Gasisolierte Systeme im Gleichspannungsbetrieb vereinen für Anwendungen moderner Energieübertragung die Forderungen nach kleinräumigen Anlagen und verlustarmem Energietransport über große Entfernungen. Für einen zuverlässigen und sicheren Betrieb muss das Verhalten der eingesetzten Gas-Feststoff-Isolierung im technologischen System bis an die Grenzen des Isolationsvermögens bekannt sein. Gegenstand der vorliegenden Arbeit ist deshalb das Überschlagsverhalten von Gas-Feststoff-Isoliersystemen unter Gleichspannungsbelastung. Dabei stehen zwei wesentliche Einflussfaktoren im Vordergrund: die Temperatur, motiviert durch reale Stromwärmeverluste, und eine feste Störstelle auf der Gas-Feststoff-Grenzfläche, motiviert durch in der Praxis nicht völlig auszuschließende, metallische Partikel. Die Effekte dieser beiden Parameter auf die Feldverteilung, die Oberflächen- und Raumladungsbildung sowie das Isolationsvermögen bei Gleichspannung werden zunächst in zwei Versuchsanordnungen separat experimentell untersucht. Anschließend wird deren Zusammenwirken und gegenseitige Beeinflussung im Gesamtsystem analysiert. Die betriebsbedingte Erwärmung der Leiter gasisolierter Systeme führt zu einer inhomogenen Temperaturverteilung, die sich auf die Eigenschaften der Isolierstoffe Gas und Epoxidharz auswirkt. Die von der Temperatur abhängige Leitfähigkeit der Feststoffisolatoren führt zu einer temperaturabhängigen Feldverteilung, bei der sich der Ort der Höchstfeldstärke verschiebt. Dabei kann sich der Absolutwert der Höchstfeldstärke erhöhen und somit das Isolationsvermögen verringern. Gleichzeitig weist das Isoliergas nahe des erwärmten Leiters lokal eine geringere Dichte und damit eine geringere dielektrische Festigkeit auf. Die thermisch bedingte Minderung des Isolationsvermögens bei Gleichspannung beträgt in der untersuchten Anordnung (25 ... 35) %. In den schwach inhomogenen Feldern gasisolierter Anlagen erweisen sich metallische Partikel auf Isolatoren ab drei Millimetern Länge als besonders kritisch. Bei einem Gasdruck unterhalb von 0,3 MPa setzen an den Partikelspitzen zum Teil bereits ab 50 % der Durchschlagsspannung ohne Partikel Teilentladungen ein, sodass die Koronastabilisierung zu einer vergleichsweise hohen Überschlagsspannung führt. Durch diese stabilen Glimmentladungen kann die Störstelle bei Gleichspannung durch die üblichen Detektionsverfahren jedoch nicht zweifelsfrei nachgewiesen werden. Oberhalb von 0,3 MPa treten vor dem Überschlag keine Teilentladungen auf. Aufgrund der fehlenden Koronastabilisierung kann die Isolationsfestigkeit durch einen erhöhten Gasdruck nicht oder nur stark unterproportional gesteigert werden. Die mit der Modellanordnung gewonnenen Erkenntnisse sind nachweislich auf Isolatoren kommerzieller Anlagen übertragbar. Das in der vorliegenden Arbeit untersuchte Überschlagsverhalten von Gas-Feststoff-Isoliersystemen unter Gleichspannungsbelastung wird maßgeblich durch die Temperaturverteilung und durch feste Störstellen auf der Grenzfläche beeinflusst. Oberflächen- und Raumladungen verändern das üblicherweise ohmsch-kapazitiv beschriebene Verhalten des Isolierstoffsystems bei Gleich- und Mischspannungsbelastung. Der Einfluss zusätzlicher Ladungsträger auf die stark temperaturabhängige Feldumbildung demonstriert, dass das Isoliergas in diesem Fall mit teilchendichte- und feldstärkeabhängigen Drift- und Diffusionsprozessen zur Modellierung des transienten Verhaltens von Gleichspannungssystemen berücksichtigt werden muss. Die Untersuchung des Systemverhaltens an den Grenzen des Isolationsvermögens ist wichtiger Bestandteil bei der Entwicklung innovativer Technologien der