Eine Möglichkeit der kostensenkenden Technologieentwicklung bei der Herstellung von Geschirrporzellan stellt das gleichzeitige Brennen von Scherben und Glasur im Einmal-Schnellbrand dar. Der Einsatz eines Gemisches aus organischen und anorganischen Additiven bringt dabei optimale Verarbeitungseigenschaften der Porzellangranulate hervor. Feinere Porzellangranulate sind in Verbindung mit einem Mindestanteil an geeigneten organischen Bindern industriell verpressbar. Daraus hergestellte Flachgeschirrartikel weisen ausreichende Gefügefestigkeiten und –dichten im ungebrannten Zustand und während des Brandes auf. Der Glasurauftrag erfolgte durch Spritzen. Eine spezielle Brennkurve ermöglicht eine ausreichend lange Entgasungsperiode vor dem Dichtsintern des Scherbens und dem Ausfließen der Glasur. Das Einsetzen einer Feuerpolitur nach Beenden der Haltezeit bei maximaler Brenntemperatur führt zu einer Verbesserung der Glasuroberflächenqualität.

Au sein d'un réseau oxygène de type K2NiF4, de formule générale (A, A')2M'0.50M0.50O4, la distorsion locale de l'octaèdre (MO6) dépend des liaisons concurrentielles (A, A')-O le long de l'axe c et M'-O dans le plan xOy. Une étude systémaique a été entreprise selon la nature des ions A, A' et M', la distorsion locale de (MO6) étant en particulier caractérisée RPE, spectroscopie IR et résonance Mössbauer. L'influence de l'environnement chimique de (MO6) a été corrélé à la transition spin faible -> spin fort dans le cas du cobalt(III) et à la stabilisation du nickel(III) à spin faible.

Submitted by Cristhiane Guerra (cristhiane.guerra@gmail.com) on 2017-01-03T17:02:58Z No. of bitstreams: 1 arquivototal.pdf: 1308787 bytes, checksum: faa482dbc4cc073365db2f7d57523db1 (MD5) / Made available in DSpace on 2017-01-03T17:02:58Z (GMT). No. of bitstreams: 1 arquivototal.pdf: 1308787 bytes, checksum: faa482dbc4cc073365db2f7d57523db1 (MD5) Previous issue date: 2016-07-26 / The art of storytelling is a popular art, common in various human societies, in different historical moments. Its main features are the transmission of knowledge, skills, values and funs. This study investigates the role of this art in the construction of pleasant emotional environments, in different spaces. To complete this goal we present a record of the history of the storytelling art, its possible disappearance in modern society, due to the industrialization, to the shitf from rural to urban environment and the hegemony of written culture to the detriment of oral culture . It also presents the phenomenon of the resurgence of this art in the late XXth century, its new characteristics, its different territories, the subjects involved, and the new roles that art had completed in this postmodern society, technologic and computerized. Being a practice that values popular knowledge, the transformation of living environments, teaching and learning, also combating the oppression of the popular classes, the art of storytelling is inserted in the context of popular education, in tune with the new emancipatory paradigms, within the territories of Popular Education, especially in the territories of affectivity, of emocions and other rationales. To measure the effects of storytelling in the process of transformation and construction of pleasant emotional environments, a research was realized, in which the students of the Projeto de Extensão PalhaSUS Project from the UFPB, had been the main subject. Those students act as caregivers clowns in different social and emotionaly vulnerable spaces, such as hospitals, care homes, schools and nursing homes. Concomitant workshops, participants include in their caregivers acting the knowledge and skills acquired in the workshops. The evaluation process used was to make focal group, which fed with datas and allowed to analyse the results of this practice, with its possible developments and challenges. / A arte de contar histórias é uma arte popular, comum nas mais diversas sociedades humanas, em diferentes momentos históricos. Suas características principais são a transmissão de conhecimentos, saberes, valores e diversão. Este estudo tem como o objetivo investigar a função dessa arte na construção de ambientes emocionais agradáveis, em diferentes espaços de convivência. Para atingir esse objetivo, apresentamos um pequeno histórico sobre a trajetória da arte de contar história, o seu possível desaparecimento na sociedade moderna, em função da industrialização, do deslocamento