Στην παρούσα Διπλωματική Εργασία μελετάται και αναλύεται η Ηλεκτρομαγνητική συμπεριφορά βασικών κυκλωμάτων και στοιχείων, τα οποία απαντώνται πάνω σε Πλακέτες Τυπωμένων Κυκλωμάτων. Η σχεδίαση και ανάλυση των μοντέλων γίνεται χρησιμοποιώντας τα Ηλεκτρομαγνητικά λογισμικά πακέτα της Agilent, ΕΜPro και ADS, ενώ για τον υπολογισμό χρήσιμων παραμέτρων χρησιμοποιείται η ελεύθερη εφαρμογή της Agilent, Appcad και η εφαρμογή Linecalc, η οποία είναι ενσωματωμένη στο ADS. Αρχικά, γίνεται μια σύντομη αναφορά στις σύγχρονες τάσεις που επικρατούν στην περιοχή των Τυπωμένων Κυκλωμάτων και περιγράφεται η χρησιμότητα των τοπολογιών που αναλύονται. Επιπροσθέτως, αναφέρεται η αναγκαιότητα και οι περιπτώσεις κατά τις οποίες είναι απαραίτητη η διεξαγωγή ηλεκτρομαγνητικής ανάλυσης των κυκλωμάτων, αλλά και τα προτερήματα που αυτή προσφέρει. Παρουσιάζεται η χρησιμότητα και αναλύεται η δομή μιας μαιανδρικής μικροταινιακής γραμμής εισαγωγής καθυστερήσεως και συγκρίνονται οι εκπομπές της ως προς τις εκπομπές μιας ευθείας μικροταινιακής γραμμής. Έπειτα, μελετάται η κατανομή του ρεύματος στο επίπεδο αναφοράς μιας απλούστερης γεωμετρίας μαιανδρικής μικροταινιακής γραμμής και παρουσιάζονται φαινόμενα περισσότερο αισθητά σε υψηλές συχνότητες. Έπειτα, μελετώνται οι εκπομπές από μια γεωμετρία μικροταινιακής γραμμής, η οποία διασχίζει σχισμή στο επίπεδο αναφοράς. Επίσης, μελετάται η συμπεριφορά μικροταινιακής γραμμής ευρισκόμενης στο χείλος μιας πλακέτας. Επιπλέον, μελετάται ένα πρόβλημα σχεδιάσεως αποτελεσματικής ηλεκτρομαγνητικής θωρακίσεως και υπολογίζεται η αποδοτικότης της θωρακίσεως. Σε επόμενο κεφάλαιο, μελετάται η επίδραση ασυνεχειών ευρισκόμενων σε μια δομή μικροταινιακής γραμμής και σχεδιάζεται ένα μεταϋλικό, ενώ παράλληλα προσδιορίζονται χαρακτηριστικές παράμετροι της δομής. Ακολούθως, σχεδιάζονται τρία είδη δομών που περιλαμβάνουν οπές via. Αυτές είναι: μία απλή via , μια δομή διαφορικών via και μια εφαρμογή απομονώσεως δυο συζευγμένων ταινιογραμμών χρήσει ενός φράχτη από οπές via. Τέλος, προσομοιώνεται η λειτουργία μιας πραγματικής πλακέτας και υπολογίζονται οι ηλεκτρομαγνητικές της εκπομπές στο μακρινό πεδίο. Παράλληλα, παρουσιάζονται ορισμένα στατιστικά του χρόνου εκτελέσεως και των απαιτούμενων πόρων για την προσομοίωση, γίνονται σχόλια και επισημάνσεις που αφορούν στα χαρακτηριστικά των χρησιμοποιούμενων αλγορίθμων για τη διεξαγωγή μετεπεξεργασίας των δεδομένων και δίνονται χρήσιμες συμβουλές όσον αφορά σε χαρακτηριστικά του λογισμικού Προσομοιώσεως και σε δυνατότητες επιταχύνσεως της Προσομοιώσεως που προσφέρονται από το ίδιο το λογισμικό. / -

Made available in DSpace on 2015-03-26T13:33:27Z (GMT). No. of bitstreams: 1 texto completo.pdf: 819545 bytes, checksum: 489ab74a37b75a1309fe61f9aaec5c2d (MD5) Previous issue date: 2007-05-04 / Conselho Nacional de Desenvolvimento Científico e Tecnológico / This dissertation analyzes and interprets the image of the Brazilian rural middle propagated by the media, in specific the Veja Magazine, printed Brazilian mass media. The analyze unit choused was the information weekly magazine that have the most public in Brazil, the Veja Magazine, studied through years of 2004 to 2005. This option have relation with the proposes of this work, that are to verify the Brazilian rural image showed to an heterogenic public but not necessary linked with the rural middle. The study wants to show the important role of the mass communications media that deals with the journalistic information in a task of mediate the reality conceptions. This study agrees with the researches that show us that the mass communications media are a tool able to exercise some influence in the messages ideas from the receivers. This analyze used the idea of symbolic power and its relationship with the language and its interactions mediate like elements that explain the news production process in a hypothetical of settings scheduling and news framings. This research, begins with the idea that the rural can be better understood in the nowadays, by the light of the concept of multifunction in the agricultural activity. So, the intention was to identify the main subjects that have relationship to the rural middle in the journal messages, but mainly the way how it is categorized, caricatured or appreciated. To it, a search have done to try to find ways to justificate and to base the journalistic messages that help to show a kind of rural representation. The reflection explore better objectived elements, like the