modernen Energieübertragung bei steigender Übertragungsleistung. / DC operated gas-insulated systems combine the demand for space saving installations and lowloss energy transport over long distances for applications of recent energy transmission. In order to ensure a reliable and safe operation, the behaviour of the gas-solid insulation, which is used in the technological system, has to be known up to the limits of the insulation properties. Hence, this thesis deals with the flashover behaviour of gas-solid insulation systems under DC voltage stress. Thereby, it focuses on two main influence factors: the temperature, due to real current heat losses, and an adhesive defect on the gas-solid interface, due to metallic particles that cannot be fully excluded in practice. Firstly, it is investigated experimentally in two test arrangements, how each parameter separately affects the electrical field distribution, the surface and volume charge accumulation and the insulation performance under DC voltage stress. Following that, their interaction and mutual influence is analysed in the whole system. Due to operating currents, the heating of the conductors in gas-insulated systems causes an inhomogeneous temperature distribution, that affects the properties of the insulating materials gas and epoxy resin. The temperature-dependent conductivity of the solid insulators leads to a temperature-dependent field distribution. Thereby, the location of the highest field strength is shifted. Since the absolute value of the highest field strength can increase, the insulation performance can decrease. Simultaneously, the insulating gas close to the heated conductor locally has a lower gas density and therefore a lower dielectric strength. The thermal related reduction of the insulation performance under DC voltage stress amounts to (25 ... 35) % in the investigated arrangement. Metallic particles, with a length of more than three millimetres and adhering on spacers, turn out to be particularly critical in the weakly inhomogeneous field of gas-insulated systems. At pressures below 0,3 MPa, partial discharges at the particle tips partly ignite already at 50 %of the breakdown voltage without a particle. The corona stabilisation leads to a relatively high flashover voltage. However, due to these stable glow discharges under DC voltage stress, the defect can not be unequivocally proven by usual detection methods. Above 0,3 MPa, no partial discharges occur before the flashover. Due to the missing corona stabilisation, with a higher gas pressure, the insulation strength is not or only disproportionately low increasing. The findings gained with the model arrangement are evidently applicable to spacers of commercial installations. The flashover behaviour of gas-solid insulation systems under DC voltage stress, examined in this thesis, is influenced significantly by the temperature distribution and adhesive particles on the interface. Surface and volume charges change the generally resistive-capacitive described behaviour of the insulation system under DC and superimposed voltage stress. The influence of additional charge carriers on the strongly temperature-dependent field transition demonstrates, that in this case, the insulating gas with its drift and diffusion processes, depending on the particle density and the field strength, has to be considered, when modelling the transient behaviour of DC operated systems. Investigating the system behaviour to the limits of the insulation properties is a crucial element of developing innovative technologies of the modern energy transmission at increasing transmissions powers.

