Biomass burning in southern Africa has brought significant challenges to the research society as a fundamental driver of climate and land cover changes. Burned area mapping approaches have been developed that generate large-scale low and moderate resolution products made with different satellite data. This consequently afford the remote sensing community a unique opportunity to support their potential applications in e.g., examining the impact of fire on natural resources, estimating the quantities of burned biomass and gas emissions. Generally, the satellite-derived burned area products produced with dissimilar algorithms provide mapped burned areas at different levels of accuracy, as the environmental and remote sensing factors vary both spatially and temporally. This study focused on the inter-comparison and accuracy evaluation of the 500-meter Moderate Resolution Imaging Spetroradiomter (MODIS) burned area product (MCD45A1) and the Backup MODIS burned area product (hereafter BMBAP) across the main-fire prone South African biomes using reference data independently-derived from multi-temporal 30-meter Landsat 5 Thematic Mapper (TM) imagery distributed over six validation sites. The accuracy of the products was quantified using confusion matrices, linear regression and subpixel burned area measures. The results revealed that the highest burned area mapping accuracies were reported in the fynbos and grassland biomes by the MCD45A1 product, following the BMBAP product across the pine forest and savanna biomes, respectively. Further, the MCD45A1 product presented higher subpixel detection probabilities for the burned area fractions <= 50% than the BMBAP product, which appeared more reliable in detecting burned area fractions > 50% of a MODIS pixel. Finally the results demonstrated that the probability of identifying a burned area within a MODIS pixel is directly related to the proportion of the MODIS pixel burned and thus, highlights the relevance of fractional burned area during classification accuracy assessment of lower resolution remotely-sensed products using data with higher spatial resolution. / Dissertation (MSc)--University of Pretoria, 2011. / Geography, Geoinformatics and Meteorology / unrestricted

Materials chemistry basically deals with rational design and synthesis of new solids exhibiting various functional properties. A sound knowledge of crystal structures and chemical bonding is needed to understand the properties of materials. Space group, cell parameters and atomic positions provide a basic crystallographic description of the structure. Crystal structure could be described in a detailed way in terms of close packing of anions and occupancy of cations in different coordination sites. The coordination polyhedra and their interconnectivity bring out the interrelationships between different structures and the properties exhibited. Transition metals (TMs) are d-block elements which occupy groups 3-12 in Periodic Table. IUPAC defines a TM as ‘an element whose atoms have partially filled d-shell, or which can give rise to cations with an incomplete d-shell’. The partially filled d-shell in TMs plays an important role in various chemical and physical properties of TMs. Although TM cations can form compounds with different anions, most of the TM containing compounds are metal oxides due to the large free energies for formation of oxides. Binary TM oxides adopt different kinds of structures among which rock salt (e.g. NiO), rutile (e.g. TiO2), and corundum (e.g. Cr2O3) are most common. Ternary TM oxides are also known to form in variety of structures with the perovskite (e.g. BaTiO3), and the spinel (e.g. MgFe2O4) structures being well known. TM oxides exhibit a broad range of electronic and magnetic properties. TM oxides, at one end, display metallic behavior (e.g. ReO3, RuO2, LaNiO3) due to the delocalized electrons and at other end, show insulating behavior (e.g. NiO) due to the localized electrons. In between, TM oxides have semiconducting properties involving either the hopping