Made available in DSpace on 2014-06-11T19:23:29Z (GMT). No. of bitstreams: 0 Previous issue date: 2010-04-30Bitstream added on 2014-06-13T19:09:17Z : No. of bitstreams: 1 perez_l_me_bauru.pdf: 2493638 bytes, checksum: 26329bfa30a60d575a769d58ce9d9493 (MD5) / Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES) / A oxidação do metanol apresenta problemas acentuadamente complexos que ainda não foram satisfatoriamente solucionados. Possui um mecanismo duplo caminho, ou seja, diretamente a CO2 ou pelo caminho alternativo via intermediários. Também como intermediário/produto da reação ocorre a formação de CO que é usualmente identificado como o agente bloqueador da superfície eletródica devido à sua adsorção irreversível. Baseado em um estudo recente da reação de oxidação do metanol sobre Pt por espectroscopia de impedância eletroquímica (EIE), este trabalho teve por objetivo aplicar a técnica de EIE no estudo da eletrocatálise da reação de oxidação do metanol sobre fases intermetálicas ordenadas de PtMn, PtSb e PtSn em meio ácido, visto que os metais Mn, Sb e Sn por apresentarem característica oxifílica, podem formar mais facilmente espécies OH que promovem a oxidação de intermediários fortemente adsorvidos nos sítios ativos da superfície eletródica. Os intermetálicos também apresentam maior distância entre os sítios da platina o que pode favorecer uma configuração de adsorção vertical da molécula de CO que é mais fácil de oxidar quando comparado a uma configuração em ponte. Uma análise prévia da atividade catalítica desses materiais para a reação de oxidação do metanol foi realizada empregando-se as técnicas de voltametria cíclica cronoamperometria. Os resultados obtidos mostraram que o processo de oxidação do metanal utilizando os intermetálicos apresentou um deslocamento para valores menos positivos do potencial de início de oxidação, necessitando de uma menor demanda energética para que o processo de oxidação ocorra sobre a superfície destes intermetálicos. A oxidação do metanol apresentou densidade de corrente de corrente de pico superior para esses materiais quando comparado... / Methanol oxidation reaction congregates very complex constraints that were not conveniently solved so far. This reaction usually follows a dual pathway, i.e. direct oxidation to CO2 or through an alternative path via stable intermediates. CO is the most commom identified intermediate of the reaction and surface blocking agent due to its irreversible adsorption characteristic. The here in research is based on recent study performed with the methanol oxidation reaction on Platinum by employing the Electrochemical Impedance Spectroscopy (EIS) technique. The aim of the research was to investigate the methanol oxidation reaction on PtMn, PtSb and PtSn ordered intermetallic surfaces, in acid medium, by means of the EIS technique. These materials were selected to the study since they have oxophilic metals (Mn, Sb and Sn) that could provide OH species on the electrode surface at electrode potentials less positive than polycrystalline Platinum under the same experimental conditions. Moreover, these surfaces also exhibits a larger Pt-Pt distance in comparison to polycrystalline Platinum that inhibits the stable bridge configuration adsorption of CO. The electrochemical data obtained have demonstrated that ehe methanol oxidation reaction on the studied surfaces presented a less positive onset potential as compared to Pt. The materials also have exhibited a higher maxima current densities and lower susceptibility for CO blocking than Pt. EIS spectra obtained fot the reaction taking place on Pt, PtSb and PtSn have presented an inductive component that is characteristic of stable intermediate adsorption process. Steady state measurements have pointed to a change in the mechanism of the reaction probably due to the action of surface oxygenated species. Furthemore, the EIS technique has been proved o be a powerful tool to investigate... (Complete abstract click electronic access below)

O objetivo deste trabalho foi a preparação de um revestimento inteligente com resina epóxi, capaz de autorreparar-se quando o sofre um defeito mecânico. A autorreparação é possibilitada pela presença de microcápsulas, dispersas na resina (revestimento de epóxi sem pigmentos) e que contêm no seu núcleo o agente de autorreparação, o óleo de linhaça. Estas cápsulas foram preparadas por uma emulsão de óleo de linhaça em água para formar micelas e sobre estas uma parede ou casca exterior de poliuréia-formaldeído. Para a avaliação da resistência à corrosão e do efeito de autorreparação do revestimento, chapas de aço carbono foram revestidas e avaliadas pela técnica de espectroscopia de impedância eletroquímica (EIE) em 0.1molL-1 1 NaCl e também foram avaliadas pelo teste acelerado de corrosão em câmara de névoa salina (SSC). Após a cura do revestimento aditivado com as microcápsulas, aplicado sobre placas de aço carbono, as medidas eletroquímicas de impedância foram realizadas em corpos de prova com um defeito mecânico provocado de forma controlada e reprodutível. Uma célula de três eletrodos foi utilizada. Estas medidas foram efetuadas após 0h, 24h e 48h da execução da incisão ou defeito mecânico. Para comparação, as mesmas medidas foram realizadas com as placas pintadas com o revestimento não-aditivado, com a mesma espessura total de 120 m. Os resultados mostraram que as cápsulas foram quebradas e se liberou o óleo de linhaça, reparando a área da incisão o defeito após pelo menos 24 horas de exposição natural ao ar ambiente. Verificou-se que para as placas revestidas sem defeito, os valores de | Z | mantiveram-se elevados. No entanto, o revestimento sem as