analyze of the selection and the placement of the messages in the news, and valorized elements in the content of the message itself, like the photography ones and the font function in the text. The data in this study shows the mass media like a tool of sense mediation and power socially legitimate, able to inform and form its frames produced about the rural middle. / Esta dissertação analisa e interpreta a imagem do meio rural brasileiro veiculado pela mídia, especificamente, a revista Veja, mídia noticiosa impressa. A unidade de análise escolhida foi a revista semanal de informação de maior circulação nacional, a Revista Veja, pesquisada ao longo dos anos 2004 e 2005. Esta opção condiz com os propósitos deste trabalho, de verificar a imagem do rural mostrada a um público heterogêneo e não necessariamente vinculado ao meio rural. A pesquisa tem como pressuposto o importante papel dos meios de comunicação de massa que lidam com a informação jornalística na tarefa de mediar as concepções de realidade. Este estudo situa-se na perspectiva das pesquisas que consideram os meios de comunicação de massa como instrumentos capazes de exercer algum efeito sobre as concepções dos receptores das mensagens. Para a análise tomou-se como base o conceito de poder simbólico em sua relação com a linguagem e as interações mediadas como elementos que explicam o processo de produção de notícias dentro da hipótese do agenda setting e do enquadramento das notícias. Nesta pesquisa, partiu-se da idéia de que o rural poder ser melhor entendido hoje, à luz do conceito de multifuncionalidade da atividade agrícola. Buscou-se, assim, identificar os principais temas relativos ao meio rural nas mensagens jornalísticas, mas principalmente o modo como ele é categorizado, caricaturado ou valorado. Para isso, recorreu- se à procura de artifícios de justificação e fundamentação da mensagem jornalística que ajudam a revelar um tipo de representação do rural. A reflexão explora elementos de caráter mais objetivo, como a análise da seleção e disposição das mensagens no noticiário, além, de elementos valorativos presentes no conteúdo da própria mensagem, como as fotográficas e função das fontes no texto. Os dados depreendidos deste estudo mostram a mídia como um instrumento de mediação de sentido e poder socialmente legitimado, capaz informar e formar a partir dos enquadramentos que produz sobre o meio rural.

The aim of this two years master’s thesis in Archive, Library and Museum studies is to investigate how the National Library of Sweden collects, arranges and provides access to its collection of printed ephemera. As a comparison, the thesis also looks at how Lund University Library is working with the same tasks. The main sources of information in this thesis comes from participant observations and interviews conducted with informants within the two libraries mentioned above. Document studies of the library’s internal documents and the Swedish Legal Deposit Law has also been used to get additional information. The findings in this thesis has been analyzed with a model based on a practice theory and a knowledge organization theory. The starting point in the investigation was to look at how these two libraries receives printed ephemera through legal deposits, if there are any problems connected to the legal deposits and if that possibly has an influence on the printed ephemera collections. The next part of the investigation focuses on how these collections has been organized with various classification systems over the years. In addition to this the survey wanted to find out if- and in what way these different systems have had an effect on the availability of this material and what tools the libraries uses to make it easier to find specific material within the collections and make it available for users. The results of the investigation show that National Library of Sweden and Lund University Library resave a wide range of material throw legal deposits but not nearly as much as they should get. One big problem is that many producers print their material outside of Sweden and are not aware that they are obligated to give copies of this to the Swedish Legal Deposit Library’s. The survey also reached the conclusion that the way the material is arranged and stored has a big impact on how accessible it is. However, by using cataloguing and digitalization the libraries can make this material more visible, and thus also more accessible.

