Eight rodent species with fossorial activity differing in a number of characteristics such as ecology, climatic conditions, geographical distribution, or kinship were studied using infrared thermography in order to describe their surface temperature and its patterns. An attempt to describe the relation between surface temperature and varied social organisation in burrowing rodents was made.

En France, Le secteur du bâtiment représente 40% de la consommation énergétique et 25% des émissions de CO₂. Afin de réduire ces impacts, une nouvelle Réglementation Thermique 2012, est rentrée en application. Dans ce contexte, l’Ecole Centrale de Lille et l’entreprise Norpac ont choisi d’engager une thèse CIFRE dans le but de développer un nouveau système d’isolation thermique par l’extérieur pour le bâtiment. Le choix s’est porté sur l’utilisation de matériaux textiles pour composer ce système appelé « Isolpac », en partenariat avec les entreprises Dickson, PEG, et l’association CLUBTEX. Les travaux de recherche ont d’abord été consacrés à la caractérisation hygrothermique, mécanique et chimique des différents matériaux qui composent le nouveau panneau d’isolation afin de définir leur propriétés intrinsèques, de les comparer avec des matériaux classiques, et de pouvoir valider leur choix pour le nouveau système. Deux méthodes d’essais de vieillissement accéléré ont été appliquées aux toiles.Ensuite, un intérêt particulier a été porté sur l’équilibre hygrothermique du panneau, à travers une simulation dynamique sur le logiciel Wufi® réalisée suite à la caractérisation préalable. En outre, la réaction au feu des panneaux et des perspectives d’essais pour garantir les performances mécaniques ont été étudiées.Enfin, la recherche de techniques de fixation et d’assemblage des panneaux est présentée. Des essais de pose in situ à l’échelle 1 ont été réalisés. Les perspectives d’essais liés à la résistance mécanique et au feu du système sont présentées. Un projet de façade démonstratrice est décrit afin d’être le support d’une demande d’avis technique expérimental du CSTB. / In France, the building industry represents 40% of the total energy consumption and 25% of the total carbon dioxide emissions. In the objective of decreasing those impacts, a new thermal regulation called “Réglementation Thermique 2012” (RT2012), has been applied. In that context, the Ecole Centrale de Lille and the company Norpac, have chosen to engage a CIFRE thesis in order to develop a new external thermal insulation system for buildings. It was chosen to use textile materials to compose that system called “Isolpac”, in partnership with Dickson, PEG and the CLUBTEX association. At first, the research work was devoted to the hygrothermal, mechanical and chemical characterisation of the different materials composing the new insulation panel, to define the intrinsic properties of different materials, to compare them with conventional materials, in order to validate the choice of materials for the new insulation system. Two accelerated ageing methods were applied on the fabrics.Then, a particular interest is focused on the hygrothermal equilibrium of the panel by using a dynamic simulation on the software Wufi® following the previous characterization. Moreover, a work on the fire reaction of the panel and on the perspectives of other tests needed to guarantee the mechanical strength was carried out.Finally, the search of fixation and assembling techniques for the panels is presented. Installation in situ at scale one were made. The perspectives of tests for qualifying the mechanical strength and the fire resistance are described. A project of a demonstrating façade is presented to be the support for a demand of an Experimental Technical Agreement of the CSTB

O hexaluminato de cálcio (CaAl12O19 ou CA6) poroso é um material promissor para aplicações de isolamento térmico pois combina baixa condutividade térmica (~0,33 Wm-1K-1 a 1400 °C), resistência mecânica razoável (2 – 8 MPa), inércia química, boa refratariedade (Tf ~1830 °C) e alta resistência ao choque térmico. Existem várias rotas para se obter o CA6 por meio de reações em temperaturas acima de 1300 °C, usando diversas fontes de Al2O3 e CaO, assim como diferentes métodos de processamento. No entanto, embora suas propriedades físicas tenham sido avaliadas, dois pontos principais ainda requerem investigação: o impacto das características das matérias-primas no desenvolvimento da microestrutura de sistemas porosos formados in situ, e a evolução da microestrutura e propriedades de sistemas obtidos a partir de CA6 pré-formado. Neste trabalho, foram produzidas peças de CA6 in situ a partir de diferentes fontes de Al2O3 (alumina calcinada e hidróxido de alumínio) e carbonato de cálcio (CaCO3) de diferentes granulometrias, processados por prensagem uniaxial e moldagem direta de suspensões e submetidas a diferentes tratamentos térmicos. As amostras (verdes e secas e após tratamento térmico) foram submetidas à análise microestrutural (MEV e DRX) e dilatométrica, ensaios para determinação das propriedades físicas (porosidade total, distribuição de tamanho de poros e condutividade térmica) e propriedades mecânicas (resistência à ruptura por compressão e