microcápsulas, após 24 horas, mostrou uma diminuição considerável no valor de módulo de impedância, |Z|. Assim, usando a técnica de EIE foi possível avaliar quantitativamente o mecanismo de autorreparação do revestimento aditivado com microcápsulas que contêm óleo de linhaça. Os ensaios acelerados de corrosão (SSC) mostraram resultados em estreita concordância com os obtidos por EIE. / The aim of this work was the preparation of a smart coating with epoxy resin which is able to repair itself (self-healing effect) after suffering a mechanical defect. Self-healing is possible due to the presence of microcapsules, dispersed in the resin (clear type epoxy coating) and contain in their core the self-healing agent, the linseed oil. These capsules were prepared in an emulsion of linseed oil in water to form micelles and an outer skin or wall of poly(urea-formaldehyde) was formed. For the corrosion resistance and the self-healing effect evaluation of the coating, carbon steel plates were coated and tested by electrochemical impedance spectroscopy technique (EIS) in 0.1molL-1 NaCl solution and by accelerated corrosion test in salt spray chamber (SSC). After curing of the capsules additivated epoxy based clear coating applied on carbon steel plates, electrochemical impedance measurements were performed on plates with a controlled and reproducible mechanical defect. A three-electrode electrochemical cell was used. These measurements were performed after 0h, 24h and 48h of making the incision or mechanical defect. For comparison, the same measurements were performed with the plates painted with a non- capsules additivated clear coating of the same total thickness of 120 m. The results showed that the capsules were broken and released the linseed oil, which indeed have repaired the incision area after at least 24 hours of natural air aging. It was found that for the plates coated without a defect, the values of impedance modulus, |Z|, remained high. However, the coating without the capsules after 24 hours, showed a considerable decrease in |Z|. So, using EIS it was possible to quantitatively assess the mechanism of self-healing of the additivated coating using microcapsules containing linseed oil. The SSC accelerated corrosion tests showed results in close agreement with those obtained by EIS.

This study deals with pastoral guidance for persons who, due to unresolved trauma, are often emotionally and spiritually wounded and consequently exhibit internalised lies. Some important questions relating to this theme put on the table here include the following: * What is the origin of an internalised lie? * What effect do these lies have on the life of the wounded person? * What is truth and how can it be discerned? * How can the wounded person be guided and protected in the renewal of his/her thinking? The basic–theoretical research shows that being emotionally wounded and the accompanying internalisation of lies usually take place during childhood. This is the period when the child does not have the verbal, emotional or spiritual competence to interpret correctly or assimilate trauma and the accompanying injury. Further it transpires that the emotionally wounded person is engaged in a daily struggle with Satan and that the struggle mainly lodges in his heart and thoughts, and is based on lies. From this section it is also clear that only truth can overcome the onslaught of Satan's misrepresentation and that the truth can only be reached in a relationship with Jesus Christ. The wounded person has the choice of whom to follow, Satan or Jesus. It is therefore essential for such a person to take up the daily responsibility for the renewal and control of his mind. For this the Lord provides special weapons with which the struggle for renewal of one?s thoughts can successfully be approached. Meta–theoretical research has shown that optimal brain functioning is of cardinal importance in the renewal of the mind since behaviour, personality, cognitive ability, emotions as well as thoughts all originate in the brain. The brain is the most complex organ in the human body and the way it functions affects a person?s choices, vision and personality as well as success or failure in life. In the case of a person manifesting broken relationships or compulsive behaviour patterns, it must first be ascertained whether the brain functions correctly before labelling the person with some or other abnormality. The study shows that the brain does have the ability to recover with the help of diet and exercise as well as attitude of mind. The empirical study involved six collaborators who had been exposed to inter–generative trauma and consequently had exhibited internalised lies. Information relevant to trauma, medical background, head injuries and the family of origin was collected and after being processed, was presented in a genogram. The structure and style of every family as well as the role of the particular respondent in every family was represented schematically and explained to the respondent. From the practical–theoretical section it clearly emerged that emotional and spiritual healing can only take place by means of God's Word and his truth. In this respect it is essential that the injured person should take daily responsibility regarding the renewal of his mind. After all, transformation is a process demanding patience and practice as well as faith in Christ and it is clear that there are no shortcuts to healing. To reach the necessary goals in this process an integrated holistic approach is necessary where the different neighbouring sciences are involved. / Thesis (Ph.D. (Pastoral))--North-West University, Potchefstroom Campus, 2011.