The history of surgery is nearly as old as the human race. Control of wound infection has always been an essential part of any surgical procedure, and is still an important challenge in hospital operating rooms today. For patients undergoing surgery there is always a risk that they will develop some kind of postoperative complication. It is widely accepted that airborne bacteria reaching a surgical site are mainly staphylococci released from the skin flora of the surgical staff in the operating room and that even a small fraction of those particles can initiate a severe infection at the surgical site.  Wound infections not only impose a tremendous burden on healthcare resources but also pose a major threat to the patient. Hospital-acquired infection ranks amongst the leading causes of death within the surgical patient population. A broad knowledge and understanding of sources and transport mechanisms of infectious particles may provide valuable possibilities to control and minimize postoperative infections. This thesis contributes to finding solutions, through analysis of such mechanisms for a range of ventilation designs together with investigation of other factors that can influence spread of infection in hospitals, particularly in operating rooms. The aim of this work is to apply the techniques of computational fluid dynamics in order to provide better understanding of air distribution strategies that may contribute to infection control in operating room and ward environments of hospitals, so that levels of bacteria-carrying particles in the air can be reduced while thermal comfort and air quality are improved.  A range of airflow ventilation principles including fully mixed, laminar and hybrid strategies were studied. Airflow, particle and tracer gas simulations were performed to examine contaminant removal and air change effectiveness. A number of further influential parameters on the performance of airflow ventilation systems in operating rooms were examined and relevant measures for improvement were identified. It was found that airflow patterns within operating room environments ranged from laminar to transitional to turbulent flows. Regardless of ventilation system used, a combination of all airflow regimes under transient conditions could exist within the operating room area. This showed that applying a general model to map airflow field and contaminant distribution may result in substantial error and should be avoided. It was also shown that the amount of bacteria generated in an operating room could be minimized by reducing the number of personnel present. Infection-prone surgeries should be performed with as few personnel as possible. The initial source strength (amount of colony forming units that a person emits per unit time) of staff members can also be substantially reduced, by using clothing systems with high protective capacity. Results indicated that horizontal laminar airflow could be a good alternative to the frequently used vertical system. The horizontal airflow system is less sensitive to thermal plumes, easy to install and maintain, relatively cost-efficient and does not require modification of existing lighting systems. Above all, horizontal laminar airflow ventilation does not hinder surgeons who need to bend over the surgical site to get a good view of the operative field. The addition of a mobile ultra-clean exponential laminar airflow screen was also investigated as a complement to the main ventilation system in the operating room. It was concluded that this system could reduce the count of airborne particles carrying microorganisms if proper work practices were maintained by the surgical staff. A close collaboration and mutual understanding between ventilation experts and surgical staff would be a key factor in reducing infection rates. In addition, effective and frequent evaluation of bacteria levels for both new and existing ventilation systems would also be important. / Tidigt i mänsklighetens utveckling har kirurgin funnits med i bilden. Hantering av infektioner har genom tiderna varit en oundviklig del av alla kirurgiska ingrepp, och finns kvar ännu idag som en viktig utmaning i operationssalar på sjukhus. För patienter som genomgår kirurgi finns alltid en risk att de efter ingreppet utvecklar någon behandlingsrelaterad komplikation. Allmänt accepterat är att de luftburna bakterier som når operationsområdet huvudsakligen består av stafylokocker frigjorda från hudfloran av operationspersonalen i operationssalen, och att endast en liten del av dessa partiklar behövs för att initiera en allvarlig infektion i det behandlade området. Sårinfektioner innebär inte bara en enorm börda för hälso- och sjukvårdsresurser, utan utgör också en betydande risk för patienten. På sjukhus förvärvad infektion finns bland de främsta dödsorsakerna i kirurgiska patientgrupper.. En bred kunskap och förståelse av spridningsmekanismer och källor till infektionsspridande partiklar kan ge värdefulla möjligheter att kontrollera och minimera postoperativa infektioner. Denna avhandling bidrar till lösningar genom analys av en rad olika ventilationssystem tillsammans med undersökning av andra faktörer som kan påverka infektionsspridningen på sjukhus, främst i operationssalar. Syftet med arbetet är att med hjälp av CFD-teknik (Computational Fluid Dynamics) få bättre förståelse för olika luftspridningsmekanismers betydelse vid ventilation av operationssalar och vårdinrättningar på sjukhus, så att halten av bacteriebärande partiklar i luften kan minskas samtidigt som termisk komfort och luftkvalité förbättras.  