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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
501

Expansion of Sickla treatment plant : A study about the replacement of standard concrete to green concrete / Utbyggnad av Sickla reningsverk : En studie om ersättning av standardbetong mot grön betong

Rasool, Sava Tnar, Sharif, Omar January 2020 (has links)
Stockholm Vatten has decided to close down the Bromma waste water treatment plantand manage the waste water from Bromma together with the waste water from the formerEolshällsverket to Henriksdal’s waste water treatment plant. Henriksdals wastewater treatment plant will be expanded for higher purification requirements and loads,estimated to be finished until 2040. This entails extensive renovations and additionsto the existing treatment plant in and on Henriksdalsberget, as well as a major expansionof the Sickla plant.The purpose of the study is to investigate an environmentally friendly alternative tothe standard concrete that will be used for the expansion of the Sickla plant. The largestenvironmental villain in concrete is the cement. The aim of this study has beento replace the cement with environmentally friendly additives in the largest possibleamount, thus reducing the negative impact of the cement on the environment.In the present study, a review was made of obtained data with exposure classes, then aliterature study was performed to gain knowledge in the area. With help from experts,two fictitious recipes for each exposure class have been calculated for the standardconcrete and the green concrete. In this way, a careful comparison between the concretetypes was made of the cement’s impact on global warming. Thereafter, a study wascarried out on existing EPDs, which were incorporated into the One Click LCA (2015)software. An LCA in the mentioned software was carried out, which enabled data to becompiled and a comparison of the climate impact between the four different fictitiousrecipes has been done.Compiled and compared data from LCA and analysis of EPDs show that 70% of thestructure with exposure class XD2 gets a 47% reduction in global warming when usinggreen concrete instead of standard concrete. Furthermore, the results show that theremaining 30% of the structure with exposure class XF3/XC4 gets a 20% reductionwhen using green concrete instead of standard concrete. The total reduction in globalwarming when using green concrete instead of standard concrete for the expansion ofSickla treatment plant was calculated to be 40%. / Stockholm Vatten har beslutat att lägga ned Bromma reningsverk och leda avloppsvattnetfrån Bromma tillsammans med avloppsvattnet från det forna Eolshällsverkettill Henriksdals reningsverk. Henriksdals reningsverk ska byggas ut för högre reningskravoch belastningar beräknade till år 2040. Detta medför omfattande om- och tillbyggnationeri det befintliga reningsverket i och på Henriksdalsberget samt en storutbyggnad av Sicklaanläggningen.Syftet med detta arbete är att undersöka ett miljövänligare alternativ till standardbetongensom ska användas vid utbyggnaden av Sicklaanläggningen. Då den främsta”miljöboven” i betongen är cementet har målet med denna studie varit att ersätta cementetmed miljövänliga tillsatsmaterial i största möjliga mängd, i syfte att minskacementets negativa inverkan på miljön.I föreliggande arbete har en genomgång utförts på erhållna data med exponeringsklasser,därefter påbörjades en litteraturstudie i syfte att inhämta kunskaper inomområdet. Med hjälp av experter har två fiktiva recept för respektive exponeringsklassräknats fram för standardbetongen och den gröna betongen. Med denna metod genomfördesen noggrann jämförelse mellan de olika recepten avseende cementets inverkanpå den globala uppvärmningen. Därefter undersöktes existerande EPD:er, vilka infogadesin i programvaran One Click LCA (2015). En LCA i den nämnda programvaranutfördes, vilket möjliggjorde att data kunde sammanställas och en jämförelse av klimatpåverkanmellan de fyra olika fiktiva recepten kunde genomföras.Sammanställd och jämförd data från LCA och analys av EPD:er visar att 70% av konstruktionenmed exponeringsklass XD2 får en reducering på 47% på den globala uppvärmningenvid användning av grön betong istället för standardbetong. Vidare visarresultatet att resterande 30% av konstruktionen med exponeringsklass XF3/XC4 fåren reduktion på 20% vid användning av grön betong istället för standardbetong. Dentotala reduktionen på den globala uppvärmningen vid användning av grön betongistället för standardbetong för utbyggnaden av Sickla reningsverk beräknades till 40%.
502

