for adhesion) and conductive filler (for electrical conductivity). They bring more conductivity, higher strength, less weight and longer durability than metal alloys. ECAs can offer numerous advantages such as fewer processing steps, lower processing temperature and fine pitch capability. Multi walled carbon nanotubes (MWCNT) were used as conductive fillers in this research because of their novel electronic and mechanical properties. The high aspect ratio of the nanotubes makes it possible to percolate at low loadings to obtain good electrical and mechanical properties. Replacing the metal filler with CNTs in the adhesive made the ECA light weight, corrosion resistant, reduced processing temperature, lead free, electrically conductive and high mechanical strength. The MWCNTs at different loadings were mixed with epoxy and epoxy: heloxy to form a composite mixture. Different loadings, additives and mixing methods were used to obtain good electrical and mechanical properties and pot life. Pressure dispensing, screen and stencil printing were the processing techniques used for making the samples. The volume resistivity, contact resistance, die shear and lap shear tests were conducted on different surface finished Printed Circuit Boards (PCB) like silver, tin and Electro less Nickel Immersion Gold (ENIG). The results are summarized and compared with traditional methods.

Carbon nanotubes (CNTs) are well known as excellent electrical conductors. However, their transport properties are limited by electrical breakdown in ambient. Moreover, the electronic properties can further be modulated by doping. Devices such as Schottky diodes, transistors and logic gates based on un-doped and doped CNT junctions have been realized. Recently, nitrogen doped CNTs show potential application in replacing platinum cathode catalyst in fuel cell technology. We synthesize pristine, nitrogen-doped and nitrogen-doped:pristine CNT intratubular junctions by one-step co-pyrolysis and explore them for different applications. We show that the position of electrical breakdown can be predicted which is essential to know for high current applications. Among other applications, we show that individual CNT intratubular junction exhibits rectifying characteristics. Further investigation indicates the intratubular junction behaves like Schottky diode. Lastly, the potential replacement of platinum by nitrogen doped CNTs in direct methanol fuel cell has been explored.

The purpose of this thesis is to propose several corotational beam formulations for both 2D and 3D nonlinear dynamic analyse of flexible structures. The main novelty of these formulations is that the cubic interpolation functions are used to derive not only the internal force vector and the tangent stiffness matrix but also the inertial force vector and the dynamic matrix. By neglecting the quadratic terms of the local transversal displacements, closed-form expressions for the inertial terms are obtained for 2D problems. Based on an extensive comparative study of the parameterizations of the finite rotations and the time stepping method, and by adopting an approximation of the local rotations, two consistent and effective beam formulations for 3D dynamics are developed. In contrast with the first formulation, the second one takes into account the warping deformations and the shear center eccentricity. The accuracy of these formulations is demonstrated through several numerical examples.

Carbon nanotubes are molecular-scale tubes of graphitic carbon that possess many unique properties. They have high tensile strength and elastic modulus, are thermally and electrically conductive, and can be structurally modified using well established carbon chemistries. There is global interest in taking advantage of their unique combination of properties and using these interesting materials as components in nanoscale devices and composite materials. The goal of this research was the correlation of the mechanical properties of coiled carbon nanotubes with their chemical structure. Individual nanocoils, grown by chemical vapor deposition, were attached to scanning probe tip using the arc discharge method. Using a scanning probe microscope the nanocoils are repeatedly brought into and out of contact with a chemically-modified substrate. Precise control over the length (or area) of contact with the substrate is achievable through simultaneous monitoring the cantilever deflection resonance, and correlating these with scanner movement. The mechanical response of nanocoils depended upon the extent of their compression. Nonlinear response of the nanocoil was observed consistent with compression, buckling, and slip-stick motion of the nanocoil. The chemical structure of the nanocoil and its orientation on the tip was determined using scanning and transmission electron microscopy. The mechanical stiffness of eighteen different nanocoils was determined in three ways. In the first, the spring constant of each nanocoil was computed from the slope of the linear response region of the force-distance curve. The assumptions upon which this calculation is based are: 1) under compression, the cantilever-nanocoil system can be modeled as two-springs in series, and 2) the nanocoil behaves as an ideal spring as the load from the cantilever is applied. Nanocoil spring constants determined in this fashion ranged from 6.5x10-3 to 5.16 TPa for the CCNTs understudy. In the second, the spring constant of the nanocoil was computed from measuring the critical force required to buckle the nanocoil. The critical force method measured the force at the point where the nanocoil-cantilever system diverges from a linear region in the force curve. Nanocoil spring constants determined in this fashion ranged from 1.3x10-5 to 10.4 TPa for the CCNTs understudy. In the third, the spring constant of each nanocoil was computed from the thermal resonance of the cantilever-nanocoil system. Prior to contact of the nanocoil with the substrate, the effective spring constant of the system is essentially that of the cantilever. At the point of contact and prior to buckling or slip-stick motion, the effective spring constant of the system is modeled as two springs in parallel. Nanocoil spring constants determined in this fashion ranged from 2.7x10-3 to 0.03 TPa for the CCNTs understudy. Using the thermal resonance of the cantilever system a trend was observed relating nanocoil structure to the calculated modulus. Hollow, tube-like nanostructures had a higher measured modulus than solid or fibrous structures by several orders of magnitude. One can conclude that the structure of carbon nanocoils can be determined from using their mechanical properties. This correlation should significantly contribute to the knowledge of the scientific and engineering community. It will enable the integration of carbon nanocoils in microelectromechanical (MEMS) or nanoelectromechanical systems (NEMS) as resonators, vibration dampers, or any other application in which springs are used within complex devices.