Dielectric resonator antenna (DRA) technologies are applicable to a wide variety of mobile wireless communication systems. The principal energy loss mechanism for this type of antenna is the dielectric loss, and then using modern ceramic materials, this may be very low. These antennas are typically of small size, with a high radiation efficiency, often above 95%; they deliver wide bandwidths, and possess a high power handling capability. The principal objectives of this thesis are to investigate and design DRA for low profile personal and nomadic communications applications for a wide variety of spectrum requirements: including DCS, PCS, UMTS, WLAN, UWB applications. X-band and part of Ku band applications are also considered. General and specific techniques for bandwidth expansion, diversity performance and balanced operation have been investigated through detailed simulation models, and physical prototyping. The first major design to be realized is a new broadband DRA operating from 1.15GHz to 6GHz, which has the potential to cover most of the existing mobile service bands. This antenna design employs a printed crescent shaped monopole, and a defected cylindrical DRA. The broad impedance bandwidth of this antenna is achieved by loading the crescent shaped radiator of the monopole with a ceramic material with a permittivity of 81. The antenna volume is 57.0  37.5  5.8 mm3, which in conjunction with the general performance parameters makes this antenna a potential candidate for mobile handset applications. The next class of antenna to be discussed is a novel offset slot-fed broadband DRA assembly. The optimised structure consists of two asymmetrically located cylindrical DRA, with a rectangular slot feed mechanism. Initially, designed for the frequency range from 9GHz to 12GHz, it was found that further spectral improvements were possible, leading to coverage from 8.5GHz to 17GHz. Finally, a new low cost dual-segmented S-slot coupled dielectric resonator antenna design is proposed for wideband applications in the X-band region, covering 7.66GHz to 11.2GHz bandwidth. The effective antenna volume is 30.0 x 25.0 x 0.8 mm3. The DR segments may be located on the same side, or on opposite sides, of the substrate. The end of these configurations results in an improved diversity performance.

Du fait de nombreuses avancées technologiques et scientifiques, l'ensemble du réseau de télécommunications a évolué vers une complexité croissante intégrant désormais des débits très importants. Grâce aux larges bandes passantes offertes par les bandes de fréquences millimétriques, les prochaines générations visent à permettre l'augmentation du nombre de services multimédias et de partage de contenus en haute définition. Cette évolution pose la problématique de concevoir des systèmes sans-fils capables de fonctionner en haute fréquence avec des rendements et coûts acceptables, ainsi qu'un encombrement minimum. Ce travail se situe dans le cadre du développement de circuits passifs, de types filtres, coupleurs et guides d'ondes qui répondent à ces défis. Nous avons développé une technique de miniaturisation pour des dispositifs en technologie imprimée, dans un premier temps dédiée aux fréquences inférieures à 20 GHz. Celle-ci repose sur la notion d'onde lente, définie comme la capacité d’une structure à ralentir la propagation des ondes la traversant. Une analyse théorique ainsi que des méthodes de conception ont été développées, puis validées par des mesures. Dans un second temps, nous avons proposé deux technologies distinctes permettant l'intégration de guides d'ondes performants en bande millimétrique en collaboration avec deux laboratoires partenaires. Une étude théorique, la conception de motifs de test et les résultats de mesure sont présentés. Ces travaux constituent une base pour la réalisation ultérieure en bande millimétrique de topologies miniaturisées grâce aux ondes lentes. / The last decades have seen the evolution of communication networks towardgreater complexity and efficiency, being now able to carry significant data rates. This evolution is the result of both scientific and technological breakthroughs. Thanks to the wide bandwidths available at millimeter-wave frequencies, the future generations will be able to supply for the the increasing demand in multimedia services, especially high-definition videos. The design of wireless systems which operate at high frequencies with acceptable efficiency, costs, and minimum size thus constitute a decisive challenge. In this context, this work focuses on the development of passive circuits such as filters, couplers and waveguides which address these issues. We developed a miniaturization technique for printed circuits technology, which in a first step is dedicated to frequencies below 20 GHz. This technique is based on a slow-wave concept, defined as the property of any structure which impose lower velocities to the electromagnetic waves. A theoretical analysis, as well as design methods were established and confirmed by measurements. Secondly, we proposed two distinct technological solutions for the integration of efficient waveguides at millimeter-wave frequencies. This work was achieved in collaboration with two other laboratories. A theoretical study, design of test features and measurementswere performed. These results intend to constitute a basis for the future realization of miniaturized slow-wave circuits at millimeter-wave frequency bands.