This study deals with pastoral guidance for persons who, due to unresolved trauma, are often emotionally and spiritually wounded and consequently exhibit internalised lies. Some important questions relating to this theme put on the table here include the following: * What is the origin of an internalised lie? * What effect do these lies have on the life of the wounded person? * What is truth and how can it be discerned? * How can the wounded person be guided and protected in the renewal of his/her thinking? The basic–theoretical research shows that being emotionally wounded and the accompanying internalisation of lies usually take place during childhood. This is the period when the child does not have the verbal, emotional or spiritual competence to interpret correctly or assimilate trauma and the accompanying injury. Further it transpires that the emotionally wounded person is engaged in a daily struggle with Satan and that the struggle mainly lodges in his heart and thoughts, and is based on lies. From this section it is also clear that only truth can overcome the onslaught of Satan's misrepresentation and that the truth can only be reached in a relationship with Jesus Christ. The wounded person has the choice of whom to follow, Satan or Jesus. It is therefore essential for such a person to take up the daily responsibility for the renewal and control of his mind. For this the Lord provides special weapons with which the struggle for renewal of one?s thoughts can successfully be approached. Meta–theoretical research has shown that optimal brain functioning is of cardinal importance in the renewal of the mind since behaviour, personality, cognitive ability, emotions as well as thoughts all originate in the brain. The brain is the most complex organ in the human body and the way it functions affects a person?s choices, vision and personality as well as success or failure in life. In the case of a person manifesting broken relationships or compulsive behaviour patterns, it must first be ascertained whether the brain functions correctly before labelling the person with some or other abnormality. The study shows that the brain does have the ability to recover with the help of diet and exercise as well as attitude of mind. The empirical study involved six collaborators who had been exposed to inter–generative trauma and consequently had exhibited internalised lies. Information relevant to trauma, medical background, head injuries and the family of origin was collected and after being processed, was presented in a genogram. The structure and style of every family as well as the role of the particular respondent in every family was represented schematically and explained to the respondent. From the practical–theoretical section it clearly emerged that emotional and spiritual healing can only take place by means of God's Word and his truth. In this respect it is essential that the injured person should take daily responsibility regarding the renewal of his mind. After all, transformation is a process demanding patience and practice as well as faith in Christ and it is clear that there are no shortcuts to healing. To reach the necessary goals in this process an integrated holistic approach is necessary where the different neighbouring sciences are involved. / Thesis (Ph.D. (Pastoral))--North-West University, Potchefstroom Campus, 2011.