Study of crack width within a suspended concrete slab with different amount of cement clinker considering lower climate impact

Feizi, Sedige, Khan, Fateha Yasmin January 2018 (has links)
This master thesis investigates the possibility of using a concrete recipe with only 70 % cement clinker for a building project named Gretas Glänta, regarding the demands of cracking for a suspended slab. The requirement to fulfill was a maximum crack width of 0.2 mm due to drying shrinkage and long- term loading. The purpose of using a lower amount of cement clinker in the concrete mix is to reduce the climate impact from the concrete. The thesis considers material testing and modelling of different concrete recipes with variation of the amount of cement clinker. Fly ash was used as the alternative binder. A total of five concrete mixes was tested. One mix with 100% cement clinker was through laboratory testing compared to mixes with 85 % and 70 % cement clinker content. A concrete mix with only 50 % cement clinker was also tested, but this mix is today not allowed according to the concrete standards, but was included in the study to test different material properties of the fresh and hardened concrete. All concrete mixes were tested with the effectivity factor 1, except for the recipe with 70 % cement clinker, which was tested for effectivity factors of 1 and 0.4. The performed study showed that the concrete mix 4 with 70 % cement clinker and with the effectivity factor 0.4 reached the strength class C35/45 after 28 days and also fulfilled the specified requirement of a maximum crack width of 0.2 mm due to drying shrinkage and long-term loading. Water permeability test showed that the concrete mix with 70 % cement clinker and an effectivity factor of 0.4 was waterproof. The concrete mix 3 with 70 % cement clinker and the effectivity factor 1 reached a strength class C30/37. The concrete mix 1 with 100 % cement clinker obtained the highest strength class C50/60 and the mix 2 with 85 % cement clinker reached strength class C45/55. The concrete mix 5 with 50 % cement clinker reached the strength class C20/25 which is the lowest strength class among the tested recipes. All the concrete recipes seemed to be waterproof according to the water permeability test. A background description of carbon dioxide emission from concrete and cement production is presented in the report. Research about ongoing methods to minimize the emission from concrete and cement industry is also summarized. FE-modelling with the software FEM-design and analytical calculations were performed to investigate the crack width due to drying shrinkage and long-term loading for the slab, for concrete mix 2 with 85 % cement clinker with effectivity factor 1 and mixes 3 and 4 with 70 % cement clinker and effectivity factors of 1 and 0.4. The properties obtained from the laboratory tests were used in the modelling and analytical calculations. Results from FEM-design and analytical calculations showed that concrete mixes 3 and 4 with 70 % cement clinker and effectivity factors of 1 and 0.4, and the concrete mix 2 with 85 % cement clinker with effectivity factor 1, fulfilled the demand on crack width. The calculation was not performed for concrete mixes 1 and 5 with 100 % and 50 % cement clinker, respectively, because they were not to be used in the building project. The results from the performed study showed that concrete mix 4 