do ambiente rural para o ambiente urbano e da hegemonia da cultura escrita em detrimento da cultura oral. Apresenta, ainda, o fenômeno do ressurgimento dessa arte, no final do século XX, suas novas características, os diferentes territórios de atuação, os perfis dos sujeitos envolvidos e os novos papéis que essa arte vem realizando nesta sociedade pós-moderna, tecnológica e informatizada. Por ser uma prática que valoriza o saber popular, a transformação de ambientes de convivência, de ensino e aprendizagem e de luta pela desopressão das camadas populares, a arte de contar histórias está inserida no contexto da Educação Popular, em perfeita sintonia com os novos paradigmas emancipatórios, dentro dos territórios da Educação Popular, principalmente nos territórios da afetividade, das emocões e das outras racionalidades. Para estudar os efeitos da arte de contar histórias no processo de transformação e na construção de ambientes emocionais agradáveis, foi realizada uma pesquisa participante, tendo como objeto os estudantes do Projeto de Extensão PalhaSUS, da UFPB, que atuam como palhaços cuidadores, em diferentes espaços de vulnerabilidade social e afetiva, tais como hospitais, casas de saúde, escolas e asilos de idosos. Concomitante às oficinas, os participantes incluíam, nas suas práticas de atuação de cuidadores, os saberes e conhecimentos desenvolvidos nas oficinas. O processo de avaliação utilizado foi o da realização de grupo focal, que municiaram dados para análise do resultado da realização da prática, apresentando seus possíveis desdobramentos e desafios.

Made available in DSpace on 2014-12-17T15:14:56Z (GMT). No. of bitstreams: 1 IdalmirSQJ_TESE.pdf: 4221987 bytes, checksum: fc99ad33bc9d1fda857f0e4c38bd43fb (MD5) Previous issue date: 2003-08-08 / Conselho Nacional de Desenvolvimento Cient?fico e Tecnol?gico / Neste trabalho, estudamos um modelo para sistemas desordenados do tipo vidros de spins consistindo de uma generaliza??o do modelo com intera??es entre p-spins, introduzindo inicialmente por Derrida, al?m disso possui tr?s termos de acoplamentos tipo modelo de Ashkin-Teller. Quando p=2 nosso modelo reproduz o Hamiltoniano de vidro de spins de Ashkin-Teller. Um dos efeitos levados em conta nesse estudo ? a exist?ncia de certos tipos de correla??es entre os acoplamentos. Esse fato o diferencia do modelo b?sico de Derrida. No presente trabalho utilizamos duas abordagens para determinar o diagrama de fases do modelo considerado. Em primeiro lugar usamos o m?todo das r?plicas, considerando inicialmente o caso onde n?o existem corela??es entre tipos distintos de acoplamentos. Nesta abordagem determinamos o diagrama de fases adotando a solu??o com simetria entre r?plicas e discutimos a estabilidade desta solu??o ? luz da an?lise pioneira de Almeida-Thouless. Verificamos que h? necessidade de usar uma procedimento de quebra de simetria entre r?plicas, o que nos leva ao diagrama de fases completo do modelo. Tamb?m consideramos duas variantes do modelo, onde s?o introduzidas correla??es entre os acoplamentos. Mostramos que o tratamento de r?plicas para esses casos reproduz os resultados obtidos para o modelo sem correla??es. Posteriormente usamos o procedimento de Derrida para estudar o modelo considerado no limite p->oo. Neste limite mostramos que o modelo original e as duas variantes consideradas anteriormente levam a um s? modelo de energias aleat?rias. Utilizando o ensemble microcan?nico recuperamos os resultados obtidos pelo m?todo das r?plicas

Eine Möglichkeit der kostensenkenden Technologieentwicklung bei der Herstellung von Geschirrporzellan stellt das gleichzeitige Brennen von Scherben und Glasur im Einmal-Schnellbrand dar. Der Einsatz eines Gemisches aus organischen und anorganischen Additiven bringt dabei optimale Verarbeitungseigenschaften der Porzellangranulate hervor. Feinere Porzellangranulate sind in Verbindung mit einem Mindestanteil an geeigneten organischen Bindern industriell verpressbar. Daraus hergestellte Flachgeschirrartikel weisen ausreichende Gefügefestigkeiten und –dichten im ungebrannten Zustand und während des Brandes auf. Der Glasurauftrag erfolgte durch Spritzen. Eine spezielle Brennkurve ermöglicht eine ausreichend lange Entgasungsperiode vor dem Dichtsintern des Scherbens und dem Ausfließen der Glasur. Das Einsetzen einer Feuerpolitur nach Beenden der Haltezeit bei maximaler Brenntemperatur führt zu einer Verbesserung der Glasuroberflächenqualität.

