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The Synthesis and Structural Characterization of Metal Oxide Nanoparticles Having Catalytic ApplicationsSmith, Stacey Janel 03 July 2012 (has links) (PDF)
Nanotechnology is blossoming into one of the premiere technologies of this century, but the key to its progress lies in developing more efficient nanosynthesis methods. Variations in synthetic technique, however, can cause variations in size, structure, and surface characteristics, thereby altering the physical properties and functionality of the particles. Careful structural characterizations are thus essential for understanding the properties and appropriate applications for particles produced by new synthetic techniques.In this work, a new ‘solvent-deficient’ method is presented for the synthesis of an unprecedentedly wide range of metal oxide nanomaterials including at least one metal oxide from each group in Groups 3-4, 6-15, and the Lanthanides. XRD, BET, and TEM structural characterizations as well as chemical purity analyses of the products are given. The intermediates associated with the method are also investigated, allowing the reaction parameters to be rationalized and culminating in a proposed mechanism for the reaction. Several of the reaction intermediates are themselves useful products, expanding the range of this already versatile method. Optimized synthesis parameters as well as structural characterizations are presented for one such intermediate product, the iron oxyhydroxide called ferrihydrite.The Al2O3 nanoparticles produced by the new method show promise in catalyst support applications, and the synthesis and structural analysis (XRD, X-ray PDF, 27Al NMR, TG/DTA-MS) of these nanoparticles is provided. The XRD, PDF, and NMR analyses reveal that the initial boehmite-like phase transforms to the catalytically useful gamma-Al2O3 phase at unusually low temperatures (300-400°C), but boehmite-like local structure defects remain which heal slowly with increasing temperature up to 800°C. The ‘pure’ gamma-Al2O3 may still contain randomized, non-cubic, local structure distortions, and it transforms directly to alpha-Al2O3 at ~1050°C. To rationalize the local structure and the absence of the delta- and theta-Al2O3 phases during the alpha-phase transition, relationships between the many Al2O3 phases are presented via innovative symmetry-mode analyses, revealing a potential quazi-topotactic mechanism for the gamma-to-alpha transition.To stabilize the gamma-Al2O3 phase to higher temperatures for catalyst applications, 3 wt% of a lanthanum dopant was added via a new, 1-pot process based on the new solvent-deficient method. This process is described and X-ray PDF, TEM, 27Al NMR, and EXAFS analyses of the La-doped gamma-Al2O3 nanoparticles reveal that the dopant resides as isolated, adsorbed atoms on the gamma-Al2O3 surface. The first coordination shell of the isolated La is increasingly La2O3-like as calcination temperature increases but changes drastically to be more LaAlO3-like after the alpha-phase transition, which is delayed ~100°C by the La dopant. Combining the EXAFS, PDF, NMR, and symmetry-mode analyses, we provide new insight into the mechanism of stabilization provided by the La dopant.
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Enhanced Capabilities for Investigating Local Structure and Magnetism: Three Dimensional Magnetic Pair Distribution Function and Symmetry Mode AnalysisHamilton, Parker 21 August 2023 (has links) (PDF)
The local structure, atomic and magnetic structure correlated over a small length scale, of a material has a strong impact on material properties. Pair distribution function (PDF) analysis is a strong tool to investigate local structure and magnetism of this nature. This work outlines extensions to current one dimensional magnetic pair distribution functions (1D-mPDF) and the fitting of structures with symmetry breaking local atomic distortions. 1DmPDF analysis has been used to study local magnetic structure, but requires a rotational averaging of the correlations so directional information is lost, as in powder diffraction experiments. Three dimensional difference magnetic pair distribution function (3D-∆mPDF) analysis does not require this rotational averaging and preserves directional information. This is a useful tool in analyzing experimental data like single crystal neutron diffraction and studying locally anisoptropic magnetic structures. Here we present a technique and software tools to calculate the 3D-∆mPDF pattern of a given structure and give a brief analysis of the local magnetic structure of MnTe. Another problem in PDF analysis is the modeling of structures with symmetry breaking local atomic distortions. Symmetry-adapted distortion modes have been used for structural refinement in Rietveld refinement for at least 10 years; more more recently, this has also been applied to PDF data. We present here a detailed discussion of the use of symmetry-adapted modes for structural refinement using PDF data. We also outline new open-sourced software tools to apply this technique and show two analyses using symmetry-adapted structural modes.
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Sturcture of Three-Dimensional Separated Flow on Symmetric BumpsByun, Gwibo 14 November 2005 (has links)
Surface mean pressures, oil flow visualization, and 3-velocity-component laser-Doppler velocimeter measurements are presented for a turbulent boundary layer of momentum thickness Reynolds number, 7300 and thickness delta over two circular based axisymmetric bumps of height H = delta and 2delta and one rectangular based symmetric bump of H = 2delta. LDV data were obtained at one plane x/H ¥ 3.26 for each case. Complex vortical separations occur on the leeside and merge into large stream-wise mean vortices downstream for the 2 axisymmetric cases. The near-wall flow (y+ < 90) is dominated by the wall. For the axisymmetric cases, the vortices in the outer region produce large turbulence levels near the centerline and appear to have low frequency motions that contribute to turbulent diffusion. For the case with a narrower span-wise shape, there are sharper separation lines and lower turbulence intensities in the vortical downstream flow.