módulo elástico). Estruturas à base de CA6 formado in situ obtidas por prensagem e moldagem direta apresentaram elevada porosidade (até 71 %) e uma resistência à compressão acima de 10 MPa. Verificou-se que o processo de conformação determinou a porosidade à verde inicial da peça, enquanto o tamanho de partícula de alumina induziu a um crescimento de grão assimétrico (partícula grossa) ou à densificação da peça (partícula fina). Dois mecanismos antagonistas acontecem ao mesmo tempo na reação in situ: a reação expansiva da formação de aluminatos intermediários (efeito porogênico) e a densificação das partículas de Al2O3. As partículas de carbonato tiveram uma grande influência no tamanho final dos poros. O efeito porogênico do hidróxido de alumínio foi efetivo até um conteúdo máximo de 50 %vol. / Porous calcium hexaluminate (CaAl12O19 or CA6) is a promising material for thermal insulation applications because it combines low thermal conductivity (~0,33 Wm-1K-1 at 1400° C), reasonable mechanical strength (2 – 8 MPa), chemical inertia, good refractoriness (Tf ~1830 °C) and high resistance to thermal shock. There are several routes to obtain CA6 by reactions at temperatures above 1300 °C, using various sources of Al2O3 and CaO, as well as different processing methods. However, although its physical properties have been studied, two main points still require investigation: the impact of the characteristics of the raw materials on the development of the microstructure of in situ formed porous systems, and the evolution of the microstructure and properties of systems obtained from preformed CA6. In this study, in situ CA6 bodies were produced from different sources of Al2O3 (calcined alumina and aluminum hydroxide) and calcium carbonate (CaCO3) of different granulometries, processed by uniaxial pressing and direct molding of suspensions and thermally treated at different temperatures. The samples (green and heat treated ones) were submitted to microstructural analysis (SEM and XRD) and dilatometry, also tests to determine the physical properties (total porosity, Hg porosimetry and thermal conductivity) and mechanical properties (compression strength and elastic modulus). In situ formed CA6-based structures obtained by pressing and direct molding showed high porosity (up to 71%) and a compressive strength above 10 MPa. It was found that the conformation process determined the initial porosity of the green body, while particle size of alumina may induce asymmetric grain growth (coarse particle) or densification of the ceramic body (fine particle). Two antagonistic mechanisms occur at the same time in the in situ reaction: the expansive reaction of the formation of intermediate aluminates (porogenic effect) and the densification of Al2O3 particles. The carbonate particles had a great influence on the final pore size. The porogenic effect of aluminum hydroxide was effective up to a maximum content of 50% vol.

År 1987 trädde en ny byggnadslag i kraft, Plan- och bygglagen(PBL). I och med den nya lagen minskade kommunens och byggnadsnämndens kontroll av projekteringshandlingar och besiktningar ute på arbetsplatsen. Efter lagändringen beror den slutgiltiga kvaliteten på en byggnad i större utsträckning på byggherrens och entreprenörernas egenkontroll. P.g.a. olika intressekonflikter inom kommunen, och att det kan förekomma starka kopplingar mellan byggherre och entreprenör, är det inte alltid självklart att kommunens tillsyn vid nybyggnation gällande till exempel egenskapskrav på energihushållning och värmeisolering utförs tillfredsställande.Med ovanstående i åtanke undersökte vi fyra flerbostadshus, två i Värnamo kommun samt två i Kristianstad. Vi undersökte om husen uppfyller de ställda värmeisoleringskraven enligt BBR(Boverkets Byggregler) 9 Kap. samt vilka krav som fanns med i respektive projekts kontrollplan. Endast ett av de fyra husen uppfyllde de ställda kraven. I kommunens kontrollplaner för de undersökta objekten ställs krav på värmeisoleringsberäkningar men några beräkningar på detta finns ej arkiverade hos kommunerna. / In 1987, a new law of building became effective, Plan- och bygglagen(PBL). The building committees' inspection of construction sites and documents decreased. The final quality of the buildings now depended in greater extent on the property developers and the contractors internal control. Due to different interests within the municipality and because of strong connections between property developers and contractors, it is not always a matter of course that e.g. the inspection of thermal insulation and energy housekeeping is executed in a satifactory fashion. With the above in mind we examined four multi-dwelling buildings, two in municipality of Värnamo and two in Kristianstad. We examined if the buildings comply with the thermal insulation requirement according to BBR (the swedish building code) and which requirements that were stated in the different projects documents of inspection.Only one out of the four buildings complies with the requirements according to BBR. In the municipality documents there are requirements of thermal insulation calculations but there are no documents that verifies that such calculations have been executed.