Flera luftflödesprinciper för ventilation inklusive omblandade strömning, riktad (laminär) strömning och hybridstrategier har studerats. Simuleringar av luft-, partikel- och spårgasflöden gjordes för alla fallstudier för att undersöka partikelevakuering och luftomsättning i rummet. Flera viktiga parametrar som påverkar detta undersöktes och relevanta förbättringar  föreslås i samarbete med industrin. Av resultaten framgår att mängden genererade bakterier i en operationssal  kan begränsas genom att minska antalet personer i operationsteamet. Infektionsbenägna operationer skall utföras med så lite personal som möjligt. Den initiala källstyrkan (mängden kolonibildande enheter som en person avger per tidsenhet) från operationsteamet kan avsevärt minskas om högskyddande kläder används. Av resultaten framgår också att ett horisontellt (laminärt) luftflöde kan vara ett bra alternativ till det ofta använda vertikala luftflödet. Ett horisontellt luftflöde är mindre känsligt för termisk påverkan från omgivningen, enkelt att installera och underhålla, relativt kostnadseffektivt och kräver vanligen ingen förändring av befintlig belysningsarmatur. Framför allt begränsar inte denna ventilationsprincip kirurgernas rörelsemönster. De kan luta kroppen över operationsområdet utan att hindra luftflödet. En flyttbar flexibel skärm för horisontell spridning av ultraren ventilationsluft i tillägg till ordinarie ventilation undersöktes också. Man fann att denna typ av tilläggsventilation kan minska antalet luftburna partiklar som bär mikroorganismer om operationspersonalen följer en strikt arbetsordning. Bra samarbete och förståelse mellan ventilationsexperter och operationsteamet på sjukhuset är nyckeln till att få ner infektionsfrekvensen. Det är också viktigt med effektiva och frekventa utvarderingar av bakteriehalten i luften, för såväl nya  som befintliga ventilationssystem. / <p>QC 20160129</p>

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Die vorliegende Arbeit widmet sich der Untersuchung von 4 Modellsystemen der Oberflächenforschung. Die verwendeten experimentellen Methoden sind Summenfrequenzerzeugungsspekroskopie (SFG), Thermische Desorptionsspektroskopie (TDS), Beugung niederenergetischer Elektronen (LEED), Augerelektronenspektroskopie (AES), Infrarotadsorptionsspektrokopie (IRAS) und Rastertunnelmikroskopie (STM). Durch die Verwendung von SFG waren Messungen bis zu 50 mbar möglich. Die untersuchten Systeme sind: CO auf Pt(111), Wasser auf Ag(001) und MgO/Ag(001), CO auf Au/MgO/Ag(001) und CO auf Au-Pd/MgO/Ag(001). Bei den Messungen von CO auf Pt(111) tritt unter bestimmten Druck- und Temperaturbedingungen eine bisher nicht näher untersuchte Doppelpeakstruktur auf, die genauer charakterisiert wurde. Die Untersuchungen von Wasser auf MgO/Ag(001) und Ag(001) zeigen, dass sich auf MgO/Ag(001) zuerst eine Monolage Wasser mit einer darauffolgenden Multilage ausbildet, wohingegen es auf Ag(001) von Beginn an in einer Multilagenschicht wächst. Die Monolage kann unter der Multilage gemessen werden und einige Resonanzen identifiziert werden. Für Au/MgO/Ag(001) zeigte sich mittels STM eine Abhängigkeit des Au-Wachstums von der Schichtdicke, die allerdings nicht spektroskopisch in Erscheinung tritt. Bei den Messungen an gemischten Au-Pd-Teilchen auf MgO/Ag(001) zeigen sich Unterschiede im Adsorptionsverhalten zwischen reinen Metallteilchen und gemischten Teilchen, die auf eine Wechselwirkung zwischen den beiden Metallen zurückzuführen ist. Nach Heizschritten auf 600 K reichern sich die Au-Atome im Mantel des Teilchens an, das Pd bildet den Kern. Die Ergebnisse aller Messungen werden unter Berücksichtigung neuer Veröffentlichungen diskutiert. / This thesis focuses on 4 different model systems of surface science. The experimental techniques used for the measurements include sum frequency generation (SFG), thermal desorption spectroscopy (TDS), low energy electron diffraction (LEED), Auger electron spectroscopy (AES), infrared adsorption spectrosocopy (IRAS) and scanning tunneling microscopy (STM). By using SFG, measurements could be performed up to a pressure of 50 mbar. The systems under investigation were: CO on Pt(111), water on Ag(001) and on MgO/Ag(001), CO on Au/MgO/Ag(001), and CO on Au-Pd/MgO/Ag(001). The system of CO on Pt(111) exhibits a two peak-pattern under certain pressure and temperature conditions which has not been studied so far. Various experiments helped to elucidate the origin of this distinct behaviour. The measurements of water on Ag(001) and MgO/Ag(001) show that on MgO, water first adsorbs as a monolayer with a following multilayer, whereas on Ag(001) it adsorbs as a multilayer from the beginning. The monolayer can be studied below the multilayer and some resonances can be identified. For the case of Au/MgO/Ag(001), STM shows that the growth mode of Au depends on the thickness of the supporting MgO film, which can not be seen with spectroscopic methods. For mixed Au-Pd particles on MgO/Ag(001) a clear difference in the adsorption behaviour between pure metal particles and mixed particles can be seen, which is explained by an interaction between these metals. Annealing the mixed particles to 600 K leads to a segregation of the metals, where the Au atoms diffuse to the shell and the Pd atoms make up the core. The results of all these measurements are discussed in the light of recent publications.