Fine-spatial-resolution LDV measurements were also obtained on half of the leeside of an axisymmetric bump (H/delta = 2) in a turbulent boundary layer. Three-dimensional (3-D) separations occur on the leeside with one saddle separation on the centerline that is connected by a separation line to one focus separation on each side of the centerline. Downstream of the saddle point the mean backflow converges to the focal separation points in a thin region confined within about 0.15delta from the local bump surface. The mean backflow zone is supplied by the intermittent large eddies as well as by the near surface flow from the side of the bump. The separated flow has a higher turbulent kinetic energy and shows bimodal histograms in local and U and W, which appear to be due to highly unsteady turbulent motions. By the mode-averaged analysis of bimodal histograms, highly unsteady flow structures are estimated and unsteady 3-D separations seem to be occurring over a wide region on the bump leeside. The process of these separations has very complex dynamics having a large intermittent attached and detached flow region which is varying in time. These bimodal features with highly correlated local u and w fluctuating motions are the major source of large Reynolds stresses local u2, w2 and -uw. Because of the variation of the mean flow angle in the separation zones, the turbulent flow from different directions is non-correlated, resulting in lower shearing stresses. Farther from the wall, large stream-wise vortices form from flow around the sides of the bump. / Ph. D.
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RISK BASED ANALYSIS AND DESIGN OF STIFFENED PLATESDwire, Heather B. 08 May 2008 (has links)
No description available.
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Stochastic distribution tracking control for stochastic non-linear systems via probability density function vectorisationLiu, Y., Zhang, Qichun, Yue, H. 08 February 2022 (has links)
Yes / This paper presents a new control strategy for stochastic distribution shape tracking regarding non-Gaussian stochastic non-linear systems. The objective can be summarised as adjusting the probability density function (PDF) of the system output to any given desired distribution. In order to achieve this objective, the system output PDF has first been formulated analytically, which is time-variant. Then, the PDF vectorisation has been implemented to simplify the model description. Using the vector-based representation, the system identification and control design have been performed to achieve the PDF tracking. In practice, the PDF evolution is difficult to implement in real-time, thus a data-driven extension has also been discussed in this paper, where the vector-based model can be obtained using kernel density estimation (KDE) with the real-time data. Furthermore, the stability of the presented control design has been analysed, which is validated by a numerical example. As an extension, the multi-output stochastic systems have also been discussed for joint PDF tracking using the proposed algorithm, and the perspectives of advanced controller have been discussed. The main contribution of this paper is to propose: (1) a new sampling-based PDF transformation to reduce the modelling complexity, (2) a data-driven approach for online implementation without model pre-training, and (3) a feasible framework to integrate the existing control methods. / This paper is partly supported by National Science Foundation of China under Grants (61603262 and 62073226), Liaoning Province Natural Science Joint Foundation in Key Areas (2019- KF-03-08), Natural Science Foundation of Liaoning Province (20180550418), Liaoning BaiQianWan Talents Program, i5 Intelligent Manufacturing Institute Fund of Shenyang Institute of Technology (i5201701), Central Government Guides Local Science and Technology Development Funds of Liaoning Province (2021JH6/10500137).
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Subdivision Rules, 3-Manifolds, and Circle PackingsRushton, Brian Craig 07 March 2012 (has links)
We study the relationship between subdivision rules, 3-dimensional manifolds, and circle packings. We find explicit subdivision rules for closed right-angled hyperbolic manifolds, a large family of hyperbolic manifolds with boundary, and all 3-manifolds of the E^3,H^2 x R, S^2 x R, SL_2(R), and S^3 geometries (up to finite covers). We define subdivision rules in all dimensions and find explicit subdivision rules for the n-dimensional torus as an example in each dimension. We define a graph and space at infinity for all subdivision rules, and use that to show that all subdivision rules for non-hyperbolic manifolds have mesh not going to 0. We provide an alternate proof of the Combinatorial Riemann Mapping Theorem using circle packings (although this has been done before). We provide a new definition of conformal for subdivision rules of unbounded valence, show that the subdivision rules for the Borromean rings complement are conformal and show that barycentric subdivision is almost conformal. Finally, we show that subdivision rules can be degenerate on a dense set, while still having convergent circle packings.