of carriers (e.g. partially reduced TiO2, Nb2O5, WO3 and so on) or the electron excitation from the valence band to the conduction band (e.g. SnO2). TM oxides are known to have diverse magnetic properties: diamagnetic (e.g. TiO2, ZrO2), paramagnetic (e.g. VO2, NbO2), ferromagnetic (e.g. CrO2, La0.67Ca0.33MnO3), ferrimagnetic (e.g. Fe3O4, MnFe2O4) and antiferromagnetic (e.g. NiO, LaCrO3). TM oxides with partially filled 3d-shell are expected to be ‘metallic’ according to Bloch-Wilson theory, but in practice they are Mott insulators (localized 3d electrons) because of correlation energy (U) involved in the transfer of d-electrons between adjacent sites. Certain TM oxides also show insulator-metal (I-M) transitions induced by change of temperature, pressure or composition. For example, VO2 and Ba2IrO4 are known for their temperature and pressure induced I-M transitions, respectively. La1-xSrxCoO3 becomes metal at a particular Sr concentration being one of the examples for composition-dependent I-M transition. TM oxides are usually synthesized by conventional ceramic method in which stoichiometric mixture of starting materials is reacted at elevated temperatures. Multiple prolonged heating with intermittent grindings in ceramic method generally results in thermodynamically controlled products. The metastable phases which are of interest may not be obtained by ceramic method. Chimie douce/soft chemistry methods are generally adopted to stabilize the metastable phases. The guiding principle behind the chimie douce is to have kinetic control (rather than thermodynamic control) to realize metastable phases. Accordingly, metastable derivatives are obtained by choosing appropriate precursors, or adopting sol-gel and molten flux or ion exchange/intercalation methods. The present thesis is devoted to an investigation of transition metal oxides towards development of functional materials exhibiting visible light absorption/emission and lithium insertion/extraction for cathode materials in lithium ion battery. TM oxides find application as photovoltaic materials, luminescent emission materials, photocatalysts, light absorption/pigment materials and so on, based on their optical properties. Ferroelectric TM oxides with perovskite structure [Green coloured (KNbO3)1-x (BaNi1/2Nb1/2O3-δ)x] are studied currently as photovoltaic materials which show high open circuit voltage (Voc = 3.5 V) despite very low short circuit current (Vsc = 40 nA cm-2). TM oxides are also known to exhibit photoluminescent emission which could be due to the doping activator ions (e.g. MnII doped Zn2GeO4) or TM oxide (e.g. CaWO4) itself being self-activator. While the green and red emissions are common for TM oxides, blue emission is rare (e.g. Ar+ irradiated SrTiO3 is a blue emitter). Coloured TM oxides with band gap in visible region are employed as photocatalysts for solar water splitting (e.g. yellow BiVO4, yellow Ag3PO4, yellow TaON, red Fe2O3) and photo-oxidation of organic pollutants (e.g. TiO2-xNx and CaCu3Ti4O12). The coloured TM oxides also find application as pigments from early times, for example, Egyptian blue (CaCuSi4O10), Han blue (BaCuSi4O10), Han purple (BaCuSi2O6), Malachite green (Cu2CO3(OH)2), Ochre red (Fe2O3) and many others. A list of pigments based on TM oxides is given in Table 1. Pigment materials are applied as colouring materials in inks, dyes, paints, plastics, ceramics glazers, enamels and textiles. Table 1. List of TM oxide based pigments and their colours Pigment colour Compound White Titanium dioxide (TiO2) Black Iron oxide black (Fe3O4) Red Iron oxide red (Fe2O3), Ca1-xLaxTaO2-xN1+x (yellow-red) Orange Iron oxide orange (Fe2O3) Yellow Yellow ochre [FeO(OH)·H2O] Green Malachite green [Cu2CO3(OH)2], Viridian (Cr2O3. 