The dissolved silicon (DSi) has a crucial role for growth of a large group of primary producers – diatoms and, hence, impact on functioning of the aquatic food web. This thesis contributes to an increased understanding of the modifications of the DSi cycling in the Baltic Sea. The results provide new information about spatial and temporal changes in DSi concentrations and nutrient ratios for the period 1970-2001 as well as during the 20th century. For the period 1970-2001, the declining DSi trends were found at the majority of monitoring stations all over the Baltic Sea. This decrease is assumed to be mainly due to the ongoing eutrophication. It is supported by the increasing trends of inorganic nitrogen and phosphorus. The trends have implications for the nutrient ratios, DSi:DIN and DSi:DIP, which are important indicators of the state of an ecosystem. The long-term retrospective DSi budget has shown that the DSi concentrations before major hydrological alterations and eutrophication were about twice the present ones. This decrease is related to both eutrophication and anthropogenic perturbations in the catchment. The occurrence of DSi concentrations close to the potentially limiting levels has been also analysed. While DSi concentrations are still high in the northern regions of the Baltic, other areas may be at risk of developing Si limitation if the decrease in DSi concentrations persists. The results depict the Baltic Sea journey from being water body with DSi levels sufficient to support diatom production to one that may experience Si limitation and its adverse ecological consequences. / Löst kisel (DSi) har en viktig roll för tillväxten av en stor grupp av primärproducenter – kiselalger, och därmed även påverkar hela den akvatiska näringskedjan. Denna avhandling bidrar till en ökad förståelse av förändringarna i DSi kretsloppet i Östersjön. Resultaten tillhandahåller ny information om rumsliga och tidsmässiga förändringar i DSi koncentrationer såväl för perioden 1970-2001 som för hela 1900-talet. För perioden 1970-2001 återfanns minskade DSi koncentrationer på mätstationer över hela Östersjön. Minskningen antas främst bero på den pågående övergödningen. Detta antagande stöds av stigande halter av oorganiskt kväve och fosfor. Sammantaget har dessa trender en inverkan på ekosystemets tillstånd och näringsämnenas kvoter, DSi: DIN och DSi: DIP. Ur ett längre tidsperspektiv kan man se att innan övergödningen och de stora hydrologiska ombildningar i Östersjöområdet var DSi koncentrationerna ungefär dubbelt så höga som idag. Dagens förekomst av DSi koncentrationer som ligger nära de potentiellt begränsande nivåerna har också analyserats. DSi koncentrationerna är fortfarande höga i norra delar av Östersjön, men är i andra områden i riskzonen för att utveckla Si begränsning om minskningen av DSi koncentrationer fortsätter. Resultaten skildrar Östersjöns resa från att vara ett havsområde med DSi halter som är tillräckliga för att understödja kiselalgernas produktion till ett sådant som kan uppleva Si begränsning och dess negativa ekologiska konsekvenser.

Isotope analyses on human and faunal skeletal remains from different Swedish Neolithic archaeological contexts are here applied as a means to reconstruct dietary strategies and mobility patterns. The chronological emphasis is on the Middle Neolithic period, and radiocarbon dating constitutes another central focus. The results reveal a food cultural diversity throughout the period in question, where dietary differences in part correspond to, but also transcend, the traditionally defined archaeological cultures in the Swedish Early to Middle Neolithic. Further, these differences, and the apparent continued utilisation of marine resources in several regions and cultural contexts, can only in part be explained by chronology or availability of resources depending on geographic location. Thus, the sometimes suggested sharp economic shift towards an agricultural way of life at the onset of the Neolithic is refuted. Taking the potential of isotope analyses a step further, aspects of Neolithic social relations and identities are discussed, partly from a food cultural perspective embarking from the obtained results. Relations between people and places, as well as to the past, are discussed. The apparent tenacity in the dietary strategies observed is understood in terms of their rootedness in the practices and social memory of the Neolithic societies in question. Food cultural practices are further argued to have given rise to different notions of identity, some of which can be related to the different archaeological cultures, although these cultures are not to be perceived as bounded entities or the sole basis of self-conceptualisation. Some of these identities have been focused around the dietary strategies of everyday life, whereas others emanate from practices, e.g. of ritualised character, whose dietary importance has been more marginal. Isotope analyses, when combined with other archaeological indices, have the potential to elucidate both these food cultural aspects. / At the time of the doctoral defense, the following papers were unpublished and had a status as follows: Paper 3: Submitted. Paper 4: Submitted. Paper 5: In press. Paper 6: Accepted.