Proteinadsorption ist in vielen biotechnologischen Anwendungen ubiquitär und ein zentrales Forschungsfeld in der Physik der weichen Materie. Das Verstehen der treibenden Kräfte hinter der Proteinadsorption würde zu einer besseren Kontrolle des Adsorptionsprozesses führen und die Entwicklung von Biosystemen mit beispielloser Funktionalität ermöglichen. In der vorliegenden Arbeit wird die Proteinadsorption an weichen polymerartigen Biomaterialien sowie deren physikalische Wechselwirkungen unter Verwendung von zwei unterschiedlichen neu entwickelten Ansätzen theoretisch untersucht. Im ersten Teil wird ein neues mehrkomponentiges kooperatives Bindungsmodell entwickelt, um die Gleichgewichts-Adsorption von Proteinen auf Mikrogelen zu beschreiben. Es war somit möglich, die wahre treibende Kraft der Proteinadsorption zu identifizieren, die hauptsächlich elektrostatischen Ursprungs ist. Eine Errungenschaft des kooperativen Bindungsmodells ist die Vorhersage der kompetitiven Proteinadsorption und -desorption auf das Mikrogel, die auf thermodynamischen Parametern der Adsorption von Proteinen einzelner Sorten basiert. Vergleiche zwischen Experimenten mit binären Proteinmischungen und theoretischen Berechnungen zeigten sehr gute Übereinstimmungen. Der zweite Teil fokussiert auf Protein-Wechselwirkungen mit Polyelektrolyten, um Adsorptionsprozesse auf mikroskopischer Ebene zu erklären. Dafür wurden geladene fleckige Partikel konstruiert und als Proteinmodelle verwendet, während ein einfaches Kugel-Feder-Modell für das Polyelektrolyt und Polyelektrolytbürste benutzt wurde. Ein zentraler Aspekt war die Bestimmung der freien Energie, das Potential der mittleren Kraft (PMF), für die Komplexbildung der beiden Bestandteile mit Vergleichen zur Modellentwicklungen. Die Simulationsergebnisse legen ein komplexes Wechselspiel von elektrostatischen Kräften und Ionenfreisetzungsmechanismen dar, die für die starken attraktiven Wechselwirkungen in den PMFs verantwortlich sind. / Protein adsorption is ubiquitous in many biotechnological applications and has become a central research field in soft matter. Understanding the driving forces behind protein adsorption would allow a better control of the adsorption process and the development of biosystems with unprecedented functionality. In this thesis, protein adsorption onto soft polymeric biomaterials and their physical interactions is studied theoretically by using two different and newly developed approaches. In the first part, a novel multi-component cooperative binding model is developed to describe the equilibrium adsorption of proteins onto microgels. It was thus possible to correctly identify the true driving force behind the protein adsorption which was found to be mainly of electrostatic origin. A key achievement by the cooperative binding model is the prediction of competitive protein adsorption and desorption onto the microgel that is based on thermodynamic parameters related to single-type protein adsorption without any variable parameters. Comparisons between experimental data of binary protein mixtures and theoretical calculations have shown excellent agreements. The second part is focused on protein interactions with polyelectrolyte materials to elucidate adsorption processes on a microscopic level. For this purpose, charged patchy particles are constructed and used as protein models while a simple bead-spring model is employed for the polyelectrolyte and polyelectrolyte brush. A central aspect was the determination of the associated free energy, the potential of mean force (PMF), on the complex formation between the two constituents with comparisons to theoretical model developments. The simulation results evidenced a complex interplay of electrostatic forces and ion release mechanisms to be responsible for the strong attractive interactions observed in the PMFs.