In the past decade, the design and manufacturing of intelligent multipurpose underwater vehicles has increased significantly. In the wide range of studies conducted in this field, the flexibility and autonomy of these devices with respect to their intended performance had been widely investigated. This work is related to the design and manufacturing of a small and lightweight autonomous underwater vehicle (AUV) with vision capabilities allowing detecting and contouring obstacles. It is indeed an exciting challenge to build a small and light submarine AUV, while making tradeoffs between performance and minimum available space as well as energy consumption. In fact, due to the ever-increasing in equipment complexity and performance, designers of AUVs are facing the issues of limited size and energy consumption. By using a pair of thrusters capable to rotate 360o on their axis and implementing a mass shifter with a control loop inside the vehicle, this later can efficiently adapt its depth and direction with minimal energy consumption. A prototype was fabricated and successfully tested in real operating conditions (in both pool and ocean). It includes the design and embedding of accurate custom multi-purpose sensors for multi-task operation as well as an enhanced coordinated system between a high-speed processor and accustomed electrical/mechanical parts of the vehicle, to allow automatic controlling its movements. Furthermore, an efficient tracking system was implemented to automatically detect and bypass obstacles. Then, fuzzy-based controllers were coupled to the main AUV processor system to provide the best commands to safely get around obstacles with minimum energy consumption. The fabricated prototype was able to work for a period of three hours with object tracking options and five hours in a safe environment, at a speed of 0.6 m/s at a depth of 8 m.

Abstract This study is about what happens to text and image content in a printed teaching material when adapted to a digital format. The purpose of my work is to find out if readability is changing in the new medium.  The theoretical focus of the study is readability, text and image in collaboration, as well as multimodality. To find out if the digital format affects readability, i have performed two text analyzes, a readability analysis of the printed material and a comparative analysis of the digital material. I have also conducted interviews with teachers and experts about the teaching methods. A test and a participant observation were conducted with the target group where my improvement proposal was compared with the existing material.  The conclusions i have come to is that there must be clear links between text and image in a digital teaching material. Color markings in body text with word explanations can interfere with the reading rhythm and too many heading levels can confuse the reader. The most important conclusion is, however, that how readable a text is depends on the audience's previous knowledge, objectives and motivation for the subject. A hard-worded factual text does necessarily need to be easier by splitting the text into short paragraphs, but it can however, make it more difficult to understand the content. / Sammanfattning Den här studien handlar om vad som händer med text och bildinnehåll i ett tryckt läromedel när det ska anpassas till ett digitalt format. Syftet med mitt arbete är att ta reda på om läsbarheten förändras i det nya mediet.  Studiens teoretiska fokus ligger på: Läsbarhet, text och bild i samverkan, samt multimodalitet. För att ta reda på om det digitala formatet påverkar läsbarheten har jag utfört två textanalyser, en läsbarhetsanalys av det tryckta materialet och en komparativ analys av det digitala. Jag har även utfört intervjuer med lärare och experter inom läromedelsutgivning. En utprovning samt en deltagarobservation genomfördes med målgruppen där mitt förbättringsförslag jämfördes med det befintliga materialet. De slutsatser jag har kommit fram till är att det behöver finnas tydliga kopplingar mellan text och bild i ett digitalt läromedel. Färgmarkeringar i brödtext med ordförklaringar kan störa läsrytmen och för många rubriknivåer kan förvirra läsaren. Den viktigaste slutsatsen är dock att hur läsbar en text är beror på målgruppens förkunskaper, läsmål och motivation för ämnet. En faktatext med svåra ord behöver nödvändigtvis inte bli lättare för att man delar in texten i korta stycken, det kan snarare bli svårare att förstå innehållet.