2H2O), Y2BaCuO5 Blue Egyptian blue (CaCuSi4O10),Cobalt aluminate (CoAl2O4), YIn1-xMnxO3 Purple Han purple (BaCuSi2O6) Violet Cobalt phosphate [Co3(PO4)2] Colours of the TM oxides arise from visible light absorption due to the ligand field d-d electronic transitions. Though d-d transitions are parity forbidden, the selection rules get relaxed due to different reasons such as symmetry reduction (due to distortion) and vibronic couplings. The colour of the TM oxides is influenced mainly by two factors (i) oxidation state of TM ion present and (ii) ligand field around the TM ion produced by anion geometry. In order to develop new pigment oxides, our strategy was to choose colourless metal oxides having unusual (five coordinated geometry) or irregular/distorted (distorted octahedral/tetrahedral) coordination geometries around metal ion and produce coloured oxides by substituting 3d-TM ions at the metal ion site. We made a detailed study on the origin of the colour and pigment quality of the resulting coloured oxides. In the present thesis, which has two parts, the first part (Part 1) discusses the development of 3d-TM ion substituted coloured oxides with potential for pigment applications. Chapter 1.1 describes the purple inorganic pigment, YGa1-xMnxO3 (0 < x ≤ 0.10), based on the hexagonal YGaO3. The metastable series of oxides were prepared by a sol-gel technique where the dried gels, obtained from aqueous solutions of metal nitrates-citric acid mixtures, were calcined for a short duration in preheated furnace around 850°C/10 mins. The purple colour of the oxides arises from the specific trigonal bipyramidal ligand field around MnIII that obtains in the YGaO3 host. Other hexagonal RGaO3 hosts for R = Lu, Tm and Ho substituted with MnIII also produce similar purple coloured materials. In Chapter 1.2, we present a study on substitution of 3d-TM ions in LiMgBO3 host [where Mg(II) has a trigonal bipyramidal (TBP) oxygen coordination)]. We find that single-phase materials are formed for LiMg1-xCo(II)xBO3 (0 < x ≤ 1.0), LiMg1-xNi(II)xBO3 (0 < x ≤ 0.1), LiMg1-xCu(II)xBO3 (0 < x ≤ 0.1) and also Li1-xMg1-xFe(III)xBO3 (0 < x ≤ 0.1) of which the Co(II) and Ni(II) derivatives are strongly coloured, purple-blue and beige-red respectively, thus identifying TBP CoO5 and NiO5 as the new chromophores for these colours. Chapter 1.3 describes the synthesis, crystal structures and optical absorption spectra/colours of 3d-TM substituted α-LiZnBO3 derivatives: α-LiZn1-xMIIxBO3 [MII = CoII (0 < x < 0.50), NiII (0 < x ≤ 0.05) and CuII (0 < x 0.10)] and α-Li1+xZn1-2xMIIIxBO3 [MIII = MnIII (0 < x ≤ 0.10) and FeIII (0 < x 0.25)]. The crystal structure of the host α-LiZnBO3, which is both disordered and distorted with respect to Li and Zn occupancies and coordination geometries, is largely retained in the derivatives, giving rise to unique colours [blue for CoII, magenta for NiII and violet for CuII], that could be of significance for the development of new, inexpensive and environmentally-benevolent pigment materials, especially for the blue colour. Accordingly, the work indentifies distorted tetrahedral MO4 (M = Co, Ni, Cu) (together with a long M-O bond that gives a trigonal bipyramidal geometry) structural units as the new chromophores for the blue, magenta and violet colours respectively, in the α-LiZnBO3 host. In Chapter 1.4, we describe the synthesis, crystal structures and optical absorption spectra of 3d-TM substituted spiroffite derivatives, Zn2-xMxTe3O8 (MII = Co, Ni, Cu; 0 < x ≤ 1.0). The oxides are readily synthesized by solid state reaction of stoichiometric mixtures of the constituent binaries at 620°C/12h. Rietveld refinement of the crystal structures from powder XRD data shows that the Zn/MO6 octahedra are strongly distorted, as in the parent Zn2Te3O8 structure, consisting of five relatively short Zn/MII – O bonds (1.898 – 2.236 Å) and one longer Zn/MII– O bond (2.356 – 2.519 Å). We have interpreted the unique colors and the optical absorption/diffuse reflectance spectra of Zn2-xMxTe3O8 in the visible, in terms of the observed/irregular coordination geometry of the Zn/MII – O chromophores. We could not however prepare the fully-substituted M2Te3O8 (MII = Co, Ni, Cu) by the direct solid state reaction method. Density Functional Theory (DFT) modeling of the electronic structure of both the parent