Freie Leitungselektronen sind bisher in oxidischen Perowskiten mit Elektronenspinresonanz (ESR) selten beobachtet worden. Meist sind solche Elektronen, insbesondere bei tiefen Temperaturen, an Gitterstörungen gebunden. In akzeptorarmem BaTiO3 ist es gelungen, mit ESR Elektronen zu identifizieren, die auch bei tiefen Temperaturen nicht an Defekte gekoppelt sind. Sie entstehen beim Einbau von Nb5+Ti in das Gitter und lokalisieren sich auf Titan-Platz als Ti3+ Jahn-Teller-Polaronen selbst. Die beiden Gebiete Jahn-Teller-Effekt und Polaronen, die sich bisher weitgehend getrennt voneinander entwickelt haben, werden hier in einer experimentellen Untersuchung vereinigt. Beim Jahn-Teller-Effekt wird eine elektronische Bahn-Entartung durch eine spontane Erniedrigung der Punktsymmetrie aufgehoben. Die Polaronenbildung erfolgt unter Bruch der Translationssymmetrie. Dabei wird die Energie des Systems erniedrigt, indem ein Zustand unter die quasi-entarteten Bandzustande abgesenkt wird. Beim System Ti3+ treten beide Effekte gleichzeitig auf: Die nach Lokalisierung eines freien Elektrons an Titan aus dem Leitungsband auftretende Bahn-Entartung des resultierenden T2-Grundzustandes wird durch einen Jahn-Teller-Effekt aufgehoben. Es bildet sich ein sogenanntes Jahn-Teller-Polaron. Als Vorbereitung der experimentellen Untersuchungen an Jahn-Teller- Polaronen dienen ESR-Messungen an verschiedenen reinen Jahn-Teller-Systemen in BaTiO3 (Mo5+, Ni+, Rh2+). Im Gegensatz zu einem Polaron ist das durch eine Störstelle im Kristall hervorgerufene Potential schon vorhanden, bevor dort ein Ladungsträger eingefangen wird. Beim Polaron bewirkt die Anwesenheit des Ladungsträgers selbst die Bildung einer Potentialmulde. Man spricht daher von Selbsteingrabung. Die untersuchten Jahn-Teller-Zentren reagieren auf äußeren uniaxialen Druck mit einer Reorientierung: Die spontan erfolgten Jahn-Teller-Verzerrungen werden entlang der Druckachse ausgerichtet. Auch beim Jahn-Teller-Polaron ist diese Reorientierung zu beobachten. Die Jahn-Teller-Kopplung ist jedoch schwächer als die des isoelektronischen Zentrums Mo5+ (4d1 ). Aufgrund der Äquivalenz aller Titan-Plätze im Kristall ist das ungepaarte Elektron an Ti3+ stärker auf seine Nachbarn delokalisiert als im Fall des Mo5+. Es wird gezeigt, daß eine delokalisierte Wellenfunktion schwächer an das Gitter ankoppelt als eine lokalisierte und daher eine schwächere Jahn-Teller-Kopplung aufweist. Es treten kleine und intermediäre Jahn-Teller-Polaronen gleichzeitig auf. BaTiO3 besitzt die Tendenz, breite Polaronenbänder zu bilden. Polaronen in diesem Material zeigen daher die Tendenz zur Delokalisierung, d. h. sie sind über mehr als einen Gitterplatz ausgedehnt und werden als intermediär bezeichnet. Eine Lokalisierung auf einen Gitterplatz, also ein kleines Polaron, bildet sich nur bei Anwesenheit von lokalen Potentialfluktuationen aus (Anderson-Lokalisierung). Unter uniaxialem Druck erfolgt eine Verringerung dieser Fluktuationen durch die Reorientierung, und ein Übergang vom kleinen zum intermediären Polaron wird beobachtet.