with 70 % cement clinker and an effectivity factor of 0.4 can be used in the building project Gretas Glänta in order to lower the climate impact from the concrete. / Examensarbetet undersöker möjligheten att använda ett betongrecept med endast 70 % cementklinker för ett husbyggnadsprojekt kallat Gretas Glänta med hänsyn till krav på sprickbildning i en fribärande platta. Kravet som ska uppfyllas är en sprickvidd på max 0.2 mm med hänsyn till krympning och långtidsbelastning. Syftet med att använda en lägre andel cementklinker i betongblandningen är att minska klimatpåverkan från betongen. Examensarbetet består av materialförsök och konstruktionsteknisk modellering för olika betongrecept, där andelen cementklinker varieras. Flygaska användes som alternativt bindemedel. Totalt undersöktes fem betongmixer. En mix med 100 % cementklinker jämfördes genom laboratorietestning med motsvarigheter med 85 % och 70 % cementklinkerinnehåll. Ett betongrecept med 50 % cementklinker undersöktes också i detta examensarbete, trots att detta idag inte tillåts enligt betongstandarderna, men inkluderades i studien för att testa olika materialegenskaper i färskt och hårdnat tillstånd. Alla betongmixerna testades med effektivitetsfaktorn 1 förutom receptet med 70 % cementklinkerandel som testades för både 1 och 0.4 i effektivitetsfaktor. Den genomförda studien visade att betongmix 4 med 70 % cementklinker och med effektiviseringsfaktor 0.4 uppnådde hållfasthetsklass C35/45 efter 28 dagar och uppfyllde också angivet krav på maximal sprickbredd 0,2 mm med hänsyn till krympning och långtidslast. Vattenpermeabilitetstest visade att betongmixen med 70 % cementklinker och effektiviseringsfaktor 0.4 var vattentätt. Betongmix 3 med 70 % cementklinker och effektivitetsfaktor 1 uppnådde hållfasthetsklass C30/37. Betongmix 1 med 100 % cementklinker erhöll den högsta hållfasthetsklassen C50/60 och betongmix 2 med 85 % cementklinker gav hållfasthetsklass C45/55. Betongmix 5 med 50 % cementklinker uppnådde hållfasthetsklass C20/25 vilket var den lägsta av de testade betongrecepten. Alla betongrecepten verkade ge vattentät betong enligt vattenpermeabilitetstest. En bakgrundsbeskrivning av koldioxidutsläpp från betong- och cementproduktion genomförs i rapporten. Forskning om pågående metoder för att minimera utsläppen från betong- och cementindustrin sammanfattas också. FE-modellering med programmet FEM-design och analytiska beräkningar utfördes för att undersöka sprickbredden med hänsyn till krympning och långtidslast för betongplattan för betongmix 2 med 85 % cementklinker och effektiviseringsfaktor 1 och betongmixerna 3 och 4 med 70 % cementklinker och effektiviseringsfaktorerna 1 och 0.4. Egenskaperna som erhölls i laboratorietesterna användes i modellerings och de analytiska beräkningarna. Resultat från FEM-design och analytiska beräkningarna visade att betongmixerna 3 och 4 med 70 % cementklinker med effektiviseringsfaktorerna 1 och 0.4 och betongmix 2 med 85 % cementklinker och effektiviseringsfaktor 1 uppfyllde kravet på sprickbredd. Beräkningen utfördes inte för betongmixerna 1 och 5 med 100 % cementklinker och 50 % cementklinker då de inte var aktuella för att användas i bostadsprojektet. Resultaten från den genomförda studien visade att betongmix 4 med 70% cementklinker och med en effektivitetsfaktor 0.4 kan användas i husbyggnadsprojektet Gretas Glänta för att sänka klimatpåverkan från betongen.
503