The aim of this thesis work was to gain understanding of the interactions between talc mineral and surfaces, liquids and chemicals relevant for industrial applications, such as pulp and paper. Talc is used in the pulp and paper industry as a filler pigment, in control of pitch (lipophilic extractives) deposits and as a coating pigment. A deeper understanding of talc interactions will be beneficial in optimizing its use. Long-range attractive interactions between talc and hydrophobic model probes, as well as pitch probes, have been measured using the atomic force microscope (AFM) colloidal probe method. Two procedures for preparation of pitch colloidal probes were developed to allow these studies. Model hydrophobic, nanorough surfaces with surface energy characteristics similar to talc have also been prepared and their interactions with hydrophobic model probes compared to interactions between hydrophobic model probes and talc. It is demonstrated that talc mineral interacts with model hydrophobic particles, as well as with pitch, by long-range attractive forces, considerably stronger than the expected van der Waals force. The possible origin of the measured interaction forces is discussed, and the conclusion is that the main cause is an attractive capillary force due to formation of a gas/vapor capillary between the surfaces. Force measurements using model hydrophobic, nanorough surfaces show that a large-scale waviness does not significantly influence the range and magnitude of the capillary attraction, but large local variations in these quantities are found. It is demonstrated that a large variation in adhesion force corresponds to a small variation in local contact angle of the capillaries at the surfaces. The nature of the surface topographical features influences the capillary attraction by affecting the local contact angle and by pinning of the three-phase contact line. The effect is clearly dependent on the size of the surface features and whether they exist in the form of crevices or as extending ridges. Entrapment of air also affects the imbibition of water in pressed talc tablets. The effects of wetting and dispersion agents on the interactions between talc and hydrophobic probes have also been investigated. It is demonstrated that a common dispersing agent used for talc, poly(acrylic acid), does not affect the capillary attraction between talc and non-polar probes. In fact, the results strongly suggest that poly(acrylic acid) does not adsorb on the basal plane of talc. From this finding it is inferred that the stabilizing effect of this additive most likely is due to adsorption to the edges of talc. In contrast, a wetting agent (the non-ionic triblock copolymer Pluronic PE6400) removes the long-range capillary attraction. It is suggested that such an ability to replace air at the talc surface is of great importance for an efficient wetting agent. The Hamaker constant for talc has also been estimated by using optical data obtained from spectroscopic ellipsometry. It is demonstrated that a nanocrystalline talc mineral, cut in different directions displays very small differences in Hamaker constant between the different crystallographic orientations, whereas a microcrystalline sample displays a significantly higher value. The estimated Hamaker constants are discussed for different material combinations of relevance for the pulp- and paper industry, such as cellulose and calcium carbonate. / Målet med detta avhandlingsarbete var att öka förståelsen för interaktioner mellan talkmineral och ytor, vätskor och kemikalier relevanta för industriella applikationer, såsom papper och massa. Talk används i pappers- och massaindustrin som fyllmedel, för kontroll av hartsrika (lipofila extraktivämnen) avsättningar och som bestrykningspigment. En djupare förståelse för talkinteraktioner kommer att vara användbart för att optimera dess användning. Långväga attraktiva interaktioner mellan talk och hydrofoba modellpartiklar, såväl som mellan talk och hartspartiklar, har uppmätts med hjälp av atomkraftsmikroskopi (AFM) genom att fästa kolloidala partiklar på kraftsensorn. Två metoder för att framställa partiklar gjorda av harts har utvecklats för att möjliggöra dessa studier. Hydrofoba, nanostrukturerade modellytor med ytenergier liknande de för talk har också tillverkats och deras växelverkan med hydrofoba modellpartiklar har jämförts med dem mellan talk och hydrofoba