and the transition metal substituted derivatives provides new insights into the bonding and the role of transition metals toward the origin of color in these materials. We believe that transition metal substituted spiroffites Zn2-xMxTe3O8 reported here suggest new directions for the development of colored inorganic materials/pigments featuring irregular/distorted oxygen coordination polyhedra around transition metal ions. Red coloured materials are rare in nature. Li2MnO3 is a unique oxide with an unusual red colour imparted by MnIV ions. Chapter 1.5 describes a detailed experimental investigation of Li2MnO3 together with other related MnIV oxides that probes the red colour of Li2MnO3 as well as its photoluminescence. Optical absorption spectra reveal a strong band gap absorption with a sharp edge at ~ 610 nm and a transparent region between ~ 610 and ~ 650 nm that causes the red colour of Li2MnO3 samples. Octahedral MnIV ligand field transitions, corresponding to both MnIV at ideal sites and MnIV displaced to Li sites in the rock salt based layered structure of Li2MnO3, are observed in the excitation spectra of Li2MnO3 samples. Optical excitation at the ligand field transition energies produces tunable emission in the red-yellow-green region, rendering Li2MnO3 a unique MnIV oxide. The honeycomb ordered [LiMn6] units in the structure likely causes both the absorption and photoluminescence properties of Li2MnO3. Lithium containing TM oxides with rock salt related structure are being investigated extensively for application as next generation cathode materials for Lithium ion batteries (LIBs). Recent research is focused on lithium-rich layered oxides (LLOs) which are solid solutions between Li2MO3 (where M = Ti, Mn and Ru) and LiMO2 (where M = Cr, Mn, Fe, Co, Ni). LLOs have excess lithium in the TM layer in addition to lithium in lithium layer of rock salt derived structure. LLOs have gained attention because of their higher discharge capacity in the range of ~ 250 mAhg-1. While most of the LLOs investigated so far contain 3d-TM ions (Mn, Fe, Co, Ni), recently there has been an interest in the study of the role of ruthenium in addition to 3d-TM ions. We have investigated ruthenium containing LLOs with a view to probe (i) the role of ruthenium and (ii) the concentration of excess lithium in the TM layers in producing higher discharge capacities. The results are discussed in the Part 2 of the thesis.Li5NiMnRuO8(Li[Li0.25Ni0.25Mn0.25Ru0.25]O2) form in the Li2RuO3 crystal structure. Electrochemical studies indicate that the Co-containing oxides exhibit a higher initial discharge capacity (for e.g. ~ 180 mAhg-1 for Li4CoRuO6) as well as a higher reversible discharge capacity (~130 mAhg-1 for Li4CoRuO6) compared to the corresponding Ni-analogs. Participation of oxide ions (higher oxidation state of Ru) in the redox process could explain the higher discharge capacity during the first cycle. Reduced capacity (capacity fade) during the subsequent cycles could arise from the oxygen evolution due to the redox process (2O2- → 2O- → O2), which is not reversible. The present work shows that ruthenium incorporation in rock salt layered oxides along with Co/Ni appears to give a beneficial effect in producing a higher discharge capacity. In addition, the compounds crystallizing with the R-3m structure (related to LiCoO2) appear to give a better reversible capacity than the compounds crystallizing in the C2/c structures (Li2TiO3 and Li2RuO3).

The diploma thesis is focused on the practical use of project management methods and tools in a selected company. The aim of the diploma thesis is to create a project for the implementation of an information system. The introductory part of this work deals with the theoretical basis of the issue and covers all phases of the project. The next part is focused on the analysis of the current state of the company. The last part of the thesis is devoted to the project itself, where the output of the thesis is a compiled project for the implementation of an information system.