Alternative methods to prevent thermal cracking in concrete / Alternativa metoder för att förhindra termisk sprickbildning i betong

Barchin, Alexander, Sedighi, Navid January 2019 (has links)
In the construction industry, concrete is the most common material, because of its good properties such as compressive strength and endurance. Concrete is a composition of several different materials where one of the main components is cement. When the hydration process starts, large amount of heat is generated. This leads to temperature rise within the structure. The heat development that takes place can become critical for massive structures such as dams and power plants, where natural cooling is not sufficient. This in combination with internal and external restraint resulting in tensions causing cracks in the structure. By controlling the temperature development, one can reduce the risk of cracking in massive structures. The controlling is divided into pre-cooling and post-cooling. Reduction of the risk for thermal cracking can be done in different ways. Parts of the cement in the concrete can be replaced by a pozzolan material such as silica fume, blast furnace slag or fly ash. Another method is to increase the size of the aggregates which makes it possible to reduce the cement content with remained strength. Cooling the aggregates or use of ice can also be used as a pre-cooling methods. The most common post-cooling method is the installation of cooling pipes. Pipes are installed between the reinforcement bars, in which one then pump through with cold water. This thesis aims at practicing the methods examined by Lagundžija & Thiam (2017). Focusing on those results that proved to be most effective, i.e. the combination of fly ash, ice and large aggregates. The results retrieved during the tests shows a significant increase in the compressive strength when using a combination of fly ash, ice and large aggregates. This gives us the opportunity to reduce the initial cement content. Reducing the cement content is the most effective factor regarding the heat development. When replacing amounts of the water with ice, it can be seen that the initial casting temperature was reduced. Further studies can be done to find the right amount of reduction of the cement that can be done while maintaining the required compressive strength. / Inom byggbranschen är betong det mest förekommande materialet, detta tack vare dess goda egenskaper, som till exempel tryckhållfasthet och uthållighet. Betongen utgörs av flera olika beståndsdelar där den centrala komponenten är cement. När cementets hydratationsprocess startar utvecklas en markant värmeutveckling. Detta leder till temperaturhöjningar inuti den nygjutna konstruktionen. Värmeutvecklingen kan bli kritisk för grövre konstruktioner, som till exempel dammar och kraftverk, där naturlig avkylning inte är tillräcklig. Detta i kombination med att inre och yttre tvång resulterar i dragspänningar som orsakar sprickor i konstruktionen. Genom att styra temperaturutvecklingen kan man minska risken för sprickbildning i massiva konstruktioner. Styrningen delas in i förberedande kylning och efterkylning. Reduktion av risken för termisk sprickbildning kan ske på olika sätt. Delar av cementen i betongen kan ersättas med ett puzzolant material som till exempel silikatstoft, masugnsslagg eller flygaska. En annan metod är att öka ballaststorleken vilket gör det möjligt att minska cementhalten med kvarvarande hållfasthet. Man kan även kyla ballasten alternativt blanda in is i mixen för att sänka den initiala temperaturen. Den mest förekommande efterkylningsmetoden är installation av kylrör. Det monteras in rör mellan armeringsjärnen, vilket man sedan pumpar kallt vatten igenom. Denna uppsats syftar på att praktiskt tillämpa de metoder som undersöktes av Lagundžija & Thiam (2017). Fokus på de resultat som visade sig vara mest effektiva, dvs kombinationen av flygaska, is och grov ballast. Resultaten som uppnåddes under de tester som utfördes visar en markant ökning i tryckhållfastheten vid användning av kombinationen med flygaska, is och grov ballast. Detta ger oss utrymmet att reducera den initiala cementhalten som används. Att minska cementinnehållet är den faktor som ger störst effekt gällande värmeutvecklingen. Fortsatta studier kan göras för att hitta rätt mängd reduktion av cementet som kan göras samtidigt som anvisad tryckhållfasthet bibehålls.
504