Με σκοπό τη μελέτη της χημείας ένταξης του υποκαταστάτη δι-2,6-(2-πυριδυλοκαρβονυλο) πυριδίνη (dpcp) με μέταλλα μετάπτωσης 3d, παρασκευάστηκαν οι τετραπυρηνικές πλειάδες [Cu4(N3)2{pyCO(OMe)pyCO(OMe)py}2(MeOH)2](ClO4)∙2MeOH (1∙2MeOH) και [Co4(N3)2(NO3)2{pyCO(OMe)pyCO(OMe)py}2]∙0.5MeOH (2∙0.5MeOH), η εξαπυρηνική πλειάδα [Ni6(CO3)(N3)6{pyCOpyC(O)(OMe)py}3(MeOH)2(H2O)][Ni6(CO3)(N3)6 {pyCOpyC(O)(OMe)py}3(MeOH)3](ClO4)2 (3∙1.8MeOH) και η διπυρηνική πλειάδα [Fe2{pyCO(OMe)py(Η)CO(OMe)py}2(MeO)2](ClO4)2∙(4∙MeOH). Στην συνέχεια μελετήθηκε η χημεία ένταξης του ίδιου υποκαταστάτη με μέταλλα 3d και 4f και παρασκευάστηκαν τα ετερομεταλλικά διπυρηνικά σύμπλοκα [ΜIILnIII{pyCOH(OEt)pyCOH(OEt)py}3](ClO4)2∙EtOH (5-16∙EtOH) με ΜΙΙ = CuΙΙ, CoΙΙ, NiΙΙ, ZnΙΙ, MnΙΙ, FeΙΙ [LnΙΙΙ = GdΙΙΙ (5 - 10), TbΙΙΙ (11 – 16) αντίστοιχα]. Όλα τα σύμπλοκα χαρακτηρίστηκαν κρυσταλλογραφικά, τα σύμπλοκα 4, 10 και 16 χαρακτηρίστηκαν με φασματοσκοπία Mössbauer ενώ τα σύμπλοκα 1 – 10 χαρακτηρίστηκαν μαγνητικά. Πιο συγκεκριμένα, οι μαγνητικές μελέτες των συμπλόκων 1 – 3, 5 και 10 έδειξαν σιδηρομαγνητικές αλληλεπιδράσεις ενώ εκείνες των συμπλόκων 4, 6, 7 και 9 έδειξαν αντισιδηρομαγνητικές αλληλεπιδράσεις. Προκειμένου να μελετηθεί σε βάθος η οικογένεια των βασικών καρβοξυλικών αλάτων του σιδήρου [Fe3O(O2CR)6(H2O)3]A, παρασκευάστηκαν δύο σειρές αυτών των συμπλόκων με R = CCl3, CHBr2, CH2F, CH2Cl, C(OH)Ph2, H, Ph, (CH2)3Cl, Me, CHMe2, Et και CMe3. Στην πρώτη σειρά συμπλόκων (17 - 28) το αντισταθμιστικό ιόν (Α) είναι ClO4-, ενώ στη δεύτερη (29 - 40) είναι NO3-. Η προσπάθεια απομόνωσης του ανάλογου με R = CF3 ήταν άκαρπη και για τα δύο αντισταθμιστικά ιόντα και οδήγησε σε ένα τετραπυρηνικό σύμπλοκο [Fe4O2(O2CCF3)8(H2O)6] (41) με δομή τύπου «πεταλούδας». Πραγματοποιήθηκαν μετρήσεις Mössbauer σε στερεά δείγματα και για τις δύο σειρές και οι ισομερείς μετατοπίσεις και οι τετραπολικές αλληλεπιδράσεις διαφέρουν μεταξύ 0.51 – 0.54 mms-1 και 0.36 – 0.76 mms-1 αντίστοιχα. Μετρήσεις Mössbauer και σε διαλύματα αυτών έδειξαν τη σταθερότητά τους και σε διάλυμα, με εξαίρεση το σύμπλοκο 29 (R = Cl3C, Α = NO3-) που οδήγησε σε σύμπλοκο τύπου «πεταλούδας». Το υψηλής συμμετρίας σύμπλοκο [Fe3O(O2CPh)6(py)3](ClO4)∙py (42) έχει μελετηθεί στο παρελθόν κρυσταλλογραφικά αλλά και με μετρήσεις ανελαστικής σκέδασης νετρονίων IINS και είχε προταθεί ύπαρξη του μαγνητικού φαινομένου Jahn-Teller σε πολύ χαμηλές θερμοκρασίες. Θέλοντας να εξακριβωθεί εάν η μαγνητική συμμετρία σχετίζεται με την πραγματική, πραγματοποιήθηκαν κρυσταλλογραφικές μετρήσεις μεταβλητής θερμοκρασίας στο εργαστήριο ΒΜ01Α του ESRF. Τα αποτελέσματα των πειραματικών μετρήσεων έδειξαν ότι η πραγματική συμμετρία παραμένει ίδια. Στη συνέχεια από μετρήσεις μαγνητικής επιδεκτικότητας ac, παρατηρήθηκε η ύπαρξη μαγνητικών φαινομένων χαλάρωσης υπό την επίδραση ασθενών μαγνητικών πεδίων. / Seeking to study the coordination