>Magister Scientiae - MSc / As human beings we are curious about our origin and ancestry. A curiosity has led to an investigation of human evolution and expansion across the world by means of population genetics and phylo-genetics by evaluating a region in Southern Africa that is largely unknown. The objective of this study was to develop a quick, inexpensive and accurate hierarchical diagnostic screening system of the MtDNA phylogenetic tree, AI-SNPs in the mtDNA genome by using High Resolution Melting analysis to evaluate the population composition and ancestral haplogroups of Southern African populations in Limpopo. The admixture between the ‘Khoesan’ hunter-gatherers, herders and the Bantu speaking populations led to population growth and expansion in Limpopo. This has contributed to populations settling in Limpopo and has thus shaped the ancestral contemporary populations. No research on these individuals residing in Limpopo has been done before, thus an investigation of their ancestral origin was necessary. A total of 760 saliva samples were collected from individuals residing in Limpopo. Only 500 saliva samples were extracted by means of an optimized salting out technique. Five hundred extracted genomic samples were genotyped by means of a quick, inexpensive High-resolution melting analysis. Of the 500 samples, the genotyping results showed 95 individuals derived for the L3 haplogroup which gives a 19% ratio of individuals screened with Multiplex 1. Only 56 individuals were derived for the L1 haplogroup, which gives a percentage of 11%. A total of 249 individuals were derived for the L0 haplogroup, making up a 50% of the total individuals genotyped. Only 100 samples were derived for L0a, making up 20% of individuals screened with Multiplex 1. Of the 95 samples derived for the L3 haplogroup, the results showed 87 individuals to be ancestral for both M and N, making up 91.57% of individuals screened with Multiplex 2. http://etd.uwc.ac.za/. In population genetics using SNPs to infer population history and ancestral origin has become significant, this study allowed researchers to evaluate population groups by investigating their genetic markers and the application of the results allowed for downstream analyses. Finally, this study provides a quick and simple screening method for the selection of lineages that are of interest for further studies.

TM-(transverse magnetic)guided waves, propagating in a lossless, nonmagnetic three-layer structure (substrate-film-cladding) are studied. Two types of the dielectric permittivities (I and II) are analyzed. All three media of the waveguide with the permittivity of type I are assumed to exhibit a local Kerr-like tensorial nonlinearity. Maxwell's equations in this case are reduced to an exact differential equation leading to a first integral, relating two electric field components so that one component can be eliminated. The other one can be found by integration. Combination of the first integral with the boundary conditions leads to an exact analytical dispersion relations (expressed in terms of integrals) establishing a link between the parameters of the problem (in particular, thickness of the film, the propagation constant of the travelling wave, the electric field components at the interface substrate-film). The film thickness and the propagation constant satisfying the dispersion relation (by given electric field component at the boundary substrate-film)are associated to the possible modes travelling through the waveguide. Numerical evaluation of the corresponding power flow derived using of Maxwell' equations and the first integral processes straightforwardly, without known wave solutions at first. The waveguide with the permittivity of type II consists of the film with the dielectric function depending on the field intensity (Kerr-type nonlinearity) as well as on the transverse coordinate (spatially varying permittivity) situated between the linear, isotropic substrate and cladding. The problem in this case is reduced to a system of two integral equations. Using the Banach fixed-point theorem it is shown that the solutions of Maxwell's equations exist in form of a uniformly convergent sequence of iterations. The conditions of the Banach fixed-point theorem are derived and used to estimate the quality of the approximation. The exact dispersion relation is derived. Results of numerical evaluation of the dispersion relation and field solutions are presented in the first approximation. Solutions of the dispersion relation, the field components and the power flow obtained using the method for the permittivity I are compared with these found using an integral equation approach (the permittivity II but without the coordinate dependence) - the consistency is remarkably good. The proposed methods seem to be applicable to permittivities more general as considered.