Ces travaux examinent le potentiel d’un papier à fort lissé pour la production de masse de tags RFID-HF imprimés. Les caractérisations menées sur le papier Powercoat HD mettent en évidence une haute tolérance à la température et une faible rugosité. De fait, il se présente ainsi comme une sérieuse alternative à l’utilisation des films polymères (PET, PEN, PI, etc.), permettant de développer pleinement les performances électriques d’encres conductrices métalliques.Deux procédés d’impression industriels ont été considérés, la flexographie et la sérigraphie ayant tout deux fait leurs preuves depuis plusieurs décennies pour l’impression graphique à hautes cadences. Le potentiel de leur utilisation pour l’impression à grande échelle de dispositifs électroniques à bas-coût est discuté dans ces travaux. De plus, les performances électriques d’encres commerciales à base d’argent sont étudiées en fonction de la taille des particules qui les composent. En effet, l’utilisation de particules métalliques à l’échelle nanométrique pourra faciliter l’activation des mécanismes de diffusion atomique, améliorant ainsi le contact physique entre les particules et favorisant la conduction électrique. En parallèle, les encres à microparticules sont moins coûteuses et leurs conditions d’utilisation moins contraignantes. Toutefois, la coalescence des particules métalliques après l’impression ne pourra être initiée sans un traitement thermique de recuit.Le recuit est usuellement réalisé dans une étuve ou un tunnel à air chaud, la température doit alors rester inférieure à la tolérance du substrat. Cela permet d’atteindre des performances électriques qui restent limitées pour des durées de procédé de l’ordre de plusieurs minutes. Afin de tenir compte des contraintes industrielles d’une production à grande échelle et de permettre d’obtenir les meilleures performances électriques en un temps réduit, l’un des principaux axes de recherche exploré consiste au déploiement des technologies émergentes de recuit photonique proche infrarouge (NIR) et lumière intense pulsée (IPL). Ces dernières sont basées sur l’absorption de l’énergie lumineuse par le film d’encre provoquant ainsi sont échauffement rapide. L’important différentiel d’absorption entre les encres et le substrat contribue, en outre, à une sélectivité de ces procédés permettant de limiter la dégradation du support tout en atteignant au niveau de l’encre, des températures pouvant être supérieures à 300°C. Pour chaque procédé de recuit, l’influence des différents paramètres sur les performances électriques finales a pu être étudiée par la mise en place d’un suivi in-situ de la résistance, permettant un échantillonnage allant jusqu’à 250 kHz.Finalement, des boucles RFID-HF ont été imprimées, recuites dans les conditions précédemment optimisées puis caractérisées. Une estimation des coûts de production a été menée afin de distinguer les contributions liées à l’encre, au support et à la puce électronique en silicium. Les résultats obtenus mettent en évidence le potentiel du papier Powercoat HD, couplé à une impression en flexographie et à un recuit proche infrarouge, permettant alors la production à grande échelle de tags RFID-HF pour un coût matière de l’ordre de 5 centimes d’euros. / This work examines the potential of a very smooth paper for the mass production of printed RFID-RF tags. Characterizations on Powercoat HD paper demonstrate high temperature tolerance and very low roughness. It thus represents a serious alternative to the use of polymeric films (PET, PEN, PI, etc.), enabling the electrical performance of metallic conductive inks to be fully developed.Two industrial printing processes have been considered, flexography and screen printing, and their use were discussed for the printing of low-cost electronic devices. Moreover, the electrical performances of commercial silver based inks are studied according to the size of their particles. Indeed, the use of metal particles at the nanometric scale can facilitate the activation of the atomic diffusion mechanisms, thus improving the physical contact between the particles and promoting electrical conduction. In parallel, microparticles inks are cheaper and their conditions of use less restrictive. In any case, the coalescence of the metal particles after printing cannot be initiated without a thermal sintering treatment.Sintering is usually carried out in an oven or hot air tunnel, the temperature must therefore remain below the tolerance of the substrate. This leads to limited electrical performances for long process duration of several minutes. In order to take into account the industrial constraints of large-scale production and to achieve the best electrical performance in a short time, one of the main explored research areas is the deployment of emerging near-infrared (NIR) and intense pulsed light (IPL) photonic technologies. These latter are based on the absorption of light energy by the ink film thus causing rapid heating. The important absorption differential between the inks and the substrate allows high heating selectivity which makes it possible to limit the degradation of the substrate while the ink temperatures may be greater than 300 ° C. For each sintering process, the influence of the various parameters on the final electrical performance has been studied by setting up an in-situ resistance monitoring, allowing sampling frequency up to 250 kHz.Finally, RFID-HF loops were printed, sintered under previously optimized conditions and then characterized. An estimate of the production costs was carried out in order to distinguish the contributions related to the ink, the substrate and the silicon chip. The obtained results demonstrate the potential of Powercoat HD paper, coupled with flexographic roll-to-roll printing and near-infrared technology, enabling the large-scale production of RFID-HF tags at a material cost of the order of 5 euros cents.