<p>År 1987 trädde en ny byggnadslag i kraft, Plan- och bygglagen(PBL). I och med den nya lagen minskade kommunens och byggnadsnämndens kontroll av projekteringshandlingar och besiktningar ute på arbetsplatsen. Efter lagändringen beror den slutgiltiga kvaliteten på en byggnad i större utsträckning på byggherrens och entreprenörernas egenkontroll. P.g.a. olika intressekonflikter inom kommunen, och att det kan förekomma starka kopplingar mellan byggherre och entreprenör, är det inte alltid självklart att kommunens tillsyn vid nybyggnation gällande till exempel egenskapskrav på energihushållning och värmeisolering utförs tillfredsställande.Med ovanstående i åtanke undersökte vi fyra flerbostadshus, två i Värnamo kommun samt två i Kristianstad. Vi undersökte om husen uppfyller de ställda värmeisoleringskraven enligt BBR(Boverkets Byggregler) 9 Kap. samt vilka krav som fanns med i respektive projekts kontrollplan. Endast ett av de fyra husen uppfyllde de ställda kraven. I kommunens kontrollplaner för de undersökta objekten ställs krav på värmeisoleringsberäkningar men några beräkningar på detta finns ej arkiverade hos kommunerna.</p> / <p>In 1987, a new law of building became effective, Plan- och bygglagen(PBL). The building committees' inspection of construction sites and documents decreased. The final quality of the buildings now depended in greater extent on the property developers and the contractors internal control. Due to different interests within the municipality and because of strong connections between property developers and contractors, it is not always a matter of course that e.g. the inspection of thermal insulation and energy housekeeping is executed in a satifactory fashion. With the above in mind we examined four multi-dwelling buildings, two in municipality of Värnamo and two in Kristianstad. We examined if the buildings comply with the thermal insulation requirement according to BBR (the swedish building code) and which requirements that were stated in the different projects documents of inspection.Only one out of the four buildings complies with the requirements according to BBR. In the municipality documents there are requirements of thermal insulation calculations but there are no documents that verifies that such calculations have been executed.</p>

R??sum?? : L???isolation thermique est essentielle dans de nombreux types de MEMS (micro-syst??mes ??lectro-m??caniques). Elle permet de r??duire la consommation d?????nergie, am??liorer leurs performances, ou encore isoler la zone chaude du reste du dispositif, ce qui est essentiel dans les syst??mes sur puce. Il existe quelques mat??riaux et techniques d???isolation pour les MEMS, mais ils sont limit??s. En effet, soit ils ne proposent pas un niveau d???isolation suffisant, sont trop fragiles, ou imposent des contraintes trop importantes sur la conception du dispositif et sont difficiles ?? int??grer. Une approche int??ressante pour l???isolation, d??montr??e dans la litt??rature, est de fabriquer des pores de taille nanom??trique dans le silicium par gravure ??lectrochimique. En nanostructurant le silicium ainsi, on peut diviser sa conductivit?? thermique par un facteur de 100 ?? 1000, le transformant en isolant thermique. Cette solution est id??ale pour l???int??gration dans les proc??d??s de fabrication existants des MEMS, car on garde le silicium qui est d??j?? utilis?? pour leur fabrication, mais en le nanostructurant localement, on le rend isolant l?? o?? on en a besoin. Par contre sa porosit?? cause des probl??mes : mauvaise r??sistance chimique, structure instable au-del?? de 400??C, et tenue m??canique r??duite. La facilit?? d???int??gration des semiconducteurs poreux est un atout majeur, nous visons donc de r??duire les d??savantages de ces mat??riaux afin de favoriser leur int??gration dans des dispositifs en silicium. Nous avons identifi?? deux approches pour atteindre cet objectif : i) am??liorer le Si poreux ou ii) d??velopper un nouveau mat??riau. La premi??re approche consiste ?? amorphiser le Si poreux en l???irradiant avec des ions ?? haute ??nergie (uranium, 110 MeV). Nous avons montr?? que l???amorphisation, m??me partielle, du Si poreux entra??ne une diminution de sa conductivit?? thermique, sans endommager sa structure poreuse. Cette technique r??duit sa conductivit?? thermique jusqu????? un facteur de trois, et peut ??tre combin??e avec une pr??