Kroniska sjukdomar ökar världen över, i både utvecklings- och industrialiserade länder. Mäniskor som lider av kroniska sjukdomar finner ofta den västerländska medicinen oförmögen att behandla deras sjukdommar, och vänder sig istället till traditionell, komplementär och alternativ medicin [TM/CAM]. TM/CAM har visat sig vara effektiv vid prevention och behandling av kroniska sjukdomar, varför det är av stort intresse att undersöka möjligheten för ökad integration av TM/CAM inom de nationella sjukvårdssystemen. Syftet med denna studie är att undersöka de krafter som främjar respektive förhindrar kommunikation och samarbete mellan utövare av ayurveda, västerländsk och traditionell medicin, samt att se hur detta påverkar integrationen av de medicinska subsystemen på Sri Lanka. Fokus för studien är ett specifikt samarbetsprojekt, “The outcome oriented, evidence informed community health promotion program”, vars mål är att integrera ayurveda och västerländsk medicin inom primärvården. En kvalitativ studie genomfördes under tre månader på Sri Lanka med hjälp av semi-strukturerade intervjuer, deltagande observation samt analys av dokument. Paul Unschulds teori om strukturerad konkurrens, samarbete eller integration användes vid tolkningen av resultaten. Resultaten tyder på att den huvudsakliga formen för samexistens mellan ayurveda och västerländsk medicin på Sri Lanka är strukturerad konkurrens, medan samarbetsprojektet siktar mot att uppnå strukturerat samarbete. Det parallella politiska system som styr samexistenseen mellan ayurveda och västerländsk medicin tycks förhindra integration, medan en ökad professionalisering genom nationella regleringar skapar ökat samarbete och integration. Brist på kunskap om ayurveda bland medicinstudenter förhindrar samarbete. Samtidigt kan inflytandet från västerländsk medicin i den auyurvediska universitetsutbildningen till synes både främja och förhindra samarbete och integration. Genom att höja kompetensen omkring forskningsmetodik och hälsovårdsystem hos ayurvediska läkare kan samarbete främjas. Likaså är forskning utformad med hänsyn till ayurvediska grundprinciper samt närvaro av nyckelpersoner med kompetens inom både ayurveda och västerländsk medicin främjande faktorer för samarbete och integration. / Non-communicable diseases [NCDs] are increasing in both developing and developed countries. Western medicine is not able to offer satisfying solutions and treatments for people suffering from NCDs. TM/CAM have shown promise of effectiveness in the prevention and treatment of NCDs and many people now turn to TM/CAM. Hence it is of great interest to investigate the possibilities of increased integration of TM/CAM in national health care systems. This study was carried out in Sri Lanka, with the aim to investigate the main forces promoting and obstructing cooperation and communication between practitioners of Ayurvedic, Western and traditional medicine, in order to see how this affects integration of the medical subsystems. The focus of this qualitative study was the “Outcome oriented, evidence informed Ayurvedic Community Health Promotion Program”; a collaboration project aiming to integrate Ayurveda and Western medicine in primary health care. Semi-structured interviews, participatory observation and document analysis were carried out during three months in Sri Lanka and the results were analysed using Paul Unschuld’s theory on structured competition, cooperation or integration. The results indicate that the overall coexistence of Ayurveda and Western medicine in Sri Lanka is structured competition, while the collaboration project is aiming for structured cooperation. The results further show that the Sri Lankan parallel political approach to integration can be argued to obstruct integration, while the regulation of Ayurvedic practitioners increases cooperation through professionalization. Education is a main influencing factor for cooperation; lack of CAM-knowledge in medical students obstructs cooperation while westernization of Ayurvedic doctors both promotes and obstructs cooperation and integration. Capacity building, research based on Ayurvedic fundamentals and keypersons with knowledge of both sectors are of importance for increased cooperation and integration to come about.

No description available.