chemistry of the ligand di-2, 6-(2-pyridylcarbonyl) pyridine (dpcp) with 3d transition metal ions, the tetranuclear complexes [Cu4(N3)2{pyCO(OMe)pyCO(OMe)py}2(MeOH)2](ClO4)∙2MeOH (1∙2MeOH) and [Co4(N3)2(NO3)2{pyCO(OMe)pyCO(OMe)py}2]∙0.5MeOH (2∙0.5MeOH), the hexanuclear complex [Ni6(CO3)(N3)6{pyCOpyC(O)(OMe)py}3(MeOH)2(H2O)][Ni6(CO3)(N3)6{pyCOpyC(O) (OMe)py}3(MeOH)3](ClO4)2 (3∙1.8MeOH) and the dinuclear complex [Fe2{pyCO(OMe)py(Η)CO(OMe)py}2(MeO)2](ClO4)2∙(4∙MeOH) were synthesized. In addition, in order to study the coordination chemistry of the same ligand with mixed 3d transition metal ions and 4f lanthanide ions, the heterometallic dinuclear complexes [ΜIILnIII{pyCOH(OEt)pyCOH(OEt)py}3] (ClO4)2∙EtOH (5-16∙EtOH) were synthesized, with ΜΙΙ = CuΙΙ, CoΙΙ, NiΙΙ, ZnΙΙ, MnΙΙ, FeΙΙ [LnΙΙΙ = GdΙΙΙ (5 - 10), TbΙΙΙ (11 – 16) respectively]. All complexes were structurally characterized and complexes 4, 10 and 16 were characterized by Mössbauer spectroscopy. Magnetic properties measurements of complexes 1-3, 5 and 10 indicated the existence of ferromagnetic interactions, while those of 4, 6, 7 and 9 indicated the existence of antiferromagnetic interactions. For the in depth study of the family of basic iron (III) carboxylates [Fe3O(O2CR)6(H2O)3]A, two series of complexes were prepared with R = Cl3C, CHBr2, CH2F, CH2Cl, C(OH)Ph2, H, Ph, Cl(CH2)3, Me, CHMe2, Et and Me3C. For the former series (17 - 28) the counteranion (A-) is ClO4- and for the latter (29 - 40) is NO3-. Attempts to prepare the respective trifluoroacetate (R = CF3) complexes were unsuccessful and the reaction system lead to the tetranuclear “butterfly” complex [Fe4O2(O2CCF3)8(H2O)6] (41), irrespective of whether perchlorates or nitrates were used as counteranions. Mössbauer studies revealed very similar isomer shifts for all complexes in the region of 0.51 – 0.54 mms-1, and variable quadrupole splittings, ranging from 0.36 to 0.76 mms-1. Mössbauer studies of the complexes were carried out in frozen MeCN solutions in order to assess their stability in solution and they proved to be stable in MeCN solutions, except complex 29 (R = Cl3C, Α = NO3-), which dissociated to a butterfly-type complex. The high-symmetry cluster [Fe3O(O2CPh)6(py)3](ClO4)∙py (42) has been structurally characterized and its Inelastic Incoherent Neutron Scattering studies have been reported. These studies suggested the existence of a magnetic Jahn-Teller effect at lower temperatures. Seeking to study if there is any correlation between magnetic and structural symmetry, we undertook variable-temperature crystallographic studies on ESRF BM01A beamline. With the results of these data we concluded that the symmetry of the crystal remained. Moreover, we have discovered that this complex exhibits magnetic relaxation phenomena under weak magnetic fields, observed by ac magnetic susceptometry.