Fabrication of SWCNT-PMMA and Activated Charcoal- PMMA composites was carried out by the compression moulding technique. Then Mechanical and Electrical properties of the composites were investigated. The morphological studies of composites showed a) good dispersion of fillers and b) good interaction between fillers and matrix. Electrical conductivity of SWCNT-PMMA composites was increased by 9 orders of magnitude (at 0.8 % volume fraction of SWCNT) and that of AC-PMMA composites increased by 16 orders of magnitude (at 17 % volume fraction of AC). The percolation threshold of both composites turned out to be lower compared to the theoretical values. A significant improvement in mechanical properties was obtained ??? particularly in AC-PMMA composites which showed a 400 % improvement in Vickers microhardness ??? raising the polymer matrix abrasion property literally to that of Aluminium alloys (Dobrazanski et al 2006). In conclusion, it is to be noted that Activated Charcoal - PMMA composites have a great potential for cost effective conducting polymer composite production by the use of cheap filler: In addition, the compression moulding technique shows good potential for cost effective fabricating technique for amorphous polymers with high electrical and mechanical properties.

[pt] Estruturas com elementos de seção aberta e paredes delgadas são amplamente utilizados em estruturas metálicas. Estes elementos têm, em geral, baixa rigidez a torção. Para seções monosimétricas e assimétricas, quando o centro de cisalhamento não coincide com o centro de gravidade, pode ocorrer acoplamento entre flexão e torção. Devido à baixa rigidez à torção, podem ocorrer grandes rotações das seções transversais da viga. Assim, uma análise do comportamento de tais elementos estruturais, levando em consideração a não linearidade geométrica, é desejável. Com este objetivo, equações diferenciais parciais de movimento que descrevem o acoplamento flexão-flexão-torção são utilizadas, em conjunto com o método de Galerkin, para se obter um conjunto de equações discretizadas de movimentos, que é resolvido pelo método Runge-Kutta. A partir das equações linearizadas, obtêm-se as frequências naturais, cargas críticas axiais e a relação entre carga axial e frequência para vigas com diferentes condições de contorno. A seguir, estudam-se as oscilações não lineares e bifurcações de uma viga engastada-livre submetida a cargas laterais harmônicas. Uma análise paramétrica detalhada, usando várias ferramentas de dinâmica não linear, investiga o comportamento dinâmico não linear e não planar da viga nas três primeiras regiões de ressonância e a influência da não linearidade, posição do carregamento, restrições à torção e parâmetros de controle do carregamento na estabilidade dinâmica da estrutura. / [en] Structural elements with open and thin-walled section are widely used in metal structures. These elements have, in general, low torsional stiffness. For monosymmetric and asymmetric sections, when the shear center does not coincide with the center of gravity coupling between bending and torsion may occur. Due to the low torsional stiffness, large twist beam cross sections may arise. Thus, an analysis of the behavior of such structural elements, taking into account the geometric nonlinearity, is desirable. For this purpose, partial differential equations describing the flexural-flexural-torsional coupling are used in conjunction with the Galerkin method to obtain a set of discretized equations of motion, which is solved by the Runge-Kutta method. From the linearized equations, we obtain the natural frequencies, axial critical loads, and the axial load and frequency relationship for beams with different boundary conditions. Next, we study the nonlinear oscillations and bifurcations of a clamped-free beam subjected to harmonic lateral loads. A detailed parametric analysis, using various nonlinear dynamics tools, investigates the nonlinear dynamic behavior and nonplanar motions of the beam for the first three regions of resonance and the influence of the non-linearity, loading position, torsional restraints and load control parameters on the dynamic stability of the structure.