Resumo. Foi realizado um estudo epidemiológico para avaliação dos fatores determinantes para a transmissão da LTA. O estudo foi realizado na área urbana, periurbana e rural da cidade de Itambaracá, incluindo a Vila Rural e as localidades de Porto Almeida e São Joaquim do Pontal, as duas últimas próximas à área impactada pelas hidrelétricas de Canoas I e II, no rio Paranapanema. Capturou-se de fevereiro de 2004 a junho 2006, 3.187 flebotomíneos. As espécies predominantes foram Nyssomyia neivai (34,36%), Pintomyia pessoai (32,57%), Migonemya migonei (11,61%), Nyssomyia whitmani (8,82%) e Pintomyia fischeri (2,73%) todas elas com capacidade de transmissão da doença. Para Ny neivai, houve predominância de machos e para as outras espécies vetoras, as fêmeas prevaleceram, com diferença estatística significante (p<0,001). As espécies mais abundantes, segundo o índice de abundância das espécies padronizado, foram Ny neivai, Pi. pessoai, Ny whitmani, Br. brumpti, Mg migonei e Pi fischeri. As maiores freqüências e diversidade das espécies foram encontradas na localidade de Porto Almeida (PA), seguida por São Joaquim do Pontal (SJP). Ny neivai apresentou médias sazonais mais elevadas e na distribuição mensal, picos em fevereiro, maio e outubro. A maior média horária desta espécie foi registrada das 19:00 às 20:00 h (1,2) mas mostrou-se ativa das 23:00 às 10:00 h da manhã. A prevalência de Acs da classe IgG para LTA em RIFI, na população humana foi de 6,73%, nos caninos de 1,75% e nos equídeos de 16,0 %. Em EIE/ELISA, a prevalência para os caninos foi de 16,49%. Na PCR, todos os cremes leucocitários correspondentes à soros reagentes a Acs da classe IgG (humanos), e Ac totais (eqüinos e caninos) foram negativos para Leishmania sp. No inquérito sócio econômico, verificou-se que a população entrevistada em sua maioria pertence à etnia branca e à faixa etária de 30-50 anos, recebem em torno de dois salários mínimos, possuem ocupações voltadas à agricultura e pecuária, nível de escolaridade fundamental (1º grau), habita casas de alvenaria, possuem animais domésticos com seus abrigos próximos às casas. Realizam atividades de trabalho e lazer em áreas de risco em proximidades às matas, áreas com animais silvestres e domésticos e com presença de matéria orgânica, que são fatores atrativos aos flebotomíneos. A população entrevistada, de uma forma geral, desconhece os aspectos da transmissão da LTA. Observou-se em todas as localidades amostradas a presença de flebotomíneos, com predominância de cinco espécies com capacidade vetorial de agentes da LTA, destacando-se Ny. Neivai , incluindo os peridomicílios. Houve transmissão ativa da doença, ocorrendo dois casos notificados e autóctones, em área de baixa freqüência de espécimes. A soroprevalência na população humana (6,73%) foi considerável, embora seja uma área de baixa ocorrência da doença. Nas localidades onde havia um foco mais recente da doença, em SJP, os cães e eqüinos apresentaram sorologia positiva. A alta prevalência de reagentes na sorologia observada em eqüídeos sugere que estes animais poderiam ser usados como sentinela para a detecção precoce da circulação do agente da LTA nas áreas estudadas. / Abstract. An epidemiological study was carried out in the urban area of Itambaracá and rural areas of the same municipality, including Vila Rural, Porto Almeida and São Joaquim do Pontal, to investigate the phlebotomine fauna and behavioral aspects of its species and also some determining factors of the transmission of American cutaneous leishmaniasis (ACL). The last two localities mentioned are situated close to the areas impacted by the Canoas I and II hydroelectric plants on the Paranapanema river. A total of 3,187 phlebotomines were captured between February 2004 and June 2006. Nyssomyia neivai predominated (34.36%), followed by Pintomyia pessoai (32.6%), Migonemyia migonei (11.6%), Nyssomyia whitmani (8.8%) and Pintomyia fischeri (2.7%), all of them implicated in the transmission of the disease. Regarding Ny. neivai, males predominated over females which may indicate the proximity of its breeding places to the capture sites. As for all the other vector species, the females were predominant, with significant statistical differences (p < 0,001). Ny neivai, Pi. pessoai, Ny. whitmani, Br. brumpti, Mg. migonei and Pi. fischeri presented the highest values for the species standardized abundance index. The greatest frequencies and diversity of the species were found at Porto Almeida (PA), a locality situated close to a well preserved forest fragment and secondly at São Joaquim do Pontal (SJP), with degraded forest. Of all the species, Ny. neivai presented the highest monthly averages with the main peak occurring in successive months of April. Its greatest hourly average was registered at 19:00-20:00 hours, but the species presented activity from 23:00 p.m. to 10:00 a.m. The prevalence of Ac IgG class, serum-reagents for Leishmania obtained with RIFI from the human, canine and equine populations was 6.73% (20/297), 1.75% (5/285) and 16% (8/50), respectively. A prevalence of 16.4% was observed by the EIE/ELISA test only for the canine population. The buffy-coat of all the reagent human and animal blood samples was tested by the polymerase chain reaction (PCR) to investigate the presence of Leishmania, with negative results. In the socioeconomic survey, it was found that the majority of the people interviewed belonged to the white ethnic and 30-50 year-old groups, earning two minimum salaries, exercising occupations associated with agriculture and livestock breeding, of fundamental school level, inhabiting brick houses and keeping pets and domestic animals in and around them. They exercise their work and leisure activities in risk areas close to forest fragments, thus in areas containing both wild and domestic animals with the presence of organic matter, which attract the sandflies. The population interviewed was, in general, ignorant of the facts involved in ACL transmission. Sandflies were observed at all the sites sampled, with the predominance of five vectors of the ACL agents, with Ny. neivai, the main vector in all three areas, also being captured in the peridomiciles. Active transmission of the disease, with two cases registered, was observed at sites with very low frequency of this sandfly. The serum prevalence in the human population (6.73%) was considerable, despite this being an area of few registered ACL cases. In the localities in which there was a more recent focus of the disease, in SJP, the dogs and equines presented positive serology. The high prevalence of equine serum reagents suggests that these animals could be used as sentinels for the early detection of the presence of the ACL agent in the area studied.