-oxydation afin d???atteindre une r??duction d???un facteur cinq. Donc cette m??thode permet de r??duire la porosit?? du Si poreux, et d???att??nuer ainsi les probl??mes de fragilit?? m??canique caus??s par la porosit?? ??lev??e, tout en gardant un niveau d???isolation ??gal. La seconde approche est de d??velopper un nouveau mat??riau. Nous avons choisi le SiC poreux : le SiC massif a des propri??t??s physiques sup??rieures ?? celles du Si, et donc ?? priori le SiC poreux devrait conserver cette sup??riorit??. La fabrication du SiC poreux a d??j?? ??t?? d??montr??e dans la litt??rature, mais avec peu d?????tudes d??taill??es du proc??d??. Sa conductivit?? thermique et tenue m??canique n???ont pas ??t?? caract??ris??es, et sa tenue en temp??rature que de fa??on incompl??te. Nous avons men?? une ??tude syst??matique de la porosification du SiC en fonction de la concentration en HF et le courant. Nous avons impl??ment?? un banc de mesure de la conductivit?? thermique par la m??thode ?? 3 om??ga ?? et l???avons utilis?? pour mesurer la conductivit?? thermique du SiC poreux. Nous avons montr?? qu???elle est environ deux ordres de grandeur plus faible que celle du SiC massif. Nous avons aussi montr?? que le SiC poreux est r??sistant ?? tous les produits chimiques typiquement utilis??s en microfabrication sur silicium. D???apr??s nos r??sultats il est stable jusqu????? au moins 1000??C et nous avons obtenu des r??sultats qualitatifs encourageants quant ?? sa tenue m??canique. Nos r??sultats signifient donc que le SiC poreux est compatible avec la microfabrication, et peut ??tre int??gr?? dans les MEMS comme isolant thermique. // Abstract : Thermal insulation is essential in several types of MEMS (micro electro-mechanical systems). It can help reduce power consumption, improve performance, and can also isolate the hot area from the rest of the device, which is essential in a system-on-chip. A few materials and techniques currently exist for thermal insulation in MEMS, but these are limited. Indeed, either they don???t have provide a sufficient level of insulation, are too fragile, or restrict design of the device and are difficult to integrate. A potentially interesting technique for thermal insulation, which has been demonstrated in the literature, is to make nanometer-scale pores in silicon by electrochemical etching. By nanostructuring silicon in this way, its thermal conductivity is reduced by a factor of 100 to 1000, transforming it into a thermal insulator. This solution is ideal for integration in existing MEMS fabrication processes, as it is based on the silicon substrates which are already used for their fabrication. By locally nanostructuring these substrates, silicon is made insulating wherever necessary. However the porosity also causes problems : poor chemical resistance, an unstable structure above 400???C, and reduced mechanical properties. The ease of integration of porous semiconductors is a major advantage, so we aim to reduce the disadvantages of these materials in order to encourage their integration in silicon-based devices. We have pursued two approaches in order to reach this goal : i) improve porous Si, or ii) develop a new material. The first approach uses irradiation with high energy ions (100 MeV uranium) to amorphise porous Si. We have shown that amorphisation, even partial, of porous Si leads to a reduction of its thermal conductivity, without damaging its porous structure. This technique can reduce the thermal conductivity of porous Si by up to a factor of three, and can be combined with a pre-oxidation to achieve a five-fold reduction of thermal conductivity. Therefore, by using this method we can use porous Si layers with lower porosity, thus reducing the problems caused by the fragility of high-porosity layers, whilst keeping an equal level of thermal insulation. The second approach is to develop a new material. We have chosen porous SiC: bulk SiC has exceptional physical properties and is superior to bulk Si, so porous SiC should be superior to porous Si. Fabrication of porous SiC has been demonstrated in the literature, but detailed studies of the process are lacking. Its thermal conductivity and mechanical properties have never been measured and its high-temperature behaviour has only been partially characterised. We have carried out a systematic study of the effects of HF concentration and current on the porosification process. We have implemented a thermal conductivity measurement setup using the ???3 omega??? method and used it to measure the thermal conductivity of porous SiC. We have shown that it is about two orders of magnitude lower than that of bulk SiC. We have also shown that porous SiC is chemically inert in the most commonly used solutions for microfabrication. Our results show that porous SiC is stable up to at least 1000???C and we have obtained encouraging qualitative results regarding its mechanical properties. This means that porous SiC is compatible with microfabrication processes, and can be integrated in MEMS as a thermal insulation material.