The island of La Gonave, ~50 km northwest of Port-au-Prince, represents the subsistence Haitian lifestyle. Little is known about human--environment interactions on La Gonave. The first objective of this research was to investigate landscape dynamics through image classification, change detection, and landscape pattern analysis using Landsat 5 (TM) imagery from 1990--2010. Five land cover classes were considered: Agriculture, Forest/Dense Vegetation (DV), Shrub, Barren/Eroded, and Nonforested Wetlands. Overall image classification accuracy was 87%. The area percent change was -39.7, -22.7, 87.4, -7.0, 10.2%, for the respective classes. Landscape pattern analysis illustrated the encroachment of Shrub in core Forest/DV patches and the decline of Agricultural patch integrity. Agricultural abandonment, deforestation, and forest regrowth generated an increasingly fragmented landscape. The second objective of this research was to better understand the survival of the red-tailed hawk (RTH) on La Gonave by exploring the human--RTH relationship. We implemented a survey (n = 121) in 10 rural villages on La Gonave regarding their perceptions and interactions with the RTH during May--June, 2012. During fieldwork we sighted seven RTHs and found one nest. Many respondents noted the aggressive behavior of RTHs during nesting, suggesting reproductive behavior on the island. Our results indicate that RTHs inhabiting this island were not persecuted, despite intense predation of domestic chickens. Aside from predation near homes, villagers do not interact with the hawk as it remains out of sight. The RTH currently has no known predators, but it remains in danger of island extirpation due to ecological degradation. / Master of Science

Les isolateurs optiques sont des composants non-réciproques très important dans les systèmes de télécommunication optique. Actuellement les composants commercialisés sont tous discrets, à cause de la difficulté d’intégration des matériaux magnéto-optiques avec les technologies de l’optique intégrée. L’objectif de ma thèse était d’ouvrir une nouvelle voie technologique pour aboutir à une telle intégration. Pour cela nous avons développé une approche basée sur l’utilisation d’un matériau magnéto-optique composite complètement compatible avec la technologie d’échange d’ions sur verre. Ce matériau est élaboré par la voie sol-gel organique-inorganique et dopé par des nanoparticules magnétiques de ferrite de Cobalt (CoFe204). Il a montré des potentialités très prometteuses, illustré par une rotation Faraday spécifique de 420°/cm (@1550nm). Ce composite est déposé par la méthode dip-coating sur un guide fait par échange ionique d’Ar+/Na+, avec des extrémités enterrées par la méthode d’enterrage sélective pour faciliter le couplage-découplage de la lumière dans la structure hybride. Enfin, un traitement thermique (<100°C) et un traitement UV compatibles avec le procédé d’échange d’ions sur verre sont appliqués sur le dispositif pour finaliser la couche magnéto-optique. La caractérisation optique de notre dispositif a montré une bonne distribution de la lumière entre la couche magnéto-optique et le guide fait par échange d’ions (un bon confinement latéral). De plus, l’application d’un champ magnétique longitudinal au composant a permis de démontrer une valeur de conversion de mode TE-TM qui correspond bien à la quantité de la lumière confinée dans la couche magnéto-optique et la biréfringence modale de la structure. Donc, le but principal de la thèse est atteint, et ces résultats montrent la faisabilité d’un convertisseur de mode TE-TM compatible avec la technologie d’optique intégrée sur verre / Optical isolators are essential nonreciprocal devices used in optical communication systems. Currently, these components are commercially available but only in bulk form, due to the difficulties to embed magneto-optical materials with integrated classical technologies. To overcome this problem, our group has developed a new approach based on composite magneto-optical matrix that is fully compatible with ion-exchanged glass waveguide technology. This material is developed by organic inorganic sol-gel process and doped by magnetic nanoparticles (CoFe2O4). Such a magneto-optical composite matrix has shown promising potentialities illustrated by a specific Faraday rotation of 420°/cm (@1550nm). Using dip-coating technique, a composite layer was coated on a glass substrate containing straight channel waveguide made by a silver/sodium ion exchange. The extremities of the guides were previously buried using selective buried method in order to facilitate coupling-decoupling of light in hybrid structure. Last, a soft annealing (<100°C) and UV treatment, both compatible with the ion-exchanged process, have been implemented to finalize the magneto-optical film. Optical characterization demonstrated a good distribution of light between the magneto-optical thin film and the ion-exchanged waveguide (good lateral confinement). Furthermore TE to TM mode conversion has been observed when a longitudinal magnetic field is applied to the device. The amount of this conversion is in good agreement with the distribution of light between the layer and the guide obtained by numerical calculations, and the modal birefringence of the structure. So, the aim of my thesis is achieved and the results demonstrate the feasibility of TE to TM mode converter fully compatible with glass integrated optics