Resumo. Foi realizado um estudo epidemiológico para avaliação dos fatores determinantes para a transmissão da LTA. O estudo foi realizado na área urbana, periurbana e rural da cidade de Itambaracá, incluindo a Vila Rural e as localidades de Porto Almeida e São Joaquim do Pontal, as duas últimas próximas à área impactada pelas hidrelétricas de Canoas I e II, no rio Paranapanema. Capturou-se de fevereiro de 2004 a junho 2006, 3.187 flebotomíneos. As espécies predominantes foram Nyssomyia neivai (34,36%), Pintomyia pessoai (32,57%), Migonemya migonei (11,61%), Nyssomyia whitmani (8,82%) e Pintomyia fischeri (2,73%) todas elas com capacidade de transmissão da doença. Para Ny neivai, houve predominância de machos e para as outras espécies vetoras, as fêmeas prevaleceram, com diferença estatística significante (p<0,001). As espécies mais abundantes, segundo o índice de abundância das espécies padronizado, foram Ny neivai, Pi. pessoai, Ny whitmani, Br. brumpti, Mg migonei e Pi fischeri. As maiores freqüências e diversidade das espécies foram encontradas na localidade de Porto Almeida (PA), seguida por São Joaquim do Pontal (SJP). Ny neivai apresentou médias sazonais mais elevadas e na distribuição mensal, picos em fevereiro, maio e outubro. A maior média horária desta espécie foi registrada das 19:00 às 20:00 h (1,2) mas mostrou-se ativa das 23:00 às 10:00 h da manhã. A prevalência de Acs da classe IgG para LTA em RIFI, na população humana foi de 6,73%, nos caninos de 1,75% e nos equídeos de 16,0 %. Em EIE/ELISA, a prevalência para os caninos foi de 16,49%. Na PCR, todos os cremes leucocitários correspondentes à soros reagentes a Acs da classe IgG (humanos), e Ac totais (eqüinos e caninos) foram negativos para Leishmania sp. No inquérito sócio econômico, verificou-se que a população entrevistada em sua maioria pertence à etnia branca e à faixa etária de 30-50 anos, recebem em torno de dois salários mínimos, possuem ocupações voltadas à agricultura e pecuária, nível de escolaridade fundamental (1º grau), habita casas de alvenaria, possuem animais domésticos com seus abrigos próximos às casas. Realizam atividades de trabalho e lazer em áreas de risco em proximidades às matas, áreas com animais silvestres e domésticos e com presença de matéria orgânica, que são fatores atrativos aos flebotomíneos. A população entrevistada, de uma forma geral, desconhece os aspectos da transmissão da LTA. Observou-se em todas as localidades amostradas a presença de flebotomíneos, com predominância de cinco espécies com capacidade vetorial de agentes da LTA, destacando-se Ny. Neivai , incluindo os peridomicílios. Houve transmissão ativa da doença, ocorrendo dois casos notificados e autóctones, em área de baixa freqüência de espécimes. A soroprevalência na população humana (6,73%) foi considerável, embora seja uma área de baixa ocorrência da doença. Nas localidades onde havia um foco mais recente da doença, em SJP, os cães e eqüinos apresentaram sorologia positiva. A alta prevalência de reagentes na sorologia observada em eqüídeos sugere que estes animais poderiam ser usados como sentinela para a detecção precoce da circulação do agente da LTA nas áreas estudadas. / Abstract. An epidemiological study was carried out in the urban area of Itambaracá and rural areas of the same municipality, including Vila Rural, Porto Almeida and São Joaquim do Pontal, to investigate the phlebotomine fauna and behavioral aspects of its species and also some determining factors of the transmission of American cutaneous leishmaniasis (ACL). The last two localities mentioned are situated close to the areas impacted by the Canoas I and II hydroelectric plants on the Paranapanema river. A total of 3,187 phlebotomines were captured between February 2004 and June 2006. Nyssomyia neivai predominated (34.36%), followed by Pintomyia pessoai (32.6%), Migonemyia migonei (11.6%), Nyssomyia whitmani (8.8%) and Pintomyia fischeri (2.7%), all of them implicated in the transmission of the disease. Regarding Ny. neivai, males predominated over females which may indicate the proximity of its breeding places to the capture sites. As for all the