R??sum?? : L???isolation thermique est essentielle dans de nombreux types de MEMS (micro-syst??mes ??lectro-m??caniques). Elle permet de r??duire la consommation d?????nergie, am??liorer leurs performances, ou encore isoler la zone chaude du reste du dispositif, ce qui est essentiel dans les syst??mes sur puce. Il existe quelques mat??riaux et techniques d???isolation pour les MEMS, mais ils sont limit??s. En effet, soit ils ne proposent pas un niveau d???isolation suffisant, sont trop fragiles, ou imposent des contraintes trop importantes sur la conception du dispositif et sont difficiles ?? int??grer. Une approche int??ressante pour l???isolation, d??montr??e dans la litt??rature, est de fabriquer des pores de taille nanom??trique dans le silicium par gravure ??lectrochimique. En nanostructurant le silicium ainsi, on peut diviser sa conductivit?? thermique par un facteur de 100 ?? 1000, le transformant en isolant thermique. Cette solution est id??ale pour l???int??gration dans les proc??d??s de fabrication existants des MEMS, car on garde le silicium qui est d??j?? utilis?? pour leur fabrication, mais en le nanostructurant localement, on le rend isolant l?? o?? on en a besoin. Par contre sa porosit?? cause des probl??mes : mauvaise r??sistance chimique, structure instable au-del?? de 400??C, et tenue m??canique r??duite. La facilit?? d???int??gration des semiconducteurs poreux est un atout majeur, nous visons donc de r??duire les d??savantages de ces mat??riaux afin de favoriser leur int??gration dans des dispositifs en silicium. Nous avons identifi?? deux approches pour atteindre cet objectif : i) am??liorer le Si poreux ou ii) d??velopper un nouveau mat??riau. La premi??re approche consiste ?? amorphiser le Si poreux en l???irradiant avec des ions ?? haute ??nergie (uranium, 110 MeV). Nous avons montr?? que l???amorphisation, m??me partielle, du Si poreux entra??ne une diminution de sa conductivit?? thermique, sans endommager sa structure poreuse. Cette technique r??duit sa conductivit?? thermique jusqu????? un facteur de trois, et peut ??tre combin??e avec une pr??-oxydation afin d???atteindre une r??duction d???un facteur cinq. Donc cette m??thode permet de r??duire la porosit?? du Si poreux, et d???att??nuer ainsi les probl??mes de fragilit?? m??canique caus??s par la porosit?? ??lev??e, tout en gardant un niveau d???isolation ??gal. La seconde approche est de d??velopper un nouveau mat??riau. Nous avons choisi le SiC poreux : le SiC massif a des propri??t??s physiques sup??rieures ?? celles du Si, et donc ?? priori le SiC poreux devrait conserver cette sup??riorit??. La fabrication du SiC poreux a d??j?? ??t?? d??montr??e dans la litt??rature, mais avec peu d?????tudes d??taill??es du proc??d??. Sa conductivit?? thermique et tenue m??canique n???ont pas ??t?? caract??ris??es, et sa tenue en temp??rature que de fa??on incompl??te. Nous avons men?? une ??tude syst??matique de la porosification du SiC en fonction de la concentration en HF et le courant. Nous avons impl??ment?? un banc de mesure de la conductivit?? thermique par la m??thode ?? 3 om??ga ?? et l???avons utilis?? pour mesurer la conductivit?? thermique du SiC poreux. Nous avons montr?? qu???elle est environ deux ordres de grandeur plus faible que celle du SiC massif. Nous avons aussi montr?? que le SiC poreux est r??sistant ?? tous les produits chimiques typiquement utilis??s en microfabrication sur silicium. D???apr??s nos r??sultats il est stable jusqu????? au moins 1000??C et nous avons obtenu des r??sultats qualitatifs encourageants quant ?? sa tenue m??canique. Nos r??sultats signifient donc que le SiC poreux est compatible avec la microfabrication, et peut ??tre int??gr?? dans les MEMS comme isolant thermique. // Abstract : Thermal insulation is essential in several types of MEMS (micro electro-mechanical systems). It can help reduce power consumption, improve performance, and can also isolate the hot area from the rest of the device, which is essential in a system-on-chip. A few materials and techniques currently exist for thermal insulation in MEMS, but these are limited. Indeed, either they don???t have provide a sufficient level of insulation, are too fragile, or restrict design of the device and are difficult to integrate. A potentially interesting technique for thermal insulation, which has been demonstrated in the