Data de aprova??o ausente. / Submitted by Jos? Henrique Henrique (jose.neves@ufvjm.edu.br) on 2017-03-29T18:49:58Z No. of bitstreams: 2 license_rdf: 0 bytes, checksum: d41d8cd98f00b204e9800998ecf8427e (MD5) wagner_barbosa_souza.pdf: 2617971 bytes, checksum: 3d7e6b01cafdb0a61d93af504071663c (MD5) / Approved for entry into archive by Rodrigo Martins Cruz (rodrigo.cruz@ufvjm.edu.br) on 2017-04-24T16:36:52Z (GMT) No. of bitstreams: 2 license_rdf: 0 bytes, checksum: d41d8cd98f00b204e9800998ecf8427e (MD5) wagner_barbosa_souza.pdf: 2617971 bytes, checksum: 3d7e6b01cafdb0a61d93af504071663c (MD5) / Made available in DSpace on 2017-04-24T16:36:52Z (GMT). No. of bitstreams: 2 license_rdf: 0 bytes, checksum: d41d8cd98f00b204e9800998ecf8427e (MD5) wagner_barbosa_souza.pdf: 2617971 bytes, checksum: 3d7e6b01cafdb0a61d93af504071663c (MD5) Previous issue date: 2016 / Com o avan?o exponencial da ind?stria de eletr?nicos, o consumo destes produtos tamb?m est? crescendo largamente. Com isso, os descartes destes equipamentos tamb?m crescem na mesma propor??o. Por ano, no mundo, estima-se que mais de 25 milh?es de toneladas de lixo eletr?nico sejam descartadas. Neste trabalho foi desenvolvido um novo m?todo hidrometal?rgico ambientalmente seguro para a extra??o seletiva de cobre, n?quel e prata provenientes de res?duos de placas de circuito impresso (PCI), empregando Sistemas Aquosos Bif?sicos (SAB) como t?cnica de extra??o. O comportamento de extra??o dos ?ons met?licos Cu (II), Ni(II), Fe(III) e Ag(I)em SAB formado por copol?mero tribloco L64 + MgSO4 + H2O foi avaliado para a otimiza??o do m?todo, verificando a influ?ncia dos seguintes par?metros experimentais sobre a extra??o dos analitos: valores de pH do SAB (3,0; 6,0; 9,0 e 11,0); natureza e concentra??o dos agentes extratores 1-(2-piridil-azo)-2-naftol (PAN) para os estudo de extra??o do Cu(II), 1-nitroso-2-naftol (1N2N) e dimetilglioxima (DMG) para a extra??o do ?on Ni(II), tiocianato (SCN) e ditizona (Dz) para a extra??o da Ag(I). A efici?ncia de recupera??o seletiva dos metais foi avaliada por meio da an?lise da porcentagem de extra??o (%E) e do fator de separa??o (S) entre os ?ons de interesse. As melhores condi??es para extra??o seletiva foram: PAN [3,5 mmol.Kg-1] em pH = 6,0 em 6 etapas consecutivas para separa??o do Cu(II), DMG [5,00 mmol.Kg-1] em pH = 9,0 para o Ni(II) e SCN[5,20 mmol.Kg-1] em pH = 9,0 para a Ag(I) . Em todas as situa??es foram obtidos valores de fator de separa??o(S) entre o analito e os concomitantes met?licos maiores que 103. As condi??es ?timas obtidas foram aplicadas ao lixiviado de PCI para a extra??o de cobre, n?quel e prata de forma sequencial, obtendo-se altos valores de S entre o analito e os concomitantes met?licos (SCu,Ni= 1,46 x 103, SCu,Fe= 1,55 x 104, SCu,Ag= 1,59 x 104, SNi,Fe= 3,27 x 104, SNi,Ag= 3,47 x 104 eSAg,Fe= 4,80 x 103).Ap?s a extra??o de cada metal foi realizado um estudo de stripping em uma ?nica etapa, onde 89,5%, 