other vector species, the females were predominant, with significant statistical differences (p < 0,001). Ny neivai, Pi. pessoai, Ny. whitmani, Br. brumpti, Mg. migonei and Pi. fischeri presented the highest values for the species standardized abundance index. The greatest frequencies and diversity of the species were found at Porto Almeida (PA), a locality situated close to a well preserved forest fragment and secondly at São Joaquim do Pontal (SJP), with degraded forest. Of all the species, Ny. neivai presented the highest monthly averages with the main peak occurring in successive months of April. Its greatest hourly average was registered at 19:00-20:00 hours, but the species presented activity from 23:00 p.m. to 10:00 a.m. The prevalence of Ac IgG class, serum-reagents for Leishmania obtained with RIFI from the human, canine and equine populations was 6.73% (20/297), 1.75% (5/285) and 16% (8/50), respectively. A prevalence of 16.4% was observed by the EIE/ELISA test only for the canine population. The buffy-coat of all the reagent human and animal blood samples was tested by the polymerase chain reaction (PCR) to investigate the presence of Leishmania, with negative results. In the socioeconomic survey, it was found that the majority of the people interviewed belonged to the white ethnic and 30-50 year-old groups, earning two minimum salaries, exercising occupations associated with agriculture and livestock breeding, of fundamental school level, inhabiting brick houses and keeping pets and domestic animals in and around them. They exercise their work and leisure activities in risk areas close to forest fragments, thus in areas containing both wild and domestic animals with the presence of organic matter, which attract the sandflies. The population interviewed was, in general, ignorant of the facts involved in ACL transmission. Sandflies were observed at all the sites sampled, with the predominance of five vectors of the ACL agents, with Ny. neivai, the main vector in all three areas, also being captured in the peridomiciles. Active transmission of the disease, with two cases registered, was observed at sites with very low frequency of this sandfly. The serum prevalence in the human population (6.73%) was considerable, despite this being an area of few registered ACL cases. In the localities in which there was a more recent focus of the disease, in SJP, the dogs and equines presented positive serology. The high prevalence of equine serum reagents suggests that these animals could be used as sentinels for the early detection of the presence of the ACL agent in the area studied.

The number of children living in a conflict zone in 2021 reached a staggering 449 million, which represents more than one out of every six children (Save the Children, 2022). When children are exposed to armed conflict the experiences can impair cognitive and social and emotional function. These functions can in return challenge and impair the child's learning processes. Through a comparative multiple-case study, using the lens of the Ecological Systems Theory, two humanitarian interventions; BLP in Gaza by NRC and HCT in Lebanon by IRC, the research aims at shining light on the opportunities and challenges with PSS educational interventions targeting children's trauma recovery and academic achievement. The research questions seek to create an understanding about how the interventions are designed and implemented and which strategies are the most impactful and less impactful, and lastly, what recommendations can be derived from the findings to guide similar NGOs in their design and implementation process. The main results showed that both BTP and HCT interventions effectively reduced traumatic stress and improved academic achievement among the beneficiaries. BLP demonstrated strengths in its multi-leveled design, parent involvement, and comprehensive materials for teachers. HCT demonstrated strengths in creating a supportive environment and structured teacher training but had low parent involvement. The findings emphasize the importance of a multi-leveled approach to enrich the child's social ecosystem.