Mathematical modeling and simulations of a submerged renewable storage system integrated to a wind farm, chosen based on the geographical and wind conditions at the Baltic Sea, gives insight on the feasibility of the submerged renewable storage and an approximation of the payback period and profits that could be generated. Genetic Algorithms were used to obtain the optimal number of spheres for a certain depth, based on 2 objective functions I.e. Minimum Life Cycle Cost (LCC) and maximum reduction in wind curtailment. The new arrangement concept shows that the Initial Capital Cost (ICC) could be decreased by 25% to 60% depending upon the number of sphere employed. Based on the inputs considered in the study, the results prove that the submerged renewable storage system would be feasible, and the profits ranging from 15 Million Euro to 29 Million Euro can be achieved at the chosen location, towards the Swedish side of the Baltic sea. Although, in a real life scenario it is assumed that only up to half of the profits obtained in the results would be achievable. The results also show that, the Pump/Turbine with a high turbine efficiency and lower pump efficiency, generated better profits, compared to a Pump/Turbine running with a higher pump efficiency and lower turbine efficiency. An attempt to increase the round-trip efficiency by adding a multi stage submersible pump, resulted in additional ICC and LCC, which saw a decrease in profits.

The study begins with a historical background over the fisheries development in North America and in the Baltic Sea area in Finland and Sweden. As we can see the fisheries development depends on the interaction between ecology, state of production, politic and also social factors. In Sweden the fishery politic has changed over the period of the study. In the 1970: s the main politic focus was on the fisheries progress, expansion and rationalization. The State in Sweden took a vast part in this development and gave economic support. In the 1980: s the fishery politic in Sweden started to change and the environmental politics began to enter the fishery politic. The environmental problems in the Baltic Sea were given attention and it was a great anxiety over the eutrophication. In the 1980: s the codpopulation declined and with them the catches declined. The conflict over the White zone 1978-1988 between Former Soviet Union and Sweden resulted in a plunder fishery in the area east of Bornholm. This plunder fishery effected the cod population enormous and the effect has continued to the late 1990: s. In 1995 Sweden joined the European Union and the common fishery politic replaced the Swedish fishery politic. The system with TAC (Total Allowable Catch) is central in the common politic and it is used to control the cod catches. But the problem is that the TAC -volume has been higher than the codpopulation could stand. Despite the politic goal in Sweden and EU to preserve the codpopulation in the Baltic Sea, the codpopulation has continued to decline. The reason to this politic failure is that the limit of the ecology has been overseen. Instead, the economic and social values have been dominating the politic and together with a to weak control of the catches and environmental problems in the Baltic Sea, the situation for the cod has been devastating.

This study is conducted with the purpose to unfold hidden sides of the EU – Russian energy cooperation and to shed a light on possible reasons for existing problems that have rarely been voiced before. This study provides an alternative view on the role of the Baltic Sea region in the overall EU – Russian energy dialogue and its current situation. In this research the historical observation of the energy interdependence regime development is examined and the crucial turning points in the energy interdependence like the EU enlargement 2004, the gas cut offs 2006 and 2009, and crises 2014 are reconsidered. The energy security policies of the EU and Russia are analyzed by adopting the realist approach and applied to the case of the Baltic Sea region. Furthermore, based on the regional complex security theory and interdependence theory, the way how interstate gas relations in the Baltic Sea region affect the EU – Russian interdependence is discussed.