The East Vaal area of the South African Post Office is faced with a high rate of teller absenteeism, which has been observed to be as high as 15 per cent. This adds to the cost of providing quality service to the company’s customers. The objectives of this study are to determine the factors that lead to the high rate of absenteeism in the East Vaal area and to make recommendations to the area management that could improve the attendance behaviour of the tellers in the area. To achieve these objectives, 51 questionnaires were prepared and handed out to the tellers with absenteeism rates of more than three percent in the East Vaal area to be completed. Face-to-face interviews with both the tellers and their branch managers were conducted. Absenteeism records and Employee Assistance Programme reports were also studied to collect more data. The findings highlighted lack of rewards for employees who reported for work regularly; employee illness; no recognition for good work performance; tellers receiving insufficient remuneration for their work; poor working conditions; and poor management style as the main reasons for the tellers taking unscheduled leave of absence. Based on the key findings, the main recommendations were that appropriate mechanisms for acknowledging and rewarding good work performance and attendance behaviour should be in place; a sick-leave pool system accessible to tellers should be introduced; establishment of performance evaluation and rewards for tellers; and introducing management practices which lead to a more open expression of opinion and participatory problem-solving / Business Management / Thesis (M.Tech. (Business Management))

Nous explorons les propriétés structurales de nanoparticules cœur-coquille, avec un cœur de ferrite MFe2O4 (M = Mn et Co) ou de ferrite mixte Mn-Zn. Ces nanoparticules sont obtenues par co-précipitation hydrothermique et sont dispersées en milieu acide par un traitement de surface empirique au nitrate ferrique, protégeant les nanograins contre une dissociation chimique par une fine couche superficielle de maghémite. La fraction volumique du cœur, de la coquille et l’épaisseur de la couche superficielle sont déterminées par dosage chimique. Nous suivons les changements structurels des nanocristaux de MnFe2O4 et CoFe2O4, pendant la durée du traitement de surface, tandis que ceux des nanoparticules de ferrite mixte Mn-Zn sont étudiés en fonction de leur teneur en zinc. Diffraction de rayons-x et de neutrons sont utilisées pour déterminer les paramètres de structure, en particulier la diffusion de cations dans les interstices de la ferrite spinelle. Pour un haut degré de fiabilité, des raffinements de Rietveld sont réalisés. Les distances inter-atomiques, l’état d’oxydation moyen et le degré d’inversion sont déterminés par spectroscopie d’absorption des rayons-x. Morphologie, cristallinité et taille des nanoparticules de ferrite mixte Mn-Zn sont étudiées par TEM/HRTEM et par diffraction des électrons. Dans les nanoparticules MnFe2O4 et de ferrite mixte Mn-Zn, on constate la présence de cations Mn3+ en environnement octaédrique, responsables de déformations anisotropes (effet Jahn-Teller). Le degré d’inversion obtenu ici diffère de celui du bulk en raison de la réduction à l’échelle nanométrique et de l'augmentation du rapport surface/volume pendant le processus de synthèse. / Structural properties of core-shell ferrite nanoparticles MFe2O4 (M = Mn and Co) and Mn-Zn ferrite nanoparticles are here investigated. The nanoparticles are synthesized by hydrothermal co-precipitation and are dispersed in acid medium thanks to an empirical surface treatment by ferric nitrate, which prevents the chemical dissociation by a thin maghemite layer incorporated at the surface of the nano-grains. Chemical titrations allow us to calculate volume fractions of core and shell, as well as the surface-layer thickness. Structural changes induced by the surface treatment are followed as a function of treatment duration in MnFe2O4 and CoFe2O4 nanocrystals. Whereas structural changes in Mn-Zn ferrite nanoparticles