Le concept de développement durable fut promu à la Conférence de Rio de 1992avec l’adoption d’un certain nombre d’instruments juridiques. Le droit africain s’estprobablement adapté aux règles et aux principes inhérents au concept avec, commeconséquence, la refonte ou la révision des codes ou lois de protection del’environnement. Face aux problèmes environnementaux récurrents, à la difficilegestion intégrée des ressources en eau, à l’opérationnalisation critique de la solidaritéà l’eau potable pour tous, à la gouvernance environnementale défaillante, la questionde l’évolution efficiente du droit de l’environnement africain au regard du conceptde développement durable se pose. Il se révèle un insuccès de la saisie du conceptpar le droit africain. Au final, un nouveau modèle de droit de l’environnement, auprofit des pays de l’Afrique de l’Ouest, s’avère nécessaire. / The concept of sustainable development was promoted in the Rio Conference in1992 with the adoption of a number of legal instruments. African law has probablyadapted to the rules and principles inherent to the concept with, as a consequence,consolidation or revision of codes and laws to protect the environment. Facingrecurrent environmental problems, the difficult Integrated water resources, criticaloperationalization of solidarity drinking water for all, the failed environmentalgovernance, the question of the efficient development of the law of the Africanenvironment in relation to the concept of sustainable development arises. It proves afailure in the seizure of the concept by the African law. Finally, a new model ofenvironmental law in favor of the countries of West Africa is necessary.

Text in Afrikaans / Die herscomgestelde gesin word in hierdie navorsingstudie ondersoek as 'n kompleksa alternatiewe gesinstruktuur met eiesoortige strukturele kenmerke, probleemarecs en rituele wat nie aan die norm von die kerngesin ontleen kan word nie. In die literotuuroorsig word hierdie aspekte van nader beskou en tot die gevolgtrekking gekom dot die belangrike rol van die eie ouer in die hersoomgestelde gesin grootliks misgekyk word. Die verbondenheid van die eie ouer aan beide die ouer-kind- en die nuwe egpoorsisteme mack ditvir hom/hoar moontlik om 'n sleutelrol te vervul tydens gesinsinteroksies, eenheidsvorming en die opvoedingsgebeure in die hersoamgestelde gesin. Dit is moontlik vir die eie ouer om vanuit 'n unieke posisie as 'n buffer te dien in die problemotiese stiefouer-stiefkindverhoudinge. Hierdie maontlikheid bestaon egter slegs indien die eie ouer oor voldoende kennis, insig en voardighede beskik. 'n Uitgebreide kwalitatiewe ondersoek aan die hand van semi-gestruktureerde onderhoude met die lede van ses hersaamgestelde gesinne het die volgende tendense aan die lig gebring: • Eie overs verwag van nuwe egliede om kinders in die hersaamgestelde gesin uit die staanspoor te aanvoor en lief te he. • Eie overs koester konflikterende gevoelens ten opsigte van die dissiplinering van hul kinders deur die stiefouer. • Eie ouers, sfiefouers en kinders in hersaamgestelde gesinne goon dikwels gebuk onder d\e los van onverwerkte gevoelens van verdriet en verlies. • Die hantering van finansies ten opsigte van inwonende eie en stiefkinders, asook nie-inwonende kinders en vorige egliede skep spanning en bemoeilik goeie verhoudinge. • Eie ouers is dikwels so verdeeld tussen die belange van nul kinders en die van hul nuwe moats dot hulle dit moeilik vind om in 'n tweede huwelik 'n betekenisvolle verhouding met hul nuwe lewensmaat op te bou. Genoemde tendense het 'n bepolende rol gespeel in die ontwikkeling von 'n begeleidingsprogram vir eie ouers. Agt sessies met doelwitte geboseer op hierdie probleemoreas is gestruktureer om die eie ouer met noodsaaklike kennis en vaardighede toe te rus ten opsigte van harmoniese verhoudingstigting en -onderhouding in hersaamgesfelde gesinne. Die begeleidingsprogram is deur middel van 'n fokusgroeponderhoud aan die evaluering von vier ouerpare in hersaamgestelde gesinne onde&Werp en is aon die hand van hul aanbevelings verfyn en gefinaliseer. / Educational Studies / D. Ed.(Psychology of Education)