Simulation of Hardening of the MahanaKhon Tower Mat Foundation

Kazi-tani, Zakaria January 2019 (has links)
Cement hydration is the result of a series of simultaneous chemical reactions occurring during the production of concrete. An excessive amount of heat is generated, which consequently may give rise to thermal stresses and cause early age cracks in concrete that may affect its structural integrity, and load bearing capacity. Incorporating fly ash into the concrete mixture has shown to be an efficient method to reduce the temperatures developed during early age hydration, especially for massive concrete structures. Fly ash does additionally affect the concrete's development of compressive strength, tensile strength and Young's modulus. The MahanaKhon tower's mat foundation is divided into 14 layers, with fly ash incorporated in the concrete mix. A finite element model was developed of the mat foundation with COMSOL Multiphysics to simulate the developed temperatures and thermal stresses during curing. The simulations were carried out as parametric studies with different strain reference temperatures. The simulated temperatures were compared with existing temperature measurements that were conducted in three different elevations in each concrete layer. The result of the temperature analyses showed that the measured temperatures were generally larger than the simulated ones, which may have been the result of the numerical model's heat conductivity and convective heat transfer coeffcient not reflecting the actual case. Furthermore, the numerical model did not take into account the effects of solar radiation, which would most likely have increased the temperature of the concrete. The maximum simulated temperatures were mostly found in the center level of the concrete, followed by the lower level, and the lowest at the top. It was also observed that the maximum temperatures in some of the mat foundation layers could exceed 70 °C, which is generally considered high since the risk of delayed ettringite formation may arise. The large temperature is partially a result of not using cooling methods, such as cooling pipes, but also due to the high initial and ambient temperatures. The result of the thermal stress analyses showed that no tensile stresses arose when the strain reference temperature, Tref, was specified to 30 °C, corresponding to the mean ambient temperature. This is due to the concrete temperature not falling below Tref, and the concrete will therefore be in expansion and only be subject to compressive stresses. Increasing Tref to 50 °C, which was considered a reasonable estimation, resulted in developed tensile stresses in all mat foundation layers, where the majority of the mat foundation layers showed a risk of superficial surface cracks. The maximum tensile stresses were found at the final time of the simulations, which was expected, since the temperatures were at their lowest as a result of removing the curing insulation. Finally, setting Tref to 70 °C, corresponding to the maximum temperature during hardening, increased the induced tensile stresses considerably, due to the large temperature gradient between Tref and the concrete temperature. The maximum stresses were, as expected, located at the top level and caused by internal restraint. The second largest tensile stresses were found in the center level, also subject to internal restraint. The lowest tensile stresses were located in the lower level, subject to external restraint. / Cementhydratation är resultatet av en serie kemiska reaktioner som sker under tillverkningen av betong. Stora mängder värme genereras, vilket följaktligen kan ge upphov till termiska spänningar och orsaka tidig sprickbildning som påverkar betongens hållfasthet, och bärförmåga. Inkludering av flygaska i betongblandningen har visat sig vara en effektiv metod avsedd att minska temperaturerna som utvecklas under hydratationen i ung betong, särskilt i massiva betongkonstruktioner. Flygaska påverkar också betongens utveckling av tryckhållfasthet, draghållfasthet och elasticitetsmodul. MahanaKhon towers bottenplatta är uppdelad i 14 lager, där flygaska inkluderades i bottenplattans betong. En finit elementmodell av bottenplattan skapades i COMSOL Multiphysics, där de utvecklade temperaturerna och termiska spänningarna i den unga betongen simulerades under bottenplattans härdningsfas. Simuleringarna genomfördes som parameterstudier med olika referenstemperaturer. De simulerade temperaturerna jämfördes vidare med befintliga temperaturmätningar som utfördes i tre olika elevationer i varje gjutetapp. Resultaten av temperaturerna visade att de uppmätta temperaturerna var generellt högre än de simulerade, vilket bland annat kan bero på att betongens värmeledningsförmåga, samt konvektiva värmeöverföringskoefficient inte återspeglade det aktuella fallet. Den numeriska modellen tog inte heller hänsyn till effekten av solinstrålning, som sannolikt skulle ökat betongens temperatur. De maximala temperaturerna hittades mestadels i betongens mittnivå, följt av den lägre nivån och slutligen lägsta nivåerna vid toppen. Det observerades även att de maximala temperaturerna i bottenplattan kunde överstiga 70 °C, vilket generellt anses vara högt då risken för fördröjd ettringitbildning kan uppstå. De höga temperaturerna beror delvis på avsaknad av kylmetoder, såsom kylrör, men även på den höga initialtemperaturen och omgivningstemperaturen. Resultaten av spänningsanalysen påvisade att inga dragspänningar uppstod när referenstemperaturen Tref denierades till 30 °C, som motsvarar den genomsnittliga omgivningstemperaturen. Detta förklaras av att betongen kommer att vara i expansion och följaktligen endast utsättas för tryckspänningar. Efter att Tref ökats till 50 °C, vilken ansågs vara en rimlig estimering i denna studie, uppstod dragspänningar i alla lager i bottenplattan, där vissa utsattes för risk för ytsprickor. De maximala dragspänningarna uppstod vid simuleringarnas slut, vilket var förväntat då temperaturerna var som lägst vid den tidpunkten till följd av att isoleringen avlägsnades. Slutligen höjdes Tref till 70 °C, vilket motsvarar den maximala temperaturen i bottenplattan under härdning. De inducerade dragspänningarna ökade avsevärt på grund av den stora temperaturgradienten mellan Tref och betongtemperaturen. Samtliga lager utsattes i detta fall för risk för genomgående sprickor. De maximala dragspänningarna påträffades på toppnivån och orsakades av inre tvång. De näst största dragspänningarna fanns i mitten av plattan och var också resultatet av inre tvång. De lägsta dragspänningarna påträffades vid plattans lägre nivå, som utsattes för yttre tvång.
505