are investigated as a function of zinc content. X-ray and Neutron diffractions are used to determine the structural parameters, in particular cationic distribution in the spinel ferrite sites. Precise structural information with high degree of reliability is obtained by Rietveld refinements. To investigate the local structure of these materials, X-ray Absorption Spectroscopy measurements are performed, allowing determining interatomic distances, mean oxidation state and inversion degree. Morphology, crystallinity and size of mixed-ferrite nanoparticles are investigated by TEM/HRTEM and electron diffraction. In Mn-Zn ferrite nanoparticles, the presence of Mn3+ in octahedral environment is responsible for anisotropic distortions, known as Jahn-Teller effect. The inversion degree obtained in this work diverges from the bulk values due to the reduction to nanoscale and to the increase of the surface/volume ratio, associated to the synthesis process.

My thesis aims at contributing to classifying the Liar-like paradoxes (and related Truth-teller-like expressions) by clarifying distinctions and relationships between these expressions and arguments. Such a classification is worthwhile, firstly, because it makes some progress towards reducing a potential infinity of versions into a finite classification; secondly, because it identifies a number of new paradoxes, and thirdly and most significantly, because it corrects the historically misplaced distinction between semantic and set-theoretic paradoxes. I emphasize the third result because the distinction made by Peano [1906] and supported by Ramsey [1925] has been used to warrant different responses to the semantic and set-theoretic paradoxes. I find two types among the paradoxes of truth, satisfaction and membership, but the division is shifted from where it has historically been drawn. This new distinction is, I believe, more fundamental than the Peano-Ramsey distinction between semantic and set-theoretic paradoxes. The distinction I investigate is ultimately exemplified in a difference between the logical principles necessary to prove the Liar and those necessary to prove Grelling’s and Russell’s paradoxes. The difference relates to proofs of the inconsistency of naive truth and satisfaction; in the end, we will have two associated ways of proving each result. ¶ Another principled division is intuitively anticipated. I coin the term 'hypodox' (adj.: 'hypodoxical') for a generalization of Truth-tellers across paradoxes of truth, satisfaction, membership, reference, and where else it may find applicability. I make and investigate a conjecture about paradox and hypodox duality: that each paradox (at least those in the scope of the classification) has a dual hypodox.¶ In my investigation, I focus on paradoxes that might intuitively be thought to be relatives of the Liar paradox, including Grelling’s (which I present as a paradox of satisfaction) and, by analogy with Grelling’s paradox, Russell’s paradox. I extend these into truth-functional and some non-truth-functional variations, beginning with the Epimenides, Curry’s paradox, and similar variations. There are circular and infinite variations, which I relate via lists. In short, I focus on paradoxes of truth, satisfaction and some paradoxes of membership. ¶ Among the new paradoxes, three are notable in advance. The first is a non-truth functional variation on the Epimenides. This helps put the Epimenides on a par with Curry’s as a paradox in its own right and not just a lesser version of the Liar. I find the second paradox by working through truth-functional variants of the paradoxes. This new paradox, call it ‘the ESP’, can be either true or false, but can still be used to prove some other arbitrary statement. The third new paradox is another paradox of satisfaction, distinctly different from Grelling’s paradox. On this basis, I make and investigate the new distinction between two different types of paradox of satisfaction, and map one type back by direct analogy to the Liar, and the other by direct analogy to Russell's paradox.