Summaries in English and Afrikaans / Die hersaamgestelde gesin word in hierdie navorsingstudie ondersoek as in komplekse alternatiewe gesinstruktuur met eiesoortige strukturele kenmerke, probleemareas en rituele wat nie aan die norm van die kerngesin ontleen kan word nie. In die literatuuroorsig word hierdie aspekte van nader beskou en tot die gevolgtrekking gekom dot die belangrike rol van die eie ouer in die hersaamgestelde gesin grootliks misgekyk word. Die verbondenheid van die eie ouer aan beide die ouer-kind- en die nuwe egpaarsisteme maak dit vir hom/haar moontlik om 'n sleutelrol te vervul tydens gesinsinteraksies, eenheidsvorming en die opvoedingsgebeure in die hersaamgestelde gesin. Dit is moontlik vir die eie ouer om vanuit in unieke posisie as 'n buffer te dien in die problematiese stiefouer-stiefkindverhoudinge. Hierdie moontlikheid bestaan egter slegs indien die eie ouer oor voldoende kennis, insig en vaardighede beskik. 'n Uitgebreide kwalitatiewe ondersoek aan die hand van semi-gestruktureerde onderhoude met die lede van ses hersaamgestelde gesinne het die volgende tendense aan die lig gebring Eie ouers verwag van nuwe egliede om kinders in die hersaamgestelde gesin uit die staanspoor te aanvaar en lief te he. Eie ouers koester konflikterende gevoelens ten opsigte van die dissiplinering van hul kinders deur die stiefouer. Eie ouers, stiefouers en kinders in hersaamgestelde gesinne gaan dikwels gebuk onder die las van onverwerkte gevoelens van verdriet en verlies. Die hantering van finansies ten opsigte van inwonende eie en stiefkinders, asook nie-inwonende kinders en vorige egliede skep spanning en bemoeilik goeie verhoudinge. Eie ouers is dikwels so verdeeld tussen die belange van hul kinders en die van hul nuwe maats dat hulle dit moeilik vind om in 'n tweede huwelik 'n betekenisvolle verhouding met hul nuwe lewensmaat op te bou. Genoemde tendense het 'n bepalende rol gespeel in die ontwikkeling van 'n begeleidingsprogram vir eie ouers. Agt sessies met doelwitte gebaseer op hierdie probleemareas is gestruktureer om die eie ouer met noodsaaklike kennis en vaardighede toe te rus ten opsigte van harmoniese verhoudingstigting en -onderhouding in hersaamgestelde gesinne. Die begeleidingsprogram is deur middel van 'n fokusgroeponderhoud aan die evaluering van vier ouerpare in hersaamgestelde gesinne onderwerp en is aan die hand van hul aanbevelings verfyn en gefinaliseer. / In this research study the reconstituted family is investigated as a complex alternative family structure with distinctive structural characteristics, problem areas and rituals which cannot be adopted from the norm of the nuclear family. In the literature survey these aspects are examined closely and the conclusion is drawn that the important role of the biological parent in the reconstituted family is ignored to a large extent. The biological parent's commitment to both the parent-child and new couple systems allows him/her to play a key role in family interactions, unit formation and educational events in the reconstituted family. It is possible for the biological parent to act as a buffer in the problematic stepparent-stepchild relationships from a unique perspective. However, this possibility only exists if the biological parent possesses sufficient knowledge, insight and skills. An extensive qualitative investigation on the basis of semi-structured interviews with members of six reconstituted families revealed the following tendencies: Biological parents expect their new spouses to accept and love children in the reconstituted family from the onset. Biological parents harbour conflicting feelings regarding the disciplining of children by the stepparent. Biological parents, stepparents and children in reconstituted families often still carry the burden of unresolved feelings of sadness and loss. The handling of finances with regard to resident own and stepchildren, as well as non-resident children and former spouses creates tension and compromises good relationships. Biological parents are often so divided between the interests of their own children and those of their new spouses that they find it difficult to build a meaningful relationship with their new spouse in a second marriage. The tendencies mentioned played a decisive role in the development of a guidance programme for biological parents. Eight sessions with aims based on these problem areas were structured to equip biological parents with the necessary knowledge and skills in respect of the development and maintenance of harmonious relationships in reconstituted families. The guidance programme was subjected to the evaluation of four sets of parents in reconstituted families by means of a focus group interview and was refined and finalised on the basis of their recommendations. / Educational Studies / D. Ed. (Sielkundige Opvoedkunde)