Fracture Characteristics Of Self Consolidating Concrete

Naddaf, Hamid Eskandari 07 1900 (has links)
Self-consolidating concrete (SCC) has wide use for placement in congested reinforced concrete structures in recent years. SCC represents one of the most outstanding advances in concrete technology during the last two decades. In the current work a great deal of cognizance pertaining to mechanical properties of SCC and comparison of fracture characteristics of notched and unnotched beams of plain concrete as well as using acoustic emission to understand the localization of crack patterns at different stages has been done. An artificial neural network (ANN) is proposed to predict the 28day compressive strength of a normal and high strength of SCC and HPC with high volume fly ash. The ANN is trained by the data available in literature on normal volume fly ash because data on SCC with high volume fly ash is not available in sufficient quantity. Fracture characteristics of notched and unnotched beams of plain self consolidating concrete using acoustic emission to understand the localization of crack patterns at different stages has been done. Considering this as a platform, further analysis has been done using moment tensor analysis as a new notion to evaluate fracture characteristics in terms of crack orientation, direction of crack propagation at nano and micro levels. Analysis of B-value (b-value based on energy) is also carried out, and this has introduced to a new idea of carrying out the analysis on the basis of energy which gives a clear picture of results when compared with the analysis carried out using amplitudes. Further a new concept is introduced to analyze crack smaller than micro (could be hepto cracks) in solid materials. Each crack formation corresponds to an AE event and is processed and analyzed for crack orientation, crack volume at hepto and micro levels using moment tensor analysis based on energy. Cracks which are tinier than microcracks (could be hepto), are formed in large numbers at very early stages of loading prior to peak load. The volume of hepto and micro cracks is difficult to measure physically, but could be characterized using AE data in moment tensor analysis based on energy. It is conjectured that the ratio of the volume of hepto to that of micro could reach a critical value which could be an indicator of onset of microcracks after the formation of hepto cracks.
506

Interaktionen zwischen Boden und Bestockung auf Kippenstandorten des Niederlausitzer Braunkohlenrevieres am Beispiel der Rekultivierungsbaumarten Gemeine Kiefer, Gemeine Birke und Traubeneiche : Wachstums-, ernährungs- und bodenkundliche Untersuchungen

Stähr, Falk 12 August 2003 (has links) (PDF)
Auf repräsentativen Kippenstandorten des Niederlausitzer Braunkohlenrevieres wurden typische Forstökosysteme der ersten Generation analysiert. Gegenstand der Untersuchung waren mittelalte Bestände (46- bis 70 Jahre) der Rekultivierungsbaumarten Kiefer (n = 22) und Birke (n = 12) sowie 24- bis 45jährige Jungbestände der Baumarten Trauben- (n = 7) und Roteiche (n = 2). Die Roteichenbestände dienten primär vergleichenden Untersuchungen. Für altersspezifische und standortsvergleichende Betrachtungen wurden Ergänzungsbestände auf Kippenstandorten und Vergleichsbestände auf unverritzten Waldstandorten zusätzlich einbezogen. Die untersuchten Erstaufforstungen stocken auf Kippenkomplexen, die klimatisch, hydrologisch und geomorphologisch vergleichbar sind und baumartenweise weitestgehend identischen bodenmeliorativen Maßnahmen sowie waldbaulichen Behandlungsverfahren unterzogen wurden. Ziel der Untersuchung war die Qualifizierung der Wechselwirkungen zwischen Kippenstandort und aufstockendem Bestand. Als Leitgrößen für die Wirkung standörtlicher Merkmale auf die Baumarten dienten wachstums- (Leistungsparameter) und ernährungskundliche Kenndaten (Vitalitätsweiser). Quantität und Qualität der Humusauflage sowie die bodengenetische Entwicklung wurden als Indikatoren für die Rückwirkungen der bestandesbildenden Rekultivierungsbaumarten auf den Standort verwendet. Besondere Berücksichtigung fand das lokale Depositionsgeschehen.
507

Novel approaches in determining baseline information on annual disposal rates and trace element content of U.S. coal combustion residues : a response to EPA’s June 2010 proposed disposal rule