modellpartiklar. Studierna visar att talkmineral växelverkar med hydrofoba modellpartiklar, såväl som med harts, genom långväga attraktiva krafter som är betydligt starkare än den förväntade van der Waals kraften. Möjliga orsaker till de uppmätta växelverkanskrafterna diskuteras och slutsatsen blir att huvudorsaken är en attraktiv kapillärkraft som uppkommer genom att en gas-/ångkapillär bildas mellan ytorna. Kraftmätningar gjorda med hydrofoba nanostrukturerade modellytor visar att en storskalig vågighet inte nämnvärt påverkar storleken av kapillärattraktionen, men stora lokala variationer existerar. Det demonstreras att en stor variation i adhesionskraft motsvaras av en liten variation i lokal kontaktvinkel för kapillärerna på ytorna. Ytornas topografi påverkar kapillärattraktionen genom att påverka den lokala kontaktvinkeln samt genom att trefaskontaktlinjen inte kan röra sig fritt över ytan. Effekten är tydligt beroende av huruvida ytojämnheterna existerar i form av nedsänkningar eller upphöjningar. Instängd luft påverkar också pressade talktabletters uppsugningsförmåga av vatten. Vätnings- och dispergeringsmedels inverkan på växelverkan mellan talk och hydrofoba partiklar har undersökts. Resultaten visar att ett vanligt dispergeringsmedel för talk, polyakrylsyra, inte påverkar kapillärattraktionen. I själva verket tyder data på att polyakrylsyra inte adsorberas på talks basalplan. Utifrån dessa resultat dras slutsatsen att polyakrylsyra stabiliserar talkdispersioner genom att adsorbera på talkkanterna. Ett vanligt vätmedel (nonjonisk triblock sampolymer Pluronic PE6400) tar å andra sidan bort långväga kapillärattraktion. Detta antyder att egenskapen att ersätta luft på talkytan är av stor betydelse för effektiva vätmedel. Hamakerkonstanten för talk har uppskattats genom att utnyttja optiska data från ellipsometrimätningar. Det demonstreras att ett nanokristallint talkmineral kapat i olika riktningar uppvisar mycket små skillnader i Hamakerkonstant mellan de olika kristallografiska orienteringarna, medan ett mikrokristallint prov uppvisar ett betydligt högre värde. De beräknade Hamakerkonstanterna diskuteras för olika materialkombinationer relevanta för pappersindustrin, såsom cellulosa och kalciumkarbonat. / QC 20100813

In power plants using large utility coal-fired boilers for generation of electricity the coal is pulverised in coal mills and then it has to be pneumatically transported and distributed to a larger number of burners (e.g. 30-40) circumferentially arranged in several rows around the burning chamber of the boiler. Besides the large pipework flow splitting devices are necessary for distribution of an equal amount of pulverised fuel (PF) to each of the burners. So called trifurcators (without inner fittings or guiding vanes) and ''riffle'' type bifurcators are commonly used to split the gas-coal particle flow into two or three pipes/channels with an equal amount of PF mass flow rate in each outflow cross section of the flow splitting device. These PF flow splitting devices are subject of a number of problems. First of all an uneven distribution of PF over the burners of a large utility boiler leads to operational and maintenance problems, increased level of unburned carbon and higher rates of NOX emissions. Maldistribution of fuel between burners caused by non uniform concentration of the PF (particle roping) in pipe and channel bends prior to flow splitting devices leads to uncontrolled differences in the fuel to air ratio between burners. This results in localised regions in the furnace which are fuel rich, where insufficient air causes incomplete combustion of the fuel. Other regions in the furnace become fuel lean, forming high local concentrations of NOX due to the high local concentrations of O2. Otherwise PF maldistribution can impact on power plant maintenance in terms of uneven wear on PF pipework, flow splitters as well as the effects on boiler panels (PF deposition, corrosion, slagging). In order to address these problems in establishing uniform PF distribution over the outlet cross sections of flow splitting devices in the pipework of coal-fired power plants the present paper deals with numerical prediction and analysis of the complex gas and coal particle (PF) flow through trifurcators and ''riffle'' type bifurcators. The numerical investigation is based on a 3-dimensional Eulerian- Lagrangian approach (MISTRAL/PartFlow-3D) developed by Frank et