literature, is to make nanometer-scale pores in silicon by electrochemical etching. By nanostructuring silicon in this way, its thermal conductivity is reduced by a factor of 100 to 1000, transforming it into a thermal insulator. This solution is ideal for integration in existing MEMS fabrication processes, as it is based on the silicon substrates which are already used for their fabrication. By locally nanostructuring these substrates, silicon is made insulating wherever necessary. However the porosity also causes problems : poor chemical resistance, an unstable structure above 400???C, and reduced mechanical properties. The ease of integration of porous semiconductors is a major advantage, so we aim to reduce the disadvantages of these materials in order to encourage their integration in silicon-based devices. We have pursued two approaches in order to reach this goal : i) improve porous Si, or ii) develop a new material. The first approach uses irradiation with high energy ions (100 MeV uranium) to amorphise porous Si. We have shown that amorphisation, even partial, of porous Si leads to a reduction of its thermal conductivity, without damaging its porous structure. This technique can reduce the thermal conductivity of porous Si by up to a factor of three, and can be combined with a pre-oxidation to achieve a five-fold reduction of thermal conductivity. Therefore, by using this method we can use porous Si layers with lower porosity, thus reducing the problems caused by the fragility of high-porosity layers, whilst keeping an equal level of thermal insulation. The second approach is to develop a new material. We have chosen porous SiC: bulk SiC has exceptional physical properties and is superior to bulk Si, so porous SiC should be superior to porous Si. Fabrication of porous SiC has been demonstrated in the literature, but detailed studies of the process are lacking. Its thermal conductivity and mechanical properties have never been measured and its high-temperature behaviour has only been partially characterised. We have carried out a systematic study of the effects of HF concentration and current on the porosification process. We have implemented a thermal conductivity measurement setup using the ???3 omega??? method and used it to measure the thermal conductivity of porous SiC. We have shown that it is about two orders of magnitude lower than that of bulk SiC. We have also shown that porous SiC is chemically inert in the most commonly used solutions for microfabrication. Our results show that porous SiC is stable up to at least 1000???C and we have obtained encouraging qualitative results regarding its mechanical properties. This means that porous SiC is compatible with microfabrication processes, and can be integrated in MEMS as a thermal insulation material.

Šiame baigiamajame magistro darbe nagrinėjama polistireninio putplasčio stiprumo savybės. Teorinėje dalyje pateikta literatūros analizė, bendros žinios apie polistireninį putplastį, gamybos būdai, panaudojimo galimybės. Išnagrinėta trijų didžiausių gamintojų Lietuvoje siūloma produkcija. Apžvelgti reikalavimai pastatų atitvarų šiluminei varžai, išnagrinėta termoizoliacinio sluoksnio storio pokytis nuo TSRS laikų iki dabar. Eksperimentinėje dalyje aprašomos naudotos medžiagos; jų charakteristikos; gniuždomasis stipris; šliejamasis stipris; išnagrinėta skirtingo tankio bandinių mikrostruktūra ir makrostruktūra. Aprašomi rezultatai, naudojant statistinės analizės programą atliekama jų analizė, suformuluojamos išvados. / The present work of Master degree studies analyzes the properties of expanded polystyrene.Theoretical par of this work introduces analysis of references, general information on expanded polystyrene, manner of production and fields of application. The work analyzes production offered by three biggest manufacturers in Lithuania, reviews the requirements applicable to thermal resistance of enclosures of the building, analyses alteration of thickness of a heat insulation layer comparing the situation in Soviet Union time and nowadays. Experimental part describes the used material, their properties, compressive strength, shear strength; analyses microstructure and macrostructure of samples of different density. The work presents the results and analysis of the results by applying software of statistical analysis; formulation of conclusions.