92,5% e 82,5% de Cu(II), Ni(II) e Ag(I), respectivamente foram disponibilizados para a etapa de eletrodeposi??o. Portanto o m?todo utilizando SAB se mostrou eficiente e dentro dos princ?pios da qu?mica verde, pois utiliza componentes at?xicos, biodegrad?veis e recicl?veis e de r?pida separa??o de fases sem a forma??o de emuls?es est?veis. Sendo um m?todo alternativo para a extra??o liquido ? liquido tradicional. / Disserta??o (Mestrado) ? Programa de P?s-Gradua??o em Qu?mica, Universidade Federal dos Vales do Jequitinhonha e Mucuri, [2016]. / With the exponential advancement of electronic industry, the consumption of these products is also growing wide. With this, the drops of this equipment also grow at the same rate. A year in the world, it is estimated that more than 25 million tons of electronic waste are disposed.This work developed a new environmentally safe hydrometallurgical method for the selective extraction of copper, nickel and silver from waste printed circuit board (PCB) using Aqueous Two-Phase Systems (SAB) as extraction technique. The extraction behavior of metal ions Cu (II), Ni (II), Fe (III) and Ag (I) SAB formed by tri-block copolymer L64 + MgSO4 + H2O was evaluated for the optimization of the method by checking the influence of the following experimental parameters on the extraction of analytes: the SAB pH (3.0, 6.0, 9.0 and 11.0); nature and concentration of agents extractors 1- (2-pyridyl-azo) -2-naphthol (PAN) Cu for the extraction method (II), the 1-nitroso-2-naphthol (1N2N) and dimethylglyoxime (DMG) for ion extraction Ni (II), thiocyanate (SCN) and dithizone (Dz) for the extraction of Ag (I).The selective metal recovery efficiency was evaluated by the percentage extraction analysis (% E) and separation factor (S) between the ions of interest. The best conditions for selective extractions were NAP [3,5 mmol.Kg-1] at pH 6.0 in 6 consecutive stages for separation of Cu (II) DMG [5.00 mmol.Kg-1] pH = 9.0 for Ni (II) and SCN [5,20 mmol.Kg-1] at pH = 9.0 for Ag (I). In all cases they were obtained separation factor values (S) between the analyte and the larger metal Concomitant 103. The obtained optimum conditions were applied to the PCI leached copper extraction, nickel and silver sequentially, yielding if high S values between the analyte and the metal concomitant (SCU, Ni = 1.46 x 103, SCU, Fe = 1.55 x 104, SCU, Ag = 1.59 x 104, SNI, Fe = 3.27 x 104, SNI, Ag = 3.47 x 104 and SAg, Fe = 4.80 x 103).After extraction of each metal it was made a study stripping in one step, where 89.5%, 92.5% and 82.5% Cu (II), Ni (II) and Ag (I), respectively, were available for the electroplating step. Therefore, the method using BSA was efficient and within the principles of green chemistry, because it uses non-toxic, biodegradable and recyclable and fast phase separation without the formation of stable emulsions components. As an alternative method for liquid - liquid extraction traditional.