al. The numerical method is capable to predict isothermal, incompressible, steady gas- particle flows in 3-dimensional, geometrically complex flow geometries using boundary fitted, block-structured, numerical grids. Due to the very high numerical effort of the investigated gas-particle flows the numerical approach has been developed with special emphasis on efficient parallel computing on clusters of workstations or other high performance computing architectures. Besides the aerodynamically interaction between the carrier fluid phase and the PF particles the gas-particle flow is mainly influenced by particle-wall interactions with the outer wall boundaries and the inner fittings and guiding vanes of the investigated flow splitting devices. In order to allow accurate quantitative prediction of the motion of the disperse phase the numerical model requires detailed information about the particle-wall collision process. In commonly used physical models of the particle-wall interaction this is the knowledge or experimental prediction of the restitution coefficients (dynamic friction coefficient, coefficient of restitution) for the used combination of particle and wall material, e.g. PF particles on steel. In the present investigation these parameters of the particle-wall interaction model have been obtained from special experiments in two test facilities. Basic experiments to clarify the details of the particle-wall interaction process were made in a test facility with a spherical disk accelerator. This test facility furthermore provides the opportunity to investigate the bouncing process under normal pressure as well as under vacuum conditions, thus excluding aerodynamically influences on the motion of small particles in the near vicinity of solid wall surfaces (especially under small angles of attack). In this experiments spherical glass beads were used as particle material. In a second test facility we have investigated the real impact of non-spherical pulverised fuel particles on a steel/ceramic target. In this experiments PF particles were accelerated by an injector using inert gas like e.g. CO2 or N2 as the carrier phase in order to avoid dust explosion hazards. The obtained data for the particle-wall collision models were compared to those obtained for glass spheres, where bouncing models are proofed to be valid. Furthermore the second test facility was used to obtain particle erosion rates for PF particles on steel targets as a function of impact angles and velocities. The results of experimental investigations has been incorporated into the numerical model. Hereafter the numerical approach MISTRAL/PartFlow-3D has been applied to the PF flow through a ''riffle'' type bifurcator. Using ICEM/CFD-Hexa as grid generator a numerical mesh with approximately 4 million grid cells has been designed for approximation of the complex geometry of the flow splitting device with all its interior fittings and guiding vanes. Based on a predicted gas flow field a large number of PF particles are tracked throughout the flow geometry of the flow-splitter. Besides mean quantities of the particle flow field like e.g. local particle concentrations, mean particle velocities, distribution of mean particle diameter, etc. it is now possible to obtain information about particle erosion on riffle plates and guiding vanes of the flow splitting device. Furthermore the influence of different roping patterns in front of the flow splitter on the uniformness of PF mass flow rate splitting after the bifurcator has been investigated numerically. Results show the efficient operation of the investigated bifurcator in absence of particle roping, this means under conditions of an uniform PF particle concentration distribution in the inflow cross section of the bifurcator. If particle roping occurs and particle concentration differs over the pipe cross section in front of the bifurcator the equal PF particle mass flow rate splitting can be strongly deteriorated in dependence on the location and intensity of the particle rope or particle concentration irregularities. The presented results show the importance of further development of efficient rope splitting devices for applications in coal-fired power plants. Numerical analysis can be used as an efficient tool for their investigation and further optimisation under various operating and flow conditions.

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