The trend of structural engineering in the recent years is toward the use of lighter and moreeconomical structural elements. In steel construction, peculiarly, thin-walled structural elements arebecoming more popular and have a growing importance. Improved techniques in a manufacturing ofthin-walled elements have led to increased competitiveness of such products in the buildingapplications. Some examples of such structural element can be found in everyday life in form ofcolumns, studs, roofing trusses, and light-weight frames. However, the use of slender profiles and acomplex cross sections shape lead to requirements to study instability phenomenon in a form of local,distortional, flexural, torsional and coupled instability. Such complex structural behavior is inevitablyaccompanied by demand to improve calculation methods and design provisions. In this thesis, aninnovative solution of structural element composed of thin-walled plates is proposed for theapplication on lattice support structure of wind turbine.Thin-walled cold-formed profiles are steel products usually made from cold rolled coils and folded inthe second step. In this way, only open profiles can be produced. The predominant problem of theopen cross-section is the excessive torsional effect caused by the non-coincidence between the shearcenter and mass center, and a poor torsional resistance. A better response is possible with closed crosssections, but such profiles could not be produced by the folding. The solution is to make semi-closedsection by assembling them into polygonal profiles with mechanical fasteners, as presented in thisthesis.Objective of this work is to study the proposed structural sections in design situation and toinvestigate possible design models. The expected structural behavior of the column is a mixturebetween the open and closed cross-section. These cases will be investigated through numerical study.In this thesis presented a comprehensive parametric study on the ultimate strength of proposed coldformedsteel columns using the Finite Element package ABAQUS. FE models were first developedfor columns by using automation that was made through MATLAB and Python script. The bucklingand non-linear FE study was done for the investigation of local (L), distortional (D) and global (G)possible buckling failures and ultimate resistance, respectively. Modelling issues such as boundaryconditions, meshing, initial imperfections, material models, and non-linear solution controls in FEAwere also addressed.The parametric study involved series of profiles of built-up polygonal cross-section types with variedthickness (t), number of corners (n), diameter (d), slenderness (slend), yield strength (fy), number ofpoints along corner radii (np), extension lip length (lext), gusset plate thickness (tg), member length (l),and density of fasteners (s/d ratio), loaded in compression and bending moment. The bending momentoccurs as the effect of forces acting on the connection. The purpose of this analysis is to study thecritical load, cross-sectional behavior, influence of the amplitude of initial imperfections on theultimate load, and influence of each parameter used in the analysis through Full Factorial Design.

Ce travail est dédié à l’étude de l’encapsulation de molécules organiques photoactives dans des nanotubes de carbone mono-feuillets. L’effet de confinement sur les propriétés vibrationnelles , structurales, et les interactions entre les sous-systèmes est étudié en fonction de la taille des nanotubes. La première partie du manuscrit est consacrée à l’étude du confinement de diméthylquaterthiophènes dans les tubes. La dynamique vibrationnelle des molécules confinées est étudiée par diffusion inélastique des neutrons et par des simulations DFT. L’étude des interactions entre les deux sous-systèmes, en termes de transfert d’énergie et de transfert de charge, est réalisée en combinant des études de photoluminescence et de Raman. La nature des transferts de charge dépend de la taille du nanotube. Pour des tubes de petits diamètres (<1.1nm), un transfert de charge photo-induit est obtenu lorsque la longueur d’excitation correspond à l’absorption de la molécule. La deuxième partie est dédiée à l’étude de l’organisation structurale de molécules de phtalocyanine encapsulées à l’intérieur des nanotubes. Ce travail combine des études expérimentales par diffraction neutronique et spectroscopie Raman à pression ambiante et sous hautes pressions. Les études structurales sont confrontées à des simulations par dynamique moléculaire. / This work is dedicated to the study of the encapsulation of photoactive molecules within single wall carbon nanotubes. The confinement effect on vibrational, structural and interactions between host and guest is studied as a function of nanotube size. The first part of the manuscript is dedicated to the confinement of dimethyl quaterthiophene within carbon nanotubes. Vibrational dynamics for the encapsulated molecules is studied coupling neutron scattering and DFT simulations. Interactions molecule/nanotube, in terms of energy transfer and charge transfer are studied combining photoluminescence and Raman spectroscopies. The nature of charge transfers depends on the size of the nanotube. For small diameters (>1,1nm) a photoinduced charge transfer is obtained when the excitation wavelength matches the absorption of the molecule. The second part of the manuscript focuses on the structural organization of encapsulated phthalocyanine molecules. This work combines neutron diffraction and Raman spectroscopy experimental studies at room and high pressures. Structural studies are discussed together with molecular dynamics simulations.