Thermal insulation materials made from natural fibrous materials, such as cellulose fibers, have advantages over others from a sustainability point of view. However, cellulosic materials are generally prone to mold and absorb moisture, and these have negative effects on the insulation properties, the durability of insulation materials, and interior air quality. In this thesis, cellulose-fiber-based insulation foams were prepared from bleached chemithermomechanical softwood pulp, and these foams showed promising thermal insulation properties and fungal resistance. Hydrophobic extractives were isolated from birch (Betula verrucosa) outer bark and used to improve the water resistance of the foams, which were impregnated in solutions of extractives and then dried. The modified foams showed greater water resistance, and the modification had no negative effects on the thermal insulation, fungal resistance, and compressive strength of the foams. Another potential problem with low density cellulosic thermal insulation materials is their poor reaction-to-fire properties. Cellulose-fiber-based insulation foams were prepared from formulations containing bleached chemithermomechanical softwood pulp and commercial fire retardants to improve the reaction of the foams to fire. Single-flame source test results showed that the foams containing 20% expandable graphite (20% EG) or 25% synergetic (25% SY) fire retardant had significantly improved reaction-to-fire properties and passed class E, which reflected that they can resist a small flame attack without substantial flame spreading for a short period according to EN 13501-1. Compared with the reference without any fire retardant, the peak heat release rate (Peak-HRR) of the 20% EG and 25% SY decreased by 62% and 39% respectively when the samples were subjected to a radiance heat flow of 25 kW m-2 in a Cone Calorimeter. The thesis demonstrates that it is possible to produce cellulose-fiber-based insulation materials with improved properties in terms of fungal, improved water resistance and reaction-to-fire properties. / <p>QC 20170428</p> / Energy-efficient cellulosic insulation products/panels for green building solutions

Les futures missions d'exploration spatiale nécessitent le stockage d'ergols cryogéniques sur de longues durées.Sous l'effet d'entrées thermiques résiduelles, l'ergol se vaporise et le réservoir s'auto-pressurise, pouvant entraîner la rupture du réservoir pour des missionssuffisamment longues. Cette thèse s'intéresse à un système de contrôle, appelé Thermodynamic Venting System (TVS), reposant sur l'injection d'un jet sous-refroidi dans le réservoir.L'injection entraîne la condensation de la vapeur, la déstratification du bain liquide et donc une baisse de pression dans le réservoir.L'étude expérimentale a permis de mettre en place une technique originale d'isolation active générant une condition de paroi à flux de chaleurnet nul. Une base de données expérimentales, d'auto-pressurisation et de contrôle TVS, a été constituée avec ce nouveau dispositif.Elle a notamment permis de valider un modèle thermodynamique homogène permettant de prédire l'évolution de température et depression dans le réservoir. Ce modèle a été étendu pour de façon à décrire le comportement de tous les éléments constitutifs du système TVS.Un outil de dimensionnement du système complet a ainsi été mis en place.En le couplant à une plateforme d'optimisation, un système TVS optimal a pu être établi pour une mission de démonstration.Enfin une étude numérique a permis de mettre en évidence, pour notre cas d'étude, les faiblesses des modèles de changement de phase disponibles dans les solveursCFD commerciaux. Une modélisation prédictive du changement de phase a été mise en place dans un code de calcul recherche puis validée sur uncas académique 1D. / Future operations in space exploration require the ability to store cryogens for long duration. Residual heat loads induce cryogenic propellant vaporization andtank self-pressurization (SP), eventually leading to storage failure for long enough mission duration.This thesis focuses on a control strategy, called Thermodynamic Venting System (TVS), based on a recirculating liquid subcooled injection. The injection results inan ullage condensation, a liquid bath destratification and thus a tank pressure reduction.Experimentally, an original active insulation technique has been set up, yielding a net zero heat flux wall boundary condition. A data base ofself-pressurisation and TVS control experiments has been gathered with this new aparatus.It was used to validate an homogeneous thermodynamic model providing a fast prediction of tank temperature and pressure during control.This model has been extended to discribe the TVS system behaviour including all its components. This full system design tool has been coupled with an optimisationplatform and an optimal TVS design has been established for a demonstration mission.Furthermore, a numerical study has evidenced the weakness of commercial CFD software to simulate phase change, for TVS configuration.A predictive phase change formulation has been set up in a home-made software and validated on a 1D academic case.