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Fusion Multicapteurs pour la Reconnaissance d'Activités des Personnes Agées à DomicileZouba Ep Valentin, Nadia 25 January 2010 (has links) (PDF)
Dans cette thèse, une approche combinant des données issues de capteurs hétérogènes pour la reconnaissance d'activités des personnes âgées à domicile est proposée. Cette approche consiste à combiner les données fournies par des capteurs vidéo avec des données fournies par des capteurs environnementaux pour suivre l'interaction des personnes avec l'environnement. La première contribution est un nouveau modèle de capteur capable de donner une représentation cohérente et efficace des informations fournies par différents types de capteurs physiques. Ce modèle inclue l'incertitude sur la mesure. La deuxième contribution est une approche, basée sur une fusion multicapteurs, pour la reconnaissance d'activités. Cette approche consiste à détecter la personne, suivre ses mouvements, reconnaître ses postures et ses activités d'intérêt, par une analyse multicapteurs et une reconnaissance d'activités humaines. Pour résoudre le problème de la présence de capteurs hétérogènes, nous avons choisi de réaliser la fusion à haut niveau (niveau événement) des différentes données issues des différents capteurs, en combinant les événements vidéo avec les événements environnementaux. La troisième contribution est l'extension d'un langage de description qui permet aux utilisateurs (ex. le corps médical) de décrire les activités d'intérêt dans des modèles formels. Les résultats de cette approche sont montrés pour la reconnaissance des AVQ pour de vraies personnes agées évoluant dans un appartement expérimental appelé GERHOME équipé de capteurs vidéo et de capteurs environnementaux. Les résultats obtenus de la reconnaissance des différentes AVQ sont encourageants.
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Dynamische Dokumenterstellung mit dem WebbrowserKnauf, Robert, Schröder, Daniel 31 January 2009 (has links) (PDF)
Wie lassen sich Corporate Design-konforme Drucksachen erzeugen, ohne Zugang zur Gestaltung zu haben.
Der Vortrag stellt das strukturierte Datenformat XML, die Transformationssprache XSLT, die Formatierungssprache XSL-FO und den FO-Prozessor Apache FOP vor.
Am praktischen Beispiel des TU Chemnitz-Plakatgenerators wird erläutert, wie der Formatierungsprozess abläuft.
Des Weiteren wird die Softwarearchitektur des Generators vorgestellt, der sich vorliegender XML-Schablonen bedient, um automatisch und dynamisch das Nutzer-Eingabeformular im Webbrowser zu erzeugen.
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Synthetic Aperture Sonar Micronavigation Using An Active Acoustic Beacon.Pilbrow, Edward Neil January 2007 (has links)
Synthetic aperture sonar (SAS) technology has rapidly progressed over the past few years with a number of commercial systems emerging. Such systems are typically based on an autonomous underwater vehicle platform containing multiple along-track receivers and an integrated inertial navigation system (INS) with Doppler velocity log aiding. While producing excellent images, blurring due to INS integration errors and medium fluctuations continues to limit long range, long run, image quality. This is particularly relevant in mine hunting, the main application for SAS, where it is critical to survey the greatest possible area in the shortest possible time, regardless of sea conditions. This thesis presents the simulation, design, construction, and sea trial results for a prototype "active beacon" and remote controller unit, to investigate the potential of such a device for estimating SAS platform motion and medium fluctuations. The beacon is deployed by hand in the area of interest and acts as an active point source with real-time data uploading and control performed by radio link. Operation is tightly integrated with the operation of the Acoustics Research Group KiwiSAS towed SAS, producing one-way and two-way time of flight (TOF) data for every ping by detecting the sonar chirps, time-stamping their arrival using a GPS receiver, and replying back at a different acoustic frequency after a fixed time delay. The high SNR of this reply signal, combined with the knowledge that it is produced by a single point source, provides advantages over passive point-like targets for SAS image processing. Stationary accuracies of < 2 mm RMS have been measured at ranges of up to 36m. This high accuracy allowed the beacon to be used in a separate study to characterise the medium fluctuation statistics in Lyttelton Harbour, New Zealand, using an indoor dive pool as a control. Probability density functions were fitted to the data then incorporated in SAS simulations to observe their effect on image quality. Results from recent sea trials in Lyttelton Harbour show the beacon TOF data, when used in a narrowband motion compensation (MOCOMP) process, provided improvements to the quality of SAS images centred on frequencies of 30 kHz and 100 kHz. This prototype uses simple matched-filtering algorithms for detection and while performing well under stationary conditions, the fluctuations caused by the narrow sonar transmit beam pattern (BP) and changing superposition of seabed multipath often cause dropouts and inaccurate detections during sea trials. An analysis of the BP effects and how the accuracy and robustness of the detection algorithms can be improved is presented. Overcoming these problems reliably is difficult without dedicated large scale testing facilities to allow conditions to be reproduced consistently.
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Concentration fluctuations of a passive scalar in a turbulent boundary layerNironi, Chiara 02 July 2013 (has links) (PDF)
This experimental study analyses the dynamics of concentration fluctuations in a passive plume emitted by a point source within the turbulent boundary layer. We aim to extend the popular study of Fackrell and Robins (1982) about concentration fluctuations and fluxes from point sources by including third and fourth moments of concentration. We also further inquire into the influence of source conditions, such as the source size, source elevation and emission velocity, on higher order concentration moments. The data set is completed by a detailed description of the velocity statistics within the TBL, with exhaustive information on both the temporal and spatial structure of the flow. The experimental data-set has been used to test two different modeling ap- proaches: an analytical meandering plume model (in one and in three dimen- sions) and a Lagrangian stochastic micro-mixing model.
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