The high electricity prices are a talked about issue in today's society where many peoplefind themselves in a critical situation as a result of them. In a more long-termperspective, Sweden faces a goal of a comprehensive transformation of the energysystem. Lighting is a contributing factor to the energy system and energy use. Light inthe form of lighting is important for the visibility of objects and the surroundings, whichis a contributing factor to safety in society.The stock market price for electricity prices in December 2022 shows a sharp risethroughout Sweden and the forecast for today's electricity prices continues to rise(Konsumenternas, 2022). Energy consumption has a direct correlation to electricitycosts and dimmed LED light sources lead to lower energy consumption (Jägerbrand,2011). An important aspect in how the sense of safety, security and architecture isemphasized is the color rendering and light level of the lighting. A study carried out byMinchen et al (2020) proves that a light source with an increased color saturation and alower used illuminance can give rise to an equivalent visibility of a board as a lightsource with lower color saturation and higher illuminance.The aim is to identify and describe previous areas of knowledge about the colorsaturation and color reproduction of light sources. Tentative theory must be tested tosee if future outcomes can be predicted with the aim of lowering the light level andenergy consumption through increased color saturation and its impact on visibility andperceived safety.In order to achieve the aim and answer the study's questions, a literature search has beencarried out, in both primary and secondary sources, with keywords and search stringsin the scientific database Web of science together with the help of the snowball methodand snowball technique. In addition, available light source data from light sourcesuppliers has been analyzed to investigate the correlation between energy consumptionand color saturation. In order to further investigate the subject and answer the questions,an experiment was carried out with two different lighting scenarios of a modeled tunnel.During the experiment, participants contributed quantitative and qualitative data byanswering questionnaires for these scenarios.The study shows that light color saturation has an impact on the energy efficiency oflight sources and that different interpretations of how light color saturation and lightlevel affect the perceived visibility. The study indicates that a lower light level can beapplied without negatively affecting safety if other factors for the environment are takeninto account, where one of the contributing factors may be light color saturation. / De höga elpriserna är en omtalad fråga i dagens samhälle där många befinner sig i enkritisk situation till följd av dem. I ett mer långsiktigt perspektiv står Sverige inför ettmål till en omfattande omställning av energisystemet. Belysning är en bidragande faktortill energisystemet och energianvändningen. Ljus i form av belysning är viktig försynbarheten till objekt och omgivningen som är en bidragande faktor till tryggheten isamhället.Börspriset för elpriser i december 2022 visar en kraftig stigning i hela Sverige ochprognosen för dagens elpriser fortsätter att stiga (Konsumenternas, 2022).Energiförbrukningen har en direkt korrelation till elkostnaderna och dimrade LEDljuskällorleder till lägre energiförbrukning (Jägerbrand, 2011). En viktig aspekt i hurkänslan av trygghet, säkerhet och arkitektur framhävs är belysningens färgåtergivningoch ljusnivå. En studie utförd av Minchen et al (2020) påvisar till att en ljuskälla meden ökad färgmättnad och en lägre använd belysningsstyrka kan ge upphov till enlikvärdig synbarhet av en tavla som en ljuskälla med lägre färgmättnad och högrebelysningsstyrka.Syftet är att identifiera och beskriva tidigare kunskapsområden om ljuskällorsfärgmättnad och färgåtergivning. Tentativ teori ska prövas till om framtida utfall kanförutsägas i syfte att sänka ljusnivån och energiförbrukningen genom en ökadfärgmättnad och dess påverkan på synbarheten och den upplevda tryggheten.För att uppnå syftet och besvara studiens frågeställningar har en litteratursökninggenomförts, i både primära och sekundära källor, med nyckelord och söksträngarvetenskapliga databasen Web of science tillsammans med hjälp av snöbollsmetodenoch snöbollsteknik. Därtill har tillgänglig ljuskälledata från ljuskälleleverantöreranalyserats för att undersöka korrelation mellan energiförbrukning och färgmättnad.För att vidare undersöka ämnet och besvara frågeställningarna genomfördes ettexperiment med två olika belysnings-scenarion av en modellerad tunnel. Underexperimentet bidrog deltagarna med kvantitativa och kvalitativa data genom att besvaraenkäter till dessa scenarion.Studien visar att ljusfärgmättnaden har en påverkan på ljuskällors energieffektivitet ochatt olika tolkningar hur ljusfärgmättnad och ljusnivå påverkar den upplevdasynbarheten. Studien indikerar att en lägre ljusnivå kan appliceras utan att påverkatryggheten negativt om andra faktorer för omgivningen tas i beaktning, där en av dombidragande faktorerna kan vara ljusfärgmättnad.