Chwialkowski, Natalia Ewa 14 February 2011 (has links)
Although products of coal combustion (PCCs) such as coal ash are currently exempted from classification as a hazardous waste in the United States under the 1976 Resource Conservation and Recovery Act (RCRA), the U.S. Environmental Protection Agency (EPA) is now revising a proposed rule to modify disposal practices for these materials in order to prevent contamination of ground- and surface water sources by leached trace elements. This paper analyzes several aspects of EPA’s scientific reasoning for instating the rule, with the intent of answering the following questions: 1) Are EPA’s cited values for PCC production and disposal accurate estimates of annual totals?; 2) In what ways can EPA’s leaching risk modeling assessment be improved?; 3) What is the total quantity of trace elements contained within all PCCs disposed annually?; and 4) What would be the potential costs and feasibility of reclassifying PCCs not under RCRA, but under existing NRC regulations as low-level radioactive waste (LLRW)? Among the results of my calculations, I found that although EPA estimates for annual PCC disposal are 20% larger than industry statistics, these latter values appear to be closer to reality. Second, EPA appears to have significantly underestimated historical PCC disposal: my projections indicate that EPA’s maximum estimate for the quantity of fly ash landfilled within the past 90 years was likely met by production in the last 30 years alone, if not less. Finally, my analysis indicates that while PCCs may potentially meet the criteria for reclassification as low-level radioactive waste by NRC, the cost of such regulation would be many times that of the EPA June proposed disposal rule ($220-302 billion for PCCs disposed in 2008 alone, versus $1.47 billion per year for the Subtitle C option and $236-587 million for Subtitle D regulatory options). / text
508

Alkalicky aktivované systémy / Alkali Activated Systems

Bílek, Vlastimil January 2017 (has links)
This doctoral thesis is focused on the possibilities of alkali-activated slag (AAS) shrinkage reduction, which would together with the use of waste sludge from waterglass production contribute to wider practical utilization of this interesting material. Besides the influence on AAS dimensional changes also effect of various factors on workability, setting time and mechanical properties was investigated. Obtained results were supported by the application of instrumental techniques like izotermal calorimetry, mercury intrusion porosimetry, scanning electron microscopy and X-ray diffraction. The results show the possibilities of reduction of AAS drying shrinkage related to its cracking tendency through the combination of increased dose of waterglass and reduced water to slag ratio (w/b), partial replacement of slag by pulverized fly ash or cement by-pass dust and application of organic admixtures, where significant effect on AAS hydration was observed. On the basis of the obtained results concrete mixtures, where the whole activator was replaced by the waste sludge form waterglass production, were designed and optimized in terms of shrinkage, mechanical properties and price. Selected concretes were also tested in semi-operating conditions.
509

Vývoj nové technologie pískového pórobetonu s využitím druhotných surovin / Development of new technology of sand autoclaved aerated concrete with using of secondary raw materials

Ondříčková, Pavlína January 2018 (has links)
Autoclaved sand aerated concrete is a modern building material with high thermal insulation properties. Only sand is used as the primary silicate component of aerated concrete in the Czech Republic. For the more favourable economic and ecological properties of aerated concrete, the use of secondary raw materials is used in this work. The secondary raw materials examined included fluidized bed and fly ash, slag and glass recycled. The aerated concrete composite with secondary admixtures was developed under hydrothermal conditions of a laboratory autoclave for 7 and 12 hours at 190°C. From the secondary raw materials tested, a 10% glass recycler additive yielded the highest strength. Other additives that have a positive effect on mechanical properties include SAKO and Oslavany. From the results of the work it is evident that the use of secondary raw materials increases the strength, improves the rheology of the mixture and supports the formation of tobermorite.
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Studium ovlivnění hydratace portlandského cementu působením zinku / The study of zinc influence on Portland cement hydration.

Ptáček, Martin January 2019 (has links)
The topic of this work is the monitoring of the effect of zinc on the hydration process in Portland mixed cement (specifically with the addition of finely ground granulated blast-furnace slag, high temperature fly ash and fluidized bed combustion filter ash). How much zinc and at what time it remains in the pore solution during hydration. Activation energy of a mixture of cement with zinc in the form of soluble salts (Zn(NO3)2.6H2O and ZnCl2) and insoluble oxide (ZnO) by isothermal calorimetry was also investigated. The XRF method has shown composition during hydration. The zinc retardation effect was investigated by isothermal calorimetry and activation energy was calculated using this method. The XRF and ICP-OES methods were used to measure the zinc content of the pore solution. And the amount of portlandite was monitored by the DTA and XRF method.

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