In the semi-enclosed Baltic Sea, excessive filamentous macro-algal biomass growth as a result of eutrophication is an increasing environmental problem. Drifting huge masses of red algae of the genera Polysiphonia, Rhodomela, and Ceramium accumulate on the open shore, up to five tones of algae per meter beach. During the aerobic decomposition of these algal bodies, large quantities of red colored effluents leak into the water what are toxic for the marine environment. In this study, feasibility of anaerobic conversion of red algae Polysiphonia, rich in nitrogen and phosphorous, was investigated. Biogas and methane potential of Polysiphonia, harvested in two different seasons [October and March], was investigated through three different batch digestion experiments and laboratory scale CSTR [continuous stirred tank reactor] at mesophilic (37oC) condition. Autoclavation [steam and heat] and ultrasound pretreatments were applied in order to enhance the biodegradation. In STR, anaerobic codigestion of algal biomass with SS [sewage sludge] was applied with a gradual increase in organic loading rate [1.5-4.0 g VS/L/day] and operated for 117 days at 20days HRT [hydraulic retention time]. Reactor digestate was analyzed four times over the period to determine the nutrients and heavy metals content. It is concluded that the methane potential of algae harvested in October is almost two-fold than that of algae harvested in March, probably due to it’s higher [more than double] nitrogen richness. An increase in biogas yield was observed upto 28% and VS reduction was increased from 37% to 45% due to autoclave pretreatment. Ultrasound pretreatment had no effect on digestion. In batch digestion, maximum methane yield 0.25 m3/kg VS added at 273oK, was obtained from algae [harvested in October] pretreated in autoclave. Codigestion of algae with SS worked well in STR with a comparatively lower OLR. At a higher OLR, methanogens were inhibited due to increased VFAs accumulation and decreased pH. A maximum biogas yield 0.49 m3/kg VS added at 310oK , was obtained from algae [harvested in October] pretreated with autoclave. The methane content of the produced biogas was 54%. Average [over a short period, day 99-107, reactor showed steady performance] maximum biogas yields from untreated algae obtained 0.44 m3/kg VSadded at 310oK and the VS reduction was calculated 32%. Digestate, to be used as a fertilizer, was found NH4-N, N, P, K, S and Na rich and only Cadmium level was above the maximal limit among the heavy metals. The sand content in algae during harvesting was considered as a factor to disrupt the operation. Codigestion of Polysiphonia algal biomass with substrate with higher C:N ratio like paper mill waste should be more appropriate to increase the methane and biogas yield. It is inconclusive whether AD process is a good method to dewater redalgae or not but large scale harvesting of algae will definitely contribute to curb eutrophication of the Baltic Sea through decreasing N and P level.

The aim of this thesis was to study the Baltic Sea Region (BSR) Programme and the North Sea Region (NSR) Programme within the Transnational Interreg IV B Programme for the period 2007-2013, by making a comparison between Sweden and Denmark. The thesis looked at the level of involvement of both National Planning Authorities in the designing process of the programmes and projects, and investigated whether the Interreg programmes influence the authorities in their work with future policy-making, and the national spatial planning policies in general. The ambition of the thesis was also to clarify the links between the Interreg Programmes, the ESDP document, the Territorial State and Perspectives of the European Union and the Territorial Agenda, and how these documents have influenced the EU Territorial Cohesion debate and the creation of the EU Baltic Sea Strategy. The reason was to better understand the role of the National Planning Authorities in the implementation of the transnational programmes and their work towards territorial cohesion. The methods used for the thesis consisted of secondary research and analysis of the intergovernmental “Territorial Documents”, the Interreg programmes and their specific projects, and not least, the study of books, articles, and other documents and sources of interest for this topic. Interviews were made with people working at Swedish “Boverket”, Danish “By- og Landskabsstyrelsen” (BLST) and “Danske Regioner” (Danish Regions). Some of the main findings have been the different approaches among the Planning Authorities towards their potential leadership in the Interreg projects, the little time dedicated to the Interreg work in general at Swedish Boverket, and Boverket’s scarce intervention in the development-process of the EU Baltic Sea Strategy. On the Danish side there is very little priority given to the diffusion and transfer of knowledge, while in Sweden on the other hand, this is one of the main issues for all the authorities involved. The conclusion is that, even if Sweden and Denmark are close neighbours and are collaborating in many fields, there are some substantial differences in attitude and action towards their role as participators of the Transnational Interreg projects, differences which, if emphasised, could be useful knowledge for both parts in order to develop their own Interreg-work, responding to the growing interest of the EU in territorial concerns. / m.bengtsson@tiscali.it

This thesis explores the avenues for the ecosystem approach to management in the Baltic Sea Region. This region is one of the most contaminated water bodies in the world, although the first Regional Seas Convention was created here and theregion has a long history of cooperation and environmental protection. The current environmental governance arrangements are examined with specific focuson governance structures, cross-sectoral integration and ecological boundaries.The ecosystem approach to management as both a tool and vision of holistic management of natural resources is traced through the evolution of environmental governance, as well as its manifestation in contemporary environmental policies in the region. It is found that the major EU directives, as well as HELCOM polices, promote the ecosystem approach and that its presence has increased inrecent years; it is now the major guiding principle in European marine governance. However, the governance structures impede implementation indifferent ways. The environmental problem areas in the region all require different governance arrangements, thus obstructing a holistic approach. The environmental problems per se also affect each other, necessitating far-reaching sectoral integration and cross-border cooperation, which at present is the major obstacle regarding implementation. The contemporary trends combining solid regionalisation through HELCOM with increased Europeanisation and macro regionalisation by different EU initiatives offer some promise, but the cross sectoral impediments must be resolved if the ecosystem approach is to become apractical approach and not just a policy principle.