Submitted by André Bianchi Laraia (andreblaraia@yahoo.com.br) on 2018-08-29T22:49:26Z No. of bitstreams: 1 Dissertacao-Andre-Bianchi-Laraia.pdf: 2142300 bytes, checksum: 9264414d38ac4ce5ec3be46acb98ca44 (MD5) / Rejected by Pamella Benevides Gonçalves null (pamella@feg.unesp.br), reason: Solicitamos que realize correções na submissão seguindo as orientações abaixo: • Necessário fazer ajuste no sumario na lateral direita nas numerações. • A palavra APÊNDICE A deve ser centralizada A palavra APÊNDICE A deve ser centralizada • Referências. A palavra Referências deve ser centralizada, As referencias devem ser justificadas, espaço simples com um espaço simples(enter) entre elas. • Sobre a elaboração das referencias e citações favor solicitar orientação para ajuste com a bibliotecária Pâmella - pamella.benevides@unesp.br • A palavra APÊNDICE A deve ser centralizada Mais informações acesse o link: http://www2.feg.unesp.br/Home/Biblioteca21/diretrizes-2016.pdf Agradecemos a compreensão. on 2018-08-30T12:07:55Z (GMT) / Submitted by André Bianchi Laraia (andreblaraia@yahoo.com.br) on 2018-09-12T01:58:28Z No. of bitstreams: 1 Tese-Andre-Bianchi-Laraia-v20-converted.pdf: 2144718 bytes, checksum: eef37a1c04c8a387ddbff2e31f67db35 (MD5) / Approved for entry into archive by Pamella Benevides Gonçalves null (pamella@feg.unesp.br) on 2018-09-12T17:38:03Z (GMT) No. of bitstreams: 1 laraia_ab_me_guara.pdf: 2144718 bytes, checksum: eef37a1c04c8a387ddbff2e31f67db35 (MD5) / Made available in DSpace on 2018-09-12T17:38:03Z (GMT). No. of bitstreams: 1 laraia_ab_me_guara.pdf: 2144718 bytes, checksum: eef37a1c04c8a387ddbff2e31f67db35 (MD5) Previous issue date: 2018-07-31 / Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES) / Este trabalho apresenta o desenvolvimento de um processo de tratamento com plasma para melhorar ametalização química de placas de circuito impresso (PCI). A pluma de plasma é gerada em argônio a partir da descarga de barreira dielétrica (DBD) promovida entre uma agulha cirúrgica e um cilindro usando capilar de borosilicato como dielétrico. A tensão picoa-pico aplicada foi de 5 kV, com forma de onda senoidal na frequência de 37 kHz e potência de descarga em torno de 765 mW. O substrato é um composto de fibra de vidro e resina epóxi. Com incidência perpendicular da pluma de plasma na superfície, o diâmetro da área tratada circular é de 10 mm. Desta forma, o ângulo de contato reduz de 75 ° a 45 ° com 3 s de interação entre superfície da amostra e a ponta do plasma e o ângulo atinge o mínimo de 33 ° após 180 s de tempo de tratamento. A metalização química foi feita com banhos seqüenciais de solução de paládio e finalizada com banho de solução aquosa de cobre. Testes de adesão padrão mostraram uma forte adesão das camadas de metal nas superfícies previamente tratadas com as plumas de plasma. Esta adesão melhora com o tempo de tratamento. A melhoria na metalização foi observada em superfície plana e também em furos usados para conectar diferentes camadas em PCIs. A área metalizada na superfície dos buracos é maior nos orifícios tratados. Quanto maior o tempo de tratamento, maior é essa área. Todos os resultados indicaram que a técnica de tratamento por plasma de placas de fibra de vidro melhora a sua metalização química pelo cobre, levando a uma adesão mais uniforme e eficaz do metal à superfície com um método ambientalmente amigável / This work reports the development of a plasma treatment process to improve the chemical metallization of printed circuit boards (PCB). The plasma plume is generated in argon from a dielectric barrier discharge (DBD) promoted between a surgical needle and a cylinder using a borosilicate capillary as dielectric. The applied peak-to-peak voltage was 5 kV, with sinusoidal waveform at 37 kHz frequency and power in the discharge around 765 mW. The substrate was a composite of fiberglass and epoxy resin. With perpendicular incidence of the plasma plume on the surface the diameter of the circular treated area was 10 mm. In this area the contact angle reduces from 75° to 45° with 3 s of the plasma-surface interaction and the angle reaches the minimum of 33° after 180 s of treatment time. Chemical metallization was made with sequential baths of solution of palladium and finished with bath of aqueous solution of copper. Standard adhesion tests showed a strong adhesion of the metal layer on surfaces previously treated with the plasma plumes. This adhesion improves with the treatment time. The improvement in the metallization was observed on flat surface and also in holes used to connect different layers in PCB’s. The metallized area on the surface of the holes is larger in treated holes. The longer the treatment time the larger is this area. All these results indicated that the technique of plasma treatment of fiberglass boards improves its chemical metallization by copper leading to a more uniform and effective adhesion of the metal to the surface with an environmental friendly method