This thesis is focused on studies on the environmental fate and methodological improvements for determination of the global contaminants, PCBs and DDTs, and locally discharged phenolics, e.g. 4,5,6-trichloroguaiacol (4,5,6-TCG), and their transformation products. 4,5,6-TCG is released from bleached pulp mills, and was chosen as a model substance, to study its fate and effects in aquatic environments. In a brackish water model ecosystem, 4,5,6-TCG was shown to be transformed via demethylation, dechlorination, and methylation reactions. Marine periphyton exposed to 4,5,6-TCG was shown to form demethylated, brominated and dimeric metabolites. Several of these metabolites were identified and quantified. Also more tightly bound chlorophenolics were recovered from the substrate, after harsh extraction procedures had been applied. Conjugates of chlorophenols in fish bile were determined as useful tracers for monitoring effluents from bleached pulp mills, even in areas far from the discharge point. To facilitate calculations of water concentrations, bile to water bioconcentration factors (bBCF-values) were determined for several phenolics, including also alkali-labile chlorocatechols. PCBs and DDTs, were assessed in Swedish lakes with background exposure of these global contaminants. A methodological study focus on the contamination risks of airborne PCBs, during freeze-drying and storage of dry sediment samples. Eutrophication has been proposed to cause lower levels of pollutants in biota in lakes due to biomass dilution but in this thesis examples of higher levels of PCBs in sediment traps, sediment and in perch, and also in higher fluxes of PCBs to the sediment, were observed. Phytoplankton are supposed to be responsible for most of the transport of the contaminants. The composition of DDTs in soil, sediment traps and in dated sediment cores was studied in some detail. PCBs, DDTs, HCB and HCHs were measured in sediments from 100 reference lakes included in the National Swedish Environmental Program. The lakes have a large variation in lake characteristics, representative for different areas in Sweden. A gradient was observed for sPCB with decreasing levels from the south west towards the north. The results suggests that longrange transport is the dominating mechanism for distribution of the contaminants analysed. In this study the levles of PCBs and DDTs were lower in eutrophic lakes than in oligotrophic lakes, in an area with similar atmospheric exposure. / <p>At the time of the doctoral defense, the following papers were unpublished and had a status as follows: Paper 4: Submitted. Paper 6: Manuscript.</p>

Climate change is expected to increase the precipitation ~30% in higher latitudes during the next century, increasing the land runoff via rivers to aquatic ecosystems. The Baltic Sea will receive higher river discharges, accompanied by larger input of allochthonous dissolved organic matter (DOM) from terrestrial ecosystems. The salinity will decrease due to freshwater dilution. The allochthonous DOM constitute a potential growth substrate for microscopic bacterioplankton and phytoplankton, which together make up the basal trophic level in the sea. The aim of my thesis is to elucidate the bacterial processing of allochthonous DOM and to evaluate possible consequences of increased runoff on the basal level of the food web in the Baltic Sea. I performed field studies, microcosm experiments and a theoretical modeling study. Results from the field studies showed that allochthonous DOM input via river load promotes the heterotrophic bacterial production and influences the bacterial community composition in the northern Baltic Sea. In a northerly estuary ~60% of bacterial production was estimated to be sustained by terrestrial sources, and allochthonous DOM was a strong structuring factor for the bacterial community composition. Network analysis showed that during spring the diversity and the interactions between the bacteria were relatively low, while later during summer other environmental factors regulate the community, allowing a higher diversity and more interactions between different bacterial groups. The influence of the river inflow on the bacterial community allowed “generalists” bacteria to be more abundant than “specialists” bacteria.    Results from a transplantation experiment, where bacteria were transplanted from the northern Baltic Sea to the seawater from the southern Baltic Sea and vice versa, showed that salinity, as well as the DOM composition affect the bacterial community composition and their enzymatic activity. The results showed that α-proteobacteria in general were favoured by high salinity, β-proteobacteria by low salinity and terrestrial DOM compounds and γ-proteobacteria by the enclosure itself. However, effects on the community composition and enzymatic activity were not consistent when the bacterial community was retransplanted, indicating a functional redundancy of the bacterial communities.  Results of ecosystem modeling showed that climate change is likely to have quite different effect on the north and the south of the Baltic Sea. In the south, higher temperature and internal nutrient load will increase the cyanobacterial blooms and expand the anoxic or suboxic areas. In the north, climate induced increase in riverine inputs of allochthonous DOM is likely to promote bacterioplankton production, while phytoplankton primary production will be hampered due to increased light attenuation in the water. This, in turn, can decrease the production at higher trophic levels, since bacteria-based food webs in general are less efficient than food webs based on phytoplankton. However, complex environmental influences on the bacterial community structure and the large redundancy of metabolic functions limit the possibility of predicting how the bacterial community composition will change under climate change disturbances.